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TECHNICAL MATERIALSAN INTRODUCTION
Materials can be defined as anything which satisfies the human needs
or
Materials are substances of which some thing is composed or made of.
Since civilization materials are in use by people to improve their standard of living.
Materials are everywhere about us in the shapes of products
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Historical Perspective
Beginning of the Material Science –
People began to make tools from stone – Start of the Stone Age about two million years ago.
Natural materials: stone, wood, clay, skins, etc.
The Stone Age ended about 5000 years ago with introduction of Bronze.
Bronze is an alloy (copper + tin + other elements). Bronze: can be hammered or cast into a variety of shapes, can be made harder by alloying, corrode only slowly after a surface oxide film forms.
12/12/14 WEC 3
Historical Perspective
The Iron Age began about 3000 years ago and continues today.
Use of iron and steel, a stronger and cheaper material
changed drastically daily life of a common person.
Age of Advanced materials: throughout the Iron Age many new types of materials have been introduced (ceramic, semiconductors, polymers, composites…).
Understanding of the relationship among structure, properties, processing, and performance of materials. Intelligent design of new materials.
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Historical Perspective
A better understanding of structure-composition properties relations has lead to a remarkable progress in properties of materials.
Example is the dramatic progress in the strength to density ratio of materials, that resulted in a wide variety of new products, from dental materials to tennis racquets.
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ENGINEERING MATERIALS-AN INTRODUCTION
Commonly encountered materials are wood (timber),
concrete, bricks, steel. plastic, glass, rubber, aluminum,
copper and paper etc.
If we look around we can easily realize that there are
many more kinds of materials.
These new types of materials are being frequently
developed as a result of constant research and
development.12/12/14 6WEC
The world of materials
Metals,alloys
Ceramics,glasses
Polymers,elastomers
Hybrids, composites
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The world of materials
Polymers,
elastomers
Ceramics,
glasses Hybrids,
composites
Metals,
alloys
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The term technical materials is specifically used to refer materials to produce technical products
However there is no limiting line between the terms Materials and Technical materials,
they can be used interchangeably
Technical materials
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Engineers
design most of the products and their processing systems for the production of
these products. Products require materials & Engineers should have the knowledge of
engineering materials i.e. an engineer should be knowledgeable about the structure
and properties of the materials so that
he is able to select the most suitable ones for each application
and he is able to develop best processing methods.
Technical materials
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Relationship b/w Structural level & Engineering properties
Subatomic level Electronic structure of
individual atoms that defines interaction among atoms (interatomic bonding).
Atomic level Arrangement of atoms in
materials (for the same atoms can have different properties, e.g. two forms of carbon: graphite and diamond)
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Relationship b/w Structural level & Engineering properties
Microscopic structure Arrangement of small
grains of material that can be identified by microscopy.
Macroscopic structure Structural elements that
may be viewed with the naked eye.
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Engineering activities depend upon the selection
of engineering materials whose properties match
the requirements of the application
Primitive cultures were often limited to the
naturally occurring materials (stone wood, clay) in
their environment.
Structure-Property-Processing-Performance Relationship
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As civilization developed, the spectrum of engineering materials expanded.
Materials could be processed and their properties altered and possibly enhanced.
The alloying and heat treatment of metals can change the properties of a material.
Structure-Property-Processing-Performance Relationship
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While earlier successes in altering materials were
largely the result of trial and error,
But now
we recognize that the properties and performance
of a material are the direct result of its structure
and processing
If we want to change the properties, we will have to
induce changes in the material structure
Structure-Property-Processing-Performance Relationship
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Classification of Technical materials
Most of the Technical materials can be
classified into main five categories as under:
1. Metallic materials
2. Polymeric materials
3. Ceramic materials
4. Composite materials
5. Electronic materials
6. Advanced materials12/12/14 17WEC
cont…… Classification
Metals Steel, Cast Iron,
Aluminum, Copper, Titanium, many others
Ceramics Glass, Concrete,
Brick, Alumina, Zirconia.
Polymers Plastics, Wood,
Cotton (rayon, nylon), “glue”
Composites Glass Fiber-
reinforced polymers,
Carbon Fiber-reinforced polymers,
Metal Matrix Composites, etc.12/12/14 18WEC
Metallic materials
These are inorganic substances which are
composed of one or more metallic elements.
Examples of metallic elements are Iron, Copper,
Aluminum.
Non-metallic elements such as Carbon,
Nitrogen and Oxygen may also be contained in
the metallic materials.12/12/14 19WEC
Metallic materials
Metals: valence electrons are detached from atoms,
and spread in an 'electron sea' that "glues" the ions
together.
Crystalline structure
Strong, ductile
high thermal & electrical conductivity
reflective. shiny if polished
Can be plastically deformed on the application of
load
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Metallic materials
Metallic materials are further classified into
ferrous, and non-ferrous materials.
Ferrous materials contain large percentage
of iron such as steels and cast irons and
Non-ferrous materials that do not contain
iron or only relatively small amount of iron.
Example of non-ferrous metals are Al, Cu,
Zn, Ti, & Ni. 12/12/14 21WEC
The word polymer is actually taken from two
Greek words, Poly = many and
mer = repeating units or parts.
Polymeric materials are usually long organic
molecular chains i. e., compounds of C & H.
So the polymeric materials are organic
compounds having many repeated units, e.g.,
Teflon, Nylon 6,6, Polythene etc.
Polymeric materials
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Polymeric materials
Polymers/plastics:
Covalent bonding sharing of e’s
Soft, ductile, low strength, low density
thermal & electrical insulators
Optically translucent or transparent.
cheap
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The word ceramics actually is taken from the Greek word
“ Keramos “ = burnt stuff / Clay.
Ceramics are inorganic materials consisting of metallic &
non-metallic elements (oxides, carbides, nitrides, sulfides)
chemically bonded together unlike metallic materials.
They may be crystalline, non-crystalline or mixtures, e.g.,
glass, refractories.
Hard, Brittle, glassy, elastic
non-conducting (insulators)
Difficult to process, low fracture toughness
Ceramic materials
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Examples of ceramic materials ranging from household to high performance combustion engines which utilize both metals and ceramics.
Ceramics
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Composite materials are mixtures of two or more
materials to produce properties that are not produced
in a single material, e.g., Fiber glass, concrete,
plywood etc.
The useful properties which can be produced in such
materials are strength, stiffness, hardness,
temperature resistance, corrosion resistance,
conductivity etc.
High cost
Delamination, etc
Composite materials
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Polymer composite materials: reinforcing glass fibers in a polymer matrix.
Composites
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Electronic materials
Semiconductors: the bonding is covalent (electrons
are shared between atoms).
Their electrical properties depend strongly on
minute proportions of contaminants. Examples: Si,
Ge, GaAs
Electronic materials are used in electronics, especially
microelectronics, e.g., Silicon, Germanium & Gallium
Arsenide etc.
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Si wafer for computer chip devices.
Semiconductors
Micro-Electrical-Mechanical Systems (MEMS)
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The Materials Selection Process
1. Pick Application Determine required Properties
2. Properties Identify candidate Material(s)
3. Material Identify required Processing
Processing: changes structure and overall shapeex: casting, machining, sintering, vapor deposition, doping forming, joining, annealing.
Properties: mechanical, electrical, thermal,magnetic, optical, deteriorative.
Material: structure, composition.
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But:Properties depend on Structure
(strength or hardness)
Har
dne
ss (
BH
N)
Cooling Rate (ºC/s)
100
200
300
400
500
600
0.01 0.1 1 10 100 1000
(d)
30 µm(c)
4 µm
(b)
30 µm
(a)
30 µm
And: Processing can change structure! (see above structure vs Cooling Rate)
12/12/14 35WEC
Properties are the way the material responds to the environment and external forces.Mechanical properties – response to mechanical forces, strength, etc.Electrical and magnetic properties - response electrical and magnetic fields, conductivity, etc.Thermal properties are related to transmission of heat and heat capacity.Optical properties include to absorption, transmission and scattering of light.Chemical stability in contact with the environment - corrosion resistance.
Properties
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Design of materials having specific desired characteristics
directly from our knowledge of atomic structure.
• Miniaturization: “Nanostructured" materials, with
microstructure that has length scales between 1 and 100
nanometers with unusual properties.
•Electronic components, materials for quantum computing.
• Smart materials: airplane wings that adjust to the air flow
conditions, buildings that stabilize themselves in earthquakes…
•
Future of materials science
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•Environment-friendly materials: biodegradable or photodegradable plastics, advances in nuclear waste processing, etc.• Learning from Nature: shells and biological hard tissue can be as strong as the most advanced laboratory-produced ceramics, • Materials
• for lightweight batteries with high storage densities,• for turbine blades that can operate at 2500°C, • room-temperature superconductors?• chemical sensors (artificial nose) of extremely high sensitivity, • cotton shirts that never require ironing…
Future of materials science
Advanced Materials
Materials used in "High-Tec" applications,
usually designed for maximum performance,
and normally expensive. Examples are:
titanium alloys for supersonic airplanes,
magnetic alloys for computer disks,
special ceramics for the heat shield of the space
shuttle, etc. 12/12/14 WEC 44
Advanced Materials Modern Material's Needs Engine efficiency increases at high temperatures: requires high
temperature structural materials Use of nuclear energy requires solving problem with residues,
or advances in nuclear waste processing. Hypersonic flight requires materials that are light, strong and
resist high temperatures. Optical communications require optical fibers that absorb light
negligibly. Civil construction – materials for unbreakable windows. Structures: materials that are strong like metals and resist
corrosion like plastics.
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