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T H E SPILL
Welcome to the fourth issue of lsquoThe Spillrsquo the chemical safety newsletter for blue-light services around the globe
The Spill provides useful information about
chemical incident management and effective
emergency response delivered by the National
Chemical Emergency Centre (NCEC)
The UK Chemsafe service managed by NCEC
on behalf of the Department for Transport and
Chemical Industries Association provides
a free at the point of use advice telephone
line that connects chemical specialists with
the emergency crews attending incidents
involving chemicals The chemical specialists
can provide advice to the emergency services
over the telephone (Level 1) on hazards
decontamination and reaction predictions
and will endeavour to make contact with the
manufacturer if additional support is required
NCEC also provides chemical advice via the
European Intervention in Chemical Transport
Emergencies (ICE) network and directly
supports several emergency services around
the world
ISSUE 4
Dangers of latest internet challenge
The next 10 years of hazmat
Hazmat response new guidance for the fire and rescue service
Chris Sowden interview
Intervention in chemical transport emergencies
Chemdatareg licences donated to help train Bosnian firefighters
Assaults involving corrosive materials
Fentanyl
Latest call statistics
Call of interest
THE SPILL ndash ISSUE 4
Hazmat 2018 is organised by NCEC and Tactical Hazmat and is supported by media partners Fire Times Asia Pacific Gulf Fire and International Fire Fighter
Now in its 11th year Hazmat 2018 is an essential opportunity for
Hazmat specialists to share experiences and knowledge with like-
minded professionals working in the hazmat and chemical incident
industry The event draws upon the knowledge and experience of a
range of hazmat professionals and industry leaders as well as that
of NCECrsquos own emergency responders amp experts and those from
Tactical Hazmat
Visit the-nceccomhazmat-2018 to book your place
Follow us at ncec_uk for event updates
Registration deadline 7 May 2018
Hazmat 2018 ndash
the premier event of the year for
Hazmat professionals
(23 amp 24 May Crowne Plaza Stratford-upon-Avon)
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
The internet has long
encouraged some
strange behaviour
with memes trends
and challenges
going viral such
as the ice-bucket
challenge the cinnamon challenge the
mannequin challenge and planking
However the need to surpass previous
challenges always had the potential to
reach dangerous heights It seems with
the latest craze it has now done so
The lsquoTide Pod Challengersquo encourages
people to chew or swallow a capsule
of liquid detergent (tide pod) that are
designed to be a single measure for use in
a washing machine In the UK these are
often known as liquitabs
Ingesting any chemical or detergent is never
a good idea The detergent in tide pods is
concentrated and classified as an irritant
corrosive or harmful by ingestion As well as
causing irritation exposure to the detergent
may result in diarrhoea and vomiting Some
of the stronger concentrates could also
cause chemical burns to the lips mouth or
anywhere else they come into contact with
Due to the colourful sweet-like appearance
of the capsules young children are attracted
to them and start playing with them which
often results in accidental exposure to the
contents The American Association of
Poison Control Centres (AAPCC) receive an
average of 29 calls per day for exposures
to children under 51 In the first 15 days of
2018 the AAPCC has already dealt with
39 cases of intentional exposure to liquid
detergent among 13 to 19 year olds This
exceeds the total number of intentional
exposures for the whole of 20162
Incidents involving liquitabs will present
little risk to first responders However
while some detergents are corrosive
most will be irritants so wearing protective
gloves will be necessary to protect the
skin Anyone exposed to the product
should have the affected area washed
with copious amounts of water This may
cause the detergent to lather but it should
wash off with continued irrigation Anyone
who has ingested the product should seek
medical advice If first responders have
any concerns about an individual who
may have undertaken this challenge our
emergency responders have access to over
1 million safety data sheets and can assist
with their expert chemical advice
1 httpsaapccs3amazonawscomfileslibrary
Laundry_Pack_Web_Data_through_122017_
z2dtIpfpdf2 httpwwwaapccorgpress83
DANGERS OF LATEST INTERNET CHALLENGE
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
David Walton ndash David is the
Deputy Chief Fire Officer
for the West Yorkshire Fire
and Rescue Service and
is the Hazmat Lead for the NFCC In
2016 David received the Queenrsquos Fire
Service Medal along with his promotion
to Deputy Chief Fire Officer He leads
the NOG programme for hazardous
materials and has over 30 yearsrsquo
experience as a firefighter
Phil David ndash Phil has served with South
Wales Police since 1988 in the commercial
vehicles unit He began his career in
commercial transport and is now an
experienced dangerous goods safety
adviser (DGSA) in addition to his police role
Caroline Raine ndash
Caroline is NCECrsquos
Head of Consultancy
and Training and was an
NCEC Emergency Responder She has
extensive experience in interpreting and
implementing EU regulations and is a
cofounder of the British Association of
Dangerous Goods Professionals (BADGP)
Her depth of knowledge regarding the
legislative landscape gives her a unique
understanding of the chemical industry
Matt Gable ndash Matt is a
Senior Emergency Planner
for the Environment Agency
and a Scientific Adviser to
West Midlands Fire Service He helped
develop the environmental aspects of
the hazardous materials environmental
protection advisers (HMEPA) course at
the Fire Service College He has plenty of
experience delivering this training to fire
and rescue services across the country
Mike Callan ndash Mike has
45 yearsrsquo experience as a
hazmat specialist and has
presented at over 1000
training conferences He is from the
United States of America (USA) and
served as Captain for Wallingford Fire
Department in Connecticut for 20 years
and now provides training to firefighters
across the USA His training has been
adopted by more than 30 state fire
training schools
The panelPeter Gustafson ndash
Peter is a hazmat
and chemical
biological
radiological and nuclear (CBRN)
expert from London Fire Brigade
with 23 yearsrsquo experience He
is one of four national CBRN
advisers attached to the London
Fire Brigade He has been
involved in writing national
policy as part of the National
Operational Guidance (NOG)
programme and conducts training
for other hazmat officers Peter
is also the national lead on lsquoall
things hydrogenrsquo for the National
Fire Chiefs Council (NFCC)
NCECrsquos annual conference Hazmat was held in May 2017 at Stratford-upon-Avon During the conference Dan Haggarty NCECrsquos Head of Emergency Response led a select panel of experts and first responders in a discussion about responding to hazmat incidents over the next 10 years
THE NEXT 10 YEARS OF HAZMAT
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
EU regulations that some people may view
as interfering and overcomplicated without
reasonable replacements being provided
However Brexit should only be an issue
for the next 2 to 3 years As for the post-
Brexit era panel members expressed their
keenness to maintain ties with European
counterparts because co-operation and
the sharing of information and experience
are important to people having a safety
role Groups such as the International
Association of Fire and Rescue Services
(CTIF) allow firefighters and hazmat
specialists to discuss developments
others may not be aware of and innovative
operational techniques that can be
deployed
One point that emerged was the
possibility of tightening up existing
precursor legislation The purchase of
many hazardous materials is completely
unregulated and while they may not
be purchased with malicious intent the
potential for misuse remains This is
particularly poignant when considering
corrosive attacks and drug synthesis which
you can read more about later in this issue
TechnologyThe next topic discussed was about
technology as a major driving force of
hazmat response Mike Callan made a
superb point that the term lsquohazmatrsquo had
not even been coined when he started
working in the industry and breathing
apparatus had yet to be introduced ndash
which is now regularly used as standard
equipment Wersquove come a long way
since then in understanding hazmat but
there is one piece of technology that is
a more recent addition to a responderrsquos
arsenal that could be usefully
improved ndash detection identification and
monitoring (DIM) equipment
DIM equipment has become key
in incidents where the hazardous
material cannot be identified easily
Specialist vehicles across the UK are
well equipped for such incidents and
with newer more compact kit entering
the market the future for this area of
technology looks bright However there
is one concerning shortcoming with all
this equipment and that is the inability to
LegislationThe first topic discussed was legislation
and its impact The most imminent issue
to be addressed is Brexit as much of the
United Kingdomrsquos legislation is tied to EU
frameworks Therefore the question has
to be asked lsquois our leaving the EU going to
significantly change thingsrsquo Matt Gable
and Caroline Raine were quick to point
out that serious consideration will have
to be given to law making ndash particularly
for the Health and Safety Executive and
Environment Agency While itrsquos likely
that Regulation (EC) No 12722008 on
classification labelling and packaging
of substances and mixtures (the lsquoCLP
Regulationrsquo) will be adopted into UK law
with minimal changes other areas may
not be so quickly brought on board Most
transport regulations are unlikely to be
affected as they originated in the United
Nations and the UK already has legislation
that covers road and rail transport ndash The
Carriage of Dangerous Goods and Use
of Transportable Pressure Equipment
Regulations (CDG) David Walton voiced
his concerns about the risk of cutting back
THE SPILL ndash ISSUE 4
ConclusionAll in all the panel discussion was a great success with many good ideas
being shared and agreement that there are many ways the field of hazmat
response can develop over the next 10 years Panel members were united
in the belief that investment is needed to be able to keep step with the
rapidly developing world of hazmat response ndash from recruiting personnel
at an earlier stage in their career to ensuring that equipment is kept well
maintained and up to date
The discussion promoted the idea of continuing to collaborate both
internally and externally The point was made that in Europe the
emergency services often call upon industry to assist with incidents This
helps draw knowledge from an area where expertise already exists which
can then be used to improve response Furthermore we must make sure
that Brexit does not mean we become isolated from Europe but that we
continue to collaborate with our European colleagues We must endeavour
to share the knowledge and experience of current hazmat professionals
with the younger generation of professionals to ensure a continued high
level of expertise throughout the industry
We would like to thank the panel of experts and all the attendees
exhibitors and organisers of Hazmat 2017 conference We look forward to
seeing you again this year In the meantime if you would like any further
information about Hazmat 2018 please contact us at ncecricardocom
or the NCEC sales line on 01235 753654
identify specific biological agents This is
a gap many would like to see filled over
the next 10 years
Another emerging technological area is
cybersecurity The Hazmat conference
was taking place only a few weeks
following the lsquoWannacryrsquo attacks that
had left the NHS and numerous other
organisations globally coping with the
aftermath Mike made another excellent
point that we adapted and overcame
the attack but the panel agreed that
improving cybersecurity in a proactive
manner must be an ongoing priority
Caroline explained that a major issue
with technology is that it changes so
fast Lithium batteries have only recently
come to the fore and any number of
emergent technologies could cause the
next big shift in legislation or hazmat
response Possible areas to watch are
autonomous vehicles such as drones
which split opinions on the panel and
equipment designed to enter hazardous
environments without human intervention
It is also worth noting that all the
technology in the world is only as good
as its support Typically the money used
to buy new equipment is only provided
for so long and updating kit can prove
costly In some cases equipment that
has been purchased canrsquot be maintained
and as a result some elements may
fail or not work as intended This is
certainly a matter that would need to be
addressed
Information and knowledgeIn 10 yearsrsquo time we could be looking
at a very different panel of experts
Therefore the question was raised about
how we are looking at bringing the new
generation of hazmat specialists up to
speed While Peter was very enthusiastic
about the path laid out for hazmat
practitioners within fire and rescue
services the observation was made that
we live in austere times Recruitment is
generally down and typically people
donrsquot begin to engage with hazmat until
they are in their late twenties Matt added
that the people with the most enthusiasm
are the younger professionals but with
finances as they are many are working
on a voluntary basis
The idea that involving the younger
generation will help to improve hazmat
response was supported by Dave Mike
and Caroline ndash each suggesting that
people need to be engaged at an earlier
stage in their professional lives and
given a sense of urgency about getting
involved in hazmat Mike made the point
that in recent years the barriers for
entry into these jobs has only increased
Therefore the older professionals have a
responsibility to pass on their knowledge
and experience
The opportunities to share knowledge
have significantly improved and over
the next 10 years it will be important
for specialists to make their voices
heard in these groups This year
delegates attending a CTIF and
Intervention in Chemical Transport
Emergencies (ICE) meeting which was
being held in the UK could also attend
the Hazmat conference as the two
events overlapped This enabled the
establishment of a fantastic forum of
ideas and experience More events and
meetings like this will be vital over the
next 10 years to continue the flow of
information provided
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
Hazmat 2018 is organised by NCEC and Tactical Hazmat and is supported by media partners Fire Times Asia Pacific Gulf Fire and International Fire Fighter
Now in its 11th year Hazmat 2018 is an essential opportunity for
Hazmat specialists to share experiences and knowledge with like-
minded professionals working in the hazmat and chemical incident
industry The event draws upon the knowledge and experience of a
range of hazmat professionals and industry leaders as well as that
of NCECrsquos own emergency responders amp experts and those from
Tactical Hazmat
Visit the-nceccomhazmat-2018 to book your place
Follow us at ncec_uk for event updates
Registration deadline 7 May 2018
Hazmat 2018 ndash
the premier event of the year for
Hazmat professionals
(23 amp 24 May Crowne Plaza Stratford-upon-Avon)
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
The internet has long
encouraged some
strange behaviour
with memes trends
and challenges
going viral such
as the ice-bucket
challenge the cinnamon challenge the
mannequin challenge and planking
However the need to surpass previous
challenges always had the potential to
reach dangerous heights It seems with
the latest craze it has now done so
The lsquoTide Pod Challengersquo encourages
people to chew or swallow a capsule
of liquid detergent (tide pod) that are
designed to be a single measure for use in
a washing machine In the UK these are
often known as liquitabs
Ingesting any chemical or detergent is never
a good idea The detergent in tide pods is
concentrated and classified as an irritant
corrosive or harmful by ingestion As well as
causing irritation exposure to the detergent
may result in diarrhoea and vomiting Some
of the stronger concentrates could also
cause chemical burns to the lips mouth or
anywhere else they come into contact with
Due to the colourful sweet-like appearance
of the capsules young children are attracted
to them and start playing with them which
often results in accidental exposure to the
contents The American Association of
Poison Control Centres (AAPCC) receive an
average of 29 calls per day for exposures
to children under 51 In the first 15 days of
2018 the AAPCC has already dealt with
39 cases of intentional exposure to liquid
detergent among 13 to 19 year olds This
exceeds the total number of intentional
exposures for the whole of 20162
Incidents involving liquitabs will present
little risk to first responders However
while some detergents are corrosive
most will be irritants so wearing protective
gloves will be necessary to protect the
skin Anyone exposed to the product
should have the affected area washed
with copious amounts of water This may
cause the detergent to lather but it should
wash off with continued irrigation Anyone
who has ingested the product should seek
medical advice If first responders have
any concerns about an individual who
may have undertaken this challenge our
emergency responders have access to over
1 million safety data sheets and can assist
with their expert chemical advice
1 httpsaapccs3amazonawscomfileslibrary
Laundry_Pack_Web_Data_through_122017_
z2dtIpfpdf2 httpwwwaapccorgpress83
DANGERS OF LATEST INTERNET CHALLENGE
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
David Walton ndash David is the
Deputy Chief Fire Officer
for the West Yorkshire Fire
and Rescue Service and
is the Hazmat Lead for the NFCC In
2016 David received the Queenrsquos Fire
Service Medal along with his promotion
to Deputy Chief Fire Officer He leads
the NOG programme for hazardous
materials and has over 30 yearsrsquo
experience as a firefighter
Phil David ndash Phil has served with South
Wales Police since 1988 in the commercial
vehicles unit He began his career in
commercial transport and is now an
experienced dangerous goods safety
adviser (DGSA) in addition to his police role
Caroline Raine ndash
Caroline is NCECrsquos
Head of Consultancy
and Training and was an
NCEC Emergency Responder She has
extensive experience in interpreting and
implementing EU regulations and is a
cofounder of the British Association of
Dangerous Goods Professionals (BADGP)
Her depth of knowledge regarding the
legislative landscape gives her a unique
understanding of the chemical industry
Matt Gable ndash Matt is a
Senior Emergency Planner
for the Environment Agency
and a Scientific Adviser to
West Midlands Fire Service He helped
develop the environmental aspects of
the hazardous materials environmental
protection advisers (HMEPA) course at
the Fire Service College He has plenty of
experience delivering this training to fire
and rescue services across the country
Mike Callan ndash Mike has
45 yearsrsquo experience as a
hazmat specialist and has
presented at over 1000
training conferences He is from the
United States of America (USA) and
served as Captain for Wallingford Fire
Department in Connecticut for 20 years
and now provides training to firefighters
across the USA His training has been
adopted by more than 30 state fire
training schools
The panelPeter Gustafson ndash
Peter is a hazmat
and chemical
biological
radiological and nuclear (CBRN)
expert from London Fire Brigade
with 23 yearsrsquo experience He
is one of four national CBRN
advisers attached to the London
Fire Brigade He has been
involved in writing national
policy as part of the National
Operational Guidance (NOG)
programme and conducts training
for other hazmat officers Peter
is also the national lead on lsquoall
things hydrogenrsquo for the National
Fire Chiefs Council (NFCC)
NCECrsquos annual conference Hazmat was held in May 2017 at Stratford-upon-Avon During the conference Dan Haggarty NCECrsquos Head of Emergency Response led a select panel of experts and first responders in a discussion about responding to hazmat incidents over the next 10 years
THE NEXT 10 YEARS OF HAZMAT
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
EU regulations that some people may view
as interfering and overcomplicated without
reasonable replacements being provided
However Brexit should only be an issue
for the next 2 to 3 years As for the post-
Brexit era panel members expressed their
keenness to maintain ties with European
counterparts because co-operation and
the sharing of information and experience
are important to people having a safety
role Groups such as the International
Association of Fire and Rescue Services
(CTIF) allow firefighters and hazmat
specialists to discuss developments
others may not be aware of and innovative
operational techniques that can be
deployed
One point that emerged was the
possibility of tightening up existing
precursor legislation The purchase of
many hazardous materials is completely
unregulated and while they may not
be purchased with malicious intent the
potential for misuse remains This is
particularly poignant when considering
corrosive attacks and drug synthesis which
you can read more about later in this issue
TechnologyThe next topic discussed was about
technology as a major driving force of
hazmat response Mike Callan made a
superb point that the term lsquohazmatrsquo had
not even been coined when he started
working in the industry and breathing
apparatus had yet to be introduced ndash
which is now regularly used as standard
equipment Wersquove come a long way
since then in understanding hazmat but
there is one piece of technology that is
a more recent addition to a responderrsquos
arsenal that could be usefully
improved ndash detection identification and
monitoring (DIM) equipment
DIM equipment has become key
in incidents where the hazardous
material cannot be identified easily
Specialist vehicles across the UK are
well equipped for such incidents and
with newer more compact kit entering
the market the future for this area of
technology looks bright However there
is one concerning shortcoming with all
this equipment and that is the inability to
LegislationThe first topic discussed was legislation
and its impact The most imminent issue
to be addressed is Brexit as much of the
United Kingdomrsquos legislation is tied to EU
frameworks Therefore the question has
to be asked lsquois our leaving the EU going to
significantly change thingsrsquo Matt Gable
and Caroline Raine were quick to point
out that serious consideration will have
to be given to law making ndash particularly
for the Health and Safety Executive and
Environment Agency While itrsquos likely
that Regulation (EC) No 12722008 on
classification labelling and packaging
of substances and mixtures (the lsquoCLP
Regulationrsquo) will be adopted into UK law
with minimal changes other areas may
not be so quickly brought on board Most
transport regulations are unlikely to be
affected as they originated in the United
Nations and the UK already has legislation
that covers road and rail transport ndash The
Carriage of Dangerous Goods and Use
of Transportable Pressure Equipment
Regulations (CDG) David Walton voiced
his concerns about the risk of cutting back
THE SPILL ndash ISSUE 4
ConclusionAll in all the panel discussion was a great success with many good ideas
being shared and agreement that there are many ways the field of hazmat
response can develop over the next 10 years Panel members were united
in the belief that investment is needed to be able to keep step with the
rapidly developing world of hazmat response ndash from recruiting personnel
at an earlier stage in their career to ensuring that equipment is kept well
maintained and up to date
The discussion promoted the idea of continuing to collaborate both
internally and externally The point was made that in Europe the
emergency services often call upon industry to assist with incidents This
helps draw knowledge from an area where expertise already exists which
can then be used to improve response Furthermore we must make sure
that Brexit does not mean we become isolated from Europe but that we
continue to collaborate with our European colleagues We must endeavour
to share the knowledge and experience of current hazmat professionals
with the younger generation of professionals to ensure a continued high
level of expertise throughout the industry
We would like to thank the panel of experts and all the attendees
exhibitors and organisers of Hazmat 2017 conference We look forward to
seeing you again this year In the meantime if you would like any further
information about Hazmat 2018 please contact us at ncecricardocom
or the NCEC sales line on 01235 753654
identify specific biological agents This is
a gap many would like to see filled over
the next 10 years
Another emerging technological area is
cybersecurity The Hazmat conference
was taking place only a few weeks
following the lsquoWannacryrsquo attacks that
had left the NHS and numerous other
organisations globally coping with the
aftermath Mike made another excellent
point that we adapted and overcame
the attack but the panel agreed that
improving cybersecurity in a proactive
manner must be an ongoing priority
Caroline explained that a major issue
with technology is that it changes so
fast Lithium batteries have only recently
come to the fore and any number of
emergent technologies could cause the
next big shift in legislation or hazmat
response Possible areas to watch are
autonomous vehicles such as drones
which split opinions on the panel and
equipment designed to enter hazardous
environments without human intervention
It is also worth noting that all the
technology in the world is only as good
as its support Typically the money used
to buy new equipment is only provided
for so long and updating kit can prove
costly In some cases equipment that
has been purchased canrsquot be maintained
and as a result some elements may
fail or not work as intended This is
certainly a matter that would need to be
addressed
Information and knowledgeIn 10 yearsrsquo time we could be looking
at a very different panel of experts
Therefore the question was raised about
how we are looking at bringing the new
generation of hazmat specialists up to
speed While Peter was very enthusiastic
about the path laid out for hazmat
practitioners within fire and rescue
services the observation was made that
we live in austere times Recruitment is
generally down and typically people
donrsquot begin to engage with hazmat until
they are in their late twenties Matt added
that the people with the most enthusiasm
are the younger professionals but with
finances as they are many are working
on a voluntary basis
The idea that involving the younger
generation will help to improve hazmat
response was supported by Dave Mike
and Caroline ndash each suggesting that
people need to be engaged at an earlier
stage in their professional lives and
given a sense of urgency about getting
involved in hazmat Mike made the point
that in recent years the barriers for
entry into these jobs has only increased
Therefore the older professionals have a
responsibility to pass on their knowledge
and experience
The opportunities to share knowledge
have significantly improved and over
the next 10 years it will be important
for specialists to make their voices
heard in these groups This year
delegates attending a CTIF and
Intervention in Chemical Transport
Emergencies (ICE) meeting which was
being held in the UK could also attend
the Hazmat conference as the two
events overlapped This enabled the
establishment of a fantastic forum of
ideas and experience More events and
meetings like this will be vital over the
next 10 years to continue the flow of
information provided
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
David Walton ndash David is the
Deputy Chief Fire Officer
for the West Yorkshire Fire
and Rescue Service and
is the Hazmat Lead for the NFCC In
2016 David received the Queenrsquos Fire
Service Medal along with his promotion
to Deputy Chief Fire Officer He leads
the NOG programme for hazardous
materials and has over 30 yearsrsquo
experience as a firefighter
Phil David ndash Phil has served with South
Wales Police since 1988 in the commercial
vehicles unit He began his career in
commercial transport and is now an
experienced dangerous goods safety
adviser (DGSA) in addition to his police role
Caroline Raine ndash
Caroline is NCECrsquos
Head of Consultancy
and Training and was an
NCEC Emergency Responder She has
extensive experience in interpreting and
implementing EU regulations and is a
cofounder of the British Association of
Dangerous Goods Professionals (BADGP)
Her depth of knowledge regarding the
legislative landscape gives her a unique
understanding of the chemical industry
Matt Gable ndash Matt is a
Senior Emergency Planner
for the Environment Agency
and a Scientific Adviser to
West Midlands Fire Service He helped
develop the environmental aspects of
the hazardous materials environmental
protection advisers (HMEPA) course at
the Fire Service College He has plenty of
experience delivering this training to fire
and rescue services across the country
Mike Callan ndash Mike has
45 yearsrsquo experience as a
hazmat specialist and has
presented at over 1000
training conferences He is from the
United States of America (USA) and
served as Captain for Wallingford Fire
Department in Connecticut for 20 years
and now provides training to firefighters
across the USA His training has been
adopted by more than 30 state fire
training schools
The panelPeter Gustafson ndash
Peter is a hazmat
and chemical
biological
radiological and nuclear (CBRN)
expert from London Fire Brigade
with 23 yearsrsquo experience He
is one of four national CBRN
advisers attached to the London
Fire Brigade He has been
involved in writing national
policy as part of the National
Operational Guidance (NOG)
programme and conducts training
for other hazmat officers Peter
is also the national lead on lsquoall
things hydrogenrsquo for the National
Fire Chiefs Council (NFCC)
NCECrsquos annual conference Hazmat was held in May 2017 at Stratford-upon-Avon During the conference Dan Haggarty NCECrsquos Head of Emergency Response led a select panel of experts and first responders in a discussion about responding to hazmat incidents over the next 10 years
THE NEXT 10 YEARS OF HAZMAT
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
EU regulations that some people may view
as interfering and overcomplicated without
reasonable replacements being provided
However Brexit should only be an issue
for the next 2 to 3 years As for the post-
Brexit era panel members expressed their
keenness to maintain ties with European
counterparts because co-operation and
the sharing of information and experience
are important to people having a safety
role Groups such as the International
Association of Fire and Rescue Services
(CTIF) allow firefighters and hazmat
specialists to discuss developments
others may not be aware of and innovative
operational techniques that can be
deployed
One point that emerged was the
possibility of tightening up existing
precursor legislation The purchase of
many hazardous materials is completely
unregulated and while they may not
be purchased with malicious intent the
potential for misuse remains This is
particularly poignant when considering
corrosive attacks and drug synthesis which
you can read more about later in this issue
TechnologyThe next topic discussed was about
technology as a major driving force of
hazmat response Mike Callan made a
superb point that the term lsquohazmatrsquo had
not even been coined when he started
working in the industry and breathing
apparatus had yet to be introduced ndash
which is now regularly used as standard
equipment Wersquove come a long way
since then in understanding hazmat but
there is one piece of technology that is
a more recent addition to a responderrsquos
arsenal that could be usefully
improved ndash detection identification and
monitoring (DIM) equipment
DIM equipment has become key
in incidents where the hazardous
material cannot be identified easily
Specialist vehicles across the UK are
well equipped for such incidents and
with newer more compact kit entering
the market the future for this area of
technology looks bright However there
is one concerning shortcoming with all
this equipment and that is the inability to
LegislationThe first topic discussed was legislation
and its impact The most imminent issue
to be addressed is Brexit as much of the
United Kingdomrsquos legislation is tied to EU
frameworks Therefore the question has
to be asked lsquois our leaving the EU going to
significantly change thingsrsquo Matt Gable
and Caroline Raine were quick to point
out that serious consideration will have
to be given to law making ndash particularly
for the Health and Safety Executive and
Environment Agency While itrsquos likely
that Regulation (EC) No 12722008 on
classification labelling and packaging
of substances and mixtures (the lsquoCLP
Regulationrsquo) will be adopted into UK law
with minimal changes other areas may
not be so quickly brought on board Most
transport regulations are unlikely to be
affected as they originated in the United
Nations and the UK already has legislation
that covers road and rail transport ndash The
Carriage of Dangerous Goods and Use
of Transportable Pressure Equipment
Regulations (CDG) David Walton voiced
his concerns about the risk of cutting back
THE SPILL ndash ISSUE 4
ConclusionAll in all the panel discussion was a great success with many good ideas
being shared and agreement that there are many ways the field of hazmat
response can develop over the next 10 years Panel members were united
in the belief that investment is needed to be able to keep step with the
rapidly developing world of hazmat response ndash from recruiting personnel
at an earlier stage in their career to ensuring that equipment is kept well
maintained and up to date
The discussion promoted the idea of continuing to collaborate both
internally and externally The point was made that in Europe the
emergency services often call upon industry to assist with incidents This
helps draw knowledge from an area where expertise already exists which
can then be used to improve response Furthermore we must make sure
that Brexit does not mean we become isolated from Europe but that we
continue to collaborate with our European colleagues We must endeavour
to share the knowledge and experience of current hazmat professionals
with the younger generation of professionals to ensure a continued high
level of expertise throughout the industry
We would like to thank the panel of experts and all the attendees
exhibitors and organisers of Hazmat 2017 conference We look forward to
seeing you again this year In the meantime if you would like any further
information about Hazmat 2018 please contact us at ncecricardocom
or the NCEC sales line on 01235 753654
identify specific biological agents This is
a gap many would like to see filled over
the next 10 years
Another emerging technological area is
cybersecurity The Hazmat conference
was taking place only a few weeks
following the lsquoWannacryrsquo attacks that
had left the NHS and numerous other
organisations globally coping with the
aftermath Mike made another excellent
point that we adapted and overcame
the attack but the panel agreed that
improving cybersecurity in a proactive
manner must be an ongoing priority
Caroline explained that a major issue
with technology is that it changes so
fast Lithium batteries have only recently
come to the fore and any number of
emergent technologies could cause the
next big shift in legislation or hazmat
response Possible areas to watch are
autonomous vehicles such as drones
which split opinions on the panel and
equipment designed to enter hazardous
environments without human intervention
It is also worth noting that all the
technology in the world is only as good
as its support Typically the money used
to buy new equipment is only provided
for so long and updating kit can prove
costly In some cases equipment that
has been purchased canrsquot be maintained
and as a result some elements may
fail or not work as intended This is
certainly a matter that would need to be
addressed
Information and knowledgeIn 10 yearsrsquo time we could be looking
at a very different panel of experts
Therefore the question was raised about
how we are looking at bringing the new
generation of hazmat specialists up to
speed While Peter was very enthusiastic
about the path laid out for hazmat
practitioners within fire and rescue
services the observation was made that
we live in austere times Recruitment is
generally down and typically people
donrsquot begin to engage with hazmat until
they are in their late twenties Matt added
that the people with the most enthusiasm
are the younger professionals but with
finances as they are many are working
on a voluntary basis
The idea that involving the younger
generation will help to improve hazmat
response was supported by Dave Mike
and Caroline ndash each suggesting that
people need to be engaged at an earlier
stage in their professional lives and
given a sense of urgency about getting
involved in hazmat Mike made the point
that in recent years the barriers for
entry into these jobs has only increased
Therefore the older professionals have a
responsibility to pass on their knowledge
and experience
The opportunities to share knowledge
have significantly improved and over
the next 10 years it will be important
for specialists to make their voices
heard in these groups This year
delegates attending a CTIF and
Intervention in Chemical Transport
Emergencies (ICE) meeting which was
being held in the UK could also attend
the Hazmat conference as the two
events overlapped This enabled the
establishment of a fantastic forum of
ideas and experience More events and
meetings like this will be vital over the
next 10 years to continue the flow of
information provided
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
EU regulations that some people may view
as interfering and overcomplicated without
reasonable replacements being provided
However Brexit should only be an issue
for the next 2 to 3 years As for the post-
Brexit era panel members expressed their
keenness to maintain ties with European
counterparts because co-operation and
the sharing of information and experience
are important to people having a safety
role Groups such as the International
Association of Fire and Rescue Services
(CTIF) allow firefighters and hazmat
specialists to discuss developments
others may not be aware of and innovative
operational techniques that can be
deployed
One point that emerged was the
possibility of tightening up existing
precursor legislation The purchase of
many hazardous materials is completely
unregulated and while they may not
be purchased with malicious intent the
potential for misuse remains This is
particularly poignant when considering
corrosive attacks and drug synthesis which
you can read more about later in this issue
TechnologyThe next topic discussed was about
technology as a major driving force of
hazmat response Mike Callan made a
superb point that the term lsquohazmatrsquo had
not even been coined when he started
working in the industry and breathing
apparatus had yet to be introduced ndash
which is now regularly used as standard
equipment Wersquove come a long way
since then in understanding hazmat but
there is one piece of technology that is
a more recent addition to a responderrsquos
arsenal that could be usefully
improved ndash detection identification and
monitoring (DIM) equipment
DIM equipment has become key
in incidents where the hazardous
material cannot be identified easily
Specialist vehicles across the UK are
well equipped for such incidents and
with newer more compact kit entering
the market the future for this area of
technology looks bright However there
is one concerning shortcoming with all
this equipment and that is the inability to
LegislationThe first topic discussed was legislation
and its impact The most imminent issue
to be addressed is Brexit as much of the
United Kingdomrsquos legislation is tied to EU
frameworks Therefore the question has
to be asked lsquois our leaving the EU going to
significantly change thingsrsquo Matt Gable
and Caroline Raine were quick to point
out that serious consideration will have
to be given to law making ndash particularly
for the Health and Safety Executive and
Environment Agency While itrsquos likely
that Regulation (EC) No 12722008 on
classification labelling and packaging
of substances and mixtures (the lsquoCLP
Regulationrsquo) will be adopted into UK law
with minimal changes other areas may
not be so quickly brought on board Most
transport regulations are unlikely to be
affected as they originated in the United
Nations and the UK already has legislation
that covers road and rail transport ndash The
Carriage of Dangerous Goods and Use
of Transportable Pressure Equipment
Regulations (CDG) David Walton voiced
his concerns about the risk of cutting back
THE SPILL ndash ISSUE 4
ConclusionAll in all the panel discussion was a great success with many good ideas
being shared and agreement that there are many ways the field of hazmat
response can develop over the next 10 years Panel members were united
in the belief that investment is needed to be able to keep step with the
rapidly developing world of hazmat response ndash from recruiting personnel
at an earlier stage in their career to ensuring that equipment is kept well
maintained and up to date
The discussion promoted the idea of continuing to collaborate both
internally and externally The point was made that in Europe the
emergency services often call upon industry to assist with incidents This
helps draw knowledge from an area where expertise already exists which
can then be used to improve response Furthermore we must make sure
that Brexit does not mean we become isolated from Europe but that we
continue to collaborate with our European colleagues We must endeavour
to share the knowledge and experience of current hazmat professionals
with the younger generation of professionals to ensure a continued high
level of expertise throughout the industry
We would like to thank the panel of experts and all the attendees
exhibitors and organisers of Hazmat 2017 conference We look forward to
seeing you again this year In the meantime if you would like any further
information about Hazmat 2018 please contact us at ncecricardocom
or the NCEC sales line on 01235 753654
identify specific biological agents This is
a gap many would like to see filled over
the next 10 years
Another emerging technological area is
cybersecurity The Hazmat conference
was taking place only a few weeks
following the lsquoWannacryrsquo attacks that
had left the NHS and numerous other
organisations globally coping with the
aftermath Mike made another excellent
point that we adapted and overcame
the attack but the panel agreed that
improving cybersecurity in a proactive
manner must be an ongoing priority
Caroline explained that a major issue
with technology is that it changes so
fast Lithium batteries have only recently
come to the fore and any number of
emergent technologies could cause the
next big shift in legislation or hazmat
response Possible areas to watch are
autonomous vehicles such as drones
which split opinions on the panel and
equipment designed to enter hazardous
environments without human intervention
It is also worth noting that all the
technology in the world is only as good
as its support Typically the money used
to buy new equipment is only provided
for so long and updating kit can prove
costly In some cases equipment that
has been purchased canrsquot be maintained
and as a result some elements may
fail or not work as intended This is
certainly a matter that would need to be
addressed
Information and knowledgeIn 10 yearsrsquo time we could be looking
at a very different panel of experts
Therefore the question was raised about
how we are looking at bringing the new
generation of hazmat specialists up to
speed While Peter was very enthusiastic
about the path laid out for hazmat
practitioners within fire and rescue
services the observation was made that
we live in austere times Recruitment is
generally down and typically people
donrsquot begin to engage with hazmat until
they are in their late twenties Matt added
that the people with the most enthusiasm
are the younger professionals but with
finances as they are many are working
on a voluntary basis
The idea that involving the younger
generation will help to improve hazmat
response was supported by Dave Mike
and Caroline ndash each suggesting that
people need to be engaged at an earlier
stage in their professional lives and
given a sense of urgency about getting
involved in hazmat Mike made the point
that in recent years the barriers for
entry into these jobs has only increased
Therefore the older professionals have a
responsibility to pass on their knowledge
and experience
The opportunities to share knowledge
have significantly improved and over
the next 10 years it will be important
for specialists to make their voices
heard in these groups This year
delegates attending a CTIF and
Intervention in Chemical Transport
Emergencies (ICE) meeting which was
being held in the UK could also attend
the Hazmat conference as the two
events overlapped This enabled the
establishment of a fantastic forum of
ideas and experience More events and
meetings like this will be vital over the
next 10 years to continue the flow of
information provided
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
ConclusionAll in all the panel discussion was a great success with many good ideas
being shared and agreement that there are many ways the field of hazmat
response can develop over the next 10 years Panel members were united
in the belief that investment is needed to be able to keep step with the
rapidly developing world of hazmat response ndash from recruiting personnel
at an earlier stage in their career to ensuring that equipment is kept well
maintained and up to date
The discussion promoted the idea of continuing to collaborate both
internally and externally The point was made that in Europe the
emergency services often call upon industry to assist with incidents This
helps draw knowledge from an area where expertise already exists which
can then be used to improve response Furthermore we must make sure
that Brexit does not mean we become isolated from Europe but that we
continue to collaborate with our European colleagues We must endeavour
to share the knowledge and experience of current hazmat professionals
with the younger generation of professionals to ensure a continued high
level of expertise throughout the industry
We would like to thank the panel of experts and all the attendees
exhibitors and organisers of Hazmat 2017 conference We look forward to
seeing you again this year In the meantime if you would like any further
information about Hazmat 2018 please contact us at ncecricardocom
or the NCEC sales line on 01235 753654
identify specific biological agents This is
a gap many would like to see filled over
the next 10 years
Another emerging technological area is
cybersecurity The Hazmat conference
was taking place only a few weeks
following the lsquoWannacryrsquo attacks that
had left the NHS and numerous other
organisations globally coping with the
aftermath Mike made another excellent
point that we adapted and overcame
the attack but the panel agreed that
improving cybersecurity in a proactive
manner must be an ongoing priority
Caroline explained that a major issue
with technology is that it changes so
fast Lithium batteries have only recently
come to the fore and any number of
emergent technologies could cause the
next big shift in legislation or hazmat
response Possible areas to watch are
autonomous vehicles such as drones
which split opinions on the panel and
equipment designed to enter hazardous
environments without human intervention
It is also worth noting that all the
technology in the world is only as good
as its support Typically the money used
to buy new equipment is only provided
for so long and updating kit can prove
costly In some cases equipment that
has been purchased canrsquot be maintained
and as a result some elements may
fail or not work as intended This is
certainly a matter that would need to be
addressed
Information and knowledgeIn 10 yearsrsquo time we could be looking
at a very different panel of experts
Therefore the question was raised about
how we are looking at bringing the new
generation of hazmat specialists up to
speed While Peter was very enthusiastic
about the path laid out for hazmat
practitioners within fire and rescue
services the observation was made that
we live in austere times Recruitment is
generally down and typically people
donrsquot begin to engage with hazmat until
they are in their late twenties Matt added
that the people with the most enthusiasm
are the younger professionals but with
finances as they are many are working
on a voluntary basis
The idea that involving the younger
generation will help to improve hazmat
response was supported by Dave Mike
and Caroline ndash each suggesting that
people need to be engaged at an earlier
stage in their professional lives and
given a sense of urgency about getting
involved in hazmat Mike made the point
that in recent years the barriers for
entry into these jobs has only increased
Therefore the older professionals have a
responsibility to pass on their knowledge
and experience
The opportunities to share knowledge
have significantly improved and over
the next 10 years it will be important
for specialists to make their voices
heard in these groups This year
delegates attending a CTIF and
Intervention in Chemical Transport
Emergencies (ICE) meeting which was
being held in the UK could also attend
the Hazmat conference as the two
events overlapped This enabled the
establishment of a fantastic forum of
ideas and experience More events and
meetings like this will be vital over the
next 10 years to continue the flow of
information provided
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
This diagram
shows the range
of operational
guidance that is
being tackled The
approach works
from left to right
starting with all
incidents looks
at the context
and then the
finer detail of the
activity required
for operational
response
The fire and rescue service has a vast amount of information to help it respond effectively to incidents Over the years this library of information grew and grew becoming unwieldy and unloved Back in 2012 the National Operational Guidance Programme began the job of reviewing it all getting it into a consistent format and making sure it was all current and based on modern best practice
HAZMAT RESPONSE NEW GUIDANCE FOR THE FIRE AND RESCUE SERVICE
Environmental Hazards
ALL INCIDENT CONTEXT ACTIVITY ACTIVITY
Performing Rescues
Hazardous Materials
Fires and FirefightingTransport
Sub-surface Height and Structures
Utilities and Fuel
Industrial and Commercial
Major Incidents
Marauding Terrorist Firearms Attack
Fires in the Built Environment
Wildfires
Water Rescue and Flooding
Rescue from Confined Space
Line Rescue
Animal Rescue
Physical Hazards
Health Hazards
Operations
Incident Command
Environmental Protection
By Fay Pisani Project Manager National Operational Guidance Programme
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
Hazardous materials guidance for UK
fire and rescue services is now made
up of several separate but linked
documents Generic guidance is
supported by specific hazard guidance
divided into three areas ndash physical health
and environmental Guidance covering
environmental protection is placed higher
in the framework as an all-incident piece
Underpinning all of this is a foundation
document that provides additional
knowledge and expertise
Generic hazmat guidance was published
in April 2016 The guidance covers the
generic hazards and controls when dealing
with hazmat incidents Guidance for Initial
Operational Response (IOR) to CBRNe
was developed early on in the Programme
in response to the political imperative A
separate piece of guidance on the special
Operational Response (SOR) to CBRNe
would then follow When the generic
Hazardous Materials guidance was later
developed it drew in much of the IOR
guidance that is not specific to CBRNe
More recently the Programme was
asked to include National Resilience (NR)
guidance into the guidance framework
The Hazardous Materials guidance will
incorporate NR guidance on IOR and
SOR CBRNe as well as NR guidance on
mass decontamination and detection
identification and monitoring (DIM) A major
change for the specific hazard guidance
being developed is the change in the
way that dangerous goods are classified
Previously the nine UN classes were used
(also known as the lsquotransport classesrsquo)
which was a basic system for the transport
of dangerous goods It was designed
The Programme took the 2012 publication lsquoOperational Guidance ndash Incidents involving hazardous materialsrsquo (produced by the Department for Communities and Local Government (DCLG) and the Chief Fire and Rescue Adviser (CFRA)) deconstructed it and then repackaged it into something manageable Along the way it brought the knowledge within it up to date
to reduce the risk of serious incidents
involving dangerous goods and the impact
of any incidents that might occur
The Project Board responsible for
developing the new guidance made a
policy decision to move away from the nine
transport classes and use the UN Globally
Harmonized System of Classification and
Labelling of Chemicals (GHS) instead It
is useful to note that the Classification
Labelling and Packaging (CLP) Regulation
((EC) No 12722008) aligns previous EU
legislation with the GHS as well
This is not a new system ndash the international
mandate that provided the impetus for
completing this work was adopted in
1992 at the United Nations Conference
on Environment and Development It is a
universal system for identifying chemicals
and communicating their hazards The
change will simplify the approach to hazmat
response and will ensure all hazards are
considered ndash including a number of hazards
to health that were previously overlooked
The GHS is divided into three areas
The physical hazards are sub divided into
16 areas ndash from explosives to flammable
liquids from gases under pressure to
organic peroxides The health list is slightly
shorter with 10 sub divisions ndash ranging
from acute toxicity to aspiration hazards
The environmental hazards are divided
into just two ndash hazards to the aquatic
environment and hazards to the ozone
layer (these have already been covered in
the published environmental protection
guidance) However the guidance focuses
on the different hazards presented to
firefighters at an incident
The Programme has created two short
animations1 2 to help explain these
changes and how they help firefighters
plan for and respond to incidents involving
hazardous materials
The first animation1 is a short intro to
the changes explaining the history and
is an accessible view for non-experts It
simplifies the hazards and control measures
for firefighters The second animation
focuses on the GHS
In addition to the two guidance documents
fire and rescue services can also consult a
new foundation resource It aims to provide
fire and rescue service personnel with
the detail required for effective safe and
proportionate hazardous material operations
At a local level policy writers in fire and
rescue services can take this document
along with the detailed guidance and
produce local policies that reflect their local
risk Itrsquos all part of a risk-based technical
framework produced by the Programme
During the summer the Programme ran
a consultation exercise The purpose
of this was to establish if there was
anything missing in the guidance and
if it was accurate and had the right
balance between the detailed foundation
materials and the more succinct guidance
documents That consultation closed at the
end of August and itrsquos too early to know
the results just yet However the plan is to
review the responses and publish the final
version by March 2018
1 httpsgooglNcjUwY
2 httpsgooglGv7njD
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
Can you describe your activities as the ER Team Leader
lsquoMy primary role is to make sure we
have a full team of responders available
for our commercial and Chemsafe
obligations I work alongside the support
responders to make sure the ERs are
equipped with the knowledge and
training that wersquove worked on and keep
them up to date with best practice and
legislationrsquo
And how have you found your experience of the Team Leader role so far
lsquoI think itrsquos very positive I took over a
very experienced team and we have had
a good level of resource in the time that
I have been in the role Many of the ERs
are very experienced and there is a good
level of stability in the team We actively
encourage our experienced ERs to share
their knowledge and experience with
newer ERs which helps them to reach
proficiency more quicklyrsquo
What parts of your career progression at NCEC have you enjoyed
lsquoI started as an ER many years ago
then became an ER supervisor and
then moved to my current role as Team
Leader Being an ER many years ago
gave me valuable experience and an
initial flavour of the advisory aspects of
the job While this was enjoyable I have
found the progression to ER supervisor
and now Team Leader stimulating as it
has given me even further experience
and the opportunity to use my skills to
develop more experts within the team
and optimise our resources to meet ever
increasing call numbersrsquo
CHRIS SOWDEN INTERVIEWChris has worked in the chemical emergency response area for over 10 years In this time he has gained extensive knowledge and experience of chemical safety regulations and how to deal with incidents to minimise the risks to people the environment assets and reputation
Chris is now the Team Leader of NCECrsquos emergency responders (ERs)
who are all qualified chemists He works closely with this team of
specialists to ensure their skills and experience are kept up to date
In this way they are equipped to respond effectively to the full range of
chemical incident calls they receive and the advice and support they
provide is appropriate and in-line with industry best practice
This enables clients to manage incidents safely while actively working
to mitigate risk
By Tuan Vu Emergency Responder
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
You left NCEC for a short time could you tell me what you were doing in that time and why you decided to come back to NCEC
lsquoI worked in the chemical manufacturing
sector and saw first hand what the
expectation of emergency response
actually was I worked with different
safety consultancies and understand
their approaches to chemical safety
which Irsquove been able to bring to NCEC
NCEC is continuously evolving and it
was so different when I came back
but the core principles of emergency
response have remained the same ndash
such as striving to be the best and
delivering the highest standard of
chemical safety advicersquo
What experiences in the chemical industry do you think are beneficial to your role as Team Leader
lsquoI first started doing dangerous goods
safety adviser (DGSA) work when I was
working in the chemical manufacturing
sector My responsibilities included
ensuring that the company I was working
for was compliant from the perspective
of classification of products that it was
moving and making sure that we had
robust systems in place for marking
drums and vehicles I also carried out
routine checks to make sure paperwork
was correctly filled in ndash although a lot
of that was automatically generated
from computer software so there
werenrsquot many issues From an ER point
of view itrsquos beneficial to have a good
understanding of transport regulations
so that we can help with specific calls
such as requests for detailed information
on loading vehicles or product
classification
I have also been involved in safety data
sheet (SDS) authoring This provides
a good level of understanding of the
hazards associated with a product
which is fundamental in emergency
response work and projects It also
enables you to interpret information for
supply classification easily and apply
it to different situations Many of the
ERs are encouraged to assist with SDS
authoring projects to improve their
knowledge ndash and I support them with my
extensive experience in this fieldrsquo
You are also taking part in the development of the National Operational Guidance (NOG) Can you provide some background as to your involvement with NOG and the collaboration behind it
lsquoI have enjoyed being involved with
both stages of the hazmat project
Tier 1 looked at general organisational
considerations needed by the
emergency service with regards to
hazmat incidents I used my regulatory
knowledge to provide technical advice
to the project team Tier 2 looked at
the types of hazardous materials that
first responders would deal with in real
incidents which included flammable
corrosive and toxic materials While
writing guidance for oxidising and
cryogenic substances I liaised with
fire and rescue service staff and
other parties The guidance has been
completed and is now being peer
reviewed I was very fortunate in that I
had the opportunity to collaborate with
hazmat officers and scientific advisers
who support fire and rescue services
and first responders They shared a
wealth of knowledge that I was able to
bring back to NCEC and pass on to
my teamrsquo
What do you think it is that you bring to Chemsafe
lsquoMy experience up to now provides
me with a deep understanding of the
challenges that the emergency services
face Being able to provide them with
technical support for various situations
can be reassuring for them Chemsafe
is a different type of call than those ERs
will normally receive and this provides
an important challenge for the team As
Team Manager I know that we have a
good blend of experienced ERs experts
and skilled trainees to continue providing
the standard of service we pride
ourselves onrsquo
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
Responsible CareCompanies in the chemical industry
have adopted Responsible Care as a
fundamental part of their role in the
communities they service with products
and employment The framework for the
scheme was first established in Canada
in 1985 and the global charter that all
members commit themselves to are
bull Continuously improve the
environmental health and safety
knowledge and performance of
technologies processes and products
over their lifecycles to avoid harm to
people and the environment
bull Use resources efficiently and minimise
waste
bull Report openly on performance
achievements and shortcomings
bull Listen engage and work with people
to understand and address their
concerns and expectations
bull Co-operate with governments and
organisations in the development and
implementation of effective regulations
and standards and to meet or go
beyond them
bull Provide help and advice to foster the
responsible management of chemicals
by all those who manage and use
them along the product chain
INTERVENTION IN CHEMICAL TRANSPORT EMERGENCIES
The European Chemical Industry
Council (CEFIC) decided to create a
pan-European scheme to promote
this message in 1991 so that all
members could make every effort to
transport their goods safely and in full
accordance with all relevant regulations
and codes of practice This scheme
is called Intervention in Chemical
Transport Emergencies (ICE)
ICEThe scheme is a co-operative
programme between European
chemical companies so effective
assistance can be provided to the
emergency services by
bull Making use of the emergency
response schemes of individual
chemical companies
bull Building on existing emergency
response schemes ndash local regional
and product-related (such as
bromine isocyanates and ethylene
oxide)
bull Co-operating with the national
competent authorities and the
national chemical industry federation
bull Promoting mutual assistance in the
chemical industry
Each ICE national scheme applies only
to distribution incidents and is formalised
between the national chemical industry
federation and the national competent
authorities In the case of the United
Kingdom the Chemsafe scheme was set
up in conjunction with the Department
for Transport (DfT) and the Chemical
Industries Association (CIA) and is
managed by the National Chemical
Emergency Centre (NCEC) which
acts as the ICE centre for the United
Kingdom
The ICE scheme is provided on a
voluntary basis but does require a
companyrsquos commitment to provide help
in land-based distribution incidents on
the request of emergency services This
assistance can be provided depending
on the capabilities of the company at
three levels
bull Level 1 Remote product information
and general advice by telephone or fax
bull Level 2 Advice from an expert at the
scene of an incident
bull Level 3 Assistance with personnel
equipment at the scene of an incident
The ultimate responsibility for
intervention at the site of an incident
rests with the emergency services but
the national ICE centre will provide
in the local language initial telephone
advice for immediate control of the
incident The centre will then contact
the producing company obtain
further information or mobilise mutual
assistance The centre can also be
contacted when
bull The supplier cannot be contacted
directly
bull The product or manufacturer cannot
be identified
bull Mutual assistance needs to be
mobilised
bull An incident occurs during international
transportation
By Dan Haggarty Head of Emergency Response
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
Each ICE centre can contact any of
the other national centres to request
assistance The chart below shows a
typical flow of response ndash although each
national scheme can adapt the operation
to its specific needs
Emergency respondersThe ICE centres in each country are
manned 24 hours a day by emergency
responders (ERs) To provide competent
assistance each ER from the ICE centre
or companies must meet a minimum
requirement through experience and
or training which has been agreed by
the chemical industry through CEFIC
For Level 1 response these skills
include interpreting safety data sheets
understanding incident handling and
having good communication skills to
pass vital information to the emergency
services
The ERs have liaised with European
colleagues on behalf of UK Fire and
Rescue Services and this contact can
be initiated as appropriate based on
the incident The case of what became
known as lsquoLe Pongrsquo in 2013 highlights
one of the situations where the scheme
can be used A number of calls were
made to the Chemsafe phone line from
the emergency services reporting a strong
smell of gas throughout the South East
of England The source of the smell was
found to be a gas leak in France Thanks
to contact with the French scheme
lsquoChemical Industry Aid for the Emergency
Servicesrsquo (TRANSAID) Network it was
found that the product released was
mostly methyl mercaptan TRANSAID
passed details of the government agency
in France dealing with the incident to
NCEC
This enabled us to relay information
back to the Chemsafe callers about the
response being taken by the French
authorities Our ER also contacted the
company involved directly to obtain
information on the progress and severity
of the incident which assisted the
response in the UK
Chemsafe and ICENCEC is proud to manage Chemsafe in
the United Kingdom as part of the ICE
scheme We provide Level 1 telephone
advice to help emergency services across
Europe when they are dealing with land-
based distribution incidents As part of
ICE we are able to contact other sources
of advice so that further support can be
requested if needed CEFIC estimates
that 75 of all transport incidents require
only Level 1 advice but the ICE scheme
is available to the emergency services to
allow chemical companies to fully support
the communities in which they operate
Advicehelp (level 1 2 3)
to Fire brigade
Inform supplier
NO
NO
NO
YES
Find supplier YES
country Icountry II
Enough info
Fire and rescue service at site of incident
Contact supplier participating company
Contact national ICEC centre II
Contact national ICEC centre I
YESFind participating
company
National ICE scheme National ICE scheme
Further informationCEFIC wwwceficorg
Responsible Care Global Charter
wwwceficorgDocuments
ResponsibleCareRC_
GlobalCharter2006[1]pdf
Mutual Aid Schemes
wwwceficorgIndustry-support
Transport--logisticsTransport-
Emergency-Scheme-ICE-Product-
Specific-Schemes
Responders
wwwceficorgDocuments
IndustrySupportTransport-and-
LogisticsICE-Guidelinespdf
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
IFRA is a charity that provides free fire safety training and kit to crews worldwide The aim of the Bosnia mission was to deliver industry-donated kit and equipment to fire crews in the city of Cazin and provide practical training on how to use the different items properly
Over the course of 2 weeks a crew of
IFRA firefighting professionals delivered
an intensive programme of training to
Bosnian fire crews and members of the
local community
The training programme focused on two
areas
Fire service training ndash aimed at local
firefighters concentrating mainly on
appliance and equipment use
Community training ndash educating local
residents on in-home fire safety and road
and water safety best practice
The fire service training covered several
key areas including breathing apparatus
road traffic collisions trauma care
firefighting tactics hazmat awareness
and information gathering which included
a demonstration of NCECrsquos Pocket
Chemdatareg mobile app
The convenience of the mobile app
proved useful to IFRA in the practical
In 2017 NCEC donated licences of its world-leading chemical hazard database Chemdata to the International Fire and Rescue Association (IFRA) as part of a relief mission to Cazin in North West Bosnia starting on 18 August
delivery of the hazmat awareness training
Pocket Chemdata allowed trainers to
access chemical hazard information
remotely demonstrating to local crews
the type of information available via such
platforms and the value it can have while
dealing with an incident
Commenting on the Bosnia mission
NCECrsquos Chemdata Product Manager
Maria Stearn said lsquoNCEC is delighted to
be a part of the relief effort and helping
IFRA to raise standards in the level
of fire safety response training being
delivered worldwide It is important to
highlight the significance of accurate and
timely chemical hazard information in an
emergency situation Wersquore pleased that
Pocket Chemdata has proved a useful
tool in demonstrating thisrsquo
The Cazin mission was IFRArsquos 9th training
mission to Bosnia and its 60th worldwide
The trip was well received by local crews
and residents alike with proud members
of the crew posting regular updates and
highlights from the mission online to
friends and followers
For more details on the
mission and to read the
highlights from the trip
please visit
wwwfacebookcom
groups389139507192
CHEMDATAreg LICENCES DONATED TO HELP TRAIN BOSNIAN FIREFIGHTERS
By Maria Stearn Chemdata Product Manager
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
ASSAULTS INVOLVING CORROSIVE MATERIALS
NCECrsquos Emergency Responders have noticed an increase in the number of calls they are receiving that relate to assaults involving acidic and caustic substances These terrible and disfiguring assaults not only present risks to the victim but also to the emergency services attending the incident With that in mind we have prepared this article to help better equip you and your teams to be able to understand what risks may be present in this sort of chemical incident and how best to protect yourselves and the victim
By Tom Johnson Emergency Responder
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
concerns regarding the atmosphere since
as nitric acid decomposes it can produce
fumes which are a mixture of nitrogen
oxides Fire service teams made the area
safe but the exact details of how this was
achieved were unavailable at the time
of writing The victim was evacuated to
hospital for treatment
In one incident the victim had nitric acid
poured over them as they slept on a sofa
This resulted in fumes and heat being
produced It also led to concerns from on-
scene responders regarding the respirable
atmosphere and whether there was a fire
risk from the contaminated sofa In this
case the fire risk was real as were the
While corrosive substances have the same classification
treatment can be affected by the nature of the corrosive
substance For example caustic agents may act insidiously due
to how quickly they destroy nerves ndash following a period of pain
the pain may stop leading the victim to believe that the effects
have stopped However unlike acids caustic agents are not self-
limiting and will continue to react far longer on the skin Acids
also have additional hazards associated with them For example
strong mineral acids such as nitric or chloric acid are oxidising
agents and can increase fire risk and cause combustible
materials to smoulder and burn Some acids also have specific
hazards For example highly concentrated sulfuric acid is
viscous and will not run off the skin quickly It is also dehydrating
meaning it will dry out the skin as well as causing burns
The following are suggested actions to
consider for first responders attending an
assault involving corrosive materials
bull Evacuate any casualties
and perform initial
decontamination Speed
is essential in acid
attacks as it may only
take a few minutes for a
corrosive agent to cause
serious damage Copious
amounts of water should
be applied to dilute the
material as much as
possible and eventually
remove it from the skin Try to ensure any
runoff does not come into contact with
other uncontaminated parts of the body
Getting people away from the agent is
also essential as it still remains hazardous
following the initial attack
bull Hand over casualties to the
ambulance service as quickly as
possible Once again due to the speed
with which corrosives act it is likely that
victims of acid attacks will need to have
medical attention or at the very least
Assaults involving corrosive chemicals (often referred to sometimes incorrectly as acid attacks) are where an assailant exposes a victim to a corrosive chemical with the intention of causing harm This is usually done by throwing or spraying a chemical into the victimrsquos
face Typically the corrosive is highly concentrated so effects are noticed
shortly if not immediately after the assault Exposure can lead to burns
scabs ulcers blanching alopecia and scarring Corrosives cause severe
and long-lasting effects when they come into contact with eyes
and can easily lead to
loss of sight
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
monitoring As a result handing over
to the ambulance service should be a
priority for other emergency services as
this will also free up their resourcing to
take care of the rest of the situation
bull Make the scene safe - reduce
fire risk and the risk of structural
damage While this may seem
obvious other risks presented by
some corrosive materials may not be
immediately apparent For example soft
furnishings soaked in nitric acid may
not appear hazardous at the time of the
incident but as the nitric acid dries and
becomes more concentrated the soft
furnishings could begin to smoulder
and eventually burst into flames hours
after contamination due to the oxidising
properties of nitric acid
bull Preserve the scene as far as
reasonably practicable Safety is of
course the top priority but reasonable
steps should be taken to ensure that
evidence is not disrupted or removed if
at all possible Prevention is the best cure
so preserving evidence will help to get
offenders off the street preventing further
attacks and may dissuade others
bull Sample the scene This will almost
certainly be carried out by forensic
teams but simple field tests may help
others in performing their job Knowing
if the liquid used in the attack was
acidic or caustic will help inform medical
personnel on a course of treatment
Likewise knowing if the substance is
oxidising will help fire teams decide
what they should remove and what can
remain undisturbed
bull ALWAYS follow your operational
guidance and training This list in no
way overrides any previous training or
operational guidance you may have
received Your response to an incident
should be based on a dynamic risk
assessment and best practice
Disfiguring assaults have been
commonplace in South Asia and the
Indian subcontinent for a long time
In the west the number of assaults
involving corrosive materials has been
steadily increasing over the last 6 years
Between 2011 and 2016 there have
been a reported 1500 attacks involving
a corrosive substance in London and
allegedly many go unreported due to
gang violence Typically this type of
crime is associated with female victims
ndash women are often attacked by jealous
former partners love rivals rejected
suitors or even angry family members
Globally women make up 80 of
corrosive substance attack victims
However in the UK 71 of victims
are male This is likely to be due to
the increased prevalence of the use of
corrosive materials within gang violence
It is thought that these assaults are largely
premeditated as it takes time to source
a corrosive agent However with gang
violence this is not always the case
as gang members may carry corrosive
materials in drinks bottles for lsquoself-
defencersquo in preference to knives or guns
This is because it will not be apparent
to observers that a person is carrying a
dangerous substance Therefore it will be
easily concealed and go undetected by
law enforcement personnel One alarming
trend we are seeing is schoolchildren
taking corrosive agents into school as an
alternative weapon to knives
A major risk with assaults involving
corrosives is the potential for others to be
affected For example a recent high-
profile case in London left 20 people
injured when an argument broke out
and ended in acid being thrown in a
busy nightclub The risk of other people
being affected is often not considered
by attackers and if it is then it may be
overlooked As a result an assault could
easily be a mass casualty situation putting
an increased strain on attending resources
As previously mentioned essential rapid
decontamination is already a challenge
due to the fast-acting nature of corrosives
so this will be even harder with numerous
casualties and limited resources
Many household items can be used in
these assaults Therefore it is difficult to tell
if something is innocuous or is intended
to be used as a weapon As with most
clandestine chemistry incidents it is worth
noting if a normal household substance is
present in large quantities or is in a strange
place For example a bottle of bleach under
the sink is fairly common However while 10
bottles in someonersquos vehicle bedroom or
lounge is not a sign of wrongdoing it may
need further investigation
NCEC has experience in
providing advice following
assaults involving corrosive
materials One example of
a call we received related to
a case of mistaken identity
where a man answered his
door and had sulfuric acid
thrown in his face The effects
were quickly noticeable ndash vision
impairment and extreme pain
ndash and the person was taken
to hospital The emergency
services thought the substance
was sulfuric acid but were
unsure because of its colour
We provided advice on
protecting the crew about
to enter the property how to
sample the substance and
how to identify the substance
We later advised the scenes
of crime officer that forensic
sampling should be carried out
immediately to avoid loss of
evidence The investigation led
to criminal proceedings and a
guilty verdict but unfortunately
the victim suffered life-altering
injuries
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
OpioidsOpioids are a class of drugs that can be
derived from opium (such as morphine
and the illegal drug heroin) or made
synthetically (such as fentanyl) Many
opioids have useful medical properties
such as pain relief and are used
extensively by medical professionals
Fentanyl is one of these drugs and has
many medical uses such as analgesia
and pain relief It is 50 to 100 times more
potent than morphine and its analogue
carfentanyl is 10000 times more potent
than morphine This means that only
small quantities of the drug are needed
to achieve the required effect However
it also means that overdoses occur using
much lower quantities
The scale of illegal opioid drugs use is
an ongoing issue around the world
State of PlayThe supply of fentanyl has been
curtailed recently as China introduced
legislation in March 2017 to make its
production and that of three other
opioids illegal According to reports
received by NCEC fentanyl is believed
to be prevalent in North America
Europe and Australia
In 2012 a number of experts from the
European Union looked at the trends
in drug use and produced a report
entitled lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo[1] This concluded
that the use of fentanyl is normally
down to the low availability low purity
or high price of heroin which drives
addicts to find alternatives
The report states that between 2001
and 2011 50 overdose deaths were
attributed to fentanyl use in the UK
but that many of these deaths may
be related to patients prescribed
with fentanyl for chronic pain It also
highlights the prevalence of drug use
in Estonia where 650 deaths were
reported between 2005 and 2011
The drug market in Europe is based
on three routes to the end user ndash illicit
production diversion and misuse
of medicines and the internet sale
FENTANYLFentanyl is attributed to an increase in drug deaths across Europe and to the opioid crisis in the United States of America (USA) It is still little known in the UK but the emergency services are seeing an increase in its presence on the illicit market In addition the number of calls to Chemsafe about fentanyl and its derivatives having been rising recently
By Dr Nigel Blumire Emergency Responder
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
of non-controlled new psychoactive
substances The manufacture of fentanyl
and its analogues have a common
synthetic route allowing rapid synthesis
and change of feedstocks if any become
unavailable All of the drugs in the
fentanyl lsquofamilyrsquo have similar analgesic
effects but vary in potency
Several articles[2][3][4] have been
published by the media in the UK
highlighting the dangers of fentanyl
The National Crime Agency reports
that in the first 8 months of 2017
at least 60 deaths were attributed
to heroin that had been laced with
fentanyl or carfentanyl[5] A national
alert was issued in April 2017 by Public
Health England to warn medical and
drugs services to remain vigilant in
relation to fentanyl prescriptions
Hazards of FentanylThe hazards associated with each drug
in the fentanyl family are similar ndash all are
toxic through skin contact ingestion
injection and inhalation Since they are
all more potent than morphine only
small quantities are prescribed normally
with only 1 of the active ingredient in
solution given for pain relief
The National Crime Agency reported that
fentanyl[5] has been detected in various
formats across Europe ndash in a capsule
as a white powder (Denmark and the
Netherlands) as a light green powder
(Slovenia and Estonia) as a brown or
light brown powder (Estonia) as a ready
to use nasal spray (Sweden) and as light
blue tablets (Finland) Lethal overdoses
can result from ingesting minute
quantities of fentanyl analogues but may
also occur via absorption through the
skin or inhalation
The Justice Institute of British Columbia
has launched a fentanyl safety website
(wwwfentanylsafetycom)[6] for first
responders It contains information
on the
bull Safe handling of suspected fentanyl
and its analogues
bull Appropriate personal protective
equipment recommended for various
quantities of the drug
bull Symptoms of an opioid overdose
(eg respiratory distress nervous
system depression drowsiness
dizziness nausea and reduced or
loss of consciousness)
bull Use of naloxone as an antidote for
opioid overdoses
bull Common side effects of using the
antidote
bull Mitigation strategies to be used
in case an overdose victim is
experiencing diarrhoea vomiting or
convulsions after being administered
the antidote
Chemicals involved in fentanyl synthesis Several chemicals can be used to
manufacture fentanyl but a high-
yielding route uses caesium carbonate
acetonitrile dichloromethane aniline
and acetic acid If these chemicals
are found with glassware and heating
equipment it is possible that fentanyl or
its derivatives are being produced The
starting material does not need a Home
Office licence
Reports in the USA indicate that the
majority of fentanyl or its derivatives
are imported into North America from
China which could potentially be the
same route for Europe[7] As well as
introducing the ban on the production
of fentanyl and its derivatives in March
2017 China is working with the USA
to try to stem the epidemic of opioid
overdoses reported in North America
References
[1] European Monitoring Centre for Drugs and
Drug Addiction lsquoFentanyl in Europe EMCDDA
Trendspotter Studyrsquo 2012
[2] lsquoFentanyl deaths Warning as drug kills
lsquoat least 60rsquorsquo BBC 1 August 2017 [Online]
Available httpwwwbbccouknewsuk-
england-40793887 [Accessed 12 August 2017]
[3] lsquoAt least 60 UK drug deaths in past eight
months linked to fentanylrsquo The Guardian 1
August 2017 [Online] Available httpswww
theguardiancomsociety2017aug01at-least-
60-uk-drug-deaths-in-past-eight-months-linked-
to-fentanyl [Accessed 12 August 2017]
[4] lsquoNational Crime Agency says 60 people have
died in the UK this year from taking painkiller
Fentanylrsquo Independent 1 August 2017 [Online]
Available httpwwwindependentcouk
newsukhome-newsfentanyl-60-people-die-
overdose-uk-national-crime-agency-painkiller-
opioid-epidemic-a7871536html [Accessed 12
August 2017]
[5] N C Agency lsquoRecent deaths possibly
linked to fentanylrsquo National Crime Agency
April 2017 [Online] Available httpwww
nationalcrimeagencygovukpublications795-
recent-deaths-possibly-linked-to-fentanylfile
[Accessed 12 August 2017]
[6] J I o B Columbia lsquoFentanyl Safety for
First Respondersrsquo Justice Institute of British
Columbia [Online] Available httpswww
fentanylsafetycom [Accessed 12 August 2017]
[7] lsquoChina Bans Four Kinds of Fentanyl ndash Why
Wonrsquot This Help the USrsquo Narconon 13 March
2017 [Online] Available httpwwwnarconon
orgblogchina-bans-four-kinds-of-fentanyl-why-
wont-this-help-the-ushtml
European Monitoring Centre for Drugs and Drug
Addiction lsquoEuropean Drug Report Trends and
Developmentsrsquo 2015
WEDINOS lsquoPHILTRE Annual Reportrsquo 2015
M McEvoy lsquoMethyl Fentanyl Bad Stuffrsquo
Fire Engineering [Online] Available http
communityfireengineeringcomprofilesblog
showid=12196723ABlogPost3A639236
[Accessed 21 August 2017]
lsquoACMT and AACT Position Statement
Preventing Occupational Fentanyl and Fentanyl
Analog Exposure torsquo American College of
Medical Toxicology and American Academy of
Clinical Toxicology [Online] Available http
wwwacmtnet_LibraryFentanyl_Position
Fentanyl_PPE_Emergency_Responders_pdf
[Accessed 21 August 2017]
lsquoCommon sense guidelinesrsquo The Interagency
Board [Online] Available httpswww
interagencyboardorgsitesdefaultfiles
publicationsIAB20First20Responder20
PPE20and20Decontamination20
Recommendations20for20Fentanylpdf
[Accessed 21 August 2017]
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
subsequently break down into ammonia in the conditions of
a sauna and produce the levels reported Our discussions
involved the health centre manager who informed us that
some teenagers had been in the sauna around the time
that the symptoms started He added that they had been
urinating on the saunarsquos heating elements and asked if this was
possibly the source We informed people at the scene that the
decomposition of urea present in urine could release ammonia
and potentially isocyanates which would cause symptoms
such as those described
The sauna coals were removed and examined outside They
were found to be the source of the ammonia and the staff were
instructed to wash down the sauna with plenty of water
Our chemical expertise means that we are aware that some
chemicals can occur in very bizarre situations Our training in
chemistry and experience means that we can predict reactions
and suggest potential products This information allows people
on scene to protect themselves and act even when we have a
novel scenario to deal with
CALL OF INTEREST
Reaction
Exercise (including ICE)
Spillagerelease
Identify chemical or company
Fire
Emergency response - general
General chemical information
Medicalfirst aid
Disposal
Emergency number checks
Decontamination
TransportHampS regulations
Information on NCECChemsafe
CALLER TYPES
LATEST CALL STATISTICS
ENQUIRY TYPES
Fire and rescue services
Police
ICE centre
Local authorityGovernment
Call data April - September 2017
By Tom Johnson Emergency Responder
Ammonia at a health club (October 2017)We received a call from a fire and rescue service attending an
incident at a health club where several people around the pool
area were complaining of runny eyes and sore throats These
are typical symptoms to be expected when there has been
a release of chlorine from pool chemicals However this was
quickly discounted because the pool had been cleaned that
morning and many people had used it before some started
presenting symptoms at around 1600 The fire and rescue
service had detected ammonia in the health clubrsquos sauna
which gave our Emergency Responders the first clue as to the
cause of the described symptoms
We considered the possible sources of ammonia in a sauna
and thought that as small amounts of uric acid are excreted
in perspiration it could come from people using the sauna
However we thought it unlikely that perspiration could
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
THE SPILL ndash ISSUE 4
01235 753363bethandaviesricardocomwwwthe-nceccomchemsafe
bull A better understanding of the role of
NCEC and its operations
bull A reminder of the Chemsafe scheme
and the role of NCEC within it
bull Improved communications between
the emergency services and NCEC
bull An overview of chemical fatality
incidents
bull An overview of waste fire incidents
bull An outline of the recent changes to
the Globally Harmonized System
of Classification and Labelling of
The objectives of the refresher training are to provide
Chemicals (GHS) to show the new
labelling and symbols that are likely to
be encountered
bull A look at the value of proportionate
advice in responding to an incident
The presentation is aimed at hazmat
officers fire control operators police
officers However we would encourage
the attendance of any others who might
find it useful for example your local
Environment Agency representative
Chemsafe EMERGENCY SERVICES REFRESHER TRAINING
Working for chemical andpharmaceu13cal businesses
FREE
Help us to help you
Chemsafe and NCEC
We are aware that many of you conduct safetycompliance visits to chemical company premises
We would appreciate it if you could remind them
that they should register safety data sheets with the
National Chemical Emergency Centre so that the
Emergency Services can rapidly access the required
information in the event of an emergency involving one
of their products
If they would like further information then please refer
them to chemsafericardocom
Chemsafe is the UK chemical industryrsquos voluntary scheme for providing expert advice to the emergency services in the event of a chemical emergency
The National Chemical Emergency Centre (NCEC) has
delivered a free advice line for over forty years through
a 365247 dedicated telephone number provided
only to the emergency services and other nominated
organisations Eligible responders can obtain the
24- hour Chemsafe number or make any other
Chemsafe related enquiries by contacting NCEC
The presentation is approximately
3-4 hours long depending on
discussion and questions
We do not charge for this
presentation but would appreciate
payment of any travel and
subsistence costs incurred
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C
TEL
+44 (0) 1235 753654
ncecricardocom
KEEP IN TOUCHIf you have any comments about or
experiences of using the Chemsafe
service that you would like to share in
future issues please contact us using
the details below
You can also contact us if you would
like to know more about Chemsafe
and the other services and products
provided by NCEC
copy R
icar
do
-AE
A 2
018
NC
EC
9J
an18
17
SPECIALIST ADVICE
HAZMAT
NCEC2018ANNUALCONFERENCE
+44 (0) 1235 753654
Visit
the-nceccomhazmat-2018
to book your place
A S I A P A C I F I C