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Mathews, Barbara

From: Carpenter, Owen <focarpenter@terracon.com>Sent: Monday, July 01, 2013 3:55 PMTo: Leamons, Bryan; Matoska, MariaCc: steve.card@albemarle.com; william.wright@albemarle.com; Fureigh, Brad N.; Mathews,

BarbaraSubject: 2012 AEIR - Albemarle Solid Waste Disposal Vault (Permit No. 0251-S3N-R1, AFIN

14-00028)Attachments: Albemarle 2012 AEIR - Solid Waste Disposal Vault.pdf

Bryan, Please find attached the 2012 Annual Engineering Inspection Report for the Albemarle Solid Waste Disposal Vault Class 3N Landfill (Permit No. 0251‐S3N‐R1; AFIN: 14‐00028). If you have any questions or need additional information, please feel free to contact us at any time. Thanks, Owen F. Owen Carpenter, P.E., P.G. Engineering Dept. Manager I Solid Waste Services Terracon Consultants, Inc. 25809 I-30 South I Bryant, Arkansas 72022 P (501) 847 9292 x309 I F (501) 847 9210 I C (501) 622 0887 focarpenter@terracon.com I www.terracon.com Delivering Success Newsletter http://ds.terracon.com

Terracon provides geotechnical, environmental, construction materials, and facilities consulting engineering services delivered with responsiveness, resourcefulness, and reliability.

Private and confidential as detailed here (www.terracon.com/disclaimer). If you cannot access hyperlink, please e-mail sender.

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2012 Annual Engineering Inspection Report Albemarle Corporation South Plant

Solid Waste Disposal Vault Class 3N Landfill

Permit No. 0251-S3N-R1 AFIN: 14-00028

June 30, 2013 Project No. 35107073

Prepared for:

Albemarle Corporation 2270 Highway 79 South

Magnolia, Arkansas 71753 (870) 235-6500

Prepared by:

Terracon Consultants, Inc. 25809 Interstate 30 South

Bryant, Arkansas 72022 (501) 847-9292

2012 Annual Engineering Inspection Report Albemarle Solid Waste Disposal Vault ■ Magnolia, Arkansas June 2013 ■ Terracon Project No. 35107073

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TABLE OF CONTENTS ADEQ ANNUAL ENGINEERING INSPECTION REPORT FORM ............................................................... 1

LIST OF ATTACHMENTS ATTACHMENT A PHOTOGRAPHIC LOG

ATTACHMENT B UPDATED DRAWINGS

ATTACHMENT C LEACHATE ANALYTICAL REPORT

ATTACHMENT D UPDATED FINANCIAL ASSURANCE

ATTACHMENT E CLOSURE PLAN

AEIR Form (Rev. Jan 2013) Page 1 of 5

ANNUAL ENGINEERING INSPECTION REPORT (AEIR) FORM Reporting Year: 2012 Note: Check applicable landfill class. Class 1 (Reg 22.423(b)) , Class 3 (22.522(a)) X , Class 4 (22.619(b)) Facility Name: Albemarle Solid Waste Disposal Vault AFIN: 14-00028 Permit #: 0251-S3N-R1 Landfill Class: 3N Report Submittal Date: June 30, 2013 Date of Landfill Site Inspection by Certifying Engineer: May 23, 2013

Complete the form as indicated Instructions are bolded and italicized.

COLUMN TO BE COMPLETED BY REPORTER

Item Regulation Reference

Item Description Report Information/Comments/Remarks Attachment Reference

1 22.423(b)(1) 22.522(a)(1) 22.619(b)(1)

Remaining volume in current cell.

a) 120,436 cubic yards

Projected date of opening new cell. b) Date: Approximately 2074 based on current utilization

2 22.423(b)(2) 22.522(a)(2) 22.619(b)(2)

Remaining volume of all permitted units. a) 120,436 cubic yards

Total air space used during the reporting period.

b) 1,958 cubic yards

Estimated remaining site life (years) based on utilization rate during the reporting period. Note: Itemize current permitted unit/cell information - use attachment if necessary.

c) Landfill Unit/Cell remaining life: Landfill unit/cell Solid Waste Disposal Vault , 61 years. Landfill unit/cell , years. Landfill unit/cell , years. d) Entire permitted landfill: 61 years remaining life.

3 22.423(b)(3) 22.522(a)(3) 22.619(b)(3)

Documentation of fill progression in compliance with permit plans, specs and operating plan and narrative. Note: Provide narrative regarding fill progression during the reporting period. Be specific about landfill unit/cell designations (example: Cell 1, Phase A completely filled; Cell 2, Phase A, 50% full, being filled south to north as of December 31). Specifically note any overfill conditions.

a) Progression narrative : The Solid Waste Disposal Vault (SWDV) is approximately 34% full. The Landfill fill progression is generally from the north to the south in the current landfill footprint. The Landfill is being filled to the maximum capacity that can be reached without affecting the efficiency of waste placement.

4 22.423(b)(4) 22.522(a)(4) 22.619(b)(4)

Documentation of compliance with regulatory operating requirements, permit conditions, approved operating plan, and other applicable regulations. Note: Review current operating plans, and permit conditions. Include photographs of engineer’s inspection as Attachment A. Check for weekly/monthly operational logs, waste volume records in and out of landfill, unauthorized waste form sheets, waste cover maintenance, stormwater reports to ADEQ, and wet weather repair information.

a) Weekly/monthly operational logs exist (Y/N)? Y b) Photos of AEIR inspection attached (Y/N)? Y c) Waste volume in and out records exist (Y/N)? Y d) Unauthorized waste forms exist (Y/N)? Y e) Daily/weekly cover adequate at time of inspection (Y/N)? N/A exempt per permit condition 9. f) Alternative Daily Cover (ADC) Plan located onsite (Y/N)? N Operations in compliance with ADC Plan (Y/N)? N/A g) Liquid Waste Management (LWM) Plan located onsite (Y/N)? N Operations in compliance with LWM Plan (Y/N)? N/A h) Liquids received to be bulked during reporting period: gallons tons i) Waste cover of inactive areas maintained adequately (Y/N)? Y j) Net amount of waste disposed in landfill during reporting period: N/A cubic yards 3,369 tons k) Leachate head level less than 1' on liner at time of inspection(Y/N)? Y

5 22.423(b)(5) 22.522(a)(5) 22.619(b)(5)

Updated contour map that depicts: Note: Provide updated drawing(s) and final cover permit drawing as Attachment B – discuss any discrepancies. Max. contour interval = 2 feet)

a) Updated contour drawing attached (Y/N)? Y b) Final cover permit drawing attached (Y/N)? Y c) List all discrepancies here: N/A d) Is there an overfill condition (Y/N)? N

(i) horizontal and vertical extent of active and inactive fill areas;

(ii) status of all permitted units/cells; (Note: Label all active (working face, bulking area,

stockpiles), inactive, closed and interim cover areas).

a) Currently, does the facility have sufficient on-site quantities and types of soils for liner and cover construction of permitted units/cells (Y/N)? Y

b) If not, where will deficiency shortfalls be obtained (be specific)? c) Is the current Design Narrative earthwork balance accurate (Y/N)? Y

(iii) survey grid (required by 22.426); Note: Include benchmarks and horizontal controls

(iv) location of other visible surface features or improvements (e.g., roads, buildings, gas control systems, etc.);

Note: Include leachate risers, manholes, monitoring wells, gas wells, etc.

(v) the person responsible for gathering the survey data and the date survey data was taken to prepare the map. Reminder: Reporting period is calendar year. Survey data should be collected to reflect the AEIR reporting period.

a) Name: Harmon Surveying, Inc.. b) Name of person using the data to produce contour map: Dodd Harmon c) Date survey data was collected: June 26, 2013

6 22.423(b)(6) 22.522(a)(6) 22.619(b)(6)

Quantity, location, and characteristics of leachate collected, recirculated, and disposed. Note: Provide analytical report as Attachment C. Provide brief narrative on this form in space provided about leachate sources, how leachate is collected, measured and disposed. Also, explain how the leachate head on the landfill liner is monitored and measured.

a) Leachate Collected: 2,182,367 gallons b) Leachate Disposed: 2,182,367 gallons c) Leachate Recirculated: 0 gallons d) Leachate Recirculation Plan exists (Y/N)? N ADEQ approval Doc # N/A e) Leachate operating records exist (Y/N)? Y f) Leachate analytical report attached (Y/N)? Y g) Leachate narrative (collection, measurements and disposal): Leachate at the SWDV is collected from the gravity line and diverted to a sump. Leachate is then directed through the facility wastewater treatment system h) Leachate narrative (verifying <1' head on liner system): Primary liner sump was functional during the site visit with automatic pump controllers keeping leachate head less than 1’.

7 22.423(b)(7) 22.522(a)(7) 22.619(b)(7)

Maintenance of stormwater controls and best management practices for erosion control. Note: List any upset conditions during the reporting period (i.e., washouts, etc…). Also, include narrative about vegetation maintenance and repair.

a) Briefly list maintenance activities and upset conditions here: Stormwater within the constructed area is collected and directed through the facility wastewater treatment system. No upset conditions exist. Maintenance is performed when necessary to insure compliance with ADEQ regulations.

8 22.423(b)(8)

22.619(b)(8)

Status of capping and closure of completed areas. Note: List areas with acreage that have received interim or final cover. Include total landfilled area acreage not yet under final certified closed cover. Note: "Certified closed" means the facility has received an approval letter from ADEQ accepting the engineer's closure certification report.

a) Lndfl unit/cell SWDV , 1.5 acres. Intrm or Final Cover (I/F): I

b) Lndfl unit/cell , acres. Intrm or Final Cover (I/F):

c) Lndfl unit/cell , acres. Intrm or Final Cover (I/F):

d) Lndfl unit/cell , acres. Intrm or Final Cover (I/F):

e) Acres of disposed waste not under final certified cover: 3.2 acres f) Acres of disposed waste area that have interim cover: 1.5 acres

9 22.423(b)(9) 22.522(a)(8) 22.619(b)(9)

Status of remedial or corrective action activities. Note: List corrective action events during reporting period (e.g., seeps and erosion correction, leachate spills, unauthorized waste handling and removal, etc…), and indicate whether action was taken in response to an ADEQ inspection.

a) Briefly list corrective actions events here: The facility graded, seeded and repaired settled and eroded areas. b) Were any of the corrective actions taken in response to an ADEQ

inspection (Y/N)? Y c) Current status of corrective actions: Erosion control features,

vegetation, etc. is being established and is ongoing. d) Did corrective actions permanently solve the conditions (Y/N)? N Explain briefly: Maintenance of erosion control features is on-going

10 22.423(b)(10) 22.522(a)(9)

22.619(b)(10)

Updated Financial Assurance documentation as required by Chapter 14. Note: Include copy of most recent financial assurance documentation as Attachment D. Also, include updated closure and post closure cost estimated as an attachment– recommend to use the Closure Costs and Post-closure Care Costs Worksheet located at ADEQ - Solid Waste - Technical Branch Home Page Specific links to the worksheets: http://www.adeq.state.ar.us/solwaste/branch_technical/pdfs/closure_costs_worksheet.xlsx and http://www.adeq.state.ar.us/solwaste/branch_technical/pdfs/post_closure_care_costs_worksheet.xlsx. . Show detailed calculations of cost items in tabular format with specific item breakdowns. Also, show source of unit cost information and/or inflationary factor adjustments – use ADEQ factors where applicable. If updated unit cost information is used instead of inflationary factors, show the source of unit cost information. Confirm estimates are based on largest area ever requiring final cover.

a) Size of the facility property under current permit? 12.8 acres b) Size of actual permitted disposal area? 6.9 acres c) What is the current total permitted disposal area that contains disposed

waste but is not certified closed? 3.2 acres d) Updated closure cost estimate amount: $ 1,324,631 e) Is the closure cost estimate based on the largest area ever requiring

closure (Y/N)? Y f) Is the existing closure financial assurance adequate for acreage not yet

certified closed (Y/N)?: Y g) Updated post closure care cost estimate amount: $ 231,810 h) Is the existing post closure care financial assurance adequate for all

permitted areas (Y/N)?: Y i) Is the financial assurance mechanism a trust fund (Y/N)? N j) Are the sources of information for updated unit cost line items shown on

the cost estimate calculations (Y/N?): N/A k) Do the unit cost items for soil cover material include actual third party

cost of materials and labor (Y/N)? Y

11 22.423(b)(11) 22.522(a)(10) 22.619(b)(11)

Revised or updated facility Closure Plan in accordance with Chapter 13. Note: Provide updated Closure Plan as Attachment E if facility obtained a permit modification during the reporting period that affects the closure and/or post closure care.

a) Was an updated Closure Plan required during this reporting period (Y/N)?: N b) Is an updated Closure Plan attached herein (Y/N)? N

12 22.423(b)(12) 22.522(a)(11) 22.619(b)(12)

Other items that affect compliance. Note: Include an ADEQ enforcement activity summary (solid waste, water, air, hazardous waste related) and, status of operating and permit fees. Also, include brief narrative concerning groundwater monitoring reports, landfill gas, leachate recirculation, alternate daily cover, etc…

a) Are there current ADEQ enforcement actions (Y/N)? N b) Summary of enforcement actions: c) Are operating and permit fees payments up-to-date (Y/N)? Y If not explain: Additional Information: d) Does the facility monitor groundwater (Y/N)?: Y If so, is it detection monitoring or assessment monitoring?: Detection Monitoring e) What is the groundwater analytical sampling frequency? 6 months f) Does the facility collect landfill gas (Y/N)?: N g) Does the facility have a Gas Monitoring Plan (Y/N)? N h) Does the facility have gas monitoring probes (Y/N)? N i) Does the facility use an alternate daily cover (ADC) (Y/N)? N If so, what type of ADC is used: N/A

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ATTACHMENT A Photographic Log

Looking at sump on rain blanket at the Solid Waste Disposal Vault Landfill

Looking north at interim closed and active areas Solid Waste Disposal Vault Landfill

Looking South at prepared area with rain blanket at Solid Waste Disposal Vault Landfill

Looking west at interim closed area Solid Waste Disposal Vault Landfill

Looking north at gated entrance to the Solid Waste Disposal Vault Landfill

Looking South from interim closed area of the Solid Waste Disposal Vault Landfill

ATTACHMENT B Updated Drawings

ATTACHMENT C Leachate Analytical Report

January 27, 2012Control No. 154600

Albemarle CorporationPost Office Box 729Magnolia, AR 71753

ANALYTICAL RESULTS

154600-11P-Sump 1-17-12 1545

AIC No.Sample Identification:

Analyte Result QualifierRL Units

D13000 mg/l200Dil: 1000Batch: S31649Analyzed: 24-Jan-2012 1427 by 07Prep: 23-Jan-2012 1535 by 07EPA 9056A

Bromide

D2500 mg/l20Dil: 100Batch: S31649Analyzed: 24-Jan-2012 1314 by 07Prep: 23-Jan-2012 1535 by 07EPA 9056A

Chloride

Volatile Organic Compounds By EPA 5030C, 8260C33 ug/l2.0

Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C Acetone

< 2.5 ug/l2.5Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C

Acrylonitrile

J1.6 ug/l0.20Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C

Benzene

1-Bromo-2-chloroethane

Bromochloromethane

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chloromethane

1,2-Dibromo-3-chloropropane

Dibromochloromethane

1,2-Dibromoethane

8600 Kanis Road • Little Rock, AR 72204 www.AmericanInterplex.com Phone 501-224-5060 • FAX 501-224-5072

ANALYTICAL RESULTS

154600-11 (Continued)P-Sump 1-17-12 1545

Volatile Organic Compounds By EPA 5030C, 8260C (Continued)< 0.50 ug/l0.50

Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C Dibromomethane

trans-1,4-Dichloro-2-butene

1,2-Dichlorobenzene

1,4-Dichlorobenzene

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

Ethylbenzene

2-Hexanone

Iodomethane

4-Methyl-2-pentanone

Methylene chloride

Styrene

1,1,1,2-Tetrachloroethane

ANALYTICAL RESULTS

154600-11 (Continued)P-Sump 1-17-12 1545

Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C Tetrachloroethene

Toluene

1,1,1-Trichloroethane

Trichloroethene

Trichlorofluoromethane

1,2,3-Trichloropropane

Vinyl acetate

Vinyl chloride

Xylenes (Total)

99.3 %Batch: V7910Analyzed: 25-Jan-2012 1923 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C

Surrogate: 4-Bromofluorobenzene (75.0-120%)

Surrogate: Dibromofluoromethane (85.0-115%)

Surrogate: Toluene-D8 (85.0-120%)

154600-12Trip Blank

Volatile Organic Compounds By EPA 5030C, 8260CJ3.5 ug/l2.0

Batch: V7910Analyzed: 23-Jan-2012 1519 by 301Prep: 23-Jan-2012 1343 by 301 EPA 5030C, 8260C Acetone

Acrylonitrile

Benzene

August 2, 2012Control No. 159592

ANALYTICAL RESULTS

159592-11P-Sump 7-19-12 1030

D9400 mg/l200Dil: 1000Batch: S32827Analyzed: 25-Jul-2012 0341 by 07Prep: 23-Jul-2012 1358 by 07EPA 9056A

Bromide

D1900 mg/l20Dil: 100Batch: S32827Analyzed: 23-Jul-2012 2334 by 07Prep: 23-Jul-2012 1358 by 07EPA 9056A

Chloride

Volatile Organic Compounds By EPA 5030C, 8260C16 ug/l2.0

Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C Acetone

< 2.5 ug/l2.5Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C

Acrylonitrile

J3.6 ug/l0.20Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C

Benzene

Bromochloromethane

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chloromethane

1,2-Dibromo-3-chloropropane

Dibromochloromethane

1,2-Dibromoethane

ANALYTICAL RESULTS

159592-11 (Continued)P-Sump 7-19-12 1030

Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C Dibromomethane

trans-1,4-Dichloro-2-butene

1,2-Dichlorobenzene

1,4-Dichlorobenzene

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

Ethylbenzene

2-Hexanone

Iodomethane

4-Methyl-2-pentanone

Methylene chloride

Styrene

ANALYTICAL RESULTS

159592-11 (Continued)P-Sump 7-19-12 1030

Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C Tetrachloroethene

Toluene

Trichloroethene

Trichlorofluoromethane

1,2,3-Trichloropropane

Vinyl acetate

Vinyl chloride

Xylenes (Total)

96.0 %Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C

Surrogate: 4-Bromofluorobenzene (75.0-120%)

110 %Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C

Surrogate: Dibromofluoromethane (85.0-115%)

97.4 %Batch: V8063Analyzed: 26-Jul-2012 2203 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C

Surrogate: Toluene-D8 (85.0-120%)

159592-12Trip Blank

Volatile Organic Compounds By EPA 5030C, 8260C< 2.0 ug/l2.0

Batch: V8063Analyzed: 26-Jul-2012 2234 by 305Prep: 26-Jul-2012 0831 by 305 EPA 5030C, 8260C Acetone

Acrylonitrile

Benzene

ATTACHMENT D Updated Financial Assurance

225,870 2.63% $231,810

$231,810

TOTAL ESTIMATED CLOSURE CARE COST

TOTAL ESTIMATED POST-CLOSURE COST

$1,324,631

2010 221,731 0.51% $222,861

POST-CLOSURE CARE COST ESTIMATE

ESTIMATED COSTIMPLICIT PRICE

DEFLATORADJUSTED POST CLOSURE COST

$1,324,631

$1,267,0322.18%$1,240,0002009

$1,290,686

ADJUSTED CLOSURE COST

2010 $1,267,032 0.51% $1,273,494

CLOSURE CARE COST ESTIMATE

2009 217,000 2.18%

ALBEMARLE CORPORATIONSOLID WASTE DISPOSAL VAULT

YEAR ESTIMATED COSTIMPLICIT PRICE

DEFLATOR

2011 222,861 1.35% $225,870

$221,731

2011 $1,273,494 1.35% $1,290,686

ATTACHMENT E Updated Closure Plan

The Closure and Post Closure Care Plan was not updated during 2012.

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