RD Titan Group Innovative TiO2. Full range of technologies for manufacturing of high-end TiO2 grades. Document No-1408IN01.06

RD Titan Group

Innovative TiO2 RD Titan Group Innovative TiO2

Full range of technologies for manufacturing of

high-end TiO2 grades Document No-1408IN01.06

1. Who we are?

We are the group of Scientists and Engineers that has a great experience in TiO2 development,

manufacturing, application and post-sale technical support

We have organized a startup company «RD Titan

Group Innovative TiO2»

The legal European company is under registration process

2

1. Who we are?

3

Our experience in the TiO2

1. Following of old TiO2 plants

reconstruction processes

2. Development and introduction

of innovative technology processes

3. Engineering of the new TiO2 plants

4.Equipment selection and development

5. Development of the new TiO2 grades

for different applications

6. Full technical support of the customers acc

REACH, EU and USA regulations

7. Development of test-methods for the different TiO2

applications

8. Close cooperation with top world TiO2

consumers

2. Our functional structure

4

R&D and QA Division

R&D and PT Division

R&D Lab Department

QA Lab Department

REACH, National

Legislations & IP

Department

3. What we offer?

• Inspection and analysis of different manufacturing stages: from raw material preparation to Packaging & Palletizing. Searching critical points in current technology, providing basic proposition for reconstruction and capital costs evaluation.

• Offers for improvement of technology processes including Know-How implementation for next stages of the sulphate process: Feed Stock Milling, Digestion, Digester Gas Scrubbing, Reduction, Settling & Sludge Filtration, Sludge Neutralisation, Liquor Filtration, Crystallisation & Copperas Removal, Concentration, Hydrolysis, Nuclei Preparation, Waste Acid Concentration, Waste Acid Neutralisation, Pre-Bleach and Post-Bleach Filtration, Bleaching, Additioning (Pre-calcinating salt treatment), Calciner Feed Filtration, Calcination & Cooling, Calciner Gas Scrubbing

• Offers for improvement of technology processes including Know-How implementation for next stages of the sulphate and chloride processes: Dry Milling, Wet Milling, Inorganic Coating, Post-Coat Filtration, Drying, Micronising, Packing & Palletising

• Selection of main equipment, references of best suppliers, engineering of critical parameters of the main equipment for basic design.

• Special technologies for manufacturing of TiO2 grades for different special applications (see details in Section 5)

• Basic and Detail Engineering of the renewal areas of the old TiO2 Plant

• Propositions concerning automatization either for individual stages or for the whole TiO2 plant.

5

1. Consulting , technologies and Know-How for reconstruction of the old TiO2 plants (all stages of the sulphate process and some stages of the chloride process)

3. What we offer?

• Offers for design of the technology processes including Know-How implementation for next stages of the sulphate process: Feed Stock Milling, Digestion, Digester Gas Scrubbing, Reduction, Settling & Sludge Filtration, Sludge Neutralization, Liquor Filtration, Crystallisation & Copperas Removal, Concentration, Hydrolysis, Nuclei Preparation, Waste Acid Concentration, Waste Acid Neutralization, Pre-Bleach and Post-Bleach Filtration, Bleaching, Additioning (Pre-calcinating salt treatment), Calciner Feed Filtration, Calcination & Cooling, Calciner Gas Scrubbing

• Offers for design technology processes including Know-How implementation for next stages of the sulphate and chloride processes: Dry Milling, Wet Milling, Inorganic Coating, Post-Coat Filtration, Drying, Micronising, Packing & Palletising

• Selection of main equipment, recommendations of best vendors, engineering of critical parameters of the main equipment for basic design.

• Propositions concerning automatization either for individual stages or for the whole TiO2 plant.

• Special technologies for manufacturing of TiO2 grades for different special applications (see details in Section 5)

• Basic Engineering and Detail Engineering of the New TiO2 Plant

6

2. Consulting , technologies, Know-How and full engineering of the new TiO2 plants (all stages of the sulphate process and some stages of the chloride process)

3. What we offer?

• Providing the test methods for TiO2 manufacturing technology control including optimal value range for the processes (from raw material stages to packaging and palletizing stage).

• Providing the test methods for quality control of the finished products for different applications including optimal value range of parameters.

• Assistance in evaluation of the customer requirements and development special quality control test methods for satisfaction of these requirements.

• Assistance in designing of manufacturing process changes for satisfaction of specific customers’ requirements.

• Assistance in TiO2 sales promotion inclusive specific requirements of different customers.

7

3. Test methods for intermediate control of the technological processes, quality control test methods, customer test methods , technical support and technical product promotion

4. Our Engineering Solutions and Know-How

8

Digestion

Reduction

Settling and Sludge

Filtration

Liquor Filtration

Crystallization & Copperas

removal

Digester Gas Scrubbing

Hydrolysis

Pre-Bleach Filtration

Bleaching Post-Bleach

Filtration

Additioning

Calciner Feed

Filtration

Calcination & Cooling

Calciner Gas Scrubbing

Ti-Ore Chlorination

Chlorides condensation

TiCl4 Purification

TiCl4 Oxidation

Dry Milling

Wet Milling

Inorganic Coating

Micronising

Drying

Post-Coating Filtration

Packaging & Palletising

Sulphate process

Chloride process

Common area of Sulphate and Chloride processes


9

Digestion

Reduction

Settling and Sludge

Filtration

Liquor Filtration

Crystallization & Copperas

removal

Digester Gas Scrubbing

Hydrolysis

Pre-Bleach Filtration

Bleaching Post-Bleach

Filtration

Additioning

Calciner Feed

Filtration

Calcination & Cooling

Calciner Gas Scrubbing

Dry Milling

Wet Milling

Inorganic Coating

Micronising

Drying

Post-Coating Filtration

Packaging & Palletising

Sulphate process

Common area of Sulphate and Chloride processes

We can propose the technologies, knowledge and Know-How of Sulphate process (yellow background) and for Common area of Sulphate and Chloride processes (green background)


10

#

General

Name of

the Area Stage Description Name of technologies and Know-How

Ti Black TB00001 Ti Black Digestion TB2000 011 Digestion stage optimization (selection of titan ore digestion mode)

2 Ti Black Digestion TB2000 021 Reaction mass agitation stage optimization during titanium ore digestion

3 Ti Black Digestion TB2000 031 Leaching stage optimization

4 Ti Black

Digester Gas

Scrubing TB2500 011Digester Gas Scrubing stage optimization when using ilmenite

5 Ti Black

Digester Gas

Scrubing TB2500 012Digester Gas Scrubing stage optimization when using ilmenite

6 Ti Black

Digester Gas

Scrubing TB2500 021Digester Gas Scrubing stage optimization when using slag

7 Ti Black

Digester Gas

Scrubing TB2500 022Digester Gas Scrubing stage optimization when using slag

8 Ti Black External Reduction TB3000 011 Reduction stage optimization for increasing of titanylsulphate constancy

9 Ti Black External Reduction TB3000 012 Reduction stage optimization for increasing of titanylsulphate constancy

10 Ti Black

Settling and Sludge

Filtration TB4000 011Settling stage optimization

11 Ti Black

Settling and Sludge

Filtration TB4000 012Settling stage optimization

12 Ti Black

Settling and Sludge

Filtration TB4000 021Sludge filtration stage optimization

13 Ti Black Liquor Filtration TB5000 011 Liquor Filtration stage optimization

14 Ti Black

Cristallisation &

Copperas Removal TB6000 010Cristallisation stage optimization

15 Ti Black

Cristallisation &

Copperas Removal TB6000 011Copperas removal stage optimization

Classification by RD

Titan Group

Innovative TiO2


11

#

General

Name of


Ti Grey TG000016 Ti Grey Hydrolysis TG1000 011 Hydrolysis stage optimization for rutile TiO2 manufacturing

17 Ti Grey Hydrolysis TG1000 012 Hydrolysis stage optimization for rutile TiO2 manufacturing

18 Ti Grey Pre-Bleach Filtration TG2000 011Pre-Bleach filtration stage optimization

19 Ti Grey Pre-Bleach Filtration TG2000 012Increasing of TiO2 extraction from weak acid

20 Ti Grey Bleaching TG3000 011 Bleach stage optimization for achievement optimal Ti3+ level

21 Ti Grey

Post-Bleach

Filtration TG4000 011Post-Bleach filtration stage optimization

22 Ti Grey Additioning TG5000 011

Additioning (Salt treatment) stage optimization for control fo calcination

process and properties of TiO2

23 Ti Grey Additioning TG5000 012

Additioning (Salt treatment) stage optimization for control fo calcination

process and properties of TiO2

24 Ti Grey

Calciner Feed

Filtration TG6000 011Calciner feed filtration stage optimization

25 Ti Grey

Calcination &

Cooling TG7000 011Calcination and Cooling stage optimization

26 Ti Grey

Calciner Gas

Scrubing TG7500 011Calciner Gas Scrubing stage optimization

27 Ti Grey

Calciner Gas

Scrubing TG7500 012Calciner Gas Scrubing stage optimization


Titan Group

Innovative TiO2


12

#

General

Name of


Ti White TW0000

28 Ti White Dry Milling TW1000 011 Dry milling stage optimization

29 Ti White Wet Milling TW2000 011 Wet milling stage optimization

30 Ti White Wet Milling TW2000 012 Wet milling stage optimization

31 Ti White Wet Milling TW2000 013 Wet mill stage optimization for particle size distribution control

32 Ti White Innorganic Coating TW3000 011

Inorganic and Organic Coating technologies for production TiO2 grades for

different application - Paint and Coatings, Plastics, Paper (detailed

description please see in Section 5)

33 Ti White

Post-Coating

Filtration TW4000 011Post-Coating filtration stage optimization

34 Ti White

Post-Coating

Filtration TW4000 012Increasing of TiO2 extraction from Post-Coating stage filtrates

35 Ti White Drying TW5000 011 Drying stage optimization

36 Ti White Micronising TW6000 011 Micronising stage optimization

37 Ti White Micronising TW6000 012 Micronising stage optimization

38 Ti White

Packaging &

Palletising TW7000 011

Temporary storage and transportation stage (pre-packaging stage)

optimization

39 Ti White

Packaging &

Palletising TW7000 012Packaging & Palletising stage optimization


Titan Group

Innovative TiO2


All Ti and further Areas: – Support in selection of pipes materials, pumps etc.

– Optimization of solid and liquid wastes of neutralization and utilization stage

– Optimization of the stage of weak acid recovering

13

5. Technologies for different TiO2 grades

14 Paint and Coatings

Plastics Décor Paper

Nano + Food

Tod

ay

Du

rin

g n

ext

2

year

s D

uri

ng

nex

t 5

yea

rs

RC-30

RC-31 RC-74

RC-54

RC-80

RC-44

RP-12 RP-32

RP-13

RP-72 RP-33

RP-73

RL-96

FA-171 RL-98

RC-8828

RP-8829 RL-8950 NR-5-20di-II

NR-5-20 NR-5-20di

Infrared

NR-15-60di

NR-70-120di NA-10-20/390

NA-10-20/450 NA-10-20/450-II

NA-5-10/390

IR-A-I

IR-A-II

IR-B



RC-54

Tod

ay

Tioxide TR-92

Tiona 595

Kronos 2315

Sachtleben R-KB-6

Tronox CR-828

RC-74

DuPont R-706

DuPont TS-6200

Tiona 596

Kronos 2160

Tiona-696

Kronos 2360

Tronox CR-800

Tronox CR-826

RC-44

DuPont R-902+

Tiona-RK-B-2

Sachtleben R-KB-2



Tod

ay

RC-44 RC-54 RC-74

1 Applications

Water-borne and Solvent-borne

Industrial and Decorative Coatings

Automotive finishes and refinishes

Coil Coatings

Powder coatings

Marine Coatings

Exterior Coatings

Automotive Finishes and

Refinishes

Coil Coatings

Powder Coatings

Marine Coatings

Aerospace Coatings

2 Properties

Easy Dispersibility

Medium durability

Good resistance to sedimentation

in Waterborn systems

Easy Dispersibility

High Opacity

Good Initial Gloss

Good Gloss Retention

High Durability

Dispersibility

High Opacity


Superior Durability

3 Specifications

3.1 TiO2 content 92-94% typical 93-95% typical 91-93% typical

3.2 Inorganic coating Alumina, Silica Alumina, Zirconia Alumina, Silica

3.3 Organic treatment present present present

3.4 Loss at 105oC <0.5% <0.5% <0.5%

3.5 Oil absorption 19-21 cm3/100g pigment 18-20 cm3/100g pigment 20-22 cm3/100g pigment

3.6 Lattice Rutile 97-100% Rutile 97-100%, Stabilized Rutile 97-100%, Stabilized

3.7 ISO 591-1:2000 R2 R2 R2

Grade name

Data#



RC-30

Tod

ay

Kronos 2020

Tiona 568

DuPont R-900

Sachtleben RDI

Sachtleben RODI

RC-31

Ishihara R-630

Sachtleben RDI-S

Kronos 2063

Kronos 2090

Sachtleben R-FD-I

Tioxide TR-52 RC-80

Kronos 2044

Tioxide RXL

Sachtleben RDDI

Sachtleben R-210

Tronox CR-800

Sachtleben R-KB-3

Tioxide R-TC-90

DuPont R-931



Tod

ay

RC-30 RC-31 RC-80

1 Applications

Electrodeposition paints

Automotive (Primers)

Can Coatings

Coil Coatings

Water-borne and Solvent-borne

Industrial and Decorative Coatings

Wood Paints

Rubber

Plastics (usable)

Can use in Printing Inks

Printing Inks

Can Coatings

Coil Coatings

Wood Paints

Water-born or solvent-born coatings

with very high gloss

Highly pigmented

emulsion paints

Exterior and interior trade sales

paints

Paper filler and coating applications

Wallpaper coatings

Flat flexographic inks

2 Properties

Excellent Dispersibility

High Opacity

High Gloss

Low Oil Absorption

Low conductivity

Super Dispersibility

High Opacity

Excellent High Gloss

Low Oil Absorption

Blue undertone

High opacity at high pigment

volume concentration

High brightness and neutral tone

Readily dispersed in all types of

milling equipment

3 Specifications


3.2 Inorganic coating Alumina Alumina Alumina, Silica

3.3 Organic treatment present present none

3.4 Loss at 105oC <0.5% <0.5% <2.5%

3.5 Oil absorption 16-18 cm3/100g pigment 16-18 cm3/100g pigment 42-46 cm3/100g pigment

3.6 Lattice Rutile 97-100% Rutile 97-100% Rutile 97-100%

3.7 ISO 591-1:2000 R2 R2 R3

3.8

Conductivity of

extract from 33%

slurry of TiO2

(according DIN

19529:2009-01) <200 mS/cm no data no data

# Data

Grade name


19 Plastics

Tod

ay

RP-13

RP-33

RP-12

RP-72 RP-32

RP-73 Kronos 2230

DuPont R-104

Kronos 2500

Tioxide TR-38

Tioxide R-FK-5

Tiona-188

Tioxide TR-23

Tiona-125

Tioxide TR-28

Sachtleben R-FK-2

Tronox CR-470

Tronox 8400

Tronox 834

Kronos 2233

Kronos 2450

Tiona RL-91

Tiona 90

Sachtleben 405

DuPont R-350

Kronos 2225

Kronos 2211

Kronos 2222

Tiona 168

DuPont R-105

Tioxide R-TC30

Kronos 2220

Sachtleben R-FK-3

Tronox 435


20 Plastics

Tod

ay

RP-12/RP-13 RP-32/RP-33 RP-72/RP-73

1 Applications

Polyolefin Masterbatch

Flexible PVC (interior)

High Temperature Cast Films

Thin Films

PVC-plastisols

Polyolefin Masterbatch

Polyethylene

Polypropylene

PVC (Interior)

PVC (Exterior, Chalking)

PVC Pipe

PVC and polyolefines (Exterior,

Nonchalking)

Agricultural Films

Outdoor Furniture

PVC-Windows sections

2 Properties

Outstanding Dispersion and

Processing

High Hydrophobic feature

No Migration of Organic Compound

Lacing Resistance

High Opacity

Blue Tint Tone and High Brightness

Outstanding Dispersion and

Processing

High Hydrophobic feature


Lacing Resistance

High Opacity

Blue Tint Tone and High Brightness

Easily Incorporated in Vinyl and

Polyolefins

Minimized Hygroscopic Property

Excellent Color Retention


High Durability

Good Chalk Resistance

Effective UV Screen

3 Specifications


3.2 Inorganic coating Alumina Alumina Alumina, Silica

3.3 Organic treatment present present present

3.4 Loss at 105oC <0.1% <0.2% <0.5%

3.5 Surface High hydrophobic features High hydrophobic features High hydrophobic features

3.6 Lattice Rutile 97-100% Rutile 97-100% Rutile 97-100%, Stabilized

3.7 ISO 591-1:2000 R1 R2 R2

# Data

Grade name


21 Décor Paper

Tod

ay

Du

rin

g n

ext

2 y

ears

D

uri

ng

nex

t 5

ye

ars

RL-96

Kronos 2800

Tronox 820

Sachtleben R-610L

Sachtleben R-PL-2

DuPont R-796+

Tiona RCL-722

No analogues, some top-companies are

conducting research

RL-98

No analogues, no data about

researches by other companies

RL-8950


22 Décor Paper

Du

rin

g n

ext

2 y

ears

D

uri

ng

nex

t 5

yea

rs RL-98 RL-8950

1 Applications

High and Low Pressure Laminate

Printing Inks for Décor Paper

Melamine moulding powders

High and Low Pressure Laminate

for outdoor applications

Printing Inks for Décor Paper for

outdoor applications

Melamine moulding powders for


New laminate paper products for


2 Properties

Outstanding Greying Resistance to

Paper Laminate

Good Yellowing Resistance to High

and Low Pressure Laminate

Superior Opacity, high brightness and

low yellowness

Dispersed readily in Water

Superior Greying Resistance to

Paper Laminate

Good Yellowing Resistance to High

and Low Pressure Laminate

Superior Opacity, high brightness

and low yellowness

Dispersed readily in Water

3 Specifications

3.1 TiO2 content 87-90% typical 85-92% typical

3.2 Inorganic coating Aluminium compounds Aluminium compounds

3.3 Organic treatment none none

3.4 Loss at 105oC <0.8% <1,0%

3.5

Light stability (Blue

Wool Scale) ~7 double 8

3.6 Lattice Rutile 97-100%, Stabilized Rutile 97-100%, Stabilized

3.7 ISO 591-1:2000 R3 R3

# Data

Grade name


23 Paint and Coatings Plastics

Du

rin

g n

ext

5 y

ears





RP-8829 RC-8828


24 Paint and Coatings Plastics

Du

rin

g n

ext

5 y

ears

RC-8828 RP-8829

1 Applications

New coatings with superior weattherability

Exterior Coatings

Automotive Finishes and Refinishes

Coil Coatings

Powder Coatings

Marine Coatings

Aerospace Coatings

New plastics with superior weatherability

PVC and polyolefines (Exterior, Nonchalking)

Agricultural Films

Outdoor Furniture

PVC-Windows sections

2 Properties

Dispersibility

High Opacity


100% Durability (no any TiO2-photocatalysis

dependent chalking and gloss losses)

Easily Incorporated in Vinyl and Polyolefins

Minimized Hygroscopic Property

Excellent Color Retention (no any TiO2-

photocatalysis dependent color changes)


100% Durability (no any TiO2-photocatalysis

dependent chalking)

Effective UV Screen

3 Specifications

3.1 TiO2 content 90-93% typical 90-93% typical

3.2 Inorganic coating Alumina, Silica Alumina, Silica

3.3 Organic treatment present present

3.4 Loss at 105oC <0.5% <0.5%

3.5 Oil absorption 20-22 cm3/100g pigment no data

3.6 Surface Hydrophilic features High hydrophobic features

3.7 Lattice Rutile 97-100%, Stabilized Rutile 97-100%, Stabilized

3.8 ISO 591-1:2000 R2 R2

3.9 ISO 591-1:2000 R2 R2

# Data

Grade name

Low-photocatalytic nano-TiO2 grades of Sachtleben and other companies

for UV-screening

Photocatalitic nano-TiO2 grades of Sachtleben, Kronos and other

companies


25 Nano + Food

Du

rin

g n

ext

2

year

s D

uri

ng

nex

t 5

yea

rs

FA-171

NR-5-20di-II

NR-5-20 NR-5-20di

Infrared

NR-15-60di

NR-70-120di

NA-10-20/390

NA-10-20/450 NA-10-20/450-II

NA-5-10/390

IR-A-I IR-A-II

IR-B

Altiris 550

Altiris 800

Kronos 1171

Hombitan AFDC

PRETIOX AV-01-FG/PhG


26 Nano + Food

Du

rin

g n

ext

2

year

s D

uri

ng

nex

t 5

yea

rs

Infrared

FA-171

Photocatalytic Nano-TiO2

grades

Low-photocatalytic Nano-

TiO2 grades

Infrared reflecting TiO2

pigments

1 Applications

Foodstuffs

Pharmaceutics

Сosmetics

Сigarette paper

NOx-decomposition

Self-cleaning coatings

Bacterial purification

Air purification

Cosmetics

UV-screening for Plastics and

Coatings

UV-screening for Building and

Construction

UV-screening for Agricultural

Films

UV-screenin for non-food

Packing

UV-screening for Fiber

Paints and Coatings with

infrared reflecting properties

Plastics with infrared reflecting

properties

2 Properties

This anatase grade complies with the

following product safety regulations:

European Union:78/25/EEC

(pharmaceuticals), 76/768/EEC,

1333/2008/EC, 2008/128/EC (food

color), 96/335/EC (cosmetics),

European Pharmacopoeia. USA: FDA

Regulation 21 CFR 73.2575 (cosmetics),

US Pharmacopeia XXIV. UN: Food and

Agriculture Organization (FAO), World

Health Organization (WHO).

Each of grades according

application requirements





# Data

Grade name

6. Development of strategic technologies for the next fifteen years

27

1. Special TiO2-grades according customer requirements. • Additional TiO2 grades not listed on this presentation • Any required modification of grades listed on this presentation

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28

2. New patented technology of TiO2 manufacturing by chloride process (for special customer order) . • New chloride method which could be patented • Best quality of finished products • Best economic efficiency of process • Best waste recovery solutions • Possibility to use raw materials with relatively low TiO2 content

Du

rin

g n

ext

15

yea

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29

3. New patented technology of TiO2 manufacturing by alternative novel process (not classic like sulphate or chloride processes). • New alternative novel method which could be patented and commercialized. • Best quality of finished products • Best economic efficiency of process • Best waste recovery solutions • Possibility to use raw materials with very low TiO2 content (even low cost not-for-TiO2-manufacturing ilmenite kinds)

Du

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g n

ext

15

yea

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30

4. Novel generation of the i-TiO2 pigments. It is revolutionary class of TiO2 pigments which will change the white pigment market • New properties • Cost effective • New applications i-TiO2: innovations * intellect * intensity

Du

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15

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All titanium dioxide technologies in one place

RD Titan Group

Innovative TiO2

www.innovativetio2.com [email protected] Skype: info.innovativetio2

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Technology

RD Titan Group Innovative TiO2. Full range of technologies for manufacturing of high-end TiO2 grades. Document No-1408IN01.06