WV Chemical Spill Mountain State Symposium 5-9-14F

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    Rahul Gupta, M.D., M.P.H., F.A.C.P.Executive Director and Health Officer

    Kanawha-Charleston Health Department

    Putnam County Health Department

    RESPONSE AND RECOVERY DURING

    ENVIRONMENTAL DISASTER: LEARNING FROM

    ELK RIVER CHEMICAL S

    PUBLIC HEALTH AND THE LARGEST CHEMICAL

    DRINKING WATER CONTAMINATION INCIDENT

    IN US HISTORY

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    Presentation Overview

    Introduction of the Incident

    Public Health Response

    Recovery Efforts Future Challenges

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    Academic Partnerships and Contributio

    Andrew Whelton, Ph.D., The Whelton Group,

    WVTAP, and University of South Alabama (USA

    Rajarshi Dey, Ph.D., USA

    LaKia McMillan, USA

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    The Incident January 09, 2014: Unknown

    volumes of crude 4-methylcyclohexanemethanol(MCHM) release was detectedfrom a Freedom Industries facinto the Elk River, WV.

    Detection via resident complaiof black licorice odor.

    Spill occurred upstream from tprincipal WV American Waterintake, treatment and distribut

    center.

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    What is MCHM

    Crude MCHM is a chemical foamused to wash coal and removeimpurities that contribute topollution during combustion.

    While initially unsure, laterestimations placed at 10, 000 USgallons of crude MCHM leaked fra one-inch hole (and another inch) in the bottom of a stainless

    steel storage tank capable ofholding 40,000 US gallons.

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    Consisted of at Least 7 Different Chem

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    Crude MCHM: How much do we know

    >80,000 such chemicals in use; very little known OSHA: Hazardous

    Carcinogenic effects? No data available.

    Specific Target organ toxicity? No data available.

    Mutagenic effects? No data available.

    Aspiration Risk? No data available.

    Developmental toxicity? No data available.

    Bioaccumulation potential? No data available

    No Human data available!

    What is the acceptable level of MCHM in drinking water CDC: There should be no MCHM in drinking water.

    (http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/mchm.asp)

    http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/mchm.asphttp://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/mchm.asphttp://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/mchm.asphttp://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/mchm.asp
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    The Response

    City of Charlestothe West VirginiaState Capitol.

    300,000 people

    served by waterutility.

    Many more visitFirst week of thelegislative sessio

    9 counties serve

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    Public Response

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    Public Health Response

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    Response contd

    ICS immediately; Metro 911 (EOC) partnerships. 24/7 information & media updates; Provided input to Governo

    Office.

    Fielded approximately 5,000 calls.

    ~2,000 facilities; ~Almost 100 Schools.

    Water distribution/Special needs populations.

    Maintained syndromic surveillance and situational awareness

    Partnerships with multiple organizations (old and new).

    Assisted with SB 373 now state law; Accredited LHDs role.

    Ongoing research activities. Multiple other activities while regular services continued.

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    Incident Timeline by C&E News

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    Continued with updates

    Feb. 5 onwards: Almost

    daily odor complaintsfrom schools and some

    school closures become

    norm for next several

    weeks.

    Mid to Late Feb.: WV TAP

    scientists find persistent low

    levels of MCHM in all homes

    tested across 9 counties

    leaving the plant, not entering.

    Asks water co to conduct

    testing of their facility.

    Mar 21-22: Water Co

    reveals intake from river

    undetectable but water

    leaving the plant for

    homes has persistent

    low levels of MCHM.

    Apr. 1: WVTAP

    scientists state

    screening levels

    for MCHM 8 times

    more stringent

    than CDC.

    A

    a

    c

    h

    e

    i

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    Recovery Process

    Our aim is to utilize credible science and data to infodecision making and assist the recovery process:

    To explore, understand and address physical, sociocultural, psychological and economic impacts.

    To accurately assess the duration of human exposu

    To assure the dissipation of chemicals from ourplumbing systems.

    To implement longitudinal population surveillanceprogram.

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    Slide Title

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    Recovery Science Development

    Funding from Governor Tomblin to WV TestingAssessment Project (TAP) independent expert panel.

    Partial funding from Kanawha-Charleston HealthDepartment.

    Partial funding for Dr. Whelton from the NSF CBETRAPID grant program; Effort not part of the WV TAPproject.

    Contributions from Dr. Rajarshi Dey, LaKia McMillan

    from University of South Alabama.

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    What Have We Learn From Data so fa

    WVTAP (Testing Assessment Project) KCHD online survey

    Home survey

    Syndromic surveillance findings

    Emergency visit findings

    WV CAPS (Community Assessment

    Population Survey). Release (5/12/14)

    Si ifi t Diff b t

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    Significant Differences between

    CDC and WVTAP Screening Levels

    Compound & AssumptionCDC WV TAP Expert Pane

    4-MCHM (ppb) 1,000 120

    PPH (ppb) 1,200 850

    DiPPH (ppb)

    1,200

    250

    Duration 14 days 28 days

    Most sensitive population 1 year old child Formula fed infant

    Exposure routes

    Ingestion only

    Ingestion, inhalation, der

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    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    100%

    Bathe Clean Cook Drink Other

    Week of January 27th Week of February 3rd Week of February 10th Week of February 17th Week of Februar

    Kanawha-Charleston Health Department

    Water Usage Survey

    January 27th - March 1, 2014

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    0%

    5%

    10%

    15%

    20%

    25%

    30%

    35%

    40%

    45%

    Jan. 27 - Feb. 2, 2014 Feb. 3 - Feb. 9, 2014 Feb. 10 - Feb. 16, 2014 Feb. 17 - Feb. 23, 2014 Feb. 24 - Mar 1, 2014

    Less than $100 $100 -$250 $250 - $500 Over $500

    Kanawha-Charleston Health Department

    Household Financial Impact of Water Contamination

    January 27th - March 1, 2014

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    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    100%

    Yes No

    96%

    4%

    Do you feel the local health department should develop a surveillance

    program to monitor the long term health impact of the chemical?

    January 27th - March 1st

    714 responses

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    Survey: 16 Residential Homes

    30 minute interview Demographics

    Building plumbing pipe material and age

    Experiences before and after the do not use order

    Means learned about the incident

    Reported tap water aesthetics and health symptoms

    Counties: Kanawha, Lincoln, Putnam

    Towns: Cross Lanes, Elk View, Nellis, South Charleston,Charleston

    23

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    Residential Plumbing Systems are Comple

    More than 1 pipe type waspresent at 31.3% of the homes

    Partly or entirely contained..

    Metal piping

    62.5% Copper

    12.5% Galvanized iron

    Plastic piping

    31.3% cPVC

    18.8% PEX6.3% PB

    24

    n=15

    Multiple Exposure Locations and Routes wer

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    Multiple Exposure Locations and Routes wer

    Found to be SignificantFactors (P-value and Odds Ratio) Symptom

    Drinking (0.000, OR=3.48), Work (0.012, OR=4.52), Sex (0.052, OR=0.48)

    Nausea

    Drinking (0.000, OR=6.35), sex (0.023, OR=0.33) Vomitin

    Drinking (0.000, OR=6.26), Food facility (0.008, OR=26.46), Work (0.013, OR=7.76),

    Home(0.051, OR=8.03)Diarrhe

    Onsetc1/peak 1(0.017, OR=2.28) Eye Irritat

    Wash/Bath (0.000, OR=5.49), Onset2/peak2(0.001, OR=0.35), Drinking (0.074,

    OR=0.53)Skin Irritat

    Wash/Bath (0.003, OR=2.9), Drinking (0.053, OR=0.54) Rash

    Work (0.003, OR=4.62), Food Facility (0.015, OR=5.85), Sex (0.096, OR=0.48)Headach

    None

    Cough

    Drinking (0.002, OR=5.20), Flushed (0.00, OR=0.20), Sex (0.025, OR=0.17)Sore Thro

    Odds ratios (OR) = probability of a patient reporting a symptom if the patient became ill during the first symptom reporting peak.

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    After the Okay to Flush Order, Nearly All Residents Chose Not

    Use Tap Water for Hygiene, Laundry, or Hydration Activities

    0%

    25%

    50%

    75%

    100%

    Drink Shower WashClothes

    BrushTeeth

    Cook Animals

    Percentage

    Water Use Activity

    Be

    Aft

    n

    Did not resume tap water use because did not believe the water was safe

    Detected licorice tap water odor after flushing

    Friends and media reported tap water was still making people sick

    Syndromic Surveillance of Sentinel Providers f

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    Syndromic Surveillance of Sentinel Providers f

    Kanawha & Putnam Counties (Jan. 9-Feb. 9)

    0

    5

    10

    15

    20

    25

    30

    PatientsReportingSymptoms

    Symptom Onset Date

    Do Not Use Order Issued

    Plumbing System Flushing Begins

    Self-Reported Symptoms from the 10

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    Self Reported Symptoms from the 10

    Sentinel Medical Providers (n=224)

    0

    20

    40

    60

    80

    100

    120

    Count

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    Source: ED Records review by CDC/WVDHHR released 4/23/14.

    htt : www.bt.cdc. ov chemical MCHM westvir inia2014

    Do Not

    Use Order

    Issued

    Plumbing System

    Flushing Begins

    http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/
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    Source: ED Records review CDC/WVDHHR released 4/2

    http://www.bt.cdc.gov/che

    M/westvirginia2014/

    http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/
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    Source: ED Records review by CDC/WVDHHR released 4/23/14.

    http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/

    Significant Differences between

    http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/http://www.bt.cdc.gov/chemical/MCHM/westvirginia2014/
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    Significant Differences between

    CDC and WVTAP Screening Levels

    Compound & Assumption

    CDC WV TAP Expert Pane

    4-MCHM (ppb) 1,000 120

    PPH (ppb) 1,200 850

    DiPPH (ppb)

    1,200

    250

    Duration 14 days 28 days

    Most sensitive population 1 year old child Formula fed infant

    Exposure routes

    Ingestion only

    Ingestion, inhalation, der

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    Community Assessment Population Surv

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    CAP Survey: Hardship

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    CAP Survey: Economic Impact

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    CAP Survey: Sources of water

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    CAP Survey: Social Trust

    F Ch ll

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    Future Challenges

    Document the complete dissipation of the chemicalsfrom our plumbing systems.

    Encourage state and federal partners to conduct furtresearch.

    Ensure impacted populations long term safety throulongitudinal population surveillance is conducted.

    Ensure that public health plays a significant role inguaranteeing chemical safety and drinking water

    protections at all levels: local, state and federal.

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    Science and Public Health

    Studies needed to be conducted:

    Human/Animal

    Chemical (Crude MCHM + PPH)

    Conduction Systems

    Qualitative Testing of Chemicals

    Human and Animal Studies

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    Human and Animal Studies

    Longitudinal population surveillance studies:Registry, biomonitoring, environmental publichealth tracking, etc.

    Occupational health studies.

    Animal studies: Toxicology (plus metabolism,excretion, bioaccumulation, mutagenicity (in-vitro/in-vivo), teratogenicity, target organ toxicitetc).

    Long term ingestion human health impact.

    Chemical (Crude MCHM/PPH) Studies

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    Chemical (Crude MCHM/PPH) Studies

    True, in-vivo half life (in treated water).

    Indoor air quality, partition/odor humanimpact issue.

    Products formation (with treated water) incold and hot temperatures, their potentialfor harm, if any, oxidizing properties.

    Combustion points (of chemicals andcompound products, if any).

    Chemical stability, reactivity.

    d i di

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    Conduction Systems Studies

    Home pipes (deposits of chemicals/compounds,leaching, adsorption, etc).

    Water heater study.

    Temperature difference and chemicals' behavior homes.

    Peer review of established flushing protocols.

    Impact of long term presence.

    Qualitative Testing of chemicals

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    Qualitative Testing of chemicals

    Current quantitative tests can test at varyinglevels. Which ones are optimum? Lowest limitsof detection?

    Inter-lab variability?

    Inter-test variability? Inter-operator variability?

    Test variability within same pipes and acrosspipes in homes?

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    Thank You!

    [email protected]

    304.348.6494 Some material used in this presentation was

    developed for Dr. Wheltons West Virginia

    presentation delivered in New Orleans, March 2014

    mailto:[email protected]:[email protected]