MTA EnergiatudomMTA EnergiatudomMTA EnergiatudomMTA EnergiatudomMTA EnergiatudomMTA EnergiatudomMTA EnergiatudomMTA Energiatudomaacuteaacuteaacuteaacuteaacuteaacuteaacuteaacutenyi Kutatnyi Kutatnyi Kutatnyi Kutatnyi Kutatnyi Kutatnyi Kutatnyi Kutatoacuteoacuteoacuteoacuteoacuteoacuteoacuteoacutekkkkkkkkoumloumloumloumloumloumloumloumlzpontzpontzpontzpontzpontzpontzpontzpont
Katalitikus Katalitikus Katalitikus Katalitikus Katalitikus Katalitikus Katalitikus Katalitikus eacuteeacuteeacuteeacuteeacuteeacuteeacuteeacutes sugs sugs sugs sugs sugs sugs sugs sugaacuteaacuteaacuteaacuteaacuteaacuteaacuteaacuterkrkrkrkrkrkrkrkeacuteeacuteeacuteeacuteeacuteeacuteeacuteeacutemiai eljmiai eljmiai eljmiai eljmiai eljmiai eljmiai eljmiai eljaacuteaacuteaacuteaacuteaacuteaacuteaacuteaacuterrrrrrrraacuteaacuteaacuteaacuteaacuteaacuteaacuteaacutesok sok sok sok sok sok sok sok
a ka ka ka ka ka ka ka koumloumloumloumloumloumloumloumlrnyezetvrnyezetvrnyezetvrnyezetvrnyezetvrnyezetvrnyezetvrnyezetveacuteeacuteeacuteeacuteeacuteeacuteeacuteeacutedelembendelembendelembendelembendelembendelembendelembendelemben
TakTakTakTakTakTakTakTakaacuteaacuteaacuteaacuteaacuteaacuteaacuteaacutecs Erzscs Erzscs Erzscs Erzscs Erzscs Erzscs Erzscs Erzseacuteeacuteeacuteeacuteeacuteeacuteeacuteeacutebetbetbetbetbetbetbetbet
MTA 2013 februMTA 2013 februMTA 2013 februMTA 2013 februMTA 2013 februMTA 2013 februMTA 2013 februMTA 2013 februaacuteaacuteaacuteaacuteaacuteaacuteaacuteaacuter 27r 27r 27r 27r 27r 27r 27r 27
Az elfogyasztott gyoacutegyszerek jelentős
haacutenyada nem sziacutevoacutedik fel hanem
kivaacutelasztoacutedik eacutes a vizelettel szennyviacutezbe majd
a szennyviacutez tisztiacutetoacutekba jut
Az erősen toxikus szennyezők mint a
gyoacutegyszer molekulaacutek nehezen bonthatoacuteak a
szennyviacuteztisztiacutetaacutesra hagyomaacutenyosan
alkalmazott moacutedszerekkel
Szerves szennyezSzerves szennyezőők gyk gyoacuteoacutegyszer molekulgyszer molekulaacuteaacutek k az az eacuteeacutellőővizekbenvizekben
Pharmaceuticals detected in environment(Data collected from 132 publications between 1997 and 2009)
Lucia HMLM Santos AN Araujo Adriano Fachini A Pena C Delerue-Matos MCBSM Montenegro Journal of Hazardous Materials 175 (2010) 45ndash95
Max konc ngl Orszaacuteg
Lipid szabaacutelyozoacutek
Bezafibrate 27 Neacutemeto
Cofibric acid
165 Neacutemeto
270 Neacutemeto
170 Neacutemeto
53 Olaszo
Gemfibrozil 70 Kanada
Laacutez- eacutes
faacutejdalomcsillapiacutetoacutek
Diclofenac 6 Neacutemeto
Ibuprofen 3 Neacutemeto
Phenazone250 Neacutemeto
400 Neacutemeto
Propylphenazone80 Neacutemeto
120 Neacutemeto
Antibiotikum Tylosin 17 Olaszo
Antiepilektikum Carbamazepine24 Kanada
258 USA
Citosztatikum Bleomycin 13 Anglia
Antipszichosztatikumok Diazepam10 Anglia
235 Olaszo
Gyoacutegyszervegyuumlletek koncentraacutecioacuteja az ivoacuteviacutezben
bullbullOHOH
bull Advanced Oxidation Processes (AOPs) ndashnagyhateacutekonysaacuteguacuteoxidaacutecioacutes eljaacuteraacutesok OH gyoumlk segiacutetseacutegeacutevel bontjaacutek le a toxikus vegyuumlleteket
Ezen eljaacuteraacutesok keacutemiai fotokeacutemiai fotokatalitikus eacutes elektrokeacutemiai moacutedszerek melyek koumlzoumls jellemzőkeacutent a rendkiacutevuumll reaktiacutev hidroxilgyoumlk (OH) keacutepzeacuteseacuten alapszanak Iacutegeacuteretes koumlrnyzetbaraacutet technoloacutegiaacutek melyek alkalmasak kis mennyiseacutegben toxikus eacutes bioloacutegiai kezeleacutessel nem eliminaacutelhatoacute vegyuumlleteket tartalmazoacute szennyviacutezek kezeleacuteseacutere
A hidroxilgyoumlkoumlk keacutemiai koumlteacuteseket szakiacutetanak fel
bullbullbullbullbullbullbullbullbullbullbullbullOHOHOH
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Az elfogyasztott gyoacutegyszerek jelentős
haacutenyada nem sziacutevoacutedik fel hanem
kivaacutelasztoacutedik eacutes a vizelettel szennyviacutezbe majd
a szennyviacutez tisztiacutetoacutekba jut
Az erősen toxikus szennyezők mint a
gyoacutegyszer molekulaacutek nehezen bonthatoacuteak a
szennyviacuteztisztiacutetaacutesra hagyomaacutenyosan
alkalmazott moacutedszerekkel
Szerves szennyezSzerves szennyezőők gyk gyoacuteoacutegyszer molekulgyszer molekulaacuteaacutek k az az eacuteeacutellőővizekbenvizekben
Pharmaceuticals detected in environment(Data collected from 132 publications between 1997 and 2009)
Lucia HMLM Santos AN Araujo Adriano Fachini A Pena C Delerue-Matos MCBSM Montenegro Journal of Hazardous Materials 175 (2010) 45ndash95
Max konc ngl Orszaacuteg
Lipid szabaacutelyozoacutek
Bezafibrate 27 Neacutemeto
Cofibric acid
165 Neacutemeto
270 Neacutemeto
170 Neacutemeto
53 Olaszo
Gemfibrozil 70 Kanada
Laacutez- eacutes
faacutejdalomcsillapiacutetoacutek
Diclofenac 6 Neacutemeto
Ibuprofen 3 Neacutemeto
Phenazone250 Neacutemeto
400 Neacutemeto
Propylphenazone80 Neacutemeto
120 Neacutemeto
Antibiotikum Tylosin 17 Olaszo
Antiepilektikum Carbamazepine24 Kanada
258 USA
Citosztatikum Bleomycin 13 Anglia
Antipszichosztatikumok Diazepam10 Anglia
235 Olaszo
Gyoacutegyszervegyuumlletek koncentraacutecioacuteja az ivoacuteviacutezben
bullbullOHOH
bull Advanced Oxidation Processes (AOPs) ndashnagyhateacutekonysaacuteguacuteoxidaacutecioacutes eljaacuteraacutesok OH gyoumlk segiacutetseacutegeacutevel bontjaacutek le a toxikus vegyuumlleteket
Ezen eljaacuteraacutesok keacutemiai fotokeacutemiai fotokatalitikus eacutes elektrokeacutemiai moacutedszerek melyek koumlzoumls jellemzőkeacutent a rendkiacutevuumll reaktiacutev hidroxilgyoumlk (OH) keacutepzeacuteseacuten alapszanak Iacutegeacuteretes koumlrnyzetbaraacutet technoloacutegiaacutek melyek alkalmasak kis mennyiseacutegben toxikus eacutes bioloacutegiai kezeleacutessel nem eliminaacutelhatoacute vegyuumlleteket tartalmazoacute szennyviacutezek kezeleacuteseacutere
A hidroxilgyoumlkoumlk keacutemiai koumlteacuteseket szakiacutetanak fel
bullbullbullbullbullbullbullbullbullbullbullbullOHOHOH
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Pharmaceuticals detected in environment(Data collected from 132 publications between 1997 and 2009)
Lucia HMLM Santos AN Araujo Adriano Fachini A Pena C Delerue-Matos MCBSM Montenegro Journal of Hazardous Materials 175 (2010) 45ndash95
Max konc ngl Orszaacuteg
Lipid szabaacutelyozoacutek
Bezafibrate 27 Neacutemeto
Cofibric acid
165 Neacutemeto
270 Neacutemeto
170 Neacutemeto
53 Olaszo
Gemfibrozil 70 Kanada
Laacutez- eacutes
faacutejdalomcsillapiacutetoacutek
Diclofenac 6 Neacutemeto
Ibuprofen 3 Neacutemeto
Phenazone250 Neacutemeto
400 Neacutemeto
Propylphenazone80 Neacutemeto
120 Neacutemeto
Antibiotikum Tylosin 17 Olaszo
Antiepilektikum Carbamazepine24 Kanada
258 USA
Citosztatikum Bleomycin 13 Anglia
Antipszichosztatikumok Diazepam10 Anglia
235 Olaszo
Gyoacutegyszervegyuumlletek koncentraacutecioacuteja az ivoacuteviacutezben
bullbullOHOH
bull Advanced Oxidation Processes (AOPs) ndashnagyhateacutekonysaacuteguacuteoxidaacutecioacutes eljaacuteraacutesok OH gyoumlk segiacutetseacutegeacutevel bontjaacutek le a toxikus vegyuumlleteket
Ezen eljaacuteraacutesok keacutemiai fotokeacutemiai fotokatalitikus eacutes elektrokeacutemiai moacutedszerek melyek koumlzoumls jellemzőkeacutent a rendkiacutevuumll reaktiacutev hidroxilgyoumlk (OH) keacutepzeacuteseacuten alapszanak Iacutegeacuteretes koumlrnyzetbaraacutet technoloacutegiaacutek melyek alkalmasak kis mennyiseacutegben toxikus eacutes bioloacutegiai kezeleacutessel nem eliminaacutelhatoacute vegyuumlleteket tartalmazoacute szennyviacutezek kezeleacuteseacutere
A hidroxilgyoumlkoumlk keacutemiai koumlteacuteseket szakiacutetanak fel
bullbullbullbullbullbullbullbullbullbullbullbullOHOHOH
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Max konc ngl Orszaacuteg
Lipid szabaacutelyozoacutek
Bezafibrate 27 Neacutemeto
Cofibric acid
165 Neacutemeto
270 Neacutemeto
170 Neacutemeto
53 Olaszo
Gemfibrozil 70 Kanada
Laacutez- eacutes
faacutejdalomcsillapiacutetoacutek
Diclofenac 6 Neacutemeto
Ibuprofen 3 Neacutemeto
Phenazone250 Neacutemeto
400 Neacutemeto
Propylphenazone80 Neacutemeto
120 Neacutemeto
Antibiotikum Tylosin 17 Olaszo
Antiepilektikum Carbamazepine24 Kanada
258 USA
Citosztatikum Bleomycin 13 Anglia
Antipszichosztatikumok Diazepam10 Anglia
235 Olaszo
Gyoacutegyszervegyuumlletek koncentraacutecioacuteja az ivoacuteviacutezben
bullbullOHOH
bull Advanced Oxidation Processes (AOPs) ndashnagyhateacutekonysaacuteguacuteoxidaacutecioacutes eljaacuteraacutesok OH gyoumlk segiacutetseacutegeacutevel bontjaacutek le a toxikus vegyuumlleteket
Ezen eljaacuteraacutesok keacutemiai fotokeacutemiai fotokatalitikus eacutes elektrokeacutemiai moacutedszerek melyek koumlzoumls jellemzőkeacutent a rendkiacutevuumll reaktiacutev hidroxilgyoumlk (OH) keacutepzeacuteseacuten alapszanak Iacutegeacuteretes koumlrnyzetbaraacutet technoloacutegiaacutek melyek alkalmasak kis mennyiseacutegben toxikus eacutes bioloacutegiai kezeleacutessel nem eliminaacutelhatoacute vegyuumlleteket tartalmazoacute szennyviacutezek kezeleacuteseacutere
A hidroxilgyoumlkoumlk keacutemiai koumlteacuteseket szakiacutetanak fel
bullbullbullbullbullbullbullbullbullbullbullbullOHOHOH
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
bullbullOHOH
bull Advanced Oxidation Processes (AOPs) ndashnagyhateacutekonysaacuteguacuteoxidaacutecioacutes eljaacuteraacutesok OH gyoumlk segiacutetseacutegeacutevel bontjaacutek le a toxikus vegyuumlleteket
Ezen eljaacuteraacutesok keacutemiai fotokeacutemiai fotokatalitikus eacutes elektrokeacutemiai moacutedszerek melyek koumlzoumls jellemzőkeacutent a rendkiacutevuumll reaktiacutev hidroxilgyoumlk (OH) keacutepzeacuteseacuten alapszanak Iacutegeacuteretes koumlrnyzetbaraacutet technoloacutegiaacutek melyek alkalmasak kis mennyiseacutegben toxikus eacutes bioloacutegiai kezeleacutessel nem eliminaacutelhatoacute vegyuumlleteket tartalmazoacute szennyviacutezek kezeleacuteseacutere
A hidroxilgyoumlkoumlk keacutemiai koumlteacuteseket szakiacutetanak fel
bullbullbullbullbullbullbullbullbullbullbullbullOHOHOH
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
bullbull KatalKataliacuteiacuteziszis
bullbull Nedves oxidNedves oxidaacuteaacutecicioacuteoacute katalitikus nedves oxid katalitikus nedves oxidaacuteaacutecicioacuteoacute
bullbull EEB (ionizB (ionizaacuteaacutelloacuteoacute sugsugaacuteaacuterzrzaacuteaacutes)s)
bullbull KombinKombinaacuteaacutelt mlt moacuteoacutedszerekdszerek a fenti ma fenti moacuteoacutedszerek dszerek
kombinkombinaacuteaacutellaacuteaacutesasa
IntInteacuteeacutezetzetuumluumlnkben folynkben folyoacuteoacute kutatkutataacuteaacutesok a sok a gygyoacuteoacutegyszerek lebontgyszerek lebontaacuteaacutessaacuteaacutera vizes oldatbanra vizes oldatban
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
NemesfNemesfeacuteeacutemoxidTi hmoxidTi haacuteaacutelloacuteoacutekatalizkatalizaacuteaacutetoroktorok
Kereskedelmi
Ru-Ir oxid bevonatuacute Ti haacuteloacute katalizaacutetor
(Magneto BV Hollandia)
Sajaacutet keacutesziacuteteacutesű
Ru oxid
Pd oxid
Ru-Ir oxid (keacutemiailag tisztiacutetott Ti haacuteloacutera felvitt)
Ru-Ir oxid
Ir-Ta oxid (mechanikusan homokfuacutevaacutessal tisztiacutetott Ti haacuteloacutera felvitt)
Hungarian patent application P 08 00677
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumlletelete
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Kereskedelmi RuKereskedelmi Ru--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute felfeluumluumllete lete kb 200 kb 200 oacuteoacutera hasznra hasznaacuteaacutelat utlat utaacuteaacutenn
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (k(keacuteeacutemiai tisztmiai tisztiacuteiacutettaacuteaacutes) fels) feluumluumlletelete
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
RuRu--Ir oxidTi hIr oxidTi haacuteaacutelloacuteoacute (mechanikusan (mechanikusan tiszttisztiacuteiacutetott) feltott) feluumluumlletelete
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
A Ti haacuteloacute katalizaacutetorok oumlsszehasonliacutetaacutesa
TOC ndashtotal organic carbon content
TOC csoumlkkeneacutes egy ipari szennyviacutez (7) (a)
eacutes fenolaacutet oldat oxidaacutecioacutejaacuteban (b) kuumlloumlnboumlző monolit katalizaacutetorokkal
a) 230 oC 50 bar b ) 200 oC 50 bar
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
IONIZIONIZAacuteAacuteLLOacuteOacute SUGSUGAacuteAacuteRZRZAacuteAacuteSS
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Forraacutesok eacutes moacutedszerek a degradaacutecioacute eacutes koumlveteacuteseacutere
Gammaforraacutes Analiacutezis UV-VIS HPLC
KOI BOI TOC Microtox toxicitaacutes (Vibrio fischeri)
EB ndash elektron gyorsiacutetoacute
Impulzusradioliacutezis meacuterőegyuumlttes
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Hiacuteg vizes oldatokban a sugaacuterzaacutes elsődleges hataacutesa a viacutez radioliacutezise
H2O rarr
bullH eaq
minus bullOH H+ OHminus H2O
2 H
2
G (bullH) = 006 microm J-1 G(bullOH) = 028 microm J-1 G(eaqminus) = 028 microm J-1
Radioliacutezis vizes oldatban
oxigoxigeacuteeacuten jelenln jelenleacuteeacutetteacuteeacutebenben
Szuperoxid gyoumlkanion (O2minusbull) eacutes perhidroxil gyoumlk (HO2
bull)
eaqminus +O2 rarr O2
minusbull k = 12 times 1010 molndash1 dm3 sndash1
Hbull + O2 rarr HO2bull k = 19 times 1010 molndash1 dm3 sndash1
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
OH
NaO
CH3
OH
CH3
OH
CH3
OH
Cl
OH
Cl
OH
Cl
OH
OH
O
O
ClCl
O
CH3O
OHO
CH3
OH
O
O
O
CH3
NHOH
Na
O
O
O
S
Na
OO
O
S
N
N
NH2
OH
NH2
OH
NH2
OH
CH3
ONH
OH
Cl
Cl
NH
OH
O
Cl Cl
NH2 CH3
O
O CH3
OH
OH
OH
OH
O
OH
O
OH
O
OH
O
OH
O
OH
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
0
500 000
1 000 000
1 500 000
2 000 000
2 500 000
Ibuprofen
Num
ber
of
boxes s
old
2001
2005
Ibuprofen (IBP)
bull nem-szteroid gyulladaacutesgaacutetloacute
(NSAID)
bull faacutejdalom csillapiacutetoacute
bull Advil Algoflex Nurofen
Rhinathiol Ibustar
(RS)-2-[4-(2-metilpropil)fenil]propaacutensav
M Farreacute D Barceloacute Toxicity testing of wastewater and sewage sludge by biosensors bioassays and chemical analysis Trends in Analytical Chemistry Vol 22 No 5 (2003)
Applications of radiation chemistry to understand the fate and transport of emerging pollutants of
concern in coastal waters by Kimberly Greenwood Jones 2007
OH
O
Illeacutes E Takaacutecs E Dombi A Gajda-Schrantz
K Raacutecz G Gonter K Wojnaacuterovits L
Hydroxyl radical induced degradation of
ibuprofen Science of the Total Environment
447 286ndash292 (2013)
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
200 250 300 350 400 45000
05
10
15
20
Abs
orba
nce
Wavelength nm
0 kGy
025 kGy05 kGy
075 kGy15 kGy
1 kGy
00 05 10 1500
02
04
06
08
10
Rel
co
ncen
trat
ion
Dose kGy
UV spektrumok N2O-dal teliacutetett 1 times 10minus4 mol dmminus3 IBP oldatban (bullOH
reakcioacute) pH sim44 Inset IBP koncentraacutecioacute vaacuteltozaacutesa a doacutezissal (HPLC
elvaacutelasztaacutes utaacuten dioacutedasoros detektaacutelaacutessal meacutert kromatograacutefaacutes csuacutecsok
integraacutelja)
HPLC-diode array detection
H3C
OH
CH3
O
CH3
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
CH3
O
CH3
O
OHO
CH3
CH3
CH3
CH3
CH3
CH3 OH
CH3
O O
OHO
OH
CH3
CH3
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OH
CH3
CH3
CH3
OH
O
OHOH
(1) mz 133 (2) mz 149 (3) mz 175 (4) mz 177
(6) mz 177 (8) mz 221(7) mz 221(5) mz 177
(9) mz 237
H3C
OH
CH3
O
CH3
1timestimestimestimes10-4 mol dm-3 ibuprofen solution
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
A degradaacutecioacutes termeacutekek azonosiacutetaacutesa
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Toxicity measured by Microtox (inhibition of Vibrio
fischeri)110-4 mol dm-3 air saturated ibuprofen solution gamma-radiolysis
0 1 2 3 40
5
10
15
20
25
30
35
40IBP 1 x 10-4 mol dm-3
Dose kGy
Inh
ibit
ion
00
05
10
cc
0
00 05 10 15 200
20
40
60
80
100
120
140
160
180 1633
1839
2303
2533
8997
Ab
so
rban
ce
Dose kGy
Changes of fluorescence inhibition in Vibrio fisheri toxicity test and the relative concentration of unaltered IBP molecules as a function of dose measured in 1x10-4 mol dmminus3 air saturated IBP solution (bullOH + O2
minusbullHO2bull reaction)
HPLC-diode array
detection
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
TOTAL COLIFORM AND FECAL COLIFORM VALUES MEASURED WITH
SAMPLES FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER
BIOLOGICAL TREATMENT BEFORE STERILIZATION AND AFTER
STERILIZATION BY CHLORINE TREATMENT OR IRRADIATION
SampleFree Cl
mg dm-3
Total Cl
mg dm-3
Dose
kGy
Total
Coli
Fecal
Coli
Fec C
Total C
I01 - - - 730 75 102
IICl1 007 009 - 560 52 93
Irad1
- - 05 1 0 -
- - 1 1 0 -
- - 20 0 0 -
I02 - - - 900 90 99
IICl2 lt005 006 - 700 80 114
Irad2
- - 05 0 0 -
- - 1 0 0 -
- - 20 0 0 -
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
COMPARISON OF CODK AND BOD5 VALUES MEASURED WITH SAMPLES
FROM A MUNICIPAL WASTEWATER TREATMENT PLANT AFTER BIOLOGICAL
TREATMENT BEFORE DISINFECTIONAND AFTER DISINFECTION BY
CHLORINE TREATMENT OR IRRADIATION
Sample TreatmentCODk
mg dm-3
BOD5
mg dm-3
BOD5CODk
I01 - 46 16 35
IICl1 Cl 62 16 26
Irad1
05 kGy 36 lt10 (6) lt17
1 kGy 32 lt10 (8) lt25
20 kGy 36 lt10 (5) lt14
I02 - 53 17 32
IICl2 Cl 58 15 26
Irad2
05 kGy 31 lt10 (7) lt23
1 kGy 39 lt10 (7) lt18
20 kGy lt30 (28) lt10 (5) lt18
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
25
Nedves oxidaacutecioacute eacutes sugaacuterzaacutes (20 bar oxigeacuten)
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
Erősen toxikus szennyviacutez
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Compounds m
TOFISOPAM 119
METHANOL 31
AMMON Cl 92
ACETIC ACID 1364
WATER 4486
0 2 4 6 8 10 12 14 163800
4000
4200
TO
C m
g dm-3C
OD
mg
dm-3
Dose kGy
TOC
COD
1100
1200
1300
1400
O CH3
OCH3
CH3
CH3
N
NH3C
O
H3CO
20 bar O2
Gyoacutegyszergyaacuteri szennyviacutez kezeleacutese
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Az ionizaacuteloacute sugaacuterzaacutest alkalmazoacute viacutez eacutes szennyviacutez kezeleacutesi technoloacutegiaacutek előnyei
oEnergia takareacutekos eacutes koumlrnyezet kiacutemeacutelő
o Nincs szuumlkseacuteg adaleacutekra koumlnnyű automatizaacutelni
o Elsziacutenteleniacuteti a szennyvizet bontja a konjugaacutelt
rendszereket sziacutencentrumokat
o Sugaacuterkeacutemiai uacuteton szagtalaniacutet
oFertőtleniacutet a mikroorganizmusok DNA-jat roncsolja
oA kezelt szennyviacutez hasznaacutelhatoacute pl oumlntoumlzeacutesre
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
Wastewater TreatmentFlue gas Purification Sludge Disinfection
Az ionizaacuteloacute sugaacuterzaacutes koumlrnyezetveacutedelmi alkalmazaacutesai
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
bullWojnaacuterovits L Takaacutecs E Irradiation treatment of azo-dye containing wastewater an overview Radiat Phys Chem 77 225-244 (2008) bullMelo R Leal J P Takaacutecs E Wojnaacuterovits L Radiolytic degradation of gallic acid and its derivatives in aqueous solution J Hazard Mater 172 1185-1192 (2009)bullHomlok R Takaacutecs E Wojnaacuterovits L Elimination of diclofenac from wastewater using irradiation technology Chemosphere 85 603-608 (2011)bullCsay T Raacutecz G Takaacutecs E Wojnaacuterovits L Radiation degradation of pharmaceutical residues in water chloramphenicol Radiat Phys Chem81 1489-1494 (2012) bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Gonter K Wojnaacuterovits L Radiation induced degradation of ketoprofen in dilute aqueous solution Radiat Phys Chem 81 1479-1483 (2012) bullChamam M Foumlldvaacutery CM Hosseini AM Tungler A Takaacutecs E Wojnaacuterovits L Mineralization of aqueous phenolate solutions a combination of irradiation treatment and wet oxidation Radiat Phys Chem 81 1484-1488 (2012)
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
bullSzaboacute L Toacuteth T Homlok R Takaacutecs E Wojnaacuterovits L Radiolysis of paracetamol in dilute aqueous solution Radiat Phys Chem 81 1503-1507 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Ionizing radiation induced reactions of 26-dichloroaniline in dilute aqueous solution Radiat Phys Chem 81 1499-1502 (2012) bullHomlok R Takaacutecs E Wojnaacuterovits L Degradation of organic molecules in advanced oxidation processes Relation between chemical structure and degradability Chemosphere DOI 101016jchemosphere201211073bullIlleacutes E Takaacutecs E Dombi A Gajda-Schrantz K Raacutecz G Gonter K Wojnaacuterovits L Hydroxyl radical induced degradation of ibuprofen Science of the Total Environment 447 286ndash292 (2013)
A teacutemaacutehoz kapcsoloacutedoacute neacutehaacuteny uacutejabb koumlzlemeacuteny
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI
KKoumloumlszszoumloumlnetnet
Wojnaacuterovits LaacuteszloacuteTungler AntalCsay TamaacutesIlleacutes Erzseacutebet
Nemzetkoumlzi Atomenergia UumlgynoumlkseacutegOTKA 60096 80154 the Swiss-Hungarian project SH214
Salvatore Silvano Emmi (Bologna)Rita Paiva Melo (Lisszabon)Bumsoo Han (Daejon Korea)Sunil Sabharwal (IAEA Beacutecs)
Homlok RenaacutetaRaacutecz GergelySzaboacute LaacuteszloacuteSaacutegi Gyuri
Dombi Andraacutes Szegedi EgyetemMakoacute Magdolna FCsMToacuteth Tuumlnde BME VBK
Homonnay Zoltaacuten ELTE KI