Prepreg excellence days - Presentation

Advanced Materials

DECEMBER, 2014

ADVANCED CHEMISTRIES RAISING PERFORMANCE

Advanced Materials

2

Advanced Materials

FOCUSED INDUSTRIES


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Advanced Materials

OUR HISTORY


1758

1884 1971

1996

1997

2000

2003

2005

2011

J.R. Geigy AG begins trading in chemicals and dyes

Chemical Industry Basel (CIBA) is formed

Ciba merges with J.R. Geigy to form Ciba-Geigy

Ciba-Geigy merges with Sandoz to form Novartis

Ciba Specialty Chemicals independent of Novartis

Vantico is formed for Performance Polymers

Vantico is acquired by Huntsman and becomes AdMat division

Huntsman becomes a public company

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Advanced Materials

2,300 employees, 80 countries, more than 1,500 products, over 2000 customers

GLOBAL PRESENCE


Americas: 527

APAC: 448

São Paulo Taboão da Serra

McIntosh

East Lansing

Spartan

Singapore

Hong Kong

Shanghai

Mumbai Chennai

Dubai

Cairo Sadat City

Istanbul

Moscow

Madrid

Pamplona

Duxford

Vienna

Bergkamen

Buenos Aires

Tokyo Kobe

Bad Säckingen

Panyu

Monthey Seoul

Taipeh

Deer Park

3 regional headquarters 13 manufacturing sites 10 sales offices IMT: 188

Europe: 1,135

Los Angeles

The Woodlands

Basel

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Advanced Materials

INNOVATION


Innovation comes from more than just new molecules It incorporates both new building blocks as well as a way of working together along the value chain.

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Advanced Materials

1930 1940 1950 1960 1970 1980 1990 2000 2010 2020

- - - - - - - - -

Lab / pilot scale availability

Internal evaluation

Customer evaluation

Commercial scale availability

Qualification 1st application

Technical drivers

MILESTONES IN EPOXIES


CIBA

CIBA

Aerospace Marine Electronics

BISHENOL A EPOXIES

OO

OO

Araldite® GY 250 Araldite® LY 556 Araldite® MY 790 …

Superior mechanical performances to polyester and phenolics

CIBA

CIBA

Aerospace Marine Electronics

DOW

CIBA

DOW

Electronics Structural Composites

CIBA

n

CH2

O

O

CH2

O

O

O

O

EPN / ECN

DOW

DOW

Electronics Structural Composites

Thermal resistance superior to Bisphenol A epoxies

Araldite® EPN 1138 Araldite® EPN 1139 Araldite® ECN 1273 Araldite® ECN 1299 …

CIBA

Structural composites

CIBA

ON

O ON

O

O

O

O

N

OTGMDA / TGPAP

Araldite® MY720 Araldite® MY0500

Thermal resistance Mechanical performance TP tougheners Compatibility Processability

UNION CARBIDE

CIBA


CIBA


CIBA

CIBA

Araldite® MY720 Araldite® 9655, 9512, 9634… Araldite® M721 Araldite® MY0500 Araldite® MY0510

Processability


CIBA

CIBA


HUNTSMAN

CIBA

TGMAP

OO

N

O

O

SUMITOMO

CIBA


Araldite® MY0600 Araldite® MY0610

Modulus improvement Similar other performances

HUNTSMAN

SHELL

FLUORENE

O O

OO

DIC

NAPHTHALENE

O

O

O

O

HUNTSMAN

N

HUNTSMAN

HUNTSMAN

HUNTSMAN

HUNTSMAN

Toughness and thermal resistance via reduction of cross linking density

Araldite® MY 0816

HUNTSMAN CoE

NEXT GENERATION EPOXIES

HUNTSMAN CoE

“20% UP”

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Advanced Materials

1960 1970 1980 1990 2000 2010 2020

- - - - - -

Lab / pilot scale availability

Internal evaluation

Customer evaluation

Commercial scale availability

Qualification 1st application

Technical drivers

?

?

Electronics Structural composites

BMI MDA

Higher thermal resistance to epoxies

?

?

Electronics Structural composites

CIBA

Structural composites Electronics

CIBA

NN CH2

O

O O

O

Me

Me

OHOH

CIBA

BMI MDA FREE


CIBA

Lower toxicity Processability

Matrimid® 5292 A/B

LONZA CIBA (R.P.)

R.P. DOW

R.P. DOW


CYANATE ESTERS

LONZA CIBA (R.P.)

R.P. DOW

R.P. DOW


Niche between epoxies and BMIs

AroCy® range

GURIT ESSEX

CIBA

Electronics

HUNTSMAN

HUNTSMAN CoE


MILESTONES IN OTHER HIGH PERFORMANCE THERMOSETS

NEXT GENERATION BENZOXAZINES

HUNTSMAN

HUNTSMAN CoE

BENZOXAZINES BISPHENOL A / F

GURIT ESSEX

FST / X-Free Thermal and mechanical performance Dielectric properties

Processing Low toxicity FST / X-Free

Interiors Structural composites

Processing Thermal and mechanical performance Araldite® LZ 8280 N 75

XU 8282-1 Araldite® MT 35600 Araldite® MT 35700

CIBA

Electronics

HUNTSMAN

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Advanced Materials

Registration, Evaluation, Authorization and Restriction

REACH FOR CHEMICALS


We are spending several millions euros each year in order to maintain current supply

Introduction of new molecules into the EU market may be commercially risky and expensive In worse case, more than 2 millions euros

Large financial and resource impact on the chemical components suppliers due to number of substances Analytical & toxicity studies, dossier preparation, chemical safety report, personal costs…

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Advanced Materials

Evolution in Europe for chemistries used in composite applications

REGULATORY / LEGISLATION


Statement Phenolics Epoxy with resins formerly "R68” & currently "H341" labelled

Epoxy with resins "Others"

Bis-Maleimides

Cyanate Ester

Benzoxazines Isocyanate

NO ISSUE with REACH registration

NO USAGE LIMITATION for composite application (prepregs or direct closed processes)

Unknown

ADDITIONAL PROTECTIVE MEASURES (not mandatory today) could be required at the working place

(1) TGMDA (2) Naphthalene epoxy

(4)

TGPAP, TGMAP Subject to test programs results (3)

(1) Formaldehyde is today under consultation for "Proposal for Harmonised Classification and Labelling" and it will be classified as Carc. 1A (2) Latest tests for REACH dossier allow removal from Mutagenic and Reprotoxic classification lists : "R68"/"H341" phrases to be removed by end 2013 (3) Mutagenic and reprotoxic tests running: Tests results expected between 2014 (MUT) and 2016 (REPRO) (4) REACH registration 2018 Remark: The above table represents Huntsman’s view based on current knowlegde at the date of the presentation and are subject to changes in regulation

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Advanced Materials

WHAT YOU SHOULD EXPECT FOR INNOVATION


CONTSRUCT BUILDING BLOCKS

MANAGE CHANGE

PROVIDE FOCUS

SPECIALTY COMPONENTS PARTNER (e.g. Huntsman)

ROLE IN INNOVATION

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Advanced Materials

CONSTRUCT BUILDING BLOCKS


FOCUS

BUILDING BLOCKS CHANGE

SP

E. C

OM

P. P

AR

TNE

R PREPREGGER

DDS

TGMDA

M5218

DICY

BIS-A

EPN

IPDA

ECN

BIS-F

Optimize Customize Synthesize

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Advanced Materials

MANAGE CHANGE


CHANGE

FOCUS

BUILDING BLOCKS

MITIGATIONS §  Processes that cover both

internal and external stake holders along the value chain

§  Product stewardship §  Apply predictive approach §  Communication of risks §  Process safety management

CHANGES REGULATORY RAW MATERIAL VARIABILITY SUPPLY CHAIN

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Advanced Materials

PROVIDE FOCUS


FOCUS

CHANGE BUILDING BLOCKS

0

20

40

60

80

100

MARKET FOCUS

MC supplier SC supplier Prepregger Tier 1 OEM

OEM TIER 1

PREPREGGER SPE. COMP. PARTNER

MASS COMMODITY

SUPPLIER

MASS COMMODITY

SUPPLIER

MASS COMMODITY

SUPPLIER

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Advanced Materials

TAMING THE WILD


FOCUS

CHANGE BUILDING BLOCKS THE COMMODITY WILDERNESS

§  General specifications with little regard to historical equivalence or customers

§  Inconsistency or fluctuation of quality §  Change management that meets internal

needs (mainly for safety) and not customer focused

§  Reluctant to create “specialty” or “unique” materials

§  “Here is our offering, take it or leave it”

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Advanced Materials

CREATING FOCUS


FOCUS

CHANGE BUILDING BLOCKS

THE PREPREGGER CIVILIZATION §  Focused needs §  Well defined specifications based on

statistical equivalence rather than just a specification range

§  Sensitive to change (effects on quality and processing time, potential breaching of approvals)

§  Change management that incorporates value chain

§  Values uniqueness

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Advanced Materials

A common blueprint along the value chain evolves into a new civilization of value.

WORKING TOGETHER TO DRIVE INNOVATION


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Advanced Materials

Araldite® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more, but not all, countries. Sales of the product described herein (“Product”) are subject to the general terms and conditions of sale of either Huntsman Advanced Materials LLC, or its appropriate affiliate including without limitation Huntsman Advanced Materials (Europe) BVBA, Huntsman Advanced Materials Americas Inc., or Huntsman Advanced Materials (Hong Kong) Ltd. or Huntsman Advanced Materials (Guangdong) Ltd. (“Huntsman”). The following supercedes Buyer’s documents. While the information and re-com-mendations included in this publication are, to the best of Huntsman’s knowledge, accurate as of the date of publication, NOTHING CONTAINED HEREIN IS TO BE CONSTRUED AS A REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NONINFRINGEMENT OF ANY INTELLEC-TUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND THE BUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES. No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducement to infringe any patent or other intellectual property right. Data and results are based on controlled conditions and/or lab work. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for its own particular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights. The Product may be or become hazardous. Buyer should (i) obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product hazards and toxicity, together with proper shipping, handling and storage pro-cedures for the Prod-uct, (ii) take all steps necessary to adequately inform, warn and familiarize its employees, agents, direct and in-direct customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportation and disposal of and exposure to the Product and (iii) comply with and ensure that its employees, agents, direct and indirect customers and contractors who may handle or be exposed to the Product comply with all safety information contained in the applicable Material Safety Data Sheets, Technical Data Sheets or other instructions provided by Huntsman and all applicable laws, regulations and standards relating to the handling, use, storage, distribution and disposal of and exposure to the Product. Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative. © 2013 Huntsman Corporation. All rights reserved. Ref. No. Prepreg Excellence Days 12.13 _EN_EU

LEGAL INFORMATION


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Prepreg excellence days - Presentation