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LONGHORN ARMY AMMUNITION PLANT
KARNACK, TEXAS
ADMINISTRATIVE RECORD
CHRONOLOGICAL INDEX
Volume 6 of
2010
Bate Stamp Numbers 00087185 – 00087951
Prepared for
Department of the Army Longhorn Army Ammunition Plant
1976 – 2010
LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS
ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX
VOLUME 6 of 2010 A Title: Report (Continued) - Final Addendum to Final Feasibility Study LHAAP-16, Longhorn Army Ammunition Plant, Karnack, Texas Author(s): Shaw Environmental, Inc., Houston, Texas Recipient: All Stakeholders Date: March 30, 2010 Bate Stamp: 00087185 - 00087951
158 Starlite Drive, Marietta, OH 45750 • T:740-373-4071 • F:740-373-4835 • http://www.microbac.com
Laboratory Report Number: L09030427
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories.
Review and compilation of your report was completed by Microbac’s Sales and Service Team. If you have questions,comments or require further assistance regarding this report, please contact your team member noted in the reviewedbox below at 800-373-4071. Team member e-mail addresses also appear here for your convenience.
Kathy Albertson Team Chemist/Data Specialist kalbertson@microbac.comStephanie Mossburg Team Chemist/Data Specialist smossburg@microbac.comTony Long Team Chemist/Data Specialist tlong@microbac.comAmanda Fickiesen Client Services Specialist afickiesen@microbac.comAnnie Brown Client Services Specialist abrown@microbac.comJacqueline Parsons Team Assistant jparsons@microbac.com
This report was reviewed on March 26, 2009.
Stephanie Mossburg - Team Chemist/Data Specialist
I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soilsamples are reported on a ’dry-weight’ basis unless specified otherwise. Analytical results for water and wastes arereported on a ’as received’ basis unless specified otherwise. A statement of uncertainty for each analysis is availableupon request. This laboratory report shall not be reproduced, except in full, without the written approval of MicrobacLaboratories.
This report was certified on March 26, 2009.
David Vandenberg - Managing Director
State of origin: TexasAccrediting authority: Texas Commission on Environmental Quality ID:T104704252-07-TXQAPP: Microbac OVDThis report contains a total of 187 pages.
Look closer. Go further. Do more.
1
00087185
Microbac REPORT L09030427PREPARED FOR Shaw E I, Inc.WORK ID: LHAAP-16
1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.1 Volatiles Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
2.1.1 Volatiles GCMS Data (8260) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202.1.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212.1.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
2.2 Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 842.2.1 Metals ICP-MS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
2.2.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 862.2.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
2.3 General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1492.3.1 Method 9056 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
2.3.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1512.3.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
3.0 Attachments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
2
00087186
1.0 Introduction
3
00087187
ID: 91238
Microbac Laboratories Inc.REPORT NARRATIVE
Microbac Login No: L09030427
CHAIN OF CUSTODY: The chain of custody number was 5792.
SHIPMENT CONDITIONS: The chain of custody forms were received sealed in a cooler. The cooler temperaturewas 3 degrees C.
SAMPLE MANAGEMENT: All samples received were intact.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and MicrobacLaboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designated person, asverified by the following signature.
Approved: 20-MAR-09
4
00087188
Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
XR5 Test reports/summary forms for blank samples;XR6 Test reports/summary forms for laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.
MICHAEL D. COCHRAN Semivolatiles Lab Supervisor March 26, 2009
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
5
00087189
Checklist ID: 37099
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 9056Prep Batch Number(s): WG298057Reviewer Name: MICHAEL D. COCHRANLRC Date: March 23, 2009
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X
Were response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
8
00087192
Checklist ID: 37099
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 9056Prep Batch Number(s): WG298057Reviewer Name: MICHAEL D. COCHRANLRC Date: March 23, 2009
EXCEPTIONS REPORTER# - Description(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
9
00087193
Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:XR1 Field chain-of-custody documentation;XR2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
XR4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
XR5 Test reports/summary forms for blank samples;XR6 Test reports/summary forms for laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
XR7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
XR8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
XR9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;XR10 Other problems or anomalies.XThe exception Report for every ”No” or ”Not Reviewed (NR)” item IN laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, if applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is true.
MIKE D. ALBERTSON Volatiles Lab Supervisor March 26, 2009
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
10
00087194
Checklist ID: 37106
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 8260BPrep Batch Number(s): WG297819, WG297941Reviewer Name: MIKE D. ALBERTSONLRC Date: March 26, 2009
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X
ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
EXCEPTIONS REPORTER# - Description1) Dibromofluoromethane was below the lower control limit in the 10x analysis of sample 05 and exceeded the upper control limit insamples 03 and 11.2) 2-Butanone exceeded the upper advisory limit in the LCS/LCSD analyzed 03/20/09. 2-Butanone exceeded the upper advisory limitand isopropylbenzene was below the lower control limit in the LCS/LCSD analyzed 03/23/09.3) 2-Hexanone and 1,2-dibromo-3-chloropropane exceeded the upper advisory limits in the LCS/LCSD analyzed 03/23/09.
Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
13
00087197
Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.
MAREN M. BEERY Metals Supervisor March 20, 2009
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
14
00087198
Checklist ID: 36953
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG297722Reviewer Name: MAREN M. BEERYLRC Date: March 20, 2009
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X ER1
ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
17
00087201
Checklist ID: 36953
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L09030427Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG297722Reviewer Name: MAREN M. BEERYLRC Date: March 20, 2009
EXCEPTIONS REPORTER#1- Due to high levels of nontarget analytes, client samples 01 through 10 were analyzed at dilutions for all analytes.ER2 - Client sample 02 required further dilution analysis in order to obtain a result for chromium within the linear range.Client sample 04 required further dilution analysis in order to obtain a result for manganese within the linear range. Clientsample 10 required further dilution analysis in order to obtain a result for nickel within the linear range.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
18
00087202
2.1 Volatiles Data
19
00087203
2.1.1 Volatiles GCMS Data(8260)
20
00087204
2.1.1.1 Summary Data
21
00087205
LABORATORY REPORT
03/26/09 16:12
L09030427
1 OFL1_A_PROD - Modified 03/06/2008
03/26/2009 16:12Report generated:1351447PDF File ID:
1
L09030427-03
L09030427-05
L09030427-05
L09030427-11
16WW32-031709
16WW16-031709
16WW16-031709
TRIP BLANK
Client ID Lab ID Dilution
1
250
10
1
Sample Analysis Summary
Date Received
19-MAR-09
19-MAR-09
19-MAR-09
19-MAR-09
Attention: Jennifer Hoang
Account Name: Shaw E & I, Inc.ABB Lummus Biulding3010 Briarpark Drive Suite 4NHouston, TX 77042
Project Number:
Site:
2773.025Longhorn AAP
P.O. Number: 389869/ 390836(GWTP)
Submitted By
For
Microbac Laboratories Inc.
158 Starlite Drive
Marietta OH 45750,740 373 4071)( -
Method
8260B
8260B
8260B
8260B
LHAAP-16Project:
22
00087206
L09030427
March 26, 2009
Report Number:
Report Date :
1 of
Microbac Laboratories Inc.
8
L09030427-03Sample Number: HPMS10Instrument:
10M71271File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
14:15Workgroup Number:Matrix: Analytical Method:Water
16WW32-031709Client ID:
Sample Tag:01Dilution:
Units:
WG2979418260BTMB1ug/L
Collect Date:03/17/2009 12:05
Prep Method:5030B 03/23/2009 14:15Prep Date:
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene Ethylbenzene 2-Hexanone Hexachlorobutadiene Isopropylbenzene p-Isopropyltoluene 4-Methyl-2-pentanone Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane
UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU
2.500.1250.1250.2000.2500.5000.5002.500.2500.2500.2500.5000.2500.1250.2500.5002.000.1250.2500.1250.2501.000.2500.2500.1250.2500.1250.2500.1250.2500.5000.2500.2500.2000.2000.2500.2500.5000.2500.2502.500.2500.2500.2502.500.2500.2000.1250.1250.2500.1250.2500.2500.1500.2000.2500.2500.2500.250
10.01.001.001.001.001.001.0010.01.001.001.001.001.001.001.001.0010.01.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.0010.01.001.001.0010.05.001.001.001.001.001.001.001.001.001.001.001.001.001.00
67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
23
00087207
L09030427
March 26, 2009
Report Number:
Report Date :
2 of
Microbac Laboratories Inc.
8
L09030427-03Sample Number: HPMS10Instrument:
10M71271File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
14:15Workgroup Number:Matrix: Analytical Method:Water
16WW32-031709Client ID:
Sample Tag:01Dilution:
Units:
WG2979418260BTMB1ug/L
Collect Date:03/17/2009 12:05
Prep Method:5030B 03/23/2009 14:15Prep Date:
U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of range
86808886
118120110115
12110299.490.4
* Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
Surrogate Lower Upper% Recovery Qual
1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-,p-Xylene
UUUUUUU
0.5000.2500.2502.500.2500.2500.500
1.001.001.0010.01.001.001.00
96-18-495-63-6108-67-8108-05-475-01-495-47-6
136777-61-2
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
24
00087208
L09030427
March 26, 2009
Report Number:
Report Date :
3 of
Microbac Laboratories Inc.
8
L09030427-05Sample Number: HPMS10Instrument:
10M71272File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
14:47Workgroup Number:Matrix: Analytical Method:Water
16WW16-031709Client ID:
Sample Tag:DL02Dilution:
Units:
WG2979418260BTMB250ug/L
Collect Date:03/17/2009 14:35
Prep Method:5030B 03/23/2009 14:47Prep Date:
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene Ethylbenzene 2-Hexanone Hexachlorobutadiene Isopropylbenzene p-Isopropyltoluene 4-Methyl-2-pentanone Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane
UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU
UUUUUUUUUUUUUUUUUUUUUUUUU
U
62531.331.350.062.512512562562.562.562.512562.531.362.512550031.362.531.362.525062.562.531.362.531.362.531.362.512562.562.550.050.062.562.512562.562.562562.562.562.562562.550.031.331.362.531.362.562.537.550.062.562.562.562.5
2500250250250250250250250025025025025025025025025025002502502502501250250250250250250250250250250250250250250250250250250250250025025025025001250250250250250250250250250250250250250250
11800
18900
67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
25
00087209
L09030427
March 26, 2009
Report Number:
Report Date :
4 of
Microbac Laboratories Inc.
8
L09030427-05Sample Number: HPMS10Instrument:
10M71272File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
14:47Workgroup Number:Matrix: Analytical Method:Water
16WW16-031709Client ID:
Sample Tag:DL02Dilution:
Units:
WG2979418260BTMB250ug/L
Collect Date:03/17/2009 14:35
Prep Method:5030B 03/23/2009 14:47Prep Date:
U Not detected at or above adjusted sample detection limit
86808886
118120110115
11810499.788.9
Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
Surrogate Lower Upper% Recovery Qual
1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-,p-Xylene
UUUU
UU
12562.562.562562.562.5125
2502502502500250250250
772
96-18-495-63-6108-67-8108-05-475-01-495-47-6
136777-61-2
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
26
00087210
L09030427
March 26, 2009
Report Number:
Report Date :
5 of
Microbac Laboratories Inc.
8
L09030427-05Sample Number: HPMS10Instrument:
10M71245File ID:03/20/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
18:49Workgroup Number:Matrix: Analytical Method:Water
16WW16-031709Client ID:
Sample Tag:DL01Dilution:
Units:
WG2978198260BTMB10ug/L
Collect Date:03/17/2009 14:35
Prep Method:5030B 03/20/2009 18:49Prep Date:
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene Ethylbenzene 2-Hexanone Hexachlorobutadiene Isopropylbenzene p-Isopropyltoluene 4-Methyl-2-pentanone Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane
UUUUUUUUUUUUUUUUUUUUUUUUUUUUU
I
UUUUUUUUUUUUUUUUUUUUUUUUIU
25.01.251.252.002.505.005.0025.02.502.502.505.002.501.252.505.0020.01.252.501.252.5010.02.502.501.252.501.252.501.252.505.002.502.502.002.002.502.505.002.502.5025.02.502.502.5025.02.502.001.251.252.501.252.502.501.502.002.502.502.502.50
10010.010.010.010.010.010.010010.010.010.010.010.010.010.010.010010.010.010.010.050.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010.010010.010.010.010050.010.010.010.010.010.010.010.010.010.010.010.010.010.0
29.643.2950024.0
14200
67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
27
00087211
L09030427
March 26, 2009
Report Number:
Report Date :
6 of
Microbac Laboratories Inc.
8
L09030427-05Sample Number: HPMS10Instrument:
10M71245File ID:03/20/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
18:49Workgroup Number:Matrix: Analytical Method:Water
16WW16-031709Client ID:
Sample Tag:DL01Dilution:
Units:
WG2978198260BTMB10ug/L
Collect Date:03/17/2009 14:35
Prep Method:5030B 03/20/2009 18:49Prep Date:
U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of rangeI Semiquantitative result (out of instrument calibration range)
86808886
118120110115
70.099.811087.2
* Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
Surrogate Lower Upper% Recovery Qual
1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-,p-Xylene
UUUU
UU
5.002.502.5025.02.502.505.00
10.010.010.010010.010.010.0
564
96-18-495-63-6108-67-8108-05-475-01-495-47-6
136777-61-2
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
28
00087212
L09030427
March 26, 2009
Report Number:
Report Date :
7 of
Microbac Laboratories Inc.
8
L09030427-11Sample Number: HPMS10Instrument:
10M71269File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
13:10Workgroup Number:Matrix: Analytical Method:Water
TRIP BLANKClient ID:
Sample Tag:01Dilution:
Units:
WG2979418260BTMB1ug/L
Collect Date:03/18/2009 00:01
Prep Method:5030B 03/23/2009 13:10Prep Date:
Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon disulfide Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethyl vinyl ether Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,1-Dichloropropene Ethylbenzene 2-Hexanone Hexachlorobutadiene Isopropylbenzene p-Isopropyltoluene 4-Methyl-2-pentanone Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane
UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU
2.500.1250.1250.2000.2500.5000.5002.500.2500.2500.2500.5000.2500.1250.2500.5002.000.1250.2500.1250.2501.000.2500.2500.1250.2500.1250.2500.1250.2500.5000.2500.2500.2000.2000.2500.2500.5000.2500.2502.500.2500.2500.2502.500.2500.2000.1250.1250.2500.1250.2500.2500.1500.2000.2500.2500.2500.250
10.01.001.001.001.001.001.0010.01.001.001.001.001.001.001.001.0010.01.001.001.001.005.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.001.0010.01.001.001.0010.05.001.001.001.001.001.001.001.001.001.001.001.001.001.00
67-64-171-43-2108-86-174-97-575-27-475-25-274-83-978-93-3104-51-8135-98-898-06-675-15-056-23-5108-90-7124-48-175-00-3110-75-867-66-374-87-395-49-8106-43-496-12-8106-93-474-95-395-50-1541-73-1106-46-775-71-875-34-3107-06-275-35-4156-59-2156-60-578-87-5142-28-9594-20-710061-01-510061-02-6563-58-6100-41-4591-78-687-68-398-82-899-87-6108-10-175-09-291-20-3103-65-1100-42-5630-20-679-34-5127-18-4108-88-387-61-6120-82-171-55-679-00-579-01-675-69-4
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
29
00087213
L09030427
March 26, 2009
Report Number:
Report Date :
8 of
Microbac Laboratories Inc.
8
L09030427-11Sample Number: HPMS10Instrument:
10M71269File ID:03/23/2009Run Date:Analyst:03/18/2009 15:23Cal Date:
13:10Workgroup Number:Matrix: Analytical Method:Water
TRIP BLANKClient ID:
Sample Tag:01Dilution:
Units:
WG2979418260BTMB1ug/L
Collect Date:03/18/2009 00:01
Prep Method:5030B 03/23/2009 13:10Prep Date:
U Not detected at or above adjusted sample detection limit* Surrogate or spike compound out of range
86808886
118120110115
11910399.589.1
* Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene
Surrogate Lower Upper% Recovery Qual
1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride o-Xylene m-,p-Xylene
UUUUUUU
0.5000.2500.2502.500.2500.2500.500
1.001.001.0010.01.001.001.00
96-18-495-63-6108-67-8108-05-475-01-495-47-6
136777-61-2
Analyte QualResultCAS. Number PQL SDL
NONEPrePrep Method:
30
00087214
2.1.1.2 QC Summary Data
31
00087215
Example 8260 Calculations
1.0 Calculating the Response Factor (RF) from the initial calibration (ICAL) data:
RF = [ (Ax) (Cis) ] / [ (Ais) (Cx) ]Example
where:Ax = Area of the characteristic ion for the compound being measured: 3399156Cis = Concentration of the specific internal standard (ug/mL) 25Ais = Area of the characteristic ion of the specific internal standard 846471Cx = Concentration of the compound in the standard being measured (ug/mL) 100
RF = Calculated Response Factor 1.0039
2.0 Calculating the concentration ( C ) of a compound in water using the average RF: *
Cx = [ (Ax) (Cis) (Vn)(D)] / [ (Ais) (RF) (Vs) ]Example
where:Ax = Area of the characteristic ion for the compound being measured 3122498Cis = Concentration of the specific internal standard (ug/L) 25D = Dilution factor for sample as a multiplier ( 10x = 10) 1Ais = Area of the characteristic ion of the specific internal standard 611048RF = Average RF from the ICAL 1.004Vs = Purge volume of sample (mL) 10Vn = Nominal purge volume of sample (mL) ( 10.0 mL ) 10Cx = Concentration of the compound in the sample being measured (ug/L) 127.2428
3.0 Calculating the concentration ( C ) of a compound in soil using the average RF: *
Cx = [ (Ax) (Cis) (Wn)(D)] / [ (Ais) (RF) (Ws) ]Example
where:Ax = Area of the characteristic ion for the compound being measured 3122498Cis = Concentration of the specific internal standard (ug/L) 25D = Dilution factor for sample as a multiplier ( 10x = 10) 1Ais = Area of the characteristic ion of the specific internal standard 611048RF = Average RF from the ICAL 1.004Ws = Weight of sample purged (g) 5Wn = Nominal purge weight (g) ( 5.0 g) 5Cx = Concentration of the compound in the sample being measured (ug/L) 127.2428
Dry weight correction:Percent solids (PCT_S) 50Cd = (Cx) (100)/PCT_S 254.4856
* Concentrations appearing on the instrument quantitation reports are on-column results and do not take into accountinitial volume, final volume, and the dilution factor.
4.0 Concentration from Linear Regression
Step 1: Retrieve Curve Data From Plot, y = mx + b
y = response ratio = response of analyte / response of IS = Ax/Ais
x = amount ratio = concentration analyte/concentration internal standard = Cx / Cis
m = slope from curve = 0.213
b = intercept from curve = - 0.00642
32
00087216
Step 2: Calculate y from Quantitation Report
y = 86550/593147 = 0.1459
Step 3: Solve for x
x = (y - b)/m = [( 0.1459 -( - 0.00642)]/ 0.213 = 0.7152
Step 4: Solve for analyte concentration Cx
Cx = Cis ( x ) = (25.0)(0.7152) = 17.88
Example Spreadsheet Calculation:
Slope from curve, m: 0.213Intercept from curve, b: -0.00642
Area of analyte, Ax: 86550Area of Internal Standard , Ais: 593147
Concentration of IS, Cis 25.00Response Ratio: 0.145917
Amount Ratio: 0.715195Concentration: 17.87988
Units of Internal Standard: ug/L
5.0 Concentration from Quadratic Regression
Step 1 - Retrieve Curve Data from Plot, y = Ax^2 + Bx + CWhere:Ax^2 + Bx + (C - y) = 0A, B, C = constants from the ICAL quadratic regressiony = Response ratio = Area of analyte/Area of internal standard (IS)x = Amount ratio = Concentration of analyte/concentration of IS
Step 2: Calculate y from Quantitation Report
y = Ax/Ais
Step 3: Solve for x using the quadratic formulaAx^2 + Bx + C - y = 0
(Two possible solutions)
Step 4: Solve for analyte concentration Cx
Cx = ( Cis )( Amount ratio)
Example Spreadsheet Calculation:
Value of A from plot: -0.00629Value of B from plot: 0.511Value of C from plot: -0.0276
Area of unknown from quantitation report: 293821Area of IS from quantiation report: 784848
Response ratio, y: 0.374367C - y: -0.40197
Root 1 - Computed amount ratio , X1: 80.44567Root 2 - Computed amount ratio , X2: 0.794396 use this solution
Concentration of IS, Cis: 25.00Concentration of analyte, Cx: 19.86 ug/L
( )( )x
b b a c ya
=± − −2 4
2
33
00087217
Instrument Run Log
Run Log ID:27121
Page: 1
Approved:
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
031809
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 NA
WG297559
3
6
9
X
X
X
Comments
Seq. Rerun Dil. AnalytesReason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
10M71171
10M71172
10M71173
10M71174
10M71175
10M71176
10M71177
10M71178
10M71179
10M71180
10M71181
10M71182
10M71183
10M71184
10M71185
10M71186
10M71187
10M71188
10M71189
10M71190
SYSTEM BLANK
SYSTEM BLANK
WG297559-01 50ng BFB STD 8260
WG297559-01 50ng BFB STD 8260
WG297559-02 0.3ug/L STD 8260
WG297559-03 0.4ug/L STD 8260
WG297559-04 1ug/L STD 8260
WG297559-03 0.4ug/L STD 8260
WG297559-04 1ug/L STD 8260
WG297559-05 2ug/L STD 8260
WG297559-06 5ug/L STD 8260
WG297559-07 20ug/L STD 8260
WG297559-08 50ug/L STD 8260
WG297559-09 100ug/L STD 8260
WG297559-10 200ug/L STD 8260
WG297559-11 300ug/L STD 8260
SYSTEM BLANK
SYSTEM BLANK
WG297559-12 20ug/L ALT SRC STD 8260
SYSTEM BLANK
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
STD31709
STD31709
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31848
STD31819
03/18/09 07:43
03/18/09 08:17
03/18/09 08:47
03/18/09 09:00
03/18/09 09:26
03/18/09 09:58
03/18/09 10:31
03/18/09 11:03
03/18/09 11:36
03/18/09 12:08
03/18/09 12:40
03/18/09 13:13
03/18/09 13:45
03/18/09 14:17
03/18/09 14:50
03/18/09 15:23
03/18/09 15:55
03/18/09 16:27
03/18/09 16:58
03/18/09 17:30
Seq. File ID Sample Information Dil Reference Date/TimeMat
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
pH
Tune failed. DNR.
No secondary for 123-TCB. DNR.
Idomethane didn't show up at all. DNR.
Comments:
10M71173
10M71176
10M71179
File ID:
File ID:
File ID:
Maintenance Log ID: 28031
34
00087218
Instrument Run Log
Run Log ID:27161
Page: 1
Approved: March 23, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
031909
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 STD31819
WG297551
Comments
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
10M71192
10M71193
10M71194
10M71195
10M71196
10M71197
10M71198
10M71199
10M71200
10M71201
10M71202
10M71203
10M71204
10M71205
10M71206
10M71207
10M71208
10M71209
10M71210
10M71211
10M71212
10M71213
10M71214
10M71215
10M71216
10M71217
10M71218
10M71219
10M71220
10M71221
10M71222
WG297549-01 50ng BFB STD 8260
WG297549-02 50ug/L CCV STD 8260
WG297549-02 50ug/L CCV STD 8260
WG297551-01 VBLK0319 BLANK STD 826
WG297549-01 50ng BFB STD 8260
WG297549-02 50ug/L CCV STD 8260
WG297549-01 50ng BFB STD 8260
WG297549-02 50ug/L CCV STD 8260
WG297551-01 VBLK0319 BLANK STD 826
WG297551-01 VBLK0319 BLANK STD 826
WG297559-12 20ug/L ALT SRC STD 8260
WG297551-02 20ug/L LCS STD 8260
L09030379-13 A 826-SPE
L09030379-01 A 826-SPE
L09030379-02 A 826-SPE
L09030379-03 A 826-SPE
L09030379-04 A 826-SPE
L09030379-05 A 826-SPE
L09030379-06 A 826-SPE
L09030379-07 A 826-SPE
L09030379-08 A 826-SPE
L09030379-09 A MS 826-SPE
L09030379-10 A MSD 826-SPE
L09030379-11 A 826-SPE
L09030379-12 A 2X 826-SPE
L09030379-14 A 826-SPE
L09030379-15 A 826-SPE
L09030379-16 A 826-SPE
L09030379-17 A 826-SPE
SYSTEM BLANK
SYSTEM BLANK
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
STD31709
STD31848
STD31848
STD31709
STD31848
STD31709
STD31848
STD31819
STD31819
STD31819
STD31819
03/19/09 12:01
03/19/09 12:27
03/19/09 13:04
03/19/09 13:36
03/19/09 14:04
03/19/09 14:28
03/19/09 15:01
03/19/09 15:25
03/19/09 15:57
03/19/09 16:33
03/19/09 17:05
03/19/09 17:38
03/19/09 18:10
03/19/09 18:42
03/19/09 19:15
03/19/09 19:47
03/19/09 20:19
03/19/09 20:52
03/19/09 21:24
03/19/09 21:56
03/19/09 22:29
03/19/09 23:01
03/19/09 23:33
03/20/09 00:05
03/20/09 00:38
03/20/09 01:10
03/20/09 01:43
03/20/09 02:15
03/20/09 02:48
03/20/09 03:21
03/20/09 03:53
Seq. File ID Sample Information Dil Reference Date/TimeMat
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Instrument Run Log
Run Log ID:27161
Page: 2
Approved: March 23, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
031909
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 STD31819
WG297551
2
3
4
6
9
14
15
16
17
18
19
20
X
X
X
X
X
X
X
X
X
X
X
X
1
1
5
10
10
50
1
10
10
VC
2-BUT
2-BUT
2-BUT
2-BUT
2-BUT
2-BUT
Comments
Seq. Rerun Dil. Analytes
Over Linear Range
Over Linear Range
Carry-over contamination
Over Linear Range
Carry-over contamination
Over Calibration Range
Over Calibration Range
Over Calibration Range
Over Calibration Range
Carry-over contamination
Over Calibration Range
Over Calibration Range
Reason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
VC was low. DNR.
VC was low. DNR.
DNR.
VC was low. DNR.
DNR.
DNR.
Comments:
10M71193
10M71194
10M71195
10M71197
10M71200
10M71205
10M71206
10M71207
10M71208
10M71209
10M71210
10M71211
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
Maintenance Log ID: 28059
36
00087220
Instrument Run Log
Run Log ID:27161
Page: 3
Approved: March 23, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
031909
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 STD31819
WG297551
21
24
25
26
27
28
29
X
X
X
X
X
X
X
10
5
10
10
1
1
10
2-BUT
2-BUT
2-BUT
2-BUT
2-BUT
Comments
Seq. Rerun Dil. Analytes
Over Calibration Range
Over Calibration Range
Over Calibration Range
Over Calibration Range
Carry-over contamination
Surrogate standard failure
Over Calibration Range
Reason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
DNR.
DNR.
Comments:
10M71212
10M71215
10M71216
10M71217
10M71218
10M71219
10M71220
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
File ID:
Maintenance Log ID: 28059
37
00087221
Instrument Run Log
Run Log ID:27181
Page: 1
Approved: March 24, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
032009
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 NA
WG297819
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
10M71224
10M71225
10M71226
10M71227
10M71228
10M71229
10M71230
10M71231
10M71232
10M71233
10M71234
10M71235
10M71236
10M71237
10M71238
10M71239
10M71240
10M71241
10M71242
10M71243
10M71244
10M71245
10M71246
10M71247
10M71248
10M71249
10M71250
10M71251
10M71252
10M71253
10M71254
10M71255
10M71256
SYSTEM BLANK
WG297818-01 50ng BFB STD 8260
WG297818-02 50ug/L CCV STD 8260
WG297819-01 VBLK0320 BLANK STD 826
WG297819-01 VBLK0320 BLANK STD 826
WG297819-02 20ug/L LCS STD 8260
WG297819-03 20ug/L LCSDUP STD 8260
L09030341-15 A 826-SPE
L09030343-09 A 8260
L09030393-01 A 826-SPE
L09030393-04 A 826-SPE
L09030341-05 A 826-SPE
L09030341-06 A 826-SPE
L09030343-01 A 8260
L09030343-03 A 8260
L09030343-05 A 8260
L09030343-06 A 8260
L09030343-07 A 8260
L09030313-21 10X 826-TC
L09030313-23 10X 826-TC
L09030313-24 10X 826-TC
L09030427-03 100X 826-LOW
L09030427-05 10X 826-LOW
L09030406-05 10000X 8260
SYSTEM BLANK
SYSTEM BLANK
SYSTEM BLANK
SYSTEM BLANK
L09030120-01 A 826-REF-BLK
L09030120-02 A 826-REF-BLK
L09030120-03 A 826-REF-BLK
L09030120-04 A 826-REF-BLK
L09030120-05 A 826-REF-BLK
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
10
10
10
100
10
10000
1
1
1
1
1
1
1
1
1
STD31709
STD31848
STD31819
STD31819
03/20/09 07:39
03/20/09 08:11
03/20/09 08:35
03/20/09 09:08
03/20/09 09:40
03/20/09 10:12
03/20/09 10:44
03/20/09 11:17
03/20/09 11:49
03/20/09 12:21
03/20/09 12:54
03/20/09 13:26
03/20/09 13:59
03/20/09 14:31
03/20/09 15:03
03/20/09 15:36
03/20/09 16:08
03/20/09 16:40
03/20/09 17:13
03/20/09 17:45
03/20/09 18:17
03/20/09 18:49
03/20/09 19:22
03/20/09 19:54
03/20/09 20:26
03/20/09 20:58
03/20/09 21:31
03/20/09 22:03
03/20/09 22:35
03/20/09 23:07
03/20/09 23:40
03/21/09 00:12
03/21/09 00:44
Seq. File ID Sample Information Dil Reference Date/TimeMat
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
17
17
17
1
1
12
1
1
1
1
1
1
1
1
1
NA
NA
NA
NA
NA
NA
NA
Instrument Run Log
Run Log ID:27181
Page: 2
Approved: March 24, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
032009
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 NA
WG297819
4
22
23
X
X
X
1
250
1
CIS12DCE, TCE
Comments
Seq. Rerun Dil. Analytes
Carry-over contamination
Over Calibration Range
Analyzed too dilute
Reason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
DNR.
DNR.
Comments:
10M71227
10M71245
10M71246
File ID:
File ID:
File ID:
Maintenance Log ID: 28070
39
00087223
Instrument Run Log
Run Log ID:27210
Page: 1
Approved: March 25, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
032309
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 NA
WG297941
5
20
X
X
1
10
Comments
Seq. Rerun Dil. Analytes
Carry-over contamination
Surrogate standard failure
Reason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
10M71258
10M71259
10M71260
10M71261
10M71262
10M71263
10M71264
10M71265
10M71266
10M71267
10M71268
10M71269
10M71270
10M71271
10M71272
10M71273
10M71274
10M71275
10M71276
10M71278
10M71279
10M71280
10M71281
10M71282
10M71283
10M71284
SYSTEM BLANK
SYSTEM BLANK
WG297940-01 50ng BFB STD 8260
WG297940-02 50ug/L CCV STD 8260
WG297941-01 VBLK0323 BLANK STD 826
WG297941-01 VBLK0323 BLANK STD 826
WG297941-02 20ug/L LCS STD 8260
WG297941-03 20ug/L LCSDUP STD 8260
WG297941-04 FBLK STD 8260
L09030428-02 A 826-SPE
L09030438-08 A 826-SPE
L09030427-11 A 826-LOW
L09030468-20 A 826-LOW
L09030427-03 B 826-LOW
L09030427-05 B 250X 826-LOW
L09030468-08 A 826-LOW
L09030468-09 A 826-LOW
L09030468-10 A 826-LOW
L09030386-01 10X 826-TC
L09030421-01 10X 826-TC
L09030452-02 A 250X 826-LOW
L09030468-17 A 100X 826-LOW
L09030468-18 A 100X 826-LOW
L09030468-19 A 2000X 826-LOW
L09030428-01 A 826-SPE
SYSTEM BLANK
1
1
1
1
1
1
1
1
1
1
1
1
1
1
250
1
1
1
10
10
250
100
100
2000
1
1
STD31709
STD31848
STD31819
STD31819
03/23/09 07:27
03/23/09 08:00
03/23/09 08:26
03/23/09 08:51
03/23/09 09:23
03/23/09 09:56
03/23/09 10:28
03/23/09 11:01
03/23/09 11:33
03/23/09 12:05
03/23/09 12:37
03/23/09 13:10
03/23/09 13:42
03/23/09 14:15
03/23/09 14:47
03/23/09 15:19
03/23/09 15:52
03/23/09 16:24
03/23/09 16:56
03/23/09 17:29
03/23/09 18:01
03/23/09 18:34
03/23/09 19:06
03/23/09 19:39
03/24/09 07:13
03/24/09 07:46
Seq. File ID Sample Information Dil Reference Date/TimeMat
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
17
17
1
1
1
1
1
1
NA
NA
NA
NA
NA
NA
NA
NA
NA
Instrument Run Log
Run Log ID:27210
Page: 2
Approved: March 25, 2009
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
HPMS10
TMB
8260B
032309
NA
MSV01 12
Internal Standard:
CCV:
Surrogate Standard:
LCS: MS/MSD:
Workgroups:
STD31494
STD31848
STD31691
STD31819 NA
WG297941
22
23
25
X
X
X
10
10
1
Comments
Seq. Rerun Dil. Analytes
Analyzed too dilute
Analyzed too dilute
Missed Tune
Reason
Column 1 ID: Column 2 ID:RTX502.2 NA
Method: SOP: Rev:5030B/5035 PAT01 11
DNR.
DNR.
DNR.
DNR.
Comments:
10M71278
10M71280
10M71281
10M71283
File ID:
File ID:
File ID:
File ID:
Maintenance Log ID: 28095
41
00087225
Data Checklist
Checklist ID: 36896
Generated: MAR-19-2009 14:16:58
CHECKLIST1 - Modified 03/05/2008
Microbac Laboratories Inc.
Date:
Analyst:
Analyst:
Method:
Instrument:
Analytical Workgroups:
18-MAR-2009
TMB
NA
8260
HPMS10
WG297559
System Performance Check BFBInitial Calibration Average RF Linear Reg or Higher Order CurveSecond Source standard % DifferenceContinuing Calibration /Check StandardsProject/Client Specific RequirementsSpecial StandardsBlanks TCL's SurrogatesLCS (Laboratory Control Sample) Recoveries SurrogatesMS/MSD/DuplicatesSamples TCL Hits Spectra of TCL Hits Surrogates Internal Standards Criteria Library Searches Calculations & Correct Factors Dilutions Run RerunsManual IntegrationsCase NarrativeResults Reporting/Data QualifiersKOBRA Workgroup DataCheck for CompletenessPrimary ReviewerSecondary Reviewer
Check for compliance with method and project specific requirementsCheck the completeness of reported informationCheck the information for the report narrativeCheck the reasonableness of the results
NAXXXXXXXXXXXXXX
NAXXXXX
NAXXX
NAXXXX
TMB
Primary Reviewer:19-MAR-2009
Secondary Reviewer:
Curve Workgroup: NA
Runlog ID: 27121
42
00087226
Data Checklist
Checklist ID: 36964
Generated: MAR-23-2009 13:54:54
CHECKLIST1 - Modified 03/05/2008
Microbac Laboratories Inc.
Date:
Analyst:
Analyst:
Method:
Instrument:
Analytical Workgroups:
19-MAR-2009
TMB
NA
8260
HPMS10
WG297551
System Performance Check BFBInitial Calibration Average RF Linear Reg or Higher Order CurveSecond Source standard % DifferenceContinuing Calibration /Check StandardsProject/Client Specific RequirementsSpecial StandardsBlanks TCL's SurrogatesLCS (Laboratory Control Sample) Recoveries SurrogatesMS/MSD/DuplicatesSamples TCL Hits Spectra of TCL Hits Surrogates Internal Standards Criteria Library Searches Calculations & Correct Factors Dilutions Run RerunsManual IntegrationsCase NarrativeResults Reporting/Data QualifiersKOBRA Workgroup DataCheck for CompletenessPrimary ReviewerSecondary Reviewer
Check for compliance with method and project specific requirementsCheck the completeness of reported informationCheck the information for the report narrativeCheck the reasonableness of the results
NAXXXXXXX
NAXXXXXXXXXXXX
NAXXX
NAXXXX
TMBMDA
XXXX
Primary Reviewer:20-MAR-2009
Secondary Reviewer:23-MAR-2009
Curve Workgroup: NA
Runlog ID: 27161
43
00087227
Data Checklist
Checklist ID: 36984
Generated: MAR-24-2009 10:06:20
CHECKLIST1 - Modified 03/05/2008
Microbac Laboratories Inc.
Date:
Analyst:
Analyst:
Method:
Instrument:
Analytical Workgroups:
20-MAR-2009
TMB
NA
8260
HPMS10
WG297819
System Performance Check BFBInitial Calibration Average RF Linear Reg or Higher Order CurveSecond Source standard % DifferenceContinuing Calibration /Check StandardsProject/Client Specific RequirementsSpecial StandardsBlanks TCL's SurrogatesLCS (Laboratory Control Sample) Recoveries SurrogatesMS/MSD/DuplicatesSamples TCL Hits Spectra of TCL Hits Surrogates Internal Standards Criteria Library Searches Calculations & Correct Factors Dilutions Run RerunsManual IntegrationsCase NarrativeResults Reporting/Data QualifiersKOBRA Workgroup DataCheck for CompletenessPrimary ReviewerSecondary Reviewer
Check for compliance with method and project specific requirementsCheck the completeness of reported informationCheck the information for the report narrativeCheck the reasonableness of the results
NAXXXXXXX
NAXXXXXX
NAXXXXX
NAXXX
NAXXXX
TMBMDA
XXXX
Primary Reviewer:23-MAR-2009
Secondary Reviewer:24-MAR-2009
Curve Workgroup: NA
Runlog ID: 27181
44
00087228
Data Checklist
Checklist ID: 37039
Generated: MAR-25-2009 16:33:40
CHECKLIST1 - Modified 03/05/2008
Microbac Laboratories Inc.
Date:
Analyst:
Analyst:
Method:
Instrument:
Analytical Workgroups:
23-MAR-2009
TMB
NA
8260
HPMS10
WG297941
System Performance Check BFBInitial Calibration Average RF Linear Reg or Higher Order CurveSecond Source standard % DifferenceContinuing Calibration /Check StandardsProject/Client Specific RequirementsSpecial StandardsBlanks TCL's SurrogatesLCS (Laboratory Control Sample) Recoveries SurrogatesMS/MSD/DuplicatesSamples TCL Hits Spectra of TCL Hits Surrogates Internal Standards Criteria Library Searches Calculations & Correct Factors Dilutions Run RerunsManual IntegrationsCase NarrativeResults Reporting/Data QualifiersKOBRA Workgroup DataCheck for CompletenessPrimary ReviewerSecondary Reviewer
Check for compliance with method and project specific requirementsCheck the completeness of reported informationCheck the information for the report narrativeCheck the reasonableness of the results
NAXXXXXXX
NAXXXXXX
NAXXXXX
NAXXX
NAXXXX
TMBMDA
XXXX
Primary Reviewer:24-MAR-2009
Secondary Reviewer:25-MAR-2009
Curve Workgroup: NA
Runlog ID: 27210
45
00087229
HOLD_TIMES - Modified 03/06/2008
03/26/2009 14:56Report generated1351337PDF File ID:
HOLDING TIMESEQUIVALENT TO AFCEE FORM 9
Microbac Laboratories Inc.
WG2978198260BAnalytical Method:
16WW16-031709
Client ID Date
CollectedDate
Extracted QDate
ReceivedDate
AnalyzedMax HoldTime Ext.
Max HoldTime Anal
Time HeldAnal.
Time HeldExt.
03/17/09 03/19/09 03/20/09 14 3.18 03/20/09 14 3.18
* EXT = SEE PROJECT QAPP REQUIREMENTS *ANAL = SEE PROJECT QAPP REQUIREMENTS
AAB#:
Login Number:L09030427
46
00087230
HOLD_TIMES - Modified 03/06/2008
03/26/2009 14:56Report generated1351337PDF File ID:
HOLDING TIMESEQUIVALENT TO AFCEE FORM 9
Microbac Laboratories Inc.
WG2979418260BAnalytical Method:
16WW32-031709
16WW16-031709
TRIP BLANK
Client ID Date
CollectedDate
Extracted QDate
ReceivedDate
AnalyzedMax HoldTime Ext.
Max HoldTime Anal
Time HeldAnal.
Time HeldExt.
03/17/09
03/17/09
03/18/09
03/19/09
03/19/09
03/19/09
03/23/09
03/23/09
03/23/09
14
14
14
6.09
6.01
5.55
03/23/09
03/23/09
03/23/09
14
14
14
6.09
6.01
5.55
* EXT = SEE PROJECT QAPP REQUIREMENTS *ANAL = SEE PROJECT QAPP REQUIREMENTS
AAB#:
Login Number:L09030427
47
00087231
SURROGATES - Modified 03/06/2008
03/26/2009 14:56Report generated:1351345PDF File ID:
SURROGATE STANDARDS
Microbac Laboratories Inc.
L09030427-05
WG297819-01
WG297819-02
WG297819-03
DL01
01
01
01
1 2 3 4Sample Number Dilution Tag
10.0
1.00
1.00
1.00
1
2
3
4
-
-
-
-
1,2-Dichloroethane-d4
Dibromofluoromethane
4-Bromofluorobenzene
Toluene-d8
8260Method:
HPMS10Instrument Id:
L09030427Login Number:
WaterMatrix:WG297819Workgroup (AAB#):
Underline = Result out of surrogate limits
99.8 70.0 87.2 110
100 116 89.7 99.6
92.7 96.2 100 95.5
94.9 99.7 100 94.9
80
86
86
88
-
-
-
-
120
118
115
110
Surrogates Surrogate Limits
DL = surrogate diluted out
HPMS10CAL ID: -18-MAR-09
ND = surrogate not detected
48
00087232
SURROGATES - Modified 03/06/2008
03/26/2009 14:56Report generated:1351345PDF File ID:
SURROGATE STANDARDS
Microbac Laboratories Inc.
L09030427-03
L09030427-05
L09030427-11
WG297941-01
WG297941-02
WG297941-03
WG297941-04
01
DL02
01
01
01
01
01
1 2 3 4Sample Number Dilution Tag
1.00
250
1.00
1.00
1.00
1.00
1.00
1
2
3
4
-
-
-
-
1,2-Dichloroethane-d4
Dibromofluoromethane
4-Bromofluorobenzene
Toluene-d8
8260Method:
HPMS10Instrument Id:
L09030427Login Number:
WaterMatrix:WG297941Workgroup (AAB#):
Underline = Result out of surrogate limits
102 121 90.4 99.4
104 118 88.9 99.7
103 119 89.1 99.5
99.6 117 88.8 100
96.7 96.5 104 94.4
94.2 98.4 96.4 96.1
104 119 90.4 102
80
86
86
88
-
-
-
-
120
118
115
110
Surrogates Surrogate Limits
DL = surrogate diluted out
HPMS10CAL ID: -18-MAR-09
ND = surrogate not detected
49
00087233
03/26/2009 14:56Report generated1351338PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
10M71228
03/20/09 09:40
03/20/09 09:40
WG297819
WG297819-01
HPMS10
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
8260BMethod:
TMBAnalyst:
L09030427Login Number:
LCS
LCS2
16WW16-031709
WG297819-02
WG297819-03
L09030427-05
10M71229
10M71230
10M71245
03/20/09 10:12
03/20/09 10:44
03/20/09 18:49
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
DL01
50
00087234
03/26/2009 14:56Report generated1351338PDF File ID:
Microbac Laboratories Inc.
METHOD BLANK SUMMARY
Report Name: BLANK_SUMMARY
10M71263
03/23/09 09:56
03/23/09 09:56
WG297941
WG297941-01
HPMS10
Blank File ID:
Prep Date:
Analyzed Date:
Work Group:
Blank Sample ID:
Instrument ID:
8260BMethod:
TMBAnalyst:
L09030427Login Number:
LCS
LCS2
FBLK
TRIP BLANK
16WW32-031709
16WW16-031709
WG297941-02
WG297941-03
WG297941-04
L09030427-11
L09030427-03
L09030427-05
10M71264
10M71265
10M71266
10M71269
10M71271
10M71272
03/23/09 10:28
03/23/09 11:01
03/23/09 11:33
03/23/09 13:10
03/23/09 14:15
03/23/09 14:47
This Method Blank Applies To The Following Samples:
Client ID Lab Sample ID Lab File ID Time Analyzed TAG
01
01
01
01
01
DL02
51
00087235
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 1351339
26-MAR-2009 14:56
Analytes Concentration Dilution Qualifier
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1-Dichloropropene
Ethylbenzene
2-Hexanone
Hexachlorobutadiene
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2.50
0.125
0.125
0.200
0.250
0.500
0.500
2.50
0.250
0.250
0.250
0.500
0.250
0.125
0.250
0.500
2.00
0.125
0.250
0.125
0.250
1.00
0.250
0.250
0.125
0.250
0.125
0.250
0.125
0.250
0.500
0.250
0.250
0.200
0.200
0.250
0.250
0.500
0.250
0.250
2.50
0.250
10.0
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2.50
0.125
0.125
0.200
0.250
0.500
0.500
2.50
0.250
0.250
0.250
0.500
0.250
0.125
0.250
0.500
2.00
0.125
0.250
0.125
0.250
1.00
0.250
0.250
0.125
0.250
0.125
0.250
0.125
0.250
0.500
0.250
0.250
0.200
0.200
0.250
0.250
0.500
0.250
0.250
2.50
0.250
10M71228
WG297819
Instrument ID:HPMS10
File ID:
Prep Date:03/20/09 09:40
Run Date:03/20/09 09:40
Analyst:TMB
Workgroup (AAB#): ug/LUnits:
8260BMethod:
WaterMatrix:
L09030427Login Number: WG297819-01Sample ID:
18-MAR-09Cal ID:HPMS10-DACA56-94-D-0020Contract #:
5030BPrep Method:
SDL PQL
52
00087236
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 1351339
26-MAR-2009 14:56
Dibromofluoromethane
1,2-Dichloroethane-d4
Toluene-d8
4-Bromofluorobenzene
116
100
99.6
89.7
Surrogates % Recovery Surrogate Limits
86
80
88
86
-
-
-
-
118
120
110
115
Qualifier
PASS
PASS
PASS
PASS
Analytes Concentration Dilution Qualifier
Isopropylbenzene
p-Isopropyltoluene
4-Methyl-2-pentanone
Methylene chloride
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl acetate
Vinyl chloride
o-Xylene
m-,p-Xylene
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0.250
0.250
2.50
0.250
0.200
0.125
0.125
0.250
0.125
0.250
0.250
0.150
0.200
0.250
0.250
0.250
0.250
0.500
0.250
0.250
2.50
0.250
0.250
0.500
1.00
1.00
10.0
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
1.00
1.00
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.250
0.250
2.50
0.250
0.200
0.125
0.125
0.250
0.125
0.250
0.250
0.150
0.200
0.250
0.250
0.250
0.250
0.500
0.250
0.250
2.50
0.250
0.250
0.500
ND Analyte Not detected at or above reporting limit
* |Analyte concentration| > RL
10M71228
WG297819
Instrument ID:HPMS10
File ID:
Prep Date:03/20/09 09:40
Run Date:03/20/09 09:40
Analyst:TMB
Workgroup (AAB#): ug/LUnits:
8260BMethod:
WaterMatrix:
L09030427Login Number: WG297819-01Sample ID:
18-MAR-09Cal ID:HPMS10-DACA56-94-D-0020Contract #:
5030BPrep Method:
SDL PQL
SDL
PQL
Method Detection Limit
Reporting/Practical Quantitation Limit
53
00087237
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLANK
PDF ID: 1351339
26-MAR-2009 14:56
Analytes Concentration Dilution Qualifier
Acetone
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,1-Dichloropropene
Ethylbenzene
2-Hexanone
Hexachlorobutadiene
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2.50
0.125
0.125
0.200
0.250
0.500
0.500
2.50
0.250
0.250
0.250
0.500
0.250
0.125
0.250
0.500
2.00
0.125
0.250
0.125
0.250
1.00
0.250
0.250
0.125
0.250
0.125
0.250
0.125
0.250
0.500
0.250
0.250
0.200
0.200
0.250
0.250
0.500
0.250
0.250
2.50
0.250
10.0
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
1.00
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2.50
0.125
0.125
0.200
0.250
0.500
0.500
2.50
0.250
0.250
0.250
0.500
0.250
0.125
0.250
0.500
2.00
0.125
0.250
0.125
0.250
1.00
0.250
0.250
0.125
0.250
0.125
0.250
0.125
0.250
0.500
0.250
0.250
0.200
0.200
0.250
0.250
0.500
0.250
0.250
2.50
0.250
10M71263
WG297941
Instrument ID:HPMS10
File ID:
Prep Date:03/23/09 09:56
Run Date:03/23/09 09:56
Analyst:TMB
Workgroup (AAB#): ug/LUnits:
8260BMethod:
WaterMatrix:
L09030427Login Number: WG297941-01Sample ID:
18-MAR-09Cal ID:HPMS10-DACA56-94-D-0020Contract #:
5030BPrep Method:
SDL PQL
54
00087238
Microbac Laboratories Inc.
METHOD BLANK REPORT
Report Name:BLA
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