Radiation

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2. Radiation heat transfer, its governing laws and its application in Food ProcessingPresented by: Malathi A.N Jr M.tech Dept. of PFE CAE Raichur. Under the guidance of : Dr.Ramchandra.C.T 2 3. Introduction Heat transfer It is transfer of thermal energy from one place to another. When an object is at a different temperature from its surroundings, heat transfer occurs so that the body and the surroundings reach the same temperature at thermal equilibrium.3Such spontaneous heat transfer always occurs from a region of high temperature to another region of lower temperature as required by the second law of thermodynamics. 4. Modes of Heat Transfer: 1) Conduction, or heat transfer by molecular scale vibration and rotation. 2) Radiation, or heat transfer by photons. 3) Convection, or heat transfer by large-scale fluid motion (liquid or gas).4 5. Conduction Heat conduction occurs as hot, rapidly moving or vibratingatoms and molecules interact with neighboring atoms and molecules, transferring some of their energy (heat) to these neighboring atoms. In other words, heat is transferred by conduction whenadjacent atoms vibrate against one another, or as electrons qkAdTx move from one atom dx another. to5 6. Convection This is the process of moving heat around by moving themolecules that contain the heat. E.g. Boiling water in a pan produces convection cells. The waterat the bottom gets heated and it rises to the top, forcing the cool water down, where it gets heated. The water at the top sends its heat into the air so the cycleiscontinuous. q = h A (Tf-Ts) q=amount of heat h=surface heat transfer coefficient6 7. Radiation Thermal radiation is the transfer of heat energy throughempty space by electromagnetic waves. No medium is necessary radiation takes place even in and through a perfectvacuum.For instance, the energy from the Sun travels through the vacuum of space before warming the earth. Radiation is the onlyform of heat transfer that can occur in the absence of any form of medium 7(i.e., through a vacuum). 8. If consider any body totalincident radiation on the body is absorbed, partly reflected and partly emitted.Incident radiationReflected radiation As per the nature of body itcan be8classified into four types Opaque Body t = 0 ; a + r =1 Black Body a =1 ; t =0; r=0 White Body r=1 ; a=0; t=0 Transparent BodyAbsorbed radiationTransmitted radiation 9. Reflectivity () is defined as the ratio of reflectedenergy to the incident energy. Transmissivity () is defined as the fraction of the incident energy that is transmitted through the object. Absorptive () is defined as the fraction ofthe incident energy that is absorbed by the object. Emmisivity ()The ratio of theemissive power of real body (E) to the blackbody emissive power ( Eb at the same temperature is the hemispherical emissivity of the surface. E b9 10. The radiation laws for black-body radiation 1.Plancks law 2.Wiens law3.Stefan-Boltzmann law10 11. Plancks Law This law governs the intensity of radiation emitted byunit surface area into a fixed direction (solid angle) from the blackbody as a function of wavelength for a fixed temperature. 2 hc 2 1 E ,T hc 5 ekT1 h = 6.625 X 10-27 erg-s (Planck Constant) K = 1.38 X 10-16 erg/K (Boltzmann Constant) C = Speed of light in vacuum11Max Planck 1858-1947 12. Wien's Law:Displacement Atany given wavelength, the black body monochromatic emissive power increases with temperature. The wavelength at which the monochromatic emissive power is a maximum is found by setting the derivative of Plancks Equation with respect to K TT2897 . 8 mKWien Where k is a constant equaling 2897.8mk (1864-1928)12max 13. Stefan-Boltzmann Law The radiation energy per unit time from a blackbody is proportional to the fourth power of the absolute temperature and can be expressed with Stefan-Boltzmann Law asq = T4 A Where, q = heat transfer per unit time (W) = 5.6703 10-8 (W/m2K4) Stefan-Boltzmann Constant T = absolute temperature Kelvin (K) A = area of the emitting body (m2) 13Josef Stefan 1835-1893Ludwig Boltzmann 1844-1906 14. Application of Radiation in Food Processing14 15. Approval of radiation processing of food in India In 1994 Government of India amended Prevention ofFood Adulteration Act (1954) Rules, and approvedirradiation of onion, potato and spices for domestic market. Additional items were approved in April 1998 and2001. 15 16. What is radiation processing? Radiation processing is controlled application of energy ofshort wave length radiations of the electromagnetic spectrum knownasionizingradiationsandincludesgammarays, accelerated electrons and X-rays to have desired effecton the product. About 5,00,000 tons of food items are irradiated per year16world wide in over 40 countries. 17. Uses of radiation processing? Some of the major objectives of radiation processing are:1.Sterilization of medical and packaging products 2.Insect disinfestations of food products 3.Inhibition of sprouting in tubers, bulbs and rhizomes 4.Delay in ripening of fruits 5.Enhancement in shelf life by destruction of spoilage microbes in foods 6.Elimination of pathogens and parasites in foods 17 18. Food Irradiation Exposure of foods to ionizing radiation in form ofgamma radiation, X-rays and electron beams to destroy pathogenic microorganism SI unit of irradiation is Gray (Gy). 1Gray = 1 joule of energy absorbed per kg of food material.18 19. Applications low Dose Applications (up to 1 kGy)1.Sprout inhibition in bulbs and tubers 0.03-0.15 kGy 2.Delay in fruit ripening 0.25-0.75 kGy 3.Insect disinfestation parasites 0.07-1 kGy19and elimination of food borne 20. Medium Dose Applications (1 kGy to 10 kGy)1.Reduction of spoilage microbes to prolong shelf-life of meat, poultry and seafoods under refrigeration 1.53 kGy 2.Reduction of pathogenic microbes in fresh and frozen meat, poultry and seafood's 37 kGy. 3.Reducing the number of microorganisms in spices 10 kGy. 20 21. High Dose Applications (above 10 kGy)1.Sterilization of packaged meat, poultry, and their products that are shelf stable without refrigeration 25.00-70.00 kGy 2.Sterilization of Hospital diets 25.00-70.00 kGy21 22. Technologies 1. Electron irradiation 2. X-rays irradiations 3. Gamma irradiations Electron irradiation Electron irradiation uses electrons accelerated in an electric field to a velocity close to the speed of light. Electrons are particulate radiation and, hence have cross section many times larger than photons, so that they do not penetrate the product beyond a few inches, depending on product density.22 23. Gamma irradiation : Gammaradiation is a part of electromagnetic spectrum. The radiation is obtained through the use of radioisotopes. (cobalt-60 or, caesium-137). Presently,caesium-137 is used only in small hospital units to treat blood before transfusion to prevent Graft-versus-host disease. Food irradiation using Cobalt-60 is the preferred23method by most processors, because the deeper penetration enables administering treatment to entire industrial pallets reducing the need for material handling. 24. X-ray irradiation : Similar to gamma radiation, X-rays are photon radiation of awide energyspectrum and an alternative to isotopebased irradiation systems X-ray irradiators are scalable and have deep penetrationcomparable to Co-60. They also permit dose uniformity. Nominal X-ray energy is usually limited to 5 MeV. USA has provisions for up to 7.5 MeV, which increases 24conversion efficiency 25. Effect of Irradiation on Microbes The high energy rays of irradiation directly damagethe DNA of living organisms, inducing crosslinkages and other changes that make an organism unable to grow or reproduce. When these rays interact with water molecules in anorganism, they generate transient free radicals that can cause additional indirect damage to DNA. 25 26. Effectiveness and Benefits of Irradiation From the obvious improvements in food safety through destruction of pathogens, irradiation provides other benefits. Some of these contributions include increasing shelf life of meats Improving quality of fruits and vegetablesProviding a suitable alternative to chemical treatments (e.g., methyl bromide and ethylene oxide), especially for decontamination of fruits and vegetables.Providing economic savings due to reduced incidence of 26illness 27. Un irradiated productsirradiated products Straw BerriesVegetablesCherries 27 28. It kills bacteria's , fungus ,insects . It will not harmful to human health. Delay in ripening and sprouting of vegetable. Irradiated materials are used forpackaging offood. No reaction with the packaging when stored. It will not effect the nutritional value. Foods can be treated after packaging Perishable foods can be kept longer without noticeable quality loss. 28 29. 1. The process is costly 2. There will be risk to human beings exposing to the radiations 3. Large energy sources is required .29 30. Radiation process spices Most spices get heavily contaminated with microbes, including pathogenic bacteria during processing while drying in open. Since radiation processing does not involve increase in temperature and humidity. It extends shelf life of spices in packed form retaining colour, aroma and other sensory properties and at the same time eliminates bacteria and microbes without leaving any chemical residues.30 31. Non Ionizing Radiations Non-ionizing radiationrefers to any type of electromagnetic radiation that does not carry enough energy per quantum to ionize atoms or molecules. Ultraviolet,visiblelight, infrared, microwave, radio waves are allexamples of non-ionizing radiation. 31 32. 32 33. Far Infrared Radiation FIRheating can be classified into 4 majorcategories: baking, drying, thawing and pasteurization Using FIR heating, baking time can be shortened,energy consumption can be reduced, and nutrition and appearance can be better preserved. FIRheatinghelpsreducebeta-carotenechlorophyll degradation in the heating process. 33and 34. Advantage s FIRheating achieved more uniform surface heating than air convection heating. FIR at 80C was found to be the best dryingcondition with a good compromise between drying time and colour of the product.34 35. MICROWAVE HEATING MW are electromagnetic waves generated bymagnetrons and klystrons. Frequency 300MHz Wavelength from 1mm to 1m industrial heating purposes the availablefrequencies are 915 and 2450MHz35 36. Microwaves are absorbed and penetrate the food. The energy of these electromagnetic radiationsexcite the water molecules (in food) which bear a positive electrical charge in one position and a negative charge at another position of the molecules (dipole). When the electric field of the microwave interact with the dipole, the water molecules begin to vibrate very rapidly in food. These vibration produces a friction that creates heat with in the food, thereby cooking it.36 37. Applications Dehydration Pasteurization Sterilization Cooking Baking37 38. How can radiation processed foods be identified in the market ? Irradiatedfood cannot be recognized by sight, smell, taste or touch. Codex Alimentarius Commission has endorsed a green irradiation logo.38 39. As per the PFA (Fifth Amendment) Rules, 1994, allpackages of irradiated foods to be marketed in India will be labeled with this logo, along with the words Processed by Irradiation method , and the date of irradiation, license number of the facility and the purpose of irradiation. Consumers will have a free choice to buy radiation processed or non- radiation processed commodity.39 40. 40