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A LEVEL CHEMISTRY
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7/21/2019 Worksheet Atom & Stoichiometry
http://slidepdf.com/reader/full/worksheet-atom-stoichiometry 1/8
Chapter 1/ Atom & Stoichiometry/ Jan 2016
Worksheet 1.1: Moles
Use the Ar values in Periodic Tale to ans!er these "uestions#
1 $hat is the mass in %rams o one mole o each o the ollo!in%'
a (inc atoms
b lead atoms
c hydro%en atoms
d hydro%en molecules
e sulur atoms
f sulur molecules )S*+
g copper),,+ nitrate)-+ ormula units
h !ater molecules
i sodium chloride ormula units .
2 a o! many moles o atoms are there in each o the ollo!in%'
ive your ans!ers to 3 si%niicant i%ures#
i 4.6 g of zinc
ii 79 g of oxygen
iii 0.156 g of calcium
iv 109.6 g of sodium
v 0.31 g of lead
vi 5.3 g of hydrogen
b $hich o these samples contains the %reatest numer o atoms'
c $hich o these samples contains the smallest numer o atoms' .*
3 o! many moles o molecules are there in each o the ollo!in%'
ive your ans!ers to 3 si%niicant i%ures#
a #0 % o !ater
b 0#0** % o caron dio4ide
c 56#3 % o caron mono4ide
d 0#065 % o ammonia .
4 o! many moles o ormula units are there in each o the ollo!in%'ive your ans!ers to 3 si%niicant i%ures#
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
a 1#00 % o calcium caronate
b 26#0 % o copper),,+ nitrate)-+
c 7#63 % o (inc chloride
d 0#163 % o aluminium o4ide .
Worksheet 1.2: Numbers of particles
Use the Ar values in Periodic Tale to ans!er "uestions 1 and 2#
1 a o! many moles o atoms are there in 1#00 mol o each o the ollo!in% molecules'
i HNO3
ii 3H!
iii HlO4
iv !H1! "4#
b o! many moles o Ca28 ions are there in 10#0 mol o CaCl2' .1
c o! many moles o Cl 9 ions are there in 3#00 mol o CaCl2' .1
d o! many moles o : 9 ions are there in 0#0500 mol o Al):+3' .1
2 a o! many %rams o caron are there in 0#500 mol o C3*' .2
b o! many %rams o caron are there in 0#100 mol o C*1*' .2
c o! many %rams o nitro%en are there in 2#00 mol o ;:3' .2
d o! many %rams o o4y%en are there in 2#00 mol o ;:3' .2
Use the value o the Avo%adro constant< L< rom =ata sheet 1 to ans!er the ollo!in% "uestions#
3 a o! many molecules are there in each o the ollo!in%'
i 0.100 mol of 3H! "1#
ii 5.00 mol of HNO3 "1#
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
iii 0.0100 mol of !H1! "1#
b o! many atoms are there in each o the ollo!in%'
i 0.100 mol of 3H! "1#
ii 5.00 mol of HNO3 "1#
iii 0.0100 mol of !H1! "1#
c o! many ions are there in each o the ollo!in%'
i 10.0 mol of al$ "$#
ii 0.0500 mol of %l&OH'3 "$#
Worksheet 1.3: Reacting masses
Use the Ar values in Periodic Tale to ans!er these "uestions#
1 a Calcium o4ide reacts !ith hydrochloric acid accordin% to the ollo!in% e"uation>
Ca: 8 2Cl ? CaCl2 8 2:
$hat mass o calcium chloride orms !hen each o the ollo!in% masses o
calcium o4ide reacts !ith e4cess hydrochloric acid'
i $!.05 g "1#
ii $.!05 g "1#
iii 56.1 (g "1#
iv 11.$$ g "1#
v 1!.7 )onnes "1#
b $hat mass o hydrochloric acid !ould react in each case' .5
c $hat mass o !ater !ould e produced in each case' .5
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
2 a $rite a alanced symol e"uation and a mass e"uation or the reaction et!een
copper),,+ o4ide )Cu:+ and nitric)-+ acid );:3+#
b $hat mass o copper),,+ nitrate)-+ )Cu);:3+2+ !ill e produced !hen each o the
ollo!in% masses o copper),,+ o4ide reacts !ith e4cess nitric)-+ acid'
i 7.95 g
ii 15.9 g
iii 159 (g "5#
3 $hat masses o caron dio4ide and !ater must react in order to produce each o the
ollo!in% masses o caronic acid )2C:3+'
a 310 %
b 6#20 @%
c 0#155 % .*
4 inc o4ide and suluric)-,+ acid react accordin% to the ollo!in% e"uation>
n: 8 2S: ? nS: 8 2:
$hat masses o (inc o4ide and suluric)-,+ acid must react in order to produce each o
the ollo!in% masses o (inc sulate)-,+'
a 3#00 %
b 17#2 %
c 0#130 % .7
Worksheet 1.4: Empirical formulae
Use the Ar values in Periodic Tale to ans!er these "uestions#
1 The ollo!in% sets o data %ive the percenta%e composition y mass o three dierent
o4ides o sodium# Calculate the empirical ormula o each o4ide o sodium#
a 7#2B sodium< 25#*B o4y%en
b 1#*B sodium< 5*#2B o4y%en
c 5#0B sodium< 1#0B o4y%en .6
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
2 The ollo!in% sets o data %ive the percenta%e composition y mass o our dierent
o4ides o nitro%en# Calculate the empirical ormula o each o4ide o nitro%en#
a 36#*B nitro%en< 63#2B o4y%en
b 6#7B nitro%en< 53#3B o4y%en
c 25#B nitro%en< 7#1B o4y%en
d 63#6B nitro%en< 36#B o4y%en .*
3 Use the ollo!in% sets o data to calculate the empirical ormula o each o these compounds#
a :ctane is a hydrocaron# 5#00 % o octane contains #21 % o caron#
b 6#5 % o aluminium sulide contains 2#32 % o aluminium#
c :rthoclase< a mineral in eldspar< is a compound o potassium< aluminium< silicon
and o4y%en# 20#00 % o orthoclase contains 2#*1 % o potassium< 1# % o aluminium
and 6#0 % o silicon# .6
4 Phosphorus and sulur orm several dierent compounds# The ollo!in% sets o data
%ive the mass o phosphorus contained in 1#000 % o each o these three compounds#
Calculate the empirical ormula o each compound#
a 1#000 % o compound contains 0#356 % o phosphorus#
b 1#000 % o compound ! contains 0#56 % o phosphorus#
c 1#000 % o compound " contains 0#37 % o phosphorus# .6
Worksheet 1.#: Moles in solution
1 a Calculate the concentration o each o the ollo!in% solutions#
i 0.!40 mol of solu)e dissol*ed in 5.00 dm3 of solu)ion
ii 0.360 mol of solu)e dissol*ed in 300 cm3 of solu)ion
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
iii 0.0$00 mol of solu)e dissol*ed in $5.0 cm3 of solu)ion
iv $4.0 mol of solu)e dissol*ed in 30.0 dm3 of solu)ion
b i $hich o the solutions aove is the most concentrated'
ii +hich of )he solu)ions a,o*e is )he mos) dilu)e &leas) concen)ra)ed'-
iii +hich of )he solu)ions a,o*e ha*e )he same concen)ra)ion- "7#
2 Calculate the concentration o each o the ollo!in% solutions#
a 0#760 % o potassium nitrate)-+ );:3+ dissolved to ma@e *0#0 cm3 o solution
b 12#0 % o CuS:#52: dissolved to ma@e 100 cm3 o solution
c 5#0 % o %lucose )C612:6+ dissolved to ma@e 300 cm3 o solution
d 120 % o nitric)-+ acid );:3+ dissolved to ma@e 200 cm3 o solution .12
3 o! many moles o solute does each o the ollo!in% samples contain'
a 60#0 cm3 o a 2#00 mol dm 93 solution
b 200 cm3 o a 0#200 mol dm 93 solution
c 0#500 dm3 o a 1#00 mol dm 93 solution
d 12#6 cm3 o a 0#250 mol dm 93 solution .
4 $hat volume o a solution o concentration 0#0*00 mol dm 93 should e measured out
to %ive each o the ollo!in% amounts' ive your ans!ers oth in dm3 and in cm3#
a 0#000100 mol
b 0#000320 mol
c 0#000 mol .6
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
Worksheet 1.$: %as &olumes
Use the Ar values in Periodic Tale to ans!er these "uestions# Dou !ill also need to @no! the molar
volume o %as at room conditions< !hich can e ound in =ata Eoo@let#
1 $hen calcium caronate is heated stron%ly< it decomposes to %ive calcium o4ide and
caron dio4ide#
a $rite a alanced symol e"uation or this reaction#
b $rite a mass e"uation )in %rams+ and include the volume o caron dio4ide<
measured at r#t#p#
c $hat volume o caron dio4ide< measured at r#t#p#< !ill orm !hen each o the
ollo!in% masses o calcium caronate decomposes'
i 1#00 %
ii 25#0 %
iii 0#0 % .6
2 $hen ammonia %as and hydro%en chloride %as mi4 to%ether< they react to orm a solid
called ammonium chloride#
a $rite a alanced symol e"uation or this reaction#
b $rite a mass e"uation )in %rams+ and include the volumes o ammonia and
hydro%en chloride< measured at r#t#p#
c $hat volumes o ammonia and hydro%en chloride %ases< measured at r#t#p#< must react
in order to produce each o the ollo!in% masses o ammonium chloride'
i 10.7 g
ii $14 g
iii 1.00 g"10#
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Chapter 1/ Atom & Stoichiometry/ Jan 2016
Worksheet 1.': End(of(chapter test
Use the Ar values in Periodic Tale to ans!er these "uestions# Dou !ill also need to @no! the molar
volume o %as at room conditions< !hich can e ound in =ata Eoo@let#
ive all your ans!ers to 3 si%niicant i%ures#
1 The reaction et!een ;a: and 2S: can e !ritten as>
2S: 8 ;a: ? ;aCl 8 2:
,n such a reaction< 1*#0 cm3 o suluric acid !as neutralised y 12#0 cm3 o
0#000 mol dm 93 sodium hydro4ide#
a $hat !as the volume< in dm3 o>
i )he acid-
ii )he al(ali- "$#
b Calculate the numer o moles o al@ali# .1
c Calculate the numer o moles o acid and then its concentration# .2
2 a 1#*0 dm3 o hydro%en chloride %as !as dissolved in 100 cm3 o !ater#
i Ho many moles of hydrogen chloride gas ere /resen)- "1#
ii +ha) as )he concen)ra)ion of )he hydrochloric acid formed- "$#
b 25#0 cm3 o the acid !as then titrated a%ainst sodium hydro4ide o concentration
0#250 mol dm 93 to orm ;aCl and !ater>
;a:)a"+ 8 Cl)a"+ ? 2:)l+ 8 ;aCl)a"+
i Ho many moles of acid ere used- "$#
ii alcula)e )he *olume of sodium hydroxide used. "4#
3 2#0 dm3 o chlorine %as !as reacted !ith sodium hydro4ide solution# The reaction ta@in%
place !as as ollo!s>
Cl2)%+ 8 2;a:)a"+ ? ;aCl)a"+ 8 ;a:Cl)a"+ 8 2:)l+
a o! many moles o Cl2 reacted' .1
b $hat mass o ;a:Cl !as ormed' .2
c , the concentration o the ;a: !as 1#00 mol dm 93< !hat volume o sodium hydro4ide
solution !as re"uired' .2