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7/17/2019 WinProp Tutorial
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1
Building, Running and Analyzing
Different Types of Fluid Models
(Dry Gas, Wet Gas, Gas Condensate)(Volatile Oil, Black Oil, Heavy Oil)
Using
WinProp
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Exercise 1 (Required File: Five Fluid Types Data.xls)
Objective: Modelling of five fluid type i.e. Dry gas, wet gas, Gas condensate, volatile oiland Black oil.
. Double click on the WinProp icon in the Launcher and open the WinProp
interface.
. Double click on “Titles/EOS/Units” and write “Dry gas/Wet gas/Gas
condensate/Volatile oil/Black oil” in the comments and the Title1 section
depending on the case you are modelling. Select PR 1978 and the equation of state
to be used in characterizing the fluid model, select “Psia & deg F” as the units
and Feed as mole. Click “OK ”.
٣. Open “ component selection” form and insert the library components in the
following order: CO2 , N 2 , C 1 , C 2 , C 3 , IC 4 , NC 4 , IC 5 , NC 5 , and FC 6 . (The order
of selection in important!).
٤. In all cases except “Dry Gas” also, characterize the C 7 +
fraction with a single
pseudocomponent by inserting a user defined component. Click on “ options”
button in the “ component definition form” and select “insert own component”
based on specific gravity (SG), boiling point (TB) and molecular weight (MW).
Use the properties given in the file: “ Five Fluid Types Data.xls”. Your
component definition form should look like Figure1 for Dry gas and Figure 2 in
case of other fluid types.
Figure1: Component definition for case of Dry Gas
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٥. Open the "composition form" and input the mole fractions of the primary
composition as mentioned in the file: “Five Fluid Types Data.xls”. The
“secondary” corresponds to the injection fluid (if applicable).
٦. Insert “two phase flash calculation form" into the WinProp interface. Open this
form by double clicking on it and under the comments section type “Standard
condition flash” . We are planning to perform a flash at 14.7 Psia and 60 deg.F.
Leave other calculation options as default. The feed composition is subjected to
mixed i.e. primary and secondary composition. The “two-phase flash calculation
form should look like as shown in Figure 3.
٧. Insert “Saturation pressure calculation Form" into the WinProp Interface to
perform a saturation pressure calculation at the reservoir temperature.
٨. Double click and open the saturation pressure calculation form. Under thecomments type “ Psat at reservoir temperature”. Also, input the reservoir
temperature and saturation pressure estimate as 180 ºF and 1000 Psia respectively.
The input value of “saturation pressure estimate” is used as an initial guess by
WinProp during the iteration processes for calculating the actual saturation
pressure.
٩. We would also like to generate a pressure-temperature phase diagram. Insert a
“two-phase Envelope” form in the Main WinProp interface. Open the form by
double clicking on it and type in “P-T envelope” under the comments section.
Input the data as shown in Figure 4.
Figure 2: Component definition for other fluid types
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Figure 3: Two phase flash calculation at standard condition.
Figure 4: Input data for two-phase envelop calculation.
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٠. Create plots of phase properties vs. pressure at the reservoir temperature using
the 2-phase flash calculation. Examples of properties which may be plotted are:
Z-factors, phase fractions, densities, molecular weights, K-values, etc. This can be
done by adding another Two-phase Flash calculation from. Type in comments as
“Phase properties as function of pressure”. Input the reservoir temperature as
180 deg F, temperature step as 0 and No. of temperature step as 1. Input the
reservoir pressure as 250 Psia, pressure step of 250 Psia and No. of pressure steps
as 12 for dry and wet gas case whereas 24 for gas condensate, volatile oil and
black oil. The reservoir temperature would also change depending on the case
you are modelling as mentioned in the file: “Five Fluid Types Data.xls”
. In the plot control tab of “two-phase calculation” form select the properties
depending on the case as follows:
No. Case Plot Property1 Dry Gas Z compressibility factor2 Wet gas Z compressibility factor3 Gas Condensate, Volatile Oil & Black oil Phase volume fraction,
Z factor, K-values (y/x)
. For all the oil cases, add a single-stage separator calculation with separator
pressure of 100 psia and separator temperature of 75 F.
٣. The final WinProp interface should look like Figure 5.
Figure 5: WinProp interface for modeling Dry Gas case.
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٤. Save the WinProp file as ‘drygas.dat’ and run it
٥. Repeat Items 1 to 14 and build a dat file for other types of fluid and save them as
‘wetgas.dat’, ‘gascondensate.dat’, ‘volatileoil.dat’, ‘blackoil.dat’ files
respectively and then run.
Note: You are now able to analyze the results in terms of the criteria for definition of
each of the fluid types. The plots for different cases are shown in Figures 6 to 14.
Dry Gas
P-T envelope : P-T Diagram
0
200
400
600
800
1000
1200
1400
-100.0 -80.0 -60.0 -40.0 -20.0 0.0 20.0
Temperature (deg F)
P r e s s u r e ( p s i a )
2-Phase boundary Critical
Figure 6 : 2-Phase P-T diagram for Dry Gas case.
Dry Gas
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
0.84
0.86
0.88
0.90
0.92
0.94
0.96
0.98
0 500 1000 1500 2000 2500 3000 3500
Pressure (psia)
V a p o r Z - F a c t o r
180.00 deg F
Figure 7 : Vapor Z factor for Dry gas case.
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Wet gas
P-T envelope : P-T Diagram
0
500
1000
1500
2000
2500
3000
-100 -50 0 50 100 150 200 250
Temperature (deg F)
P r e s s u r e ( p s i a )
2-Phase boundary
Figure 8: 2-Phase P-T diagram for Wet Gas case.
Wet gas
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
0.90
0.92
0.94
0.96
0.98
0 500 1000 1500 2000 2500 3000 3500
Pressure (psia)
V a p o r Z - F a c t o r
220.00 deg F
Figure 9: Vapor Z factor for wet gas case
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Gas condensate
P-T envelope : P-T Diagram
0
2,000
4,000
6,000
8,000
10,000
12,000
-100 0 100 200 300 400 500 600
Temperature (deg F)
P r e s s u r e ( p s i a )
2-Phase boundary Critical
Figure 10: 2-Phase P-T diagram for Gas condensate case.
Gas condensate
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psia)
L i q u i d P
h a s e V o l u m e %
280.00 deg F
Gas condensate
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
65
70
75
80
85
90
95
100
105
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psia)
V a p o r P h a s e V o l u m e %
280.00 deg F
Gas condensate
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
0.00
0.20
0.40
0.60
0.80
1.00
1.20
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psia)
L i q u i d Z - F a c t o r
280.00 deg F
Gas condensate
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
0.90
0.95
1.00
1.05
1.10
1.15
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psia)
V a p o r Z - F a c t o r
280.00 deg F
Figure 11: Phase volume fractions and Z factors for gas condensate
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Gas condensate
Phase properties as fn(P) : Phase Properties (Solvent
Mole Fraction = 0.0000)
1.00E-03
1.00E-02
1.00E-01
1.00E+00
1.00E+01
1.00E+02
0 1000 2000 3000 4000 5000 6000 7000
Pressure (psia)
K v a l . ( v a p o r / l i q . )
( T e m p e r a t u r e = 2 8 0 . 0
0
d e g F )
CO2 N2 C1 C2 C3 IC4 NC4
IC5 NC5 FC6 C7+
Figure 12: K value for gas condensate case.
Volatile oil
P-T envelope : P-T Diagram
0
5,000
10,000
15,000
20,000
-200 0 200 400 600 800
Temperature (deg F)
P r e s s u r e ( p s i a )
2-Phase boundary Critical
Figure 13: 2-Phase P-T diagram for Volatile oil case.
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Black oil
P-T envelope : P-T Diagram
0
500
1000
1500
2000
2500
3000
-200 0 200 400 600 800 1000 1200
Temperature (deg F)
P r e s s u r e ( p s i a )
2-Phase boundary Cr itical
.
Figure 14: 2-Phase P-T diagram for Black oil case.
Additional Practice:
For the black oil data case, investigate the effect on the simulated separator
calculation induced by changing the following parameters:
•
Apply the volume shift correlations• Set the hydrocarbon binary interaction parameters to zero
• Reduce the C 7 + Pc by 20%
٦. To set volume shift to correlations, double click ‘Component
Selection/Properties’ and click on ‘VolumeShift’ tab, choose ‘Reset to
correlation values’ then save as 'blackoil1_volshift correlation value.dat' file. Go
back to the VolumeShift tab again and click on "Reset to Zero's" and save as
'blackoil1_volshift set to zer.dat' file. Run both data files and compare the results
on Separator calculation. It should look like to the following outputs:
Separator output with Volshift set to zero:
Oil FVF = vol of saturated oil at 2877.86 psia and 170.0 deg F per vol of stock tank
oil at STC(4) = 1.111
API gravity of stock tank oil at STC(4) = 58.10
Separator output with Volshift set to correlation value:
Oil FVF = vol of saturated oil at 2877.86 psia and 170.0 deg F per vol of stock tank
oil at STC(4) = 1.137
API gravity of stock tank oil at STC(4) = 32.77
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٧. Open ‘blackoil.dat’ again and set hydrocarbon binary interaction parameter to
zero, by double clicking at ‘Component Selection/Properties’ . Click on ‘Int.Coef.’ tab and click on ‘HC-HC Group / Apply value to multiple non HC-HC
pair…’ Check on 'HC-HC' and change Exponent value to zero and press 'OK'
twice. Save as a new name and see the result at Separator calculation. It should
be like following:
Oil FVF = vol of saturated oil at 2027.10 psia and 170.0 deg F per vol of stock tank
oil at STC(4)= 1.115
API gravity of stock tank oil at STC(4) = 58.15 .
٨. To reduce the C 7 + Pc by 20% , double click ‘Component Selection/Properties’ and change the Pc value of C 7 + to 12.36 and see the result again it should be
like:( make sure to save the file in new name).
Oil FVF = vol of saturated oil at 2142.23 psia and 170.0 deg F per vol of stock tank
oil at STC(4) = 1.100
API gravity of stock tank oil at STC(4) =104.78
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WinProp Exercise 2
Objective: To determine the MMP and MME for a rich gas injection flood into thereservoir (Like CO2 Flooding)
Starting with the black oil data set from Exercise 1 , create P-X phase diagrams at the
reservoir temperature for the following injection fluids:
. Addition of secondary stream with the following compositions:
• Pure N 2
• Pure CO2
• Dry gas (from Exercise 1)
• A rich gas stream with the composition (in mole %):
CO2 1.4
N 2 1.0 C 1 33.2
C 2 23.3
C 3 25.3
IC 4 3.8
NC 4 9.6
IC 5 2.1
NC 5 0.3
The required forms and their arrangement of the calculation options in WinProp
interface should look like as shown in Figure 15 for this case. Save this file as
‘blackoil_richgas_MMP_MME.dat’
Figure 15: Addition of solvents in black oil and calculation of MMP and MME
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. Run a multi-contact miscibility calculation to determine the MMP for pure rich
gas injection. Insert a Multiple-contact miscibility calculation form and input the
data shown in Figures 16 and 17 presented below.
Figure 16 : Input data for calculation of MMP.
Figure 17 : Rich gas (make-up gas) composition for calculation of MMP.
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Analyze the output file for results of single contact miscibility and multi-contact
miscibility pressures and mole fraction of make-up gas.
SUMMARY OF MULTIPLE CONTACT MISCIBILITY in *.OUT file
CALCULATIONS AT TEMPERATURE = ٧٠.٠٠ ٠ deg F
______________________________________________
FIRST CONTACT MISCIBILITY ACHIEVED
AT PRESSURE ٠.٤٩ ٨ ٠ ٠ E+٠٤ Psia
MAKE UP GAS MOLE FRACTION = ٠. ٠٠ ٠ ٠ E+٠
MULTIPLE CONTACT MISCIBILITY ACHIEVED
AT PRESSURE = ٠.٣ ٨ ٤ ٠ ٠ E+٠٤ Psia
MAKE UP GAS MOLE FRACTION = ٠. ٠٠ ٠ ٠ E+٠
BY BACKWARD CONTACTS - CONDENSING GAS DRIVE
3. Run a multi-contact miscibility calculation to determine the minimum amount of rich
gas necessary to add to the dry gas to achieve miscibility at 4500 psi (MME calculation).
For this insert the “Multiple-contact miscibility calculation” form and input the
following parameters. Notice that in this case only one pressure value is used at which
the miscibility is desired. In the composition form the starting point for the make-up gas
fraction is from 50%.
Figure 18: Input data for calculation of MME calculation.
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Figure 19: Rich gas (make-up gas) composition for calculation of MME.
Analyze the output file for results of single contact miscibility and multi-contact
miscibility pressures and mole fraction of make-up gas.
SUMMARY OF RICH GAS MME CALCULATIONS AT TEMPERATURE = ٧٠.٠٠ ٠ deg F
FIRST CONTACT MISCIBILITY PRESSURE
(FCM) IS GREATER THAN ٠.٤٥ ٠ ٠ ٠ E+٠٤ psia
MULTIPLE CONTACT MISCIBILITY ACHIEVED
AT PRESSURE = ٠.٤ ٥ ٠ ٠ ٠ E+٠٤ psia
MAKE UP GAS MOLE FRACTION = ٠.٩ ٠ ٠ ٠ E+٠٠
BY BACKWARD CONTACTS - CONDENSING GAS DRIVE
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Exercise 3: Raleigh Oil(Required File: Raleigh black oil-data.xls)
Objective: Plus fraction splitting, matching experimental constant composition
expansion, separator test and differential liberation tests.
. Initialize WinProp through CMG launcher.
. Insert a title: “plus fraction characterization” and select PR (1978), Psia & deg
F, feed as moles in the “specify titles, EOS and unit system” form.
٣. In the component selection/Properties form add the following library components
and compositions as given in the file: “Raleigh black oil-data.xls”.
Figure 20: black oil composition for Raleigh oil.
٤. To split the C 7 + fraction into pseudocomponents; double click on “ Plus fraction
Splitting" form. on " General" Tab; Specify Gamma distribution function, 4 pseudocomponents, The first single carbon number in plus fraction as7 and leave
others as default Go to "Sample 1" Tab.
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Figure 21: Plus fraction splitting for Raleigh Oil .
٥. Input the MW+ as 190 , SG+ as 0.8150 and Z+ (mole fraction of C 7 + fraction) as
0.2891. Make sure alpha is equal to 1.
٦. Save the dataset as ‘raleigh oil.dat’ and run it. After running the data set, use the“Update component properties” in the File menu. And save the data set as
‘raleigh oil_plus fraction splitting.dat’. You will now notice that 4 hypothetical
pseudo components have been added in the components form.
٧. In order to match the CCE, Differential liberation and separator test, use the data
given in the file “Raleigh black oil-data1.xls”. then open "Saturation Pressure", "constant composition expansion", "separator" "differential liberation" forms
in sequence. Input the experimental data given in the file “Raleigh black oil-
data1.xls”.( you can also input all above forms, from another WinProp dataset).
٨. On the “Component Selection/properties” form, set the volume shifts to thecorrelation values. Save your model as ‘raleigh oil_experimental data.dat’ and
run it once to validate your model and check for errors in the input data.
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٩. Click on Regression /start on top menu and open Open "Regression Parameters"
form before "Saturation Pressure" form( before any regression calculation) and
insert " End Regression " form at end(after all forms that are supposed to be
included in regression process, i.e. CCE, Saturation Pressure, Differential
Liberation and Separator ). This defines the “Regression Block.”
٠. Select the heaviest pseudocomponent’s Pc and Tc, volume shifts of all C 7 +
pseudocomponents and C 1 , and the hydrocarbon interaction coefficient exponent
as regression variables. Set the convergence tolerance to 1.0 E-06 in "Regression
Controls" tab and then save and run the data set.
Figure 22: Regression control for experimental data matching.
. Adjust the weight of some key experimental data points. Try setting the weight for
separator API gravity to 5.0 , saturation pressure to 10.0 , and differential
liberation API gravity at std conditions to 0.0. Re-run the regression.
. In some cases, you may have to change the lower and upper bounds of theregression parameters depending on whether these bounds are reached during
the regression. In this case the following bounds were used:
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Figure 23: Variable bounds used during the regression.
٣. Analyze the *.out file and refer to the summary of Regression Results for
comparison of the experimental versus calculated values.
٤. After completing the match to the PVT data, update the component properties and
again save the file under a new name as ‘raleigh oil_experimental data_vis.dat’in preparation for viscosity matching.
٥. For viscosity matching, temporarily exclude the saturation pressure, constant
composition expansion and separator calculations from the data set by right-
clicking on each option and selecting “Exclude” from the pop-up menu.
٦. In the "Differential Liberation" form, set the weight for the viscosity data to 1.0 ,
and all other weights to 0.0.
٧. On the viscosity parameters tab of the " Regression Parameters" form, remove all
previously selected parameters, and then select “Vc, vis(l/mol)” for C 1 and theC 7 + pseudo components as regression variables. Run the data set.
٨. After completing the match to the viscosity data, update the component properties
and save the file under a new name ‘raleigh oil_Blackoil PVT.dat’ in preparation
for generating the IMEX PVT table.
٩. Remove the regression forms and include any options that had previously been
excluded. Add a “Black Oil PVT Data” option at the end of the data set.
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٠. On the ‘Black Oil PVT Data’ form, enter the saturation pressure data, desired
pressure levels and the separator data. Enter mole fractions of 0.1 , 0.2 and 0.3 for
the swelling data.
Figure 24: Black oil PVT export for IMEX .
Figure 25: Pressure levels for back oil PVT
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Figure 26 : Water properties for back oil PVT
. Leave the “Oil Properties” controls at the defaults, and then select “Use solution
gas composition…” for the swelling fluid specification on the “gas properties”
tab. Run the data set.
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Exercise 4: Heavy Oil for STARS(Required file: “Heavy Oil for STARS-data.xls”)
Objective: Plus fraction splitting, matching lab data and generation of fluid model for
STARS
. Initialize WinProp through CMG launcher.
. Insert a title: “Fluid Model for STARS” and select PR (1978), psia & degF, feed
as moles in the “specify titles, EOS and unit system” form.
٣. In the component selection/Properties form add C 1 library component and
composition as given in the file: “Heavy Oil for STARS-Data.xls”.
٤. Split the C 6 + fraction into pseudocomponents. In order to split the C 6 + fractions,
insert a “Plus fraction Splitting” form in the WinProp interface. The first single
carbon number in plus fraction should be 6 . Also, specify the number of Pseudo-
components to 4.
Figure 27 : Plus fraction splitting for Heavy Oil .
٥. Under the “sample1” tab, input SG+ as 0.989 and Mole fractions and Molecular
Weights for liquid component as given in the file: “Heavy Oil for STARS-
Data.xls”.
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Figure 28: Plus fraction splitting for Heavy Oil.
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٦. Add ‘Saturation Pressure’ form. Save the dataset as ‘S 1-char.dat’ and run it.
After running the data set, use the “Update component properties” feature and
save the data set as ‘S 2-regression psat.dat’. You will now notice that 4
hypothetical pseudo components have been added in the components form.
٧. We will do regression to match the lab measured saturation pressure. On the
regression parameters form, select the heaviest pseudocomponent’s Pc, and the
hydrocarbon interaction coefficient exponent as regression variables.. Run the
dataset. After running the dataset, use the “Update component properties”
feature and save the data set as ‘S 3-lumping.dat’.
٨. Add a ‘Component Lumping’ form and lump last three heavy components.
‘Component Lumping’ form should look like Figure 29
Figure 29: ‘Component lumping’ form for Heavy Oil.
٩. Run the dataset. After running the dataset, use the “Update component
properties” feature and save the data set as ‘S 4-regression.dat’.
٠. After lumping we need to open ‘Separator’ and 'Saturation Pressure' forms to do
another regression. Enter saturation pressure, reservoir temperature, GOR and
API data from “Heavy Oil for STARS-Data.xls”.
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. Select Pc and Tc of heaviest components, and Vol shift of two heavier components
as regression parameters. Run the dataset. After running the dataset, use the
“Update component properties” feature and save the data set as ‘S 5-
regression_visc.dat’.
. We will repeat regression to match viscosity at 10 and 100 deg C as given in
“Heavy Oil for STARS-Data.xls”. Insert two ‘Two phase Flash’ forms to input
experimental viscosity data. One of such ‘Two phase flash calculations’ form
would look lie as shown in figure 30.
Figure 30: Experimental viscosity data for Heavy Oil .
٣. On "Component definition" form, set viscosity model type to Pedersen
Corresponding State Model. Select all check boxes on Viscosity Parameters tab
on ‘ Regression Parameters’ form. Run the dataset. After running the dataset, use
the “Update component properties” feature and save the data set as ‘S 6 -STARS
PVT.dat’.
٤. It is now the time to generate fluid model for STARS. Insert two ‘CMG STARS
PVT Data’ forms. Select Basic STARS PVT data on one of the forms and Gas-
Liquid K-Value table on the other then save and Run it . The file with *.STR
extension is ready to be input into STARS model through Builder.