Advanced cleaning product formulations Vol. 2

ADVANCED CLEANINGPRODUCT FORMULATIONS

ADVANCED

CLEANING

PRODUCT

FORMULATIONSVolume 2

Reprint Edition

by

Ernest W. Flick

rn:::-J NOYES PUBUCATIONS~ Westwood, New Jersey, U.S.A.

Copyright 1994 by Ernest W. FlickNo part of this book may be reproduced or utilized inany form or by any means, electronic or mechanical,including photocopying, recording or by any informa-tion storage and retrieval system, without permissionin writing from the Publisher.

Library of Congress Catalog Card Number: 89-30274ISBN: 0-8155-1346-1Printed in the United States

Published in the United States of America byNoyes PublicationsFairview Avenue, Westwood, New Jersey 07675

10 9 8 7 6 543 2

Library of Congress Cataloging-in-Publication Data(Revised for vol. 2)

Flick, Ernest W.Advanced cleaning product formulations.

Includes bibliographical references and index.1. Cleaning compounds. I. Title.

TP990.F56 1989 668'.1 89-30274ISBN 0-8155-1346-1

In Memory of

My Father and Mother

and

Aunt Elva

v

Preface

This book (Volume 2) presents more than 800 up-to-date advanced cleaningproduct formulations for household, industrial and automotive applications. It isthe result of information received from numerous industrial companies and otherorganizations. The data represent selections made at no cost to, nor influencefrom, the makers or distributors of these materials. Only the most recentformulas have been included. All formulations are completely different thanthose contained in Volume 1, which was published in 1989.

Formulation in the cleaning product industry has gradually been undergoingsignificant change during the past years. Raw materials costs have risen andmanufacturers have been reluctant to pass along these increases. Environmentalconsiderations have also played a part. By changing formulations to improvecost/performance characteristics, manufacturers have been able to control costsbut still enhance performance. This book presents manufacturers' suggestedformulations which might meet new performance criteria.

The formulations in this book are divided into the following sections andchapters, with the number of formulations indicated in ( ):

I. Household and Industrial Cleaners and Polishes1. Bathroom Cleaners (29)2. Dairy and Food Industry Cleaners (15)3. Degreasers (20)4. Dishwashing Detergents (67)5. Detergents/Disinfectants (36)6. General Purpose Cleaners (47)7. Hard Surface Cleaners (60)8. Laundry Products (217)9. Metal Cleaners (87)

10. Polishes, Coatings and Sealers (32)11. Rinse Aids (6)12. Rug, Carpet and Upholstery Shampoos and Cleaners (21)

vii

viii Preface

13. Miscellaneous Cleaners (96)

II. Transportation Cleaners and Polishes

14. Auto Cleaners and Polishes (9)15. Car and Truck Wash Compounds (38)16. Whitewall Tire Cleaners (10)17. Miscellaneous (19)

Each formula is located in the chapter which is most applicable. The reader,seeking a formula for a specific end use, should check each chapter which couldpossible apply. In addition to the above, there are two other sections which willbe helpful to the reader.

III. A chemical trademark section where each tradenamed raw materialincluded in the book is listed with a chemical description and thesupplier's name. The specifications which each raw material meetsare included, if applicable.

IV. Main office addresses of the suppliers of trademarked rawmaterials.

Each formulation in the book lists the following information, as available, in themanufacturer's own words:

Description of end use and most outstanding properties.

The percent by weight or volume of each raw material included inthe formula, rounded to a decimal figure.

Key properties of the formula, which are the features that thesource considers to be more outstanding than other formulationsof the same type.

The formula source, which is the company or organization thatsupplied the formula. The secondary source may be the originatingcompany and/or the primary source's publication title, or both. Aformula number is included, if applicable.

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations whosupplied the original starting formulations included in this book. I also thank thesuppliers of the raw materials included in these formulations, who furnishedinformation describing their trademarked raw materials.

Newburyport, MassachusettsApril 1994

Ernest W. Flick

Notice

To the best of our knowledge the information in thispublication is accurate; however, the Publisher doesnot assume any responsibility or liability for theaccuracy or completeness of, or consequences arisingfrom, such information. These formulations do notpurport to contain detailed manufacturing nor userinstructions, and by its range and scope could notpossibly do so. Mention of trade names or com-mercial products does not constitute endorsement orrecommendation for use by the Author or Publisher.

Some advanced cleaning products and raw materialscould be toxic if used improperly, and therefore duecaution should always be exercised in the use of thesematerials. Final determination of the suitability andreliability of any information or product for usecontemplated by any user, and the manner of that use,is the sole responsibility of the user. We stronglyrecommend that users seek and adhere to amanufacturer's or supplier's current instructions forhandling each material they use.

The Author and Publisher have used their best effortsto include only the most recent data available. Thereader is cautioned to consult the supplier in case ofquestions regarding current availability.

x

Contents and SUbject Index

SECTION IHOUSEHOLD AND INDUSTRIAL CLEANERS

AND POLISHES

1. BATHROOM CLEANERS 2Aerosol Bathroom Cleaner 3Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Bathroom Cleaner with Hypochlorite Bleach (Mildew

Remover) 4Bowl Cleaner (with Nonionic) 5Bowl Cleaner (NonioniclPerfume) 5Phosphoric Acid Bowl Cleaner 5Clear Liquid Acid Bowl Cleaner 6Acid Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6Liquid Household Drain Cleaner 6Household/Light Industrial Type Germicidal Acid Bowl

Cleaner 7Bowl Cleaner 7Industrial Type Concentrated Germicidal Acid Bowl

Cleaner 8Standard Bowl Cleaner 8Bowl Cleaner with Biocide 8Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9Foaming and Cloudy Ammonia 9Industrial Solvent Cleaner 9Solvent Cleaner 9Tile and Toilet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 10Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 10

xi

xii Contents and Subject Index

Toilet Bowl Cleaner-Liquid 11Toilet Bowl Cleaner-Solid . . . . . . . . . . . . . . . . . . . . . . . . . .. 11Toilet Bowl Cleaner-Good Quality 11

2. DAIRY AND FOOD INDUSTRY CLEANERS . . . . . . . . . . . . . .. 12Acid Dairy Cleaner and Lime Remover 13Liquid Milkstone Remover, Low Foam 13Acid Dairy and Brewery Equipment Cleaning Fonnulation 13Dairy Cleaners-Dairy Farm Acid Liquid 14Dairy Cleaners-Alkaline Powder 14Dairy Pipeline Cleaner, Medium Duty 15Dairy Pipeline Cleaner, Heavy Duty. . . . . . . . . . . . . . . . . . . .. 15Manual Application Dairy Cleaner . . . . . . . . . . . . . . . . . . . . .. 15Dairy Pipeline Cleaner, Low Foam 15Dairy Pipeline Cleaner, Powder . . . . . . .. 16Food Industry Cleaners-General Use Liquid 17Food Industry Cleaners-Powder 17

3. DEGREASERS 18Alkaline Soak and Spray CleanerslDegreasers 19Heavy Duty Spray Degreaser . . . . . . . . . . . . . . . . . . . . . . . . .. 19Degreaser Concentrate (Liquid) 19Degreaser Concentrates-Premium Quality for Hard Water 20Degreaser Concentrates-Prenlium Quality for Medium-

Hardness Water 20Degreaser Concentrates-High Quality Concentrate . . . . . . . . .. 20Degreaser Concentrates-Good Quality Concentrate for High

Pressure Spray System . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 21Degreaser Concentrates-Heavy Duty CleanerlDegreaser . .. 21Heavy Duty Degreaser--d-Limonene Microemulsions 22Heavy Duty Degreaser-Aqueous Degreaser, Fonnulation A 22Heavy Duty Degreaser-Aqueous Degreaser, Fonnulation B 22Heavy Duty Degreaser-Aqueous Degreaser, Fonnulation C 23Heavy Duty Degreaser-Microemulsion Degreaser 23Non-Aqueous (Solvent) Degreaser 24Industrial Degreasing Steanl Cleaner 24ButyllD-Limonene Degreaser 24Solvent Degreasers, Flush-Off Type-High Quality for

Heavy Oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 25Solvent Degreasers-High Quality for Regular Oils 25Solvent Degreasers-Powder Degreasers, Caustic,

Non-Phosphate 25Solvent Degreasers-Non-Caustic, Phosphate . . . . . . . . . . . . .. 25

Conten(s and Subject Index xiii

4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . .. 26Automatic Dishwash Detergent, Consumer (powder,

Dry Blended) 27Machine Dishwashing Detergent (I and II) (Liquid) . . . . . . . . .. 27Automatic Dishwasher Detergent-Dry Mix Fonnulation . . . . .. 28Automatic Dishwasher Detergent-Agglomerated

Fonnulation 28Automatic Dishwashing Detergent 29Dishwashing (Machine) Powder . . . . . . . . . . . . . . . . . . . . . . .. 29Automatic Liquid Dish Detergent . . . . . . . . . . . . . . . . . . . . . .. 30Automatic Liquid Dishwash Detergent 30Liquid Dishwash Detergent-Economy 31Liquid Dishwash Detergent-Economy 31Economy Liquid Dishwash 33Liquid Dishwash Detergent-Intermediate 34Intermediate Liquid Dishwash 38Liquid Dishwash Detergent-Intermediate 38Liquid Dishwash Detergent-Premium 39Premium Liquid Dishwash 39Liquid Dishwash Detergent-Premium 40Premium Liquid Dishwash 43Dishwash Liquid Concentrate 44Dishwash Liquid from Concentrate-Premium Quality 44Dishwash Liquid from Concentrate--Good Quality 44Dishwash Liquid fronl Concentrate-Economy 45Dishwash Liquid from Concentrate--Generic 45Dishwash Liquid Formulation-Premium Quality 45Dishwash Liquid Formulation-Good Quality . . . . . . . . . . . . .. 46Dishwash Liquid Formulation-Economy 46Dishwash Liquid Formulation-Generic 46Hand Dishwash Liquid-High Quality 47Hand Dishwash Liquid-Good Quality . . . . . . . . . . . . . . . . . .. 47Hand Dishwash Liquid-Economy 47Industrial Dishwash, Mild Liquid . . . . . . . . . . . . . . . . . . . . . . . 48Machine Dishwash, Liquid 48Industrial Dishwash Fonnulations

Good Quality Pot and Pan Cleaner 49High Quality Alkaline Pot and Pan Cleaner 49Regular Duty, Good Quality, Mild Liquid 50

Industrial Dishwash Formulations-High Quality Pot andPan Cleaner 50

1&1 Machine Dishwash: Dry Blend Formulation 511&1 Machine Dishwash: Slurry Automatic Dishwash 511&1 Machine Dishwash: Dry Powder 52

iv Contents and Subject Index

1&1 Machine Dishwash: Dry Powder, No Surfactant 521&1 Machine Dishwash: Flatware Presoak Block . . . . . . . . . . .. 52Liquid Dishwash Detergent 53Dishwashing (Hand) Liquid . . . . . . . . . . . . . . . . . . . . . . . . . .. 53Liquid Dishwash Detergent

Strong Cleaning Dishwash Based on Barlox 12 . . . . . . . . .. 54Mild Dishwash Based on Lonzaine CO 54Low Cost Household Product 55

Liquid Dishwasher Detergent . . . . . . . . . . . . . . . . . . . . . . . . .. 55Liquid Machine Dishwashing Detergent 56Machine Dishwashing Detergent 56Premium Light Duty (Dishwashing) Liquid . . . . . . . . . . . . . . .. 57Moderate Light Duty (Dishwashing) Liquid 57Economy Light Duty (Dishwashing) Liquid 57

5. DETERGENTS/DISINFECTANTS 58Aerosol Surface Disinfectant 59CD 1.6 DetergentlDisinfectant 60CD 1.6 (D&F) DetergIDisinfect 61CD 3.2 DetergentlDisinfectant 62CD 3.2 (D&F) DetergIDisinfect 63CD 4.5 DetergentlDisinfectant 64CD 4.5 (D&F) DetergentlDisinfectant . . . . . . .. 65NP 1.8 (D&F) DetergentlDisinfectant 66NP 3.2 DetergentlDisinfectant 67NP 3.2 (D&F) DetergentlDisinfectant 68NP 4.5 DetergentlDisinfectant 69NP 4.5 (D&F) DetergentlDisinfectant 70NP 5.5 HW DetergentlDisinfectant 71NP 5.5 HW (D&F) DetergentlDisinfectant 72NP 7.0 DetergentlDisinfectant 73NP 7.0 (D&F) DetergentlDisinfectant 74NP 9.0 DetergentlDisinfectant 75NP 9.0 (D&F) DetergIDisinfect 76NP 11.0 HW (D&F) DetergentlDisinfectant 77NP 12.5 DetergentlDisinfectant 78NP 12.5 (D&F) DetergentlDisinfectant 79NP 22.0 HW (D&F) DetergentlDisinfectant 80DetergentlDisinfectant Pump Spray 81Disinfectant Pump Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 82Sanitizing Agent (powder) 82Disinfectant/Sanitizer: BTC 1010 7.5% Solution 83Disinfectant Cleaner-Non-Phosphate Liquid Concentrate 83Powder DetergentlDisinfectant 84

Contents and Subject Index xv

PT 3.2 Pine Odor Disinfectant 85Disinfectant Cleaner-Liquid Concentrate with Phosphate 85PT 4.0 Pine Scent DisinfectantlDetergent 86Disinfectant Cleaner-Hospital/Clinical Strength . . . . . . . . . . .. 86Veterinarian Type Disinfectant 0 87Sanitizing Cleaner (powder) 0 o. 8720% Veterinarian Type Disinfectant 88Germicidal Disinfectant (Concentrate) 88

6. GENERAL PURPOSE CLEANERS . . . . . . . . . . . . . . . . . . . . . .. 89Ajax Type All-Purpose Cleaner 90All Purpose Spray Cleaner . 0 0 0 0 0 o. 90All Purpose Cleaner 0 0 91Pine Odor 0 91Abrasive Cleaner, Liquid . . . . . . . . . . . . . . . 0 96Alkaline Cleaner, Heavy Duty . . . . . . . . . . . . . . . . . . . . . . . .. 96Alkaline Industrial Cleaner 96Food Processing Equipment Cleaner, Spray 96Hard Surface Cleaner 97Hard Surface Cleaner, Ammoniated 0 0 0 o. 97Chlorinated Cleaner-Sanitizer 0 0 0 0 97Non-Caustic Cleaner 0 0 0 0 0 0 0 0 98All Purpose Cleaner Concentrate (Liquid, Foam) . 0 0 0 0 99All Purpose Concentrate (Liquid) 0 0 0 0 99All Purpose Heavy Duty Cleaner 100All Purpose Heavy Duty Industrial Cleaner . . . . . . . . . . . . . .. 100Non-Phosphate All Purpose Heavy Duty Industrial Cleaner . .. 100All Purpose Spray Cleaner 101Multi-Purpose Cleaner Concentrate 101All Purpose CleanerlDegreaser-"Simple Green" Type .. 0 0 0 101General Purpose Cleaner-Household 102General Purpose Cleaner-Industrial 102All Purpose Cleaner 0 102All Purpose (Non-Phosphate) Cleaner 0 102General Purpose Spray and Wipe Cleaner . . . . . . . . . . . . . . .. 103Spray and Wipe Cleaner 103General Purpose Spray and Wipe Cleaner . . . . . . . . . . . . . . .. 104Neutral All Purpose Cleaner-No Rinse . . . . . . . . . . . . . . . .. 105Wallffile/Floor Cleaners-Regular Duty, All Purpose 106WallffilelFloor Cleaners-Light Duty, All Purpose . . . . . . . .. 106WallffilelFloor Cleaners-Heavy Duty, All Purpose Spray ... 106WallffilelFloor Cleaners-Regular Duty, All Purpose Spray .. 107WaUffilelFloor Cleaners-Regular Use Ammoniacal Powder 0 0 107

xvi Contents and Subject Index

7. HARD SURFACE CLEANERS 108All Purpose Hard Surface Cleaner 109All Purpose Hard Surface Cleaner-Paint and Woodwork

Cleaner (Liquid) 109All Purpose Hard Surface Cleaner for Wood Surfaces 109Concentrated Hard Surface Cleaner 110Hard Surface Cleaner 110Creamy Hard Surface Cleaner 111Liquid Gentle Abrasive Cleanser for all Non-Porous Hard

Surfaces 111Non-Butyl Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . .. 111Hard Surface Cleaner 112All Purpose Hard Surface Cleaner 114Industrial Hard Surface Cleaner-A 114Industrial Hard Surface Cleaner-B 114Hard Surface Cleaners-All Purpose Liquid Concentrate 115All Purpose Spray-High Quality 115All Purpose Spray-Good Quality 115Hard Surface Cleaners-All Purpose Creamy Scouring

Cleanser, Soft Abrasive Type: High Quality 116Soft Abrasive Type: Good Quality 116Leather, Vinyl and Plastic Cleaner . . . . . . . . . . . . . . . . . . . .. 116Hard Surface Cleaner-All Purpose D-Limonene Cleaner,

High Quality Concentrate 117D-Limonene Cleaner: Degreaser Non-Phosphate 117D-Limonene Cleaner: Degreaser with Phosphate 117Hard Surface Cleaners-All Purpose Economy with

Phosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 118Economy Non-Phosphate 118Hard Surface Cleaners-All Purpose Pine Oil Cleaner,

High Quality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 119Pine Oil Cleaner-Good Quality 119Hard Surface Cleaners-All Purpose Ready-to-Use Liquid 120Spray and Wipe Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 120Hard Surface Cleaner Concentrate (Liquid) . . . . . . . . . . . . . .. 121Hard Surface Cleaner 121Hard Surface Cleaner Concentrate (Liquid) . . . . . . . . . . . . . .. 122Hard Surface Cleaner 122Hard Surface and Floor Cleaner . . . . . . . . . . . . . . . . . . . . . .. 123Hard Surface Cleaners-Liquid Concentrate 125Hard Surface Cleaners-Spray Type 125Hard Surface and Floor Cleaner . . . . . . . . . . . . . . . . . . . . . .. 125Hard Surface Cleaners-All Purpose Hard Surface Cleaner 126

Liquid Concentrate, High Quality with Phosphate 126

Contents and Subject Index xvii

High Quality Non-Phosphate 126Regular Quality with Phosphate . . . . . . . . . . . . . . . . . . .. 127Regular Quality Non-Phosphate 127Non-Phosphate Premium Quality Liquid Concentrate,

for Hard Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 128Non-Phosphate Premium Quality Liquid Concentrate

for Medium-Hardness Water .. . . . . . . . . . . . . . . . . .. 128Non-Phosphate Premium Quality for Heavy Oil Removal . 129Non-Phosphate Premium Quality Lower pH . . . . . . . . . .. 129

Hard Surface Spray Cleaner (Liquid) 130Spray and Wipe Household Hard Surface (Liquid) . . . . . . . . .. 130Moderate Foaming Hard Surface Cleaner-A . . . . . . . . . . . . .. 131Moderate Foaming Hard Surface Cleaner-B 131High Foaming Hard Surface Cleaner-A 131High Foaming Hard Surface Cleaner-B 131

8. LAUNDRY PRODUCTS 132Aerosol DetergentJDisinfectant 133Aerosol Starch 134Aerosol Fabric Size 134Aerosol-Type Prespotters-Solvent-Based-Premium Quality . 135Aerosol-Type Prespotters-Solvent-Based-High Quality .... 135Alkaline Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 136Caustic-Gluconate Soak Formulation 136Alkaline Soak Tank Cleaner for Brass 136Built-Liquid Detergent Formulations 137Detergent/Softener 138High Foaming Detergent/Softener 140Detergent-Softener (1/4 Cup Formulation) 141Detergent-Softener (1/2 Cup Formulation) 142Dry-Blended Compact Laundry Powders Containing Phosphate 143

High Density, One-Quarter Cup-High Quality 143High Density, One-Quarter Cup--Good Quality . . . . . . .. 143High Density, One-Half Cup-High Quality 144High Density, One-Half Cup--Good Quality 144High Density, One-Half Cup-Regular Quality 145

Dry-Blended Compact Laundry Powders with Bleach HighDensity, Three-Quarters Cup-High Quality withPhosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 146

High Quality Non-Phosphate . . . . . . . . . . . . . . . . . . . . . . . .. 146Economy Fabric Softener 147Fabric Softener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 150Fine Fabric Wash Detergent 155Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 155

xviii Contents and Subject Index

Hand-Wash Laundry Liquids-Moderate Foam 156Hand-Wash Laundry Liquids-High Foam, Extra Mild. . . . .. 156Heavy Duty Detergent 157Liquid Heavy Duty Laundry Detergent Concentrate . . . . . . . .. 157Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . .. 158Liquid Laundry Detergent-Economy 158High-Foaming, Light-Duty Liquid Detergent 159Liquid Detergent 159Liquid Laundry Detergent 159High Solids Fabric Softener . . . . . . . . . . . . . . . . . . . . . . . . .. 160Premium Fabric Softener . . . . . . . . . . . . . . . . . . . . . . . . . . .. 161Industrial Laundry Detergent-l 162Industrial Laundry Detergent- 2 162Industrial Laundry Detergent-3 162Industrial Laundry Detergent-4 1621&1 Laundry-Low Temperature Powder, Caustic . . . . .. 1631&1 Laundry-Low Temperature Powder, Non-Caustic 1631&1 Laundry-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1631&1 Laundry-Low-Foam Powder . . . . . . . . . . . . . . . . . . . .. 1631&1 Laundry Liquid 1641&1 Laundry Liquid, Non-Phosphate 1641&1 Laundry Slurry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1641&1 Laundry: Liquid, No Phosphate 165Two-Step Build Laundry Liquid (for Automatic Dispensing

Equipment) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1651&1 Laundry: Powder 1661&1 Laundry: Powder, with Phosphate 1661&1 Laundry Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 167Low Temperature 1&1 Laundry Powder 167Laundry Builder, Silicated, Industrial Supply (Liquid,

Medium Alkalinity) . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 168Laundry Builder, Industrial Supply (powder, Medium

Alkalinity) 168Laundry Builder, Silicated-Linen Supply (Liquid, High

Alkalinity) 169Laundry Detergent-Linen Supply (powder, Low Alkalinity) .. 169Laundry Detergent (Built)-Institutional Supply (Liquid) 170Laundry Detergent-Commercial Built Laundry Liquids 171

High Quality with Phosphate . . . . . . . . . . . . . . . . . . . . .. 171Premium Quality with Phosphate . . . . . . . . . . . . . . . . . .. 172Premium Quality Non-Phosphate 172

Laundry Detergents-Commercial-Two-Step Built Laundry .. 173Liquid Formulations 173

Laundry Detergent-Commercial Unbuilt Liquids . . . . . . . . . .. 174

Contents and Subject Index xix

Premium Quality 174High Quality 174Good Quality 175

Laundry Detergents-Commercial-Regular Quality BuiltLaundry Liquids 176

Highly Alkaline Liquids with Phosphate . . . . . . . . . . . . .. 176Highly Alkaline Liquids Non-Phosphate 176Lower Alkalinity Liquid with Phosphate 177Lower Alkalinity Liquid, Non-Phosphate . . . . . . . .. 177

Laundry Detergent, Consumer (Concentrated, High DensityPowder, Dry Blended) 178

Laundry Detergent (Non-Phosphate), Consumer (Concentrated,High Density Powder, Dry Blended) . . . . . . . . . . . . . . . . .. 178

Laundry Detergent, Consumer (powder, Dry Blended) . . . . . .. 179Laundry Detergent, I and I-Unbuilt (Liquid) 179Laundry Detergent-Industrial and Institutional Supply

(powder, Low Alkalinity) 180Laundry Detergent (Non-Phosphate)-Industrial Supply

(powder, Medium Alkaline) 180Laundry Detergent, Linen Supply (powder, High Alkalinity) 181Laundry Builders, Linen Supply (powder, High Alkalinity) .. 181Laundry Detergent, Linen Supply (powder, Medium

Alkalinity) 182Laundry Builder, Silicated and Phosphated, Linen Supply

(Liquid, High Alkalinity) 182Laundry Detergents-Liquids-Laundry Liquid Concentrate 183Laundry Liquid from Concentrate-Good Quality 183Laundry Liquid from Concentrate-Store Brand 184Laundry Liquid from Concentrate-Economy 184Laundry Liquid from Concentrate-Generic 184Laundry Detergent (Non-Phosphate)----Consumer (powder) 185Laundry Detergent (Non-Phosphate)-Linen Supply (powder,

Medium Alkalinity) . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 185Laundry (Dry Powder)-Machine 186Laundry (Liquid)-Machine 186Laundry (Light Duty Liquid)-Hand 186Fine Fabric Wash Detergent 186Laundry Liquids with Enzymes-Premium Quality 187Laundry Liquids with Enzymes-Good Quality . . . . . . . . . . .. 187Laundry Liquids with Enzymes-with Fabric Softener and

Enzymes 188Laundry Powders-Commercial Low Temperature Powder 189

Phosphate/Caustic . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 189PhosphatelNon-Caustic 189

xx Contents and Subject Index

Non-PhosphatelNon-Caustic 189Laundry Prespotters, Pump Spray-Type-Premium Quality 190Laundry Prespotter-Solvent BaselPump Spray Type 191Laundry Prespotter-Water BaselPump Spray Type 191Laundry Prespotter-Water BaselPump Spray Type, Economy . 191Light Duty Liquid for Fine Washables 192Fine-Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 192Liquid Detergent (1, 2, 3, 4) 193Liquid Detergent (5, 6) 194Heavy Duty Liquid Laundry Detergent . . . . . . . . . . . . . . . . .. 198Liquid Laundry Prespotter . . . . . . . . . . . . . . . . . . . . . . . . . .. 199Laundry Prespotter 199Liquid Medium Duty All-Purpose Detergents . . . . . . . . . . . .. 200Liquid Heavy Duty Detergent 200Low-Foam Powdered Laundry Detergent 201Handwash Laundry Detergent 201Powdered Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . .. 201Liquid Detergent with Ammonia 201Moderate Laundry Liquid-Built . . . . . . . . . . . . . . . . . . . . . .. 202Moderate Laundry Liquid-Non-Built 202Cold Water Wool Detergent 202Non-Phosphate Dry-Blended Compact Laundry Powders 203

High Density, One-Quarter Cup 203High Quality 203Good Quality . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 203

High Density, One-Half Cup 204High Quality 204Good Quality . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 204Economy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 204

Non-Phosphate Laundry Powder 205Unbuilt Heavy Duty Laundry Formulation 205Gelled Laundry Detergent 205Non-Phosphate Laundry Powder 206Non-Phosphate Highly Alkaline Liquid Laundry Detergent 206Non-Phosphate Liquid Laundry Detergent 206One-Half Cup Built Laundry Liquids-High Quality 207

High Quality, High Foam 208One-Half Cup Laundry Liquids with Fabric Softener 209

Premium Quality 209Good Quality 209

One-Quarter Cup Unbuilt Laundry Liquid 211Regular Quality 211Super Premium Quality . . . . . . . . . . . . . . . . . . . . . . . . .. 212Premium Quality 212

Contents and Subject Index xxi

Powdered Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . .. 213Laundry Detergent-Linen Supply (powder, Medium

Alkalinity) 213Premium Laundry Liquid (Non-Built) 214Premium Laundry Liquid (Built) 214Laundry Liquid with Fabric Softener 214Pump Spray Prespotters-Water-Based 215

Good Quality 215Regular Quality 215Economy 215

Rinse-Added Fabric Softener 216So/San Commercial Fabric Softener Sanitizer 216Softener/Sour .. . . . . . . . . . . . . . . . .. 217So/San Household Fabric Softener Sanitizer 221Fabric Softener . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 2215% BTC 2125M Powdered Fabric Softener/Sanitizer 222Softener/Sour 22220% BTC 2125M Powdered Fabric Softener Sanitizer 223Economy Fabric Softener 223

9. METAL CLEANERS 224Acid Cleaner, Iron and Steel, Soak or Spray . . . . . . . . . . . . .. 225Acid Cleaner, Aluminum, Soak or Spray 225Powdered Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 225Acid Aluminum Cleaner 225Acid Cleaner (powder Form) . . . . . . . . . . . . . . . . . . . . . . . .. 226Thickened Phosphoric Acid-Formula 1 . . . . . . . . . . . . . . . .. 226Thickened Phosphoric Acid-Formula 2 . . . . . . . . . . . . . . . .. 226Acid Metal Cleaner ...,............................ 227High-Luster Copper Cleaner . . .. 227Alkaline Cleaner, Aluminum, Soak 228Alkaline Cleaner, Aluminum, Spray . . . . . . . . . . . . . . . . . . .. 228Aluminum Etching Bath 228Aluminum Bright-Dip Bath . . . . . . . . . . . . . . . . . . . . . . . .. 228Alkaline Cleaner, Iron & Steel, Soak 229Alkaline Cleaner, Iron & Steel, Spray 229Zinc Phosphating-Immersion 229Alkaline Metal Cleaners-High Quality 230Alkaline Metal Cleaners-Good Quality . . . . . . . . . . . . . . . .. 230Aluminum Cleaners-Acid Aluminum Brightener 231Alkaline Aluminum Cleaner with Phosphate 231Aluminum Cleaner (powder) 232Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . .. 232Degreasing Solvent Cleaners 233

xxii Contents and Subject Index

Gel Degreaser 233High Quality Metal De-Oiling Liquid Concentrates (Oill

Spill/Rig Cleaners) 234For Heavy Oil 234General Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 234For Light Oil .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 235Spray Cleaner with Phosphate 235

Household Metal Polish, Soft Paste Wax 236Aluminum Cleaner 236Liquid Rust Removers 236Liquid Degreasing Steam Cleaner 237Powdered Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . .. 237Liquid Heavy Duty Alkaline Cleaner 238Powdered Heavy Duty Alkaline Cleaner . . . . . . . . . . . . . . . .. 238Liquid Heavy-Duty Alkaline-Solvent CleanerlDegreaser . . . .. 239Spray Degreaser 239Liquid Steam Cleaner 240Low Foaming Acid Cleaner 241Liquid Acid Cleaner 241Metal Cleaner 241Low Foaming Alkaline Cleaner 242High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . .. 242Liquid Heavy Duty Alkaline Cleaner ~ .. 242Low Temperature Iron Phosphating 243CleaninglPhosphating Solution . . . . . . . . . . . . . . . . . . . . . . .. 243Zinc Phosphating-Spray 243Metal Cleaners-Paint Stripper (Base) 244Alkaline Wash Powder with Phosphate . . . . . . . . . . . . . . . . .. 244Metal Cleaner (powder) 245Metal Cleaner (Liquid) 246Metal Conditioner, Wash-Off Type 247Metal Conditioner, Wipe-Off Type 247Metal Cleaner, Solvent Emulsion . . . . . . . . . . . . . . . . . . . . .. 247Metal Treating Bath 248Acid Aluminum Cleaner 248Rust Removers, Liquid-Acid 249Rust Removers, Liquid-Alkaline 249Solvent Cleaner 250Medium Duty Alkaline Cleaner 250Industrial Cleaners (Viscous Liquid Alkaline Cleaner) 250Liquid Acid Cleaner 250Spray Metal Cleaning 251Metal Cleaner, Solvent-Emulsifier 251 tSpray Metal Cleaning Concentrate-A 252

Contents and Subject Index xxiii

Spray Metal Cleaning Concentrate-B 252Alkaline Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 252Steam Cleaners-Steam/Spray Liquid 253Steam Cleaners-Powder 253Steam Cleaners-Non-Phosphate Concentrate 253Tank Cleaners-Soak Tank ... . . . . . . . . . . . . . . . . . . . . . .. 254Tank Cleaners-Fuel Oil (Bunker C) Tank . . . . . . . . . . . . . .. 254

10. POLISHES, COATINGS AND SEALERS 255Aerosol Furniture Polish 256Liquid Appliance and Kitchen Counter Top Polish 256Aerosol Shoe Polish 257Shoe Polish Paste Wax 257Antistatic Floor Polish (ML-870-408 20% Solids) . . . . . . . .. 258Concrete Sealer (Mor-Flo 155-362, 18% Solids) 259Creamy Furniture Polish 260Floor Polish 261Floor Sealer 271High Speed Floor Coating . . . . . . . . . . . . . . . . . . . . . . . . . .. 273Mop-On Restorer Concentrate . . . . . . . . . . . . . . . . . . . . . . .. 274Nonresilient Sealer 275Non-Zinc Floor Polish 276Removable Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 281Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 282Aerosol Appliance Polish 282Spray Buff Concentrate . . . . . . . . . . . . 0 283Urethane Modified Sealer 284

11. RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 285Dishwasher Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 286Rinse Aid 287

12. RUG, CARPET AND UPHOLSTERY SHAMPOOS ANDCLEANERS 288

BTC 99/824 Carpet Cleaner/Deodorizer (Extraction) 289Carpet Prespotter 289Carpet Cleaner ("Steam" Extraction) 290Carpet Shampoo (Liquid) ,............ 291Rug Steam Cleaner (Liquid) 291Extraction Type Low Foam Carpet Shampoo 291Rug Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 292Rug Steam Cleaners-Powder with Phosphate 293Rug Steam Cleaners-Liquid Cleaner 293Rug Steam Cleaners-Non-Phosphate Powder 293

xxiv Contents and Subject Index

Rug and Upholstery Shampoos-Good Quality Liquid . . . . . .. 293Rug and Upholstery Shampoos-High-Foaming Liquid . . . . .. 293Rug and Carpet Cleaner-Low Foam . . . . . . . . . . . . . . . . . .. 294Rug and Carpet Cleaner-Moderate Foam 294Liquid Steam Cleaner 294Rug and Upholstery Cleaners-"Dry Brittle" Liquid Cleaners . 295

High Quality 295Good Quality 295Economy 295

13. MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 296Acid CD Dairy Cleaner Sanitizer . . . . . . . . . . . . . . . . . . . . .. 297Liquid Acid Dairy Sanitizer and Cleaner 297Acid Cleaner-Hydrofluoric Acid Type 298Acid Cleaner-Ammonium Bifluoride Type 298Viscous Acid Cleaner 298Acid Cleaner with Corrosion Inhibitor 299Heavy Duty Steam Cleaner 299Caustic Equipment Cleaner 299Alkaline Derusting Compound and Electrocleaner 300Metal Burnishing Compound 300Alkaline Wax Stripper 301Household and Industrial Cleaners Wallpaper Penetrant . . . . .. 301Economy Pine Cleaner 301Baking Pan Cleaner (powder) 302Food Industry Cleaner (Liquid) 302Bottle Washing Concentrate 303Powdered Bottle Washing Con1pound . . . . . . . . . . . . . . . . . .. 303BIC 2125M-P40 Powdered Sanitizer 30450% BTC 776 Swimming Pool Algaecide 304Butyl Caustic Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 305Aluminum Cleaner I 306Powdered Caustic Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . .. 306Industrial Cleaner 306CWorinated All Purpose Cleaner Sanitizer for Food

Processing Plants 307Medium Duty Liquid Steam Cleaner 307Power Foam (Foam Cleaner) . . . . . . . . . . . . . . . . . . . . .. 308Concentrated Liquid Steam Cleaner . . . . . . . . . . . . . . . .. 309

CIP Cleaner (powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 310Milk Can Cleaner (powder) . . . . . . . . . . . . . . . . . . . . . . . . .. 310Cleaner Built-#1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311Cleaner Built-#2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 311Lightly Build D-Limonene Cleaner 311

Contents and Subject Index xxv

Concrete Cleaners (powder) 312Printing Plant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 312Creme Cleanser '. 313Creamy Scouring Cleanser 313Liquid Sandpaper (Water Base) 314Bottle Washing Compound 314Dry Cleaner Formula 315Dry Cleaner Pre-Spot . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 315Ink and Rubber Roll Cleaner . . . . . . . . . . . . . . . . . . . . . . . .. 315Formulation Effective for Removing Oil from Hard Surfaces .. 315Dry Powdered Detergents 316Highly Alkaline Cleaner 316Low Foaming, Heavy Duty, Spray Tank Cleaner 316

Phosphate Containing Formula 316Non-Phosphate Formula 316

Liquid Cleaner for High Pressure Application 316Dust Control Foamer 317Pet Conditioner 317Floor Cleaner and Wax Stripper. . . . . . . . . . . . . . . . . . . . . .. 318Foam Marker Concentrate, High Quality-High Viscosity 319Foam Marker Concentrate, High Quality-Low Viscosity 319Gentle Abrasive Lotion Cleanser for Bathroom and Kitchen .. 320Polishing Cleaner for Plastic Windows . . . . . . . . . . . . . . . . .. 320Grease Cutting Pressure Wash . . . . . . . . . . . . . . . . . . . . . . .. 321Industrial Degreasing Steam Cleaner 321Light Duty Neutral Cleaner . . . . . . . . . . . . . . . . . . . . . . . . .. 321Low Foaming Industrial Cleaner-A Through D . . . . . . . . . .. 322Hand Cleaners-Waterless 323Hand Cleaners-Liquid 323Liquid Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 324Liquid Soap . . . . .. 324Micro Emulsion Cleaner I Through III . . . . . . . . . . . . . . . . .. 325Non-ButyllD-Limonene Cleaner 325Non-Abrasive Cleanser. . . . . . . . . . . . . . . . . . . . . . . . . . . .. 326Liquid Drain Cleaner 326Powdered Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . .. 327Powdered Concrete Cleaner with Bleach 327Heavy-Duty Paint Stripper 327Steam Cleaning Compound I Through III . . . . . . . . . . . . . . .. 328Heavy Duty Steam Cleaner 328Waterless Hand Cleaner 329"Waterless" Hand Cleaner Gel . . . . . . . . . . . . . . . . . . . . . . .. 329Waterless Hand Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . .. 330Liquid Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 330

xxvi Contents and Subject Index

SECTION IITRANSPORTATION CLEANERS AND POLISHES

14. AUTO CLEANERS AND POLISHES 332Cream Car Wax . . . . .. 333Detergent Resistant, Cleaner-Polish for Automobile Painted

Surfaces 334Silicone Car Paste Polish . . . . . . . . . . . . . . . . . . . . . . . . . . .. 334Detergent Resistant, Corrosion Resistant, Automobile

Cleaner, Polish Formulation 335Liquid Silicone Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . .. 335Liquid Car Polish 336Wax Emulsion Formulation 336Liquid Silicone Polish for New Cars and Metallic Paints 337Silicone Spray Wax 337

15. CAR AND TRUCK WASH COMPOUNDS 338Aluminum Trailer Cleaner and Brightener 339Aluminum Truck Cleaner and Brightener 339Truck Wash 339Car Wash 340Car Wash Detergent (powder) 341Car Wash Concentrate 341Car Wash Liquids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 342Car Wash Liquid Concentrates-High Quality 343Car Wash Liquid Concentrates-Good Quality 343Car Wash Liquid Concentrates-Economy 343Car Wash Liquid Concentrates-Generic 344Car Wash Powder-Premium Quality 345Car Wash Powder-Good Quality 345Car Wash Powders-Premium Quality with Phosphate 346Car Wash Powders-Premium Quality, Non-Phosphate 346Car Wash Powders-Good Quality 346Car Wash Concentrate 346Car Wash Concentrate-Economy 347Car Wash Concentrate-Moderate 347Car Wash Concentrate-Premium 347Heavy Duty Car Wash for Trucks 348Transportation Vehicle Cleaning Formulation-Pressure Wash . 348High Quality Car Wash Shampoo 348Truck Wash-Good Quality, Non-Phosphate 349Truck Wash Detergent (powder) 349Truck Wash-Premium, Quality with Phosphate 350Truck Wash-Good Quality with Phosphate 350

Contents and Subject Index xxvii

Truck Wash-High Quality Non-Phosphate 350Vehicle Wash, Powder, Aluminum Brightening 351Vehicle Wash, Liquid, Aluminum Brightening 351Vehicle Wash Powder (High Performance) 351

16. WHITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . .. 352Automobile Whitewall Tire Cleaner . . . . . . . . . . . . . . . . . . .. 353Liquid White Wall Tire Cleaner 353White Wall Tire Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . .. 354Specialty Products White Wall Tire Cleaner . . . . . . . . . . . . .. 356

17. MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 357Aircraft Cleaners-Solvent-Based 358Aircraft Cleaners-Powder 35'8Aircraft Cleaners-High Quality Liquid 358Aircraft Cleaner and Brightener . . . . . . . . . . . . . . . . . . . . . .. 359Aircraft Exterior Cleaner. . . . . . . . . . . . . . . . . . . . . . . . . . .. 360Creamy, Vinyl Surface Protectant 361Liquid,. Vinyl Surface Protectant 361Leather and Vinyl Cleaner 362Leather, Vinyl and Plastic Cleaner . . . . . . . . . . . . . . . . . . . .. 362Silicone Aerosol Spray for Battery Terminals and Rubber

Lubrication . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 363Underbody Rust Inhibitor 363Concrete Truck Cleaner 363FiberglasslBoat Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 363Windshield Washer Cleaners-High Quality . . . . . . . . . . . . .. 364Windshield Washer Cleaners-Good Quality 364Windshield Washer Cleaners-Winter Use . . . . . . . . . . . . . .. 364

SECTION III: TRADEMARKED RAW MATERIALS 365

SECTION IV: SUPPLIERS' ADDRESSES 391

Section I

Household and IndustrialCleaners and Polishes

1

1. Bathroom Cleaners

2

Bathroom Cleaners 3

Aerosol Bathroom Cleaner

Formulation E2-7258 produces a product that is used onsurfaces such as ceramics or metals. When applied, this productprovides the coated surface with excellent water-shedding char-acteristics.

Aerosol Concentrate:

art: Ingredients: Percent by WeillhtA Dow Corning HV-490 Emulsion 1 .5

Isopropanol 2.6

B Renex 698 4.1Dowanol DMP 4.1Versene Powder 6.1Water 81.6

Suggested Aerosol Formulation:

Ingredient~: Percent by WeightE2-7258 Concentrate 95.0Isobutane 5.0

Preparation:1. Mix Part A with agitation.2. Mix Part B separately.3. Add Part B to Part A while stirring.4. Pressure fill in lacquer-lined cans with Epon-coated vapor tap

valves and mechanical break-up spray heads.

SOURCE: Dow Corning Corp.: Formulation E2-7258

Bathroom Cleane~

Eormulation~

WaterDowanol DPM (or 1:1 PnB:DPM) glycol etherTriethanolamineDowcicide A1 antimicrobialDowfax 2A1 surfactantVersene 100 chelating agentVersene acid

Wt.%86.90

4.001 .000.560.985.500.30

This formulation has not been registered with the Environmen-tal Protection Agency (EPA). Any formulation which you mightchoose to market with germicidal, disinfectant type claims mustbe registered with the EPA as required by the Federal Insect-icide, Fungicide and Rodenticide Act (FIFRA).

SOURCE: The Dow Chemical Co.: Formula 21

4 Advanced Cleaning Formulations

Bathroom Cleaner with Hypochlorite Bleach (Mildew Remover)

lJl9..redients:Sodium hydroxideSodium metasilicate, pentahydrateBio-Terge PAS-8SSodium hypochlorite (15%)Water, 0.1.

% by Wt.1 .00.55.0

14.079.5

Mixing Procedure:Dissolve sodium hydroxide and metasilicate in water. Add

remaining ingredients in the order shown above while mixing.Properties:

Appearance: Clear liquidpH, as is: 13.0Viscosity @ 25C, cps: 15Solids, %: 3.0

Use Instructions:Use as is. Leave on surface for 1-2 minutes, then wipe with a

sponge and rinse.Performance:

Removes mildew stains and soap scum very effectively. Use ontile, grout, tub, tub walls, shower curtains, shower doors,garbage cans, and diaper pails.

Formulation No. 268

Bathroom Cleaner with Hypochlorite Ble~ch (Mildew Remov~

lngredients:Sodium hydroxide (50%)Sodium metasilicate, pentahydrateAmmonyx LOSodium hypochlorite (15%)Water, D.l.

~~1 .00.55.0

14.079.5

Mixing Procedure:Dissolve sodium hydroxide and metasilicate in water. Add re-

maining ingredients in the order shown above while mixing.Properties:

Appearance: Clear liquidpH, as is: 13.0Viscosity @ 25C, cps: 15Solids, %: 3.0

Use Instructions:Use as is from a trigger spray bottle. Let react for 1-2

minutes, then wipe with a sponge and rinse.Performance:

Removes mildew stains and soap scum very effectively. Use ontile, grout, tub, tub walls, shower curtains, shower doors,garbage cans, and diaper pails.

Formulation No. 469

SOURCE: Stepan Co.: Formulations

Bathroom Cleaners 5

Bowl Cleaner (With Nonionicl

Water75% Phosphoric AcidSurfonic N-150 (nonionic)Tomah Acid Thickener37% HCl

Viscosity @ 20C: 1750 cps.pH: 1.3SpG: 1.049 @ 74F.Wt./Gal.: 8.74 @ 74F.

Bowl Cleaner (Nonionic/Perfume)

Water75% Phosphoric AcidTomah Acid ThickenerSurfonic N-150 (nonionic)37% HelCherry Almond Maskant (N-19198)*Mint Spice Maskant (N-19197)*Pine/Vanilla Maskant (N-19199)*

Viscosity @ 20C: 1750 cps.pH: 1.3SpG: 1.049 @ 74F.Wt./Gal.: 8.74 @ 74F.* Quest Intl

Phosphoric Acid Bowl Cleaner

Water75% Phosphoric AcidTomah Acid ThickenerSalt (NaCl)Surfonic N-150 (nonionic)Cherry Almond Maskant (N-19198)*Mint Spice Maskant (N-19197)*Pine/Vanilla Maskant (N-19199)*

Viscosity @ 20C: 1800 cps.pH: 1.3SpG: 1.049 @ 74F.Wt./Gal.: 8.74 @ 74F.*Quest I nt 1 .

SOURCE: Exxon Chemical Co.: Easier Mixing Formulas

Wt. %68.03.00.54.0

24.5

Wt. %67.93.04.00.5

24.50.1

Wt. %77.712.74.05.00.50.1


Clear Liquid Acid Bowl Cleaner

Monateric CEM-38 is stable in acid systems and can beformulated as follows:

WaterHydrochloric Acid 37%Monateric CEM-38

Use Concentration: 4-8 ounces per toilet bowl

Acid Bowl Cleaner(9.9% active HC11

WaterHCl (37%)Mona AT-1200Phosphoteric T-C6

Viscosity: 200 cps

82.5-72.5%15.0-25.0%

2.5%

% by wt.66.526.75.01 .8

Procedure:Mix acids into water. Add Mona AT-1200. Agitate until homo-

geneous. Add any other ingredients.

lj qui d t-tousehol d Orai n Cl eaner

WaterSodium Hydroxide-FlakesMonaterge 85

Mixing Procedure:Carefully (caution exotherm) add ingredients in

listed with good agitation.

Liquid Household Drain Cleaner

WaterNaOH (Solid)Monafax 1293

SOURCE: Mona Industries, Inc.: Formulas

Bowl Cleaner

D.!. WaterAnionic APSMuriatic Acid

SOURCE: Burlington Chemical Co., Inc.: Formula

% by Wt89.59.51 .0

the order

% Wt.88.010.02.0

87 parts5 parts8 parts

Bathroom Cleaners 7

Household/Light Industrial Type Germicidal Acid Bowl Cleaner

Ingredients:WaterHydrochloric acid (37% active)Neutronyx 656BTC 2125M (50% Active) EPA Reg. No. 1839-46Lytron 300Anthraquinone Blue 3GMethyl Salicylate

% by Wt.72.7521.603.002.000.500.050.10

Mixing Procedure:Charge vessel with water and add acid slowly. Allow acid

mixture to cool before adding remaining ingredients in ordershown.Properties:

Appearance: White, opaque liquidpH, as is:


Industrial Type Concentrated Germicidal Acid Bowl Cleaner

Ingredients:WaterHydrochloric acid (37% active)Neutronyx 656BTC 2125M (50% Active) EPA Reg. No. 1839-46Lytron 300 Latex

% by Wt.39.454.13.03.00.5

Mixing Procedure:Charge vessel with water and add acid slowly. Allow acid

mixture to cool before adding remaining ingredients in ordershown.Properties:

Appearance: White J opaque liquidpH J as is:

Bathroom Cleaners 9

Spray Cleaner

WaterCaustic Soda FlakesButyl CellosolveMonamine ALX-100S

Add ingredients in order listed.

Foaming and Cloudy Ammonia

Household ammoniaMonamine ALX-100SMorton resin E-295

I~dustrial Solvent Cleaner

Monamine ALX-100Sd-LimoneneWater

94.0%1.0%2.0%3.0%

98.9%1.0%0.1%

8.0%5.0%

87.0%

Thorough mixing will result in a coarse, but very stableemulsion cleaner for greasy machine parts which are not attackedby the solvent.

WaterTKPP (Powder)Sodium Metasilicate (Anhydrous)Monateric 1188MIgepal CO-710 (NPE 10-11)Ethylene Glycol Mono Butyl Ether

~-.b~flh179.55.05.04.51 .05.0

Procedure:Blend Water, TKPP, and SMS together until dissolved, add

remaining ingredients.Typical Properties:

Appearance: Clear LiquidCloud Point: 54CKraft Point:


rile & Toilet Cleaner

Phosphoric Acid, 75% (1)Tallow Glycinate (2)Tallow Amine Ethoxylate (3)Water

Phosphoric Acid, 75% (1)Hydrochloric Acid, 37%Tallow Glycinate (2)Tallow Amine Ethoxylate (3)Water

(1) Monsanto Co.(2) Such as Varion TEG, Sherex Chern. Co.(3) Such as Varonic T-202, Sherex Chern. Co.

WaterPhosphoric Acid, 85% (1)Hydroxyacetic Acid, 50%Mazon 41EDTA (3)Kelzan Gum Thickener (4)

(1) Monsanto Co.(2) Mazer Chemicals, Inc.(3) Versene, Dow Chemical Co.(4) Kelco Corp.

SOURCE: Monsanto Co.: Acid Cleaners: Formulas

WaterHypochloriteCaustic SodaAnionic APS

~23.60.51 .0

74.9

%17.613.50.51 .0

67.4

%72.512.010.04.00.51 .0

96 parts2 parts1 parts1 part

SOURCE: Burlington Chemical Co., Inc.: Starter Formulations

Bathroom Cleaners 11

Toilet Bowl CleanersLiquid

Neodol 25-12UreaEDTA (a)Water, dye, perfumeProperties:

Viscosity, 73F, cps: 5Phase coalescence temp., F: >176pH: 10.6

%w5.0

10.00.5

to 100%

%wNeodol 25-12 10.0PEG (1400) (b) 10.0Urea 80.0

a) Ethylenediamine tetraacetic acid, tetrasodium salt (100%basis).

b) Polyethylene glycol with molecular weight about 1400.

Liquid Acid Toilet Bowl Cleaners (Disinfectant)High Quality

Neodol 25-12Germicide (a)Hydrochloric acid (35%) (b)Cocoamidopropyl betaine (30%) (c)Water, dyeProperties:

Viscosity, 73F, cps: 11Phase coalescence temp., F: >176pH: 1.0

Good Quality

%w3.05.0

50.03.0

to 100%

%w3.05.0

20.03.0

to 100%

Neodol 25-12Germicide (a)Hydrochloric acid (35%) (b)Cocoamidopropyl betaine (30%) (c)Water, dyeProperties:

Viscosity, 73F, cps: 7Phase coalescence temp., F: >176pH: 1.0(a) Bardac 2250, Lonza Inc., or equivalent product.(b) May substitute with phosphoric acid.(c) Such as Lexaine C, Inolex Chemical Co., or equivalent

SOURCE: Shell Chemical Co.: NEODOL Starting Formulations forCleaning Products: Formulas

2. Dairy and Food Industry Cleaners

12

~cid_Dairy Cleaner and Lime Remover

WaterNonionic surfactant (1)Phosphoric Acid (75%) (2)

(1) Triton N101 or X100, Union Carbide Co.(2) Monsanto Co.Use level 3-6oz./gallon. [2.3-4.7 1./100 1.J

Deionized Water70% Hydroxyacetic AcidPhosphoric Acid, 85% (1)Sodium BisulfateAlcohol ethoxysulfate (2)

(1) Monsanto Co.(2) Avanel S150, PPG or Neodol 25-3S, Shell

Phosphoric Acid, 75% (1)Gluconic AcidNonionic Surfactant (2)Water

35%5%

60%

48.4%28.6%10.0%

5.0%8.0%

3-0-65%0-25%1-10%q.s.

13

(1) Monsanto Co.(2) Plurafac RA-43 or Pluronic 25R2, BASF, or Triton CF12 or

DF12, Union Carbide

~~.J._~__~ai r~Brew~r'y'-_I;..lli!i pment .CJ eani n9 Formul ati on

Phosphoric Acid, 75% (1)Dequest 2000 (50% so1 .) (1)Water

(1) Monsanto Co.Use at about 1 pint/10 gal. water @ 140-160F

(1.25 1./100 1. @ 60-70C)

SOURCE: Monsanto Chemical Co.: Acid Cleaners: Formulas

50%15%35%


Dairy Cleaners (a)Dairy Farm Acid Liquid (b)

Neodol 25-3Neodol 25-12Phosphoric acid (85%)Butyl Oxitol glycol etherWater

Properties:Phase coalescence temp., F: >165pH: 1.0

Use Concentration:1/4-2 oz./gal.

Blending Procedure:Add acid to water last.

Alkaline Powd~

Neodol 1-5Sodium tripolyphosphateSodium metasilicate, pentahydrateSodium carbonateTetrasodium pyrophosphate

%w1 .02.0

57.33.0

to 100%

%w5.0

30.010.040.015.0

Blending Procedure:Mix solid builders and filler thoroughly. Add surfactants

slowly while mixing; mix thoroughly.

a) Neodol surfactants may be used as components of cleaners forfood processing equipment. Since the cleaning compound is notconsidared a food additive, it is not subject to FDA regula-tions as long as it is followed by a potable water rinse.

b) Good as milkstone remover and equipment cleaner (manual app-lication).

c) Use intended for manual application, not for circulationcleaning.


Dairy Cleaner

0.1. WaterHydroxyacetic AcidPhosphoric Acid 85%Sodium BisulfateAnionic APS

(Removes milkstone)

48 parts28 parts10 parts

5 parts9 parts

SOURCE: Burlington Chemical Co. J Inc.: Starter Formulation

Dairy and Food Industry Cleaners 15

JJlflrJ~J;Li_~D~_Sodium Tripolyphosphate (1)Nonionic Surfactant (2)Sodium Metasilicate, AnhydrousSodium CarbonateACL 60 Chlorinating Compo (3)Sodium Sulfate

(1) Monsanto Co. STP Code 185(2) Such as Union Carbide Triton N-101(3) Monsanto Co.

InSlr~J;!i~.IJ_t.=-Sodium Tripolyphosphate (1)Nonionic Surfactant (2)Sodium Metasilicate, AnhydrousSodium CarbonateACL 60 Chlorinating Compo (3)Sodium Sulfate

(1) Monsanto Co. STP Code 185(2) Such as Union Carbide Triton N-101(3) Monsanto Co.

! !l9!:~.Qj~JJ~~.Neodol 25-12 (1)C-12 LAS (60%) (2)Sodium Tripolyphosphate (3)Sodium Metasilicate, pentahydrateSodium Sulfate, decahydrate

(1) Shell Chemical Co.(2) Witco Chemical Co. Witconate 1260 or equiv.(3) Monsanto Co. STP Code 101

Q~lrJL~eline Cleaner,. Low.Fo~m

IXl.-Med i UJ_:t~Triton CF-54 Surfactant (1)Sodium HydroxideSodium Silicate, AnhydrousSoda AshSodium Tripolyphosphate (2)

(1) Union Carbide Co.(2) Monsanto Co. STP Code 101

~L%

301-3

1020

2-4Balance

Wt_~~

451-3

1520

2-4Balance

~~-~5.03.0

35.035.022.0

w~.%5.0

10.030.030.025.0

SOURCE: Monsanto Chemical Co.: Sodium Tripolyphosphate: Formulas


Dairy Pipeline Cleaner{powder)

Soil: Fat and proteinSurface: Stainless steelApplication Method: Clean in placeManufacture: Ribbon or paddle blender

Composiiion_A~Sodium CarbonateSTPP*Triton DF-16Metso Beads 2048Sodium Hydroxide Beads

.c_QJnpg_~jj;j_Qn_Jt;_

Sodium CarbonateSTPP**C12-C15 Linear Alcohol, 12 Moles EO***Alkylaryl Sulfonate, Acid (98%)Metso Beads 2048

Use Dilution: 0.33-1.5% bw (1/4 oz - 20z/gallon)*Rohm & Haas

**Shell, Union Carbide, Vista***Witco, Vista, Stepan

SOURCE: The PC Corp.: PC Formulary: Formula

DajJ:Y- Pi pe1 i ne Cl eane~

Triton XL-80N SurfactantPhosphoric Acid (85%)Water

% Wt30.025.05.0

30.010.0

~__'y{t28.035.05.02.0

30.0

5.022.073.0

SOURCE: Union Carbide Surfactants: Starting Formulation OF#-31

Dairy and Food Industry Cleaners 17

Food Industry Cleaners Ca)General Use Liquid

Neodol 23-6.5C12 LAS (60%) (b)Sodium metasilicate, pentahydrateTetrapotassium pyrophosphateSodium xylene sulfonate (40%)Butyl Oxitol glycol ether (c)Water, dye, perfume

Properties:Viscosity, 73F, cps: 4Phase coalescence temp., F: >165pH: 13.1

Use Concentration:1-2oz.jgal.

Powder Cd)

Neodol 23-6.5Sodium carbonateSodium hydroxide, beadsSodium metasilicate, pentahydrateTetrasodium pyrophosphate

%w5.05.03.02.02.05.0

to 100%

~~5.0

31.521.318.623.6

Blending Procedure for Powder Only:Mix solid builders thoroughly. Add surfactant slowly with

mixing, mix thoroughly.

a) Neodol surfactants may be used as components of cleaners forfood processing equipment. Since the cleaning compound is notconsidered a food additive, it is not subject to FDA regula-tions as long as it is followed by a potable water rinse.

b) Witconate 1260, Witco Corp., or Bio-Soft 0-62, Stepan Co., orequivalent product may be used.

c) Shell Chemical Co.d) Use intended for soak tank cleaner.


3. Cegreasers

18

Degreasers 19

Alkaline Soak and Spray Cleaners/Degreasers

% wt/wt8.0

tetraacetate tetrasodium salt (38% sol In) 5.0(45% sol 'n.) 20.0

50.017.0

Ingredients:Amphoterge KJ-2Ethylene diamineSodium hydroxideKasil No.1WaterPreparative Procedure:

Charge the mixing vessel with all the water. Slowly add thesodium hydroxide followed by the Kasil No.1 and EDTA Na4. Whenthe system is fully dissolved, add the Amphoterge KJ-2. Continueto mix until the solution is clear.

Formula Y-47-8

Heavy Duty Spray Degreaser

% wt/wt3.0

2.51 .53.05.01 .0

84.0

Ingredients:Amphoterge K-2Ethylenediamine tetraacetic acid, tetrasodium salt

(38% so1 ' n . )Sodium carbonateSodium metasilicate pentahydrateCarsonol SHSUnamide D-10WaterPreparative Procedure:

Charge all of the water to the mixing vessel. While stirring,add the sodium carbonate and sodium metasilicate pentahydrate.After these salts dissolve, add the EOTA-Na4, followed by Unamide0-10, Carsonol SHS and Amphoterge K-2. Continue to mix until thesolution is clear.

Formula J-12-1

SOURCE: Lonza. Inc.: Formulas

Degreaser Concentrate(Liquid)

Soil: Grease, oilSurface: Paint, polymeric, metalApplication Method: Spray or wipeManufacture: Mix tank with propeller stirrer

Composition:WaterMetso Beads 2048EDTA, Tetrasodium (37%)*Phosphate Ester**C9-C11 Linear Alcohol, 6 Moles EO**C9-C11 Linear Alcohol, 2.5 Moles EOUse Dilution: Normal Duty: 1.5% bw (2 ozjgal)

Heavy Duty: 3.0% bw (4 ozjgal)*Mona Industries, Rohm & Haas **Shell, Vista

% Wt62.08.0

10.010.05.05.0

SOURCE: The PC Corp.: PC Formulary: Formula


Degreaser ConcentratesPremium Quality for Hard Water

Neodol 91-6Neodol 91-2.5Sodium metasilicate, pentahydrateEDTA (a)Phosphate ester (b,c)Water, dye, perfume


premium Quality for Medium-Hardness Water

Neodol 91-6Neodol 91-2.5Sodium metasilicate, pentahydrateEDTA (a)Sodium xylene sulfonate (40%)Water, dye, perfume


Neodol 91-6 (d)Neodol 91-2.5 (d)Sodium metasilicate, pentahydrateEDTA (a)Phosphate ester (b)Water, dye, perfume

Properties:Phase coalescence temp., F: 140pH: 13.3

%w5.05.0

12.010.812.5

to 100%

%w5.05.06.76.0

15.0to 100%

%w5.05.0

10.04.0

10.0to 100%


%w6.03.03.0

10.0to 100%

% by Wt.50.09.55.00.5

10.025.0

Degreasers 21

Degreaser Concentrates (Continued)Good Quality Concentrate for High Pressure Spray System

Neodol 1-5Sodium metasilicate, pentahydrateEDTA (a)Sodium xylene sulfonate (40%)Water, dye, perfumeProperties:

Phase coalescence temp., F: 140pH: 12.9

Blending Procedure:Dissolve Neodol ethoxylate(s) and hydrotrope (phosphate ester

or sodium xylene sulfonate) in water. Add EDTA salt and sodiummetasilicate with vigorous stirring until homogeneous.Recommended Dilutions:

Heavy-duty use: 1 part concentrate to 32 parts water (4oz.jgal.).

Regular-duty use: 1 part concentrate to 64 parts water(2oz.jgal.)

a) Ethylenediamine tetraacetic acid, tetrasodium salt (100%bas is) .

b) Triton H-66, Union Carbide Corp., or equivalent product.c) May replace phosphate ester with 17.6% sodium xylene sul-

fonate (40%).d) The combination of Neodol 91-6 and 91-2.5 can be replaced

with Neodol 1-5.SOURCE: Shell Chemical Co.: NEODOL Starting Formulations for

Cleaning Products: Formulas

Heavy Duty Cleaner/Degreaser

Ingredients:d-LimoneneNi nol 11-CMMakon 12Ammonyx LOButyl CellosolveWater, 0.1.Mixing Procedure:

Add surfactants and butyl cellosolve to D-Limonene and mixuntil clear. Add water slowly while under high agitation. Mixuntil clear.Properties:

Appearance: Clear yellow liquidOdor: CitruspH, as is: 9.0Viscosity @ 25C, cps: 50Density, lbsjgal: 7.6

Use Instructions: Use as is or dilute with water.Performance: Removes grease, tar, chewing gum, and other oily

soils effectively.SOURCE: Stepan Co.: Formulation No. 207


Heavy Duty Degreaser

Combinations of Burco TME and Burco FAE can be used to producemicroemulsions with terpene solvents such as d-Limonene. Thiscombination can also be used as an emulsifier for mineral spir-its, varsol, kerosene, etc. With these petroleum solvents, mi-croemulsions can be prepared by increasing the level of surfact-ants or the use of a water soluble solvent such as Burcosolv TM.

p-Limonene Microemulsions

Components:d-LimoneneBurco FAEBurco TMEWater

% by Weight16111 162

Dissolve Burco FAE and Burco TME in d-Limonene. Add waterslowly with stirring. Mix will thicken, then thin as water add iscompleted.

This formulation can be concentrated to as much as twice theactivity level as given above. The ratios of solvent and surfact-ants must remain the same. More concentrated formulations willbuild higher viscosity.

Aqueous degreasers can be produced using Burco TME and BurcoFAE. Equal concentrations of Burco TME and Burco FAE give theoptimum performance properties. Additives such as chelates, det-ergent polymers, and water soluble solvents can enhance the per-formance of the aqueous degreasers. Typical formulations aregiven below:

Aqueous Degreaser Formulation-A

Components:WaterBurco FAEBurco TMETEA 85%

Components:WaterBurco FAEBurco TMEBurcotreat 900-ATEA 85%

Aqueous Degreaser Formulation-B

% by Weight50.602020

0-10

~~Weight462020

410

SOURCE: Burlington Chemical Co., Inc.: Heavy Duty Degreasers:Formulas

lJegreasers 23

Heavy Duty Degreasers (Continued)Aqueous Degreaser Formulation-C

Components:WaterBurco FAEBurco TMEBurcosolv TM

% by Weight40202020

Procedure:Heat water to 65C. Add Burco FAE and stir until dissolved.

Cool and add remaining components in the order listed.Formulation A is the base formulation. TEA is an optional

additive that gives some reserve alkalinity and improved flashrust inhibition.

Formulation B will have improved hard water tolerance andbetter soil anti redeposition properties. Formulation C willgive improved removal of very heavy greases. Combinations ofthese variations are feasible but must be evaluated for stab-ility.

Aqueous degreaser formulations containing the Burco TME/BurcoFAE combination must be used at dilutions containing at least 2%surfactant to obtain good oil emulsification. Higher levels maybe required depending on the soil.

Emulsions obtained using these products may be broken orsplit by acidifying the emulsion. Typically, the solution mustbe acidified to a pH of 4 or lower to achieve good splitting.A pH of 3 or below is preferred.

Mjcroemulsion Degreaser

WaterBurcoterge DG-40Butyl PropasolMineral Spirits

To 100% Total25-50%

10%0-10%

The level of Burcoterge DG-40 is adjusted according to theseverity of the cleaning requirements. Petroleum solvent, suchas mineral spirits, will add cleaning that often cannot beattained without the solvent. This is particularly true forsoils containing waxes or high viscosity oils.

Applications for the degeaser formulations include:Metal DegreasingRemoval of Oil Stains from concrete and other hard surfacesShip and Tank CleaningOil Spill Emulsification

SOURCE: Burlington Chemical Co., Inc.: Heavy Duty Degreasers/BURCOTERGE DG-40: Formulas


Non-Aqueous (Solvent) Degreaser

Componen~

Vista LPA SolventAlfonic 810-60 EthoxylateAlfonic 810-40 EthoxylateWater, perfume, dye

q.s.: quantity sufficient to make 100 percent

Properties:Approximate pH: 7.5Cloud/clear: below 40F

Order of Addition:LPA Solvent, ALFONIC 810-60, ALFONIC 810-40, Water

SOURCE: Vista Chemical Co.: Example Starting Formulation

WaterSodium Metasilicate Anhydrous50% NaOHTrisodium NTATomah AO-14-2Tomah 0-14-2Nonionic Surfactant

pH: 13.0SpG: 1.060 @ 74F.Wt./Gal.: 8.83 @ 74F.

~.M1YlLQ-Li mQD.ene Degrease~

wt. %75.015.05.0q.s.

~-!_~81.52.09.51 .01 .51 .53.0

Compon~JJj;~

Butyl CellosolveD-LimoneneE-14-5Alkali SurfactantNonionic Surfactant (HLB 13)WaterEDTA45% KOHMEA (monoethanolamine)

~~ttl~15.03.53.55.02.0

68.01 .01 . a1 .0

Add the first five ingredients and mix well. Slo~ add thewater with good mixing. Continue mixing and add the remainingingredients. Formulation should be clear.

SOURCE: Exxon Chemical Co.: Formulations

Degreasers 25

~olvent Degreasers, Flush-Off TypeHigh Quality for Heavy Oils

Neodol 91-8Neodol 91-2.5Neodol 25-3Shell Sol 71 or 72 (a)WaterProperties:

Viscosity, 73F, cps: 6Phase coalescence temp., F: >176

Neodol 91-6Neodol 91-2.5Shell Sol 71 or 72 (a)Butyl Oxitol glycol ether (b)WaterProperties:

Viscosity, 73F, cps: 8Phase coalescence temp., F: >176

Blending Procedure for Solvent Degreasers:Add water last, and mix vigorously.(a) Isoparaffinic solvent, b.p. 356-401F. Shell

Shell Sol 140 or Shell Mineral Spirits 145,can be substituted.

(b) Shell Chemical Co.

PO"Yde.r~~r:...easer~

~austi~L Non-Phosphate

Neodol 91-6Neodol 91-2.5Sodium metasilicate, anhydrousSodium hydroxide, beadsSodium carbonate (a)

%w10.05.05.0

79.01 .0

%w15.05.0

60.018.02.0

Chemical Co.;150 or 150EC

~~2.52.5

32.032.031.0

%w2.52.5

30.030.035.0

Neodol 91-6Neodol 91-2.5Sodium metasilicate, anhydrousTrisodium phosphate, anhydrous basisSodium carbonate (a)Blending Procedure for Powder Degreasers:

Mix solid builders thoroughly. Add surfactants slowly whilemixing. Mix thoroughly.(a) May include 5%w ethylenediamine tetraacetic acid, tetrasodium

salt or replace sodium carbonate with trisodium phosphatebuilder for enhanced quality product.


4. Dishwashing Detergents

26

Dishwashing Detergents 27

Automatic Dishwash Detergent, Consumer(powder J dry blended)

Soil: Acidic food fat, oil and proteinSurface: Ceramic, glass and metalApplication method: Automatic dishwashing machineManufacture: Ribbon or paddle blender

Composition:Britesil H20STPP (dense powder)Sodium Carbonate (dense powder)Nonionic surfactant (low foam)Sodium polyacrylate (5,000 mw)Sodium dichloroisocyanurate, 2 H20

Density (lb/ft3) range: 45-62(glee) range: 0.7-1.0

%Wt30.040.024.02.51.52.0

(*Note: Density of finished product is dependent on powderedraw materials particle size and density).

Machine Dishwashing Detergent (1 and 1)(Liquid)

Soil: Food grease, oil and proteinSurface: Metal, ceramic and glassApplication Method: Dishwasher (spray)Manufacture: Mix tank with propeller stirrer

Composition:WaterAcrysol ASE 108Triton DF-16Potassium Hydroxide (45%)TKPP (60%)N Clear

Use Dilution: 0.15-0.30% bw (0.2-0.4 oz/gallon)

SOURCE: PC Corp.: PC Formulary: Suggested Formulas

% Wt50.96.93.01.2

25.013.0


Automatic Dishwasher Detergent-Dry Mix Formulation

Raw Materials:Britesil H-20 or C-20Surfonic LF-37STPP) anhydrousSTPP-6H20Inorganic Salts*Sodium Dichloroisocyanurate-2H20

% by Weight25

3272220

3

* The inorganic salts can be sodium sulfate) sodium carbonateor a mixture of the two.

Mixing Instructions:a) Mix the Britesil and the inorganic salts together.b) Add the Surfonic LF-37 to the mixed Britesil-inorganic salts

and mix thoroughly until the surfactant has been absorbed tothe maximum extent possible.

c) Add the hydrated STPP to the resulting salt-Surfonic mixtureand mix thoroughly. Then add the anhydrous STPP to the mixtureand mix thoroughly.

d) Add the Sodium Dichloroisocyanurate dihydrate to the productmixture last and mix into the product .

.Raw Mat e ria 1s :STPP) anhydrousSodium CarbonateSodium Sulfate) anhydrousBritesil C24Surfonic LF-37Sodium Dichloroisocyanurate-H20Water

~~ Weight34191518

338

Mixing Instructions:a) Mix together the STPP) sodium carbonate and Britesil.b) Slowly spray a mixture of the Surfonic LF-37 and water onto

a well-stirred mixture of solids from step (a). Continuestirring the mixture to allow time for the surfactant toabsorb and the water to partially hydrate the salts.

c) Mix thoroughly the sodium sulfate and the sodium dichloro-isocyanurate. Then add this material to the stirring salt-surfactant mixture and continue to mix until a flowing)granular product.

SOURCE: Texaco Chemical Co.: Formulas


Automatic Dishwashing Detergent

Ingredients:Sodium tripolyphosphate, denseMakon NF-5Britesil H-20CDB ClearonSodium carbonate, dense

% by Wt.40.03.0

30.02.0

25.0

Mixing Procedure:Charge blender with carbonate. Add Makon NF-5 and mix for one

minute. Add remaining ingredients and mix.

Properties:Appearance: White free flowing powderpH, 1% aqueous: 11.0

Use Instructions:Use per dishwasher manufacturer's instructions.

Performance:Excellent performance at low temperature, low foam and defoam-

ing of food soils, no spotting, etching or streaking on glass-ware.

SOURCE: Stepan Co.: Formulation No. 311

Dishwashing (Machine) Powder

Sodium tripolyphosphate, hexahydrateSoda ashSodium metasilicateSodium sulfatePoly-Tergent SLF-18CDB Clearon sodium dichloroisocyanurateWater

SOURCE: Olin Chemicals: POLY-TERGENT Surfactants: Formula

~4420.51514

31 .52

% by Wt.35.75

0.502.000.30

25.003.008.00

24.001 .45

% By Wt.35.733.320.08.03.0

q.s. to pH of 12.0


Automatic Liquid Dish Detergent

Ingredients:Water) D.I.Macaloid clayVan Gel ESMonostearyl acid phosphateK Sil #6Sodium hydroxide (50%)Sodium hypochlorite (15%)Sodium tripolyphosphateBio-Terge PAS-8SMixing Procedure:

Add clay and Van Gel ES to water while mixing. Heat and stirfor 1 hour. Cool and add defoamer. Premix K Sil #6 and sodiumhydroxide and then add while mixing. Add half of phosphate andcontinue mixing. Add bleach. Add remainder of phosphate andlastly add Bio-Terge PAS-8S.Properties:

Appearance: Off white) opaque) slurrypH) as is: 12 . 0Viscosity @ 25C) cps: 13000Phosphorus) % (calculated): 6.1Solids) %: 50.01 week at room temp.: Slight weeping

Use Instructions:Fill dispenser cup completely

Performance:Performs as well as national products.Formulation No. 253

Automatic Liquid Dishwash Detergent

Ingredients:Water) D.I.TKPP (60%)K Sil #1Sodium hypochlorite (15%)Bio-terge PAS-8SSodium Hydroxide (50%)Mixing Procedure:

Dissolve builders in water. Add remainder of ingredients inthe order given with agitation.Properties:

Appearance: Clear liquidpH) as is: 12.0Density) lbsjgal: 10.42Viscosity @ 25C: Water thin

Use Instructions:Measure into machine to give concentrations of 2 td 4 ozjgal

Comment:If a viscous product is desired) a clay thickener can be

added at levels of 1.0-5.0% prior to the addition of builders.SOURCE: Stepan Co.: Formulation No. 25


Liquid Dishwash Detergent-Economy

Ingredients:Water, 0.1.Bio-Soft LD-190Sodium Chloride

% By Wt.88.110.9

1 .0

Mixing Procedure:Blend ingredients in the order given. Adjust pH to 6.5-7.5

with sulfuric acid if necessary_

Properties:Appearance: Straw-colored, clear liquidViscosity @ 25C, cps: 190-230pH, as is: 6.5-7.5Sol ids, %: 10-12Cloud point, C:

% by Wt.76.7517 .152.852.500.75

%~16.303.753.25

76.70



..!l:l9l:::-edients:Water, D.!.Alpha-Step LD-200Steol CS-460Sodium ChlorideOpacifierMixing Procedure:

Charge water, holding back enough to predilute opacifier4:1 water/opacifier. Add ingredients in order given above,mixing thoroughly between additions. Add diluted opacifier last.Adjust pH to 6.5-7.5 as necessary.Properties:

Appearance: White, opaque liquidpH, as is: 7.0Viscosity @ 25C, cps: 150Solids, %: 13Density, lbs/gal: 8.61Freeze/thaw, 3 cycles: Pass

Use Instructions:Squirt small amount into sink and fill with hot water.

Performance:Mini-Plate Test:

Above formulation: 13 mini-plates washedCommercial economy dishwash: 10 mini-plates washedPalmolive control: 40 mini-plates washed

Comment: Opacifier: Lytron 305 from Morton ThiokolFormulation No. 558

~~id Qishwash De~ergent-Economy

lQ_9Tedi en~~._Bio-Soft LD-150UreaSodium ChlorideWater, D.!.Mixing Procedure:

Add urea and salt to water and mix until dissolved. Then addBio-Soft LD-150 and mix until clear and homogeneous.Properties:

Appearance: Clear, yellow liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 150-200Freeze/thaw, 3 cycles: PassSolids, %: 14-16



Above formulation: 11 mini-plates washedPalmolive control: 40 mini-plates washed




Ingredients:Bio-Soft 5-100Sodium hydroxide (50%)Ninol 40COSodium chlorideWater, D.I.

% By Wt.7.31 .92.40.8

87.6

Mixing Procedure:Add caustic to water and slowly add 5-100 while mixing. Add

Ninol 40CO and salt and mix until clear. Adjust pH to 6.5-7.5with sulfuric acid or sodium hydroxide as necessary.

Properties:Appearance: Clear straw-colored liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 230-280Solids, %: 10-12Freeze/thaw, 3 cycles: Pass


Formulation No. 210

Economy Liquid Dishwash

Ingredients:Alpha-Step LD-200Sodium ChlorideWater

% by Wt.30.0

1.069.0

Procedure:Charge water and dissolve sodium chloride.Blend in Alpha-Step LD-200 and mix until homogeneous.Dye and fragrance as desired.

Properties:Appearance: Clear Yellow LiquidpH, as is: 6.5-7.5Solids, %: 15Viscosity, cps: 140Freeze/Thaw Stability: PassSOC Stability: PassUse Level: Squirt small amount into sink and fill with hot

water.

Formulation No. 215

SOURCE: Stepan Co.: Formulations


Economy Liquid Dishwash

Ingredients:Alpha-Step ML-ABio Soft 0-62Ninol 40-CaSodium ChlorideWater

% by Wt.6.5

15.01 .52.5

74.5

Procedure:Charge water. Blend in Alpha-Step ML-A and Ninol 40-Ca with

good agitation. Blend in Bio Soft 0-62. Add sodium chloride; mixuntil homogeneous. Adjust pH to 6.5-7.5 with sodium hydroxide toincrease or sulfuric acid to decrease.

Dye and fragrance as desired.Properties:

Appearance: Clear Yellow LiquidpH, as is: 6.5-7.5Solids, %: 16Viscosity at 25C, cps: 150Freeze/thaw Stability: PassSOC Stability: PassUse Concentration: Squirt small amount into sink and fill with

hot waterFormulation No. 218

~~id Dishwash Detergent-Intermediate

~~Ji~tD~_~_Water, 0.1.Stepanate SXSBio-Soft 0-40Steol CS-460Ammonyx La

r~Y_1J--i_~_

47.21 .5

38.86.56.0

Mixing Procedure:Add ingredients in the order given above. Adjust pH to 7.0-7.5

with sulfuric acid if necessary.Properties:

Appearance: Clear yellow liquidpH, as is: 7.0-7.5Viscosity @ 25C, cps: 250-300Solids, %: 21-23




Comment:Ammonyx La not only improves the viscosity and foaming prop-

erties of the formulation but also -imparts emolliency.



Liquid Dishwash Detergent-Intermediate

Ingredients:Water, D.I.Stepanate SXSBio-Soft LD-190

% By Wt.62.35.0

32.7

Mixing Procedure:Blend ingredients in order given. Adjust pH to 6.5-7.5 with

sulfuric acid if necessary.Properties:

Appearance: Clear yellow liquidViscosity @ 25C, cps: 275-325pH, as is: 6.5-7.5Solids, %: 31-33Cloud point, C:



Ingredients:Steol CS-460Ninol 40-COBio-Soft 0-40Water, 0.1.

% by Wt.8.03.0

50.039.0

Mixing Procedure:Add surfactants in the order given, mix well, then add water

while agitating. Mix until homogeneous. Adjust pH to 6.5-7.5with sulfuric acid if necessary.

Properties:Appearance: Clear liquidViscosity @ 25C, cps: 225-275Freeze/thaw, 3 cycles: PasspH, as is: 6.5-7.5Solids, %: 27-29

Use InstructionsSquirt small amount into sink and fill with hot water.

Formulation No. 24


Ingredients:Water, D.I.Bio-Soft LD-150Sodium chloride

% By Wt.54.545.00.5

Mixing Procedure:Blend ingredients in the order given. Adjust pH with sulfuric

or citric acid if necessary.

Properties:Appearance: Clear yellow liquidViscosity @ 25C, cps: 150-300pH, as is: 6.5-7.5Solids, %: 22-24







Ingredients:Water, 0.1.NaOH (50%)Stepanate SXSBio-Soft S-100Steol CA-460Ninol 96-SLKessco EGMSOpacifying agent (Lytron 305)

% by Wt.46.7

4.89.5

17.816.53.60.50.6

Mixing Procedure:Add ingredients in order given. Adjust pH to 6.5-7.5 with

sulfuric acid or sodium hydroxide as necessary.

Use Instructions:Squirt a small amount into sink and add hot water

Formulation No. 277


1JJ...9.redients:Water, 0.1.Bio-Soft LD-190Sodium chlorideUrea

% by Wt.68.121.92.08.0

Mixing Procedure:Blend ingredients in order given. Adjust pH with sulfuric

acid to 6.5-7.5 before the addition of urea.

Properties:Appearance: Clear straw-colored liquidViscosity @ 25C, cps: 150-200Solids, %: 29-31Freeze/thaw, 3 cycles: PasspH, as is: 6.5-7.5


Performance:Mini-plate Test:




Intermediate Liquid Dishwash

Ingredients:Alpha-Step ML-ABio Soft 0-62Ninol 40-COSodium ChlorideWater

% By Wt.10.023.02.01 .5

73.5

Procedure:Charge water and blend in Alpha-Step ML-A and 40-CO. With

good agitation J add Bio Soft D-62 and mix until homogeneous.Add sodium chloride and continue mixing until blended. AdjustpH to 6.5-7.5.

Dye and fragrance as desired.

Properties:Appearance: Clear Yellow LiquidpH J as is: 6.5-7.5Solids J %: 22ViscositYJ cps: 200Freeze/thaw Stability: PassSOC Stability: PassUse Concentration: Squirt small amount into sink and fill with

hot water

Formulation No. 217


I ngrediJillts~Water J 0.1.NaOH (50%)Stepanate SXSBio-Soft S-100Steol CS-460Ninol 40CO

% by Wt.63.84.91 .9

18.48.03.0

Mixing Procedure:Add ingredients in the order given above. Mix well between

additions. Adjust pH to 6.5-7.5 with sulfuric or caustic ifnecessary.


Properties:Appearance: Clear yellow liquidpH J as is: 6.5-7.5Viscosity @ 25C J cps: 225-275Solids J %: 28-30Freeze/thaw J 3 cycles: Pass



Liquid Dishwash Detergent-Premium

Ingredients:Bio-Soft LO-150Sodium Chloride

% By Wt.98.8

1 .2

Mixing Procedure:Blend ingredients in the order given. Adjust pH to 6.5-7.5

with sulfuric acid if necessary.

Properties:Appearance: Clear yellow liquidViscosity @ 25C J cps: 175-225pH J as is: 6.5-7.5Solids J %: 50-51Freeze/thaw J 3 cycles: Pass

Use Instructions:Squirt a small amount into sink and fill with hot water.



Formulation No. 23

Premium Liquid Dis~wash

~edients_;..

Alpha-Step ML-ASio Soft D-62Water

% by Wt.26.030.044.0

Procedure:Charge water and add Alpha-Step ML-A with good agitation.

Blend in Bio Soft 0-62. Mix until homogeneous. Adjust pH to 6.5to 7.5 with sodium hydroxide to increase J or sulfuric acid tolower. Dye and fragrance as desired.

Properties:Appearance: Clear Yellow LiquidpH, as is: 6.5-7.5Solids, %: 31Viscosity, cps: 250 @ 25CFreeze/thaw Stability: PassSOC Stability: PassUse Concentration: Squirt small amount into sink and fill

with hot water.




Ingredients:Sio-Soft LD-150Sodium sulfateStepanate SXSAmmonyx LO

% By Wt.93.0

2.03.02.0

Mixing Procedure:Add sodium sulfate to Bio-Soft LD-150 and mix well.Add Stepanate SXS with mixing and then add Ammonyx LO.Mix until clear and homogeneous. Adjust pH with sodiumhydroxide or sulfuric acid if necessary.

Properties:Appearance: Clear yellow liquidpH, as is: 7.0-7.5Viscosity @ 25C, cps: 200-260Solids, %: 48-52


Performance:Mini-plate test:


Formulation No. 276

~iquid Dishwash Detergent-Premium

~edienj;~

Bio-Soft S-100Steol CS-460Ninol 96-SLStepanate SXSSodium chlorideNaOH (50%)Water, 0.1.

% By Wt.16.716.93.89.82.54.4

45.9

Mixing Procedure:Add NaOH to water and mix. Add Stepanate SXS followed by Bio-

Soft S-100. Mix well. Add Steol CS-460, and Ninol 96-SL whilemixing. Lastly add salt and mix until clear and homogeneous.Properties:

Appearance: Clear, light yellow liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 225-275Solids, %: 34-36





~edjents:

Bio-Soft 5-100Sodium hydroxide (50%)Alpha-Step ML-AStepanate SXSWater, 0.1.

% by Wt.21 .35.6

26.01 .0

46.1

Mixing Procedure:Add Stepanate SXS and sodium hydroxide to water.Add Bio-Soft 5-100 while mixing to about a pH of 7.Add Alpha-Step ML-A and mix until clear and uniform.

Properties:Appearance: Clear yellow liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 200-250Solids, %: 36-37Freeze/thaw, 3 cycles: Pass




Formulation No. 466


I n9 red i ents~_Bio-Soft 5-100Sodium hydroxide (50%)Alpha-Step ML-AStepanate SXSKessco EGMSWater, 0.1.

r~~~21 .05.5

26.01 .01 .5

45.0

Mixing Procedure:Add Stepanate SXS and sodium hydroxide to water. Add Bio-Soft

5-100 while mixing to about a pH of 7. Add Alpha-Step ML-A andmix. Heat to 60C and add EGMS. Continue mixing uQtil EGMS hasdissolved and product comes back to ambient temperature.Properties:

Appearance: Pearlized liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 300-400Solids, %: 38-39Freeze/thaw, 3 cycles: Pass







Ingredients:Bio-Soft LD-150Stepanate SXSKessco EGDSWater, D.I.

% By Wt.80.0

7.51 .0

11 .5

Mixing Procedure:Blend Stepanate SXS and water. Add LD-150 and heat to 60C.

Add EGDS and mix until homogeneous. Continue mixing and cool toroom temperature. Adjust pH to 6.5-7.5 with sulfuric acid ifnecessary.Properties:

Appearance: Opaque, pearly, white liquidpH, as is: 6.5-7.5Solids, %: 41-43Viscosity @ 25C, cps: 250-300Freeze/thaw, 3 cycles: Pass




Formulation No. 273

Liquid Dis~wash Detergent-Premium

Ingredients:Bio-Soft D-62Steol CS-460Ninol 96-SLStepanate SXSSodium ChlorideWater, D.1.

% by Wt.29.216.93.88.02.5

39.6

Mixing Procedure:Add Stepanate SXS to water and mix. Add Bio-Soft D-62, Steol

CS-460, and Ninol 96-SL while mixing. Lastly add salt and mixuntil clear and homogeneous. Adjust pH to 6.5-7.5 with sulfuricacid if necessary.Properties:

Appearance: Clear, light yellow liquidpH, as is: 6.5-7.5Viscosity @ 25C, cps: 225-275Solids, %: 34-36




Premium Liquid Dishwash

Ingredients:Alpha-Step LD-200Water

% by Wt.70.030.0

Procedure:Charge water. With agitation, blend in the LD-200 and mix

until homogeneous. Dye and fragrance as desired.

Properties:Appearance at 25C: Clear Yellow LiquidpH, as is: 6.5-7.5Solids, %: 35Viscosity at 25C, cps: 280Freeze/thaw Stability: PassSOC Stability: PassUse Level: Squirt small amount into sink and fill with hot

water.

Formulation No. 243

Premium Liquid Dishwash

Ingredients:Alpha-Step ML-40Bio Soft 0-62Steol CS-460Ninol 40-COWater

% by Wt.21 .629.35.83.5

49.8

Procedure:Charge water. Add ML-40 and 40-CO and mix until homogeneous.

With good agitation, slowly add CS-460 and 0-62. Adjust pH to6.5-7.5 with sodium hydroxide to increase or sulfuric acid todecrease. Dye and fragrance as desired.

Properties:Appearance: Clear Yellow LiquidpH, as is: 6.5-7.5Solids, %: 31Viscosity, as 25C, cps: 250Freeze/thaw Stability: PassSOC Stability: PassUse Concentration: Squirt small amount into sink and fill

with hot water



Dishwash Liquid Concentrate

Neodol 25-3A (60%)Linear alkylbenzene sulfonate (97%)(a)FADEA (b)Preservative(s)Water

Properties:Viscosity, 73F, cps: 700Active matter, %w: 45

%w22.527.84.50.1

to 100%

Blending Procedure:Dissolve preservative and alkylbenzene sulfonate in water.

Add Neodol 25-3A slowly to well stirred mixture, then add amide.Best results will be obtained if water is warm (e.g. 120F).

(a) Linear dodecylbenzene sulfonic acid such as Bio-Soft5-100, Stepan Co., or equivalent product, plus an equival-ent amount of caustic (NaOH) can be used. pH should bebetween 5.5 and 7.5 before Neodol 25-3A is added (adjustwith more alkylbenzene sulfonate or caustic).

(b) Fatty acid diethanol amide, such as Ninol 49CE, StepanCo., or equivalent product.

Dishwash Liquid from Concentrate-Premium Quality

ConcentrateEthanol SD-3AWater, dye, perfume

Properties:Viscosity, 73F, cps: 240Clear point, F: 32

Dishwash Liquid from Concentrate-Good Quality

ConcentrateEthanol SD-3AWater, dye, perfume


%w71 . 14.0

24.9

%w55.62.0

42.4

Blending Procedure:Dissolve the ethanol or sodium sulfate in the water. Add the

concentrate slowly with stirring. Adjust the pH to 6.5-7.0 usingcitric acid.

SOURCE: Shell Chemical Co.: NEODOL Starting Formulations


Dishwash Liquids From Concentrate (Continued)

ConcentrateWater, dye, perfume


ConcentrateSodium sulfate, anhydrousWater, dye, perfume


Economy

Generic

%w44.455.6

%w22.23.0

74.8

Blending Procedure:Dissolve the ethanol or sodium sulfate in the water. Add the

concentrate slowly with stirring. Adjust the pH to 6.5-7.0 usingcitric acid.

Dishwash Liquid Formulation-Premium Quality

Neodol 25-3S (60%)C12LAS (60%) (a)FADEA (b)Sodium xylene sulfonate (40%)Sodium chlorideWater, dye, perfume, preservatives

Properties:Viscosity, 73F, cps: 270Clear point, F: 38Adjust pH to 6.5-7.0 with citric acid.

%w18.330.04.08.53.0

to 100%

(a) Witconate 1260, Witco Corp., Bio-Soft 0-62, Stepan Co.,or any equivalent product may be used.

(b) Fatty acid diethanol amide, such as Ninol 49CE, StepanCo., or equivelent product.

SOURCE: Shell Chemical Co.: NEODOL Starting Formulations forCleaning Products


Dishwash Liquid FormulationsCContinued)Good Quality

Neodol 25-35 (60%)C12LAS (60%)(a)FADEA(b)EthanolWater, dye, perfume, preservatives


Economy

Neodol 25-35 (60%)C12LAS (60%)(a)FADEA(b)Sodium xylene sulfonate (40%)Sodium sulfateSodium chlorideWater, dye, perfume, preservatives


Generic

Neodol 25-35 (60%)C12 LAS (60%) ( a )FADEA(b)Sodium xylene sulfonate (40%)Sodium chlorideWater, dye, perfume, preservatives

Properties:Viscosity, 73F, cps: 2

Healthcare

Advanced cleaning product formulations Vol. 2