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Page 1: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

International Journal ofRenewable Energy

& Its CommercializationIJRECJAN -JUNE 2016

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International Journal of Renewable

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Page 5: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

PUBLICATION MANAGEMENT TEAM

INTERNAL MEMBERS

Associate Manager

ChairmanMr. Puneet Mehrotra

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New Delhi

Hidam Renubala

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Commissioning Editors

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Page 6: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

EDITORIAL BOARD MEMBERS

Prof. C. M. NarayananNational Institute of Technology, Durgapur,

West Bengal, India

Dr. Didik PrasetyokoDepartment of Chemistry, Faculty of

Mathematics and Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia

Dr. Gengan SaravananDepartment of Chemistry, Central University of

Tamil Nadu, Thiruvarur, Tamil Nadu, India

Dr. Goutam BanerjeeAtlantic LNG Chair in Environmental Engrg,

Department of Civil & Env. Engrg, The University of The West Indies St. Augustine,

Trinidad and Tobago

Dr. Kanu MurmuDepartment of Agronomy, F/Ag, Bidhan

Chandra Krishi Viswavidyalaya,West Bengal, India

Dr. Krushna Prasad ShadangiDepartment of Chemical Engineering,

Veer Surendra Sai University of Technology,Sambalpur, Odisha, India

Dr. Linthoingambi NingombamCentre for Environmental Sciences,

Central University of South Bihar, BIT, Patna,Bihar, India

Dr. M. Jhansi L. KishoreDepartment of Chemical Engineering,

Institute of Technology, Nirma University, Ahmedabad, Gujarat, India

Dr. Nanda Gopal SahooDepartment of Chemistry, Nanoscience and

Nanotechnology Centre D.S.B. Campus,Kumaun University, Nainital, Uttarakhand, India

Prof. Pushpa JhaSant Longowal Institute of Engineering &

Technology, Sangrur, Punjab, India

Dr. QingSong WangUniversity of Science and Technology of China,

State Key Laboratory of Fire Science,Anhui, China

Dr. Rajesh DasHaldia Institute of Technology, Haldia,

West Bengal, India

Dr. Shivkumar RanganathanR & D (Battery), Su – Kam Power Systems Ltd.,

Apparel Park Cum Industrial Area, Baddi, Himachal Pradesh, India

Dr. Srinivasan AnandanCenter for Nano-materials, International Advanced Research Centre for Powder

Metallurgy & New Materials, Hyderabad, Andhra Pradesh, India

Dr. Suranani SrinathDepartment of Chemical Engineering,

National Institute of Technology, Warangal,Andhra Pradesh, India

Dr. Susarla Venkata Ananta Rama SastryMVGR College of Engineering,

Vizianagaram,Andhra Pradesh, India

Prof. T. K. RadhakrishnanDepartment of Chemical Engineering,

National Institute of Technology, Tiruchirappalli,Tamil Nadu, India

Venugopal AkulaCSIR-Indian Institute of Chemical Technology,

Hyderabad, Telangana, India

Page 7: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

EDITORIAL BOARD MEMBERS

Dr. Vipan Kumar SohpalDepartment of Chemical Engineering &

Biotechnology, Beant College of Engineering & Technology, Gurdaspur, Punjab, India

Dr. Wenming YangNational University of Singapore,

Singapore

Page 8: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

From the Editor's Desk

Dear Readers,

We would like to present, with great pleasure, the inaugural volume of a new scholarly

journal, International Journal of Renewable Energy and Its Commercialization. This

journal is part of the Applied Sciences, and is devoted to the scope of present renewable

energy issues, from theoretical aspects to application-dependent studies and the validation

of emerging technologies.

This new journal was planned and established to represent the growing needs of renewable energy and its

commercialization as an emerging and increasingly vital field, now widely recognized as an integral part of

scientific and technical investigations. Its mission is to become a voice of the Renewable Energy and its

Commercialization Science community, addressing researchers and practitioners in this area.

The core vision of International Journal of Renewable Energy and Its Commercialization in Journals Pub is

to propagate novel awareness and know-how for the profit of mankind ranging from the academic and

professional research societies to industry practitioners in a range of topics in Renewable Energy in

general. Journals Pub acts as a pathfinder for the scientific community to published their papers at

excellently, well-time & successfully.

International Journal of Renewable Energy and Its Commercialization focuses on original high-quality

research in the realm of Solar energy, solar power and solar thermal energy, Hydroelectricity and

hydropower, Biofuel and sustainable biofuel, Geothermal energy, Biomass conversion, Wind energy

technology, Ocean thermal energies, Socio-economic and energy management, Climate change and global

warming, Renewable energy industry, Nuclear power, Mechanical and thermal energy

Many scientists and researchers have contributed to the creation and the success of the International

Journal of Renewable Energy and Its Commercialization. We are very thankful to everybody within that

community who supported the idea of creating an innovative platform. We are certain that this issue will be

followed by many others, reporting new developments in the field of renewable energy.

This issue would not have been possible without the great support of the Editorial Board members, and we

would like to express our sincere thanks to all of them. We would also like to express our gratitude to the

editorial staff of JournalsPub, who supported us at every stage of the project.

It is our hope that this fine collection of articles will be a valuable resource for chemical engineering readers

and will stimulate further research into the vibrant area of Renewable Energy and its Commercialization.

Puneet Mehrotra

Managing Director

Page 9: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

1. Stability Analysis of Mahua Seed and Waste Polystyrene Co-pyrolytic Oil Krushna Prasad Shadangi, Kaustubha Mohanty 1

2. Sustainable Development: The Current Indian Scenario S.V.A.R. Sastry, Ch.V.R. Murthy 8

3. Investigation on Stability Analysis of Polanga oil Methyl EsterGyana Ranjan Behera, B. Prasanth, Biswajeet Nayak, Swarup Kumar Nayak, Purna Chandra Mishra 16

4. Sustainable Biofuels: Current ScenarioAmit Agnihotri 24

5. Solar Energy: Current Indian Scenario

Chhavi Jain 27

Contents

Page 10: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

IJREC (2016) 1–7 © JournalsPub 2016. All Rights Reserved Page 1

International Journal of Renewable Energy and Its Commercialization Vol. 2: Issue 1

www.journalspub.com

Stability Analysis of Mahua Seed and Waste Polystyrene Co-

pyrolytic Oil

Krushna Prasad Shadangi1*

, Kaustubha Mohanty2

1Department of Chemical Engineering, V. S. S. University of Technology, Burla, Odisha, India

2Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, India

Abstract

Biomass pyrolytic oil is a complex mixture of organic compounds and obtained in a non-

equilibrium state. Hence, the physical properties of bio-oil such as calorific value, viscosity,

pH, density, flow ability and chemical compositions vary during storage. In this study, co-

pyrolysis of Mahua seed was performed with waste polystyrene and studied the fuel

properties and composition. The co-pyrolytic oil was produced at 2:1 ratio of seed to waste

polystyrene using a semi batch reactor. Since, the previous study confirmed that 2:1 ratio

was the optimum ratio of seed to waste polystyrene resulted in high calorific value pyrolytic

oil, the stability of the co-pyrolytic oil is performed in the present study. The stability study of

the co-pyrolytic oil was observed for 40 days at 40 °C. It was confirmed that Mahua seed and

waste polystyrene co-pyrolytic oil was not stable after 10 days of aging. The fuel properties

and composition varied with the aging time. The reduction in the calorific value was

observed beyond 20 days of aging whereas viscosity started reducing with aging.

Keywords: co-pyrolytic oil; DSC analysis; FTIR analysis; fuel properties; stability analysis

INTRODUCTION

The complexity of biomass pyrolytic oil is

because of the composition. Biomass

pyrolytic oil is a composition of alkane,

alkene, alcohol, aromatic, aldehyde, ester,

acid and nitriles along with some water

soluble and insoluble chemicals. The water

soluble chemicals consist of various

anhydrous sugars and levoglucosan. The

existence of oxygen and oxygenated

compounds are the major cause of its low

calorific value as well as stability. The

presence of oxygen in the biomass

pyrolytic oil arises also in the form of

water. This creates problems during

storage and affects the physiochemical

properties of pyrolytic oil. During ageing,

the properties of biomass pyrolytic oil

such as viscosity, density, calorific value,

pH and water content vary and latterly the

pyrolytic oil quality reduces. It was

reported that the viscosity of biomass

pyrolytic oil increased after three months

of aging at 35–37 °C.[1]

The effect of aging

on viscosity also observed at low and high

temperature by Diebold and Czernik

(1997) and conveyed that the viscosity

increased twice at high temperature

compared to low temperature.[2]

The

change in the viscosity was quite fewer

when the biomass pyrolytic oil stored at

less than 20 °C.[1]

Hence, the pyrolytic

should be stored at low temperature. The

increase in the viscosity may be due to the

loss of volatiles. Czernik et al. (1994)

studied the storage stability of pyrolytic oil

and reported that proper cracking of

pyrolytic oil was less viscous due to low

molecular weight.[3]

The premature

entrance of partially pyrolyzed particles,

Page 11: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

IJREC (2016) 8-15 © JournalsPub 2016. All Rights Reserved Page 8

International Journal of Renewable Energy and Its Commercialization Vol. 2: Issue 1

www.journalspub.com

Sustainable Development: The Current Indian Scenario

S.V.A.R. Sastry1*

, Ch.V.R. Murthy2

1Department of Chemical Engineering, MVGR College of Engineering, Vizianagaram, Andhra Pradesh, India

2Department of Chemical Engineering, AUCE (A), Andhra University, Visakhapatnam, Andhra Pradesh, India

Abstract

India has emerged as one of the most promising countries for the development of a

biotechnology business pole because it is a mega biodiverse country containing more than

two million different species of animals, plants and microorganisms. One of the biggest

drawbacks of this country is the laws that govern innovation: intellectual property law and

provisional measures of access to genetic resources do not encourage innovation in this

sector. The evaluation system of universities is also a factor that delays innovation because

the number of scientific articles is more important than the development of new services,

products and processes. Moreover, the country features a wide variety of skilled PhD

researchers. These researchers are highly capable of adapting, researching and innovating

in an environment with limited financial resources. The national biotechnology strategy has

emerged in an atmosphere of contradictions, with several financial and governmental

incentives and limitations on the dual education - business environment and laws. The Indian

biotechnology scenario is discussed in this article by aggregating national realities and

difficulties for the strengthening of one of the globally emerging technologies.

Keywords: biotechnology, genetic resources access, intellectual property, sustainable

development

INTRODUCTION

In 1972, the United Nations Organization

created the World Commission on

Environment and Development, at which

time it adopted the term sustainable

development. This term was consecrated

during the United Nations Conference on

Environment and Development (“Rio-92”)

in 1992 in the city of Rio de Janeiro. This

meeting marked a new era of world

development with the creation of two

important documents: Agenda 21 and the

Earth Charter. Agenda 21 established

priorities and commitment among the

countries to reflect and distribute new

values for future planning. The Earth

Charter was published in 2000 by a

commission and addresses the ethical

rights to the construction of a more just,

sustainable and peaceful XXI century

society. New goals were set, and

awareness campaigns were launched

around the world.

Sustainable development searches for

alternatives to the excesses caused by

classical capitalism, such as

overconsumption, the need for excessive

profits, creation of tons of waste, depletion

of natural oil and water resources and

exaggerated pollution. New models of

monetary and business thinking have

arisen based on this new attitude. The

environment, which had been of

insignificant interest to companies and

industries, became their focus to create a

perspective that it is no longer a concern of

few, but of the entire society.

Page 12: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

IJREC (2016) 16–23 © JournalsPub 2016. All Rights Reserved Page 16

International Journal of Renewable Energy and Its Commercialization Vol. 2: Issue 1

www.journalspub.com

Investigation on Stability Analysis of Polanga oil Methyl Ester

Gyana Ranjan Behera1, B. Prasanth

1, Biswajeet Nayak

2, Swarup Kumar Nayak

1,*, Purna Chandra Mishra

1

1School of Mechanical Engineering, KIIT University, Bhubaneswar, Odisha, India

2Department of Mechanical Engineering, Krupajal Engineering College, Bhubaneswar, Odisha, India

Abstract

Biodiesel is a renewable alternative fuel and consists of mono-alkyl esters of the fatty acids.

One of the major technical problems associated with the biodiesel is its storage stability and

susceptibility to oxidation because of its chemical nature. This nature of the biodiesel is due

to unsaturated fatty acid chains in its molecular structure. Also, the presence of the double

bond in the molecule of the biodiesel produces a high level of reactivity with the oxygen. The

products of the oxidation cause the biodiesel to become acidic and to form insoluble gums

and sediments that can plug fuel filters. Hence, the storage of biodiesel over extended periods

may lead to degradation of fuel properties that may affect the fuel quality. In this work,

biodiesel was derived from Polanga oil and the biodiesel samples were stored at room

temperature and conducted the oxidation stability test utilizing various antioxidants like

(BHT, TBP and OBPA) using Biodiesel Ranchimat instrument and storage stability study

over a period of 6 weeks. At regular intervals, biodiesel samples were analyzed to measure

the acid value, viscosity, calorific value, density, flash point and fire point. From the results,

it is found that BHT was the most effective antioxidant used among all others on PoME

(Polanga oil methyl ester). With respect to storage stability, there is a slight difference in the

properties of the polanga biodiesel, but within the limits of the biodiesel specifications upto

the storage period of 5 weeks.

Keywords: anti-oxidants, biodiesel, oxidation stability, storage stability, transesterification,

Ranchimat

INTRODUCTION

A slow revision of the world vitality

implements highlights that a significant

small amount of the gross vitality

devoured is gotten from the blazing of old

hand powers. Among the old dog fills,

sinuous coal, oil based powers contributes

a most excessive in the tumble of the

circumstance that of their affiliated

physicochemical and ardent properties.

Biodiesel composes of fatty acid mono-

alkyl esters with higher concentrations of

long-chain mono-and polyunsaturated

compounds to develop better cold flow

properties.[1–3]

The presence of such type

of mono-and polyunsaturated compounds

make methyl ester highly effective to

oxidative degradation.[4]

Storage stability

is the ability of liquid fuel to resist change

in its physical and chemical characteristics

brought about by its interaction with its

environment. The key factors for

introducing biodiesel is customer

acceptance, standardization and quality

assurance and storage stability is one such

criteria. The stability of biodiesel during

storage is more severe than that for

conventional diesel fuel. The resistance of

biodiesel to oxidative degradation during

storage is an important issue for viability

and sustainability of such alternative fuels.

Page 13: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

IJREC (2016) 24–26 © JournalsPub 2016. All Rights Reserved Page 24

International Journal of Renewable Energy and Its Commercialization Vol. 2: Issue 1

www.journalspub.com

Sustainable Biofuels: Current Scenario

Amit Agnihotri* Department of Chemical Engineering, ITM, Gwalior, Madhya Pradesh, India

Abstract

In context to the concerns related to attenuation of crude oil reserves, rise in demand and

price of petroleum, global climate change and energy security; bioenergy is increasingly

becoming relevant as a potential alternative to fossil fuels. Biofuels are derived from

renewable bio-mass resources and therefore provide a strategic advantage to promote

sustainable development associated with high economic growth. Here, in this short review,

an overview of current scenario of biofuel production is discussed.

Keywords: biofuel, ethanol, feedstock

INTRODUCTION

Fuels are inevitable for industrial growth

and development, and progress of any

country. The life span of fossil fuel

resources has always been frightening.

Biodiesel, a renewable source of energy

seems to be an ideal solution for global

energy demands in many countries

including India.

Bio-fuels are liquid or gaseous fuels

produced from biomass resources such as

plant materials. Biofuels are derived from

renewable bio-mass resources and provide

a strategic advantage in promoting

sustainable development by supplementing

the conventional energy sources.

Biofuels help to replace diesel, petrol or

other fossil fuels for use in transportation,

stationary, portable and other applications.

Being sustainable, the biofuels are

beneficial in meeting the rapidly

increasing requirements for fuels

associated with high economic growth, as

well as in meeting the energy needs of

India’s vast rural population.

Biofuels have been grouped into first-,

second- and third-generational categories,

viz.

First Generation Biofuels

These are largely made from feedstock

that is conventionally being used as food.

This includes sugars, starch, vegetable

oils, and biodegradable output wastes from

agriculture, industry, forestry and

households. The first generation biofuels

meets 30% of national requirement,

however there are certain limitations

associated with it. Today, first-generation

biofuels (ethanol from corn and biodiesel

from vegetable oil and animal fats) have

taken a lot of heat in the media as being

the culprit behind rising food prices.[1]

These cannot be produced beyond a

threshold level without threatening the

nation’s food security. They are also not

cost-competitive compared to the existing

fossil fuels. Since, there are limited

numbers of low-cost options for feedstock;

the first-generation biofuels have nearly

reached their maximum market share in

the fuels market.

Page 14: International Journal of Renewable Energy and its Commercialization vol 2 issue 1

IJREC (2016) 27–28 © JournalsPub 2016. All Rights Reserved Page 27

International Journal of Renewable Energy and Its Commercialization Vol. 2: Issue 1

www.journalspub.com

Solar Energy: Current Indian Scenario

Chhavi Jain*

MM College, Modinagar, Uttar Pradesh, India

India with a rapidly growing economy

stands 5th in the world in terms of

production and consumption of electricity.

The country has tremendous scope of

generating solar energy largely because of

its geographical location which enables to

receive solar radiation almost throughout

the year. Almost every part of India

receives 4–7 kWh of solar radiation/m2

which is equivalent to 2300–3200 of

sunshine h/yr. Several states including

Punjab, Haryana, Gujarat, Madhya

Pradesh, West Bengal, Andhra Pradesh

have the potential to trap solar energy due

to their location. Solar energy is the best

form of renewable energy source that

enables to fulfill energy needs of the

country and also allows bridging the gap

between the energy demand and supply.

Solar energy is the best replacement to any

other non-renewable energy sources in

India. It is inexhaustible and environment-

friendly. It does not release any harmful

gas like CO2 that could harm the

ecosystem. Solar energy is used for

various purposes such as heating, drying,

cooking and electricity. In a developing

country like India, where energy is scarce,

solar power is the best alternative for

power generation.

Not only this, solar energy system is cost-

effective and can be easily installed

anywhere including houses. However,

there are certain limitations associated

with the use of solar energy. Large land

spaces are required to install a solar power

plant. Only those areas that receive good

amount of sunlight are used for solar

power generation. The solar power panels

require high maintenance and can be easily

damaged, hence require great care and

huge maintenance expenses. Furthermore,

it is quite not feasible to generate energy

during night time with solar energy.

The Indian solar market is growing in size.

Thar Desert is known to have some of

India’s best solar power projects that are

estimated to generate 700–2100 GW. In

2014, the then Chief Minister of Gujarat,

Narendra Modi, inaugurated the country’s

biggest solar power plant at Diken in

Neemuch district of Madhya Pradesh.

India is now gaining prominence in the

field of solar power generation due to

several undergoing solar policies and

projects.

In a latest report by indiatimes.com, India

is supposed to have an additional solar

power generation capacity of nearly 5 GW

in 2016. This is much more than what was

observed in the previous year 2015. It is

the Mercom Capital Group, a global clean

energy communications and research

group that is expected to have the solar

installations in India to a total of 5 GW

this year.

A total of 7.5 GW solar installations were

set by May 2016 and nearly 2.2 GW new

capacities have been installed so far this

year. According to the solar project

pipeline, 22 GW have been surpassed of

which 13 GW are still under construction

and the other 9 GW are in the request for

proposal process. The Indian government

has shown strong interest towards the use

of renewables with solar power in

particular. By the end of FY2015-16, the

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