Lecture 7
Chapter 3
Electromagnetic Theory, Photons.and Light
Sources of light Emission of light by atoms The electromagnetic spectrum – see supplementary material Light in bulk matter and dispersion
Sources of light
Linearly accelerating charge
Synchrotron radiation—light emitted by charged particles deflected by a magnetic field
Bremsstrahlung (Braking radiation)—light emitted when charged particles collide with other charged particles
Accelerating charges emit light
B
Synchrotron radiation: Advanced Photon Source
Argonne National Lab, Chicago, IL
http://www.aps.anl.gov/
1104 m circumference storage ring
The vast majority of light in the universe comes from molecular vibrations emitting light.
Electrons vibrate in their motion around nucleiHigh frequency: ~1014 - 1017 cycles per second.
Nuclei in molecules vibrate with respect to each other
Intermediate frequency: ~1011 - 1013 cycles per second.
Nuclei in molecules rotateLow frequency: ~109 - 1010 cycles per second.
Emission of light by (isolated) atoms
Quantum mechanics: electrons in atoms can only be in discreet states characterized with specific (quantized) energy
Transition of electron between discreet states with different energies causes emission or absorption of a single photon with energy matching the energy difference between the electron statesThe energy of this photon and frequency of EM wave are connected via Planck’s constant: E = h
Atomic and molecular vibrations correspond to excited energy levels in quantum mechanics.
Ene
rgy
Ground level
Excited level
E = h
The atom is at least partially in an excited state.
The atom is vibrating at frequency, .
Energy levels are everything in quantum mechanics.
Excited atoms emit photons spontaneously.
When an atom in an excited state falls to a lower energy level, it emits a photon of light.
Molecules typically remain excited for no longer than a few nanoseconds. This is often also called fluorescence or, when it takes longer, phosphorescence.
Ene
rgy
Ground level
Excited level
Different atoms emit light at different widely separated frequencies.
Frequency (energy)
Atoms have relatively simple energy level systems (and hence simple spectra).
Each colored emission line corresponds to a difference between two energy levels.
These are emission spectra from gases of hot atoms.
Atoms and molecules can also absorbphotons, making a transition from a lower level to a more excited one.
This is, of course, absorption.
Ene
rgy
Ground level
Excited level
Absorption lines in an otherwise continuous light spectrum due to a cold atomic gas in
front of a hot source.
Einstein showed that stimulated emission can also occur.
Before After
Absorption
Stimulated emission
Spontaneous emission
Molecules have many energy levels.A typical molecule’s energy levels:
Ground electronic state
1st excited electronic state
2nd excited electronic state
Ene
rgy
Transition
Lowest vibrational and rotational level of this electronic “manifold”
Excited vibrational and rotational level
There are many other complications, such as spin-orbit coupling, nuclear spin, etc., which split levels.
E = Eelectonic + Evibrational + Erotational
As a result, molecules generally have very complex spectra.
Water’s vibrations
Decay from an excited state can occur in many steps.
Ene
rgy
The light that’s eventually re-emitted after absorption may occur at other colors.
Infra-red
Visible
Microwave
Ultraviolet
The Greenhouse effectThe greenhouse effect occurs because windows are transparent in the visible but absorbing in the mid-IR, where most materials re-emit. The same is true of the atmosphere.
Greenhouse gases:
carbon dioxide water vapor
methanenitrous oxide
Methane, emitted by microbes called
methanogens, kept the early earth warm.
Visible Infra-red
Blackbody radiationBlackbody radiation is emitted from a hot body. It's anything but black!
The name comes from the assumption that the body absorbs at every frequency and hence would look black at low temperature.
It results from a combination of spontaneous emission, stimulated emission, and absorption occurring in a medium at a given temperature.
It assumes that the box is filled with molecules that, together, have transitions at every wavelength.
Blackbody emission spectrumThe higher the temperature, the more the emission and the shorter the average wavelength.
Blue hot is hotter than red hot.
The sun’s surface is 6000 degrees K, so its blackbody spectrum peaks at ~ 500 nm--in the green. However, blackbody spectra are broad, so it contains red, yellow, and blue, too, and so looks white.
Electromagnetic spectrum
See supplementary lecture notes
Light in bulk matter
Maxwell eq-ns in free space EM wave speed is00
1
c
In medium, 0 and 0 in Maxwell equation must be replaced by and and phase speed of EM wave in medium becomes slower:
1
v
Absolute index of refraction:00
vcn
Relative permittivity:
0
0
B
E
KK
Relative permeability: BE KKn
EKn Maxwell’sRelationFor nonmagnetic transparent materials KB1:
However, n depends on frequency (dispersion) and Maxwell equation works only for simple gases.
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