Transcript
  • 1. LITTER GENERATEDAMMONIA CAPTURED BYACTIVATED CARBONDERIVED FROM BROILERLITTERKari Fitzmorris Brisolara, ScD, MSPHLouisiana State University,Health Sciences CenterDana M. Miles, PhD and Isabel M. Lima, PhDUSDA Agricultural Research Service

2. RESEARCH OBJECTIVES Analyze waste sources for their potential as activatedcarbons Create activated carbons and char from broiler litterusing steam activation to minimize cost and wasteproduction. Assess the physical properties of the carbons Determine the efficacy of the activated carbon andchar with regard to ammonia adsorption usinglaboratory-based direct-measurement experimentsfollowed by manure emissions studies. 3. COLLECTION 4. CARBON 5. ACTIVATEDCARBONSPoultry Cake Carbon 2500x Poultry Litter Carbon 250x 6. COST OF SOURCE MATERIAL FORACTIVATED CARBONBiosolid cost $3 to 10 / ton plus binder - pelletized.Bituminous coal $60 to 80 / ton plus binder -pelletized. (2010 average $60.88/ton)Saving of >6 times in source material for activatedcarbon 7. ACTIVATED CARBON MARKETIt is anticipated world demand for virgin activated carbon will rise 9.9 -17 percent yearly through 2014.The global market for activated carbon is forecast to reach a marketsize of 2.3 million metric tons by the year 2017One of the main drivers of growth is mercury control technology forindustrial air purification applications to meet new emissionsstandardsThe primary uses are currently water treatment and air purification3 largest players in the industry Calgon, Norit & MeadWestvaco.Calgon reported cost of products sold increased 8.4% to $95.5 million in the thirdquarter of 2011.There are NO carbons with good metals adsorbing propertiescurrently on the market.Current value for a high quality carbon is about $1.50+/lb. 8. COMMON SOURCES FOR ACTIVATEDCARBONBituminous coalCoconut shellsAlternative Sources Nut shells (pecan, walnut) Sugarcane bagasse Soybean hulls 9. ACTIVATED CARBON FROM WASTEBiosolids Most studies only examined pyrolyzed municipalwastes no activationOther wastes Tires Paper mill waste 10. COMPARISON WITH OTHERCARBONSSample Sample DescriptionOur carbons Made from pelletized manure, steam activated under N2Coal, coconutshell or woodbasedPUR RF Replacement Filter, coal derived, 10x20 mesh, originally in block forCalgon F300 Filtrasorb 300, GAC by Calgon Carbon for removal of organicpollutants from munic/indust wastewaters. Made frombituminous coal.Made from pelletized coal, ground coconutshells/sawdust, steam activated under N2Norit Darco Hg Powdered (


Recommended