Download pdf - SAFETY DATA SHEET JMS STYLET-OIL · JMS Stylet-Oil is registered with the EPA FIFRA as a pesticide. Classifications on this SDS are not the same as the EPA label (#65564-1). Some

SAFETYDATASHEETJMSSTYLET-OIL

SECTION2:HAZARDIDENTIFICATIONSignalWord: DangerSkinIrritation: CausesmildskinirritationEyeIrritation: CauseseyeirritationAcuteToxicityOral: LD50>5,000mg/kgAcuteToxicityDermal: LD50>2,000mg/kgHazardCategories: Oral/Dermal/InhalationToxicity-5/5/5;Eye/SkinIrritation-2B/3;AspirationHazard-1HazardStatement: Maybeharmfulifswallowed Maybeharmfulincontactwithskin Causeseyeirritation Causesmileskinirritation Maybeharmfulifinhaled MaybefatalifswallowedandentersairwaysAggravatedMedicalCondition:NoneknownJMSStylet-OilisregisteredwiththeEPAFIFRAasapesticide.ClassificationsonthisSDSarenotthesameastheEPAlabel(#65564-1).SomeSectionsoftheSDSaresupersededbyFederallawforaregisteredpesticide.Section15REGULATORYINFORMATIONprovidesmoredetailedinformation.

SECTION3:INFORMATIONONINGREDIENTS:COMPONENT CASNUMBERS %byWeightWHITEMINERALOIL 64742-54-7;64742-55-8; 98.00

8042-47-5InertIngredients: Nonhazardous 2.9


SECTION4:FIRSTAIDMEASURESEye:Checkforandremovecontactlenses.DONOTuseaneyeointment.Flushthoroughlywithwater,keepingeyelidsopenforatleast15minutes.Ifirritationoccurs,seekmedicalassistance.Inhalation:Removefromfurtherexposure.Useadequaterespiratoryprotectionifassistingsomeoneaffected.Ifrespiratoryirritation,nausea,dizzinessorunconsciousnessoccurs,seekimmediatemedicalassistance.Ifbreathinghasstopped,assistventilationwithamedicaldeviceorusemouth-to-mouthresuscitation.Ingestion:DONOTinducevomitingbecauseofdangerofaspiratingliquidintolungsunlessdirectedbyaphysicianorpoisoncontrolcenter.Lowtoxicityoningestion,haslaxativeeffectandrapidlyeliminated.Physicalassessmentadvised.Skin:Removecontaminatedclothing.Removeandlaundercontaminatedclothingbeforereuse.Washcontaminatedskinwithnon-abrasivesoapandwaterforatleast15minutes.Seekmedicalattentionifrednessorirritationoccurs.

SECTION5:FIREFIGHTINGPROCEDURESEXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Do not use streams of water. FIRE FIGHTING INSTRUCTIONS: Evacuate area. Prevent run-off from fire, control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes, Carbon Monoxide, and irritating vapors. FLAMMABILITY PROPERTIES: FLASH POINT ASTM D92 (open cup typical) ° F = COC > 360 ° F


SECTION6:SPILLORLEAKHANDLINGPROCEDURESSPILLMANAGEMENT:LandSpill:Stopleakifyoucandosowithoutrisk.Recoverbypumpingorwithsuitableabsorbent. WaterSpill:Stopleakifyoucandosowithoutrisk.Confinethespillimmediatelywithbooms.Warnothershipping.Removefromthesurfacebyskimmingorwithsuitableabsorbents.Seektheadviceofaspecialistbeforeusingdispersants.ENVIRONMENTALPRECAUTIONS:Largespills:Dikefaraheadofliquidspillforlaterrecoveryanddisposal.Prevententryintowaterways,sewers,basementsorconfinedareas.Contactlocalauthoritiesregardingspills/leaks.


SECTION8:EXPOSURECONTROLS/PERSONALPROTECTIONComponentswithworkplacecontrolparameters:Containsnosubstanceswithoccupationalexposurelimitvalues.Localexhaustshouldbesufficient.ENGINEERINGMEASURES:Nospecialventilationrequirements.Goodgeneralventilationshouldbesufficienttocontrolworkerexposuretoairbornecontaminates.PERSONALPROTECTIVEEQUIPMENTRespiratoryProtection:Userespiratoryprotectionwhenadequatelocalexhaustventilationisnotprovided,orexposureassessmentdemonstratesthatexposuresarewithinrecommendedexposureguidelines.Respiratorselectionmustbebasedonknownoranticipatedexposurelevels,thehazardsoftheproductandthesafeworkinglimitsoftheselectedrespirator.Filtertype: Organicvaporfilter HandprotectionMaterial: Neoprene,nitrile,polyvinylalcohol(PVA),Viton(R)Remarks: Chemical-resistant,imperviousglovescomplyingwithanapproved

standardshouldbewornatalltimeswhenhandlingchemicalproductsifariskassessmentindicatesthisisnecessary.

EyeProtection: Ifcontactislikely,safetyglasseswithsideshieldsare recommendedSkinandbodyprotection: Anyspecificclothinginformationprovidedisbasedon publishedliteratureormanufacturerdata.Thetypesof clothingtobeconsideredforthismaterialinclude: Noskinprotectionisordinarilyrequiredundernormal conditionsofuse.Inaccordancewithgoodhygiene practices,precautionsshouldbetakentoavoidskin contactHygienemeasures: Alwaysobservegoodpersonalhygienemeasures,suchaswashing

afterhandlingthematerialandbeforeeating,drinkingand/orsmoking.Routinelywashworkclothingandprotectiveequipmenttoremovecontaminants.Discardcontaminatedclothingandfootwearthatcannotbecleaned.Practicegoodhousekeeping.

ENVIRONMENTALCONTROLS: SEESECTIONS6,7,12,13

SECTION7:HANDLINGANDSTORAGEHANDLING: Smoking,eatinganddrinkingshouldbeprohibitedintheapplicationarea. Incaseofinsufficientventilation,wearsuitablerespiratoryequipment. Avoidcontactwitheyes,skinandclothing. Donotingest. Keepawayfromsourcesofheatandignition. Keepcontainerclosedwhennotinuse.STORAGE: Storeinoriginalcontainer.Openedcontainersshouldberesealedandkeptuprighttopreventleakage. Storeindry,cool,well-ventilatedarea. Storeislabelledcontainers. Donotstoreinheatordirectsunlight. Protectfromfreezing.


SECTION9:PHYSICALANDCHEMICALPROPERTIESAppearance Clearandbrightneutral

BoilingPoint >200 °CPhysicalState LiquidOdor NoneVaporDensity(Air=1) N/APourPoint °C(F) -27(-5)FreezingPoint NDDensityat20 °C 0.85-0.862FlashPointphysical °C(F) >160(345)SeeSection5FlammableLimits LEL:NDUEL:NDViscositycStat40 °C 13AutoignitionTemperature NDVaporPressure <0.013kPa(0.1mmHg)at20 °CEvaporationRate(N-ButylAcetate=1) ND

SolubilityinWater Miscible

OxidizingProperties SeeSections3,15,16

SECTION10:STABILITYANDREACTIVITYSTABILITY: StableundernormalconditionsCONDITIONSTOAVOID: Excessiveheat.HighenergysourcesofignitionMATERIALSTOAVOID: StrongoxidizersHAZARDOUSDECOMPOSITIONPRODUCTS: DoesnotdecomposeatambienttemperaturesHAZARDOUSPOLYMERIZATION: Willnotoccur


SECTION11:TOXICOLOGICALINFORMATIONACUTETOXICITYPotentialacutehealtheffects: Inhalation: Noknownsignificanteffectsorcriticalhazards Ingestion: Noknownsignificanteffectsorcriticalhazards Skincontact:Noknownsignificanteffectsorcriticalhazards Eyecontact: NoknownsignificanteffectsorcriticalhazardsINHALATION CONCLUSION/REMARKSToxicity:LC50>5,000mg/m3 Minimallytoxic.Basedontestdataforother

structurallysimilarmaterials.Negligiblehazardatambient/normalhandlingtemperatures.Basedonassessmentofthecomponents

INGESTIONToxicity:LD50>5,000mg/kg

Minimallytoxic.Basedontestdataforstructurallysimilardata

SKIN:LD50>5,000mg/kg

Minimallytoxic.Basedontestdataforotherstructurallysimilarmaterials.Negligibleirritationatambienttemperatures.Basedontestdataforstructurallysimilarmaterials

EYE:Irritation Maycausemild,shortlastingdiscomforttoeyes.Basedontestdataforstructurallysimilarmaterials


SECTION11:TOXICOLOGICALINFORMATIONCHRONIC/OTHEREFFECTSFortheproductitself: Repeatedand/orprolongedexposuremaycauseirritationtotheskin,eyesorrespiratorytract.Baseoilseverelyrefined.Notcarcinogenicinanimalstudies.RepresentativematerialpassesIP-346,ModifiedAmestestand/orotherscreeningtests.Dermalandinhalationstudiesshowedminimaleffects;lungnon-specificinfiltrationofimmunecells,oildepositionandminimalgranulomaformation.Dermalandinhalationstudiesshowedminimaleffects.Notsensitizingintestanimals.CARCINOGENICEFFECTS:Containsnocarcinogens.Similarcompoundsessentiallynon-toxic.Nocomponentofthisproductatlevelsgreaterthan0.1%isidentifiedasacarcinogenbyACGIHortheInternationalAgencyforResearchonCancer(IARC).Nocomponentofthisproductatlevelsgreaterthat0.1%isidentifiedasacarcinogenbytheU.S.NationalToxicologyProgram(NTP)ortheU.S.OccupationalSafetyandHealthAct(OSHA),NTPofIARC.Althoughisnospecifictestdataonallthebaseoilcomponents,themineralbaseoilwouldnotbeexpectedtoexhibitcarcinogenicpotentialbasedonwhatisknownofthetoxicityofmineralbaseoilsingeneral.TheDMSOextractbyIP-346oftheoilislessthan3%(Typical0.2%withMaximum0.5%0.Consequently,itisnotclassifiedasacarcinogen.Thebaseoilinthisproductisseverelyhydro-treatedbyallhydro-processingroute.Bythisrefininghistorywouldbeshowednoevidenceofcarcinogenicpotential.MUTAGENICEFFECTS:Nocomponentofthisproductatlevelsgreaterthan0.1%isclassifiedbyestablishedregulatorycriteriaasamutagen.TERATOGENICEFFECTS/DEVELOPMENTALTOXICITY:Nocomponentofthisproductatlevelsgreaterthat0.1%isclassifiedbyestablishedregulatorycriteriaasteratogenicorembryonic.REPRODUCTIONTOXICITY:Nocomponentofthisproductatlevelsgreaterthan0.1%isclassifiedbyestablishedregulatorycriteriaasareproductivetoxin.OVER-EXPOSURESIGNS/SYMPTOMSSkin: NoknownsignificanteffectsofcriticalhazardsIngestion: NoknownsignificanteffectsofcriticalhazardsInhalation: Noknownsignificanteffectsofcriticalhazards


SECTION12:ECOLOGICALINFORMATIONTheinformationgivenisbasedondataavailableforthematerial,thecomponentsofthematerialandsimilarmaterials.ECOTOXICITY

Materialnotexpectedtobeharmfultoaquaticorganisms.MOBILITY

Miscibleinwater.Withoutagitationseparationfromwaterwilloccurwiththeoilfloatingtothewatersurface

PERSISTENCEANDDEGRADABILITYBiodegradationisinherentlyexpected

BIOACCUMULATIONPOTENTIAL Hasthepotentialtobioaccumulate,howevermetabolismorphysicalpropertiesmayreducethebioconcentrationorlimitbioavailability?ECOLOGICALDATADataforHighlyRefinedSeverelyHydrotreatedoilforsimilarmaterialsTEST Duration OrganismType TestResultsAquatic–ChronicToxicity

21days Waterflea NOELR1.05mg/l:dataforsimilar

7days Fish NOEC:>5,000mg/l(IUCLIDDataset)

7days AquaticInvertebrates NOEC:>5,000mg/l(IUCLIDDataset)

Careshouldbetakentominimizereleaseofthisproductintotheenvironment

EnvironmentalFate&DistributionPersistence&DegradationToxicityEffectonEffluentTreatment

NoDataAvailableNoDataAvailableProductmaybepartiallyremovedinbiologicaltreatmentprocesses

OtherTypical(notaspecification) AcuteToxicitytoFishEffectConcentrationonAlgaeReadyBiodegradabilityRespirationInhibitionAbsorption/DesorptionAbioticDegradability-Hydrolysis

NoDataAvailableNoDataAvailableNoDataAvailableNoDataAvailableNoDataAvailableNotmeasurable


SECTION13:DISPOSALCONSIDERATIONSDisposalmethods:ThismaterialmustbedisposedofaccordingtoFederal,Stateorlocalprocedures

undertheResourceConservationandRecoveryAct:"Empty"containersretainresidue(liquidand/orvapor)andcanbedangerous.DONOTPRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRINDOREXPOSESUCHCONTAINERSTOHEAT,FLAME,SPARKS,STATICELECTRICITY,OROTHERSOURCESOFIGNITION:THEYMAYEXPLODEANDCAUSEINJURYORDEATH.Donotattempttocleansinceresidueisdifficulttoremove."Empty"drumsshouldbecompletelydrained,properlybungedandpromptlyreturnedtoadrumreconditioner.Allothercontainersshouldbedisposedofinanenvironmentallysafemannerandinaccordancewithgovernmentalregulations.

SECTION14:TRANSPORTINFORMATIONUNProperShippingName: NotregulatedbyDOT,IATAorIMDGMarinePollutant: NotaPollutantSpecialProvisionsfortransport: NoneidentifiedThis product in non-hazardous. The product contains no known carcinogens. No special warning labels are required under OSHA 29CFR 1910.1200. OSHA hazard warnings are not applicable for this product. Therefore, no OSHA Warnings would appear on the label. No EPA hazard classification code. HS TARIFF CLASSIFICATION:2710.19.4540


SECTION15:REGULATORYINFORMATIONEurope MaterialisnotdangerousasdefinedbytheEUDangerousSubstances/PreparationsDirectives.

EULABELING:NotregulatedaccordingtoEUdirectives.MaterialisnotdangerousasdefinedbytheEUDangerousSubstances/PreparationsDirectivesClassificationandlabelinghavebeenperformedaccordingtoEUDirectives67/548/EEC,1999/45/ECand2001/58/EC(includingamendments)andtheintendeduse

UnitedStates EPASARATitleIIIChemicalListings Section302ExtremelyHazardousSubstances:None Section304CERCLAHazardousSubstances:None SARA311/312CATEGORIES

1. Immediate(Acute)HealthEffects:YES2. Delayed(Chronic)HealthEffects:NO3. FireHazard:NO4. SuddenReleaseofPressureHazard:NO5. ReactivityHazard:NO

OSHAHAZARDCOMMUNICATIONHAZARD:Whenusedforitsintendedpurposes,thismaterialisnot classifiedashazardousinaccordancewithOSHA29CFR1910.1200Canada

WHMIS(CanadianWorkplaceHazardousMaterialsInformationSystems)ThisproductwhentestedasawholeisnotacontrolledsubstancewithinthemeaningoftheHazardousProductsAct.

GermanyWaterHazardousClass(WGK):1(lowhazardtowater)NATIONALLEGISLATION/REGULATIONS Ozonedepletingchemicals:NoozonedepletingchemicalsarepresentorusedinmanufactureREGULATORYSTATUSANDAPPLICABLELAWSANDREGULATIONS Complieswiththefollowingnational/regionalchemicalinventoryrequirements:DSL,ENCS,T SCA Special:


SECTION15:REGULATORYINFORMATIONREGULATORYSTATUSANDAPPLICABLELAWSANDREGULATIONS Complieswiththefollowingnational/regionalchemicalinventoryrequirements:DSL,ENCS,T SCA Special: Inventory StatusAICS AllcomponentsarelistedorexemptedELINCS RestrictionsApplyIECSC AllcomponentsarelistedorexemptedKECI AllcomponentsarelistedorexemptedPICCS Allcomponentsarelistedorexempted

DetailU.S.Regulations

USINVENTORY(TSCA8b):ListedoninventorySARATitleIIISection302ExtremelyHazardousSubstances(40CFRPart355):ThisproductisnotregulatedunderSection302ofSARAand40CFRPart355SARATitleIIISections311/312HazardousCategorization(40CFRPart370):DefinedasImmediate(Acute)HealthEffectsbyOSHAunder29CFR1910.1200(d)SARA313toxicchemicalnotificationandreleasereporting:NoproductswerefoundCERCLASections102a/103HazardousSubstances(40CFRPart302.4):ThismaterialisnotregulatedunderCERCLASections103and107

StateRegulations Noproductswerefound

CaliforniaProp65:Noproductswerefound


USAHazardousMaterialInformationSystemandNationalFireProtectionAssociation(U.S.A.)DegreeofHazard NFPA HMIS HAZARDRATINGS Health 1 1 Insignificant Fire 1 1 Slight Reactivity 0 0 Moderate PersonalProtection B High Theinformationandrecommendationscontainedhereinare,tothebestofourknowledgeandbelied,accurateandreliableasofthedateissued.Youcancontactustoensurethatthisdocumentisthemostcurrentavailable.Theinformationandrecommendationsareofferedfortheuser’sconsiderationandexamination.Itistheuser’sresponsibilitytosatisfyitselfthattheproductissuitablefortheintendeduse.Ifbuyerrepackagesthisproduct,itistheuser’sresponsibilitytosatisfyhealth,safetyandothernecessaryinformationisincludedwithand/oronthecontainer.Appropriatewarningsandsafe-handlingproceduresshouldbeprovidedorretransmissionofthisdocument,inwholeorinpartisnotpermitted.

SECTION16:OTHERINFORMATIONThisproductsafetydatasheetwaspreparedincomplianceandConformstoHazComm2012/UnitedStates.CertainelementsrefertoCommissionDirective2001/58/EC.,91/155/EEC,67/548/EECand1999/45/ECforreferenceaswellastheirrelevantamendments,ontheapproximationoflaws,regulationsandadministrativeprovisionsrelativetotheclassification,packagingandlabelingofdangeroussubstancesandpreparations.DateofIssue:6-February2018ATE=AcuteToxicityEstimateBCF=BioconcentrationFactorGHS=GloballyHarmonizedSystemofClassificationandLabelingofChemicalsIATA=InternationalAirTransportAssociationIBC=IntermediateBulkContainerIMDG=InternationalMaritimeDangerousGoodsLogPow=logarithmoftheoctanol/waterpartitioncoefficientMARPOL73/78=InternationalConventionforthePreventionofPollutionfromShips,1973asmodifiedbytheProtocolof1978.(“Marpol”)=marinepollutionUN=UnitedNationsN/D=Notdetermined;N/A=NotapplicableKEYTOTHERISKCODESINSECTION2AND3OFTHISDOCUMENT(forinformationonly)EURiskPhrases:R20:HarmfulbyinhalationR65:Harmful:maycauselungdamageifswallowedSafetyPhrases:S2:KeepoutofreachofchildrenS62:Isswalloweddonotinducevomiting:seekmedicaladviceimmediatelyandshowthiscontainerorlabel