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WHMIS SDS Binder 2020

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PS-HTR-ST-43-E_Lead Acid Battery SDS US Version #: 05 Issue Date: 04/01/2015 Revision Date: 03/16/2017 1 of 11

Safety Data Sheet

1. IDENTIFICATION

Product Name: Lead Acid Battery Synonyms: SLI Battery

Product Use: Vehicle Electrical System Manufacturer/Supplier: Johnson Controls Battery Group Address: P.O. Box 590 Milwaukee, WI 53201 US

General Information Number: (800)-333-2222 ext. 3138 Contact Person: Industrial Hygiene & Safety Department

Emergency number: CHEMTREC: 800-424-9300

NOTE: The Johnson Controls sealed cell/battery is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). The information contained in this SDS is supplied at the customer’s request for information only.

2. HAZARD(S) IDENTIFICATION

Health Environmental Physical Acute Toxicity (Oral, dermal, inhalation)

Category 4 Aquatic Chronic 1 Aquatic Acute 1

Explosive Chemical, Division 1.3

Skin corrosion/irritation Category 1A

Eye Damage Category 1

Reproductive Category 1A

Carcinogenicity (lead) Category 1B

Carcinogenicity (acid mist) Category 1A

Specific target organ toxicity (repeated exposure)

Category 2

Label Elements:

Health Environmental Physical

Hazard Statements DANGER! Causes severe skin burns and eye damage. Causes serious eye damage. May damage fertility or the unborn child if ingested or inhaled. May cause cancer if ingested or inhaled. Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure.

Precautionary Statements Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing, eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Causes skin irritation, serious eye damage. Contact with internal components may cause irritation or severe burns. Avoid contact with internal acid. Irritating to eyes, respiratory system, and skin.


May form explosive air/gas mixture during charging. Extremely flammable gas (hydrogen). Explosive, fire, blast or projection hazard.

3. COMPOSITION / INFORMATION ON INGREDIENTS

INGREDIENTS (Chemical/Common Names): CAS No.: % by Wt: Lead 7439-92-1 34 Lead Oxide 1309-60-0 31 Sulfuric Acid 7664-93-9 34 Lead Sulfate 7446-14-2


6: ACCIDENTAL RELEASE MEASURES

Protective Measures to be Taken if Material is Released or Spilled

Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge of un-neutralized acid to sewer. Acid must be managed in accordance with approved local, state, and federal requirements. Consult state environmental agency and/or federal EPA.

Waste Disposal Method

Dispose of as a hazardous waste. Dispose of in accordance with applicable local, state and federal regulations.

7. HANDLING AND STORAGE

Handling Unless involved in recycling operations, do not breach the casing or empty the contents of the battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage and short circuits. Keep away from combustible materials, organic chemicals, reducing substances, metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping.

Storage Store batteries under roof in cool, dry, well-ventilated areas separated from incompatible materials and from activities that may create flames, spark, or heat. Store on smooth, impervious surfaces provided with measures for liquid containment in the event of electrolyte spills. Keep away from metallic objects that could bridge the terminals on a battery and create a dangerous short-circuit. Room ventilation is required for batteries utilized for standby power generation. Never recharge batteries in an unventilated, enclosed space.

Charging: There is a possible risk of electric shock from charging equipment and from strings of series connected batteries, whether or not being charged. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Batteries being charged will generate and release flammable hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking and avoid creation of flames and sparks nearby. Wear face and eye protection when near batteries being charged.

Other Follow Manufacturers Recommendations regarding maximum recommended currents and operating temperature range. Do not overcharge beyond the recommended upper charging voltage limit. Applying pressure or deforming the battery may lead to disassembly followed by eye, skin and throat irritation.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits

US OSHA Specifically Regulated Substances (29 CFR 1910.1001 – 1050) Ingredient CAS Number Type Value

Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Lead Sulfate 7446-14-2 TWA 0.05 mg/m³

US OSHA Table Z-1 Limits for Air Contaminants ( 29CFR 1910.1000)

Ingredient CAS Number Type Value Sulfuric Acid 7664-93-9 PEL 1 mg/m³

US ACGIH Threshold Limit Values

Ingredient CAS Number Type Value Form Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Lead Sulfate 7446-14-2 TWA 0.05 mg/m³ Sulfuric Acid 7664-93-9 TWA 0.2 mg/m³ Thoracic Fractions


US NIOSH: Pocket Guide to Chemical Hazards

Ingredient CAS Number Type Value Lead 7439-92-1 TWA 0.05 mg/m³ Lead Oxide 1309-60-0 TWA 0.05 mg/m³ Sulfuric Acid 7664-93-9 TWA 1 mg/m³

International Exposure Limits (mg/m3) *Chemical & Common Name Quebec PEV Ontario OEL EU OEL Lead and Lead Compounds (inorganic) 0.05 0.05 0.15 (a) Electrolyte (H2SO4/H2O) 1 0.2 0.05 (b)

(a) As inhalable aerosol (b) Thoracic fraction

Biological limit values ACGIH Biological Exposure Indices

Ingredient Value Determinant Specimen Sampling Time Lead 300 µg/l Lead Blood * Lead Oxide 300 µg/l Lead Blood * Lead Sulfate 300 µg/l Lead Blood *

* - For Sampling details please see the source document. Engineering Controls (Ventilation): Store and handle in well-ventilated area. If mechanical ventilation is used, components must be acid-resistant. Handle batteries cautiously, do not tip to avoid spills. Make certain vent caps are on securely. If battery case is damaged, avoid bodily contact with internal components. Wear protective clothing, eye and face protection, when filling, charging, or handling batteries. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Charge batteries in areas with adequate ventilation. General dilution ventilation is acceptable. Respiratory Protection (NIOSH/MSHA approved): NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection. Skin Protection: NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, clothing and boots. Eye Protection: NONE REQUIRED FOR NORMAL HANDLING OF THE FINISHED PRODUCT. If necessary to handle damage product where exposure to the organic electrolyte is a possibility, chemical splash goggles and a face shield are recommended. Other Protection: In areas where water and sulfuric acid solutions are handled in concentrations greater than 1%, emergency eyewash stations and showers should be provided, with unlimited water supply. Chemically impervious apron and face shield recommended when adding water or electrolyte to batteries. Wash Hands after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating, pungent odor.

Odor Threshold Not applicable. pH Not applicable Boiling Point Not applicable unless individual components exposed.


Battery Electrolyte (Acid) - 230 - 233.6 °F (110 - 112 °C) Lead - 3191 °F (1755 °C)

Melting Point Lead - 621.32 °F (327.4 °C) Specific Gravity (H2O = 1)

1.215 to 1.350

Flash Point 498.2 °F (259.0 °C) Hydrogen Evaporation Rate (Butyl Acetate = 1)

< 1

Vapor Pressure (mm Hg @ 20 ° C)

Battery Electrolyte (Acid) 11.7

Flammability Upper/lower flammability or explosive limits

Hydrogen Flammability Limit Lower- 4.1 %

Flammability Limit Upper – 74.2 %

Vapor Pressure Not applicable. Vapor Density 3.4 (Air = 1) Battery Electrolyte (Acid) Relative Density 1.21 - 1.3 Battery Electrolyte (Acid) Solubility Lead and Lead dioxide are not soluble.

100 % Battery Electrolyte (Acid). % Volatile by Weight Not applicable unless individual components exposed. Partition coefficient (n-octanol/water)

Not applicable

Auto-ignition temperature 1076 °F (580 °C) Hydrogen.

Decomposition temperature

Not applicable

Viscosity Not applicable 10. STABILITY AND REACTIVITY

Stability The sealed battery is considered stable. Conditions to Avoid Sparks and other sources of ignition; high temperature; over charging. Incompatibility (materials to avoid)

Electrolyte: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals, sulfur trioxide gas, strong oxidizers, and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. Lead compounds: Avoid contact with strong acids, bases, halides, halogenates, potassium nitrate, permanganate, peroxides, nascent hydrogen, and reducing agents. Arsenic compounds: strong oxidizers; bromine azide. NOTE: hydrogen gas can react with inorganic arsenic to form the highly toxic gas – arsine

Hazardous Decomposition Products

Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, hydrogen sulfide. Lead compounds: Temperatures above the melting point are likely to produce toxic metal fume, vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas.

Hazardous Polymerization Will not occur. 11. TOXICOLOGICAL INFORMATION

NOTE: Under normal conditions of use, this product does not present a health hazard. The following information is provided for organic electrolyte and lead exposure that may occur due to container breakage or under extreme conditions such as fire. Organic electrolyte – reacts with moisture/water to produce hydrofluoric acid in trace quantities. Hydrofluoric acid is extremely corrosive and toxic. In severe exposures it acts as a systemic poison and causes severe burns. The reaction may be delayed. Any contact with this material, even minor, requires immediate medical attention.


ROUTES AND METHODS OF ENTRY Inhalation EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation. Lead Compounds: Inhalation of lead dust or fumes may cause irritation of upper respiratory tract and lungs.

Skin Contact EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE. Sulfuric Acid: Severe irritation, burns and ulceration. Lead Compounds: Not absorbed through the skin.

Skin Absorption EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

In the event of overcharging or damage to the unit, exposure to organic electrolyte solution/mist is possible. Extreme exposures to the organic electrolyte can be absorbed through the skin.

Eye Contact EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Severe irritation, burns, cornea damage, and blindness. Lead Compounds: May cause eye irritation.

Ingestion EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: May cause severe irritation of mouth, throat, esophagus and stomach. Lead Compounds: Acute ingestion may cause abdominal pain, nausea, vomiting, diarrhea and severe cramping. This may lead rapidly to systemic toxicity and must be treated by a physician.

SIGNS AND SYMPTONS OF OVEREXPOSURE Acute Effects EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Severe skin irritation, damage to cornea, upper respiratory irritation. Lead Compounds: Symptoms of toxicity include headache, fatigue, abdominal pain, loss of appetite, muscular aches and weakness, sleep disturbances and irritability

Chronic Effects EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.

Sulfuric Acid: Possible erosion of tooth enamel, inflammation of nose, throat & bronchial tubes. Lead Compounds: Anemia; neuropathy, particularly of the motor nerves, with wrist drop; kidney damage; reproductive changes in males and females. Repeated exposure to lead and lead compounds in the workplace may result in nervous system toxicity. Some toxicologists report abnormal conduction velocities in persons with blood lead levels of 50 μg/100 ml or higher. Heavy lead exposure may result in central nervous system damage, encephalopathy and damage to the blood-forming (hematopoietic) tissues.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of sulfuric acid with skin may aggravate diseases such as eczema and contact dermatitis. Lead and its compounds can aggravate some forms of kidney, liver and neurologic diseases.

ADDITIONAL HEALTH DATA All heavy metals, including the hazardous ingredients in this product, are taken into the body primarily by inhalation and ingestion. Most inhalation problems can be avoided by adequate precautions such as ventilation and respiratory protection covered in Section 8. Follow good personal hygiene to avoid inhalation and ingestion: wash hands, face, neck and arms thoroughly before eating, smoking or leaving the work site. Keep contaminated clothing out of non-contaminated areas, or wear cover clothing when in such areas. Restrict the use and presence of food, tobacco and cosmetics to non-contaminated areas. Work clothes and work equipment used in contaminated areas must remain in designated areas and never taken home or laundered with personal non-contaminated clothing. This product is intended for industrial use only and should be isolated from children and their environment. The 19th Amendment to EC Directive 67/548/EEC classified lead compounds, but not lead in metal form, as possibly toxic to reproduction. Risk phrase 61: May cause harm to the unborn child, applies to lead compounds, especially soluble forms.

Toxicological Data Constituents Species Test Results


Sulfuric Acid (CAS 7664-93-9) Acute Oral LD50 Rat 2140 mg/kg

CARCINOGENICITY

Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mist containing sulfuric acid" as a Category I carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of sulfuric acid or sulfuric acid solutions contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under normal use of this product. Misuse of the product, such as overcharging, may result in the generation of sulfuric acid mist. Lead Compounds: Lead is listed as a Group 2A- carcinogen, likely in animals at extreme doses. Per the guidance found in OSHA 29 CFR 1910.1200 Appendix F, this is approximately equivalent to GHS Category 1A. Proof of carcinogenicity in humans is lacking at present. IARC Monographs. Overall Evaluation of Carcinogenicity Lead (CAS 7439-92-1) Lead oxide (CAS 1309-60-0) Lead sulfate (CAS 7446-14-2)

2A Probably carcinogenic to humans. 2A Probably carcinogenic to humans. 2A Probably carcinogenic to humans.

NTP Report on Carcinogens Lead oxide (CAS 1309-60-0) Lead sulfate (CAS 7446-14-2)

Reasonably Anticipated to be a Human Carcinogen. Reasonably Anticipated to be a Human Carcinogen.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed.

Reproductive toxicity May damage fertility or the unborn child. Specific target organ toxicity - single exposure

No data available.

Specific target organ toxicity - repeated exposure

Lead: May cause damage to organs (blood, central nervous system) through prolonged or repeated exposure.

Aspiration hazard Not classified. 12. ECOLOGICAL INFORMATION

Environmental Fate Lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most studies include lead compounds and not elemental lead

Environmental toxicity Aquatic Toxicity: Sulfuric Acid 24-hr LC50, freshwater fish (Brachydanio rerio): 82 mg/L

96 hr- LOEC, freshwater fish (Cyprinus carpio): 22 mg/L Lead 48 hr LC50 (modeled for aquatic invertebrates):


Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION

Note: Transportation requirements do not apply once the battery pack has been installed in a vehicle as part of the vehicle’s functional components. United States DOT: DOT rules specified in 49 CFR 173.159 regulate the transport of wet spillable batteries. 49 CFR 173.159 (e) specifies that when transported by highway or rail, electric storage batteries containing electrolyte or corrosive battery fluid are not subject to any other requirements of this subchapter, if all of the following are met: (1) No other hazardous materials may be transported in the same vehicle; (2) The batteries must be loaded or braced so as to prevent damage and short circuits in transit; (3) Any other material loaded in the same vehicle must be blocked, braced, or otherwise secured to prevent contact with or damage to the batteries; and (4) The transport vehicle may not carry material shipped by any person other than the shipper of the batteries. If any of these requirements are not met, the batteries must be shipped as hazardous materials GROUND – US-DOT/CAN-TDG/EU-ADR/APEC-ADR: Proper Shipping name Batteries, Wet, Filled with Acid UN number UN2794 Hazard classification 8 Packing group N/A Labels Corrosive AIRCRAFT – ICAO-IATA: Proper Shipping name Batteries, Wet, Filled with Acid Packing group None Hazardous class 8 Label/Placard Required Corrosive UN Identification UN2794 Environmental Hazards No ERG Code 8L Reference IATA packing instructions 870 (IATA DRG Edition 54) VESSEL – IMO-IMDG: Proper Shipping name Batteries, Wet, Filled with Acid Packing group N/A Hazardous class 8 Label/Placard Required Corrosive UN Identification UN2794 Environmental Hazards No EmS F-A, S-B Reference IMDG packing instructions P801

15. REGULATORY INFORMATION

This product is an article pursuant to 29 CFR 1910.1200 and as such is not subjected to the OSHA Hazard Communication Standard. TSCA TSCA Section 8b – Inventory Status: Inventory Status: All chemicals comprising this product are either exempt or listed on the TSCA Inventory. TSCA Section 12b (40 CFR Part 707.60(b)) No notice of export will be required for articles, except PCB articles, unless the Agency so requires in the context of

individual section 5, 6, or 7 actions.


TSCA Section 13 (40 CFR Part 707.20) No import certification required (EPA 305-B-99-001, June 1999, Introduction to the Chemical Import Requirements

of the Toxic Substances Control Act, Section IV.A) OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Lead (CAS 7439-92-1) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity Lead Oxide (CAS 1309-60-0) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity Lead Sulfate (CAS 7446-14-2) Reproductive toxicity Central nervous system Kidney Blood Acute toxicity EPA SARA Title III Section 302 EPCRA Extremely Hazardous Substances (EHS): Sulfuric acid is a listed "Extremely Hazardous Substance" under EPCRA, with a Threshold Planning Quantity (TPQ) of

1,000 lbs. EPCRA Section 302 notification is required if 500 lbs. or more of sulfuric acid is present at one site (40 CFR 370.10). For more information consult 40 CFR Part 355.

Section 304 CERCLA Hazardous Substances: Reportable Quantity (RQ) for spilled 100% sulfuric acid under CERCLA (Superfund) and EPCRA (Emergency Planning

and Community Right to Know Act) is 1,000 lbs. State and local reportable quantities for spilled sulfuric acid may vary.

Section 311/312 Hazard Categorization: EPCRA Section 312 Tier Two reporting is required for non-automotive batteries if sulfuric acid is present in

quantities of 500 lbs. or more and/or if lead is present in quantities of 10,000 lbs. or more. For more information consult 40 CFR 370.10 and 40 CFR 370.40

Section 313 EPCRA Toxic Substances: 40 cfr section 372.38 (b) states: If a toxic chemical is present in an article at a covered facility, a person is not

required to consider the quantity of the toxic chemical present in such article when determining whether an applicable threshold has been met under § 372.25, § 372.27, or § 372.28 or determining the amount of release to be reported under § 372.30. This exemption applies whether the person received the article from another person or the person produced the article. However, this exemption applies only to the quantity of the toxic chemical present in the article.

Supplier Notification: This product contains toxic chemicals that may be reportable under EPCRA Section 313 Toxic Chemical Release

Inventory (Form R) requirements. For a manufacturing facility under SIC codes 20 through 39, the following information is provided to enable you to complete the required reports:

RCRA Spent Lead Acid Batteries are subject to streamlined handling requirements when managed in compliance with 40

CFR section 266.80 or 40 CFR part 273. Waste sulfuric acid is a characteristic hazardous waste; EPA hazardous waste number D002 (corrosivity) and D008 (lead).

Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Lead Sulfate (CAS 7446-14-2) Safe Drinking Water Act (SDWA)


Not regulated Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Sulfuric acid (CAS 7664-93-9) 6552 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Sulfuric acid (CAS 7664-93-9) 20 % WV DEA Exempt Chemical Mixtures Code Number Sulfuric acid (CAS 7664-93-9 6552 US State Regulations US. Massachusetts RTK – Substance List Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) US New Jersey Worker and Community Right-to-know Act Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) US Pennsylvania Worker and Community Right-to-know Law Lead ( CAS 7439-92-1) Sulfuric acid (CAS 7664-93-9) US Rhode Island RTK Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) US. California Proposition 65 WARNING: This product contains chemicals known to the State of California to cause cancer. Battery posts, terminals and related accessories contain lead and lead compounds, chemicals known to the state of

California to cause cancer and reproductive harm. Wash hands after handling. *Battery companies not party to the 1999 consent judgment with Mateel Environmental Justice Foundation should include a Proposition 65 Warning that complies with the current version of Proposition 65.

US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Lead ( CAS 7439-92-1) Lead Oxide (CAS 1309-60-0) Lead Sulfate (CAS 7446-14-2) Sulfuric acid (CAS 7664-93-9) International Inventories Country(s) or Region Inventory Name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA)

Inventory Yes

* A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s). A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). CANADIAN ENVIRONMENTAL PROTECTION ACT: These products are manufactured articles and are exempt from regulation.

CANADIAN WHMIS CLASSIFICATION: This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

16. OTHER INFORMATION

Issue Date: 04/01/2015 Further information: NFPA Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3=Serious 4 = Severe


NFPA ratings

Disclaimer Johnson Controls Battery Group, Inc. cannot anticipate all conditions under which this information

and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

/5Safety Data Sheet

acc. to OSHA HCSPrinting date 09/25/2014 Revised On 09/25/2014

39.4.1

1 Identification of the substance and manufacturerTrade name: LIGHT GRAY PRIMERProduct code: 98764Product category PC9a Paints and coatings.Manufacturer/Supplier: Lawson Products, Inc.

8770 W. Bryn Mawr AvenueChicago, IL 60631USAphone: 773-304-5050

Emergency telephone number: 888-426-4851

2 Hazard(s) identificationClassification of the substance or mixtureFlam. Aerosol 1 H222 Extremely flammable aerosol.Press. Gas H280 Contains gas under pressure; may explode if heated.Carc. 2 H351 Suspected of causing cancer.Repr. 2 H361 Suspected of damaging fertility or the unborn child.Skin Irrit. 2 H315 Causes skin irritation.Eye Irrit. 2A H319 Causes serious eye irritation.STOT SE 3 H336 May cause drowsiness or dizziness.GHS Hazard pictograms

GHS02 GHS04 GHS07 GHS08Signal word DangerHazard statements Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.Causes skin irritation.Causes serious eye irritation.Suspected of causing cancer.Suspected of damaging fertility or the unborn child.May cause drowsiness or dizziness.

Precautionary statements If medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Obtain special instructions before use.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Do not spray on an open flame or other ignition source.Pressurized container: Do not pierce or burn, even after use.Wash hands thoroughly after handling.Use only outdoors or in a well-ventilated area.Do not handle until all safety precautions have been read and understood.Wear protective gloves/protective clothing/eye protection/face protection.Avoid breathing dust/fume/gas/mist/vapours/spray.Use personal protective equipment as required.IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing.If skin irritation occurs: Get medical advice/attention.IF ON SKIN: Wash with plenty of water.Take off contaminated clothing and wash before reuse.IF exposed or concerned: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.Specific treatment (see on this label).Store locked up.Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.Store in a well-ventilated place. Keep container tightly closed.Dispose of contents/container in accordance with local/regional/national/international regulations.

3 Composition/information on ingredientsChemical Description: This product is a mixture of the substances listed below with nonhazardous additions.Dangerous components:

67-64-1 Acetone 23.24%74-98-6 propane 12.6%

13463-67-7 titanium dioxide 7.43%106-97-8 n-butane 7.4%108-88-3 Toluene 6.08%

64742-89-8 VM&P Naphtha 5.62%14807-96-6 Talc 4.3%

1330-20-7 xylene (mix) 3.96%64-17-5 ethyl alcohol 3.81%

(Contd. on page 2) US4

/5Safety Data Sheet


Trade name: LIGHT GRAY PRIMER

(Contd. of page 1)

39.4.1

64742-47-8 Mineral Spirits 3.0%123-86-4 n-butyl acetate 2.67%110-19-0 isobutyl acetate 1.52%108-65-6 PM acetate 1.31%

4 First-aid measuresAfter inhalation: Supply fresh air; consult doctor in case of complaints.After skin contact: Remove contaminated clothing. Wash exposed area with soap and water.After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.After swallowing: Rinse out mouth and then drink plenty of water.

Rinse mouth with water. Do not induce vomiting.Most important symptoms andeffects: DizzinessIndication of any immediate medicalattention needed: No further relevant information available.

5 Fire-fighting measuresExtinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray.Special hazards: Can form explosive gas-air mixtures.Protective equipment forfirefighters: A respiratory protective device may be necessary.

6 Accidental release measuresPersonal precautions, protectiveequipment and emergencyprocedures: Use respiratory protective device against the effects of fumes/dust/aerosol.Methods and material forcontainment and cleaning up: Dispose contaminated material as waste according to section 13.

7 Handling and storagePrecautions for safe handling Use only in well ventilated areas.Storage requirements: Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing conditions.

Store locked up.

8 Exposure controls/personal protectionComponents with limit values that require monitoring at the workplace:67-64-1 AcetonePEL (USA) Long-term value: 2400 mg/m³, 1000 ppmREL (USA) Long-term value: 590 mg/m³, 250 ppmTLV (USA) Short-term value: (1782) NIC-1187 mg/m³, (750) NIC-500 ppm

Long-term value: (1188) NIC-594 mg/m³, (500) NIC-250 ppmBEI

74-98-6 propanePEL (USA) Long-term value: 1800 mg/m³, 1000 ppmREL (USA) Long-term value: 1800 mg/m³, 1000 ppmTLV (USA) refer to Appendix F106-97-8 n-butaneREL (USA) Long-term value: 1900 mg/m³, 800 ppmTLV (USA) Short-term value: 2370 mg/m³, 1000 ppm108-88-3 ToluenePEL (USA) Long-term value: 200 ppm

Ceiling limit value: 300; 500* ppm*10-min peak per 8-hr shift

REL (USA) Short-term value: 560 mg/m³, 150 ppmLong-term value: 375 mg/m³, 100 ppm

TLV (USA) Long-term value: 75 mg/m³, 20 ppmBEI

1330-20-7 xylene (mix)PEL (USA) Long-term value: 435 mg/m³, 100 ppmREL (USA) Short-term value: 655 mg/m³, 150 ppm

Long-term value: 435 mg/m³, 100 ppmTLV (USA) Short-term value: 651 mg/m³, 150 ppm

Long-term value: 434 mg/m³, 100 ppmBEI


/5Safety Data Sheet



(Contd. of page 2)

39.4.1

64-17-5 ethyl alcoholPEL (USA) Long-term value: 1900 mg/m³, 1000 ppmREL (USA) Long-term value: 1900 mg/m³, 1000 ppmTLV (USA) Short-term value: 1880 mg/m³, 1000 ppm123-86-4 n-butyl acetatePEL (USA) Long-term value: 710 mg/m³, 150 ppmREL (USA) Short-term value: 950 mg/m³, 200 ppm

Long-term value: 710 mg/m³, 150 ppmTLV (USA) Short-term value: 950 mg/m³, 200 ppm

Long-term value: 713 mg/m³, 150 ppm110-19-0 isobutyl acetatePEL (USA) Long-term value: 700 mg/m³, 150 ppmREL (USA) Long-term value: 700 mg/m³, 150 ppmTLV (USA) Long-term value: 713 mg/m³, 150 ppm108-65-6 PM acetateWEEL (USA) Long-term value: 50 ppmIngredients with biological limit values:67-64-1 AcetoneBEI (USA) 50 mg/L

Medium: urineTime: end of shiftParameter: Acetone (nonspecific)

108-88-3 TolueneBEI (USA) 0.02 mg/L

Medium: bloodTime: prior to last shift of workweekParameter: Toluene

0.03 mg/LMedium: urineTime: end of shiftParameter: Toluene

0.3 mg/g creatinineMedium: urineTime: end of shiftParameter: o-Cresol with hydrolysis (background)

1330-20-7 xylene (mix)BEI (USA) 1.5 g/g creatinine

Medium: urineTime: end of shiftParameter: Methylhippuric acids

Hygienic protection: Immediately remove all soiled and contaminated clothing.Wash hands after use.Avoid contact with the eyes and skin.Do not eat or drink while working.

Breathing equipment: A respirator is generally not necessary when using this product outdoors or in large open areas. Incases where short and/or long term overexposure exists, a charcoal filter respirator should be worn.If you suspect overexposure conditions exist, please consult an authority on chemical hygeine.

Hand protection: Protective gloves. The glove material must be impermeable and resistant to the substance.Eye protection: Tightly sealed goggles

9 Physical and chemical propertiesAppearance: Aerosol.Odor: AromaticOdor threshold: Not determined.pH-value: Not determined.Melting point/Melting range Undetermined.Boiling point: -44 °C (-47 °F)Flash point: -19 °C (-2 °F)Flammability (solid, gas): Extremely flammable.Decomposition temperature: Not determined.Auto igniting: Product is not self-igniting.Danger of explosion: In use, may form flammable/explosive vapour-air mixture.Lower Explosion Limit: 1.7 Vol %Upper Explosion Limit: 10.9 Vol %Vapor pressure: Not determined.


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39.4.1

Relative Density: Between 0.77 and 0.85 (Water equals 1.00)Vapour density Not determined.Evaporation rate Not applicable.Partition coefficient: n-octonal/water: Not determined.Solubility: Not determined.Viscosity: Not determined.VOC content: 568.7 g/l / 4.75 lb/glVOC content (less exempt solvents): 50.7 %MIR Value: 1.10Solids content: 25.5 %

10 Stability and reactivityReactivity: Stable at normal temperatures.Conditions to avoid: Do not allow can to exceed 120 degrees Fahrenheit. Do not warehouse in subfreezing

temperatures.Chemical stability: Not fully evaluated.Possibility of hazardous reactions: No dangerous reactions known.Incompatible materials: No further relevant information available.Hazardous decomposition: No dangerous decomposition products known.

11 Toxicological informationLD/LC50 values that are relevant for classification:13463-67-7 titanium dioxideOral LD50 >20000 mg/kg (rat)Dermal LD50 >10000 mg/kg (rbt)Inhalative LC50/4 h >6.82 mg/l (rat)106-97-8 n-butaneInhalative LC50/4 h 658 mg/l (rat)1330-20-7 xylene (mix)Oral LD50 8700 mg/kg (rat)Dermal LD50 2000 mg/kg (rbt)Inhalative LC50/4 h 6350 mg/l (rat)64-17-5 ethyl alcoholOral LD50 7060 mg/kg (rat)Inhalative LC50/4 h 20000 mg/l (rat)123-86-4 n-butyl acetateOral LD50 14000 mg/kg (rat)Inhalative LC50/4 h >21.0 mg/l (rat)110-19-0 isobutyl acetateOral LD50 4763 mg/kg (rbt)108-65-6 PM acetateOral LD50 8500 mg/kg (rat)Inhalative LC50/4 h 35.7 mg/l (rat)Information on toxicological effects: No data available.Sensitization: No sensitizing effects known.Carcinogenic categoriesIARC (International Agency for Research on Cancer)13463-67-7 titanium dioxide 2B

108-88-3 Toluene 3 14807-96-6 Talc 2B

1330-20-7 xylene (mix) 3 64-17-5 ethyl alcohol 1

NTP (National Toxicology Program)None of the ingredients is listed.OSHA-Ca (Occupational Safety & Health Administration)None of the ingredients is listed.

12 Ecological informationAquatic toxicity: Hazardous for water, do not empty into drains.Persistence and degradability: The product is degradable after prolonged exposure to natural weathering processes.Bioaccumulative potential: No further relevant information available.Mobility in soil: No further relevant information available.


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39.4.1

Other adverse effects: No further relevant information available.

13 Disposal considerationsDispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or compact. Partially empty cans must bedisposed of responsibly. Do not heat or cut empty containers with electric or gas torches.Recommendation: Completely empty cans should be recycled.

14 Transport informationUN-Number UN1950DOT Aerosols, flammableADR 1950 AerosolsTransport hazard class(es):Class 2.1Marine pollutant: NoSpecial precautions for user: Warning: GasesEMS Number: F-D,S-UPackaging Group: --UN "Model Regulation": UN1950, Aerosols, 2.1

15 Regulatory informationSARA Section 355 (extremely hazardous substances):None of the ingredients in this product are listed.SARA Section 313 (Specific toxic chemical listings):

108-88-3 Toluene1330-20-7 xylene (mix)CPSC: This product complies with 16 CFR 1303 and does not contain more than 90 ppm of lead.California Proposition 65 chemicals known to cause cancer:13463-67-7 titanium dioxide

100-41-4 ethyl benzene1333-86-4 Carbon black

108-10-1 methyl isobutyl ketoneCalifornia Proposition 65 chemicalsknown to cause developmentaltoxicity: 108-88-3 Toluene

67-56-1 MethanolEPA:

67-64-1 Acetone I 108-88-3 Toluene II

1330-20-7 xylene (mix) I 110-19-0 isobutyl acetate D

16 Other informationContact: Regulatory Affairs

US4

SAFETY DATA SHEET LIQUID ELECTRICAL TAPE, 113 g

Version 4.1

Revision Date: 11/11/2019

SDS Number: 869937-00003

Date of last issue: 02/26/2019 Date of first issue: 09/06/2016

1 / 34

SECTION 1. IDENTIFICATION

Product name

: LIQUID ELECTRICAL TAPE, 113 g

Product code

: 893.198010

Other means of identification

: No data available

Manufacturer or supplier's details Company name of supplier

: Würth Canada Limited

Address

: 345 Hanlon Creek Blvd GUELPH, ON N1C 0A1

Telephone

: +1 (905) 564 6225

Telefax

: +1 (905) 564 3671

Emergency telephone

: CANUTEC (24/7): +1 (613) 996-6666 or/ou *666 (cellu-lar/cellulaire)

E-mail address : [email protected]

Recommended use of the chemical and restrictions on use Recommended use

: Insulation for wire and/or cables Coatings

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations Flammable liquids

: Category 2

Skin irritation

: Category 2

Eye irritation

: Category 2A

Carcinogenicity

: Category 2

Reproductive toxicity

: Category 2

Specific target organ toxicity - single exposure

: Category 3

Specific target organ toxicity - repeated exposure

: Category 2 (Auditory system)

Aspiration hazard

: Category 1

GHS label elements


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Hazard pictograms

:

Signal Word

: Danger

Hazard Statements

: H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361f Suspected of damaging fertility. H373 May cause damage to organs (Auditory system) through prolonged or repeated exposure.

Precautionary Statements

: Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equip-ment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ atten-tion. P337 + P313 If eye irritation persists: Get medical advice/ atten-tion.


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P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal: P501 Dispose of contents/ container to an approved waste dis-posal plant.

Other hazards Vapors may form explosive mixture with air.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture

: Mixture

Components Chemical name CAS-No. Concentration (% w/w) Distillates (petroleum), light distillate hydrotreating process, low-boiling

68410-97-9 >= 30 - < 60

Xylene 1330-20-7 >= 10 - < 30 Butanone 78-93-3 >= 5 - < 10 Limestone 1317-65-3 >= 5 - < 10 Heptane 142-82-5 >= 1 - < 5 Ethylbenzene 100-41-4 >= 1 - < 5 Silicon, amorphous 112945-52-5 >= 1 - < 5 Cumene 98-82-8 >= 0.1 - < 1 n-Octane 111-65-9 >= 1 - < 5 Actual concentration or concentration range is withheld as a trade secret

SECTION 4. FIRST AID MEASURES

General advice

: In the case of accident or if you feel unwell, seek medical ad-vice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled

: If inhaled, remove to fresh air. Get medical attention.

In case of skin contact

: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

In case of eye contact

: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.


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If easy to do, remove contact lens, if worn. Get medical attention.

If swallowed

: If swallowed, DO NOT induce vomiting. If vomiting occurs have person lean forward. Call a physician or poison control center immediately. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

: May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure.

Protection of first-aiders

: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists (see section 8).

Notes to physician

: Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media

: High volume water jet

Specific hazards during fire fighting

: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.

Hazardous combustion prod-ucts

: Carbon oxides Metal oxides

Specific extinguishing meth-ods

: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

Special protective equipment for fire-fighters

: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.


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SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec-tive equipment and emer-gency procedures

: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions

: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g., by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate contain-ment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor-bent. Local or national regulations may apply to releases and dispo-sal of this material, as well as those materials and items em-ployed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures

: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Ground and bond container and receiving equipment.

Local/Total ventilation

: If advised by assessment of the local exposure potential, use only in an area equipped with explosion-proof exhaust ventila-tion.

Advice on safe handling

: Do not get on skin or clothing. Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure as-sessment Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.


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Conditions for safe storage

: Keep in properly labeled containers. Store locked up. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.

Materials to avoid

: Do not store with the following product types: Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters Components CAS-No. Value type

(Form of exposure)

Control parame-ters / Permissible concentration

Basis

Xylene 1330-20-7 STEL 150 ppm 651 mg/m³

CA AB OEL

TWA 100 ppm 434 mg/m³

CA AB OEL

TWAEV 100 ppm 434 mg/m³

CA QC OEL

STEV 150 ppm 651 mg/m³

CA QC OEL

TWA 100 ppm CA BC OEL STEL 150 ppm CA BC OEL TWA 100 ppm ACGIH STEL 150 ppm ACGIH Butanone 78-93-3 TWA 200 ppm

590 mg/m³ CA AB OEL

STEL 300 ppm 885 mg/m³

CA AB OEL

TWA 50 ppm CA BC OEL STEL 100 ppm CA BC OEL TWAEV 50 ppm

150 mg/m³ CA QC OEL


CA QC OEL

TWA 200 ppm ACGIH STEL 300 ppm ACGIH Limestone 1317-65-3 TWA 10 mg/m³ CA AB OEL TWAEV (to- 10 mg/m³ CA QC OEL


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tal dust) TWA (Total

dust) 10 mg/m³ CA BC OEL

TWA (respir-able dust fraction)

3 mg/m³ CA BC OEL

STEL 20 mg/m³ CA BC OEL Heptane 142-82-5 TWA 400 ppm CA BC OEL STEL 500 ppm CA BC OEL TWAEV 400 ppm

1,640 mg/m³ CA QC OEL

STEV 500 ppm 2,050 mg/m³

CA QC OEL

TWA 400 ppm 1,640 mg/m³

CA AB OEL

STEL 500 ppm 2,050 mg/m³

CA AB OEL

TWA 400 ppm ACGIH STEL 500 ppm ACGIH Ethylbenzene 100-41-4 TWA 100 ppm


STEL 125 ppm 543 mg/m³

CA AB OEL

TWA 20 ppm CA BC OEL TWAEV 100 ppm



CA QC OEL

TWA 20 ppm ACGIH Silicon, amorphous 112945-52-5 TWAEV

(respirable dust)

6 mg/m³ CA QC OEL

TWA (Res-pirable)

1.5 mg/m³ CA BC OEL

TWA (Total) 4 mg/m³ CA BC OEL Cumene 98-82-8 TWA 50 ppm


TWA 25 ppm CA BC OEL STEL 75 ppm CA BC OEL TWAEV 50 ppm


TWA 50 ppm ACGIH n-Octane 111-65-9 TWAEV 300 ppm

1,400 mg/m³ CA QC OEL

STEV 375 ppm 1,750 mg/m³

CA QC OEL

TWA 300 ppm 1,400 mg/m³

CA AB OEL

TWA 300 ppm CA BC OEL TWA 300 ppm ACGIH


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Biological occupational exposure limits Components CAS-No. Control

parameters Biological specimen

Sam-pling time

Permissible concentra-tion

Basis

Xylene 1330-20-7 Methyl-hippuric acids

Urine End of shift (As soon as possible after exposure ceases)

1.5 g/g cre-atinine

ACGIH BEI

Butanone 78-93-3 methyl ethyl ketone


2 mg/l ACGIH BEI

Ethylbenzene 100-41-4 Sum of mandelic acid and phenyl gly-oxylic acid


0.15 g/g creatinine

ACGIH BEI

Engineering measures : Minimize workplace exposure concentrations. If advised by assessment of the local exposure potential, use only in an area equipped with explosion-proof exhaust venti-lation. Dust formation may be relevant in the processing of this pro-duct. In addition to substance-specific OELs, general limitati-ons of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Rele-vant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles.

Personal protective equipment Respiratory protection

: If adequate local exhaust ventilation is not available or expo-sure assessment demonstrates exposures outside the re-commended guidelines, use respiratory protection.

Filter type

: Combined particulates and organic vapor type

Hand protection Material : Neoprene

Material : Nitrile rubber

Material : Polyethylene


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Material : PVC

Material : Fluorinated rubber

Remarks

: Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. For special applications, we recommend clarifying the resistance to che-micals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Breakthrough time is not determined for the pro-duct. Change gloves often!

Eye protection

: Wear the following personal protective equipment: Safety goggles

Skin and body protection

: Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: If assessment demonstrates that there is a risk of explosive atmospheres or flash fires, use flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

Hygiene measures

: If exposure to chemical is likely during typical use, provide eye flushing systems and safety showers close to the wor-king place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

: liquid

Color

: black

Odor

: No data available

Odor Threshold

: No data available

pH

: No data available

Melting point/freezing point

: No data available

Initial boiling point and boiling range

: 79 - 141 °C

Flash point : -7 °C


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Evaporation rate

: No data available

Flammability (solid, gas)

: Not applicable

Flammability (liquids)

: Ignitable (see flash point)

Upper explosion limit / Upper flammability limit

: No data available

Lower explosion limit / Lower flammability limit

: No data available

Vapor pressure

: 78 mmHg (20 °C)

Relative vapor density

: > 1 (Air = 1.0)

Relative density

: 0.83

Solubility(ies) Water solubility

: insoluble

Partition coefficient: n-octanol/water

: Not applicable

Autoignition temperature

: No data available

Decomposition temperature

: No data available

Viscosity Viscosity, kinematic

: No data available

Explosive properties

: Not explosive

Oxidizing properties

: The substance or mixture is not classified as oxidizing.

Particle size

: Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity

: Not classified as a reactivity hazard.

Chemical stability

: Stable under normal conditions.

Possibility of hazardous reac-tions

: Highly flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents.

Conditions to avoid

: Heat, flames and sparks.

Incompatible materials : Oxidizing agents


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Hazardous decomposition products

: No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact

Acute toxicity Not classified based on available information.

Product: Acute oral toxicity

: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Acute inhalation toxicity

: Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapor Method: Calculation method

Acute dermal toxicity

: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg Remarks: Based on data from similar materials


: LC50 (Rat): > 5.61 mg/l Exposure time: 4 h Test atmosphere: vapor Remarks: Based on data from similar materials


: LD50 (Rabbit): > 2,000 mg/kg Remarks: Based on data from similar materials

Xylene: Acute oral toxicity

: LD50 (Rat): 3,523 mg/kg Method: Directive 67/548/EEC, Annex V, B.1.


: LC50 (Rat): 27.571 mg/l Exposure time: 4 h Test atmosphere: vapor


: LD50 (Rabbit): > 4,200 mg/kg

Butanone: Acute oral toxicity : LD50 (Rat): > 2,000 - 5,000 mg/kg


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Remarks: Based on data from similar materials


: LC50 (Rat): > 25.5 mg/l Exposure time: 4 h Test atmosphere: vapor Method: OECD Test Guideline 436 Remarks: Based on data from similar materials



Limestone: Acute oral toxicity

: LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 420 Assessment: The substance or mixture has no acute oral tox-icity Remarks: Based on data from similar materials


: LC50 (Rat): > 3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Based on data from similar materials


: LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials

Heptane: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials


: LC50 (Rat): > 73.5 mg/l Exposure time: 4 h Test atmosphere: vapor


: LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials

Ethylbenzene: Acute oral toxicity

: LD50 (Rat): 3,500 mg/kg


: LC50 (Rat): 17.8 mg/l Exposure time: 4 h Test atmosphere: vapor

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg


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Silicon, amorphous: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials


: LC50 (Rat): > 2.08 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Based on data from similar materials



Cumene: Acute oral toxicity

: LD50 (Rat): 2,700 mg/kg



n-Octane: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg Remarks: Based on data from similar materials


: LC50 (Rat): > 24.88 mg/l Exposure time: 4 h Test atmosphere: vapor Assessment: The substance or mixture has no acute inhala-tion toxicity



Skin corrosion/irritation Causes skin irritation.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Species : Rabbit Method : OECD Test Guideline 404 Result : Skin irritation Remarks : Based on data from similar materials

Xylene: Species : Rabbit Result : Skin irritation

Butanone: Assessment : Repeated exposure may cause skin dryness or cracking.


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Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Remarks : Based on data from similar materials

Limestone: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Remarks : Based on data from similar materials

Heptane: Species : Rabbit Result : Skin irritation Remarks : Based on data from similar materials

Silicon, amorphous: Species : Rabbit Method : OECD Test Guideline 404 Result : No skin irritation Remarks : Based on data from similar materials

Cumene: Species : Rabbit Result : No skin irritation

n-Octane: Species : Rabbit Result : Skin irritation Remarks : Based on data from similar materials

Serious eye damage/eye irritation Causes serious eye irritation.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Species : Rabbit Result : No eye irritation Remarks : Based on data from similar materials

Xylene: Species : Rabbit Result : Irritation to eyes, reversing within 21 days

Butanone: Species : Rabbit Result : Irritation to eyes, reversing within 21 days


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Method : OECD Test Guideline 405

Limestone: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405 Remarks : Based on data from similar materials

Heptane: Species : Rabbit Result : No eye irritation Remarks : Based on data from similar materials

Silicon, amorphous: Species : Rabbit Result : No eye irritation Method : OECD Test Guideline 405 Remarks : Based on data from similar materials

Cumene: Species : Rabbit Result : No eye irritation

n-Octane: Species : Rabbit Result : No eye irritation Remarks : Based on data from similar materials

Respiratory or skin sensitization

Skin sensitization Not classified based on available information.

Respiratory sensitization Not classified based on available information.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Test Type : Buehler Test Routes of exposure : Skin contact Species : Guinea pig Result : negative Remarks : Based on data from similar materials

Xylene: Test Type : Local lymph node assay (LLNA) Routes of exposure : Skin contact Species : Mouse Result : negative


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Butanone: Test Type : Buehler Test Routes of exposure : Skin contact Species : Guinea pig Method : OECD Test Guideline 406 Result : negative

Limestone: Test Type : Local lymph node assay (LLNA) Routes of exposure : Skin contact Species : Mouse Method : OECD Test Guideline 429 Result : negative Remarks : Based on data from similar materials

Heptane: Test Type : Maximization Test Routes of exposure : Skin contact Species : Guinea pig Result : negative

Cumene: Test Type : Maximization Test Routes of exposure : Skin contact Species : Guinea pig Result : negative

n-Octane: Test Type : Maximization Test Routes of exposure : Skin contact Species : Guinea pig Result : negative Remarks : Based on data from similar materials

Germ cell mutagenicity Not classified based on available information.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative Remarks: Based on data from similar materials

Genotoxicity in vivo

: Test Type: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials


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Germ cell mutagenicity - Assessment

: Classified based on benzene content < 0.1% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note P)

Xylene: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Test Type: Chromosome aberration test in vitro Result: negative

Test Type: In vitro mammalian cell gene mutation test Result: negative

Test Type: In vitro sister chromatid exchange assay in mam-malian cells Result: negative


: Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Skin contact Result: negative

Butanone: Genotoxicity in vitro


Test Type: In vitro mammalian cell gene mutation test Result: negative


Test Type: DNA damage and repair, unscheduled DNA syn-thesis in mammalian cells (in vitro) Result: negative

Test Type: Saccharomyces cerevisiae, gene mutation assay (in vitro) Result: negative


: Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative

Limestone: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials

Test Type: Chromosome aberration test in vitro


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Method: OECD Test Guideline 473 Result: negative Remarks: Based on data from similar materials

Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Remarks: Based on data from similar materials

Heptane: Genotoxicity in vitro


Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative Remarks: Based on data from similar materials



: Test Type: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials

Ethylbenzene: Genotoxicity in vitro


Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative



: Test Type: Unscheduled DNA synthesis (UDS) test with mammalian liver cells in vivo Species: Mouse Application Route: Inhalation Method: OECD Test Guideline 486 Result: negative

Silicon, amorphous: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials

Genotoxicity in vivo : Test Type: Mutagenicity (in vivo mammalian bone-marrow


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cytogenetic test, chromosomal analysis) Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials

Cumene: Genotoxicity in vitro

: Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 Result: negative


: Test Type: In vivo micronucleus test Species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative

n-Octane: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative Remarks: Based on data from similar materials

Test Type: Chromosome aberration test in vitro Result: negative Remarks: Based on data from similar materials

Test Type: In vitro mammalian cell gene mutation test Result: negative Remarks: Based on data from similar materials


: Test Type: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials

Carcinogenicity Suspected of causing cancer.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Species : Mouse Application Route : Skin contact Exposure time : 102 weeks Result : negative Remarks : Based on data from similar materials

Carcinogenicity - Assess-ment

: Classified based on benzene content < 0.1% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note P)


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Xylene: Species : Rat Application Route : Ingestion Exposure time : 103 weeks Result : negative

Heptane: Species : Rat Application Route : inhalation (vapor) Exposure time : 2 Years Result : negative Remarks : Based on data from similar materials

Ethylbenzene: Species : Rat Application Route : inhalation (vapor) Exposure time : 104 weeks Result : positive Remarks : The mechanism or mode of action may not be relevant in hu-

mans.

Silicon, amorphous: Species : Rat Application Route : Ingestion Exposure time : 103 weeks Result : negative Remarks : Based on data from similar materials

Cumene: Species : Rat Application Route : inhalation (gas) Exposure time : 105 weeks Result : negative

Carcinogenicity - Assess-ment

: Limited evidence of carcinogenicity in animal studies

n-Octane: Species : Rat Application Route : inhalation (vapor) Exposure time : 2 Years Result : negative Remarks : Based on data from similar materials

Reproductive toxicity Suspected of damaging fertility.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Effects on fertility : Test Type: Two-generation reproduction toxicity study


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Species: Rat Application Route: inhalation (vapor) Result: positive Remarks: Based on data from similar materials

Effects on fetal development

: Test Type: Embryo-fetal development Species: Rat Application Route: inhalation (vapor) Result: negative

Reproductive toxicity - As-sessment

: Some evidence of adverse effects on sexual function and fertility, based on animal experiments.

Xylene: Effects on fertility

: Test Type: One-generation reproduction toxicity study Species: Rat Application Route: inhalation (vapor) Result: negative


: Test Type: Embryo-fetal development Species: Rat Application Route: inhalation (vapor) Result: negative

Butanone: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials


: Test Type: Embryo-fetal development Species: Rat Application Route: Inhalation Method: OECD Test Guideline 414 Result: negative

Limestone: Effects on fertility

: Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Remarks: Based on data from similar materials


: Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat Application Route: Ingestion Method: OECD Test Guideline 422 Result: negative Remarks: Based on data from similar materials


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Heptane: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials


: Test Type: Embryo-fetal development Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials

Ethylbenzene: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: inhalation (vapor) Method: OECD Test Guideline 416 Result: negative


: Test Type: Embryo-fetal development Species: Rat Application Route: Inhalation Method: OECD Test Guideline 414 Result: negative

Silicon, amorphous: Effects on fetal development

: Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials

Cumene: Effects on fertility

: Species: Rat, male Application Route: inhalation (vapor) Result: negative


: Test Type: Embryo-fetal development Species: Rat Application Route: inhalation (vapor) Method: OECD Test Guideline 414 Result: negative

n-Octane: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials


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: Test Type: Embryo-fetal development Species: Rat Application Route: inhalation (vapor) Result: negative Remarks: Based on data from similar materials

STOT-single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Assessment : May cause drowsiness or dizziness.

Xylene: Assessment : May cause respiratory irritation.

Butanone: Assessment : May cause drowsiness or dizziness.

Heptane: Assessment : May cause drowsiness or dizziness.

Cumene: Assessment : May cause respiratory irritation.

n-Octane: Assessment : May cause drowsiness or dizziness.

STOT-repeated exposure May cause damage to organs (Auditory system) through prolonged or repeated exposure.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Assessment : No significant health effects observed in animals at concentra-

tions of 1 mg/l/6h/d or less.

Xylene: Routes of exposure : inhalation (vapor) Target Organs : Auditory system Assessment : Shown to produce significant health effects in animals at con-

centrations of >0.2 to 1 mg/l/6h/d.

Ethylbenzene: Routes of exposure : inhalation (vapor) Target Organs : Auditory system


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Assessment : Shown to produce significant health effects in animals at con-centrations of >0.2 to 1 mg/l/6h/d.

Repeated dose toxicity

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Species : Rat NOAEL : 0.98 mg/l Application Route : inhalation (vapor) Exposure time : 28 Days Remarks : Based on data from similar materials

Xylene: Species : Rat LOAEL : > 0.2 - 1 mg/l Application Route : inhalation (vapor) Exposure time : 13 Weeks Remarks : Based on data from similar materials

Species : Rat LOAEL : 150 mg/kg Application Route : Ingestion Exposure time : 90 Days

Butanone: Species : Rat NOAEL : 14.84 mg/l Application Route : inhalation (vapor) Exposure time : 90 Days Method : OECD Test Guideline 413

Limestone: Species : Rat NOAEL : > 300 mg/kg Application Route : Ingestion Exposure time : 28 Days Method : OECD Test Guideline 422 Remarks : Based on data from similar materials

Heptane: Species : Rat NOAEL : 12.35 mg/l Application Route : inhalation (vapor) Exposure time : 90 Days

Ethylbenzene: Species : Rat LOAEL : 0.868 mg/l Application Route : inhalation (vapor)


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Exposure time : 13 Weeks

Species : Rat NOAEL : 75 mg/kg LOAEL : 250 mg/kg Application Route : Ingestion Method : OECD Test Guideline 408

Silicon, amorphous: Species : Rat NOAEL : 1.3 mg/l Application Route : inhalation (dust/mist/fume) Exposure time : 13 Weeks Remarks : Based on data from similar materials

Cumene: Species : Rat NOAEL : 125 ppm LOAEL : 250 ppm Application Route : inhalation (vapor) Exposure time : 90 Days

n-Octane: Species : Rat NOAEL : 24.3 mg/l Application Route : inhalation (vapor) Exposure time : 90 Days Remarks : Based on data from similar materials

Aspiration toxicity May be fatal if swallowed and enters airways.

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

Xylene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

Butanone: The substance or mixture causes concern owing to the assumption that it causes a human aspi-ration toxicity hazard.

Heptane: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.


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Ethylbenzene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

Cumene: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

n-Octane: The substance or mixture is known to cause human aspiration toxicity hazards or has to be re-garded as if it causes a human aspiration toxicity hazard.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Distillates (petroleum), light distillate hydrotreating process, low-boiling: Toxicity to fish

: LL50 (Pimephales promelas (fathead minnow)): 8.2 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Remarks: Based on data from similar materials

Toxicity to daphnia and other aquatic invertebrates

: EL50 (Daphnia magna (Water flea)): 4.5 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 202 Remarks: Based on data from similar materials

Toxicity to algae/aquatic plants

: EL50 (Pseudokirchneriella subcapitata (green algae)): 3.1 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 201 Remarks: Based on data from similar materials

NOELR (Pseudokirchneriella subcapitata (green algae)): 0.5 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 201 Remarks: Based on data from similar materials

Toxicity to fish (Chronic tox-icity)

: NOELR (Pimephales promelas (fathead minnow)): 2.6 mg/l Exposure time: 14 d Test substance: Water Accommodated Fraction Method: OECD Test Guideline 204 Remarks: Based on data from similar materials

Toxicity to daphnia and other aquatic invertebrates (Chron-

: NOELR (Daphnia magna (Water flea)): 2.6 mg/l Exposure time: 21 d


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ic toxicity)

Test substance: Water Accommodated Fraction Method: OECD Test Guideline 211 Remarks: Based on data from similar materials

Xylene: Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 13.5 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 24 h Method: OECD Test Guideline 202 Remarks: Based on data from similar materials

Toxicity to algae/aquatic plants

: EC50 (Skeletonema costatum (marine diatom)): 10 mg/l Exposure time: 72 h

Toxicity to fish (Chronic tox-icity)

Documents

WHMIS SDS Binder Services - 2020 Part 2 of 2.pdf · Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear