37
Welcoming Remarks by the Conference Chair Dear PPS Friends, On behalf of the Organizing Committee, I would like to welcome each of you warmly to the PPS Americas Conference 2012 in Niagara Falls, Canada. It is very encouraging to note that polymers (and polymer-based composites) have created a lot more new applications compared to metallic and ceramic materials, and that polymer products have been replacing numerous metallic, ceramic, wood, and paper products in various industries. For example, usage of polymer parts in automobiles increased from 1% in 1960 to 7% in 2000, and to 15% in 2006 by weight. We are watching rapidly changing demands, challenges, and opportunities as the resin prices are going up, new technologies are available, emerging Chinese companies are actively moving in the markets, etc. I have personally observed that any products based on inexpensive technologies without much scientific component could not survive in the markets. In this context, there is a strong need of: (i) in-depth understanding of the existing technologies and (ii) science- based innovations in materials, products, and manufacturing processes. Our PPS Conferences have been a great channel of disseminating the scientific and technological advancements for the polymer processing area. PPS Americas Conference 2012 will serve the role of satisfying these two needs of in-depth understanding and science-based innovations. I would like to acknowledge the great efforts made by the Organizing Committee consisting of Professor Hani Naguib, Guida Williamson, Dr. Sunny Leung, Dr. Amir Ameli, Dr. Anson Wong, Reza Rizvi, Lun Howe Mark, Raymond Chu, Reza Nofar, Konstantin Kovalski, Shahrzad Gaffari, Peter Jung, and Vahid Shaayegan. Without their sacrifice and commitment, this event could not have been organized successfully. The support of our sponsors DSM Xplore and Leistritz and our industry displays have assisted greatly in bringing you a quality event with a fantastic program. And finally, I would like to thank The Department of Mechanical and Industrial Engineering at the University of Toronto for their countless hours of administrative help and support of this exciting field of science. Welcome again. Chul Park Chair of PPS Americas Conference 2012

Welcoming Remarks by the Conference ChairWelcoming Remarks by the Conference Chair Dear PPS Friends, On behalf of the Organizing Committee, I would like to welcome each of you warmly

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  • Welcoming Remarks by the Conference ChairDear PPS Friends,

    On behalf of the Organizing Committee, I would like to welcome each of you warmly to the PPS Americas Conference 2012 in Niagara Falls, Canada.

    It is very encouraging to note that polymers (and polymer-based composites) have created a lot more new applications compared to metallic and ceramic materials, and that polymer products have been replacing numerous metallic, ceramic, wood, and paper products in various industries. For example, usage of polymer parts in automobiles increased from 1% in 1960 to 7% in 2000, and to 15% in 2006 by weight.

    We are watching rapidly changing demands, challenges, and opportunities as the resin prices are going up, new technologies are available, emerging Chinese companies are actively moving in the markets, etc. I have personally observed that any products based on inexpensive technologies without much scientific component could not survive in the markets. In this context, there is a strong need of: (i) in-depth understanding of the existing technologies and (ii) science-based innovations in materials, products, and manufacturing processes.

    Our PPS Conferences have been a great channel of disseminating the scientific and technological advancements for the polymer processing area. PPS Americas Conference 2012 will serve the role of satisfying these two needs of in-depth understanding and science-based innovations.

    I would like to acknowledge the great efforts made by the Organizing Committee consisting of Professor Hani Naguib, Guida Williamson, Dr. Sunny Leung, Dr. Amir Ameli, Dr. Anson Wong, Reza Rizvi, Lun Howe Mark, Raymond Chu, Reza Nofar, Konstantin Kovalski, Shahrzad Gaffari, Peter Jung, and Vahid Shaayegan. Without their sacrifice and commitment, this event could not have been organized successfully. The support of our sponsors DSM Xplore and Leistritz and our industry displays have assisted greatly in bringing you a quality event with a fantastic program. And finally, I would like to thank The Department of Mechanical and Industrial Engineering at the University of Toronto for their countless hours of administrative help and support of this exciting field of science.

    Welcome again.

    Chul Park

    Chair of PPS Americas Conference 2012

  • PPS Americas Conference 2012 Sponsors and Industry Display Participants Sponsors �

    2

  • Industry Display Participants Anton Paar Canada

    Brabender Technologie Inc. Compuplast

    C.W. Brabender Instruments Inc.

    Dieter Scientific

    Hanser Publications

    Instron

    TA Instruments

    3

  • Table of ContentWelcoming Remarks by the Conference Chair 1

    Sponsors and Industry Display Participants 2

    Table of Content 4

    PPS 2012 Organizing Committees 5

    Polymer Processing Society 6

    General and Special Symposia 8

    General Information

    Registration 9

    Instructions for Speakers, Poster, and Best Student Poster Competition 10

    Internet Facility, Niagara Tour & Winery Banquet, Breakfast and Coffee Breaks 11

    Summary of Events 12

    PPS Americas Conference 2012 Schedule 14

    PPS Americas Conference 2012 Map 15

    Plenary and Keynote Lectures 16

    Technical Program of PPS Americas Conference 2012 22

    Program of the Poster Session 35

    Abstracts of Plenary Lectures 38

    Abstracts of Keynote Lectures and Oral Presentations 45

    Tuesday, May 22, 2012 Morning Sessions 46

    Tuesday, May 22, 2012 Afternoon Sessions 117

    Wednesday, May 23, 2012 Morning Sessions 190

    Wednesday, May 23, 2012 Afternoon Sessions 260

    Thursday, May 24, 2012 Morning Sessions 280

    Thursday, May 24, 2012 Afternoon Sessions 352

    Abstracts of Poster Presentations 414

  • PPS 2012 Organizing Committees Conference Chair Chul Park

    Technical Program Chair Hani Naguib

    Technical Committee and Advisors

    Adbellah Ajji

    Phil Bates

    Pierre Carreau

    Michel Huneault

    Musa Kamal

    UT Sundararaj

    John Vlachopoulos

    Organizing Committee Amir Ameli

    Raymond Chu

    Shahrzad Gaffari

    Peter Jung

    Sunny Leung

    Lun Howe Mark

    Reza Nofar

    Reza Rizvi

    Vahid Shaayegan

    Anson Wong

    Conference Coordinator Guida Williamson

  • Polymer Processing SocietyThe Polymer Processing Society (PPS) was founded in March 1985 at the University of Akron, Akron, Ohio, USA. The intent was to provide a mechanism and format for interaction and presentation of research results in the international polymer processing community.

    The goals of the society are to foster scientific understanding and technical innovation in polymer processing by providing a discussion forum for the worldwide community of engineers and scientists in the field. The thematic range of the PPS encompasses all formulation, conversion and shaping operations applied to polymeric systems in the transformation from their monomeric forms to commercial products.

    Membership in PPS is open to all researchers in the field, and to all persons who feel the activities of the society advance their professional development.

    PPS Executive Officers

    President: Ica Manas-Zloczower (USA)

    President-Elect: Gluseppe Titomanlio (Italy)

    Past President: Takeshi Kikutani (Japan)

    Secretary: Evan Mitsoulis (Greece)

    Treasurer: M. Cengiz Altan (USA)

    IPP - Chief Editor: Andrew Hrymak (Canada)

    PPP – Chief Editor: Musa Kamal (Canada)

    Member-at-Large: Sati Bhattacharya (Australia)

    Member-at-Large: Mosto Bousmina (Morocco)

  • PPS Country Representatives

    Austria: Clemens Holzer

    Belgium: Paula Moldenaers

    Brazil: Elias Hage Jr and Luiz Antonio Pessan

    Canada: UT Sundararaj

    China: X. Xi / Qi Wang

    Czech Republic: Petr Saha

    France: Jean-Marc Haudin

    Germany: Volker Altstaedt and Hans-Joachim Radusch

    Hungary/South Africa: Laszlo Halasz

    India: Anup K. Ghosh

    Iran: Hossein Nazockdast

    Israel: Sam Kenig

    Japan: Toshitaka Kanai and Kiyohito Koyama

    Korea: Jin Kon Kim

    The Netherlands Gerrit W. M. Peters

    Portugal: Jose Covas

    Saudi Arabia: I. A. Hussein

    Taiwan: Shih-Jung Liu

    Thailand: Krisda Suchiva

    Turkey: Yusuf Menceloglu

    UK: Phil D. Coates

    USA: Marino Xanthos

  • General and Special Symposia Symposia Chairs

    G01 Biodegradable and Sustainable Polymers

    Michel Huneault Amar Mohanty

    G02 Blow Molding, Rotomolding, and Thermoforming

    Celine Bellehumeur

    G03 Blends, Properties, and Structure UT Sundararaj Roland Hingmann

    G04 Composites Phil Bates Marie-Claude Heuzey

    Martin Bureau

    G05 Crystallization Jean-Marc Haudin

    Abdellah Ajji

    G06 Mixing and Extrusion Sebastian Canevarolo

    Dilhan Kalyon

    G07 Films and Fibers Takeshi Kikutani

    Miko Cakmak

    G08 Foams Volker Altstaedt Masahiro Ohshima

    G09 Injection Molding Musa Kamal Tom Turng

    G10 NanoMaterials and Nano-composites

    Mosto Bousmina

    Masami Okamoto

    G11 Numerical Computation Andrew Hrymak Patrick Anderson

    G12 Reactive Processing Costas Tzoganakis

    G13 Rheology Savvas Hatzikiriakos

    Joao Maia Jose Covas

    S01 Industrial Session John Perdikoulias

    Charles Martin

    S03 Polymer Coatings and nanocoatings

    John Vlachopoulos

  • Registration Conference registration will commence on Monday, May 21st, at 1:00 pm at the registration desk located in the Oakes Foyer on the Mezzanine level. Onsite registration is also available at the registration desk during the conference. Registration Fees:

    PPS Members CAN $650 Non Members CAN $730 Students (without banquet) CAN $230 Exhibitors (includes full conference) CAN $1300 Niagara Tour & Winery Banquet (Guest) CAN $150 One Day Only (does not include banquet) CAN $275

    The registration for non members includes one year membership in the Polymer Processing Society beginning after the conference. The full registration fees will cover the reception on Monday, the Niagara Tour & Winery Banquet dinner on Wednesday as well as all lunches. All fees include HST.

    o Please note that you must register first and then submit a cheque as payment. o Credit cards are NOT being accepted at this time. o Payment onsite is only available by cheque or exact cash amount in Canadian Funds. o Receipts will only be available onsite upon check in at registration.

    Submit Payment by Cheque:

    Cheque payable to: University of Toronto Mail to: PPS Americas Conference 2012

    176 Endeavour Drive Cambridge, ON N3C 4C9 Canada

    Payments

    o The preferred method of payment is by cheque in Canadian Funds. o Cancellation prior to May 1st is subject to a $50 processing fee. Cancellations must be

    submitted in writing to [email protected]. Cancellations after May 1st are not refundable.

    o For further information or questions, please contact Guida Williamson at (519) 249-0545 or via email at [email protected].

    o If you would like to be on our mailing list, please send us your email.

    9

  • Instructions for Speakers Keynote oral papers are limited to 30 minutes and Regular oral presentations are limited to 20 minutes, including approximately 5 minutes for questions, discussion and changeover of the session. Speakers are requested to present themselves to their session chair 15 minutes before the beginning of the session. The presentation rooms will be equipped with projectors, computers and laser pointers.

    Poster Instructions The Poster session will be held in the Oakes Foyer, Wednesday May 23rd from 04:00 pm to 05:30 pm. The maximum poster dimensions are 34 inches (86 cm) high by 26 inches (66 cm) wide. The posters should be installed on the poster boards according to the assigned poster number. The posters should be installed from Tuesday May 22nd morning to Thursday May 23rd afternoon till 03:00 pm.

    PPS Americas 2012 Best Student Poster Competition The organizing committee is pleased to announce the best student poster competition as part of the PPS Americas 2012 Conference in Niagara Falls. Posters will be judged by a committee and the finalists are required to present their posters at the poster session on Wednesday, May 23, 2012. All finalists will be honored during the Poster Competition Award Ceremony held in the Oakes South Ballroom on Thursday, May 24, 2012, at 8:20 am.

    10

  • Internet Facility Complimentary Wireless Internet access is available at the Lobby level and at the Great Room Lounge & Bar. Please visit the Front Desk to obtain an access code for the service. Wired and Wireless High Speed Internet access is also available to other areas of the hotel at a daily rate of $12.95 CAD + taxes. Please visit the Front Desk for details.

    Niagara Tour & Winery Banquet The Niagara Tour & Winery Banquet is scheduled on Wednesday, May 23, 2012 from 5:30 pm to 8:00 pm, following the Poster session. Shuttle buses will depart the Marriott Gateway on the Falls hotel at 5:15 pm and at 6:15 pm. Participants are advised to get on the bus at the parking lot side entrance by the pool 15 minutes prior to the scheduled departure time.

    Breakfast and Coffee Breaks Breakfast

    For Marriott Gateway on the Falls guests, breakfast vouchers are included with your stay and will be issued at the Front Desk upon checking-in.

    Coffee Breaks

    Coffee and tea are provided. ��

    11

  • Summary of EventsDate Time Event Location

    MondayMay 21

    13:00 – 20:00 Registration Oakes Foyer

    18:00 – 21:00 Welcome Reception Oakes Foyer

    TuesdayMay 22

    07:00 – 08:15 Coffee/Tea Oakes Foyer

    08:15 – 08:30 Opening Ceremony Oakes South

    08:30 – 09:15 Plenary Lecture Oakes South

    09:20 – 10:10 Technical Program Various conference rooms

    10:10 – 10:30 Coffee Break & Industry Displays Oakes Foyer

    10:30 – 12:20 Technical Program Various conference rooms

    12:20 – 14:00 Lunch & Industry Displays Oakes Foyer

    14:00 – 14:45 Plenary Lecture Oakes South

    14:50 – 15:40 Technical Program Various conference rooms

    15:40 – 16:00 Coffee Break & Industry Displays Oakes Foyer

    16:00 – 17:40 Technical Program Various conference rooms

    WednesdayMay 23

    07:00 – 08:30 Coffee/Tea Oakes Foyer

    08:30 – 09:15 Plenary Lecture Oakes South

    09:20 – 10:10 Technical Program Various conference rooms

    10:10 – 10:30 Coffee Break & Industry Displays Oakes Foyer

    10:30 – 12:20 Technical Program Various conference rooms

    12:20 – 14:00 Lunch & Industry Displays Oakes Foyer

    14:00 – 14:45 Plenary Lecture Oakes South

    14:50 – 15:40 Technical Program Various conference rooms

    15:40 – 16:00 Coffee Break & Industry Displays Oakes Foyer

    16:00 – 17:40 Poster Session Oakes Foyer

    17:30 – 20:00 Niagara Tour & Winery Banquet

    ThursdayMay 24

    07:00 – 08:20 Coffee/Tea Oakes Foyer

    08:20 – 08:30 Poster Competition Award Ceremony Oakes South

    08:30 – 09:15 Plenary Lecture Oakes South

    09:20 – 10:10 Technical Program Various conference rooms

    10:10 – 10:30 Coffee Break & Industry Displays Oakes Foyer

    10:30 – 12:20 Technical Program Various conference rooms

    12:20 – 14:00 Lunch & Industry Displays Oakes Foyer

    ��

  • ThursdayMay 24

    14:00 – 14:45 Plenary Lecture Oakes South

    14:50 – 15:40 Technical Program Various conference rooms

    15:40 – 16:00 Coffee Break & Industry Displays Oakes Foyer

    16:00 – 17:20 Technical Program Various conference rooms

    17:20 – 18:00 Closing Ceremony Oakes South

    ��

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    G03

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  • PPS Americas Conference 2012 Map

    Venue: Marriott Gateway on the Falls

    Mezzanine Room 1: Oakes Foyer (Registration�& Posters) Room 2: Oakes North West Room 3: Oakes North East Room 4: Oakes South

    Third Floor Level Room 5: Ontario Room 6: Niagara

    1

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  • Plen

    ary

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    ures

    Spea

    ker

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    ��

  • Key

    note

    Lec

    ture

    s

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    day,

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    hors

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    G01

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    urea

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    un, D

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  • 09:5

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  • 11:2

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    of

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    sity

    Pol

    yeth

    ylen

    e N

    ucle

    ated

    by

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    on

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    otub

    es S

    tudi

    ed b

    y U

    ltra

    Fast

    DSC

    F.

    Tao

    , D. A

    uhl,

    L. B

    onna

    ud,

    P. D

    uboi

    s, C

    . Bai

    lly

    G13

    -12

    Rheo

    logy

    and

    Mec

    hani

    cal

    Prop

    ertie

    s of W

    ood

    Fibr

    e-

    Poly

    prop

    ylen

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    ompo

    site

    s us

    ing

    By-P

    ass

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    usio

    n Rh

    eom

    eter

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    Ngu

    yen,

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    utz

    G07

    -59

    Char

    acte

    ristic

    s of N

    eat a

    nd

    Use

    d M

    icro

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    Hollo

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    bran

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    r CO

    2 Ca

    ptur

    e in

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    bran

    e Co

    ntac

    tors

    S.

    M. S

    edgh

    i, D.

    Rod

    rigue

    , J.

    Bris

    son,

    M. I

    liuta

    G10

    -22

    Smal

    l and

    Wid

    e An

    gle

    X-ra

    y Sc

    atte

    ring

    on P

    oly(

    buty

    lene

    te

    reph

    thal

    ate)

    +

    Func

    tiona

    lized

    Car

    bon

    Nan

    otub

    es H

    ybrid

    s G

    . Bro

    za, L

    .A.S

    .A. P

    rado

    , Z.

    Rosl

    anie

    c, S

    .S. F

    unar

    i, K.

    Sc

    hulte

    11:4

    0 - 1

    2:00

    G01

    -6

    Woo

    d Fi

    ber B

    ioco

    mpo

    site

    s Ba

    sed

    on P

    olyl

    actic

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    d an

    d its

    Ble

    nds w

    ith

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    mop

    last

    ic S

    tarc

    h M

    . Mih

    ai, N

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    ros,

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    dar

    G05

    -56

    UHM

    WPE

    : The

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    e Lo

    ng C

    hain

    s for

    Mod

    ifyin

    g Fl

    ow-in

    duce

    d Cr

    ysta

    lliza

    tion

    Y. K

    awas

    him

    a, R

    . Zha

    ng, L

    . Ro

    ng, Y

    . Noz

    ue, N

    . Num

    ao,

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    agam

    atsu

    , Y.

    Shin

    ohar

    a, Y

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    emiy

    a, J.

    A.

    Korn

    field

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    -117

    Th

    e M

    elt L

    inea

    r and

    N

    onlin

    ear V

    isco

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    tic

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    vior

    of P

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    ary

    Blen

    ds w

    ith

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    asiz

    e on

    Cor

    e-sh

    ell

    Mor

    phol

    ogy

    Z. Ja

    vidi

    , H. N

    azoc

    kdas

    t

    G07

    -96

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    ysis

    on

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    ss-o

    ptic

    al

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    vior

    of C

    arbo

    n Di

    oxid

    e ba

    sed

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    lyca

    rbon

    ates

    H.

    Men

    ju, W

    . Tak

    arad

    a, T

    . Ki

    kuta

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    G10

    -127

    A

    Stud

    y on

    the

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    tric

    al

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    uctio

    n an

    d Pi

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    ne-C

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    n N

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    late

    let C

    ompo

    site

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    12:0

    0 - 1

    2:20

    G01

    -62

    Mor

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    ogy

    of P

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    lact

    ic

    acid

    )/Lo

    w D

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    nds

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    lali

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    is

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    -192

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    of i-

    PP in

    M

    id T

    erm

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    arin

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    . Ede

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    f Org

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    us T

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    -98

    An In

    vest

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    ion

    into

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    low

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    mal

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    ctio

    n M

    olde

    d M

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    led

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    on

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    e Fi

    lled

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    ocom

    posi

    tes

    M. M

    ahm

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    , G. S

    anto

    s, M

    . Ar

    jman

    d, U

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    dara

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    rk

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    4:00

    Lu

    nch

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    stry

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    play

    s in

    Oak

    es F

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    14:0

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    4:45

    Ro

    om: O

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    usa

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    posi

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  • 14:5

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    5:20

    G07

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    ates

    15:2

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    5:40

    G01

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    fect

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    of S

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    . Tan

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    rao

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    ends

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    ct o

    f Nan

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    onte

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    n th

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    d Pr

    oper

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    arz,

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    R. K

    akro

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    Co

    ffee

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    16:0

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    6:20

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    zono

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    ncia

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    Ap

    plic

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    n of

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    lyla

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    ends

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    eng,

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    euze

    y, P

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  • 16:4

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    7:00

    G01

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    Po

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    7:20

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