Water Treatment Plant Residue Management Modification

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    WATER TREATMENT

    PLANT RESIDUE

    MANAGEMENT

    ALAN ANTONYI Semester MTech

    Environmental Engineering

    VNIT

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    CONTENTS

    Introduction

    What is residual management plan?

    Different categories of residuals inwater treatment

    Sources of residues

    ProcessMethods of disposals

    Chemical recovery

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    RESIDUALS

    Unwanted waste materials removed from

    water

    Compounds created by the addition of

    chemicals at different stages of treatment

    such as floc, lime solids etc

    Organic and inorganic compounds in

    gaseous, liquid and solid forms

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    What is residual management plan?

    Characterize form, quantity, and quality

    of the residuals.

    Determine appropriate regulatory requirements.

    Identify feasible disposal options.

    Select appropriate residuals processing/

    treatment technologies.

    Develop a residuals management strategy thatmeets both the economic and noneconomic

    goals established for a water treatment facility.

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    RESIDUAL CATEGORIESSludge waste produced in sedimentation basins in

    conventional coagulation-filtration plants or lime softeningplants

    Spent filter back wash water that has been used to cleanfilters in conventional or softening plants

    Membrane concentrateliquid waste consisting ofcontaminants rejected by the membrane and any additivesapplied before membrane treatment

    Brine residualsliquid waste similar to the concentrategenerated by the desalination membrane operations butproduced by the ion exchange process

    Spent carbon - carbon that has exceeded its useful life asadsorbent

    Off gaseswaste produced by air stripping facilities thatreleases vapour to the atmosphere

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    RESIDUAL SOURCES

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    TREATMENT PROCESSES AND

    RESIDUES PRODUCED

    PRE SEDIMENTATION The residues generated consist of clays, silts,

    sands, and other heavy settleable materials

    present in the raw water.

    COAGULATION, FLOCCULATION, AND

    SEDIMENTATION

    coagulant metal hydroxides along with source

    water natural organic matter, suspended solids,microorganisms, radionuclides, and other

    organic and inorganic constituents.

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    Contd.

    Moisture content : (97 to 99.5%)

    Color : varies from light brown to black

    Feathery, bulky, and gelatinous.

    requires additional processing such as thickening,dewatering, or drying prior to disposal.

    difficult to dewater.

    LIME SOFTENING calcium carbonate (85 to 95% total solids)

    hydroxide of magnesium, aluminium, and othermetals.

    clay and silt particles.

    minor amounts of unreacted lime .

    inorganic and organic matter.

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    Contd..

    FILTRATION clay and silt

    microorganisms (bacteria, viruses, and protozoan cysts)

    colloidal and precipitated humic substances

    natural organic particulates from the decay ofvegetation.

    ION EXCHANGE

    Calcium and mg ions, also removes nitrates, barium,

    radium, arsenate, selenite, excess levels of fluoride, lead,

    and chromate

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    Contd..

    ACTIVATED CARBON removes ions or molecules from the source water by

    adsorbing the chemicals in the source water onto the

    treatment media

    remove naturally occurring organic materials, taste, odor,synthetic organic compounds, as well as disinfection by-

    products

    Residuals generated by GAC include backwash water (or

    surface wash water) and spent media.

    Backwash water generally contains the removed contaminants

    such as suspended solids, biological films, organics, and some

    filter media.

    The spent media (or carbon) is sent off site for regeneration or

    disposal.

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    TECHNOLOGIES AND

    PRACTICES FOR

    PREVENTING, TREATING,

    DISPOSING OF, AND

    DISCHARGING SOURCE

    WATER TREATMENTRESIDUALS

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    BMPs.

    Pollution prevention and waste

    reduction.Residuals treatment.

    Disposal of wastes.

    Discharge of wastes.

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    ZERO DISCHARGE STATUS

    Generate residues but do not discharge

    multiple benefits such as water conservation,

    environmental improvements, and cost

    reduction. Achieved by a combination of pollution

    prevention/waste management and residuals

    treatment practices, such as recycling,

    evaporation, composting, landfill disposal, spray

    irrigation, underground injection, and land

    application.

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    POLLUTION PREVENTION

    AND WASTE REDUCTION Optimizing source water intake conditions to reduce

    suspended solids and thereby reduce source water

    treatment requirements.

    Optimizing filter media for finished water and residuals.

    Optimizing pH to reduce coagulant chemicals used.

    Reducing softening chemicals used by frequent monitoring

    of source water hardness.

    Returning backwash water and filter-to-waste to the head

    of the source water treatment plant for reuse. Reusing precipitative softening chemicals by recycling

    softening residuals.

    Recovering treatment chemicals.

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    RESIDUAL HANDLING

    PROCESSES

    Thickening

    Conditioning

    Dewatering

    Drying

    Disposal and Reuse

    Coagulant recovery

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    THICKENING

    increase the solids content of the residuals by removing a

    portion of the water

    1. Gravity thickener

    2. Floatation thickener

    3. Gravity belt thickener

    Gravity Thickener

    carbonate and metallic hydroxide residuals areconveyed to gravity settling tanks at a flow rate that allows

    the residuals sufficient retention time to settle

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    CONDITIONING

    Chemical conditioning

    This conditioning involves the addition

    of ferric chloride, lime, or polymer

    Physical conditioning

    1.Freeze-thaw conditioning:

    This process may be accomplishedthrough either an open-air process in cold

    weather climates or through mechanical

    equipment.

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    Contd..

    2. Thermal conditioning: Thermal conditioning at high

    temperatures (350F to 400F) under

    high pressure

    Effective when there is a high organic

    content present in the solids.

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    DEWATERINGStorage Ponds and Lagoons

    Can be used for storage, thickening,

    dewatering, or drying.

    Final residual disposal

    Sand drying beds

    dewater residuals by gravity drainage,followed by evaporation. Water drainsthrough the sand and exits through theunder-drain.

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    Mechanical Dewatering

    Processes

    Belt Filter Presses

    Sludge sandwiched between two

    porous belts is passed over and underrollers of various diameters

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    CENTRIFUGE

    A process that uses the force developed by

    fast rotation of a cylindrical bowl to

    separate solids from liquids.

    When a mixture of solids and water

    enters the centrifuge, it is forced against

    the bowls interior walls, forming a pool of

    liquid that separates into two distinctlayers.

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    DISPOSAL

    The most common methods of WTP

    residuals disposal used in the water

    industry are

    Land application

    Land filling

    Direct stream discharge Discharge to the sewers

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    CHEMICAL RECOVERY

    Coagulant Recovery

    Extracting aluminum or iron coagulantsfrom the waste stream.

    Extraction is achieved by acidification

    Extraction pH is typically in the range of1.8 to 3.0.

    Acid contact time of 10 to 20 minutes

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    Water Treatment Plant Residuals

    for Use in Storm-Water Control Measures

    Sustainable alternative to landfill disposal of WTRs. The incorporation of residuals into SCMs may

    provide additional water quality improvements

    Aluminum-based coagulants are commonly used in

    water treatment systems aluminum-based water treatment residuals (Al-WTR)

    are effective at removing phosphate at

    concentrations found in storm-water runoff.

    In addition to research has shown that WTRs have

    the potential to remove a variety of other

    contaminants from water. These contaminants

    include cadmium, lead , zinc, arsenic, mercury,

    perchlorate and fluoride.

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    CONTD

    Hydraulic conductivity of the residuals Are modified by heating

    it in elevated temperature

    1. drying at 105C for at least 24 h

    2. Baking at 1,000C.

    1,000C was chosen because increases in temperature

    have been shown to transform amorphous aluminum

    hydroxide to more thermodynamically stable phases

    minimize leaching from WTRs.

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    REFERENCES

    Drinking Water Treatment Plant ResidualsManagement Technical Report (EPA 2011)

    ASCE, 1996. Technology Transfer Handbook:Management of Water Treatment PlantResiduals, ASCE and AWWA Ed. NY.

    Tech Brief : Water Treatment Plant ResidualsManagement,

    Feasibility Study of As-Received and Modified

    (Dried/Baked) Water Treatment Plant Residualsfor Use in Storm-Water Control Measures (JohnKomlos1; Andrea Welker, M.ASCE2; Vito Punzi3;and Robert Traver, M.ASCE4) (ASCE JOURNAL)

    http://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/(asce)ee.1943-7870.0000737%20112.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdfhttp://localhost/var/www/apps/conversion/tmp/scratch_9/water%20treatment%20seminar/RELAVANT/residuals_management_report.pdf
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    THANK YOU