€¦ · Web viewSubstance Name CAS# EC# Percentage by weight Risk phrases Hazard Class and Category Code(s) Hazard statement Code(s) Pictogram, Signal Word Code(s) Propyl 4-hydroxybenzoate

SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,

Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691

Fax # +91 40 27171249Email : [email protected]

Visit us : www.preservativesindia.com

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY

1.1 Identification of the substance EC# 202-307-7

CAS# 94-13-3

NIOSH, Registry of Toxic Effects (RTECS) Identification Number

DH280000

Substance Name Propyl Praben (Propyl 4-hydroxybenzoate)

Synonym: Benzoic acid, 4-hydroxy-, propyl esterPropyl p-hydroxybenzoate

Chemical Formula C10H12O3

1.2 Use of the substance/mixture Cosmetics Hair care Preservative The recommended use level is 0.10.6% by weight of product as supplied. It is easy to handle, very stable and cost-effective. It is stable over a wide range of pH and temperature conditions It does not discolor product when combined with additives or by changes in pH.

1.3 Company/undertaking identification

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Safety Data Sheet Saligin PP

http://www.preservativesindia.com/

mailto:[email protected]





The person responsible for placing the substance on the market within Community

Full address SALICYLATES & CHEMICALS PVT. LTDA-25, ROAD NO.18, IDA NACHARAM,HYDERABAD – 500 076ANDHRA PRADESH INDIA

Telephone No. +91- 40-27171550, 27174691

1.4 Emergency telephone Emergency

telephone number of the company

+91- 40-27171550, 27174691

Specification if this phone number is available only during office hours

2. HAZARDS IDENTIFICATION

Classification according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL

Hazard Class and Category Code(s)

Skin Irr. 2Eye Irr.2 Resp. Sens. 1

Hazard statement Code(s)

H315H319H334

Most important adverse physicochemical, human health and environmental effects and symptoms relating to the uses and possible misuses of the mixture that can reasonably be forseen

May be harmful in case of inhalation.

CARCINOGENIC EFFECTS: None found

Slightly harmful in the aquatic environment or are otherwise designed for biocidal action

Causes irreversible eye damage

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Substance Name CAS# EC# Percentage

by weightRisk

phrases

Hazard Class and Category Code(s)

Hazard statement Code(s)

Pictogram, Signal Word

Code(s)

Propyl 4-hydroxybenzoate

94-13-3 202-307-7 100% R 37 Resp. Sens. 1

H334

WngR 36/38 Skin Irr. 2

Eye Irr. 2H315, H319

Wng3 COMPOSITION / INFORMATION ON INGREDIENTS.

Propyl 4-hydroxybenzoate 94-13-3 100%

4. FIRST AID MEASURES

Subdivision of information according to route of exposure Eye contact Check for and remove any contact lenses.

Do not use an eye ointmentSeek medical attention

Skin Contact After contact with skin, wash immediately with plenty of water.Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap.Be particularly careful to clean folds, crevices, creases and groin.Cover the irritated skin with an emollient.If irritation persists, seek medical attention.Wash contaminated clothing before reusing.

Serious Skin Contact

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial creamSeek medical attention.

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Inhalation Allow the victim to rest in a well ventilated area.Seek medical attention.

Serious Inhalation

Evacuate the victim to a safe area as soon as possible.Loosen tight clothing such as a collar, tie, belt or waistband.If breathing is difficult, administer oxygen.If the victim is not breathing, perform mouth-to-mouth resuscitation.Seek medical attention.

Ingestion Do not induce vomiting.Loosen tight clothing such as a collar, tie, belt or waistband.If the victim is not breathing, perform mouth-to-mouth resuscitation.Seek medical attention.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media SMALL FIRE Use DRY chemical powder or carbon dioxide. LARGE FIRE Use water spray or fog.

Cool containing vessels with water jet in order to prevent pressurebuild-up, autoignition or explosion.During a fire,highly toxic and irritating gases carbon oxides (CO, CO2) may be generated

Other information Flammability of

the ProductNon Flammable

Products of Combustion

Products of combustion are toxic. At high temperatures, this will release CO and Co2

6. ACCIDENTAL RELEASE MEASURES

Methods for cleaning up: Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal

container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirement

Large Spill Wear appropriate protective equipment and NIOSH/MSHA approved respirator where mists or vapors of unknown concentrations may be generated (self-contained breathing apparatus preferred)Dike and contain spill with inert material (sand, earth, etc.) and transfer the powder to containers for recovery or disposal

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Keep spill out of sewers and open bodies of water

7. HANDLING AND STORAGE

7.1 Handling Keep locked up Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation. Wear suitable respiratory equipment if ingested, seek medical advice immediately and show the

container or the label. Avoid contact with skin and eyes

7.2 Storage

Keep away from heat. Keep away from sources of ignition. Keep container tightly closed Keep in a cool, well-ventilated place Ground all equipment containing material. Keep container dry. Keep in a cool place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Exposure limit valuesNo Limits have been found from OSHAConsult local authorities for acceptable exposure limits.

Source Type ValueOEL TWA No Limits have been found

OEL No Limits have been foundLLV No Limits have been found

8.2 Exposure controls

8.2.1 Occupational Exposure controls Engineering

ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.

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If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.

(a) Respiratory protection

Dust respirator Be sure to use an approved/certified respirator A self contained breathing apparatus should be used to avoid inhalation of the product.

(b) Eye protection Splash goggles

(c) Skin protection Lab coat Be sure to use approved/certified or equivalent Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 General Information Physical state Solid Color White

9.2 Important health, safety and environmental information

pH at 250C Not Available Molecular Weight 180.2 g/mol Melting Point 96°C (204.8°F

Solubility Soluble in methanol, diethyl ether, acetone. Very slightly soluble in cold water, hot water

Density Not Known Boiling point 68 deg C Specific Gravity 1.063 (Water = 1

10. STABILITY AND REACTIVITY Stability: The product is stable.

10.1 . Materials to avoid:

Oxidising agents Mineral acids

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.Note

Corrosivity: Non-corrosive in presence of glass, steel, stainless steel(304), stainless steel(316). Polymerization: No.

11. TOXICOLOGICAL INFORMATION

Acute effects (acute toxicity, irritation and corrosivity)

The substance (as fume or dust) is mildly irritating to the respiratory tract.

Sensitisation

May cause allergic skin reaction.

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) Carcinogenic

EffectsNone Found

Other Toxic Effects on Humans: Lungs The substance is toxic to lungs

ORAL LD50(RAT) : LD50 = 6332 mg/kg. DERMAL(RABBIT): MILD IRRITANT EYES(RABBIT) : MILD IRRITANT INHALATION LD50(RAT ): No information found

12. ECOLOGICAL INFORMATION

12.1. EcotoxicityNo information has been found

12.2. Bioaccumulative potential Not bioaccumulative

12.3. Products of Biodegradation

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Using a Zahn-Wellens test(2), which requires a 0.2 - 1.0 g/L dry inolculum and 50-400 dissolved organic carbon/L test concentration(1), analogous methylparaben degraded 100% after 6 days with a 2 day acclimation period in a sludge inoculum(2), suggesting that propylparaben may be subject to biodegradation(SRC).

12.4. Toxicity of the Products of Biodegradation The products of degradation are as harmful as the original product.

13. DISPOSAL CONSIDERATIONS

Substance Disposal Material in the elemental state should be recovered for reuse or recycling. Contact a licensed

professional waste disposal service to dispose of this material. Observe all federal, state, and local environmental regulations.

14. TRANSPORT INFORMATION

DOT(Department of Transportation) Classification

Not classified

Identification Shipping name: Propyl Paraben RID(Regulations

Concerning the International Transport of Dangerous Goods by Rail) /ADR(Agreement on Dangerous Goods by Road)

Non-hazardous for road transport

IMDG( International Maritime Dangerous Goods)

Non-hazardous for sea transport

IATA(International Air Transport Association)

Non-hazardous for air transport

UN number

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http://www.iata.org/







15. REGULATORY INFORMATION

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Classification and Labelling according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL

Respiratory and Skin sensitisationLabel elements Respiratory sensitisation Skin sensitisation

GHS Pictogram

Signal Word Warning WarningHazard Statement H334: May cause allergy or asthma

symptoms or breathing difficulties if inhaled

H315: Causes skin irritationH319: Causes serious eye irritation

Precautionary Statement prevention

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.

P261: Avoid breathing dust/fume/gas/mist/vapours/spray

P285: In case of inadequate ventilation wear respiratory protection.

P272: Contaminated work clothing should not be allowed out of the workplace.P280: Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary Statement Response P304 + P341: IF INHALED: If

breathing is difficult, remove victim tofresh air and keep at rest in a position comfortable for breathing.

P302 + P352: IF ON SKIN: Wash withplenty of soap and water.

P342+ P311: symptoms: Call a POISON CENTER or doctor/physician.

P333 + P313: If skin irritation or rashoccurs: Get medical advice/attention.

P321: Specific treatment as per first aid measure.P363: Wash contaminated clothingbefore reuse.

Precautionary Statement StoragePrecautionary Statement Disposal

P501: Dispose of contents/container in accordance with local/regional/national/international regulation

P501: Dispose of contents/container in accordance with local/regional/national/international regulation

May be harmful to the aquatic environment

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Other regulatory information HMIS (Hazardous Materials Identification System) Classification

2 = Moderate Hazard = Temporary or minor injury may occur

1= Minimal Hazard = Materials that must be preheated before ignition will occur.

0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water, polymerise, decompose, condense or self reactE =

NFPA (National Fire Protection Association)

2= Health Hazard = Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.1= Flammability = Must be preheated before ignition can occur.0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.

Federal and State RegulationsNo information found

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OSHANo information found

16. OTHER INFORMATION

Technical Advice Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the

factory Create a Register for Workplace Chemicals; Set priorities concerning the safety in the organization Create emergency plans for the assessed hazards; Organize occupational health care and regular surveys as necessary; Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards,

and to reliably measure and/or estimate occupational exposures to chemicals when needed; Start collecting case studies of accidents and sickness records in the enterprise to create a basis

for priority measures in the control of hazards; Involve workers in safety organizations, such as the system of Safety Representatives and

Committees. Do regular inspection using checklists made for the particular chemicals and chemical processes in

use; Mark and label all chemicals; Keep at hand an inventory list of all chemicals handled in the place of work together with a

collection of Chemical Safety Data Sheets for these chemicals; Train workers to read and understand the Chemical Safety Information, including the health

hazards and routes of exposure; train them to handle dangerous chemicals and processes with respect;

Plan, develop and choose the safe working procedures; Reduce the number of people coming into contact with dangerous chemicals; Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals; Train workers to know and understand the emergency procedures; Equip and train workers to use personal protective equipment properly after everything possible

has been done to eliminate hazards by means of other methods;

List of relevant R phrases R37 Irritating to respiratory system R36/38 Irritating to eyes and skin

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Created By:ELC GROUP Contact Person momaja s.r.o. Jastin SardharaKrakovska 9, Prague 1, 110 00Czech Republic Tel. +420 22 491 0000 Fax. +420 22 491 0671

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Salicylates and Chemical Pvt. Ltd. be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages.

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Documents

€¦ · Web viewSubstance Name CAS# EC# Percentage by weight Risk phrases Hazard Class and Category Code(s) Hazard statement Code(s) Pictogram, Signal Word Code(s) Propyl 4-hydroxybenzoate