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CHAPTER 1 -CHAPTER 1 -
Introduction and ReviewIntroduction and Review
All Are InterconnectedAll Are Interconnected
ORGANIC
CHEMISTRY
BIOCHEMISTRY
BIOINORGANIC
CHEMISTRY
ORGANIMETALLIC
CHEMISTRY
MATERIALS
SCIENCE
POLYMER
CHEMISTRY
TEXTILES
MEDICINAL
CHEMISTRY
NATURAL
PRODUCTS
Carbon can bond to itself and other Carbon can bond to itself and other elements to form long chains or ringselements to form long chains or rings
H
O
O H
O H
H
H
H
O H
H
O H
O H
C H3
H3
C
H3
C
HH
H O
C H3
C H3
H
C
O H
O
GlucoseCholesterol
Lauric Acid
Anthracene
C C HH
Acetylene
C
C C
O H
OH
H
Oleic Acid
Carbon can form different types of Carbon can form different types of bonds – single, double, triplebonds – single, double, triple
Shape is Everything!Shape is Everything!
The Essence of an AtomThe Essence of an Atom
A Planetary ModelA Planetary Model
Periodic TrendsPeriodic Trends1. Electronegativity1. Electronegativity
GeneralGeneralTrendsTrends
Periodic TrendsPeriodic Trends1. Electronegativity1. Electronegativity
Foundation of Classical ModelFoundation of Classical ModelAnd Valence Bond TheoryAnd Valence Bond Theory
Periodic TrendsPeriodic Trends2. Atomic Radii2. Atomic Radii
Periodic TrendsPeriodic Trends3. Ionization Energy3. Ionization Energy
Periodic TrendsPeriodic Trends3. Ionization Energy3. Ionization Energy
Blocks correspond to orbital types in which Blocks correspond to orbital types in which outermost Valence electrons are being filledoutermost Valence electrons are being filled
Shapes of Different Types of Shapes of Different Types of OrbitalsOrbitals
Spherical Boundary Surface Of Spherical Boundary Surface Of S-OrbitalsS-Orbitals
Cross section of 1s-orbitalCross section of 1s-orbital
Cross section of 2s-orbitalCross section of 2s-orbital
Cross Section of s-OrbitalsCross Section of s-Orbitals
Spherical Boundary Surface Of Spherical Boundary Surface Of p-Orbitalsp-Orbitals
Spherical Boundary Surface Of Spherical Boundary Surface Of p-Orbitalsp-Orbitals
Blocks correspond to orbital types in which Blocks correspond to orbital types in which outermost Valence electrons are being filledoutermost Valence electrons are being filled
Summary of Formal ChargesSummary of Formal Charges
Electrostatic Potential Map of Electrostatic Potential Map of the Carbonate Anionthe Carbonate Anion
Acids & Bases - Acids & Bases -
An Introduction To An Introduction To
Chemical ReactionsChemical Reactions
A Lewis Acid-Base Reaction A Lewis Acid-Base Reaction
Acidity Increases Down Groups Acidity Increases Down Groups Of The Periodic TableOf The Periodic Table
Acidity Increases Across Periods Acidity Increases Across Periods
Acidity Increases Across Periods Acidity Increases Across Periods
Increases With Electronegativity of Increases With Electronegativity of Element Bearing Negative Charge Element Bearing Negative Charge
Summary Of Periodic Trends Summary Of Periodic Trends In Relative AcidityIn Relative Acidity
Potential Maps of EthanolPotential Maps of EthanolAnd TrifluoroethanolAnd Trifluoroethanol
A Typical Acid Base ReactionA Typical Acid Base Reaction
A Typical Acid Base ReactionA Typical Acid Base Reaction
A Typical Acid Base ReactionA Typical Acid Base Reaction