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IJSRD - International Journal for Scientific Research & Development| Vol. 1, Issue 3, 2013 | ISSN (online): 2321-0613 All rights reserved by www.ijsrd.com 744 Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre Hitesh L. Jadav 1 Dr. Pravin P. Rathod 2 Prof. J. J. Goswami 3 1 PG Student 2 Associate Professor 3 Associate Professor 1, 2, 3 Mechanical Engineering Department, 1, 2, 3 Government Engineering College, Bhuj-370 001 (Kutch-Gujarat-INDIA) Abstract—Increase in energy demand, stringent emission norms and depletion of oil resources led the researchers to find alternative fuels for internal combustion engines. Many alternate fuels like Alcohols, Biodiesel, LPG, CNG etc. have been already commercialized in the transport sector. In this context, pyrolysis of solid waste is currently receiving renewed interest. The disposal of waste tyres can be simplified to some extent by pyrolysis. The properties of the Tyre pyrolysis oil derived from waste automobile tyres were analysed and compared with the petroleum products and found that it can also be used as a fuel for compression ignition engine. In the present work, blends of Diesel-Tyre pyrolysis oil was used in a diesel engine without any engine modification. The entire work is concentrated to enhance the performance and emission parameters of C.I. engine for the blend of Diesel and pyrolysis oil of tyre. To enhance the performance the effect of supercharging was used. The experiment is carried out on C.I. engine using pure diesel and various blends such as TPO10, TPO20 and TPO30 at normal atmospheric pressure and at different supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar and results were compared. It is observed from the results that at supercharged pressures 1.2 bar and 1.4 bar, the performance parameters like brake thermal efficiency and brake specific fuel consumption and emission parameters like emission of CO and HC have been improved. But the emission of NO x was not improved as there is rise in peak temperatures of combustion due to supercharging the emission of NO x increases. Keywords: Pyrolysis oil of tyre, C.I Engine, Supercharging, brake specific fuel consumption, brake thermal efficiency. I. INTRODUCTION Diesel engines are attracting greater attention due to higher efficiency and cost effectiveness, because of that they have been widely used as a power of engineering machinery, automobile and shipping equipment. Oil provides energy for 95% of transportation. All countries including India are grappling with the problem of meeting the ever increasing demand of transport fuel within environment concerns and limited resources. So, the most attentive question arises in our country and at world level is “How long we can use this petroleum fuels? “The solution of this question is in three words `Reduce’,' Reuse' and `Recycle'. There is a predominant increase in tyre wastes due to phenomenal increase in number of vehicles within India. The annual disposal of waste tyre volume will increase at the same rate as new tyre is manufactured. These discarded wastes pose a threat to the environment and human health if not handled properly. Thus timely action regarding recycling of used tyres is necessary to solve the problem keeping in view the increasing cost of raw material, resource constraints and environmental problems including fire and health hazards associated with the stockpiles of the used tyres. The recycling of waste tyre can be done by the pyrolysis process. Pyrolysis is the process of thermally degrading a substance into smaller, less complex molecules. Pyrolysis produces three principal products: such as pyrolysis oil, gas and carbon black. Fig.1: Tyre Pyrolysis oil The use of pyrolysis oil of tyre as a substitution to diesel fuel is an opportunity in minimizing the utilization of the natural resources. Several research works have been carried out on the pyrolysis of waste automobile tyres.Performance, exhaust emission and combustion tests were carried out by many researchers on the CI engine using blends of Pyrolysis oil of tyre and diesel. All tests were conducted by starting the engine with Diesel fuel only. After the engine was warmed up, it was then switched to pyrolysis oil-diesel blend. The result showed that the engine operated with pyrolysis oil-diesel blends give brake thermal efficiencies marginally higher than Diesel fuel. But the blends show higher Brake specific fuel consumption (BSFC) value than Diesel fuel due to the lower calorific value of blend. The NO x , CO and HC emissions are higher for blend than Diesel fuel. The main objective of this study is to enhance the performance and emission characteristics for the blend of Diesel and Pyrolysis oil of Tyre in 4-stroke single cylinder, water cooled CI engine using the effect of supercharging experimentally. In this research work, the performance parameters like brake thermal efficiency, brake specific energy consumption and engine exhaust emissions of NO x , HC and CO were measured.

Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

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Increase in energy demand, stringent emission norms and depletion of oil resources led the researchers to find alternative fuels for internal combustion engines. Many alternate fuels like Alcohols, Biodiesel, LPG, CNG etc. have been already commercialized in the transport sector. In this context, pyrolysis of solid waste is currently receiving renewed interest. The disposal of waste tyres can be simplified to some extent by pyrolysis. The properties of the Tyre pyrolysis oil derived from waste automobile tyres were analysed and compared with the petroleum products and found that it can also be used as a fuel for compression ignition engine. In the present work, blends of Diesel-Tyre pyrolysis oil was used in a diesel engine without any engine modification. The entire work is concentrated to enhance the performance and emission parameters of C.I. engine for the blend of Diesel and pyrolysis oil of tyre. To enhance the performance the effect of supercharging was used. The experiment is carried out on C.I. engine using pure diesel and various blends such as TPO10, TPO20 and TPO30 at normal atmospheric pressure and at different supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar and results were compared. It is observed from the results that at supercharged pressures 1.2 bar and 1.4 bar, the performance parameters like brake thermal efficiency and brake specific fuel consumption and emission parameters like emission of CO and HC have been improved. But the emission of NOx was not improved as there is rise in peak temperatures of combustion due to supercharging the emission of NOx increases.

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Page 1: Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

IJSRD - International Journal for Scientific Research & Development| Vol. 1, Issue 3, 2013 | ISSN (online): 2321-0613

All rights reserved by www.ijsrd.com 744

Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

Hitesh L. Jadav1 Dr. Pravin P. Rathod2 Prof. J. J. Goswami3

1PG Student 2Associate Professor 3Associate Professor 1, 2, 3 Mechanical Engineering Department,

1, 2, 3 Government Engineering College, Bhuj-370 001 (Kutch-Gujarat-INDIA)

Abstract—Increase in energy demand, stringent emission norms and depletion of oil resources led the researchers to find alternative fuels for internal combustion engines. Many alternate fuels like Alcohols, Biodiesel, LPG, CNG etc. have been already commercialized in the transport sector. In this context, pyrolysis of solid waste is currently receiving renewed interest. The disposal of waste tyres can be simplified to some extent by pyrolysis. The properties of the Tyre pyrolysis oil derived from waste automobile tyres were analysed and compared with the petroleum products and found that it can also be used as a fuel for compression ignition engine. In the present work, blends of Diesel-Tyre pyrolysis oil was used in a diesel engine without any engine modification. The entire work is concentrated to enhance the performance and emission parameters of C.I. engine for the blend of Diesel and pyrolysis oil of tyre. To enhance the performance the effect of supercharging was used. The experiment is carried out on C.I. engine using pure diesel and various blends such as TPO10, TPO20 and TPO30 at normal atmospheric pressure and at different supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar and results were compared. It is observed from the results that at supercharged pressures 1.2 bar and 1.4 bar, the performance parameters like brake thermal efficiency and brake specific fuel consumption and emission parameters like emission of CO and HC have been improved. But the emission of NOx was not improved as there is rise in peak temperatures of combustion due to supercharging the emission of NOx increases. Keywords: Pyrolysis oil of tyre, C.I Engine, Supercharging, brake specific fuel consumption, brake thermal efficiency.

I. INTRODUCTION Diesel engines are attracting greater attention due to higher efficiency and cost effectiveness, because of that they have been widely used as a power of engineering machinery, automobile and shipping equipment. Oil provides energy for 95% of transportation. All countries including India are grappling with the problem of meeting the ever increasing demand of transport fuel within environment concerns and limited resources. So, the most attentive question arises in our country and at world level is “How long we can use this petroleum fuels? “The solution of this question is in three words `Reduce’,' Reuse' and `Recycle'.

There is a predominant increase in tyre wastes due to phenomenal increase in number of vehicles within India. The annual disposal of waste tyre volume will increase at the same rate as new tyre is manufactured. These discarded

wastes pose a threat to the environment and human health if not handled properly. Thus timely action regarding recycling of used tyres is necessary to solve the problem keeping in view the increasing cost of raw material, resource constraints and environmental problems including fire and health hazards associated with the stockpiles of the used tyres.

The recycling of waste tyre can be done by the pyrolysis process. Pyrolysis is the process of thermally degrading a substance into smaller, less complex molecules. Pyrolysis produces three principal products: such as pyrolysis oil, gas and carbon black.

Fig.1: Tyre Pyrolysis oil

The use of pyrolysis oil of tyre as a substitution to diesel fuel is an opportunity in minimizing the utilization of the natural resources. Several research works have been carried out on the pyrolysis of waste automobile tyres.Performance, exhaust emission and combustion tests were carried out by many researchers on the CI engine using blends of Pyrolysis oil of tyre and diesel. All tests were conducted by starting the engine with Diesel fuel only. After the engine was warmed up, it was then switched to pyrolysis oil-diesel blend. The result showed that the engine operated with pyrolysis oil-diesel blends give brake thermal efficiencies marginally higher than Diesel fuel. But the blends show higher Brake specific fuel consumption (BSFC) value than Diesel fuel due to the lower calorific value of blend. The NOx, CO and HC emissions are higher for blend than Diesel fuel.

The main objective of this study is to enhance the performance and emission characteristics for the blend of Diesel and Pyrolysis oil of Tyre in 4-stroke single cylinder, water cooled CI engine using the effect of supercharging experimentally. In this research work, the performance parameters like brake thermal efficiency, brake specific energy consumption and engine exhaust emissions of NOx, HC and CO were measured.

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Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

(IJSRD/Vol. 1/Issue 3/2013/0087)

All rights reserved by www.ijsrd.com 745

II. EXPERIMENTAL SET UP AND PROCEDURE The experimental set up consists of a single-cylinder, four stroke, direct injection diesel engine of 3.7 kW rated power diesel engine, fuel measuring equipment and exhaust gas analyser. The engine is coupled to a rope brake dynamometer through a load cell. The schematic layout of the experimental set-up is shown in Figure 1. A reciprocating air compressor was used for supercharging purpose. A surge tank with a valve is provided to maintain uniform inlet air pressure.

Fig. 2: Schematic layout of the experimental set-up

Pyrolysis oil of tyre was used as a test fuel in different proportion with diesel fuel. The Pyrolysis oil was blended with commercial diesel in TPO0 (Tyre Pyrolysis Oil 0% + Diesel 100%), TPO10 (Tyre Pyrolysis Oil 10% + Diesel 90%), TPO20 (Tyre Pyrolysis Oil 20% + Diesel 80%), and TPO30 (Tyre Pyrolysis Oil 30% + Diesel 70%).

Parameters Diesel Make Bajaj

Engine Single cylinder DI diesel engine

Cooling water-cooled Power 3.7 kW/ 5hp

Compression Ratio 16.0:1

Bore× stroke 80mm × 110mm Rated Speed 1500 rpm

Capacity 553 cc Table. 1: Specifications of diesel engine

Experimental Procedure:

1) Engine was run at constant speed of 1500 rpm and the fuel injection pressure was kept at recommended value of 180 bar.

2) The various blends like TPO10 (Tyre Pyrolysis Oil 10% + Diesel 90%), TPO20 (Tyre Pyrolysis Oil 20% + Diesel 80%), and TPO30 (Tyre Pyrolysis Oil 30% + Diesel 70%) was prepared for experiment.

3) First only diesel fuel was used and engine performance parameters like Brake thermal efficiency and Brake thermal efficiency and emission parameters such as CO, HC and NOx emission was taken. Then using various blends such engine parameters was observed.

4) After first set of reading without supercharged pressure, then reading was taken using the different supercharged pressure. The supercharged pressure used was 1.2, 1.4, 1.6 bar. Then Following engine performance and emission parameters were analysed.

Performance Parameters:

1) Brake Specific Fuel Consumption (BSFC). Kg/kwh 2) Brake thermal efficiency, % 3) Brake Power, kW

Emission Parameters:

1) Carbon Monoxide (CO), % vol. 2) Hydrocarbon (HC), ppm 3) Nitrogen Oxide, ppm

III. RESULT AND DISCUSSION. In performance analysis the engine parameters such as Brake specific fuel consumption and Brake thermal efficiency analysis were carried out.

Brake Specific Fuel Consumption

The variation of BSFC with load for pure diesel is shown in the figure 3 for normal atmospheric pressure and for 1.2, 1.4 and 1.6 bar supercharged pressure. It is observed that there is reduction in the BSFC at different supercharged pressure. But at the higher load it increases. So there is reduction of the BSFC using the effect of supercharging.

The variation of BSFC with load for blend of TPO10 (Tyre Pyrolysis Oil 10% + Diesel 90%) is shown in the figure 4 for normal atmospheric pressure and for 1.2, 1.4 and 1.6 bar supercharged pressure.

Fig. 3: Variation of BSFC with Load for pure diesel fuel

TPO10

Load (kg)

2 4 6 8 10 12 14 16 18

BS

FC

(kg

/kW

h)

0.25

0.30

0.35

0.40

0.45

0.50

0.55

Atm Pressure

1.2 bar pressure

1.4 bar pressure

1.6 bar pressure

Fig. 4: Variation of BSFC with Load for Blend TPO10

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Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

(IJSRD/Vol. 1/Issue 3/2013/0087)

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For the blend of TPO10, BSFC is 0.499 kg/kWh for the 4kg of load at normal atmospheric pressure which became 0.491 kg/kWh at 1.2 bar supercharged pressure and 0.480 kg/kWh at 1.4 bar pressure. So there is reduction in BSFC using the effect of supercharging. But for 1.6 bar supercharged pressure it increases again and became 0.484 kg/kWh. Therefore up to 1.4 bar supercharged pressure there is reduction in the Brake Specific fuel consumption. Again for various loading condition, there is reduction in BSFC up to 1.4 bar supercharged pressure then after it increases.

Similarly for the blend of TPO20 and TPO30 at normal atmospheric pressure the Brake specific fuel consumption is higher compared to that with the supercharged pressure up to 1.4 bar then after it starts increasing. Figure 5 and figure 6shows the variation of BSFC with load for TPO20 and TPO30 respectively.

Fig. 5: Variation of BSFC with Load for Blend TPO20

It can be also observed that up to 12kg of load there is reduction in the BSFC using the effect of supercharging. Further, for 16kg of the load BSFC increases.

Fig. 6: Variation of BSFC with Load for Blend TPO30

Therefore it can be concluded that the performance parameter like brake specific fuel consumption can be enhanced using the effect of the supercharging. For pure diesel and for blends like TPO10, TPO20 and TPO30 up to supercharged pressure 1.4 bar there is reduction in BSFC for load up to 12 kg. Then after for 1.6 bar supercharged pressure there is increase in the values of BSFC.

Brake Thermal Efficiency

As shown in shown in the figure 7, the graph of Load Vs Brake thermal Efficiency for the pure diesel. The Brake thermal efficiency for 4kg of load at normal atmospheric pressure is 17.19%. Now using the supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar the Brake thermal efficiencies are 17.46%, 17.62% and 17.43% respectively. It can be observed from the graph that there is improvement in the

Brake Thermal Efficiency up to 1.4 bar supercharged pressure and for 1.6bar pressure it decreases again. Similarly for loads 8kg, 12kg and 16kg similarity can be seen.

Fig.7: Load Vs Brake Thermal Efficiency for Pure diesel

The graph of Load Vs Brake thermal efficiency for blend TPO10 is shown in figure 8.

Fig.8: Load Vs Brake Thermal Efficiency for Blend TPO10

The Brake thermal Efficiency for the blend TPO10 for 4kg of load at normal atmospheric pressure is 16.70%. For supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar the brake thermal efficiencies are 16.98 %, 17.35% and 17.20 % respectively. It can be seen that there is improvement in the brake thermal efficiency up to 1.4 bar supercharged pressure. For 1.6 supercharged pressure there is decrease in the brake thermal efficiency.

The graph of Load Vs Brake thermal efficiency for blend TPO20 is shown in figure 9. The Brake thermal Efficiency for the blend TPO20 for 4kg of load at normal atmospheric pressure is 16.41%.

TPO20

Load (kg)

2 4 6 8 10 12 14 16 18

BT

E %

14

16

18

20

22

24

26

28

30

Atm Pressure

1.2 bar Pressure

1.4 bar pressure

1.6 bar pressure

Fig. 9: Load Vs Brake Thermal Efficiency for Blend TPO20

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Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

(IJSRD/Vol. 1/Issue 3/2013/0087)

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For supercharged pressures 1.2 bar, 1.4 bar and 1.6 bar the brake thermal efficiencies are 16.55 %, 16.63 % and 16.53 % respectively. It can be seen that there is improvement in the brake thermal efficiency up to 1.4 bar supercharged pressure. For 1.6 bar supercharged pressure there is decrease in the brake thermal efficiency.

Similarly for the blend TPO30, the brake thermal efficiency from normal pressure to supercharged pressure up to 1.4 bar increase and for 1.6 bar supercharged pressure there is decrease in the efficiency. The graph of Load Vs Brake thermal efficiency for blend TPO30 is shown in figure 10.

Fig. 10: Load Vs Brake Thermal Efficiency for Blend

TPO30

Therefore it can be concluded that the performance parameter like brake thermal efficiency can be enhanced using the effect of the supercharging. For pure diesel and for blends like TPO10, TPO20 and TPO30 up to supercharged pressure 1.4 bar there is improvement in brake thermal efficiency for load up to 12 kg. Then after for 1.6 bar supercharged pressure, thermal efficiency decreases.

Carbon Monoxide (CO) Emission

Carbon monoxide in the exhaust emission is the indication of an extent of incompleteness of combustion. The variation of CO emission for various loads is shown in the figure 11 for pure diesel. It can be observed that as the load increases the emission of CO also increases. At normal atmospheric pressure the emission of CO is 0.02%vol. for 4kg of load. At different supercharged pressures there is little decrease in the emission of the CO as compared with the normal atmospheric pressure it can be seen from the graph.

Pure Diesel

Load (kg)

2 4 6 8 10 12 14 16 18

CO

(%

vol. )

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

0.09

Atm Pressure

1.2 bar pressure

1.4 bar pressure

1.6 bar pressure

Fig. 11: Load Vs CO Emission for Pure diesel

TPO10

Load (kg)

2 4 6 8 10 12 14 16 18

CO

(vol.%

)

0.03

0.04

0.05

0.06

0.07

0.08

0.09

0.10

Atm Pressure

1.2 bar Pressure

1.4 bar pressure

1.6 bar pressure

Fig. 12: Load Vs CO Emission for Blend TPO10

The graph of Load Vs CO emission for blend TPO10 is shown in figure 12.It can be seen from the graph that for the blend TPO10, the emission of CO decreases at different supercharged pressures compared with the normal atmospheric pressure.

Fig. 13: Load Vs CO Emission for Blend TPO20

TPO30

Load (kg)

2 4 6 8 10 12 14 16 18

CO

(vo

l.%)

0.05

0.06

0.07

0.08

0.09

0.10

0.11

0.12

Atm Pressure

1.2 bar pressure

1.4 bar pressure

1.6 bar pressure

Fig. 14: Load Vs CO Emission for Blend TPO30

Similarly for blend TPO20 and TPO30 the result is same. The emission of CO decreases at different supercharged pressures compared with the normal atmospheric pressure. The graph of Load Vs CO emission for blend TPO20 and TPO30 is shown in figure 13 and figure 14 respectively.

Therefore it can be concluded that with the effect of supercharging there is little decrease in the emission of the CO. CO is formed when there is insufficient O2 to oxide the fuel fully during the combustion of fuel.[11] As due to supercharging the inlet pressure is increases so sufficient air

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Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

(IJSRD/Vol. 1/Issue 3/2013/0087)

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for combustion is available. So there is decrease in the emission of CO due to supercharging effect.

Hydrocarbon (HC) Emission

The graph of load Vs HC emission for pure diesel is shown in figure 15. It can be observed that emission of hydrocarbon decreases as there is increase in the supercharged pressure. At normal atmospheric pressure the HC emission at 4kg load is 29 ppm and at supercharged pressures 1.2 bar, 1.4 bar and 1.4 bar are 28 ppm, 27 ppm and 26 ppm respectively.

Pure Diesel

Load (kg)

2 4 6 8 10 12 14 16 18

HC

(p

pm

)

24

26

28

30

32

34

36

38

40

42

44

Atm pressure

1.2 bar Pressure

1.4 bar pressure

1.6 bar pressure

Fig. 15: Load Vs HC Emission for Pure diesel

For the loads 8kg, 12kg and 16kg also at supercharged pressures there is decrease in the emission of the HC. With supercharging pressures the HC emissions decreased because of the reduction in the delay period of combustion and improved homogeneity of the mixtures. [1]

Fig. 16: Load Vs HC Emission for Blend TPO10

The graph of Load Vs HC emission for blend TPO10 is shown in the figure 15. Here also from the graph it can be seen that emission of HC decreases with increasing the supercharged pressure. Similarly for blend TPO20 and TPO30 the result is same. The graph of Load Vs HC emission for TPO20 and TPO30 is shown in the figure 17 and 18 respectively.

Nitrogen Oxide (NOx)

NOx formation is effected by the temperature and fuel air residence time. At higher temperatures the nitrogen dissociates into nitrous oxide which is a harmful pollutant. [1] The variation of NOx with load for diesel and various blends at atmospheric pressure is shown in figure 19.

TPO20

Load (kg)

2 4 6 8 10 12 14 16 18

HC

(p

pm

)

30

35

40

45

50

55

60

Atm Pressure

1.2 bar Pressure

1.4 bar Pressure

1.6 bar Pressure

Fig. 17: Load Vs HC Emission for Blend TPO20

Fig. 18: Load Vs HC Emission for Blend TPO30

Fig. 19: Load Vs NOx Emission at atmospheric pressure

It can be noticed that with the increase of engine load NOx formation increased because of the rise in peak temperatures of combustion. With the effect of supercharged pressure there is a slight increase in formation of NOx due to a rise in temperature of combustion. The graph of Load Vs NOx emission for inlet pressure of 1.2bar is shown in the figure 20.

Fig. 20: Load Vs NOx Emission at inlet pressure of 1.2 bar

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Enhancing the Performance & Emission for the Blend of Diesel & Pyrolysis oil of Tyre

(IJSRD/Vol. 1/Issue 3/2013/0087)

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Comparing the NOx emission at normal atmospheric pressure and at 1.2 bar supercharged pressure, it is found that there is increase in the amount of NOx as the inlet pressure is increase. NOx emissions are more at full load condition due to lower combustion chamber temperature at part load.

IV. CONCLUSION The following are the conclusions from the results obtained after experimentations. 1) The performance parameter like Brake specific fuel

consumption (BSFC) was enhanced using the effect of supercharging. For supercharged pressures 1.2 bar and 1.4 bar there was reduction in BSFC and it started increasing again for supercharged pressure 1.6 bar for all loads. Similarly in the case of Brake thermal efficiency also there was increase in of BTE for supercharged pressures 1.2 bar and 1.4 bar for all loads and for 1.6 bar.

2) Due to the effect of supercharging there is little decrease in the emission of the CO. For supercharged pressures 1.2 bar and 1.4 bar there was decrease in the emission of CO. But for supercharged pressure 1.6 bar there was increase in the emission of CO. Similar condition for HC also for 1.2 bar and 1.4 bar supercharged pressure there was decrease in the emission of HC then for 1.6 bar supercharged pressure there is increase in the emission of HC. But the emission of NOx is increase using the effect of supercharging.

ACKNOWLEDGEMENT We would like to sincerely acknowledge the en-courageous efforts of Mechanical Engineering Department of Government Engineering College, Bhuj. Our heartfelt thanks to faculty members who helped us in prepare paper and give direction with their precious suggestions & rich experience.

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