I larrell Shale
Harnett sfia le
Tung Limestone
mown. umerione
Urn•Mom
ppor1.4 Ilnufteene
O rug .A1Khe, Vnl,ey Lamm nilareellus
Onondaga LIMOStOne
iskanv Sandstone
Figure 2. Stratigraphy of Lower and Middle Devonian in Appalachian Basin
(After, Wrightstone, 2009)
c ;
Mdl eel les Snake
Using XRF, SEM and Pyrolysis for an Economic Appraisal of the Marcellus Formation of Western Pennsylvania for Fracking Purposes Presented at: AAPG 2015 Annual Convention & Exhibition, Denver, Colorado, May 31" — June 3rd by Paul Comets; Chuck Stringers; Christian Scheibel; Albert Maende2; Erik Boice3
(1) Halliburton, Houston, TX, United States, (2) Wildcat Technologies, LLC, Humble, TX, United States (3) Noble Energy, Houston, TX, United States
Introduction
An economic appraisal of the Marcellus Formation of Western Pennsylvania and West Virginia (Figure 1) was done for purposes of determining its best
producible hydrocarbons-bearing facies and suitable frac stage placement. The appraisal is comprised of reservoir characterization and a geochemical study of
core and drill cuttings retrieved from a single vertical well. The analyzed well penetrated the Devonian-age Burkett, Tully Limestone, Hamilton and Marcellus
Formations as well as the top portion of the Onondaga Formation (Figure 2).
Figure 1. Marcellus Shale Play in Appalachian Basin
(EIA, 2011)
This economic appraisal seeks to demonstrate that analyses of drilled rock cuttings by using the Advanced Sample Analysis (ASA) methodology is a cost-effective
alternative to generate the essential data required for identifying the best producible hydrocarbons-bearing facies and suitable frac stage placement. ASA
methodology comprises of the use of XRF, SEM-EDX (or EDS) and Pyrolyzer. ASA data can also be correlated with MWD/LWD and wire-line tool responses.
Analyses
LaserStrat° Spectro° XEPOS Ill EDX
Analytical results from X-ray Fluorescence (XRF) provide chemical signatures of over 35 elements of the analyzed rock core or cuttings. These include the major
elements sodium, magnesium, aluminum, silicon, phosphorus, sulfur, potassium, calcium, titanium, manganese, and iron, reported as oxides in weight percent (wt
%). The minor and trace elements including chloride, vanadium, nickel, copper, zinc, arsenic, bromine, rubidium, molybdenum, thorium, and uranium are reported
in parts per million. The concentrations of potassium, thorium and uranium are computed into a theoretical gamma ray response (ChemoGR®) expressed in
American Petroleum Institute (API) equivalent units. This enables a direct comparison with gamma ray responses recorded from down-hole tools. The major
elements are utilized to model the mineralogy of the samples. In addition, some trace elements such as Ba and Zr are also utilized to model minor minerals such as
barite and zircon respectively. The modelled mineralogy is then utilized to calculate a Relative Brittleness Index (RBI) (Buller et cll., 2010), where the RBI represents
an enhancement of Jarvie's (2007) mineralogy based definition of rock brittleness for the Barnett Shale.
LithoSCAN° FEI Wellsite° SEM-EDX (EDS)
The SEM-EDX with QEMSCAN ® analysis provides accurate mineralogical composition of a rock sample through the use of the SEM with Energy Dispersive X-ray and
associated analysis program. Further, SEM-EDX analysis provides accurate porosity determination. In this analysis a 5lim Back Scatter Electron (BSE) resolution
image was used for porosity calculations. The 5µrn resolution enables identification of pore sizes in the micro-pore range of 1 to 62.5pm (Loucks et al. 2012).
HAWK° Pyrolysis and TOC
Pyrolysis instruments analyze suitably ground rock samples by using an initial isotherm to release the free oil of the rock (S1), detectable by a Flame Ionization
Detector (FID), followed by temperature ramping in an inert environment to a suitable maximum temperature that allows for FID recognition of any bitumen and
asphaltene that may be present, as well as measurement of hydrocarbons that are yielded from the break-down of the rock's kerogen component (S2), whose peak
generation temperature is recorded as the Tmax maturity parameter (Dow, 2011). On completion of the pyrolysis cycle, air is passed through the pyrolysis
instrument, while ramping the temperature to a suitable maximum that allows for the rock sample's oxidation products which consist of carbon monoxide and
carbon dioxide to be measured by Infra-Red detectors.
Abstract
An analysis of a core from the Marcellus Formation of Western Pennsylvania was
undertaken using three laboratory instruments; Spectro XEPOS® XRF, FEI Wel!site® SEM
with EDX capability and HAWK pyrolyzer. A fourth parameter that was taken into
consideration was porosity measurements from a PHIE and PHIT neutron emitting tool.
Unexpected relationships emerged from a comparison between the various downhole
curves.
Hydrocarbons that were generated from kerogen pyrolysis (S2) varied greatly in value
with the neutron probe's total porosity. Macroporosity as detected by the SEM
(analyzed greater than 5 microns) showed more agreement when compared to the
Total Organic Carbon (TOC). Macroporosity data varied with the siliceous microfossil
content, particularly radiolaria within the Marcellus Formation, and non-specific shell
hash in the overlying Burkett Formation. According to the analyses there is evidence of
redeposited or transported silica paralleling these zones.
The free oil (S1) showed a similar distribution to the S2 and indicated locations of three
prospective "sweet spots"; Burkett Formation, Upper Marcellus Formation, and Lower
Marcellus Formation. Carbonate horizons indicate low porosity due to the presence of
clay. The SEM images also show the presence in the limestone with extensive
bioturbation, shell fragments, and phosphatic enrichment. Pyrolysis analysis reveals
low TOC values within these horizons as well. The carbonate-rich, relatively oxidizing
paleoenvironment allowed various species of burrowing organisms to thrive. The
remainder of the Marcellus Formation appears to have been deposited under
substantially anoxic conditions and is largely composed of silty clay; the siltiest region is
situated near the base of the formation. The zones of lowest clay content located in the
middle of the Lower Marcellus Transgressive System Tract (TST) also contain the
greatest macroporosity and highest oil content (Si, S2). This TST sequence likely
corresponds to the best of the three prospective sweet spots.
Organic richness is optimal within the Marcellus Formation, ranging between 2 and 12
percent (%) TOC. Based on the analyses, this zone is evidently a source rock; S2 values
reported averaged greater than 5 milligrams hydrocarbons per gram of rock. The
Burkett and Tully Limestone often contains more than 2% TOC. Tmax maturity data
shows the Marcellus Formation is situated in the Condensate/Wet Gas window (Tmax
of 455 — 475 °C). The Lower Marcellus sweet spot shows a relatively low clay and high
silt content making it the best candidate for frac stage placement. This zone shows high
brittleness and elevated hydrocarbons content (S1 and S2). At the base of the Marcellus
and immediately above the Onondaga Limestone there is a very thin zone of extreme
ductility that appears to correspond to a bentonitic ash layer. The combination of
detailed lithological analyses with an appraisal of the hydrocarbons within the
Marcellus and adjacent formations allows zonation in terms of potential economic
productivity and engineering suitability for fracking purposes.
V 1-.N.AL r ec
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°Note: Lists olthe mineralogical composition whose sum provided the LiS_Siliceous Mudstone,LiS_Argillaceous
Mudstone and DS_Carbonate analytical results
LiS_Siliceous Mudstone LiS_Argillaceous Mudstone LiS_Carbonate
1.1.11..
The siliceous and argillaceous mudstone
contents of these three formations are plotted
in Figure 4. It is very significant that, as from the
Hamilton Formation down-hole all the way to
the Lower Marcellus HST, the argillaceous
mudstone content is far higher than that of the
siliceous mudstone content. When the Lower
Marcellus TST is penetrated, there is a
crossover and the siliceous mudstone content is
greater than the argillaceous mudstone
content. It is also significant that it is the Lower
Marcellus TST that has the highest free oil,
kerogen yield and TOC values. The only other
unit that shows higher siliceous mudstone
content when compared to the argillaceous
mudstone content is the Burkett Formation. It's
free oil, kerogen yield, and TOC values however,
are lower than those of the Marcellus
Formation. Table 2 shows the summary of
pyrolysis, porosity and mineralogy values for
the studied formations
Figure 4 Siliceous and Argillaceous Mudstone contents
of the Burkett, Hamilton and Marcellus Formations
Using XRF, SEM and Pyrolysis for an Economic Appraisal of the Marcellus Formation of Western Pennsylvania for Fracking Purposes Presented at: AAPG 2015 Annual Convention & Exhibition, Denver, Colorado, May 3151 -June 3rd by Paul Comets; Chuck Stringers; Christian Scheibel; Albert Maende2; Erik Boice3
(1) Halliburton, Houston, TX, United States, (2) Wildcat Technologies, LLC, Humble, TX, United States (3) Noble Energy, Houston, TX, United States
Results The XRF, SEM, Pyrolysis and TOC analytical results for the Burkett, Tully, Hamilton, Marcellus, Upper Marcellus (U.M.) Transition Stand Track (TST), Lower Marcellus (L.M.) High Stand Track (HST) and Lower Marcellus Transition Stand Track (TST) are
summarized in Table 1 whereby the mean value for S1, S2, Tmax, TOC, OSI (Jarvie and Baker, 1984), HI, Porosity, Siliceous Mudstone, Argillaceous Mudstone and Carbonate contents are displayed. Maturity wise, a Tmax of less than 430°C is deemed to
indicate immaturity (Peters, 1986) while the Oil window is delineated by a 430 to 455° C range with the Condensate/Wet Gas zone falling within the 455 to 475° C range (Jarvie, 2012). The Dry Gas to Post Mature zone is at temperatures greater than 475° C.
Table 1. Mean 51, S2, Tmax, TOC, OSI, HI, Porosity, Siliceous Mudstone, Argillaceous Mudstone and Carbonate contents for the Burkett, Tully, Hamilton, Marcellus, Upper Marcellus (U.M.) TST, Lower Marcellus (L.M.) HST and Lower Marcellus TST
Formation
"Er
Dep. ift) Corrected
illr Sl-f ree Oil
(ingHC/g
rack)
)Se- ImPHC/13
rock)
, S' !r:', "n
Maturity
TOC (Total
Organic
Carbon)
(wt. %)
Oil Oil
Saturation
Index
151/TOC x
1001
HI
Hydrogen
Index
(52/TOC a
1001 mg
Hug TOC
Mr
LisPorosity
' -
LiS_Siliceous
Mudstone.
. Argillaceous
Mudstone .
1=
. .
'S-Csr'nste
Burkett_rnea n 6246.756275.8 5.00 6.41 470 7.16 70 89 66.92 32.78 0.34
Tully 6260.45 2.5 2.89 071 3.37 74 86 19.7 77.9 2.3
Ha mnItonnlea n 6280.25-6302.05 1.63 2.19 066 2.33 66 67 16.27 43 00.63
Ma rtes I usrnea n 6320.4-6327.7 4.42 5.51 463 6.12 78 85 1.08 20.4 62.86 15.52
U. M TST_mea n 6329 5-633 5 6.35 867 458 9.16 69 94 1.5 19.73 76.53 2.07
L.M HST_nlea n 6354.656356.5 9.6 4.36 066 5.97 159 73 1.1 19.05 79.15 0.65
L M TST_Inea n 6359.356373.2 8.72 10.93 060 11.75 81 90 4.57 02.61 4107 11.69
Ononda ga_rnea n 6375.7-6378.9 2.36 5.21 430 5.33 45 144
Hunters, I I e_nlea n 6381.6 0.13 0.17 331 0.49 27 35
From Table 1, it can be seen that all the represented formations, except for the Huntersville, have a TOC of
at least 2%, which happens to be what is considered to be the minimum TOC required for a viable shale
oil or shale gas resource system. The Lower Marcellus (L.M.) TST not only contains the highest TOC but also the highest porosity, S1 and S2 values. Therefore, it appears to have the greatest free oil content as
well as the greatest kerogen generation potential while the second in rank for these TOC, 51 and 52
parameters is the Upper Marcellus (U.M.) 1ST. The data identifies the Lower Marcellus TST and the
Burkett as containing a siliceous mudstone content exceeding 40% (by weight). All of the formations are
within the Condensate/Wet Gas zone. The maturity data for the Onondaga and Huntersville samples are
not indicative of these formation's actual maturity due to their very low yield of hydrocarbons from
kerogen (S2 parameter) which makes their Tmax maturity measurement to be unreliable. Fr“. MI. P.m 71.K DK and PermAy M SlAntHornlhon end %Want Fennitrent
Figure 3. Free oil (51), kerogen yield
(S2), TOC and porosity of the Burkett, Hamilton and Marcellus Formations
The free oil (S1), kerogen yield (52), TOC and porosity of the Burkett, Hamilton and Marcellus Formations are plotted in Figure 3 where it is evident that these three parameters parallel each other
but are at their highest within the Lower Marcellus TST. Figure 3 also shows a gradual reduction trend in S1 values in conjunction with sudden increase in porosity as the Lower Marcellus TST is
drilled deeper. Evidently this S1 trend shows free oil within macropores of the Lower Marcellus TST migrating downward to the Onondaga Formation. This migration is attributed to the down-hole
increasing content of siliceous radiolaria that, in turn, created increased porosity through diagenesis.
Table 2. Summary of pyrolysis, porosity and mineralogy values for the
Burkett, Tully, Hamilton, Marcellus, Upper Marcellus (U.M.) TST,
Lower Marcellus (L.M.) HST and Lower Marcellus TST.
lir Depth (k) Corrected
ilr 51-Free Oil
(mgHC/6 rock)
2Perogen
Yield
(mgHC/6 rock)
llr 53
(mgCO2/3 rock)
Tmax-
Maturity
(( 'C)
TOC
(Total
Organic Carbon) (wt %)
Production
Index
(51/51+52)
051
Oil Saturation
Index
(51/TOC x 100)
HI
Hydrogen
Index
(52/TOC x
100) mg HC/g TOC
1
Oxy
0
gen
Index
(S3/TOC
x100)
mg
CO23
,is2or,6i,
TOC
LiS_Siliceous
Mudstone.
LiS_Argillaceous
Mudstone* LiS Carbonate*
j
0.34
Formation
L AIL Burkett_mean 6246.75-6275.8 5.00 6.41 0.18 470 7.16 0.44 70 89 2 66.92 32.78
Range for 6 samples 4.05-6.24 5.37-7.69 0.13-0.22 468-473 6.28-8.20 0.39-0.49 61-83 85-94 2-3 52-80 19-38 0.1-0.5
Tully 6260.45 2.5 2.89 0.15 471 3.37 0.46 74 86 4 19.7 77.9 2.3
Hamilton_mean 6284.25-6302.05 1.63 2.19 0.23 466 2.33 0.51 66 67 26 16.27 43 40.63
Range for 3 samples 0.25-3.89 0.21-5.86 0.22-0.26 464-467 0.53-5.54 0.40-0.60 47-82 40-106 'l 4-49 15.3-16.9 28.4-55.2 27.9-56.1
Marcel I us_mean 6320.4-6327.7 4.42 5.51 0.208 463 6.12 0.48 78 85 7 1.08 20.4 62.86 15.52
Range for 6 samples 1.33-7.56 1.11-9.89 0.16-0.25 461-466 1.44-10.65 0.42-0.55 66-92 73-89 2-16 0.1-2.5 10.8-30.7 33.4-85.3 2.5-51.3
U.M.TST mean 6329.5-633.5 6.35 8.665 0.2075 458 9.16 0.42 69 94 2 1.5 19.73 76.53 2.07
Range for 4 samples 4.08-8.06 5.73-9.97 0.16-0.27 457-459 6.4410.26 0.40.0.46 63-79 8997 2-3 0.7-2.1 18.8-20.9 75.8-77.4 1.2-2.1
L.M HST_mear 6354.65-6356.5 9.6 4.355 0.13 466 5.97 0.68 159 73 2 1.1 19.05 79.15 0.65
Range for 2 samples 7.33-11.87 3.97-4.74 0.12-0.14 464468 5.36-6.58 0.65-0.71 137-180 72-74 2-3 0.8-1.4 18.419.7 77.9-80.4 0.40.9
L.M. TST_mear 6359.35-6373.2 8.72 10.93 0.16 464 11.75 0.45 81 90 2 4.57 42.61 41.07 11.69
Range for 9 samples 1.9-12.04 2.37-17.16 0.11-0.21 456-486 3.11-17.32 0.33-0.72 31-101 73-101 1-7 0.2-11.1 13.458.6 1.480.7 0.6-65.6
Onondaga_mean 6375.7-6378.9 2.36 5.21 0.24 430 5.33 0.28 45 144 34
Range for 3 samples 0.17-6.56 0.32-13.37 0.17-0.34 385-455 0.39-14.85 0.16-0.35 44-49 82-261 ' 1-54
Hunte rsyl I le mean 6381.6 0.13 0.17 0.27 331 0.49 0.43 27 35 55
1-.N.AL r
AAPG 2015 Annual Convention & Exhibition, Denver, Colorado, May 315t - June 3rd www.wildcattechnologies.com
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Using XRF, SEM and Pyrolysis for an Economic Appraisal of the Marcellus Formation of Western Pennsylvania for Fracking Purposes Presented at: AAPG 2015 Annual Convention & Exhibition, Denver, Colorado, May 31" -June 3 rd by Paul Comets; Chuck Stringers; Christian Scheibe'; Albert Maende2; Erik Boice3
(1) Halliburton, Houston, TX, United States, (2) Wildcat Technologies, LLC, Humble, TX, United States (3) Noble Energy, Houston, TX, United States
Illustrated here (Figure 5) are core images, mineralogy
and porosity of samples from the Burkett, Tully,
Hamilton, Marcellus, Upper Marcellus TST, Lower
Marcellus HST and Lower Marcellus TST together with
the pertinent comments rating their prospective
hydrocarbon zones.
Figure 5. Core images, mineralogy and porosity of
samples from the Burkett, Tully, Hamilton, Marcellus,
Upper Marcellus TST, Lower Marcellus HST and Lower
Marcellus TST together with the pertinent comments
rating their hydrocarbons prospectivity. *Note:
Formations core images, mineralogy and porosity
analyses by Halliburton's LithoSCAN®.
Figure 6 is a chart of the geochemical and mineralogical characterization of the well bore XRF,
SEM-EDX and pyrolysis results. As illustrated by the data, the ASA profile provides, among other
things, in-depth formation information about structural behavior and mineralogical content as
well as potential hydrocarbon zones. This information also aids in further division of the
recognized formation into chemostratigraphic units based on the rock behavior and content. For
instance, the illustration of the brittleness in the RBI column reveals rock mechanics based on
mineralogy within the respective formations that could conceivably accept efficient frac stage
placement (red). Areas in green are characterized as highly ductile and are at risk for problems
associated with frac stage placement in clay-rich formation zones.
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Figure 6. Profile of the geochemical and mineralogical characterization of the well bore XRF, SEM-EDX
and pyrolysis results
Acknowledgements We are grateful to Noble Energy, Halliburton and Wildcat
Technologies for allowing the publication of this study.
We also wish to thank AAPG for giving us this opportunity to
make our presentation.
Conclusions
In conclusion, an appraisal of the Marcellus Formation of Western Pennsylvania and West Virginia was performed for purposes of determining its best
producible hydrocarbons-bearing facies and suitable landing zone. This appraisal was motivated by the need to understand the peculiar geological,
geochemical and petrophysical properties of unconventional resource systems using a more economical method that can "ground truth" data obtained
by down-hole tools and other sources. In these systems the organic-rich source rock that is usually a shale, either simultaneously serves as the reservoir
or is part of a source-reservoir hybrid system, that consists of a variety of combinations of interbedded shale, limestone, dolomite, siltstone and
sandstone rocks. At this time, a limited suite of MWD/LWD tools was employed while drilling in these systems. The same was true for wire-line logging
after the well was drilled. This economic appraisal effectively demonstrates that analyses of drilled rock cuttings by using the Advanced Sample Analysis
(ASA) methodology is an economical alternative for generating the data required for identifying the best producible hydrocarbons-bearing facies and
suitable frac stage placement.
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Jarvie, D.M. & Baker, D.R.; 1984. Application of the Rock-Eval III oil show analyzer to the study of gaseous hydrocarbons in an Oklahoma gas well: 187th ACS National Meeting,
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Evalforfindingbypassedpayzones.pdf.
Loucks, R.G., Reed, R.M., Ruppel, S.C. and Hammes, U.; 2012. Spectrum of pore types and networks in Mudrocks and a descriptive classification for matrix-related mudrock
pores. AAPG Bulletin, 96/6, p.1071-1098.
Peters, K. E., 1986, Guidelines for Evaluating Petroleum Source Rock Using Programmed Pyrolysis, AAPG Bull. v. 70, No. 3, p. 318-329.
Wrightstone, g., 2009, Marcellus Shale - Geologic Controls on Production: Search and Discovery Article # 10206 (2009), AAPG.
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