146
@ National Library - of'canada Bibljothequenationale A du Canada Onawa, Canada KIA ON4 If pages are mlsslng contact the university which i;ran!ed the degree Some pages may- have ~ndist~nct prmt especiall, i : Ihe original pages were typed with a poor !,pewri;er ritrbn C: if the.university_sent us an Inferior phc;'c,copy Prev~ousLy copyrighted rnater~als ijc~rr;al aCtc:e; c;o- lrshed tests etc ; are not frlmd 3 -- . . ,

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@ National Library - of'canada Bibljothequenationale A

du Canada

Onawa, Canada K I A ON4

I f pages are mlsslng contact the university which i;ran!ed the degree

Some pages may- have ~ndist~nct prmt especiall, i: Ihe original pages were typed with a poor !,pewri;er r i t r b n C: if the.university_sent us an Inferior phc;'c,copy

Prev~ousLy copyrighted rnater~als i jc~rr ;a l aCtc:e; c;o- lrshed tests etc ; are not frlmd 3 -- . .,

B.A:, U n i v e r s l t ~ o f W e s t e r n O n t a r l o , 1965 <

/ ' - -

A' THESIS SUBMITTED I N PARTML &

F U L F I L L M ~ T OF THE REQUSEMENTS -?OR T H E D E ~ E E

MASTER OF ARTS:

In t h e ~ e p a r t m e n t

. G e o g r a p h y

Wber t L l o y d S h e r w o o d 1987

SIMON FRRSER UNIVERSITY

J u n e 1987 -i

All r l g h t s r e s e r v e d . T h l s . w ~ r k may n o t be r e p r o d u c e d In w h o l e o r i n pa r t , by p h o t o c o p y

or o t h e r means, w i t h o u t permission o f t h e author.

. . ' .

Permission has been granted - to the National Library of Canada to microfilm this thesis and to lend or sell copies of-the film.

--

~ h e author (copyright owcer) h a s r ' e s e r v e d o t h e r publication rights, and neither the ,thesis nor extensive ext acts from it

5 3 may be printed r otherwise reproduced without his/her writken p&rmiseion. -

ISBN '0

B

L'autorisation a &t& accordhe h la ~ibliothhque nationale , du Canada de lmicrof ilmer* 7

cette th&se et de prgter ou de vendre des exemplaires du film.

L'auteur (titulaire du droit d'auteur) se r&serve les autres droits de publicztion; ni la th&se ni de longs extraits de celle-ci ne doivent &tre imprim68 ou autrqment reproduits sans son autorisation hcrite.

APPROVAL

Name: Rober t Lloyd Shemood

Degree:. . Master o t A r t s

T i f l e of Thes is : - Eva lua t ion of M u l t i p s e c t r a l Video Remote ~ e n s i h g ' * . .b - t o r t h e De tec t ion of Hydfocarbon Spill Thickness

i 7

k x a m ~ n l n ~ C o m i t t e e : . -

Chainran: I. Hutchmson

A.C.E. Rober ts Sen io r S u p r v l s o r

- J.C. Day

H. C. S c h r e i e r A s s o c i a t e P r o f e s s o r

E x t e r n a l Examiner /

Department o t S o i l s Sc ience U n i v q r s i t y of B r i t i s h Columbia

->

. I hereby g r a n t t o Simon Fraser U n i v e r s i t y t h e r ~ q h , t ti- . l e n ~

my t h e s i s , p rb je t t o r extended essay ( t h e t i t l e o f wL7ich r s s , -c - . r , uelcw)

<to u5ers o f t h e Simon Fraser U n i v e r s i t y L i b r a r y , 2nd t o m k s ?;I,-: i a l o r

s i n g l e cop ies o n l y f o r such users o r i n response t o a r e q w s - Tr - - i the

l i b r a r y of any o t h e r u n i v e r s i t y , o r o t h e r educa t i ona l i f is- i , i . . - i - r~ GZ.

i t s own behalf o r f o r one o f i t s users . I f u r t h e r sg ree -::J' , I - . - G r -

f o r m u l t i p l e copy ing o f t h i s work f o r s c h o l a r l y cbrooses 1;;. :q cl-an-,z

by me o r t h e Dean o f Graduate S tud ies . I t i s dnderstcod 7 1 3 - ,lFr ! i r ~ g

o r p u b l i c a t i o n o f t h i s work f o r firanrial g s i n snsl I ;otU5+- I f - cd

w i t h o u t my w r i t r e n perx i i ss ion . 1 " .

'T- T i t l e o f T h e s i s / ~ r c ; e c + / E x t e n d e ~ Essc)

Eva1 u a t i o n o f Flu1 t i spec t ra l V ideo Revote --- S e n s i n q -----. f o r t h e -- _De.tecti.o-n---

o f Hydrocarbon Spi 11 Th ickness ---- -- --- - / - - - -

Author: -

( s i g n a t u r e ,

Robe r t - L l oyd Sherwood ,-.

June 26 , 1987

( d a t e )

ABSTRACT

" . - - - This s t u d y v a s d e s i g n e d to evalrrate whether hydrocarbon s p i l l

t h i c k n i s e , could be e s t i m a t e d by measuri* l i g h t : ref ; lectance d i f f e r e n c e s

a c r o s s t h e photographic spec t rum ( 330 - '1 10 0 nanometers ) . The t h e o r e t i c a l

a s p e c t s of hydrocarbon s p i l l remote s e n s i n g were reviewed t o a r , r i ve a t an - *

unders tanding of how hydrocarbons a c t on water a n d how t h e e l e c t r u n a ~ e t i c

spectrum can be u t i l i z e d f o r imaging o i l s p i l l s . The l i t e r a t u r e d e a l i n g w i t h

o p e r a t i o n a l and expe r imen ta l o i l s p i l l remote sensing: r e y e a l e d t h a t

o p e r a t i o n a l systems have been m&inly complex an expens ive , b u t no t designed - P f o r de te rmining s p i l l t h i c k n e s s . S e v e r a l e x p r i m e nka l s t u d i e s d i sag reed a s

t o whether s e l e c t e d photographic spectrum bands c o u l d be e f f e c t i v e l y used f o r "

t h i c k n e s s d i s c r i m i n a t i o n .

I n i t i a l pho tog raph ic exper iments and t h e h igh l e v e l of r a d i o m e t r i c

I

r e s o l u t i o n of v ideo cameras s t r o n g l y favored t h e i r p o t e n t i a l u se t o t e s ' t t h e

p o s s i b i l i t y of d e t e c t i n g hydrocarbon s p i l l t h i c k n e s s . Graph ica l and

s t a t i s t i c a l a n a l y s e s of c o n t r o l l e d l a b o r a t o r y test d a t a s,howed t h a t v i d e o

imagery c o l l e c t e d w i t h s p e c i f i c f i l t e r s cou ld p rov ide comparat ive e s t i m s t e s

of hydrocarbon t h i c k n e s s up t o 1000 microns ( I -1. O i l t h i ckn ' e s s

a. d i sc r imina t ion , was b e t t e r f o r t r a n s l u c e n t hydrocarbons s u c h 3 low30 o i l , .

d i e s e l o i l and g a s o l i n e t h a n f o r c rude o r waste oils*. The m e t e f f e c t i v e .

f i l t e r s were 88A; 550nm bandpass and a 301A/46 combinat ion. \

1 ~ n a l y t ' i c a l r e s u l t s of a f i e l d t r i a l u s i n g a c o n t r o l l e d

P

Bur ra rd I n l e t confirmed t h a t it was p o s s i b l e t o i d e n t i f y r e l a t i v e

s p i l l ' t h i c k n e s s from r e f l e c t a n c e measurements, a l though n o t wi th t h e same -

s t a t i s t i c a l s i g n i f i c a n c e 'as i n t h e l a b o r a t o r y t e s t s . The most e f f e c t i v e

iii

+

;e 1BA and 500nm bandpass under t h e s p e c i f i c environmental + --

encountered. Analyses of 35 nun c o l o r photographic iplagery a l s o

f i l t e r s w e

cond i t ions

a c w r e d during t h e f i e l d t r i a l confirmed the importance o f t h e blue-green . .

band i n imaging s p i l l t h i c k n e s s .

,- 3- d q >

Completion of t s s s t u d y w a s ?nly p$$~,le th rough t h e '-nerous

6

-2 ' - P' * .

a s s i s t a n c e of many a number of ageficies. My t hanks are . - J

e s p e c i a l l y extended t o ,br 4 Roberts , my s e n i o r !Superviaor ! who p a t i e n t l y .-

p i l o t e d me and i t&oughxthe s tudy . I a l s o thank D r . . Chad Day

B f o r h i s camments, and D r . John P i e r c e f o r h i s i n s i g h t s

1 , on s t u d y method. j

E n v i r o e n t Canada was i n s t r u m e n t a l i n making t h e p r o j e c t succes;

and w a s a t a l l t i m e s ve ry s u p p o r t i v e , o f my e f f o r t s . The Environmental

Emergencies Branch of t h a t Department o f f e r e d a c c e s s t o i t s r e c o r d s and o i l

s p i l l l i t e r a t u r e . Kei th Hebron c a r r i e d o u t s u r f a c e sampling d u r i n g t h e f i e l d

t r i a l . Richard S t r u b provided l a b a s s i s t a n c e , Lee Harding and Roger McNetill

made a v a i l a b l e t h e i r knowledge i n canpu te r systems and s t a t i s t i c s , H a l Nelson b

and Duane Bro the r s ekped i t ed t h e Ocean --ping Approval P r o c e s s ' for t h e f i e l d - -

t r i a l and Merv inga gas generous ly donated funds from Environment Canada - 3 ,

h e a d q u a r t e r s . Ka r l Fupka and John Mi l len p e r m i t t e d c o n s i d e r a b l e f l e x i b i l i t y

i n my work scHedule a t Environmental P r o t e c t i o n t o enable 'me t o under take t h e

I n d u s t r y suppor t i nc luded t h a t of Andy Hofbauer of S h e l l Canada

Limi ted who "p rov ided hydrocarbon samples, dock usage and 45 g a l l o n drums. 1"

B l a i r Humghrey of Seakem Oceanography L imi t ed - loaned equipment f o r f i e l d ,

- t r i a l s u r f a c e sampling. Martyn' Green and s t a f f o f Burrard Clean Limited were.

e s s e n t i a l i n my g a i n i n g pe rmis s ion f o r a marine d i e s e l s p i l l because of t h e

rkspons ib i l i - t y . t h e y assumed f o r . s p i l l c o n t r o l and c l eanup . I

L i l l i a n Pearson i s a p p r e c i a t e d f o r h e r d r a f t i n g a s s i s t a n c e , Viv ian

Wray f o r h e r prompt and a c c u r a t e %word p r o c e s s i n g , an@ Deb sherw&$,' my wi fe ,

f o r h e r p a t i e n c e and unde r s t and ing .

APPROVAL ABSTRACT ACKNOWLEDGEMENTS TABLE -OF CONTENTS LIST OF-T I%s LIST OF FI 3 URES r '

1 INTRODUCTION 1 . 1 Study Object-iv-e

TABLE OF CONTENTS --

PAGE - ii iii

v v i

v i i i X

* . . 4

' 1 1

-

THEORETICAL ASPECTS OF HYDROCARBON -SPILL RmOTE SENSING The Behaviour of Hydrocarbons on Water F o r t i o n s of t h e E l e c t r a a g n e t i c Spectrum Used i n O i l S p i l l Remote Sens ing U l t r a v i o l e t V i s i b l e Near I n f r a r e d Thermal I n f r a r e d Microwave

S-rY #

3 OIL SPILL RP~OTE SENSING 3 . 1 Opera t iona l Systems 3 . 1 . 1 Remote Sens ing of O i l S p i l l s i n Canada 3 . 1 . 2 Opera t iona l Systems i n Other Cqun t r i e s 3 .2 Experimental S t u k e s '

3 . 2 . 1 Sensor Systems 3 . 2 . 1 . 1 ' Photographic cameras s ~ r d r n b l t i s p e c t r a l s c a n n e r s 3 .2 .1 .2 Video Systems 3 .2 .1 .3 ULTV 3 .2 .1 .4 Radar

, 3 . 2 . 2 S p e c t r a l Bands 3 .2 .2 .1 U l t r a v i o l e t 3 . 2 . 2 . 2 V i s i b l e 3 . 2 . 2 . 3 Near o r photographic i n f r a r e d 3 . 2 . 2 . 4 Thermal i n f r a r e d , 3 . 2 . 2 .*5 Microwave 3 .2 .3 O i l Type 3 .2 .4 O i l Thickness 3 . 3 Determina t ion of Study Ob jec t ive and Senaor System

. - TABLE OF CONTWCS - C b n t i n u e d

- - 3 -

% PAGE - 4 HETHOD IXVELOPWT AND CONTKlLLED TESTS 4 .1 Method of D a t a C o l l e c t i o n 4 .1 .1 P i l o t T e s t 4.1.2' She1 l b u r n R e f i n e r y Tes t_- 4.1.3 F i n a l C o n t r o l l e d T e s t 4.2 D a t a C o m p i l a t i o n 4 .3 - D a t a A n d l y s j s a n d 1 n t e r 6 e t a t i o n

L

5 'FIELD TRIAL e <

5 .1 Method of Data C 6 l l e c t i o n 5 .2 D a t a C o m p i l a t i o n 5 . 2 . 1 Surf ace S a m p l e s - 5.2.2 I m a g e r y 5.3 D a t p A n a l y s i s a n d I n t e r p r e t a t i o n '

>

6 " DISCUSSION AND CONCLUSIONS . 92

REFERENCES 98 i

APPENDIX 1. DESCRIPTION OF W O T E SENSING INSTRUMENTATION 104

APPENDIX 2. PREFERRED FILM AND F I L T E ~ TYFES USED FOR RENOTE' SENSING OF OIL SPILLS " 113

- ? L'

APPENDIX 3. ' TRANSMITTANCE RANGS OF FILTERS USED I N ONTmLLED i

TESTS AND FIELD TRIAL

APPENDIX 5 . LAB PROCEDURES FOR QUANTIFICATION C$Z DIESEL" OIL COLLECTED I N a~~ SOGENT PAD DURING FIELD TRIAL SURFACE SAMPLING . 130

4

-

TABLE - ' 1

2

3

4

(r

5

6

7

8

9

10

11

12

13

14 *

A Guide t o t h e R e l a t i o n ~ h i c k n & s a n d Volume o f

D e s c r i p t i v e V ~ e r m i n o l o g y

PAGE - Between t h e Appearance, F l m t i n g O i l 5

f o r O i l S i g h t i n g s .7 a

! 4

Summary and E v a l u a t i o n o f F a c t o r s R e l a t e d - t o ' O i l S p i l l D e t e c t i o n 13

0

Canadian A i r b o r n e Remote S e n s i n g C a p a b i l i t y A

f o r O i l S p i l l s 17

Summary o f Sensor System E v a l u a t i o n S t u d i e s -

'Condi t ions R e l a t e d t o Remote S e n s i n g of O i l S p i l l T h i c k n e s s 4 1

a

Hydrocarbon T h i c k n e s s and Adjus ted Mean Grey L e v e l b y Hydrocarbon Type and ~ i l t e i Type 1n - .

Shade C o n d i t i o n s i n F i n a l C o n t r o l l e d T e s t - 56

R e s u l t s of L i n e a r a n d Logar i thmic ' M u l t i p l e Combined R e g r e s s i o n s o f F i n a l C o n t r o l l e d T e s t Data b y Hydrocarbon Type 63

\ .

R e s u l t s of- b g a r i t h m i c M u l t i p l e R e g r e s s i o n s of A d j u s t e d Mean Grey U v e l s A g a i n s t Hydrocarbon T h i c k n e s s e s by Hydrocarbon Type and F i l t e r Type • ’ 0 ; - ~ i n a l C o n t r o l l e d T e s t m t a 65 *

Sample Weigh ts Determined by Chemical A n a l y s i s and C o r r e s p o n d i n g C a l c u l a t e d Sample Th i c hesses 7 7

Measured Diesel O i l T h i c k n e s s e s and A d j u s t e d Mean . Grey L e v e l s by F i l t e r Type ,in F i e l d T S i a l 80

Measured Diesel O i l T h i c k n e s s k s and Band R a t i o s From F i e l d T r i a l 35 nun Color Photography 8 1

Results of L i n e a r and L a g a r i t h m i c Combined R e g r e s s i o n s o f F i e l d ~ r i a i Data

R e s u l t s of L i n e a r and I o g a r i t h i c M u l t i p l e -

R e g r e s s i o n s o f Adjust-ed Mean Grey L e y e l s A g a i n s t Diesel O i l T h i c k n e s s e s by F i l t e r Type f b r F i e l d T t i a l D a t a

v i i i

/ -- -

I l

LIST OF TABLES - Continued ,

t PA GE - .

- - Resu l t s of Linear and Iagar i thmic Mul t ip le Regressions of Band Ra t ios ~g ia ins t* Diesel O i l Thicknesses f o r F i e l d Trial 35 mm Photography 88 h 1

TAB LE - e

15

Measured Diese l O i l Thicknesses and F i l t e r

- Rat ios f r o m F i e l d T r i a l ~ i d e 0 1 k a ~ e r ~ , ' 90

Resul ts of Linear alid Logarithmic W l t i p l e Regressions of F i l t e r Rat ios Against Diese l O i l Thiclmesses f o r F i e l d T r i a l Video Imagery , \

1

B 5

, LIST QP FIGURES. < -

FIG~JRE - t. . t *

. I ' , . Q I

PAGE - k 1

0

Major Marine Hydrocarbon S p i l l s i n i B r i t i s * ~ o l u m b i a , 1972-19840 .

**

2 I * . - Gross weatherPngCC ~ x o c e s sepa as Tbey Af fec t

041 on the &a S q f a c e P \

8 t

d , ' c'

u s 3 \ . ma ' ~ l ~ & t ~ ~ ~ ~ g n e t ~ ~ ' ~ ~ t r u m ' " C v

', 2, X 4 Spec,trqJ Radiance &om a m , i n Layer of

C . Crude O i l and. Moderately C l e a r C o a s t a l e.

4 , . ' : water of f n f i n i t e " .- Qepth wi th 4 3 O S o l a r

. . I ' ~ l t i t l u d e I . . - a . - ..

5 . E'rench ~ u p e r k ~ c l o p e m~canngr System * 9

0

Swedish M a r i t i m e S u r v e i l l a n c e System e

7 U. S . 1i reye S u r v e i l l ance S$stem

8 A r r a g e m e n t of P i l o t T e s t Buckets , Simon F r a s e r Un ive r s igy Remote Sens lng Labora to ry , 15 August 1986 443 , I

. - 9 S p e c t r a l S e n s i t i v i t y of t h e RCA Newicon and

Sony CCD Video cameras 4 4 I - .

Transmi t t ance S i g n a t w e of 46 i

Design Q•’ Pipe C y l i n d e r s i n 4 7

. Schematic of 4 5 Gal lon r rum Layout, S h e l l b u r n Re f ine ry T e s t , 15 September 1986 !

4 9 4

4

. Arrangement of 4 5 Gal lon Drums, S h e l l b u r n ~ e f i n e r ~ T e s t , 1,5 September 1986' * 50

14 Example of a D i g i t i z e d Image - Diesel O i l ,

I = 301A/46 Combination F i l t e r , Shade - Showing Nanina l Th icknes se s From 1 M l q o n t o 10000 Microns 6 3

Example of a P r o f i l e d and Graphed Image - Dlese l O i l , 301A/46 Combination F l l t e r , Shade 5 5:

C

-- - - - - - - I h - 1 . . -

LIST OF FIGURES - Cont inued

. % - -

F I G URE - PA GE - 16 . P l o t o f A d j u s t e d Mean 'Grey L e y e l V e r s u s

H y d r o ~ a r b o n T h i c k n e s s b y F i l t e r Type f o r Crude O i l '. 5 7

17 P l o t o f A d j u s t e d Mean Grey L e v e l Versus

Hydrocarbon ~ h i c k n e s s by F i l t e r Type f o r Waste O i l 5 8 4

18 . P l o t of A d j u s t e d Mean Grey L e v e l V e r s u s 1 . . H y d r o c a r b o n - T h i c h e s s by F i l t e r Type f m

i <( 10W30 011 - 59 -

19 P l o t o f ~ d j u s t e : Mean Grey L e y e l V ~ ~ S U S P

- 1

Hydrocarbon T h i c k n e s s by F i l t e r Type • ’ o r <., D i e s e l O i l

i

2 0 P l o t of A d j u s t e d Mean Grey L e v e l V e r s u s Hydrocarbon ~ h i k h e s s b y F i l t e r Type f o r G a s o l i n e - 6 1

2 1 F i e l d Trial S t u d y Area 68

2 2 Schemat ic of Video System i n A i r c r a f t f o r F i e l d T r i a l

S p e c t r a l s e n s i t i v i t y o f F i l m s Used - i n F i e l d T r i a l

= 1

Diagram of Ross-Belore O i l T h i c k n e s s Sampler

A e r i a l V i e w .of F i e l q T r i a l , B u r r a r d I n l e t , 18 March 1987 * \

~ x a m ~ l e o f a P r o f i l e d a n d Graphed Image - F i e l d Tr ia l , B u r r a r d I n l e t , . 18 March 1987

P l o t o f A d j u s t e d Mean Grey L e v e l Versus Hydrocarbon T h i c k n e s s by F i l t e r Type for A l l F i e l d T r i a l F l i g h t L i n e s

P l o t o f A d j u s t e d Mean Grey L e v e l Versus Hydrocarbon T h i c k n e s s by F i l t e r Type Wi thou t F i e l d mial F l i g h t L i n e s 5, 8 a n d . 9 a

f l ~ x a m ~ l e of ~ s e u d o - & l o r e d S p l i t Image - F i e l d T r i a l , B u r r a r d I n l e t , 18* March 1987

d . .

k - xi

Two h u n d r e d a n d e l e v e n m a j o r h y d r o c a r b o n s p i l l s occurred i n B r i t i s h

~ b ~ u m b i a n m a r i n e watets b e t w e e n 1972 a n d 1984 ( C a n a d a , 1986a). T h e s e spills

were w i d e l y d i s t r i b u t e d a l & n g t h e coast ; b u t t h e , m a j o r concentrations were I n

t h e i n d u s $ r i a l r z e d s o u t h w e s t ( F l q u r e 1 ) .

E n v i r o n m e n t a l a n d economic losses f r o m s u c h s p i L l s c a n be

significant. I n a J a n u a r y . 1 9 8 6 , s p i l l , a n e s t i m a t e d 350 w a t e r f o w l w e r e

# s e r i o u s l y o i l e d i n Sooke ~ a y - • ’ r a n what a p p e a r e d td be clandestine b l l g e

pumplng ( C a n a d a , 1 9 8 6 b l . A 1973 s p l l l o f f West Vancouver f r o m a s h l p

c o l l ~ s l o n r e s u l t e d i n c l e a n u p c o s t s of o v e r $600 ,~000 ( C a n a d a , 1983b: 3 4 ) .

E a r l y d e t e c t i o n a n d knowledge o f t h e d l s t r l b u t i o n and t h l c k n e s s of

s u c h 6 p l l l S c a n ass is t I n r e d u c l n g t h e l r environmental a n d ecoznan ic cpsts by

effectively g u i d l n g c l e a n u p e f f o r t s t o a r e a s of max-lm h y d r o c a r b o n d concentration. A number 0: r e m o t e s e n s l n g s y s t e m s v a r y l n g considerably I n

c o m p l e x i t y , a c c u r a c y a n d cost h a v e b e e n d e v e l o p e d f o r s p l l l d e l i n e a t r o n , b u t

n o n e h a v e b e e n able t o d e p l c t t h e t h i c k n e s s o f s u c h r e l a u v e l y t h l a s p i l l s .

I . % s t u ' Obi ective

The o b j e c t i y e of t h l s s t u d y was t o e v a l u a t e w h e t h e r h y d r o c a r b o n . - s p i l l t h l c k n e s s c o u l d be e s t i m a t e d b y n e a s u r l n g l l g h t i e f ~ k c t a n c e d l • ’ f e r e n c e s

u s i n g m u l t i s p e c t r a l v i d e o r e m o t e s e n s i n g . V i d e o was c h o s e n ' b e c a u s e i t h a s

p o t e n t i a l f o r r e a l - t l m e , a n a l o g t o d l g l t a l image a n a l y s l s u s l n g

m i c r o c p m p u t e r s . V l d e o c a m e r a s ~ l s o h a v e a h l g h l e v e l o f radiometric =<

I r e s o l u t i o n and- t h e r e f o r e can be expec ted t o perform b e t t e r t h a n f i l m . In .

a d d i t i o n , t h e y a r e much lower i n c o s t t h a n o t h e r s y s t a n s such as

m ~ l t i s ~ e c t r a l ' s canne r s .

L o g i s t i c a l l y , v i d e o systems have t h e advantdge of compactness and

low we igh t f o r installation I n l i g h t aircraft. Use of a four-camera a r r a y k -

made a m u l t i s p e c t r a l approach p o s s i b l e by .permitting s imul taneous imaging of 9

up t o fou r bands @ t h i n t h e p h o t o g ~ a p h r c spec t rum ( 3 0 0-1 100 nanometers ) . - I

Subsequent ana lyses determined t h e more ef f e c t l v e f l l t e r s f o r estimating o

\ spill t h i c h e s s . The system s e l e c t e d f o r t h e s tudy was l n t ended t o be

I

exper lmehta l o n l y ; a f u l l y o p e r a t i o n a l v ldeo sys tem would r e q u i r e ad& t l o n a l *

evaluation under a b roade r r ange of f i e l d m n & t l o n s .

me Behavim of E y d r o c u k r p s on W a t e r

Hydrocarbons a s s o c i a t e d wcth m a r i n e s p i l l s i n c l u d e n a p t h a s ,

g a s o l i n e s , k e r o k e n e s , d i e s e l f u e l s , b u n k e r s and c r u d e o i l s . T h e i r a p p e a r a n c e ,

on w a t e r depends on q u a n t i t i e s p r e s e n t , spill ' d u r a t i o n , w e a t h e r i n g and

v i s c o s i t y . AS $ h w n i n ~ & l e 1 and o r i g i n a l l y deScrib\ed b y H o r n s t e i n '( 1 9 7 3 ) ,

* hydrocarbon s p i l l s c a n be characteristically,silvery, i r i d e s c e n t , d a r g brown

'-7

t o b l a c k , o r 'a l l g h t e r brown r e p r e s e h t i n g a t h i c k n e s s r a n g e o f 0.0001 to 1

m. However, a p p e a r a n c e a l s o c a n v a r y depending on hydrocarbon t y p e and '

environmental c r ; n & t i o n s ; a mre r e l i a b l e s e n s o r t h a n t h e human e y e 1s r,

t h e r e f o r e r e q u i r e d .

There a r e s e v e r a l major w e a t h e r i n g p r o c e s s e s whlch d e t e r m i n e t h e C

f a t e p f h y d r o c a r b o n s , o r 011 c o l l o q u i a l l y , o n m a r i n e w a t e r s ( p l g u r e 2 ) .

These i n c l u d e p h y s i c a l p r o c e s s e s such a s e v a p o r a t i o n , c h e m i c a l i n f l u e n c e s as .

would o c c u r t h r o u g h t h e u s e o f d i s p e r s a n t s and b i o l o g i c a l p o c e s s e s l i k e

b i o d e g r a d a t i o n . E v a p o r a t i o n u s u a l l y i s t h e dominant f a c t o r i n t h e

decompos i t ion o f hydrocarbons .

Envi ronmenta l conditions and w e a t h e r i n g c a n r e s u l t i n a v a r i e t y o f

p h y s i c a l c o n f i g u r a t i o n s . of o i l s p i l l s o n w a t e r ( T a b l e 2 ) . Srmoth s l i c k s a r e ,

t h e common c o n c e p t i o n o f s p l l l s . However, i n many c a s e s , s p i l l s can a p p e a r

i n s t r e a m e r s o r windrows, i s o l a t e d p a n c a k e s o r consolidated t a r l a l l s .

I. H o l l i n g e r ( 1 9 7 4 ) h a s shown t h a t t h i c k r e g l o n s of s l i c k s c o n t a i n more t h a n 90

p e r c e n t o f t h e o i l l n less t h a n t e n p e r c e n t of t h e s l l c k area. T h l s

emphas izes t h e a d v a n t a g e s f o r s p i l l c l e a h u p i f r e l a t i v e t h i c k n e s s e s c a n be

r e m o t e l y d e t e c t e d .

TABLE 1. A GUIDE TO THE RELATION BETWEEN THE APPEARANCE, THICKNESS I

AND VOLUME OF FLOATING 01 L -

O I L CONDITION APPEARANCE APPROXIMATE APPROXIMATE 'THICKNESS (mm) VOLUME (m3/km2) *

/

0

Light s h e e n S i l v e r y 0 .0001 0 . 1

Heavy s h e e n

U n e r n u l s i f i e d o i l

a I r i d e s c e n t

E m u l s i f i e d Brown/orange 1 o r m o r e 1000 .0 011

d

L

- A d a p t e d f r o m : C a n a d a , 1 9 8 4 a : 1 1 v - 9.

ADSORPTION: PROCESS OF OIL ADHERING TO THE SURFACE OF SOtfE SUBSTANCE- GENERALLY LEADS TO SINKING. !

i -

l

?' 4

BIODEGFADATION: CHANGES IN THE CHEMICAL AND PHYSICAL PROPERTIES OF AN OIL THROUGH BIOLOGICAL ACTIVITY. w

-- -

*

- -

. -

-

CHE~ICAL DISPERSION: REDUCTION OF OIL/UATER INTERFACIAL TENSION BY THE ADDITION OF SURIACTENTS TO OIL WHICH AID ITS DISPERSIOH.

'+ + - -

1 -- I - *

i I)

FIGURE 2. GROSS WEATHERING PROCESSES AS THEY f AFFECT OIL ON THE SEA SURFACE

a

. \

I

. N

DISSOLUTION: -A PROCESS WHICH ACCOUNTS FOR THE SOLUBLE HYDROdARBONS IN OIL DISSOLVING IN THE WATER. 1

>

NLSIFICATION: A MIXTURE OF OIL AND WATER WHICH IS CAUSED BY SONE STIRRING ACTION (SUCH AS WAVES), EWULSIONS ARE EITHER WATER IN OIL OR,OIL IN WATER, DEPENDING ON THE RELATIVE PERCENTAGES OF EACH SUBSTANCE. I

I

EVAPORATION: CowERsIoN OF A LIQUID m A v u o ~ , m RATE OF AMORATION DEPENDS OH THE VOLATILITY, TEMPERATURE, WIND AND SURFACE AREA' OF THE SLICK. EVAPORATION WILL USUALLY ACCOUNT FOR A LARGE PORTION OF LOST qIL.

P

OXIDATION: THE COMBINATION OF HY~RocARBoNS WITH OXYGEN. SUNLIGHT WILL AID OXIDATION. THIS IS CALLED PHOTO-OXIDATION, PRODUCING OTHER COF~OUNDS WHICH HAY DISSOLVE IN WATER OR DISPERSE QUICKER.THIS IS A SLOW PROCESS, AND LIMIT~D TO ?KE SURFACE OF A SLICK. \

, \)

SOURCE: Pavio, R o b r r t , and D.L, Poyton, 1983: 346 T i

MOUSSE: A WATER-IN-OIL P~ULSION FORMED WHEN WATER IS MIXED W ~ H OIL BY SOME A G I T A T I O N P R O C E S SUCH AS W A V ~ ACTION. T H I S FORM O F O I L IS MORE READILY FORMED BY HEAVIER OZLS THAN LIGWTER OILS. IF A MOLLSSE IS FORMED-IT CAN RANGE 1 COLOR FPOM L I G H T BROWN T O RUST AND DARK BROWN. THE COLOR IS DEPENDENT ON T k TYPE 6 F O I L , AMOUNT OF WEATTHERIYG I T HAS UNDEACONE AND T H E PRESENCE A O P SURFACE A C T I V E AGENTS.

0 .

PANCAKES: ARE GENERALLY SEEN A S ISOLATED PATCHES OF WEATHERED O I L . THEY ARE ROUGHLY ROUND OR OBLIQUE, G I V I N G R I S E T O . T H E I R NAME, AND CAN RANGE I N S l Zt FROM ABOUT 6 CM T O A FEW KILOMETERS I N FSEjIUS.

SHEEN: ' THE NAME A S C R I B E D T O O I L THAT IS DFTECTIBLE BY A DAMPthEL, OH " S L I C K " SEA SURFACE. SHEEfj CAh RANGE FROM BEING V I S I B L E ONLY BY THE. S L I C K I T tUf lMS-

T O HAVING A RAINBOW OR GRAY COLPR ASSCCIA!I'ELJ WITH I T . 1 -

S L I C K : A SMOOTH SEA SURFACE AREA RESULTING FROM S U P F R E S S l O t i OI SMGL CAPILLARY WAVES BY O I L .

STREAMERS : L I N E S OF O I L , OF ANY FORM, 3

TARBALLS: A FORMATIOfj OF "GLOBULES OF O I L " @CURRZ NG WHEh WEATHEhELi 01 L UNDERGOES A SERIES OF PHYSICAL PROCESSES THA++-BREAK UP L A R G L ~ D A T C H E ~ u t ,CJIL I N T O COMPACT SSEMI-SOLID OR S O L I D MASSES RANGING FRW 5 MM T O 15 M1". 1 K

DIAMETER.

WINDROWS: PARALLEL BAPiDS O F FLOATING MATERIAL Oh THE W A T E R S U P J A C L . ( c I I L , SARGASSUM, E T C . ) WITH THE LONG A X I S A L I G h E D WITH THE W I N b L,IFE.C'IIOh.

WIND S L I C K S : PATCHES OF CALM SEA SURFACE CAUSEL BY L a ' k L I Z t L , h % A S Ob W l NIg SHEAR WHERE WIND CONDITIONS CHANGE S O RAPIDLY T H h l ' C h P I L L k R Y lrikVE.5 WI hO'X

HALE TIME T O DEVELOP. WIND S L I C K S DG NOT CONCENThATE PATEHJAL bh THt WIs'IEJ- - SURFACE AS DO WINQkDWS. WIND S L I C K S MAY BE C ~ J N F U S E . ~ WITH At* O l L 5 L I L K .

. Source: P w i a , Robert, a n d D . L . Payton, 1983: 3 4 7

-

c-.d - -- p--pp----- --

Research under taken by Ahmadjian et a l . (1976) i n d i c a t e d t h a t , -- --

a l though weather ing a f f e c t s t h e p h y s i c a l and chemical p r o p e r t i e s o f s p i l l e d

o i l , it does no t u s u a l l y o b v i a t e t h e p o t e n t i a l f o r remote d e t e c t i o n . Far

mre c r i t i c a l to remote s e n s i n g are such f a c t o r s as c loud cove r a n d sea s t a t e

which can e n t i r e l y e l i m i n a t e t h e use of some s e n s o r s such a s s a t e l l i t e

p l a t f o r m s . -In development of t h e method f o r t h i s s t u d y , t h e s e and o t h e r

f a c t o r s were taken i n t o c o n s i d e r a t i o n and a r e ekp la ined acco rd ing ly . 2

a Portions of the Electromagnetic Spectnm Used i n O i l Sp i l l Reaote

The e l ec t romagne t i c spectrum i s a continuum of energy t r a v e l l i n g a t < -

t h e speed of l i g h t ( 3 X lo8 s e c m x s e c and i s d e s c r i b e d i n te rms

of wavelength o r f requency . F i g u r e 3 i l l u s t h a t e s t h e spec t rum a n d p r w i d e s

I

d e s c r i p t i y e terms f o r c e r t a i n bands w i t h i n it. Based on Canada (1984b) ,

Canada (1983a ) , Axelssun and Ohlsson ( 1 9 7 3 , Cakoe (1973) and E s t e s e t a l . ' -- (1972) , a b r i e f summary

f. 7 1

11

fo l lows .

,

2.2.1 U l t r a v i o l e t .

i 0.4 micrometers (p) o r

band g e n e r a l l y used f o r

a

of t h e bands used i n t h e remote s e n s i n g of o i l s p i l l s

I

s

The u l t r a v i o l e t (UV) spectrum ranges from 0.1 t o ,

160 t o 400 n a n a n e t e r s ( m n ) . The p r t i o n of t h e W

remote s e n s i n g purposes i s between 0.3 and 0 .4pm; 4

a b s o r p t i o n by t h e atmosphere i s v e r y s t r o n g below 0.29 p m . - There a r e two mechanisms f o r d e t e c t i n g o i l s l i c k s i n t h e W: t h e

i

r e f l e c t a n c e d i f f e r e n t i a l between o i l and wa te r , and f luo rescence . A s

i 1 lu s t ; a t ed i n F i g u r e 4 , o i l h a s a h i g h e r r e f l e c t a n c e t h a n s e a water i n t h e 4

FIGURE 4. SPECTRAL BADLANE FROM A THlN L N € R OF CRUDE OIL AND MODERATELY CLEAR - COASTAL WATER OF INFINITE DEPTH WITH . 43' SOLAR ALTITUDE

C i I 1 I I

300 $00 500 600 TOO 800 900 lo(

WAVELENGTH X ( N M )

S O U R C E : Un-lted S t a t e s , . 1971 a : 701 .

I n e a r u l t r a v i o l e t . S e n s o r s which s e l e c t i v e l y f o c u s on t h i s part of t h e

-- A

e l e c t r a n a g n e t i c s p e c t r u m t h e r e f o r e are t h e o r e t i c a l l y capableYof s u p e r i o r o i l

s p i l l - d e t e c t i o n . The second phenomenon, f l u o r e s c e n c e , occurs when a p o r t i o n

o f t h e u l t i a v i o l e t a b s o r b e d by o i l is r e L e m i t t e d a t a l o n g e r wave leng t

0.4 t o 0 .7 pm, p r o v i d i n g a r e l a t i v e l y weak s i g n a l f o r o i l s p i l l d e t e c t i o n -

p u r p o s e s .

2.2.2 V i s i b l e . The v i s i b l e p o r t i o n of t h e s p e c t r u m between 0 .4 and

0 .7 pm i s t h e r e g i o n s e n s i t i v e t o t h e human e y e . The mechanism f o r 011

d e t e c t i o n i n t h i s band i s t h e r e f l e c t a n c e d i f f e r e n t i a l between o i l a n d w a t e r . - -

The d i f f e r e n t i a l 'is w e a k e s t between 0 .45 and 0 .5 p m ; w a v e l e n g t h s below and - above usualJy p r o v i d e improved o x l / w a t e r c o n t r a s t .

$

.'

2.2.3 N e a r Infrared. The n e a r i n f r a r e d r e g l o n (IR) f rom 0 . 7 t o 1 . 1 prn

i s n o t d e t e c t i b l e by t h e human e y e . I ts pr imary usefulness f o r r e m o t e

d e t e c t i o n i s a l s o t h e r e s u l t of t h e r e f l e c t a n c e d i f f e r e n t l a 1 between w a t e r

and o i l a s i l l u s t r a t e d i n F l g u r e 4 . I n f a c t , i n t h l s r e g i o n t h e r a d i a n c e from

a n o i l s l i c k c a n be between 2 0 and 100 p e r c e n t g r e a t e r t m n from t h e

S w r a u n d i n g w a t e r ( C a t o e , 1973: 2 6 9 ) .

- 2.2.4 Thermal Infrared. The shor twave l n f r a r e d between 1 . 2 and 3.0 pm

h a s l i t t l e u t i l i t y i n t h e r e m o t e s e n s l n g of 011 s p i l l s o n w a t e r . Beyond

3 . 0 p m , e m i t t e d ( t h e r m a l ) i n f r a r e d becomes a p r l m a r y s o u r c e of d e t e c t l b l c

e n e r g y . I n t h e t h e r m a l i n f r a r e d , r e m o t e s e n s i n g i s u s u a l l y c o n f i n e d t o

, s p e c t r a l r e g i o n s c a l l e d a t m o s p h e r i c windows where t h e a t m o s p h e r e 1s

- - - I

0

- - - - -

3 ' . - + u f f i c i e n t l y t r a n s p a r e n t t o a l l o w r a d i a t i o n t o t r a v e l

+ - /

-- '%. .a r -

- o v e r p a t h s of

i s i g n e i f i c a n t l e n g t h w i t h l i t t l e abso rp t ion . The main windows are f r a n 3.1 t o J- < .-

4.1 prn and 8 .0 t o 14.0 p m . T h e 6 0 i l s p i l l d e t e c t i o n mechanism i n t h e thermal @,

i n f r a r e d i s t h a t of t h e the rma l emiss ion d i f f e r e n t i a l between w t e r and o i l

which i s g r e a t e s t i n t h e 8.0 t o 14.0 pm r e g i o n (Catoe and McLean, 1979: 4 ) . u 0

2.2-5 , Hicrwave. The microwave p o r t j o n of t h e e l ec t romagne t i c

spectrum ranges from 1 mm t o 1 .meter i n wavelength. A p r i n c i p a l mechanism

f o r o i l s p i l l d e t e c t i o n i n t h e p a s s i v e microwave r a g i o n (0 .1 cm t o 30 cm) i s # ,

* e

t h e emis s ive d i f f e r e n t i a l between o i l and water ; t h e emis s ive s i c p a t m e of

pe t ro leum p r o d u c t s is s i g n i f i c a n t l y h i g h e r t han t h a t of a calm s e a (Canada, . 1984b: 2 .19 ) . Sea s u r f a c e damping (wave s t r u c t u r e modif icat ion ' ) a l s o p l a y s a

- I

r o l e i n t h e microwave r e g i o n by r educ ing s e a s u r f a c e roughn s and e m l s s i v i t y

(Catoe and McLean, 1979: 8 ) . ? The a t t i v e p o r t i o n ( 1 . 5 cm t o 70 cm) of t h e microwave spectrum i s

known a s t h e r a d a r r e g i o n . I n ' t h i s band, t h e damping ef f e c t o f o i l o n water

can r e s u l t i n what i s known a s a b a c k s c a t t e r c r o s s - s e c t i o n d i f f e r e n t i a l .

That i s , o i l ' s damping e f f e c t on s u r f a c e wa te r s r educes t h e a m u n t of energy -.

be ing b a c k s c a t t e r e d compared t o sur rounding wave-tossed a r e a s . According t o P ,

I

to Catoe ( 1973: 2701, ' a dec rease of up t o t h r e e o r d e r s of magnitude i n r e t u r n

sign% s have been observed f o r n a t u r a l o i l s l i c k s . .

2

-I 2.2.6 -. fl, 3 summarizes t h e d s t e c t i o n mechanis VP a p p r o p r i a t e t o t h d k l e c t r a n a g n e t i c bands d i s c u s s e d above. Table 3 a l s o

i d e n t i f i e s weather c o n s t r a i n t s , f a l s e a la rms and t h e poten., t ial f o r day and

's,

TA

BL

E

3.

SUM

MA

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AN

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19

79

: 2

0

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0-

d

n i g h t o p e r a t i o n s f o r each band. Weather c o n s t r a i n t s i n c l u d e haze , f o g ,

c l o u d s , h a i l and r a i n . F a l s e a la rms which can c a u p l i c a t e i n t e r p r e t a t i o n of

s e n s o r d a t a i n c l u d e f i s h o i l s l i c k s , suspended s o l i d s , wind s l i c k s , sha l low -i

wate r , upwel l ings and calm s e a s (Un i t ed S t a t e s , 1974 1 . Remote s e n s i n g i n a l l

of t h e e l ec t romagne t i c spectrum (between u l t r a v i o l e t and microwave) i s

a v a i l a b l e under d a y l i g h t c o n d i t i o n s . However, p a s s i v e remote s e n s i n g u s i n g

t h e photographic p o r t i o n of t h e spectrum ( 0 . 3 - 1.1 p m ) i s n o t p o s s i b l e b

f t

d u r l n g hours of darkness . ,

Much of t h e o i l s p i l l remote sens ing undertaken t o d a t e h a s been

i n r e l a t i o n t o l a r g e s p i l l s from t a n k e r s o r o f f s h o r e o i l r i g s . The o i l s

involved have been p r i m a r i l y heavy crudes. L i t t l e remote sens ing e f f o r t has

been p u t i n t o t h e more chronic problem of smal l harbour s l i c k s of l i g h t e r

hydrocarbons such as d i e s e l o r gaso l ine . This chapter examines t h e r eco rd of

o i l s p i l l remote sens ing by reviewing ope ra t iona l systems and summarizing t h e

r eco rd of experimental s t u d i e s .

3. 1 Operational Systems

Considerable v a r i a t i o n e x i s t s amongst c o u n t r i e s i n terms of t h e i r

use of remote sens ing f o r t h e d e t e c t i o n of o i l s p i l l s . There is no

cons is tency i n e i t h e r system types o r c o s t s . The s e c t i o n s which fo l low

desc r ibe systems used on s p i l l s i n Canada, Europe and t h e United S t a t e s .

3.1.1 Remote Sens ing of Oil Spills in Canada. According t o an

ex tens ive l i t e r a t u r e search , p r i m a r i l y through t h e Canada Centre f o r Remote

Sensing (CCRS), t h e r e i s l i t t l e documented use of remote sens ing of a c t u a l

s p i l l s i n Canada. Thornson and McColl (Canada, 1972) descr ibed a remote

sens ing survey on t h e 4 February 1970 of a Chedabucto Bay bunker C o i l s p i l l .

That survey was undertaken t o a s s i s t i n d e l i n e a t i n g t h e d i s t r i b u t i o n of o i l

and t o eva lua t e t h e use fu lnes s of an 8 - 14pm i n f r a r e d l i n e scanner

(Appendix 1 ) and s e v e r a l 35 and 75 mm photographic cameras. F l i g h t s were

scheduled under day and n i g h t condi t ions . The au tho r s determined t h a t bo th

sensor t ypes were capable of m n i t o r i n g s l i c k a r e a . The thermal scanner

.- - -

/ I- /=

c o u l d o n l y be u s e d u n d e r l i m i t e d c o n d i t i o n s when t h e r e w a s a s i g n i f i c a n t

t e m p e r a t u r e d i f f e r e n c e between ~ i l and water. The p h o t o g r a p h t c imagery w a s

l i m i t e d t o d a y l i g h t f a i r w e a t h e r o b s e r v a t i o n . Pho tography was t h e a u t h o r s I' p r e f e r e n c e f o r simple s u r v e i l l a n c e , p a r t i c u l a r l y w i t h c e r t a i n f i l m / f i l r 7 c o m b i n a t i o n s s u c h as Kodak Plus-X w i t h a W r a t t e n 39 ( u l t r a v i o l e t

f i l t e r . -- / /

The o n l y o t h e r major Canad ian s p i l l o f o p p o r t u n i t y ,doted i n t h e

l i t e r a t u r e w a s frpm t h e K u r d i s t a n o i l t a n k e r . O ' N e i l e t a (Canada, 1980) -. i u s e d a r e l a t i v e l y e x t e n s i v e s%nsor package t o s e a r c h f o / a n d map bunker C 011

which had been s p i l l e d from t h e K u r d i s t a n o n 16 March 1979. I n c l u d e d i n

. -- t h e i z ' c h o i c e 'of s e n s o r s w a s a r n u l t i s p e c t r a l s c a n n e r w i t h i n f r a r e d and t i s i b l e

c h a n n e l s , a low l i g h t l e v e l t e l e v i s i o n (LLLTV) camera (Appendix I ) , l a r g e a

f o r m a t p h o t o g r a p h i c r e c o n n a i s a n c e cameras and a s p e c i a l i z e d " m u l t i - d e t e c t o r

e l e c t r o - - 0 p t l c a 1 imaging s c a n n e r " . Between 17 March -and 2 A p r l l , a t o t a l of

n l n e s o r t i e s were f lown w i t h o i l b e i n g o b s e r v e d and mapped on s l x of t h e s e . Q r

- , Each o•’ t h e s e n s o r s p r o v e d t o be c a p a b l e of o i l d e t e c t i o n u n b r s p e c i - f i c . I

con&t ions , b u t t h e a u t h o r s d i d n o t p r o v i d e a c o m p a r a t i v e e v a l u a t i o n . T h e l r

o n l y r e f e r e n c e t o s p i l l t h i c k n e s s was t h a t t h l n s l i c k s showed b r l g h t a g a i n s t 4

t h e d a r k w a t e r w i t h W and c o l o r p h o t o g r a p h y . D

A l t b u g h CCRS, a few o t h e r government a g e n c i e s and s e v e r a l p r i v a t e

remote s e n s i n g f i r m s have been i n v o l v e d i n t h e development and evaluation of

o i l s p i l l d e t e c t i o n s y s t e m s i n Canada ( T a b l e 4 ) , t h e r e i s a l a c k of o t h e r

p u b l i s h e d i n f o r m a t i o n on a c t u a l a p p l i c a t i o n s of t h e s e s y s t e m s t o real o i l

sp i l l s . Whi le i t is known t h a t v i s u a l o b s e r v a t i ' o n s from a i r c r a f t a r e o f t e n

accompanied by t h e u s e o f 35 mrn cameras w i t h + e i t h e r o r b o t h s k y l i g h t and

- p o l e r i z i n g f l l t e r s (Canada, 1 9 8 6 ~ ) ~ i t a p p e a r s t h a t m r e s o p h i s t i c a t e d

TABLE 4. CANADIAN AIRBORNE RPllOTE SENSING CAPABILITY FOR OIL SPILLS

AGENCY OR COMPANY AIRCRAFT SENSORS

Canada Cent re f o r Convair 580 Falcon - Remote Sensing DC3 ( 2 ) - (Federa l Department - of Energy, Mines - and Resources) -

- -

LLLTV Dual channel l i n e scanner M u l t i s p e c t r a l l i n e scanner Four channel r e s e a r c h SAR Laser f luorosensor AGSV and cameras MEIS (exper imenta l )

Ontar io Cent re f o r Navaho Chief t a n - Daedalus I R l i n e scanner Remote Sensing - 2 Vintens (70mm) and (P rov inc i a l Min i s t ry (9" x 9") of Natura l Resources) - 4 Hasselblad (70mm)

- A e r i a l v ideo

Atmospheric Environ- E l e c t r a ( 2 ) ment Serv ice ( I c e Branch) Fede ra l Department of Environment

- APS 94D Radar - Bendix thermal mapper - 70mm camera

Department of Aurora CF104 National Defense

- Reconofax X IIIA l i n e scanners

- Other c l a s s i f i e d m i l i t a r y eq uipme n t

A t l a n t i c Canada PA23 Piper Aztec - LLLTV Airborne Sensing - B&W daytime TV (& c o l o r ) (Crown Corpora t ion) - FLIR

- Cameras

MARS Aer i a l Remote Grumman G I Sensing Limited

- Motorola APS 94 D - SLAR - Aer ia l cameras - I R l i n e scanner

I n t e r a Technologies Cessna 41 1 Limited Cessna 310

P ipe r Navaho

- Daedalus I R l i n e scanner ( s i n g l e and d u a l )

- A e r i a l cameras - LLLTV - SAR - SLAR

L

TABLE 4. CANADIAN AIRBORNE REMOTE SENSING CAPABILITY FOR OIL SPILLS - Cont 'd

OR COMPANY A1 RC RAFT SLWSORS # 7

A e r i a l Mapping & Beechcra f t - Z e i s s RMK A 15/23 aer ia l Photography L i m i t e d S u p e r King A i r B-200 camera - - - Radar a l t imeter (FP-kI) ' - LLLTV

'I - TV (B&W) - B&W s u p p o r t p h o t o l a b

Les Releves . F l y i n g by I - Bendix t henna1 mapper

Geophysiques I n c . Aerophoto I n c . - 70mm camera

Eiorcor E n g i n e e r i n g B r i t ten-Norman - Bendix RDR ground s e a r c h and Research L i m i t e d I s l a n d e r Q r a d a r

' - RCA 1040 I S I T TV s y s t e m - 7kun camera

Adapted from: Canada, 19845: 3-104 and 3-106 and canadd; - l983a: 248

s y s t e m s are i n f r e q u e n t l y u t i l i z e d p r o b a b l y as a r e s u l t of t h e i r g r e a t e r

c a n p l e x i t y , l a c k of a v a i l a b i l i t y or g r e a t e r cost.

3.1.2. 0perational,Systemsbin Other C o u n t r i e s . - Massin (1981) d e s c r i b e d - ,

a n a i r b o r n e r e m o t e s e n s i n g s y s t e m d e v e l o p e d b y F r a n c e f o r d e t e c t i n g ,

i d e n t i f y i n g , c l a s s i f y i n g , mapping and t r a c k i n g o i l s p i l l s . The French s e n s o r - I

package i n c l u d e d a n i n f r a r e d l i n e s c a n n e r , a n a v l g a t l o n s y s t e m , a videotape

r e c o r d e r t o combine t h e s c a n n e r and n a v i g a t i o n d a t a , a n d e o & s p l a y , a r a d ~ o

t r a n s m i b t e r and v a r i o u s p h o t o g r a p h l c carnerds whlch c o u l d a l l be c a r r l e d I n a

twin-eng ine a i r c r a f t . The ground r e c e p t o r sys tem was composed of a r a d r o

/ - r e c e i v e r , a s y s t e m t o s e p a r a t e scan'ner and f l i g h t d a t a , a v l d e o d l s p l a y u n l t ,

a v i d e o t a p e r e c o r d e r and a l a s e r beam r e c o r d e r f o r h a r d copy. F l g u r e 5

p r o v l d e s a s c h e m a t i c of t h i s " S u p e r c y c l o p " sys tem.

According t o Mass ln , t h e s y s t e m was operationally l l r n l t e d w l t h

r e s p e c t t o w e a t h e r c o n & t l o n s a n d l a c k o f consistency I n t h e l n f r u e d bdnd . b e c a u s e of t h e r m a l v a r l a b l l l t y c a u s e d by c o l d w a t e r r l s r n g ~ n t h e wake of

v e s s e l s o r l n t e r f e r e n c e from c l o u d s : B p a n s l o n of t h e sys tem to overcrme

t h e s e l i m i t a t r o n s i n c l u d e d a p r o p o s a l f o r t h e u s e of a m u l t r s p e c t r a ' l l i n e

s c a n n e r and a s l d e - l o o k l n g a l r b o r n e r a a a r . Massrn a l s o suc jges tea ttla t >

comparison of I n f r a r e d and v l s l b l e Imagery c o u l d p r o v r d e some ~ n f ormat l o n

a b o u t a v e r a g e s p l l l thickness, b u t d r d n o t & t a r 1 tYjw t h l s c o u 1 d . t ~ -

Backlund and ~ o l m s t r a n ( 1 9 8 3 ) described a Swedish package -

c a n p r i s l n g a n i n t , e g r a t e d s r d e - l o o k i n g a l ~ b m n e r a d a r ( h p p n d l x 1 ) , a n

4, ~ n f r a r e d / u l t l a v r o l e t s c a n n e r and p h o t o g r a p h l c cameras. L a t a t i t o r a y e a n d -

+ d o c m ~ n t a t i o n i n c l u d e d - . a P o y a r o l d camrjra a n d d r g i t a 1 cassette r e c o r d e r .

.

. FIGURE 5. FRENCH SUPERCYCLOPE SCANNER SYSTEM

EQUIPMENT ON B O A R D -

I I 1 CONTROL SCOPE

S O U R C E : M a u i n , ,J. M. , 1981 : 177

! /

e

Naviga t iona l d a u were integrated i n t o t.ke system as w e l l . S y s m add-ons - - i nc luded image l i n k s -to t h e ground by microwave, a .handheld TV camera, a

microwave r ad iome te r and a l a s e r f l u o r o s e n s o r ( F i g u r e 6 ) .

The Swedish system h a s been i n o p e r a t i o n a l s e r v i c e s i n c e 1980 and

h a s been t e s t e d i n v a r i o u s f l i g h t programs f o r t h e French and Dutch

Q governments, t h e European Economic Canntuni t y and Swedish Coast Guard.

I

Although Backlund and Holmstrom provided no a n a l y s e s from t h e l r exper iments ,

t h e y c la imed t h e system had performed very , s a t i s f a c t o r i l y. The W &anne l on

t h e scanne r was used s u c c e s s f u l l y t o i p g e s p l l l a r e a and t h e IR channel t o

i n d i c a t e r e l a t i v e o i l t h i c k n e s s . Unfo r tuna te ly , t h e y provlded no d e t a l l s on

t h i c k n e s s & s c r i m i n a t i o n performance. While t h e a u t h o r s a ~ g u e d t h a t t h e

\ . Swedish system was low we igh t , lo; volume, low I n p v e r c o n s w n p t ~ o n , r e h a b l e

and needed only a minimum of s e r v i c e , Backlund ( 1 9 7 9 ) quoted system

i n s t a l l a t i o n c o s t s a t t h a t t ime a s $ 5 3 ~ ~ . 0 0 0 U.S., a h i g h sum f o r m e t

emergency response groups.

perhap; ' the most e l a b o ? a t e and t e c h n o l o g i c a l l y advanced 011 spr 11

- - s u r v e i l l a n c e system 1s t h e U . S. Coast Guard ' s "Alreye" ( N h l t e and Schmldt, '

1983 ) . I t was deslgned t o l n c l u d e a s ide- looklng a l r b o r n e r a d a r , a t h r e c -

channel i n f r a r e d / u l t r a v i o l e t l l n e s canne r , an a e r l a1 r wxronnal sance cam ra , a n

a l r b o r n e d a t a a d a p t a t i o n system and a c o n t r o l d i s p l a y and r ecv rd c o n s o l e - In

add i t i o . . , t o i d e n t l f y p l l u t l n g v e s s e l s a t n l g h t , an a c t l v e cp tcd t e l c v l s m n

was developed f o r t h e Alreye . Each senso r could p r o d u c e a n r i o t atc~ci hard c q l y

imagery ( ~ i q u r e 7 ) . A s of 1583, t h e sys tem was t o be installed o n six U..he

Coast Guard j e t aircraft.

A key f e a t u r e of t h e Alreye crxn1,uter was i t s o r i t r ~ r d imacjr:-

processing c a p a b i l l t l e s whlch Inc luded s u c h enhancerent f u r r ~ " , I o n s as s ~ t l t 1 a1

i

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- -- - f i l t k r i n g , i n t e n s i t y s c a l i n g , f r o-frame, averaging , m a g n i f i c a t i o n zoom, -

h i g h r e s o l u t i o n zoom, a u t a n a t i c cter generat ion! -g raph ic o v e r l a y and

a geometr ic c o r r e c t i o n . A comple and i n t e g r a t e d system, t h e Aireye w a s ve ry

expensive and r e q u i r e d a h igh degree of s o p h i s t i c a t i o n and t r a i n i n g f o r use .

I t was developed p r i m a r i l y f o r s p i l l a n d - v e s s e l i d e n t i f i c a t i o n purposes ; t h e

- - L i t e r a t u r e d i d no t document i ts a b i l i t y t b measure s p i l l t h i c k n e s s .

The ,French , Swedish and American systems were developed a f t e r

ex tens ive ' r e s e a r c h and f i e l d t r a i n i n g . Although each was claimed t o be. a n

i n t e g r a t e d package c a p a d e of o i l d e t e c t i o n under v i r t u a l l y any c i rcumstance ,

problems of poor wea the r , heavy s e a s t a t e s and f a l s e t a r g e t s have r e s t r i c t e d

t h e i r u t i l i t y . While s o p h i s t i c a t i o n ' w a s t h e r ea son f o r t h e i r v e r s a t i l i t y , i t

w a s a l s o - t h e cause of t h e i r h igh c o s t s . Moreover, whether t h e y were A l e to

a c c u r a t e l y i d e n t i f y s p i l l t h i c k n e s s cou ld n o t be determined from t h e

l i t e r a t u r e .

The .video system developed f o r t h i s s tudy i s more l i m i t e d i n scope ,

d b u t much lbwer i n c o s t . I n a d d i t i o n , i t s performance i n lneasuring t h i n s p i l l

t h i c k n e s s

may b e s u p e r i o r . Assess ing i t s e f f e c t i v e n e s s i n de te rmining s p i l l -

i s h c ~ main o b j e c t i v e of t h i s s t u d y . *

Experimental Studies

To e v a l u a t e t h e c a p a b i l i t y and e f f e c t i v e n e s s of o i l s p i l l s e n s o r s \

t h . r h expe r imen ta l s t u d i e s , it i s u s e f u l t o have a d e s i g n concept of what

/

might be cons ide red a n ' i d e a l ' system. O'Neil e t a l . (1981) sugges ted such -- a sys tem shou ld :

- - -

- - - - - - - -- -

Oprovide cont inuous , day and n i g h t , a l l weather , wide a r e a , real-time surveillance - -

* d e t e c t any o i l s p i l l t h a t occu r s i n t h e marine m v i r o n m e n t b o t h o n and below t h e s u r f a c e

Oconfirm t h a t t h e d e t e c t e d subs t ance i s i n f a c t o i l Ornap t h e a r e a l e x t e n t of t h e s p i l l Oo\tain t h e t h i c k n e s s d i s t r i b u t i o n and q u a n t i f y t h e amount of o i l s p i l l e d

Oiden t i fy t h e sou rce of p o l l u t i o n and t h e s p e c i f i c t y p e of p o l l u t a n t be ing d i scha rged

Oprovide p r e c i s e n a v i g a t i o n a l accuracy f o r s p i l l and sou rce l o c a t i o n a n d p o s i t i o n i n g of c l ean -up v e s s e l s t

Odocument a l l c o l l e c t e d d a t a o n - h a r d copy r e c o r d s f o r l e g a l ev idence .

TFis 'is a demanding l is t and one no t cap'ab,le of berng s a t i s f l e d by

any s img le senso r . Nonethe less t h e list can s e r v e a s a r e f e r e n c e when

e v a l u a t i n g e x i s t i n g i n s t r u m e n t a t i o n . Table 5 a l p h a b e t i c a l l y l i s t s s t u - * ~ s of

a c t u a l f i e l d t r i a l s of many d i f f e r e n t s e n s o r s c o v e r i n g much of t h e c

/

e l ec t romagne t i c spectrum. Some ,of , t h e s t u h e s compara t ive ly e v a l u a t e d one

. I

p a r t i c u l a r t y p e of s e n s o r such a s pho tog raph ic camer%s, whi le o t h e r s canpar ed

d i f f e r e n t s enso r t y p e s such a s m u l t i s p e c t r a l s canne r s and r a d a r . Appendlx 1

d e s c r i b e s t h e v a r i o u s i n s t r u m e n t a t i o n t y p e s r e f e r e n c e d i n Table 5 .

Table 5 s h o w s - t h a t s e n s o r e v a l u a t i o n s t u d l e s h l s t o r l c a l l y have

o c c u r r e d i n two main t i m e p e r i o d s - t,he e a r l y 1970's a-nd t h e 1980's . I_ - * Research f o r t h e f i r s t of t h e s e p e r i ~ d s sugges ted a heavy emphasls on

pho tog raph ic s e n s o r s a s w e l l a s i n i t i a l exaam@atlon of a wlde v a r l e t y of

s e n s o r s ove r much of t h e e l ec t romagne t i c spectrum. Work I n t h e 1980's has $

been based on improvements i n t h e electronics of s ens lng a n d r e c o r & n g u r u t s .

3.2. 1. - Sensor a s t e r s . Examination of t h e r e s u l t s p r e s e n t e d l n Tabl-e

5 l e a d s t o t h e fo l lowing c o n c l u s i o n s with r e s p e c t to senso r s y s t a n s , s p e c t r a l

bands , o i l t ype a n d o i l t h i c k n e s s .

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ero

(8

44

3)

an

d K

odak

E

kta

ch

rom

e

MS

~e

ro

~r

a~

h;

ic

(2

44

8)

Co

lor

film

.

Fo

ur

len

s i

0 mm

mo

dis

ied

K

-24

ae

ria

l cam

ep

a,

Kodak

W

ratt

en

18

A

an

d U

V

to

mid

- v

isib

le

fi

lt

er

s ,

Kodak

(8

40

3)

Tri

-X

Ae

rec

on

B

lac

k

an

d W

hit

e

film

.

Be

nd

ix

TM

/LN

-2

an

d B

en

dix

T

M/L

N-3

in

fra

re

d l

ine

s

ca

nn

ers

.

Fix

ed

b

eam

, d

ua

l p

ola

riz

ed

m

icro

ka

ve

ra

dio

me

ters

.

WA

VEL

ENG

TH

OR

FR

EQU

ENC

Y

Vis

ible

an

d p

ho

to-

gra

ph

ic

infr

are

d

Ult

rav

iole

t t

o

mid

dle

w

av

ele

ng

th

vis

ible

-

I 4

-

5.5

pm

an

d

8 -

14

pm

res

pe

ct-

iv

ely

6

Ce

nte

r fr

eq

ue

nc

ies

o

f 1

0.2

GHZ

an

d,

d

30

GH

z re

sp

ec

t-

ive

ly

%+

- In

f ra

red

giv

es

sli

gh

tly

sh

arp

er

oil

wa

ter

co

ntr

as

t a

t l

ow

su

n

an

gle

s,

bu

t b

oth

v

isib

le a

nd

in

fra

red

co

loz

a

re

us

efu

l i

n s

pi

ll

de

tec

tio

n.

- 0

.36

t

o 0

.40

pm

are

mo

at

uq

efy

l w

av

ele

ng

ths

fo

r h

yd

roc

arb

on

d

ete

ct i

on

, b

ut

0.6

0

als

o h

as

p

ote

nti

al.

- 8 -

14

Prn

ima

ge

ry is

muc

h s

up

eri

or

to

4 -

5.5

pm

an

d is

be

st

of

all

im

ag

ery

o

f a

uth

ors

un

de

r c

lea

r

we

ath

er

co

nd

itio

ns

.

- M

icro

wav

e s

en

so

rs h

av

e

po

ten

tka

l i~

oi

l s

pi

ll

de

tec

tio

n a

s a

n a

ll*

w

ea

the

r b

ack

-up

t

o o

the

r s

en

qr

s,

alt

ho

ug

h m

icro

wav

e s

en

so

rs c

ap b

e c

on

fuse

d b

y

sh

ips

' w

akes

an

d

se

a

co

nd

itio

ns

.

Ge

rac

i a

nd

Ca

lta

bia

nc

(

19

83

)

Goo

dman

a

nd

Mo

rris

on

L

(19

85

)

TAB

LE 5

. SU

MM

ARY

OF

SEN

SOR

SY

STEM

EV

ALU

ATI

ON

S

TU

DIE

S -

Co

nti

nu

ed

SEN

SOR

SY

STEM

~a

va

l' Re

sea

rch

L

ab

ora

tory

fo

ur

fre

qu

en

cy

du

al

po

lar-

iz

ed

sy

nth

eti

c a

pe

tatu

red

ra

da

r.

Co

nv

en

tio

na

l 3

5 m

rn

ca

me

ras

Kod

ak

Wra

tte

n

12

fil

ter

,*

Kod

ak

Hig

h

Sp

ee

d

an

d K

od

ak

Ek

tac

hro

me

In

fra

red

Co

lor

f il

ms

.

Air

bo

rne

AG

A

Th

erm

ov

isio

n

Sy

ste

m.

- -

~o

no

ch

ko

me

LL

LT

V

wit

h a

C

orn

ing

7

-51

f

il

te

r a

nd

p

la

ri

ze

r.

Ba

rr

an

d

Str

ou

d t

he

rm$

l jm

a g

e r .

WA

VEL

ENG

TH

OR

FREQ

UEN

CY

Ph

oto

gra

ph

ic

, in

fra

re'd

fr

om

0

.7

to

0.9

pm

Th

erm

al

in•’

rak

ed

fr

om

2

.0

to

5.6

j.&

m

Ult

rav

iole

t an&

ph

oto

gra

ph

ic

in•

’ rare

d

7

RE

SUL

TS

- R

eli

ab

le o

ii

sp

il

l d

ete

cti

on

is

'pd

ss

ible

ov

er

wid

e

qre

as

un

de

r a

dv

ers

e w

ea

the

r c

on

dit

ion

s,

bu

t th

ere

is d

iff

icu

lty

i

n o

bta

iniq

g.

rea

l-ti

me

p

roc

ess

ing

.

- C

olo

r in

fra

red

ph

oto

gra

ph

s c

an

be

dig

itiz

ed

to

de

term

ine

ar

ea

co

ve

r-

ag

e o

f o

il

sp

ills

. -

Bo

th

infr

are

d p

ho

tog

rap

hy

a

nd

'

the

rma

l in

fra

red

im

ag

ery

are

e

ffe

cti

ve

in

. id

en

tify

ing

oi

l 0

0

wa

ter,

b

ut

the

y m

ust

be

use

d t

o-

ge

the

r to

pro

vld

e

ac

cu

rate

da

ta

inte

rpre

tati

on

. -

Ne

ith

er

met

ho

d is

ca

pa

ble

of

de

term

inin

g o

il

ty

pe

or

th

ick

ne

ss

.

- Im

ag

ery

w

as

com

bin

ed

into

a c

oq

po

s-

. ite

mo

nit

br

imag

e w

ith

re

d f

or

IR

, G

lue

fo

r W

a

nd

g

ree

n f

or

po

sill

ion

.

ima

ge

ry.

I

- E

ss

en

tia

l o

il

sp

il

l a

rea

l in

foq

ka

- ti

on

pro

vid

ed

i

n a

re

ad

ily

un

d4

r-

sto

od

fo

rma

t in

re

al-

tim

e.

I I I

. I

_TA

B'L

E 5.

SUM

MA

RY

OF

SEN

SOR

SY

STEM

EV

ALU

ATI

ON

. S

TU

DIE

S -

Co

nti

nu

ed

RE

SEA

RC

HE

R

SEN

SOR

SY

STEM

W

AV

ELEN

GTH

O

R

FREQ

UEN

CY

Co

nv

en

tio

na

l v

ide

os

f

or

V

isib

le s

pe

ctr

um

p

os

itio

na

l a

nd

na

vig

ati

on

- $1 i

nfo

rma

tio

n.

Go

rdo

n e

t a

l.

--

Nin

e

inc

h F

air

ch

ild

T-1

1

- U

ltra

vio

let

( U

n,i

ted

S

tate

s,

ca

me

ras

wit

h a

la

rge

(0

.32

-

0.4

0 p

m)

19

71

bl

an

d

va

rie

ty o

f f

il

te

r a

nd

fi

lm

to

M

unda

y --

et a

l.

(19

71

) ty

pe

s.

in•

’ r a

red

(0

.72

-

0.8

0 pm

-)

70

mm

fo

rma

t c

am

era

s w

ith

a

lar

ge

va

rie

ty o

f f

il

te

r

, a

nd

f

ilm

ty

pe

s.

Mu

ltis

pe

ctr

al

lin

e s

ca

nn

er

wit

h

17

ch

an

ne

ls e

ac

h.

Ho

rva

th

an

d

Ste

wa

rt

Mu

ltis

pe

ctr

al

lin

e s

ca

nn

er

0.3

2 -

0.3

8 p

m

(Un

ite

d S

tate

s ,

wit

h

17

c

ha

nn

els

. 0

.45

-

0.4

7

pm

1

9jl

a)

,

0.5

5 -

0.5

8p

m

9.3

-

11

.7 p

m

I

RE

SUL

TS

6

- E

qu

ipm

en

t p

ort

ab

le,

ea

sil

y i

ns

tall

-

ed

, lo

w

in

ma

inte

na

nc

e-a

nd

ea

sy

to

o

pe

rate

.

. P

- G

oo

d

thin

sli

ck

de

tec

tio

n i

s p

ra-

vid

ed

b

y

W +

-

blu

e

ba

nd

ph

oto

g~

ap

hy

th

ick

s

lic

k b

y

gre

en

ba

nd

. -

Red

a

nd

ph

oto

gra

ph

ic

infr

are

d b

an

ds

are

no

t u

se

ful

fo

r o

il d

ete

cti

on

, b

ut

the

rma

l in

fra

red

ca

n d

ete

ct

oil

-

Bo

th p

ho

tog

rap

hy

a

nd

sc

an

ne

r d

ata

g

ive

go

od

r

es

ult

s;

ph

oto

gra

ph

y is

c

he

ap

er,

b

ut

sc

an

ne

r c

an

be

ea

sil

y '

qu

an

tifi

ed

.

*

- S

un

a

ng

le,

hy

dro

ca

rbo

n t

yp

ee, a

nd

s

lic

k t

hic

kn

es

s c

an

va

ry

the

re-

f le

cta

nc

e a

nd

th

erm

al

info

rma

tio

n

rec

ord

ed

b

y

dif

fe

re

nt

ch

an

ne

ls.

- O

il

ty

pe

c

an

no

t b

e

dis

tin

gu

ish

ed

b

y

MSS

in

str

um

en

tati

on

, b

ut

re-

fle

cta

nc

e r

eg

ion

s

(UV

to

IR) d

efi

ne

ar

ea

l e

xte

nt

an

d,

tog

eth

er

wit

h

the

rma

l d

ata

, c

an

ap

pro

xim

ate

s

pi

ll

-

thic

kn

es

s.

-

RES

EAR

CH

ER

Low

e a

nd

Ha

se

ll

( 1

96

9)

Ma

rte

c

Lim

ite

d

(Can

ada,

1

98

5)

SEN

SOR

SY

STEM

Mu

ltis

pe

ctr

al

lin

e s

ca

nn

er

wit

h

12

ch

an

ne

ls.

Ha

sse

lbla

d 5

00

EL

/M,

Kod

ak

Wra

tte

n

18A

f

ilte

r,

Kod

ak

Tri

-X

Bla

ck

an

d W

hit

e fi

lm

Pe

nta

x M

E-S

uper

3

5 nun,

no

f

ilte

rs

, K

od

ac

olo

r 2

00

a

nd

Ilf

ord

XPl.

RCA

Mod

el

TC

1030

H

Low

L

igh

t L

ev

el

Te

lev

isio

n

wit

h a

C

orn

ing

7-

51

fi

lt

er

a

nd

ho

riz

on

tal

po

lari

ze

r.

Th

erm

al

Imag

ing

L

td.

Sy

stem

80

20

P

yro

-Ele

ctr

ic

Vid

ico

n.

WA

VEL

ENG

TH

OR

FR

EQU

ENC

Y

Ult

rav

iole

t to

th

erm

al

in•’

rare

d

Ult

rav

iole

t

Vis

ible

Ult

rav

iole

t a

nd

n

ea

r in

fra

red

Th

erm

al

infr

are

d

(8

- 1

4p

m)

RE

SUL

TS

- Bo

th u

ltra

vio

let

an

d t

he

rma

l in

fra

- re

d p

rov

ide

th

e b

es

t c

on

tra

st

ag

ain

st

bac

kg

rou

nd

se

aw

ate

r.

- Good

res

ult

s a

re

ac

hie

va

ble

un

de

r a

de

qu

ate

li

gh

t c

on

dit

ion

s,

bu

t sy

ste

m i

s n

ot

ca

pa

ble

of

rea

l-ti

me

o

pe

rati

on

or

de

term

ina

tio

n o

f o

il

ty

pe

or

th

ick

ne

ss.

- Vis

ible

ph

oto

gra

ph

y is

no

t a

s

dis

cri

min

ati

ng

as

W.

- E

xc

ell

en

t o

il-w

ate

r d

isc

rim

ina

tio

n

res

ult

s w

ith

ov

erc

as

t s

kie

s a

nd

c

alm

wa

ters

. - T

his

sy

ste

m h

as

a w

ide

fie

ld o

f v

iew

, is r

eli

ab

le a

nd

ea

sy

to u

se.

- O

il

de

tec

tio

n c

ap

ab

ilit

ies

of

un

it

are

min

imal

.

TAB

LE

5.

SUM

MAR

Y O

F SE

NSO

R

SY

ST

EM

, EV

AL

UA

TIO

N

ST

UD

IES

-

Co

nti

nu

ed

.

P

Mau

gh

an e

t a

l.

--

( 1

97

3)

- O

il

ca

n b

e d

ete

cte

d,

ev

dn

un

de

r n

igh

t c

on

div

ion

s ,

bu

t n

um

ero

us

fa

lse

ta

rg

ets

ar

e r

ec

ord

ed

, th

e

fie

ld g

f v

iew

is

na

rro

w a

nd

in

terp

reta

tio

n is

dif

fic

ult

.

Ba

rr a

nd

~

tr

ou

d IR

18

T

he

rma

l In

fra

red

Im

ager

y

Sy

ste

m.

Th

erm

al,

in

fra

red

(

8 -

14

pm

)

sli

ck

ra

the

r th

an

sli

ck

it

se

lf.

Oil

sp

ills

Se

nso

r w

hic

h

me

asu

res

sp

ec

tra

l ra

dia

nc

e

fro

m

va

po

ur

clo

ud

fro

m

-. T

his

sy

ste

m p

rod

uc

es

vir

tua

lly

no

u

se•’

ul

da

ta e

xc

ep

t u

nd

er

ve

ry

sp

ec

ial

co

nd

itio

ns

o

f lo

w w

ind

a

nd

Th

erm

al

inf;

are

d

(8

'-

14

pm

)

hig

h

ev

ap

ora

tio

n.

- d

ly

po

sit

ive

co

lor

film

(S

O-3

97

) w

ith

Wra

tte

n

1A

fi

lt

er

ca

n p

rov

ide

a

de

qu

ate

im

ige

ry q

ua

lity

un

de

r le

ss t

ha

n o

pti

mu

m w

ea

the

r c

on

dit

ion

su

ch

as

clo

ud

or

ha

ze

.

An

arr

ay

of

thre

e H

ass

el-

b

lad

5

00

EL

70

mm

c

am

era

s,

Kod

ak

Wra

tte

n

1A

fi

lt

er

w

ith

Kod

ak

Co

lor

SO

-39

7,

Kod

ak

Wra

tte

n

12

fi

lt

er

w

ith

~d

dk

kk

Ker

och

rom

e C

olo

r In

fra

red

(2

44

3)

an

d

no

f

il

te

r w

ith

Kod

ak

Plu

s-

X

Pa

nc

hro

ma

tic

(

24

02

).

Ph

oto

gra

ph

ic

spec

;ru

rn

\

L

,

Mil

lard

et a

l.

( 1

97

3)

--

Mil

lard

a

nd

Wo

ole

ver

(

19

73

) a

nd

- U

se

of

a

Co

rnin

g

7-5

1

fi

lt

er

(W

ve

0

.67

prn

an

d b

elo

w

0.4

2 pm

) o

n pn

ine

xp

en

siv

e

co

nv

en

tio

na

l te

lev

ks

ion

c

am

era

w

ith

bla

ck

a

nd

wh

ite

mo

pit

or

ca

n g

rea

tly

. e

nh

an

ce

de

tec

tio

n k

f o

i s

pil

ls r

el

at

ie

to

th

e e

ye

.

Vid

eo

c

am

era

w

ith

sp

ec

tra

l a

nd

po

la<

izin

g

fil

tra

tio

n.

Ph

oto

gra

ph

ic

spe

ctr

um

TA

BL

E

5.

SUM

MA

RY

O

F

SEN

SOR

SYSTEM

EV

AL

UA

TIO

N STUDIES -

Co

nti

nu

ed

I

,

4

Tw

o v

ide

o c

am

era

s w

ith

b

P

ho

tog

rap

hic

-

Th

e

two

ca

me

ra

sy

ste

m c

an

min

imiz

e

ea

ch

v

lew

ing

th

rou

gh

a

, t

he

ef

fe

cts

of

su

n

gl

in

t w

hen

o

pe

rati

ng

i

n a

s

ub

tra

cti

ve

po

lar-

p

ola

riz

ati

on

f

il

te

r o

rl'e

nt

ed

90•‹ t

o t

he

oth

er

. iz

inq

fa

sh

ion

.

i I

I R

r~

nti

c

~mer e

t a

1 .

1 An

a

rr

ay

of

fou

r H

aa

se

l-

--

CI!

A

, I

tV

7J

)

1 bla

d

50

0 EL/M

70m

m

ca

me

ras

a

nd

I'

i ancl

a

Ze

~s

s RM

K

15

23

1 , Ru

dd

er ~t

61

. --

ca

me

ra,

a

wid

e

ran

ge

of

I (

Un

l*

~d

5'

~t

~s

,

1'37

2 )%

f 1 l

te

rs

~

nc

lud

lng

Ko

dak

I

1 W

ratt

en

IH

A,

39

C,

47

8,

32

,

I 1

35

, 6

5,

75

, 9

8

an

d

99

,

li j

Km

lak

T

r L

-X

Ae

rcy

rap

hlc

, B

lark

a?

d

Kh

lt

e

(24

03

1,

RE

SUL

TS

-

I I , Nevi l

l~

t*

t a

l.

( 1

97

9)

--

I I

' h

'i,~

iak

Ek

tac

hrm

e HS

Ae

ro-

1 y

r<

lph

lr C

olo

r

( 2

24

H 3

an

d

1 K

~<

dd

k A

ero

dir

?n

p Co i

or

I I

WA

VEL

ENG

TH

OR

F

RE

QU

EN

~K. \

t I RL

.ISWH

CH

EH

SEN

SOR

SY

STE

M

I ~

ma

ge

or

da

y

us

e

in

hig

h se

a s

tate

$.

I

LL

LT

V

wit

h a

h

or

izo

nta

l p

ol

dr

~z

~n

g

f~

lt

er

a

nd

-

Co

rn

~n

y 7-5

1

f ~

lt

er

.

Ul

tr

av

~o

le

t, v

ls-

ib

le a

nd

p

ho

tn-

gra

ph

lc lnf r

are

d

1

- H

igh

c

on

tra

st,

re

al-

t.im

d

ynam

ic

ima

ge

ry

of

oil

sp

il

l p

os

sib

le u

nd

er

va

r io

ue

sk

y c

on

dit

ion

s.

- N

igh

t u

se

ii

mit

ed

wh

en

lig

hts

in

- M

ult

iba

nd

ph

oto

gra

ph

s

tog

eth

er

wit

h

co

lor

ph

oto

gra

ph

s a

re e

ff

ec

tiv

e i

nl

o

i 1 s

pi 1

1 d

ete

cti

on

. I

- M

axim

um

ima

ge

c

on

tra

st

en

ha

na

em

en

tl

- P

"

of

hy

dro

ca

rbo

ns

is

ac

hie

ve

d

wit

h

the

fo

llo

win

g

fil

m/f

rlt

er

c

au

bin

a-

tio

ns

:

24

03

/99

a

nd

2

40

3/3

2

(vis

i-

ble

b

an

d),

2

42

4/9

9

an

d

24

24

/32

(ph

oto

gra

ph

ic

inf

r.a

red

b

an

d).

I.

*

TAB

LE

5;

SUM

MAR

Y O

F

SEN

SOR

SY

STEM

EV

ALU

ATI

ON

S

TU

DIE

S -

Co

nti

nu

ed

RE

SEA

RC

HE

R

5 S

EN

SO

R

SYST

EM

WA

VEL

ENG

TH

. OR

FR

EQU

ENC

Y

1

. (1

97

5)

I

S m

ult

i-b

an

d

ca

me

ra w

ith

V

isib

le t

o t

he

rma

l in

fra

red

ae

ria

l fi

lms

. in

fra

red

Wil

d RC-8

ae

ria

l c

am

era

"

wit

h c

olo

r a

nd

bla

ck

a

nd

w

hit

e

film

s.

I Fu j

its

u t

he

rma

l s

ca

nn

er.

I

lin

e s

ca

nn

er .'

-7

Th

aman

e

t a

l.

(19

72

) A

v

ari

ety

of

ca

me

ras,

--

Ult

rav

iole

t t

o

fi

lt

er

s a

nd

fi

lm t

yp

es

. p

ho

tog

rap

hic

in

fra

red

Ult

rav

iole

t sc

an

ne

r.

Ult

rav

iole

t

Nin

e

ch

an

ne

l b

lac

k

an

d ,

* I ul

tra

vio

let

to

I w

hit

e m

ult

isp

ec

tra

l I i

nfr

are

d

1 sc

an

ne

r.

I

RE

SUL

TS

- C

olo

r p

ho

tog

rap

hy

is

su

ita

ble

fq

r

de

term

ina

tio

n o

f s

lic

k a

rea

, e

sp

ec

iall

y w

ith

fe

w c

lou

ds

an

d

low

w

ind

s.

- T

her

mal

im

ag

es

are

eff

ec

tiv

e f

or'

th

ick

oi

l s

lic

ks

on

ly.

c

- B

lac

k

an

d w

hit

e p

ho

tog

rap

hy

an

dJo

r s

ca

nn

er

ima

ge

ry g

ive

ad

equ

a&

are

al

info

rma

tio

n o

n s

pil

ls;

co

lor

fia

rns

ad

d little

ex

ce

pt

co

st.

- T

on

al

va

ria

tio

ns

, w

hic

h

ca

n b

e re

pre

se

nta

tiv

e o

f o

il

fil

m t

dlo

k-

, n

es

s,

are

mre

ea

sil

y i

de

nti

fie

d o

n

ph

oto

gra

ph

s.

- D

iffe

ren

tia

l p

ola

riz

ati

on

ca

n a

dd

c

on

tra

st

be

twe

en

o

il

an

d w

ate

r.

Th

om

son

and

McC

oll

(C

an

ad

a,

19

72

)

/ Yor

sf

~e

ld et a

l.

--

TA

BL

E

5.

SUMMARY

OF

SE

NSO

R

SYST

EM

EVA

LUA

TIO

N

STU

DI4

3S -

~o

nt'

inu

ed

'

SEN

SOR

SY

STE

M

WA

VEL

ENG

TH

- R

ESU

LT

S -

'4

OR FREQUENCY ''

Sid

e-l

oo

kin

g

sy

nth

eti

c

ap

era

ture

ra

da

r.

Rad

ar

ban

d

da

y-n

igh

t c

ap

ab

ilit

y,

co

nd

itio

ns

are

hig

h

Vin

ten

70mm

ca

me

ras

wit

h

se

ve

ral

film

an

d

fi

lt

er

ty

pe

s.

Mo

d~

fie

d Re

co

no

fax

in

fra

red

li

ne

sc

an

ne

r.

Co

nv

en

tio

nal

da

yli

gh

t te

lev

~s

lon

an

d

LL

LT

V.

cbb

b'f Le

ica

M

-3

35m

m cameras,

Kod

ak

Wra

tte

n,

28,

18A

, 3

9,

8913 f

il

te

rs

in

va

rlo

us

co

mb

inati

on

s w

ith

Kod

ak

Plus-X

Ae

rog

rap

hic

P

an-

ch

ro

ma

t~c

Infr

are

d

(24

24

) a

nd

K

odak

H

~g

h Sp

ee

d

Ek

ta-

ch

rom

e

Co

lor

fllr

ns.

P

P

Ult

rav

iole

t,

vis

- ib

le a

hd

ph

oto

- g

rap

hic

in

fra

red

8 -

14

,%m

I - ,

Th

e b

es

t f

ilm

/fil

ter

c

an

bin

ati

on

f

or

de

lin

ea

tin

g o

il s

lic

ks

is Kodab

Plu

s-X

w

ith

Kod

ak

Wra

tte

n 3

9.

- T

he

infr

are

d l

ine

sc

an

ne

r is

us

efu

l i

n o

il

de

tec

tio

n o

nly

wh

en

the

re

is

a

sig

nif

ica

nt

tem

pe

ratu

re d

if f

ere

nc

b

etw

ee

n

oi

l a

nd

wa

ter.

Ult

rav

iole

t,

vis

- ib

le a

nd

ph

oto

- g

rap

hic

in

•’ ra

red

Vls

ible

sp

ec

tru

m

1

- T

he

re i

s s

ign

ific

an

t d

ete

cti

on

ca

pt

ab

ilit

y i

n t

he

ult

ra

vio

let

an

d b

lu

~

ba

nd

s,

less i

n t

he

in

fra

red

an

d

alm

ost

no

ne

i

n t

he

gre

en

an

d r

ed

. -

Best

fil

m/f

ilte

r

ca

nb

ina

tio

ns

a

re

eit

he

r 2

42

4 o

r 2

40

2 f

ilm

wit

h e

ith

r

18A

o

r 39

fil

ter

s.

f -

Oil

ty

pe

c

an

no

t b

e

sp

ec

ific

all

y

dete

rmin

ed

, *

bu

t Lt

may

be p

oss

ible

I to

sh

ow

oi

l t

yp

e

dif

fere

nc

es

wh

en

mo

re

tha

n'o

ne

ty

pe

1s

pre

se

nt-

~ .,

- U

sefu

l f

or

vie

w

of

sp

ill

du

rin

g

I

fli

gh

t a

nd

to

aid

fli

gh

t li

ne

n

av

iga

tio

n a

nd

tr

ac

k r

ec

ov

ery

.

I -

RE

SEA

RC

HE

R

Yu

anfu

e

t a

l.

(19

82

) --

Zw

ick

e

t a

l.

(19

81

) --

TAB

LE

5.

SUM

MAR

Y O

F SE

NSO

R

SYST

EM

EVA

LUA

TIO

N

ST

UD

IES

~-

Co

nti

nu

ed

SEN

SOR

SY

STEM

W

AV

ELEN

CJT

H

OR

FR

EQU

ENC

Y

I

- C

olo

r a

nd

mu

ltis

pe

ctr

al

Ult

fav

iole

t ,

vis

- c

am

era

sy

g te

rns.

. ib

le,

ph

oto

gra

ph

ic

an

d t

he

rma

l in

fra

- re

d a

nd

mic

row

ave

Th

erm

al

infr

are

d s

ca

nn

er.

b

an

d

Sc

an

nin

g m

icro

wav

e ra

dio

- m

ete

r.

LL

LT

V

wit

h a

p

ola

riz

ing

f

il

te

r a

nd

a

sp

ec

tra

l f

il

te

r c

en

tere

d a

t 0

.40

p

m a

nd

0.7

5 p

m.

RE

SUL

TS

- S

en

sit

ivit

y i

n b

lue

a

nd

g

ree

n m

akes

it p

refe

rab

le t

o p

ho

tog

rap

hy

, y

et

ine

xp

en

siv

e .

I

- U

ltra

vio

let

is b

es

t f

or

de

tec

tin

g I

thin

oi

l s

lic

ks

, b

lue

-gre

en

is

nd

t

be

st,

re

d f

or

th

ick

sli

ck

s a

nd

p

ho

tog

rap

hic

in

fra

red

' ii

ot'

ve

ry

use

•’ ul.

-

Co

lor

ph

oto

gra

ph

y of

•’e

ra t

on

al

dif

fere

nc

es

re

lati

ve

to

va

rio

us

o

il

co

nd

itio

ns

. I

\

- H

igh

est

co

ntr

as

t f

or

mu

ltis

pe

ctr

a

- p

ho

tog

rap

hy

is

qu

rin

g o

verc

ast

i

sk

ies

, b

ut

un

de

r n

o c

on

dit

ion

s u

rn

oi

l t

yp

e

or

th

ick

ne

ss

be

reli

ab

ly

de

term

ine

d,

1 -

Th

erm

al

infr

are

d a

nd

mic

row

anre

s

en

sin

g c

an

de

tec

t o

il

du

rin

g b

otl

! d

ay

an

d

nig

ht.

I

Vis

ible

sp

ec

tru

m

- -

Co

ns

iste

ntl

y h

igh

tai

l a

nd

wak

er

co

ntr

as

t f

or

al

l o

il

ty

pe

s b

ut

no

a

pp

are

nt

va

ria

tio

n f

or

th

ick

ne

ss

.

M

Photographic -as and rriltispsctral -ers. - -

1. These s e n s o r s o p e r a t e b e s t with f e w c l o u d s , l i t t l e haze and low

winds jShimoda e t a1 . , 1 9 7 5 ) . -,

2 . P h o t o g r a p h i c a n d s c a n n e r i n f o m t i o n b o t h p o v i d e f a i r 011 -

s p i l l d e t e c t i o n c a p a b i l i t y (Munday , 1971 ; U n i t e d S t a t e s ,

3. Good a r e a l i n f o r m a t i o n c a n be p r o v i d e d by t h e s ~ s e n s o r s ( G e r a c l

and C a l t a b i a n o , 1983; Shimoda -- e t a l . , 1975 ) ; c o l o r a p p e a r s t o

p r o v i d e l i t t l e a d v a n t a g e o v e r b l a c k and w h l t e (Thaman -- e t a l . ,

4. D i f f e r e n t i a l ' p o l a r i z a t i o n c a n i n c r e a s e 011 and w a t e r c o n t r a s t

9

(Tharnan e t , a l . , 1972) . -- 5. Although l l r n i t e d by a l a c k of r e a l - t l m e c a p a b l l l t y , -

photographic cameras have t h e a d v a n t a y e of b e l n y c p n e r a l l y 1-5

expensive t h a n s c a n n e r s (Munday e t a l . , 1971; U n i t e d S t a t e s , --

6

6. The b e s t f l l m / f l l $ e r combinations a p p a r t o be 2402/18k o r 3 ( > ,

24d3/32 o r 99 , 2424/18A, 3 2 , 39 o r 9 9 , and SO-397/1A (Vlz ) . , , .

1974; Maughan -- e t a 1 ; , 1973; Reinheirner e t a1 . , 1973; Canada , -- 1972;, Uni ted S t a t e s , 1 9 7 2 ) . T h l s I S a wide a w r t r w n t of f ~ l m

and f l l t e r t y p e s , b u t the most p r e f e r - r e d b a n d s a rn r )nqx t t l i e s c *

a p p e a r s t o be t h e W - b l u e a n d r e d ( h p ~ a n d l x 2 ) .

areal sp i l l deilin 6 a t i o n (Canada, 1985; Zwick e t al . , 1981;

N e v i l l e e t a l . , 1979). -- W and red o r I R bands t o g e t h e r o f f e r c o n s i d e r a b l e o i l l w a t e r

Z

c o n t r a s t enhancement ( M i l l a r d and Woolever, 1973; M i l l a r d e t -

a - d l . , 1913). - P r a c t i c a l advantages of v ideo s y s t e s i n c l u d e r ea l - t ime viewing

and r eco rd ing , p o r t a b i l i t y , e a s e of i n s t a1 l a t i o n and o p e r a t i o n ,

low c o s t , and u s e i n f l i g h t l i n e n a v i g a t i o n and t r a c k recovery

( ~ a n a d a , 1985; Goodman and Morrison, -1985; N w i l l e e t dl., -- 1979; Worsf ie ld e t a l . , 1975) . --

3-2.1.3 LLISV- - 1. Capable of d e t e c t i n g o i l on water under n i g h t c o n d i t i o n s , t h i s

s e n s o r ty* a l s o o f f e r s t h e advantages of r e a l - t i m e d a t a

p r e s e n t a t i o n , wide f i e l d view and e a s e of u se (Goodman and

M o r r i k n , 1985; N e v i l l e e t a l . , , 1979). -- 2. May be l i m i t e d i n n i g h t u s e when l i g h t s a r e i n image o r i n d a y ,

use i n h i g h s e a s t a t e s ( N e v i l l e e t a l . , 1979). - -- 3. No a p p a r e n t a b i l i t y t o d e t e c t t h i q k n e s s (Zwick e t a l . , 1981 ). --

3.2.1.4 Radar.

1. T h i s s e n s o r can d e t e c t o i l under adve r se weather c o n d i t i o n s and

a t n i g h t b y measuring b a c k s c a t t e r d i f f e r e n c e s between o i l e d and

u n o i l e d wa te r s i n moderate s e a s t a t e s , but, i s n o t capab le of

r e a l - t i m e p r o c e s s i n g o r d e t e c t i o n a d e r calm o r s e v e r e s u r f a c e

c o n d i t i o n s (Thaman e t a l . , 1972; Aukland e t a l . , 1971; Catoe - - -- -- and O r t h l i e b , 1971; United S t a t e s , 1970).

3 6

Spectral Bands-

Ultraviolet.

1. T h i s b a n d i s c o n s i s t e n t l y r e p o r t e d t o o p t i m i z e t h e c o n t r a s t

b e t w e e n o i l a n d uater, p a r t i c u l a r l y w i t h r e s p e c t to t h r n

s l i c k s ( C a n a d a , 1985; Yuanfu -- et a l . , 1982 ; V l z y , 1974; Auk land

e t a l . , t 9 7 1 t C a t o e a n d O r t h l i e b , 1971'; Munday e t a l . , 1971; -- --

U n i t e d S t a t e s , 1971b; U n i t e d S t a t v 1970; L o w e a n d H a s e l l , "e

1969) .

V i s i b l e .

1. The b l u e band n e a r t h e u l t r a v i o l e t h a s so-me c a p a b i l r t y f o r o o l l

s p i l l detection (Yuanfu -- e t d l . , 1982; V ~ z y , 1 9 j 4 ; Hurlday - e t

a l . , 1971 ; uni ' ted ' S t a t e s , 1 9 7 1 b ) . -

2 . Some s o u r c e s r e p r t e d t h a t t h e g r e e n b i n d r s u s e f u l f o r

recording t h r c k 011 s l l c k s (Munday -- e t a l . , 1971 ; U n l t e t l b t a t c b , 'r

? 3 7 1 b ) , w h i l e a n o t h e r a r g u e d f o r t h e r e d b a n d (Yuanfu -- e t a1 .,

1 9 8 2 ) . V l z y ( 1 9 7 4 ) c l a i m e d n e i t h e r was s u l t a t l e .

/ H e a r or photographic infrared.

1. T h r s band by l t s e l f h a s p r o v e n of llttle u s 0 ~n 011 7 3 ~ 1 ~ 1 1 *- -

d e t e c t r o n o t h e r t h a n f o r t h e prx51ble e x ( - q ' t l o r , o f l o w bun

a n g l e c o n d r t l o n s (Yuanf u -- e t a l . , 1982 ; k u k l a r ~ d -- ct a! . , I 4 7 1 ;

C a t o e a n d O r t h l l e b , 1471; Munday -- e t a l . , 19711 U n i t e 4 St ate . , ,

1971b; UrA:ted States, 14751.

1. While several a u t h o r s r e p o r t t h a t t h i s port'ion of t h e spectrum I

i s s u i t a b l e f o r o i l s p i l l i d e n t i f i c a t i o n (Yuanfu 'kt dl., 1982;

Munday e t a l . , 127-1; United S t a t e s , 1971b; &owe and H a s e l l , . ,

1

1969) , c e r t a i n c a v e a t s may apply . Fbr example, sane t h e r m a l B

s e n s o r s a r e much less e f f e c t i v e - t h a n o t h e r s , some image t o o - "

many f a l s e t a r g e t s (Canada, 1985) a n d some a r e o n l y capab le of

d e t e c t i n g t h i c k s l i c k s i n c l e a r weather c o n d i t i o n s (Shinad: et

?.$This p o r t i o n of t h e spectrum can be u t i l i z e d by c e r t a i n

i n s t r u m e n t s as dl 1-weather backup t o o t h e r se nso rs , b u t

e x i s t i n g microwave i n s t r u m e n t a t i o n can be confused by b o a t H

wakes o r s e a waves (Aukland e t a l . , 1971 ; Catoe a n d Or th l ieb , ' -- 197P; United S t a t e s , 1970).

O i l Type. -

- No s e n s o r system i s a p p a r e n t l y capab le of a c c u r a t e l y

i d e n t i f y i n g types of s p i l l e d o i l (Canada, 1985; G r a c i , and

.iZaltabiano, 1983; Yuanfu -- e t a l . , 1982; Horvath and Stewar t , .

1971) . However, i t may be p o s s i b l e t o ~ s h o w o i l t ype u

d i f f e r e n c e s when more than one o i l t ype i s p r e s e n t (Vizy ,

3 ,

- - -

oil 'IbLckmere.

- There i s reportedly l i m i t e d potentla1 for E-ta a a n s i n g --

t e c h n i q u e s t o i d e n t i f y o i l s p i l l t h i c k n e s s . l b n a l variat ions f

in c o l o r photogr-aphy may i n d l c a t e t h i c k n e s s d i f f e r e n c e s

(Thamanf et g., 1972) as might a combina t ion of mu l t i s p e c t r a l

bands from u l t r a v i o l e t t o thermal - (Uni ted S t a t e s , 1971a ) . These c o n c l u s i o n s as d e r ~ v e d from Table 5 a r e l n a g r e e w n t m t h

/

s l m i l a ~ summarizat ions by s e v e r a l o t h e r a u t h o r s r n c l u d n g Canada (1984b) ,

and Wobber ( 1 9 7 1 ) . Their reviews summarize senso r t y p e s and spectral bands,

b u t provldp no r e f e r e n c e s from t h e L i t e r a t u r e . -

-4 I

3.3 Determination of Study Objective and Sensor System.

' The preceding interpretation of Table 5 r n d l c a t e d t h h t d ~ a h l c

a r e a l d e l l n e a t l o n of o r 1 s p ~ l l s was f e a s r b l e wi th a v a r r e t y of s e n s o r s a n d

under a range of environmental c o n & t r o n s . Such was' no t t h e c a s e m t h 011

type o r t h l c k n e s s . The l r t e r a t u r e was c l e a r t h a t 011 type denti if l c a t l o n has

r,ot h e n ach leved , but t h e r e 1s &sagreerrrent over whether 61,111 t h ~ c k n c s s car)

be determrned . ..Id

Canada ( l 9 8 5 ) , Geracl and Ca l t ab rano (1983 J , Zwzck e t al. (1981 ) , --

Shlmoda e t a l . ( l 9 7 5 ) , Thaman e t a l . ( 1972) and United S t a t e s ( 1971a) kla-ve -- -- l n d l c a t e d t h a t 011 t h l c k n e s s de te r rn lna t lon by remote scnsl ncj t e c klrilques 16

u n c e r t d l n a t b e s t . However, wl thrn t h e v l s ~ b l e s ~ , e ~ t r u m , some su:c:es& a t o i l

t h i c k n e s s i d e n t l f r c a t r o n has been achleved accord lny t o Yuanf u -- e t al. ( 1982 1,

Munday -- e t a l . (7971) and Unrted S t a t e s ( 1 9 7 1 t ) t h r o u g h u s e of the ultraviolet

, - band f o r t h i n s l r c k s and t h e red orr green bands f o r t h l c k e l l c k $ .

In a n e f f o r t t o r e s o l v e t h e m a t t e r , a aeries Q•’ testa and a field - -

t r i a l w e r e undertaken in t h i s s t u d y wi th t h e o b j e c t i v e o f de t e rmin ing whether -

o i l s p i l l t h i c k n e s s c o u l d be determined through s e l e c t e d f i l t r a t i o n i n t h e

photographic spectrum. It w a s i n t ended t h a t t h e s e experinrents exaqine ,

s e v e r a l o i l t ypes and a range of s e n s o r f i l t e r s f r a n t h e , W t o I R i n r e l a t i o n

t o s p i l l t h i c k n e s s .

Imaging of o i l s p i l l t h i c k n e s s can be a f f e c t e d by o i l type-, o p t i c a l .

such as s k y l i g h t and camera a n g l e , and water c o n d i t i o n s such a s

s u r f a c e r,oughness and t u r b i d i t y . Table 6 l ists t h e s e condi t ions : r a t e s t h e i r

importance and d e s c r i b e s how each w a s & a l t w i th i n t h i s s t u d y . Owing t o t h e /

. - -

r e p u t e d d i f f i c u l t y i n a c c u r a t e l y s e n s i n g o i l t h i c k n e s s , most of ' these

v a r i a b l e s were e l i m i n a t e d o r minimized i n o r d e r t o i s o l a t e f i l t e r t y p e a s - t h e

key t h i c k n e s s de t e rminan t .

With r e s p e c t t o s e n s o r system s e l e c t i o n , Table 5 i n t e ; p r e t a t l o n

s u g g e s t s very p r a c t i c a i r e a s o n s f o r choos ing v ideo : r e a l + i m e viewing a n d

r e c o r d i n g , p o r t a b i l i t y , e a s e of i n s t a l l a t i o n and o p e r a t i o n and u s e i n f l i g h t

. x

l i n e n a v i g a t i o n and t r a c k r ecove ry . Its a n a l o g t o d i g i t a l c h a r a c t e r i s t i c s , "

C a l low r a p i d and a c c u r a t e computer enhancement and a n a l y s i s . Video a l s o h a s

s a t i s f a c t o r y s e n s i t i v i t y in t h e b l u e and green bands f o r optimum u s e i n l i g h t

o v e r c a s t c o n d i t i o n s . The f i n a n c i a l c o n s t r a i n t s of most emergency response

o r g a n i z a t i o n s a l s o a rgue s t r o n g l y i n f a m r of v ideo because of i t s low c o s t .

With t h e s e advantages , v i d e o consequen t ly became t h e pr imary system of 1

cho ice . O .

..

TABLE 6. CONDITIONS &TED TO REMOTE S E N S ~ N G OF O I L SPILL THICKNESS - .

--

I L

w

Optical C o n d i t i o n s

O i l Type

Water C o n d i t i o n s

IMPORTANCE.

Majo r

M o d e r a t e

&]or

Major

Majo r "

Ma ] o r

M o d e r a t e

Min6r

CONDITIONS

S u n l i g h t

S k y l i q h t - t

Camera a n g l e

Crude o i l Waste o i l 10W30 o i l D i e s e l o i l ~ a s o l i n e

Surf ace r o u g h n e s s

T u r b i d i t y

M a r i n e v e g e t a t i o n

Tempe r a t u r e S a l i n i t y D i s s o l v e d

o x y g e n

i HOW DEALT WITH I N STUDY

Near ve r t i ca l sun angle$ t e s t e d . T e s t f n g d o n e with o v e r c a s t s k i e s . k o k a n g l e c o n s t a n t a t vertic'al'.

%

A\ IC

Each o i l t y p e s e p a r a t e l y imaged w i t h a v a r i e t y of f l l t e r s .

S e a s t a t e c a n g r e a t l y a f f e c t r e f l e c t i v i t y ; o n l y calm conditions imaged. F i l t r a t i o n i n t h e r e d band t e s t e d . This c a n be a f a c t o r n e a r - s h o r e ; n o n e a r s h o r e areas i m a g e d .

T h e s e a re n o t o f s u f i l c i \ e n t i m p o r t a n c e t o l n f l u e n c e r e s u l t s .

CBLLPTKR 4. lLgTHOD DlWEtO- AND '-LIsD -S 1

* L

Canmencing i n t h e summer of 1986, a s e r i e s of e o n t r o l l e d -

exper iments were c a r r i e d o u t t o tes t t h e hypo thes i s tha&,sel"ected v i d e o

f i l t r a t i o n can determine r e l a t i v e s p i l l t h i c k n e s s . These 9 . " exper iments were c o n t r o l l e d - t o l i m i t t h e v a r i a b l e s a f f e c t i n g t h e - o p t i c a l - -:

I

t h i t h e s s r e l a t i o n s h i p . F o r , example, envi ronmenta l i30nditions such as 0 . '1

su r f a c e roughness and . t u r b i d i t y cou ld be e l i m i n a t e d , whi le a p p r o p r i a t e

weather c o n d i t i o n s cou ld be used when t h e y became a v a i l a b l e . In a d d i t i o n , % .

t h e exper iments p e r m i t t e d s e l e c t i v e t e s t i n g of v a r i o u s v ideo ,cameras and

f i l t e r s p r i o r t o a c t u a l f i e l d u se . q -

.+*> . - -. The c o n t r o l l e d t e s t s p r p g r e s s i v e l y improved on one ano thea u n t l l a

v4

r e l t a b l e da t a s e t was adqu i r ed . Data were c o l l e c t e 6 f o r each expell'irnent i n

2.

t h e s e r i e s , b u t d i g i t a l d a t a compi l a t ion and a n a l y s i s werg completed o n l y f o r

t h e f i n a i t e s t .

4.1 M e t h o d of Data Collection -

Z

P?

4. 1. 1 Pilot Test. On 15 August 1986, a p i l o t t e s t was under taken a t

~ k m n F r a s e r U n i v e r s i t y f o r a b r i e f s i m p l i f s e d look a t whether th ickr iess \

- d i f f e r e n c e s cou ld be o b s e v e d . ' S i x t e e n t e n - l i t e r wh i t e bucke t s were f i l l e d

B I

with f r e s h w a t e r . F i f t e e n of t h e s e were in t roduced w i t h v a r y l n g q u i n t i t i e s \

(one drop t o 5 0 0 ml*) of waste o i l , d i e s e l o i l and g a s o l i n e . The o t k h was

- - l e f t wi th o n l y f r e shwa te r a s a c o n t r o l (Figure 8 ) . A Sony CCD v i d e o camera,

w i t h a s p e c t r a l s e n s i t i v i t y from t h e W t o t h e I R ( F i g u r e 9 ) was u t i l i z e d t o h -

image t h e c l u s t e r o f L b u c k e t s under b o t h d i r e c t s=ligh:t a n d f u l l shade

FIGURE 8. ARRANGEMENT OF PILOT TEST BUCKETS, SIMON FRASER UNIVEKSITY mOTE SENSING LABORATORY, 15 AUGUST 1986

Note: This 35 mm photograph shows shadow and sun lit areas i n t h e white buckets. The video imagery used for evaluat ion purposes i n t h e t e s t was c o l l e c t e d under f u l l sun condit ions i n i t i a l l y and then under f u l l shade condi t ions t o l i m i t exposure problems corn sun-shade c o n t r a s t .

#

\' .

-

-

FIGURE 9. SPECTRAL SENSITIVITY ' OF THE RCA NEWVICON AND SONY CCD V I D E O CAMERAS -

400 550 700 85(r . 1000 1150 I300

W A V E LENGTH ( N M I . -

,

SOURCE : Roberts, A ., and 0 . J. Evans, 1986: 7 3 2

condi t ions . S ix d i f f e r e n t f i l t e r types (18A, 88A, 400nm, 450nm, 500nm and

600nm) were s e p a r a t e l y mounted i n f r o n t of t h e camera l e n s to provide

s p e c i f i c wavelength coverage wi th in t h e photographic spectrum. The

t ransmi t tance c h a r a c t e r i s t i c s of t h e 18A g l a s s f i l t e r i s shown in Figure 10

by way of example. Appendix 3 shows t h e t r ansmi t t ance ranges of a l l of t h e

f i l t e r s used i n t h e p i l o t test .

The r e s u l t i n g recorded imagery was d isp layed on a monochrome

monitor i n t h e l a b and examined v i s u a l l y without enhancement. N o d i g i t a l o r

s t a t i s t i c a l ana lyses were undertaken. A t t h i s s imple l e v e l of examination,

t h e t e s t succeeded i n d a m n s t r a t i n g t h a t i t was p n s s i b l e t o v i s u a l l y

d i sc r imina te amongst t h i c k l a y e r s ( g r e a t e r t han 100 p m ) and o i l t ypes such as

crude o i l and gaso l ine , b u t n o t amongst t h i n n e r l a y e r s ( less t h a n 100 p m ) . However, it was considered a p o s s i b i l i t y t h a t d i g i t a l enhancement and

a n a l y s i s would be a b l e t o e i t h e r provide t h i s d i sc r imina t ion and/or s e t

d i sc r imina t ion limits f o r t h i n n e r l a y e r s . One p o t e n t i a l cause of t h e poor

t h i n l aye r d i sc r imina t ion w a s t h e t r ans lucence and *ite c o l o r of t h e buckets

which would have s i g n i f i c a n t l y i nc reased l i g h t l e v e l s (a lbedo) •’ran bottom

r e f l e c t a n c e . In t h e " t h i n l aye r " buckets t h i s would have added t o t h e

non-oil r e f l e c t a n c e and masked t h e weaker o i l r e f l e c t a n c e . A second t e s t was

t h e r e f o r e planned t o e l imina te t h i s background albedo problem.

4. 1.2 Shellburn Refinery Test. Arrangements were made wi th Shel lburn

Refinery, Burnaby, B.C., f o r u s e of i t s dock and foreshore f o r t h e second

test i n t h e series. I n each of f i v e 45 ga l lon drums donated by S h e l l Canada

Limited, f i v e e igh t - inch diameter ABS p l a s t i c p ipe c y l i n d e r s one foo t i n

l e n g t h were clamped v e r t i c a l l y ' (F igu re 11 1. A s i x t h 45 ga l lon drum was t o be

TOP P L A N

45 GALLON STEEL TANK

CLAMP MOUNTS

8 . DlA. A B S PLASTIC PIPE

MATTE BLACK INNER COATING ON 45 GALLON S T E E L TANK AND CYLINDERS

S E A W A T E R u OBLIQUE CUTAWAY VIEW

- - - - --- -

* 1

used as a c o n t r o l and t h e r e f o r e had n c clamped c y l i n d e r s . All of t h e

c y l i n d e r s a n d t h e i n t e r i o r of e v e r y drum w a s p a i n t e d m a t t e black t o r e d u c e

t h e h c k g r o k d a1 bedo. 1 I

The s i x drums were p o s i t i o n e d i n a n exposed area a d j a c e n t t o t h e

S h e l l b u r n Qck where seawater w a s pumped t o w i t h i n two i n c h e s of t h e top of

each drum. Diesel . o i l , g a s o l i n e , b u n k e r f u e l , w a s t e o i l and c r u d e o i l were

, , e a c h i n t r o d u c e d i n t o d i f f e r e n t drums i n f i v e q u a n t i t i e s r a n g i n g • ’ r a n 0.0324

cc t o ' 3 2 . 4 c c ( F i g u r e s 12 and 1 3 ) .

The q u a n t i t i e s o f h y d r o c a r b o n p l a c e d i n t h e c y l i n d e r s ' i n each drum

were o r i p n s l l y i n t e n d e d t o s u n u l a t e f i v e d i f f e r e n t t h i c k n e s s e s r a n g i n g •’rom

1 t o 10000 pm. U n f o r t u n a t e l y p o o l i n g o f t h e s m a l l e r h y d r o c a r b o n q u a n t i t i e s

(when t h e e n t i r e s u r f a c e w i t h i n e a c h c y l i n d e r w a s n o t c o v e r e d ) r e s u l t e d i n

some u n c e r t a i n t y as t o e x a c t t h i n l a y e r t h i c k n e s s e s . C a l c u l a t i o n s of - quantities f o r t b e purpose of r e p r e s e n t a t l n g t h i c k n e s s e s were as f o l 1 . 0 ~ ~ :

I n s l d e a r e a of each c y l i n d e r = t(r2 = 3.1416 ( 10.16 cm12 = 324 a n 2

If 1 p m = 0.001 mm, t h e n 10000 p m = 10 mrn = 1 cm

T h e r e f o r e , t o c o v e r a n a r e a of 32.4 cm2 t o a t h i c k r . e s s of 10000 a m , 324 cc

( 3 2 4 cm2 x 1 cm) were required*

~ o r r e s p o k d l n ~ t h i c k n e s s e s f o r o t h e r c y l i n d e r s were:

100 pn - 3.24 cc '

Imaglng was done under sun and s h a d e conditions w l t h a Sony CCD

vzdeo c a n e r a s e t on a p e d e s t a l m u n t b e s l d e th& S h e l l b u r n Qck a p i x o x l m t e l y

FIG

UR

E

12.

SC

HE

MA

TIC

O

F 4

5

GA

LL

ON

DR

UM

LA

YO

UT

, S

HE

Lk

8U

RN

.

RE

FIN

ER

Y

TE

ST

J,

15

SE

PT

EM

BE

R

CO

NT

RO

L

WA

ST

E O

IL

OJ

ES

EL

OIL

BU

NK

ER

F

UE

L

6

GA

SO

LIN

E

FIGURE 13. ARRANGEMENT OF 45 m L U N DRUMS, SHEL&BUIW W I N E R Y TEST, 15 SEPTEMBER 1986

above t h e drums pos i t i oned on t h e foreshore . F i l t e r s used i n t h e t e s t were

18A, 87B, 88A, 450nm, 550nm and 650nm (Appendix 3 ) .

On v i s u a l l y reviewing t h e v ideo imagery l a t e r on a monochrane

monitor, it was discovered t h a t , although some v a r i a t i o n s i n o i l type and

t h i c k n e s s were d i sce rnab le , t o o l a r g e an a r e a appeared i n each image. This

meant t h a t i n d i v i d u a l c y l i n d e r s were too s m a l l f o r proper viewing o r

d i g i t i z i n g . In a d d i t i o n , t h e non-ver t ica l sun ang le caused d i r e c t sun and

deep shade c o n t r a s t s i n t h e drums which r e s u l t e d i n a t o o wide exposure range

t h a t made a c c u r a t e r e f l e c t i v i t y measurements very d i f f i c u l t . Consequently,

it was necessary t o design a t h i r d and f i n a l c o n t r o l l e d test.

4.1.3 Final Cbntrolled Test. The s e t u p f o r t h e f i n a l c o n t r o l l e d t e s t

(05 October 1986) a t S i m n Frase r Univers i ty was s i m i l a r t o t h e Shel lburn

Refinery test except t h a t t h e drums were pos i t i oned i n a s t r a i g h t l i n e and

imaged i n d i v i d u a l l y from a near v e r t i c a l p o s i t i o n . The water c o n t r o l was i n

t h e c e n t r e of each drum between c y l i n d e r s r a t h e r t han i n a s e p a r a t e drum.

Hydrocarbon types were c rude o i l , waste o i l , 10W30 o i l , d i e s e l o i l and

gasol ine . Hydrocarbon q u a n t i t i e s were aga in 0.0324 c c t o 324 c c t o r e p r e s e n t

t h i cknesses r ang ing by o r d e r of magnitude b e t w e n one and 10000 pm

(micrometers o r microns) . However, pool ing of t h e sma l l e r q u a n t i t i e s (0.0324

- 3.24 c c ) made accu ra t e de te rmina t ion of t h e s e t h i c k n e s s e s impassible .

The camera s e t u p was i d e n t i c a l t o t h a t of t h e p i l o t t e s t except

t h a t an RCA Newvicon r a t h e r t h a n a Sony CCD v ideo camera was used.

F i l t r a t i o n inc luded no f i l t e r , 18A, 88AI 650nm, 550nm, 450nm, 301A/92

combination, 50 and 30 1A/46 combination (Appendix 3 ) . (No f i l t e r impl ied

f u l l t r ansmi t t ance throughoGt ' t h e photographic spectrum according t o t h e

I s p e c t r a l s e n s i t i v i t y of the capera - F i g u r e 9 . ) A t e n - s e c o n d d u r a t i o n

hydrocarbon image a n d a separate f i v e - s e c o n d label led image were r e c o r d e d o n .

a Sony 8mm v i d e o cassette r e c o r d e r ( V C R ) far each h y d r o c a r b o n type under b o t h _r

I direct strn a n d f u l l s h a d e c o n d i t i o n s .

4.2 Data Caqilation

The imagery a c q u i r e d i n t h e f i n a l c o n t r o l l e d t e s t was f l r s t

examlned f o r c a n p l e t e n e s s and c lar l t y . T_he f lve - second l a b e l l e d images . *

-- - A .-- , ,' ' ' preced lng ,_ the t en-second hydrocarbon linages were used t o l d e n t l f y t a p e

c o u n t e r r e a d i n g s on t h e VCR for each f i l t e r f o r each .hydroci i rbon for suf, a n d

s h a d e c o n d i t i o n s . W i t h i n e a c h t en-second h y d r o c a r b o n image i n t e r v a l

. ( a p p r o x i m t e l y 3 0 0 v i d e o f r a m e s ) , t h e c l e a r e s t r o ' k i o n w a s s e l e c t e d b r 1

d l g i t i z a t i o n .

p i g i t i z a t i o n was c a r r i e d o u t on t h e Simon F r a s e r TJri lversl ty VAX

1 l/7SG IIS image a r i a l y s l s s y s t e m u s i n g a waveform r ron l to r and t l m e b a s e

d o r r e c t o r . The l a t t e r two p l e c e s of ha rdware were ~ n c l u d e d I n t h e s y s t e m t o

adjust t h e peak v o l t a g e f o r e a c n unage t o e n s u r e H o p e r e x p o s u r e and t o

p r o v l d e lmage s y n c h r o n l z a t l o n f o r the v l d e o d l g l t l z e r I n t h e a n a l y s l s sys tem.

An example of a d i g i t i z e d image o f b e s e l o i l u s i n g a 3 3 1 A / 4 6 cor rbrna t lon

f l l s e r under f u l l s h a d e conditions and v a r y i n g t r c k n e s s e s 1s p r o v l d e d I n / R

F l g x e 14. ) 3 b

~ o l l o w l n ~ & g ; t l z a t l o n , t h e l n d l v l d u a l llcage f r a m e s were v r s u a l l y ..

examined. I t was n o t i c e d t h a t a nuraker of d x e c t s - m c o n h t m n rmages were

4 o v e r e x p s e d o r a e q r a d e d b e c a u s e of oveA?roltage f l a r e from s p e c u l a r

re f ;e=ance. F i n a l a ~ a l y s e s f o r t h l s c o n t r o l l e d t e s L were t h r e f o r e

FIGURE 1 4 . EXAMPLE OF A DIGITIZED IMAGE - DIESEL OIL, 301A/46 COMBINATION FILTER, SHADE - SHOWING NOMINAL THICKNESSES FRCM 1 M1CW)N TO 1 0 0 0 0 MICRONS

- ---- -- ---

/

reqtricted t o shage cond i t ions only , because of t h e d i f f i c u l t y of dea l ing

wi th t h e s e d i s t o r t e d high c o n t r a s t images.

Using t h e XIS System 5 0 0 sof tware ( I n t e r n a t f o n a l Imaging Systems

Lnc., 19801, s e v e r a l da ta ewmina t ion p rocedwes were run or- each image.

P r o f i l e s and graphs of r ad iomet r i c va lues , a s i l l u s t r a t e d i n F i g u r e 15, were -

f i r s t used f o r s e l e c t e d t a r g e t r e f l e c t a n c e c r o s s - s e c t i o n s to determine i f

d i g i t a l b r i g h t n e s s l e v e l s ( a l s o known a s r e f l e c t i v i t y o r grey l e v e l s )

inc reased I n r e l a t i o n -to hydrocarbon q u a n t i t y (i .e . , approximite t h i c k n e s s ) . This appeared t o be t h e case , s o another so f tware r o u t i n e ( b l o t c h ) was used

\

t o measure grey l e v e l s In des ignated a r e a s o r b l o t c h e s .

F i n a l l y , f b r each s e l e c t e d t a r g e t a r e a , each p l x e l was individually

examined to r e c o r d p i x e l - s p e c i f i c grey l e v e l values ( 8 kt r e s o l u t i o n : 0-256

l e v e l s ) . I n each image f o r each q u a n t i t y ( o r approximate t h i c k n e s s ) , 1 2 grey

l e v e l p l n t s were sampled and averages acrcss t h e s l l c k a r e a . An ad lacen t

water a r e a was a l s o sampled 12 t imes , averaged and s u b t r a c t e d f r m t h e

hydrocarbon mean grey l e v e l t o reduce any h i a s caused b y radlometr lc camera

l e n s distortions such a s l r g h t f a l l -o f f . The r e s u l t i n g values were def lned

a s a d j u s t e d mean grey l e v e l s ( o r r e f l e c t l n t y l e v e l s ) and w r e recorded by

hydrocarbon type and filter type ( T a b l e . 7 ) . These d a t a provrded t h e b a s l s

f o r 'subsequent s t a t l s t l c a l calculations . ' r"

\

The

us i ng STATPRO

nicr ocomputer

4.3 Data Analysis and Interpreation 3

data compi la t ion i n Table 7 was graphed by hydrocarbon type

sof tware (Penton Software Inc. , 1985 ) on an IBM-AT

(F igures ' t 6 - ? 0 ) . I n al l . f l v e graphs. t h e r e appeared t o be a,n i

FIGURE 15- EXAMPLE OF A PROFILED AND GRAPHED IMAGE - DIESEL OIL, 3 0 9 A / 4 6 CCMBINATION FIUPER, SHADE

X-axis: Number of pixels along selected red profile Y-axis : Reflectivity or grey level where

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, i n c r e a s e i n a d 2 u s t e d mean grey l e v e l (or w i t h a n i n c r e a s e ._

- - - . . - i n hy&ocarbon q u a n t i t y or a p p r o d m t e

i However, t h e a d j u q t e d mean g r e y l e v e l betweep 1 09 and 10000 m i c r o n s d i d n o t

-- d f o l l o w t h i s v e n d . a I n s t e a d , v p l u e s (?line s l o p s ) over 100.0 h i c r o n s were m r e

I 4 B or less n e u t r a l w i t h no g e n e r a l p o s i t i v e t r e h d a p p a r e n t .

t . . f J

A n d y r e d by hydrocarbon t y p e , e l o p e s be&een 1 a n d f00O.

rmcrons a p p e a r e d s t e e p e r f o r t h q trans n t h y d r o c a r b o n s s&h as- 10W30 011, -. - 1 -

&esel 011 a n d gasoline. 1n t h e =re ue c r u d e and w a s t e o l l , s , t h e y d l d , 9

n o t shov ,as much r e f l e c t a n c e & f f e r e n t r a l . T h l s c o u l d have been' a

, 'consequence %of a lower c a p a c i t y of t h e c r u d e and w a s t e 011s ,to pe-t p a s s a ye

through them of i n t e r g a l l y r e f l g c t e d l i g h t w l t h l n t h e c y l i n d e r s and t h e r e f o r e P . .

t h e s e c u r v e s " f l a t t e n e d o u t " e o o n e r .

There w a s a l s o a relatively consistent p a t t e r n I n a d j u s t e d mean

. , - grey l e v e l s f o r a f • ’ = r e n t ' f l l t e r t y p e s . Forr ewrnp le , t h e 18h f i l t e r u s u a l l y

had t h e l o w e s t of o v e r a l * l g r e y l e v e l s , w h l f e t h e 65Dnm and "no f l l t e r n

f l l t e r s d e m n s t r a t e d r k l a t i v e l y h i g h e r a d j u s t e d mean g r e y l ,evels. T h l s was a

f w x t l o n of e x p o s u r e l e v e l s ( v o l t a g e ) w i t h l n t h e camera; t h e s e l e v e l s were a

f m c t l o n of t h e t r a n s m s s l o n c h a r a c t e r l s t l c s of e a c h f l l t e r a n d t h e s p e c t r a l

6" s e n g l t l v i t y o f t h e c a n e r a a s w e l l as f - s t o p and l l g h t l e v e l .

A s e r i e s o f . statistical a n a l y s e s were a l s o c a r r l e d o u t on t h e & t a

l n T a b l e 7 u s i n g SHkZAM (Whlte, 1984) s o f t w a r e on a T C a l l a n U n l s t a r

mic rocompute r . The f l r s t a n a l y s i s was a combined f l l t e r m u l t l p l e r eyes s l o n

f o r e a c h h y d r o c a r b o n t y p e i n which o i l t h i c k n e s s w a s . s e t as t L e i n d e p e n d e n t

variable and each grey l e v e l set a s t h e depericknt v a r i a b l e . R e s u l t i n g 1

r e g r e s s i o n s l o p e , T - r a t i o and ~2 v a l u e s f o r b o t h l i n e a r and l o y a r i t h m l c

6erles are p r e s e n t e d i n T a b l e 8. T h e s e values c l e a r l y s b w e d t h e

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r e l u t i o n s h i p o f a d j u s t e d mean grey l e v e l to h y d r o c a r b n t h i c k n e s s to be A -

l o g a r i t h m i c r a t h e r t h a n l i n e a r . L o g a r i t h m i c r e g r e s s i o n slopes i m p l i e d a

distinct t r e n d of i n c r e a s i n g a l b e d o or g r e y l e v e l w i t h i n c r e a s i n g t h i c k n & s ,

suppo-ing -- t h e .study h y p o t h e s i s t h a t v i & o imagery can detect d i f f e r e n c e s ' in

s p i l l t h i c k n e s s . T - r a t i o s f o r t h e 'logarithmic r e g r e s s i o n s were a l s o - \

c o n s i s t e n t l y h i g h e r , i n d i c a t i n g a g r e a t e r ?egree o f s i g n i f l & n c e t b n for t h e

.* l r n e a r , while R~ v a l u e s d e m o n s t r a t e d t h a t the l o g a r i t h m x r e g r e s s i o n s had a

h t t e r o v e r a l l f i t t h a n t h e l i n e a r e s t i u n t i o x x i . L o g a r i t h m i c r e g r e s s i o n t s l o p e s f o r t h e l l g h t e r h y d r o c a r b o n s , 10W30 o i l , d r e s e l o i l and gasoline, w e r e

steeper t h a n f o r c r u d e o r w a s t e 011, c o n f l r m l n g a s l m l l a r observation n o t e d - 9-

e a r l r e r I n r e l a t l o n to figures 16 - 20. The coef f l c l e n t s of t h e l o g a r l t h m x

r e g r e s s i 6 n s a1 1 e x h l b l t e d a h r g h statistical s l $ l f l c a n c e . S t a n d a r d e r r o r s - -z.

and f-statistics f rom t h e SKkZAM o u t p u t a l s o were exarmned; I n a l l c a s e s t h e

f - s t a t ~ s t i c s indicated s i g n i f i c a n c e of t h e e q u t l o n s as a whole.

The second a n a l y s i s a p p l i e d t o T a b l e 7 & L U was a l o g a r i t h u u c

m u l t l p l e r e g r e s s i o n of a d j u s t e d mean g r e y l e v e l a F l n s t hydrocarbon t h r c k n e s s

by hydrocarbon t y p e and f l l t e r t y p e ( T a b l e 9 ) . I n e a c h c a s e , t h e a d j u s t e d

of a particular f l l t e r was s e t a s t h e d e ~ n c k n t v a r l a b l e and '

- - 11 t h l c k n e s s a s t h e lndepef iden t G s r i a b l e . I n t e r m s of

v a l u e s , T a b l e 9 c o n f l r m s t h e e a f l l e r 7 j

& s c r m r n a t l o n of hydrocarbon t h l c k n e s s by w l d e o lmagery was q c a t e r f o r

l i g h t e r h y d r o c a r b o n s t h a n f o r t h e more opaque c r u d e and w a s t e o i l s . F l l t e r s

m t h the m o s t m e a n i n g f u l and consistent v a l u e s f o r r e c p e s s l o n s l o p e , T - r a t l o

and R~ w e r e "no f i l t e r " , 88k, 550nm, 4 5 0 m and 301A/46 r e s p e c t i v e l y . T h l s

was particularly so f o r &?=,el o i l and g a s o l i n e . I t s h o u l d be n o t e d t h o u g h

t h a t , t n e l e n s u s e d w i t h t h e 1 8 A g l a s s f l l t e r r e s u l t e d i n u n d e r e x p o s u r e s and

t h a t a g e l a t i n f i l t e r o r lene w i t h a l a r g e r aperature would have p r w i d e d

better r e s u l t s as would have gain oontrpox ad jus tmen t s d a i n the vi*o canrera

r i t s e l f .

*

I n sumrmry, a n a l y s i s of t h e f lnaL c o n t r o l l e d test d a t a showed t h a t

v ideo imagery with s e l e c t e d f i l t r a t i o n c o u l d p o v i d e o r B r of m a ~ i t u d e ? .

comparisons 6f h y d r o c a r w n t h i c k n e s s e s up t o 1000 microns (1 mm) based on -* c

', f ef l e c t a n c e measurements. Thicknesses g e a t e r t h a n 1000 microns s b w e d n o J ,

d s s c e r n a b l e r n c i e a s e r n r e f l e c t a h c e va lues . The a b l l l t y of v l d e o systems t o

&sc r l rmna te r e l a t rve o l l t h l c h e s s e s appeared to be g e a t e r f o r t r a n s 1 ucent

hydrocarbons such a s lm30 011, d l e s e l 011 and g a s o l l n e r n c o n t r a s t t o

o r w a s t e 011s. For t h e s e . l r @ t e r hydrocarbons, f l l t e r s whlch appeared

p rov lde t h e g r e s t e s t r e f l e c t a n c e dsf f e r e n c e s , a s de f lned by r e q r e s s l o n 6

' T - r a t i o and R ~ , were "no f ~ l t e r " , 8Bk, 550nm, 450nm and 301A/46.

#

crude

t o

s l o p e ,

(he of t h e problems encountered in t h e c o n t r o l l e d test s i t u a t i o n

was npooling" of t h e hydrocarbons on t h e su r face of t h e cyl inders . A f i e l d

t r i a l was t h e r e f o r e planned to provide a l a rge su r face a rea t o reduce t h i s

d i f f i c u l t y . The f i e l d t r i a l a l s o o f fe red an oppor tunt i ty t o i n v e s t i g a t e t h e

e f f e c t s of c e r t a i n environmental parameters a s well as t o test t h e remote

sensing equipment under opera t ional condit ions.

5.1 H e t b o d of D a t a Collection

The study a r e a i d e n t i f i e d f o r f i e l d t e s t i n g of t h e r e s u l t s acquired

from t h e con t ro l l ed tests was i n Burrard I n l e t (Figure 2 1 ) . This a r e a was

s e l e c t e d because of i t s usual ly calm, c l e a r waters, i t s proximity t o an

a i r p o r t and cleanup equipment depot, and i t s concentra t ion of potent i a1 o i l .

s p i l l sources including f r e i g h t e r anchorages, four r e f i n e r i e s , t h r e e chemical

p l a n t s and some chemical t r a n s f e r te rminals . Environmental Protec t ion

Service (EPS) records (Canada, 1986d) indica ted t h a t seven medium-sized o i l

s p i l l s occurred i n Burrard I n l e t i n 1985, approx imte ly one every two m n t h s .

With t h i s frequency it was o r i g i n a l l y an t i c ipa ted t h a t a convenient s p i l l of

opportunity would be l i k e l y f o r undertaking a f i e l d t r i a l . Environmental

Emergencies Branch of EPS agreed t o provide n o t i f i c a t i o n i n t h e event of any

medium-sized s p i l l i n Burrard I n l e t and, a s we l l , s eve ra l a i r c r a f t s p i l l

searches were made. Between October 1986 and e a r l y arch 1987, only one

s p i l l of s u f f i c i e n t s i z e occurred i n t h e area. Unfortunately, t h e remote

sensing a i r c r a f t t o be used i n t h e study was under r e p a i r a t t h e time.

* . W i t h o u t a sp i l l of o p p o r t u n i t y , it became n e c e s s a r y t o o b t a i n -'

-

f ' - > C --

p e r m i s s i o n to create a f i e l d t r i a l s p i l l s p e c i f i c d l l y for t h e s t u d y .

A p p l i c a t i o & v a s made to t h e w e d n A p p r o v a l P r o c e s s (ODAP) f o r this b-

purpose (Append ix 4 ) . A g e n c i e s such as t h e C a n a d i a n C o a s t G u a r d , D e p a r t m e n t -

,o f F i s h e r i e s a n d O c e a n s , c a n 2 d i a n W i l d l i f e Service a n d P o r t of Vancouve r were

n o t i f i e d . C b n c e r n w a s w p r e s s e d b y same o f t h e e n v i r o n n m n t a l agencies, b u t f

a p p r o v a l e v e n t u a l l y was g r a n t e d b a s e d o n t h e e x t e n s i v e r n v o l v e m e n t o f B u r r p r d

C l e a n L i m l t e d , a s p i l l c l e a n u p c o n t r a c t o r whlch a s sumed r e s p o n s l b l l t y f o r

s p i l l c o n t r o l a n d c l e a n u p .

The v l d e o p a c k a g e d e v e l o p e d f o r t h e f l e l d t r i a l , c o n s l s t e d of a f o u r

camera a r r a y v i t h e a c h camera h a v r n g i t s own Ehm v l d e o cassette r e c o r d e r a n d

, ' s e l e c t e d opt ical f l l t e r , a waveform m o n r t o r a n d a m o n o c h r m e m o n l t o r , ( F i g u r e ,

6 2 2 ) . A s w i t c h c o n t r o l was ;r;z:.jded f o r camera s e l e c t i o n f o r & s p l a y o n t h e '

monochrome monito; . The c a m e r a s c o n s l s t e d o f t h r e e Sony CCLJ mo*&hromes and -l 8 2 ' J

a n R f A k i e w l c o n b l a c k arid A l t e . The v l d e o c a m e r a s v e r e s e n s i t r v e I n t , h e

r a n g e s shown i n F l g u r e 9. The h y d r o c a r b n c h o s e n was d lese l b e c a u s e i t had -. i d e m n s t s a t e d good t h l c k n p s r e f l e c t a n c e rn t h e f m a 1 c o n t r o l l e d tes t - a n d wds

\

a p p r o v a b l e u n d e r ODAP. The f r l t e r s s e l e c t e d were I t i A , SOOnm, 600nm a n d , 88k

( A p p e n h x 3 ) . I n s p l t e of some of t h e d i f f i c u l t l e s e x p e r i e n c e d w l t h t h e 18.4

- f i l t e r i n t h e f l n a l c o n t r o l l e d t e s t , ~t was n o n e t h e l e s s c h o s e n b e d a u s e of ~ t s . . a - I

w e l l d o c , u m n t e d h i g h o l l t o w a t e r a n t r a s t . The r e m l n l n g t h r e e filters e a c h

r e p r e s e c t e d a band selectlor? v?~l=t. h a 3 ' p r o v e n prom:s ing r n t h e final

c 6 n t r o l l e d test. . - ai

I n a d d l t l o n t o t h e v l d e o e q u l p n e n t , two Nlkon 35 mm p h o t o g r a p h l c 2

cameras w l t h 2 4 nm. t j lkkor lenses vCre u t i l l z e d l n t h e f i e l d t r i a l . me of &

t h e c a m e r a s was l m d e d v l t h Kodak 2 4 4 3 k e r o c h r o m e I n f r a r e d f i l m and f l t t e d

j .

w i t h a tiikon 056 IWfat ten 2 2 ) f i l t e r t o e l i m i n a t e t h e b lue and -blue-green E I " . . C

e p e c t r a l r e g i e n e . ' The u t h ~ r ~ c a m e r a caontainh k d a k 5037 Ektackcrme Tungsten : . + 1 5

s - .

. f i lm and u d d a n 858 f i l t e r . The two cameris c m i n e d & p r o v i d e f u l l -

a- photographic spec t rum Waging . he s p e c t r a l s e n s i t ivl t y 'of - t h e ' two- f i l m .

2 - . types i s shown i n F i g u r e 23.) 4 " - . a

-\

/ &

, . L C

The a i r c r a f t used rnl fie1.d trid d a t a &o l l e&ion . w a s h Cessna. 185 - . d 5'

wirh'9 inch and 16 l n c h pho'tography p o k t s , a 1000 m i l e rqqge and 30~000 f e e t * \

0 L

a l t i t u d e c a p a b l l ~ t y . Tn l s a i r c r a f t 1s r e l a t l v e l k i n p x ~ n s i v 6 t o prpduce and . , c

o p e r a t e , y e t h a s practical per formance characteristics f o r o p e r a t i o n a L u s e .

, . * d W f e r e n c e measurements of s p 1 l l thickness f o r cor re1 ,a t lon w l t h - * , ,b: t L .

0

v ideo and pho tog rap lpc imagery o b t a m e d from t h e a l r c r a f t were c o l lect 'ed t i

. . th rough s u r f a c e s a ~ p l - h g from a b o a t u6ing.a ~ o s s - ~ e l o r e ~ s a m ~ l 6 ; ( F t g u r e 24!.

1

Tnk s a p l e r t o be d+opp&d o n t o a s p s l l s u r f a c e so r h a f i t s * ,

a a b o t t o d edge c o c l d t r ap . and +sorb- fhaf a r e q of t h e s p l l wit? a s p 5 c i a l l y

4 ' L

n 1

dgslgned absorbent pad. A f t e r each f i e l d Trial sample was ~ b t a ~ L n e d t t h e .. a

absortn2ntwas removed and p l a c e d l n t o a numbered, t lme-referenced sampllng . , r P

] a r which w a s > s e a l e d f o r l a t e r labo;atory analysis. 9 . ?

' - Ch 10 3anuary 1987, a p r e l l m l n a r y s o r t i e was xrade ove r Burrard - "

- - 1$1et,to check t h e v l d e o ' systea under rGl-eipe . c p n & t i + n s . R11 c a n p n e n t s ,

riqke,d s i i ccpss fu l lq except t h a t ifhe sensitivity of t h e $ens .on t h e liewvicon a

\

casiera was n 6 t h igh enough f o r ;he r e l a Q t i v e l y h i g h o p a u t y o i t h e 18A f i l t e r . - . \ - \ *

mi's was l a t e r r e c e i f l e d P r i o ~ t o t h e q c t u a l f ~ e l d t r i a l ' t h r w g h use o f ' r , .

&f f e r g n t l e n s w t h ( a n a $ d i t l o n a l f - s top . P

bb * \ I

. - -. Th5 f l e l d ' t r l a l to& p l a c e on 18 March, l-987 i n Bur ra rd I ? 5 ' '

a ( ~ i ~ u r e 2 1 ) ar a p p r o j e d un&; ODAP. R Begies sf 'conse;u$lve pas b . i

- 1 CGSaan3. 500 f o % e l e v a % l o z s were ca3e between I 1 18 hours and 1 2 0 0 hours

- t* - r"

1 - , - t - - a

-, c

FIGURE. 2% S P E C T ~ A L ~ E N S I T I V I T Y O f FILMS USED IN FIELD TRIAL

0

C D

0 ' 1 I

4 -B ' 0 " - -

* 1

= 3

e

U O D A K 2443 AE- CHROME' INFRARE'O FICM '

FIGURE 25. AERIAL VIEW OF FIELD TRIAL, BURRARD INLET, 18 MARCH 1987

P a c i f i c Stsndard Time. Sur face sampling was c a r r i e d ou t s inmltaneously wi th

t h e ovgrhead passage of t h e a i r c r a f t ; uatch synchroniza t ion between t h e f i e l d

, sampler and camera o p e r a t o r made it l a t e r p o s s i b l e to patch t h e l abora to ry

r e s u l t s from t h e s u r f a c e samples with t h e video and photographic imagery. A

t o t a l of 18 p a s s e s were made of which four were l a t e r dropped from a n a l y s i s "

because two were on ly f o r 6quipment adjustment, one had no s u r f a c e samples

and one d id not inc lude t h e 6ampling.boat i n t h e v ideo imagery. The camera

m t h t h e i n f r a r e d f i l m malf unctmned nea r t h e s t a r t of opera t ions and , -

1

theriefore prevented c d l l e c t i o n of color ' I R photographs. This r e s u l t e d i n

l ack of photographic co r robora t ion of video rR r e s u l t s .

Enviroqmental conditions during t h e f i e l d t r i a l were optimum i n

terms o,•’ l l m i t i n g t h e p o t e n t i a l v a r i a b l e s i d e n t i f i e d in Table 6. The s e a was

t c a l e and c l e a r , while t h e sp i l l s i t e was s u f f i c i e n t l y o f f s b r e f o r marme

vegetation n o t t o be a ' f a c t o r . The sun was a t a n e a r v e r t i c a l angle and

t h e r e was a c o n s i s t e n t , m d e r a t e l y t h i c k cloud cover a t 2 , 0 0 0 f e e t which

minimized t h e sun g l a r e problem. These c o n d i t i o n s p l u s t h e f u l l func t ion ing

of t h e v ideo equipment onboard t h e a i r c r a f t and t h e s u r f a c e sampler on t h e .t

, boa t p r w i d e d 14 f l i g h t l i n e s of u s e f u l *&ta . ~ & t from t h e l o s s of one

a d d i t i o n a l f l l g h t l i n e wi th t h e colo; photographic camera, e x c e l l e n t c o l o r *

I I ~. p h o ~ o g r a p h s were acqu i red f o r a l l o ther f l i g h t l i n e s .

f

na ta Compilation

5.2.1 Surface !%mples . Surf ace samples c o l l e c t e d dur ing t h e f i e l d r ' 1 -"

t r i a 1 were q u a n t i t a t i v e l y analyzed i n ' the West Vancouwr - A n a l y t i c a l e 't

Laboratory of Environment Canada. Deta i led procedures f o r t h e quantification

of t h e diese; o i l c o l l e c t e d i n each &orbent-pad a r e p resen ted in A p e n d i x 5. L

A P e r k i n - ~ l n e r -?lode1 8 8 2 I n f r a r e d Spectrophotometer provlded t h e a f i a l y t l c a l

' results, The va lue o b t a i n e d f o r each sample frarn t h e chemica l a n a l y s i s was -

expressed i n mg- The methog f o r t r a n s l a t i n g w e i # t t o t h i c k n s s s &r e a c h 4

sample was + f o l l o v s :

Thickness (TI = Volume of D iese l Sample (V) Area' a f Ross-Belore Sample Pad (A)

Kndwing Weight (W) = Densi ty (D) x Volume (V) . Then V = WID

and T = !W/D)/A

5

+ - Now W i s known i n mg f o r each sample, by l a b o r a t o r y a n a l y s i s ,

- D i s how; by l a b o r a t o r y q u a l i t y ' c o n t r o l f o r t h e d i e s e l o i l I

I . used i n t h e f i e l d t r i a l 10.8625 gm/cc), , A i s : d e r i v e d by A = wr2 = 3.142 x 7.72 = 186.3 cm2, So T can be c a l c u l a t e d i n cm o r F m .

7 *

Weight and conve r t ed t h i c k n e s s val 'ues f o r e a c h f l i g h t l i n e sample

i l a r e p re sen ted i n Table 10. Thickness v a l u e s a r e . inc luded i n r e f l e c t a n c e / . r

- t h l c kness c o r r e l a t i o n s a e s c r i b e d l a t e r i n t h i s c h a p t e r .

C

.%

. , * C - I

a .* 5.2.2 For m a n i n g f u l d a t a compi l a t ion of f i e l d t r ia l

imagery, it was l k s t n e c e s s a r y t o i d e n t i f y * ich f l i g h t l i n e s s b w e d pu r face ,

sampling a c t u a l l y o c c m r i n g , i n o r d e r t o be a b l e t o c o r r e l a t e imagery

3 * * . measurements wi th s u i f a c e t h i c k n e s s e s . For t h e 14 v i d e o f l i g h t >lines f i t t i n g

1 - d . t h i s ca t egory , th-e imagery was a g a i n reviewed with' c o u n t e r r e a d i n g s o; t h e

v ideo c a s s e t t e r e c o r d e r n o t e d where t h e sampling b a t appeared n e a r t h e ,

/'

c e n t e r o r n a d i r of t h e l e n s . Each of thethcounter r e a d l n g s was used a s = ;

r image d i g i t i z a t i o n on t h e VAX11/750 I I S image a n a l y s i s system

form moni tor and t i m e base c o r r e c t o r . 1

For t h e c o l o r photography, images *ich showed s u r f a c e sampling ,, '

I i

r e s e l e c t e d f o r VAX 1 l/75O IIS d i g i t i z a t l o n . D i q i t i z a t i o n

"r

TABLE l o . SAMPLE WEIGHTS DETERMINED BY c a m m a ANALYSIS AND

FLIGHT LINE

NUMBER

1 2 3 4 5 6 7 8 9

10 1 1 12 13 14

SAMPLE WEIGHT (mg)

U S 0 19

31800

/ 6 2 9 6 5 2 0 -55

9 13 17 -

9 ' 44 4 2

was carried out by s e c u r i n g each s e l e c t e d c o l o r 35 mm f rame on a l i g h t , t a b l e

and imaging i t v i t h a v i & o camera rqlulated by a waveform .onitor: Each

frame was s e q u e n t i a l l y imaged v i t h R a t r a n 25 (red) , 58 ( g r e e n ) a d 47 ( b l u e ) . \

f i l t e r s I n c o n j u n c t i o n w i t h a 301A f i l t e r ( f o r e l i m i n a t i o n of n e a r i n f r a r e d

ene rgy ) s o as t o c r e a t e a d i g i t i z e d c o l o r composi te image.

The f i r s t examinat ion of t h e 14 d i g i t i z e d v ideo images ( F i g u r e 26)

was used t o de te rmine t a r g e t r e f l e c t i v i t y a c f o s s a t r a n s e c t . Th i s p r o f i l i n g

- %-'

--mid graphing conf i rmed s p l l l t h i c k n e s s vb r i a \ ions s o t h a t a seconq r o u t i n e

( p o i n t s ) was used t o de te rmine a d j u s t e d mean grey l e v e l s ( b r i g h t n e s s l e v e l s )

I n a manner i d e n t i c a l to t b a t u sed for t h e f i n d c o n t r o l l e d test. Table 11

show% a d j u s t e d mean grey l e v e l s by f i l t e r t y p e and d i e s e l . o i 1 t h i c k n e s s ( a s

de r ived i n t h e .preceding s e c t i o n ) on a f l i g h t Line b a s i s a s w e l l a s a l t i t u d e - .'

and t ime of sampling.

With r e s p e c t t o t h e b g i t i z e d r e d , g reen and b lue bands acqu i r ed

f r o m t h e 35 mm c o l o r photography, t h e a d j u s t e d mean grey l e v e l f o r e a c h band -

of t h e s e l e c t e d image f o r each f l i g h t l i n e was determined us ing t h e p i n t s

and a r e shown i n Table 1 2 a l o n g w i t h measured d i e s e l o i l t h i c k n e s s e s . It

* 3

s h o g l d be n o t e d ' t h a t c e r t a i n f l i g h t l i n e s a r e m i s s i n g • ’ r a ~ Table 1 2 as \

e x p l a i n e d i n more d e t a i l i n t h e n e x t s e c t i o n .

5- 3 Data Analysis and. Interpretation

Table 11 d a t a were p r e s e n t e d i n two graphs ( F i g u r e s 27 'and 28 - I .

B F i g u r e -27 p o r t r a y e d a canp$ i&fed p l o t of a d j u s t e d ' m a n g e y l e v e l w r s u s L

* 9 d i e s e l o i l t h i c k n e s s - i n t h e lower . hydrocarbon t h i c k n e s y ( l e s s t h a n 2 5 pm) . Highex t h i d k n w s e s up to 1979 microns sugges t ed an i n c r e a s e i n a d j u s t e d m a n

F

grey 1e;el. o r * r e f l e c t i v i t y , v i t h a n incre 'ase i n hydrocarbon t h i c k n e s s . The

FIGURE 26. EXAMPLE OF A PROFILED AND GRAPHED IMAGE - FIELD TRfA.8 BURRARD INLET, 18 M?iRCH 1987

' .

X-axis: Number of p i x e l s along se lected red p r o f i l e Y-axis : Ref lec t iv i ty or grey l e v e l where

0 = f u l l darkness and 256 = f u l l brightness

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anomalies i n t h e lower th ickness range could poss ib ly be explained by

examination of Table 11 which s b w e d t h a t adjus ted m a n grey l eve l s f o r

f l i g h t l i n e s 5, 8 and 9 f o r a l l f i l t e r types were comparatively high.

Re-examination of t h e d i g i t i z e d images fo r t h e s e f li*t lines indica ted t h a t

sampling u n c e r t a i n t i e s were l i k e l y t h e cause. That is, e i t h e r exact sampling

p o i n t s dur ing su r face sampling w e r e d i f f i c u l t t o i d e n t i f y o r t h e sampling

boat was i n an a r e a i n which th ickness v a r i a t i o n s were c lose together .

Owing t o t h e s e c o n s t r a i n t s , Table 1 1 f i g u r e s were r e -p lo t t ed

without f l i g h t l i n e s 5, 8 and 9 (Figure 28). The p l o t i n t h i s f i g u r e showed

a considerably improved c o r r e l a t i o n between adjus ted m a n grey l e v e l and

hydrocarbon th ickness through t h e range of hydrocarbon th ickness values

considered. In o the r words, t h e s e s e l e c t e d f i e l d data confirmed t h e e a r l i e r

f i n a l con t ro l l ed t e s t r e s u l t s yhich indica ted higher r e f l e c t i v i t y values with

higher s p i l l th ickness .

Again using t h e da ta i n Table 11, s t a t i s t i c a l analyses were

c a r r i e d out . The f i r s t a n a l y s i s was a combined f i l t e r mul t ip le r eg ress ion

f o r t h e d i e s e l o i l i n which t h e th ickness of t h e d i e s e l was set a s t h e

independent va r i ab le and each grey l e v e l s e t a s t h e dependent va r i ab le .

Result ing reg ress ion s lope , T-rat io and ~2 values f o r both l i n e a r and

logarithmic s e r i e s were derived and a r e presented i n Table 13. These values

ind ica ted t h a t t h e r e l a t i o n s h i p of adjus ted mean grey l e v e l t o hydrocarbon

th ickness was s t a t i s t i c a l l y b e t t e r represented i n logari thmic r a t h e r than

l i n e a r fashion, and t h a t excluding f l i g h t l i n e s 51 8 and 9 considerably

enhanced t h e r e s u l t s . Logarithmic regress ion s lopes for both data sets

suggested t h a t grey l e v e l increased with th ickness a s per t h e study

hypothesis. T-rat ios f o r t h e logari thmic reg ress ions ind ica ted a high degree

of s ign i f i cance and R~ values (without f l i g h t l i n e s 5, 8 and 9 ) had t h e

TAB

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b e s t o v e r a l l f i t . Standard e r r o r s and f - s t a t i s t i c s from t h e SHAZAM output

ind ica ted s ign i f i cance of t h e equations a s a whole ( d t h o u t Lines 5, 8 and 9 ).

Table 14 d i sp lays t h e r e s u l t s of l i n e a r and logari thmic mul t ip le

regress ions of adjus ted mean grey l e v e l s a w i n s t d i e s e l o i l t h i cknesses f o r

t h e four f i l t e r types f o r two d a t a s e t s - a l l f l i g h t l i n e s , and a l l f l i g h t s

l i n e s except 5, 8 and 9. I n each case t h e adjus ted mean grey l e v e l of a

p a r t i c u l a r f i l t e r was set a s t h e dependent va r i ab le and o i l th ickness a s t h e

independent va r i ab le . Again t h e outputs showed t h a t t h e logari thmic

regress ions were more meaningful than t h e l i n e a r . In terms of r eg ress ion

s lope , T-rat io and R2 values, inc reases i n hydrocarbon th ickness appeared t o

c o r r e l a t e with r e f l e c t a n c e values f o r all f i l t e r types. omit t ing f l i # t l i n e s

5, 8 and 9 improved t h e c o r r e l a t i o n outputs . F i l t e r s providing t h e most

meaningful s t a t i s t i c a l values f o r regress ion s lope , T-rat io and R2 were 18A

and 500nm. This was only i n p a r t i a l agceement with t h e f i n a l c o n t r o l l e d t e s t .

i n which t h e 18A d id no t produce s t rong s t a t i s t i c a l r e s u l t s , al though t h e

l i t e r a t u r e c l e a r l y supported t h e usefulness of 18A f i l t e r s in enhancing o i l

and water c o n t r a s t (Vizy, 1974). However, t h e reasons f o r t h i s were

recognized dur ing t h e c o n t r o l l e d test; c o r r e c t i v e camera and lens a d j u s t m n t s

were made p r i o r t o t h e f i e l d t r i a l which l e d t o t h e improved resu l t s . .

with r e s p e c t t o t h e 35 mm co lo r photography, s t a t i s t i c a l analyses

were undertaken on Table 12 data . Linear and logari thmic mul t ip le regress ions

were ca lcu la ted f o r band r a t i o s aga ins t th icknesses f o r t h e f l i g h t l i n e s s b w n

i n t h a t t a b l e . Result ing reg ress ion s lopes , T-rat ios and R~ values appear

i n Table 15. The band r a t i o with t h e bes t s t a t i s t i c a l r e s u l t s was t h e

red-blue which was i n agreement wi th Aukland and Trexler (United S t a t e s , 1970)

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were n m l t i p l y r e q e s s e d a g a i n s t dieseq o i l thicknesses both U n e a r l y a n d

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suggest& t h e importan& of the 1 8 A f i l - r r e l a t i v e to t h e o t h e r s . , -

I n summary, f l e l d trlal d a t a a n a l y s i s , b o t h , g r a p h i c a l l y and - -

s t a t r s t r c a l l y , s b u e d . t h a t v l d e o imagery w i t h s e l e c t e d fll t i o n could P". ~ d e n f l f y r e l a t r v e s p r l l t h r c k n e s s e s i n t h e o r d e r of two t o t h r e e o r d e r s of

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~ a ~ i c u d e based or; r e f ;ectar,de m a s u r e m n t s under s p e c l f i c e n v u o r u k n t d l -ha' -

c o n d ~ t r o n s ' . Because of w m e uncertainty o v e r s a m p l l n g accuxacy, th ln &ck

r e s a l t s f o r t h e ~ ? r e l d tria2 were c o n f u s r n g . However, d e l e t i o n of suspect " <

' fl1gY.t l i n e s l e d t o ana:ytrcal , r e s u l t s vfirch s t r o n g l y s u g g e s t e d t h a t 18k0hnd

/ ' 53fix-i: f l l t e r s were u s e k l r n l d e n t l f y i n g r e l a t i v e d i e s e l t h l c h e s s e s under

l r ~ ~ t e d e n v i r o n m e n t a l con& t r o n s . Ad& t l o n a l a n a l y s e s of band and f l l t e r

- r a t l o r f & h e r canflrme~ t h r s r e s u l t , The field t r l a l r e s u l t s were for

e x p r l c e c t a : p u r p o s e s or-iy; dcveiopnient of an o p e r a t r o n a l s y s t e n wouf d

r'ec-.;lre a d a t r o n a : f l e l d trials u n d e r different c o n & t l o n s . ,

' F l e l d tr;L data - r e p r e s e n t e d s e y e r a l photoqaph:c' bands a n d , i n

<-.at sezse , were m ~ i t l s p e c t f a l . mwever , no s p e c l a : c o r r h n a t r o n s of f r l t e r s -

sbwzrsg p t e n t r a l f o r t h i c 3 h e s s d r s z r m l n a t i o n such a s t h e 18h t o g e t h e r w l t h

t h e 5C1Z.x~ e r e t e s t e d . Ir. a e d i t i o r . , t n e s t a t i s t ' i c a l tests e w n m e d o n l y a

' ' 51;lglo s e l a t , m n s e i ~ &see: : a p a r t r c g l a r f i l t e r and o i l t h i c k n e s s . ,

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r e f l e c t a n c c d i f f e r e n c e s u s i n g a m u l t l q e c t r a l Video r-te s e n s i n g s y s t e m .

I - -- 4 7------- - - - -

It i s i m p r t a n t td n o t e t h a t e s t - imat ion , 'was r e l a t i v e ; no a t t m p t var made to P

ascribe s p e c i f i c th*knesses to specific g r e y leuels o n a p r e d i c t i v e basis.

i I n s t e a d , t h e imager; vas a n a l y z e d f o r g r e y l e v e l s i n r e h t b n t o known

, h y d r o c a r b n t h i c k n e s s e s . R e l a t i v e t h i c k n e s s d e t e r u n a t i o n a p p e a r e d tb h e

p c s d b l e u p to 1000 ui lc rons . Beyond t h a t t h e r e was PO CLscerriable i n c r e a s e

i n r e f l e c t a n c e v a l u e s . S t a t i s t i c a l a n a l y s e s of t h e two i n d e p e n d e n t tests

( c o n t r o l l e d a n d f r e l d ) s u g g e s t e d t h a t f o r b a t h the r e f l e c t a n c e ' to t h i c h e s s

relationship ap&ared to be l o g a r i t h m i c .

I n t h e find' c o n t r o l l e d t es t , 011 t y p e seemed t o be a f a c t o r m t h e

a b l l i t y t o r e s o l v e &f f e r e n c e s I n hydrocarbon t h i c k n e s s . D r e s e l slmwed g o d

r e f l e c t \ a n c e / t h ~ c k n e s s r e l a t i o n s h i p s ; t h l s was Gonf i rmed by t h e f l e l d tri a1 . F u r t h e r s t u a e s would be needed to b e t t e r u n d e r s t a n d t h e r e q u k e r r e n t s f o r I

h y d r o c a r b o n t y p e i d e n t l f r c a t k o n and f u l l m u l t i s p e - c t r a l e v a l u a t r o

example, f l l t e r s r e p r s S e R t 1 n g & f f e r e n t bands c o u l d be combmed 4

- t h e canera s e t u p o r 9 g r t a l l y on t h e coaeputer t o p r o v l d e

\ i n a g i n g . I n ad&$ r o n , m u l t i v a r i a t e a n - a l y s l s c o d d be rwi ori' t h e r d u l t i n g

\ 8

da:a t o i d e n t i f y o p t i n a l ' ca r i c lna t ion& f o r i d e n t i f y l n $ s p r l 1 4 L

With r e s p e c t to t h e f r l t e r s {sed d t h t h e v i d e o cameras , o q l y t h o s e

\ 1- t h e b l u e - g r e e n barid I5001-m were e f f e c t i v e b d e r b o t h h h k ' f i n a l

0

A C . - con4dof i e d test and f l ~ l d t r l ' a l c o n d i t i o n s . However, t h e 18h f l l t e r - t h e best r e s u l t s ~ n t h e f l e A & trla2 a f t e r p r o p e r espsure l e v e l s were 1 I

I

a c h i e v e d . The f m a l + c o n t r o l l e d t e b t in iagery of t h e 1 8 R was p o r because of

L

uzderexposlpe: F i l t e r r e s u l t s fraa t h e v l d e o imagery a c c o r d e d w i t h ~ u n d a y

a l . 1 l9i ' l ) and U n l t e d States ( l g i ' l b ) & l C h ; e p r t e d t h a t q o d t h r n s l i c k d - d e t e c t i o n w a s provided by u s i n g W and b l u e band p h t o g r a p k y , a n d t h ~ c k e r

_.

s l i c k d e t a c t i ~ n . the bsnd. It r lao c & u r i e & ~ ~ _ X ~ a n f u & & . ~ U b 8 2 ~ ) ~ - L -

. C. r .

i n terns of t h e W aad b l u e - g r e e n , b u t d i s a i y e e d i n the use of t h e red band A

for t h i c k e r s l i c k s . Hovever , a n a l y s e s of d i g i t i z e d p h o t o g r a p h i c imagery

s u g g e s t e d t h e i m p o r t a n c e of the red and b l & b i n d s i n i m a g i n g spill * .

t h r c k n e s s , as per Yuanfu e t a l . ( 1982 ) . This was c o n f i r m e d i n t h e c o n t r o l l ? d

test f o r t h i c k n e 2 s e s g r e a t e r t h a n 100 mrcrons for t h e l r a t 011s a n d . g a s o h n e

(f igures 18-20 1. ..

I n s u m r y , t h e concl%asrons drawn from- t h e e x p e r i m e n t s u n d e r t a k e n

. - I n t h i s s t u d y are a s follous :

'

i-

1. H y d r o c a r b n ' s p i l l t h r c k n e s s can be r e l a t l v e i y e s t r m e e d r n t h e

- o r d e r of .two t o three o r f k r s of magni tude by m a s ~ x r n g L i g h r . ..

I.

r e f l e c t a n c e ,&f- fe rences - u s m q m u l t i s p e c t r a i v l d e o r e m o t e

sensing.

- 2. R e f l e c t a n c e m g a s u r e n e n t s f o r c a n p a r l n g o i l t h i c k n e s s e s ai-e o n l y

1 '

ef f e c t i v e ;n s p l l l t h l c k r i e s s e s l e s s tkar . 1000 microns'. . . -

3 . Blue-green an3 u i t r a v i o l e t band v l d e o f l l t r a t r o r i rs best f o r

2 ' s b w i n g r e l a c l v e hyctrqcarbon t h i c k n e s s rn s l i c k s less , t h a n -a

4. Some of t h e e x p e r i m n t s Buggested t h a t t h e red band may be

u s e f u 1 uner Imi t e d , c o n & t i o n s s u c h ,as o n l y t r a n s l u c e n t

h y d r o c a r b d n s g r e a t e r t h a n 100 rmcrons . 1 --

3

5. T r a r L s l u 6 & n t hy&ocarbons s u c h as 10W3G 011, & e s e l 011 a n d d

g a s a i i n e a i i p b e t t e r t h r c k n e s s d e t e r m n a t i o n t h a c d o opaque '

- h y d r o c a r b o n s such a s c r u d e o r was te o i l s . r - E x p e r i n e r . t s by o t h e r s have f o c c s e d on t h e p t e n t l a l for r e m o t e

se?slr,g t e c h n r q u e s to l d e n t l f y absolute hydrocarbon s p r l f th lc imesses . T h i s

i study d e a l t w i t h the__ques t ion of whether d e t e r m i n a t i o n of r e l a t i v e t h i c k n e s s

- - -- - - - - -- - -- - -- - va$ possible and m n c l r i d e d - t h a t A t was. Thi s is i m p r t a q t wi th respect to

*

f o c u s i n g o i l s p i l l cleanup e f f o r t s r knowing t h a t t h i c k r e g i o n s of s p i l l s -4

c o n t a i n - more t h a n 90 percent of t o t a l o i l in less t h a n te+5qpercent of t h e '

' 0

spi l l a r e a ( H o l l i n g e r r 7974) . The experimenta1 v i d e o system developed f o r

t h e f i e l a t r i a l t h e r e f o r e c o u l d be of p r a c t i c a l u s e i n a s s i s t i n g c l e a n u p .#

e f f o r t s under similar environmental c o a t i o n s . (S However, a f u l l y A 8

operational s y s t e @ v o u l d r e q u i r e m r e t e s t i n g with r e s p e c t to s u n l i g h t - - -

s k y l i g h t r v e a t h e r and s e a s t a t e , turbidity, n e a r ' s h o r e l i n e v e g e t a t i o n - ,

Fu tu re t e s t i n g c o u l d a l s o i n c l u d e use of a l a r g e r a p e r a t u r e l e n s

c

v l t h an 1 8 A f i l t e r under c o n t r o l l e d c o n & t i o n s , and m r e extensi,ve s u r f a c e B

- sam2llng i n f i e l d t r i a l s , to provrde a l a ~ g e r d a t a s e t . Of c o u r s e , $uch A

t r l a l s a r e l b g ~ s t ~ c + l ~ canplex and may be very costly. They must be

d e s i F e i f o r very e f f s c i e n t d a t a c o l l e c t i o n . F l i g h t e l e v a t i o n s a t 5 0 0 f e e t

are recamended because t h e r e & l t l n g l a r g e r iu fagery p e m t s m r e F e c l s e tl

~ d e n t i f l c a t i o n of spi l l samplrng l o c a t i o n s . A l t i t u d e appeared t o have. no

beaz;ng on th8 a b i l i t y t o d e t ~ m e t h < c h e s s th rwgh- r -e l l e c t a n c e

dif f e r e n c c s . However , a l l o b s e r v a t i o n s were made a t r e l a t i v e l y low a l t i t u d e . ;

a tmcsphersc e f f e c t s c o u l d k e impor t an t a t g r e a t e r h e i & t s . /

I n s p i t e of some of the u n c e r t a i n t i e q : -. 4 a s s o c i a t e d w i t h t h e

m i t i s p e c t r a l v i d w . r&mte s e n s i n g system used i n t h e f l e l d t r r a l , data .

a n a l y s l s c l e a r l y d e m n s t r a t e d t h a t t h e system was c a p a b l e of e s t i m a t i n g

re la t ive hydrocarbon spill t h r c h e s s e s to two or t h e e o r d e r s of m a ~ i t u d e o n

t h e basis of l i g h t r e f l e c t a n c e d i f f e r e n c e s under c e r t a i n environmental .

imqgery and subsequent s t a t i s t i c a l analyses . F'urther computer ?. - t rea tmqnts 6f 6.c

-- -- -

t h e da ta vouq l i k e l y prtrduce improved resol% ion t h o u g h s u p r v i s e d

c l a s s i f i c a t i o n procedures and r e l a t e d m u l t i v a r i a t e techniques ; r e s u l k i n g L=

c l a s s i f i e d images can be pseudo-colored and d isplayed with sp l i t imaging- for \ .

i l i u s t r a t i r q t h e i d e n t i f i e d d i f f e r e n c e s i n hydrocarbon t h i c k n e s s (F igure 29 ) . Appl ica t ion of such techniques--ta t h e hydrocarbon . s p i l l t h i cknesb method '

developed i n t h i s stfudy should prove of c o n s i d e r a h e b e n e f i t i n improving o i l .I

s p i l l c leanup opera t ions .

FIGURE 29. EXAMPLE OF A PSEUDO-COLORED S P L I T IMAGE - FIELD TRIAL, BURRARD I N U T , 18 MARCH 1987

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Purposesa. ' Photographic Appl icat ions i n Science, Technology andc Medicine 6 ( 4 ) : 7-8.

Worsfold, -chard D . { John A. N l a n and Bruce E. 'Fret-. 1975. ' The Use of T e l e v i s i o n for ~ e & e Sens inga . Remote Sensing 'of Envrr6nment 4 : -

?.'

5-35.

- Yuanfu, Shun, Zheng pla2an and Teng Xuyan. 1982. Woni tor ing Marine

P o l l u t i o n by Airborne Remote Sensing Techniques" . prate edings of the 16th I n t e r n a t l o ~ a l S F p s r m o n Remote S e n s l n g of Envlronnent. E , n ~ l r ~ n m e n t a > kesearcii I n s t r t u t e of Hlchrgan , U n l v e r s l t y of Mlchlgan ,

~ ' l l n n Arbpr, mch., I: 234-248. * + ~ v l c k ; H. B. , R. A. X e v i l l e an3 R.A. O ' K e i l . 7981. *A E e c m m n d e d Sensor f o r

t h e Detection and Trackrng of-011 SpQls" . Proceehngs of the S y ~ p s i u n ? on Appf l c a t i o n of Iterate Sens lng Data on t h e C o n t r n e n t a l Shelf, Voss, Korxay , Hay 19-23 , 1981. Europear. Space Agency, P a r r s , Prance : 77-68.

To t h e e y e , t h e a p p e a r a n c e of a n o i l s l i c k i s e x t r e m e l y variable",epennding o n i l l u m i n a t i o n c o n d i t i o n s , o i l t y p e and t h i c k n e s s , r e l a t i v e C l o c a t i o n s of t h e s l i c k and t h e o b s e r v e r , e n v i r o m n t a l , c o n d i t i o n s p r e v a i l i n g a t t h e t i m e , a n d the physicalaand m e n t a l s t a t e o f t h e o b s e r v e r . Even under r d e a l c o n & t r o n s , She w a t e r t o om1 c d n t r a s t is s u b t l e r n t h e v i s i b l e p o r t i o n o f - t h e s p e c t r u m , s t r a l n l n g a n y o n e ' s v l s u a l a c u l t y .

It is owlng t o t h e s e l l u t a t i o n s of t h e human e y e w i t h r n t h e

v r s b l e s p e c t r u m as w e l l as r t s t o t a l i n a b l k t y below and above t h e v i s i b l e ,

'L-' t h a t a v a r l e t y o f o i l s p i l l s e n s o r s y s t e m s have been d e v e l o p e d . They a r e

kseussed z n t h i s a p p e n d l x r e l a t t v e t o t h e p o r t i o n s of t h e s p e c t r u m d t h m

wfilch they o p e r r a t e . Hore d e t a i l e d s w r i e s of remote s e n s i n g equipment a r e

\ -

p r mi-ded b y Canada ( l984k) and, L ~ l l e s a n r l a n d K i e f e r ( 1974 ) . %

F

V i s i b l e , Near Visible and Infrared Sensors t

Photographic Sensors. T h e r e i s a wide r a n g e o f p h o t o g r a p h i c cameras

a v a i l a b l e f o r o i l s p i l l r e m o t e s e n s i n g from 35 mm r a f l e x t o large forrnat w i t h

c o r r e s p o n d i n g l o w t o h i g h c o s t - Magazine c a p a c i t y , c y c l e r a c e , l e n s o p t i c s ,

r e s o l u t i o n a n d s h u t t e r speed c a n v a r y c o n s i d e r a b l y . I n a d d i t i o n , t h e r e a r e

many c o l o r and b l a c k a n d w h i t e f l l m t y p e s which d i f f e r i n speed, r e s o l u t i o n

and wavelength s e ~ s l t i v i t y . T n e r e ara also numerous f i l t e r s a v a i l a b l e which

can f u r t h e r i s o l a t e p o r t i o n s o f t h e e l e c t r o m a g . n e t i c s p e c t r u m .

Photographic cameras o f f e r high r e s o l u t i o n and can provide

s tereoscopic coverage and mul t i spec t ra l imaging. General a v a i l a b i l i t y of

many lenses , f i l m s and f i l t e r types is a l s o an advantage. ' However,

photographic systems are n o t real- t ime and some systems are very c o s t l y .

Radiometers. A radiometer is a pass ive non-imaging device which measures

t h e absolute value of t h e energy emitted and/or r e f l e c t e d from an o b j e c t .

Typical a i rborne radiometers provide p o i n t measurements along an a i r c r a f t ' s

f l i g h t path. Incaning rad ia t ion is transduced i n t o an e l e c t r i c a l c u r r e n t

which i s then recorded. Radiometer s e n s i t i v i t y can range from t h e

u l t r a v i o l e t to t h e f a r i n f r a r e d depending on t h e type of sensing e l e ~ n t

incorporated i n t h e instrument. (Radiometers which d e t e c t between 0 .3 and

1 m a r e known a s photometers). In addi t ion , energy i n s p e c i f i c s p e c t r a l

bands can be detec ted through use of f i l t e r s o r a d i f f r a c t i o n gra t ing .

Line ScaMers. While radiometers generate a one-dimensional p r o f i l e along

a f l i g h t l i n e , scanners c r e a t e a two-dimensional r e c o r d f o r a s w t h beneath

t h e a i r c r a f t . In e f f e c t , a l i n e scanner i s a radiometer which sweeps f r a n

s i d e t o s i d e a s t h e a i r c r a f t moves above t h e ground c r e a t i n g a series of

cross-prof i les . Scanner system components include a c o l l e c t i o n system

c o n s i s t i n g of a mirror which o s c i l l a t e s on a s h a f t o r i e n t e d p a r a l l e l to t h e

f l i g h t l i n e and a s o l i d s t a t e de tec to r or de tec tor a r ray where received

energy i s converted i n t o e l e c t r i c a l impulses and recorded on an

electromagnetic tape. Scanners sense t h e photographic and thermal por t ions

of t h e electromagnetic spectrum, although some a r e a l s o capable of sens ing

t h e microwave band. In t h e cake of mul t i spec t ra l scanners, incoming energy

-- - - - - -- - -- -- - . . -

I

is split in- smaller ban- by a p r i s m o r d i f f r a c t i o n mat-+ It h - - -

p o s s i b l e t o develop a ccmpsite, color picture by d e s i g n s i n g h d i f f e r e n t 2 I

mncrgy band (i . a * , c o l o r ) to e a c h &me1 and s u p e ~ j r n p & n g &annex images . . I

r o t h e r typemo'f s c a n n e i is the p u s h b r o a n a s c a n n e r i n which, r a t h e r " a

t h a n a n b s c i l & t i n g mirror, t e r r a i n r a d i a n c e i s r e c o r d e d through r e s a t e d

s a m p l i n g by a solid s t a t e s e n s o r a r r a y . M r c r a f t f o r w a r d p p t f o n a g a i n - 3

' p r o v i d e s the s c a n d i r e c t i o n . P u s h b r o p s c a n n e r s & g e r a l l y h a v e a h i g b r

r e s o l u t i p n t h a n a t a n d a r d m u l t i s p e c t r a l s c a n n e r s k c a h s e of t h e p r e c i s e B

g e a n e t r y of t h e i r s e n s o r a r r a y , g r e a t e r s i g n a l power f r o m t h e l a r g e area of

t h e i r f o c a l p l a n e and minimum m e c h a n i c a l d i s t u r b a n c e s l x c a u s e t h e y l a c k a

mwing k r r o r ' .

1

V i h Syst410. Vldeo o r ' t e l e v l s l o n ~ y s t e m s c o n s l s t Of a n o p t ~ c s package

*.ich c o l l e c t s lncoinlng r a h a t l o n a n d f o c u s e s it o n a n =age tube or e o h d

s t a t e d e t e c t o r . S o l i d s t a t e d e t e c t o r s u t i l i z e p h o t o d e t e c t o r a r r a y s and

s i l i c o n c h i p s . Different i n t e q a t e d circuit t e c h n o l o g i e s a r e available

i n c l u d i n g t h e c h a r g e c o u p l e d e v i c e (CCDf , t h e c h a r g e i n j e c t i o n d e v i c e (CID)

a n d metal o n s l l i c o n (30s) [Heisne-, 1986). Vldeo o u t p u t can be a c h i e v e d by ,

a c a t h o d e ray tube e h o v i n g a real-time i u a g e , r e c o r d e d o n a v i d e o t a p e or t F b

k. digitized i n a freeze-fraw im*. B m h c o l @ ~ $ a n d b l a c k a n d white systems

-A

a r e a-;al lable; higher r e s o l u t i o n is a t t a i n a b l e a c k and v h i t e , ~t i s w

P

m p r t a n t that t h e mxitor and r e c o r d e r are caupat with t h e camra owing

t'o t h e "ueakest l i n k " ~ 1 e . P i s m,Ie s t a t e s t h a t the r e s o l . u t i o n , SfK r a t i o ,

and C;sml",ion of t h e entire s y s t e n v i l l n e v e r exceed t&k= of t h e e a k e s t -% +=

c m F c e n t , & e t h e r c a n e r a , recorder o r w n i t o r ( W h i t e , 1983).

Resolution and s e n s i t i v i t y of video systems can vary as a funct ion

of e l e c t r o n beam diameter ac ross t h e cathode ray tube ecreen, imperfect

e lec t ro-opt ics and detection-induced noise , b u t they have t h e advantage of

opera t ing i n real-time a t r e l a t i v e l y l o w c o s t . Spec t ra l s e n s i t i v i t y can

range from u l t r a v i o l e t t o thermal b u t most cameras are l imi ted to t h e

photographic spectrum. Se lec t ive f i l t r a t i o n is r e a d i l y achievable using a

v a r i e t y of o p t i c a l f i l t e r s .

Video cameras commonly c r e a t e an image which is geometrical ly

d i s t o r t e d by 1 - 2 percent depending on camera apera ture and t iming

re la t ionsh ips . One key component of video cameras i s t h e l ens ; f o c a l length

and apera ture diameter determine f i e l d of view and a m u n t of ava i l ab le l i g h t ,

two important f a c t o r s f o r adequate remote sens ing of o i l s p i l l s .

One important v a r i a b l e a m n g s t video cameras is t h e a b i l i t y to

produce images under low l i g h t condit ions a s i s t h e case with low l i g h t l e v e l

t e l e v i s i o n (LLLTV) . I n t h e s e systems image-forming e lec t rons are

e l e c t r o s t a t i c a l l y acce le ra ted before being focused on a f luorescen t

phosphorus screen. Usually capable of opera t ing i n t h e same electromamet i c

range a s conventional TV's, they have t h e added advantage of being usable

under s t a r l i g h t , moonlight, dawn o r dusk oondit ions, bu t a r e expensive

r e l a t i v e t o s tandard videos.

Forward-Looking Infrared ( IrLIR) Devices. FLIRs a r e b a s i c a l l y l i n e

scanners which opera te in t h e thermal i n f r a r e d por t ion of t h e spectrum. The

main components of a FLIR a r e a scanner, a de tec to r a r ray and e l e c t r o n i c

components including output devices. One canmn scanning technique i s

'4 - con t iguqus ecanning which is a combinat ion of h igh speed h o r i z o n t a l @canning

- - - - - - - - - - - -

w i t h o s c i l l a t i n g v e r t i c a l @cans. De tec to r a r r a y s r e q u i r k mupsrcool ing to

77. I. ; usually th rough t h e use of l i q u i d n i t r o g e n . The met CQILPY)~ d i s p l a y

unkt is that of a s t a n d a r d t e l e v i s i o n m n i t o r with t h e o p t i o n of videotape o r

8 i n g l e ' f r a . u ~ r e c o r d e r s . While capab le of r ecogn iz ing s m a l l t a r g e t s o v e r

ranges of s e v e r a l m i l e s , FLI% are cor respondingley c o n s t r a i n e d by a l i m i t e d

fyeld of view. I

d .

? l m r o u e ~ . Fluorescence r a d i a t i o n i s c r e a t e d when a molecule abso rbs

a photon a n d subsequently e t s another photon v i t h less e n e r g y bat Tea ter-

wavelength. M o s t f l u o r o s e n s o r s o p e r a t e i n t h e u l t r a v i o l e t p o r t i o n of t h e '

spec t rum through d e t e c t i o n of n a t q r a l f l m r e s c e n c e o r art i f i c d l l y s t i m u l a t d d f l u o r e s c e n c e , dependrng on t h e senso r system. With f luorescence- induce d systems, p u l s e d or con t inuous wave l a s e r s ( l i g h t a m p l i f i c a t i o n by s t i m u l a t e d

e c i t t e d r a d i a t i o n ) c r e a t e t h e f l u o r e s c e n c e . F luo rescence i s u s u a l l y recorded

on a magnet ic t a p e via a t e l e s c o p i c r e c e i v e r .

Ac t ive Gated T e l e v i s i o n (-1- &nsorr. One of t h e g e n e r a t i o n of new /

1

combined seneor systems, t h e a c t i v e g a t e d t e l e v i s i o n combines a low l i g h t

l e v e l t e l e v i s i o n v i t h a l a s e r . I n i t s p a s s i v e mode , t h e system f u n c t i o n s as

k an LLLTV capable -of n i g h t s e n s i t i v i t y ; i n t h e a c t i v e m&, a p u l s e l a s e r is

7- t r a n s u t t e d t o t h e t a r g e t . The ca-tensifier i n t h e I+LUV is t h e n g a t e w on 'to act a s a r e c e i v e r ' . %is approach p rov ides h igh t a r w t r e a d a b i l i t y

under l i m i t e d l i g h f c o n d ~ t i o n s w i t h a reduced , f i e l d of view. t

v

F fjnr --me Prauhaufer - d d c &*as iR ~~ - - v

spectrum are caused by e a l e c t e d absorption of l i g h t by in t h e upper

atmosphere w i t h the s t r o n g e s t l i n e s o c c u r r i n g i n t h e u l t r a v i o l e t and

i n f r a r e d bands of t h e spec t rum d u r i n g daylight hours. The Fraunhaufer Line

d i s 2 r i m i n a t o r records luminescence through canpa r i son of sky and t a r g e t ,

r ad i ance 'on a s e l e c t e d . -

t h e system c o n s i s t s of

hraunhaufer l i n e in t h e soh$

one t e l e s c o p e look ing skyward

spec t rum- 7Uechanica l ly

and ' a n o t h e r towazds t h e

q d i u t d , a chopper wheel a l t e r n a t i n g between them, f i l t e r s , a photo--

m u l t i p l i e r i a l i g h t c o l l e c t o r and e l e ' c t r o n i c c m p o n e n t s i n c l u d i n g a - -

mini-canputer which c a l c u l a t e s luminescence and r e f l e c t a n c e v a l u e s .

Passive Wcrwaye e s t e r s . P a s s i v e mrcrowave sys tems o p e r a t e ~n a f a s h r o n

s i m i l a r t o t he rma l radiometers and scanne r s and $her e f o r e are -capable of

* e i t h e r f l i g h t p a t h p r o f l l e s or wlder s can l i n e s along t h e l e n g t h of a f l i g h t

path. The main &if f e r e n c e between p a s s l v e mlcrovave a e n m r s and radrorne t e r s 3

i s t h a t t h e former u t i l i z e a n t e n n a s r a t h e r ' t han photon d e t e c t i o n e l emen t s .

Energy c o l l e c t e d v i a a n an tenna i s ampl r f i ed and canpa red tq an r n t e r n a l 0

c a l i b r a t i o n t empera tu re r e f e r e n c e s i g n a l . T h e d i f f e r e n c e between t h e two is '9

e l e c t r o n i c a l l y d e t e c t e d and r eco rded i n such o u t p u t r e c o r d e r s a s a a 7

synchronized f l l m r e c o r d e r . -

Pass ive microwaveJsensors r eco rd energy i n the microwave portion of B

the e l e c t r a n a q n e t i c spec t rum from a' v a r r e t y of e m i s s u n eourccs . These may

Inc lude n o t on ly t a r g e t t empera tu re and l n s t a n t radiation, b u t a l s o e m i t t e d ,

- - - - - - - -

r e f l e c t e d or transmitted e n e r g i e s frcan o t h e r sources e u c h as t h e s k y or

- -

atmosphere. W i n g to t h e v a r i e t y of murces, p a e s i v e mfcroi iave-energy y i e l d s

a n o i s y r iwa l which can h d i f f &it to i n t e r p r e t . This i s p a r t i c u l a r l y

cr i t ical w i t h r e s p e c t t o o i l s p i l l d e t e c t i o n f o r which microwave s y s t e m s

a t t e m p t to d i s c f i m i n a t e between open w a t e r waves a n d s u r f a c e w a t e r calmed' by

o i l . il I

. ,

S i d e - h k i n g Nrbotne Radar ( 6 1 'Systems. ' Radar s t a n d s f o r r a d i o

d e t e c t i o n a n d r a n g i n g . It i s b a s i c a l l y a n a c t i v e p i a o w a v e sys tem which u s e s A

r a d l o waves t o d e t e c t o b j e c t 6 a n d d e t e r m i n e t h e i r r a n g e t h r o u g h t r a n s m i s s i o n -

of a h o r t b u r s t s o f microwave e n e r g y a n d r e c o r d i n g t h e i r r e t u r n o r b a c k s c a t t e r 8

r e f l e c t i o n s . M*'

One p a r t i c u l a r ' t y p e of r a d a r , s i d e - l o o k i n g a i r b o r n e r a d a r o r SLAR,

u s e s a n a n t e n n a u n f k r a n p a i r c r a f t t o p r o p a g a t e micr&ave e n e r g y to a target . . f

A s y n c p r o n i z e r s w i t c h v a r i e s t h e a n t e n n a between t r a n s m i t t i n g and r e c e i v i n g

mode. Received. e n e r g y ie p r o c e s s e d t o p roduce a n a m p l t u & / t i m e v r & o sl w a l

I which i s r e c o r d e d on a f i l m r e c o r d e r . Each image l i n e on t h e f i l m i s a t o t a l . r e p r e s e n t a t j o n of t h e s i g n a l s t r e n g t h *om a s i n g l e r a d a r p u l s e . A s t r i p

h

i r r a g e . 1 ~ c r e a t e d i n t h e f i l m r e c o r d e r t h r o u g h a s e r i e s of s u c h p u l s e s .

Synthetic llpe s SLAR s y s t e m s are known' i

as r e a l a p e r a t u r e s e n s o r s h e c a u s e t h e y depend on t h e a c t u a l p h y s i c a l l e n g t h .

of t h e i r a n t e n n a , s y n t h e t i c a p e r a t u r e r a d a r or S k R s y s t e m s depend o n modif iedp

data r e c o r d i n g a n d p r o c e s s i n g t e c h k i q u e s to s y n t h e s i z e t h e ef f e c r of a l o n g

a n t e n n a . SAR's r e c o r d b o t h t h e a m p l i t u d e and f r e q u e n c y o f t a r g e t r e t u r n s as

compared to only amplitude for SLARs. Frequency information from a target i s

compared t o a control frequency reference signal generated internal ly with

the resu l t ing pattern recorded photogra@ically o r on mawetic tape. These

signal f i lms must be interpreted i n turn by a laser opt ical processor. SAR

is very ccmplex and requires dependable performance from i t s many system

components.

/ % -~ APPENDIX 2 : PREFZR-a FIW. XSG FILTER TYPES FOF. F~EMoTE

S E S S I H G Of G I L SPILLS a

PREFERRED F I U l AND FILTER TYPES FOR REMOTE SENSING OF OIL SPILLS

FILM

2402

2403

2424

SO-397

DESCRIPTION

Kodak Plus-X Aerographic (Black and White) Panchromatic wi th extended r e d s e n s i t i v i t y

Kodak T r i - X Aerographic (Black and White) Panchromatic wi th extended r ed s e n s i t i v i t y

Kodak I n f r a r e d Aerographic (Black and White) I n f r a r e d , v i s i b l e and u l t r a v i o l e t (weak between 500-600 nm)

Kodak Ektagraphic EF Aerographic (Color r e v e r s a l ) S e n s i t i v e m u l t i l a y e r balanced

FILTER I WAVELENGTH (urn

380 - 1100 310 - 400 and 700 - 800 300 - 520 and 600 - 1100 300 - 500 and 680 - 1100 520 - 590 and 740 - 1100

hFP.E?;LiX 3. TF&.?YS.YZT?k%CE F X i G E S OF FILTERS USEL Ih CGKIICLLED ,- TESTS k ? L FiELC T F . X

TRANSMITTANCE RANGES OF FILTERS USED IN CONTW3LLED TESTS AND FIELD TRlAL -

FILTER 1 T ~ S X I T T A N C E RAfiGE (b!) I -

310 - 400 dhd 70'0 - 8 0 0 430 - 480 and 750 - 1 1 O G 830 - 1 1 0 0 - C

7 2 0 - 1 1 0 6 400 - 520 6?0 - 690 375 - 4 2 5 425 - 475 475 - 525 325 - 575 575 - 6 2 5 625 - 675

A P P E K D I X 4 . D O C U K E W A T I O N FROH OCEAN DUMPING APPRDVAL PROCESS

APPLICATIOK

.

fir

L r

FROM DE

Gos.emment. Gowemement - of Canada $u Canada : MEMORANDUM

iron mental P royec t i on %.,nservat i o n and ;Protect ion

/ 4

B. A. Heskjn 7 Regional D i r e c t o r , P a c i f i c & ~ u h n " . -

A t t e n t i o n : H. Ne lsoq - Ocean Dumping _1

Bob Sherrrood 9 . 1 0

Senior Phys ica l S c i e n t i s t R e f e r r a l and Impact Anal-ysis

- P a c i f i c & ' futon Region ' t

SUBJECT' wn O i l S p i l l Remote ~ e n s i n i Experiment

NOTE DE SERVICE *

DUR ALE - N / REFERENCE I

At tached i s an appl i c a t i o n f o r approval under t h e &ean Dumping Cont ro l Program f o r an o i l s p i l l remote sensing experiment on March 18, 1987 i n

- Su r ra rd I n l e t . The i n t e n t o f t h e experiment i s t o t e s t an ar ray* o f v ideo &

h e r a s and f i l ' t e r s on board a Cessna 185 f o r t h i c k n e s s d e t e c t i o n o f a d i e s e l s p i l l o f knbwn q u a n t i t y . I n a d d i t i o n , t h e exper iment w i l l p rov ide

' a n o p p o r t u n i t y f o r Eu r ra rd Clean t o improve i t s s p i l l response c a p a b i l i

A l l p recaut ions w i l l be taken t o ensure t h a t no escape o f p roduct , n o r any , form o f envi ronmental degradat ion occurs. EP personnel w i l l be present d u r i n g a l l re leases o f t h e d i e s e l f u e l and can c a l l a h a l t t o t he work a t any t ime. Only sea co i t i o n s i n which t h e fuel can be r e a l i s t i c a l l y expected t o be recover % ,w i l l be worked. O i l containment b a r r i e r s , a skimmer and sorbents w i 11 be u t il i z e d i n c leanup fo1 1 owing t h e - a i , r c r a f t o v e r f l i g h t s . A smal l runabout ' w i t h outboard w i l l be used t o keep b i r d s away f rgm t h e area p r i o r t o at%d d u r i n g cleanup.

I recognize t h e ex t remely t i g h t timefr-ame i n which approval i s be.ing , sought and thank you f o r your e f f o r t s i n t h i s regard.

Should a d d i t i o n a l i n f o r m a t i o n be r e q u i r e d , p lease c o n t a c t me a t 666-5925.

Bob Sherwod

&. ,rCATlON FOR A PERMIT TO DUMP AND/OR TO LOAD SUBSTANCES FOR W I N G AT SEA DEMANDE WAUTORISATION D'IMMERSION w M CHARGEMENT DE SUBSTANCES i IMMERGER

PART A BASIC INFORMATION PARTIE A R E N S E I ~ N E M E N T S ~ ~ N ~ R A U X

1 NAME OF APPLICANT I Nom Ou n U l r a n t T E L . W / W Q t & .

DIGSCL OTHER t(#Ify) & t n ( o r k l n r )

TOTAL WTV TO BE OUMPED S SWRCE OF SULZTANCE NAME OF FIRM i l l WPl*.bl*J Qluntltd t o U e 1 l m n u r r r

I ADDRESS I 2 WPE OF BUSINESS I Ty# a'.ntm9r*.

C / O E N J ~ ~ ? , w G W + &&.w K R P I C C L I J ~ be- P I W ~ ~ L k Y / s dcc;? \ /Ad~o. '~b& ec v 3 t r 4 2

I I I PART B CARRIER INFORMATION PARTIE I RENSEIGNEMENTS SJR LE TRANWORTEUR

R-rY*t A4b =-fw

4 & ~ t r im, L % P E . F ~ ~ ~ (TO f . 7 A -ore ~ S G S'ISTWAJ 5 . q ~ ~ PJ sf? ,; .& i n f'- hu77 6 OESCRIBE ACTIVITY FROM WHICH SUESTANCE ORIOINATLI

Dkr l re I'aclhltd m s u o w b h MI* fomutlon 08 (L UDrl.IK. 7 WHY IS IT NECESSARY TO DUMP SUBSTANCE AT SEA!

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8 NAME OF CARRIER COMPANV Wom O. la cwngmnh d. t r a w o r t

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TITLEIS) I TlhmlS)

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PWS~LILL Sr * Y l 6 I

3 NAMEIS) OF INDIVIDUAUS) RtLPDNSIBLE FOR LOADING A N 0 DUMPING ON BEHALF OF APPLICANT N a m 18 m n o n m chaw& au Chammnt at W I ' l e m ou nom au r w u d r ~ n t

ADDRESS / Mntn sw, y e 1034 TEL. No I No 08 161.

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4% & J ~ G . C Z s r r ) (3) N O V ~

IAME OF SHIP NAME OF MASTER PORT OF REGISTRY iom au b a t ~ u om au u ~ l t a l w PO* d'attache

B l c ~ t ? ! ~ &*.JuL%( ~ Q R P & ~ C W ~ J ~ L N.4 FFlC lAL NUMBER OVERALL LENGTH EXTREME BREADTH DEADWEIGHT TONNAGE iumdro o f f k m L o y u u r kors-twt b r w r MI fort Charyment an l w r a

TEL. NOIS) I NOtrl W t 1

-

I I I EGISTRATION MARKS MAX. GROSS WEIGHT AS AUTHORIZED NAME OF PILOT I N COMMAND I a r g u ~ ~ ' I ~ ~ ~ ~ I c Y I ~ ~ I o ~ BV CE RTlFlCATE OF AIRWORTHINESS Nom au pllota commandant 60 bor

Polds brut m u . autorlrl par Ie cartlfkat m navlprblllt6

ESCRIBE CARRIER OR OTHER STRUCTURE Ikr l re la tranwortaur w l ' w v r ~ .

I EXTREME EREADTH DEADWEIGHT TONNAGE u r w r au fort m a r r m a n t an 8wra

I

NAME OF MASTER. PILOT. OR OTHER INDIVIDUAL I N COMMANC Nom au capltalm, pilot* ou autre cornmanant dm bard

NAME OR NUMBER (If any) Nom w n u d r o ir'U y 4 k u )

OVERALL LLNOTH Longueur nawtout

- -.. ..r r n - r u m m u rr WR L L A l O W

1s PORT OF DEPARTURE 1. PROPOSED LOADING DATE(S) ISMETUOD OF LOADING AND STOWAGE PROCOSED An u *pu t wrmoa m m k ae ~ ~ ~ r p w n t mi d * n b n w , 1

I I 17 WHERE 16 DOES NOT U R V STATE REQUIRED DURATION OF PERMIT TOTAL Q U A N T I W CREQUENCV M D RATE OF DUMPING

Y 16 IU s'ePDII0w DI. 1Mlauw DY~C n ~ u l n w l'autorkauon Owntnd cotan FrWuna #I cwru .r om6railons

METHOD OF DISPOSAL I M E m O D E D~LIMINATION

FORM OF PACKAGING OR CONTAINERIZATION I ~ D ) WLLO OF CARRIER DURING IIC) DISCUARGE RATE

I I I PAW D DWP UTE INCORYATIOII PARTIE D RENSEIQYEMENTS W R LE LIEU D l Y Y E R 0 O N 20 GEOGRAPHICAL COORDINATES OF DUMPSITE 1 DEPTH OF SEA A T PROPOSE0 DUMPSITE

C o o m o n n k e6wramlaur au 11.11 a l m m n l o n ~ o l o n a u r r la m r au I h u almnwrsIon 2 f wi.)gG C,

22 REASON FOR SELECTION OF PROPOSED SITE I Ramnr du m o l x du I b u m o w &

I 1

NOTE: In carnlnp out any wcerury tests lne a N l y a Vloula follow aocumntea ProcWures ma De DreDarM t o r u r l b a- procadwas In 0.~11.

NOTE: Pour .ffutun la eruls ndcaukw. I 'nWSte Oolt wbn la IndmoMs I m l a d a et ma DIM I la dkrwe m -11.

(a) OEPTU OF DISCUARGE U d o w u a s M h n otdfli%de .bow m r u f l u e 1.1 DESCRIBE CARRIER TRACK WHILE OUMPING W wdk.bk) DIcrln Ie w e t du transmrtaur au cows r ~ ' m m m r u o n I

23 PHYSICAL PROPERTIES IPROPRI~TCS PHYSIOUES

I

I I 1 24 CHEMICAL AND BIOCHEMICAL PROPERTIES I PROPRlETES CHlMlOUES ET BlOCHlMlOUES

la) ARE SUBSTANCES NAMED I N SCHEDULES I A N 0 II OF W E ACT PRESENT? I F VES. IN WHAT CONCENTRATIONS Y a441 d n w w t a n c n mmtlonndrs w x annexes I e t I1 6# la Lo1 1% OUI, aans awllss concentrations

I I I I

ODOUR Oaeur

L'-Lc

VISCOSITV v l ~ s l t d

2 - L c c C S

1.1 LlOUlDS

L i i u i d n

COLOUR Coumur

IN WATER

COLOUR bulwf LI C lr x-~,

OOOUR Odeur

COLOUR Couleur lClSOLIDS

I N WATER

SPECIFIC GRAVITV -Id1 1dClfI0W

0 . 6 1 - 0 .4 8

CHEMICAL OXYGEN DEMAND Denume c h l m h u a'oxy+e

@ )

CHEMICAL STAB1 LITY

8ubilid rhimiqw

PARTICLE SIZE DISTRIBUTION AND SETTLING RATE I N SEAWATER Grosuur d.1 par tku ln et t w a ae Jalmentrt lon aanr I'w 0. nwr

OXIDATION REDUCTION POTENTIAL Pobn tb l d'oxydorlQuctlon

VAPOUR PRESSURE Tanslon 0. vemur

4.5

OOOUR Oaeur

hi A REACTlVlTV WlTU SEAWATEP . Rbctlvltd a v u 12.11 u m a

MISCIBILIW W l W SEAWATER M l u I ~ l I I t d avec I'UU O. la m r

LC% 7- . 5 , f f~

V . w r & C - C - m Q W ~ U J

CHANGE ON EXPOSURE TO ATMOSPHERE AND SUNLIGUT Cnang8rmm au contact ae l'atmospn&re et r la lumldm a u nolelt

I

TAINTING,COLWR CWANOE AND O W E R UNOESIRABLL CONTAMINANT LCFECTS ON SEAFOOD Colorwon, C h m F U I t c coutwr et .utm .(MI 0. c m w n m t l o n W I Y r O l a w L (NIU C mr

P?%le.Llyhf O F 4 4 ( . d t ' ~ & O F S k S S l b e L~~~

INHALATION / InhYatbn

W o n thm a w l l u n t 1s a c n ~ o n t l o n . m l r r tho t1Ih or c ~ m c l t y and IoImDhono numwr of the w r w n slsnlnm MIS awlkmtlon. SI Im mudrant a t une roclh6, aonnu n t l t n ou e ionctlon ot Ie n u d r o do tlldpnone du r lwaulro aa la onmame.

%"o.n- P 1 r Y s , L + c j ; , L 4 1 ~ : ............................... 7. .........-...... k . L ....................................................... DATE SIGNATURE OF APPLICANT / Slgnaturo du r.qu(rant TITLE / Tltro

.......... ...................................... I L L . NO. I NO H 141.

APPROVALS

- -- - -I#- * -- I

Rprectm I'mronnement

c6~s-t- and Protectinn h

3rd F loor , Kap l l ano 100, Park Royal Yest Vancouver, b .~ . V7T U2 ,

March 17, 1987

Mr. Bob Shemood Environment Canada Conservatiop and P r o t e c t i o n b

3 r d F loor , Kapi lano 100 '

Park Royal, Yest Vancouver, B.C. -. V 7 T 1A2

Dear Mr. Sherwood:

W Re: Ocean Dumping c o n t r o l Program, F i l e No. 4543-2-02173 Simon Fraser Un ive rs i t y , Burnaby, B.C. -

Your proposal has been reviewed pursudnt t o - subsect ion 33.1(1) o f the F i s h e r i e s Act. Attached are the cond i t i ons cover ing your a p p l i c a t i o n t o conduc t lobd ing acd ocean dumpfng. Your a t t e n t i o n i s d i r e c t e d i n p a r t i c u l a r t o C o n d t i o n s 3, 5, 8 and 9.

a

Y l t h re ference t o Cond i t ion 3, the prescr ibed a c t i v i t y w i l l be r e s t r i c t e d to t h e date requested by the Proponent, i e : March 18, 1.987. Any a c t i v i t i e s ou t s i de o f t h i s date w i l l be sub jec t .to f u r t he r review. U i t h reference to cond i t i ons 9.2, 9.3,- and 9.4, you are requested t o ensure t h a t extreme cau t i on and d i l l i g e n t e i s exerc ised t o ensure no adverse impact on the environment.

Please be advised t h a t i t i s the r e s p o n s i b i l i t y o f the Proponent to ensure t h a t a l l con t rac to rs invo lved i n the loading/dumping a c t i v i t y are made

'

aware o f any r e s t r i c t i ons and/or condi t ions.

It i s understood t h a t the Proponent has obtained a11 necessary permi ts / approvals, etc., from other r egu la to r y agencies i n respect .o f the p r o j e c t ( s ) descr ibed herefn.

$ 0

I f you have any questions, please con tac t M r . H. Ye1 son a t 666-2947 o r Mr.- 0. Brq thers a t 666-2990.

Yours t r u l y ,

l He!-kin, P. Eng.

Di rec to r P a c i f i c and Yukon

--

DEPARTMENT W THE ENVIROWEWT OCEAN DUHPING CONTROL PR06RAH . A - -- --

pp

COHDITIOWS FOR OCEAN DISPOSAL -FILE~WDTK~FZ-W~~~-~- pppp

1. PROPOWEM -

S$wn Fraser Uni vers i ty - I I

To dump and/or loud substances fo r 'dumping a t sea for expert.enta1 I

purposesi Diesel o i l will be s p i l l e d to test remote sensing equfplaent *

l

and oi 1 contai mCnt and m o v e r y capabil I t f e s . I

3. TERM- . . I

Valid from March 18, 1987 t o Cbrch 17, 1988. Loading and Qumping will be r e s t r i c t e d to perfods which will not'impose a th rea t t o biological resources; These periods y f l l be speci f ied by t h i s off ice .

4. LOADING SITE IS)

Vancouver Harbour; 49*17.4ztw, m * 0 3 . 5 a 1 u

Bur-rard I n l e t ; 49'17.75 ' N , 122'56. SO'U

A s t a d e p t h of not l e s s than ZO'wtres.

" Diesel o i l wil l ~ ' ~ o u r e d from 10 gallon . d

\ I TOTAL QUAKilTY TO BE DlMPED

Mot to exceed 50 imper,iat gat tons. d

Diesel o i l .

9. WHITORING REQIIIREWEHTS ANC TIRING RESTRICTIONS

9.1 The Proponent should notify t h i s o f f ~ c e a minimumof f i v e working '

deys pr ior to loading and 6 ~ j i n g . The notf f i ca t ion should rnclude t h e following information: 1

I i ) load s i t e and dump s i t e - i 1 nature and quant?ty of the material to be dumped i ) proposed da te (5 ) ~e ~ h i c 4 the l o a d ~ n g and dumping wf l l take place.

..... 2

DEPARTMENT OF THE ENVIRONMENT OCEAN DUMPING CONTROL PROGRAM FILE NO.: 4543-2-02173

9.2 The Proponent sha l l ensure ninimal Impact to the marine environnent and 1 i v i n g resources a t the experiment s l te. The e x p e r l w n t sha l l be conducted a t a t i n e then wind and wave act ion al low the necessary cont ro l o f quiprnent to ensure adequate recovery o f o i l .

9.3 Equipment on-site to ensure containment and recovery o f s p i l l e d o i l sha l l Include: o i l containment barr iers; a skinmer; and sorbents. The o i l contalnnent ba r r i e rs be deployed p r i o r t o any release o f o i l .

9.4 No dumping o f o i l sha l l take place u n t i l an Ocean Dumping Inspector I s present on-site and has approved comnencement o f the experiment.

9.5 The Proponent should repor t to the Director, Environmental Protection, Pac i f i c Region, w i th in 30 days o f expiry o f the Approval, the nature and quant i ty of mater ia l disposed o f pursuant t o the Approval and the date(s1 on rrhich the a c t i v i t y occurred.

~ri . HESKIN, P. E ~ G Director

Environmental Protect ion Conservation and Protect ion

P a c i f i c Region March 17, 1987

PEPOSIT O I L I N T O BURRARD INLET FOR SCIENTIFIC P ~ O S E S m m t s -/Dour

Bob Sherwood S e n i o r P h y s i c a l S c i e n t i s t Enviromentgal P r o t e c t i o n Conse rva t ion L: P r o t e c t i o n P a c i f i c and Yukon Region L

PURSUANT TO SECTION 4 ' 1 and 3 5 ' 2 ' OF TKE MIGRATORY BIRDS CONVENTION ACT A V D REGULATIONS, THIS P E W J T AUTHORIZES THE DEPOSIT OF UP TO 50 GALLONS OF DIESEL FUEL IN'TO BURRARD IKLET NEAR GATES PARK FOR THE PURPOSES OF TESTING REMOTE S E N S I N G EQUIPMENT AND CLEANUP CAPABILITIES. '9"-

Conserva t ion and p r o t e c t i o n

r Hal Nelson I

Ocean Ihmping P a c i f i c 6 Yukon Region

' s e n i o r P h y s i c a l S c i e n t i s t R e f e r r a l and Impact Ana lys i s M P a c i f i c 6 Yukon Region

I

StZURlTY - UASSIF IUTW - DE SECURITE --l 71.-

SUBJECT WET - Ocean Dumping C o n t r o l Program - Simon F r a s e r U n i v e r s i t y

The t e s t e p i l l s propose3 f o r Warch 18 , "1987 i n Rurrard I n l e t were e u c c e s s f u l l y ' executed a s planned. Video and photographic remote s e n s i n g da-ta of t h e s p i l l s

v e r e c o l l e c t e d and a r e now be ing anafyzed . 1

Environmental c o n d i t i o n s were optimal-vave h e i g h t s minimal , v i n d s l i g h t and c loud cover 10/10 a t 2000'. B u r r a r a Clean c o n t r o l l e d and c leaned up the o i l v e r y e f f i c i e n t l y a n d - w e n took t k e o p p ~ r t u n i t y ~ t o mop up some a d j a c e n t u n r e l a t e d s l i c k s .

/' I m u l d l i k e t o thank you, Duane Bro the r s and a l l t h o s e involved i n ' the Ocean Duaping approval p roces s f o r your c y s i d e r a t e and expedi t i o u s review and comments.

I

Bob Sherwood' .

APPENCIX 5. PROCEDURES FOR QUAKTIFICATlOt ; OF I j l E S E L O I L COLLECTE.5 IK EACH SORBEXT PAL LibhlNL FlEL'J T H l k i .

-&

C u t u p & = b e n t pads to f i t 100 ml c e n t r i f u g e the- .,

Add g l a s s *ads tC, f i t 100 p.l c e n t r i f u g e tub;. Add cu t -up p a d &'I00 m l c e n t r i f u g 6 , t u b k . . , Add 2 'ml - c o n c e n t r a t e d s u l f u r i c a c i d .

I

Cover w i t h &screw c a p and c e n t r i f u g e a t 350 0 .WM f o r i 0 i i n u t e s .; Remove pad. . a

E x t r a c % l i q u i d o n bo t tom o f . c e n t r i f u g e i n t o 100 rnl voluhetr'ic f l a s k and . slush t u b e w i t h f r e o n 113. -

P u t p a d .back i n t o c e n t r i f u i e t u b e . Add -10 m l f r e o n 1 1 3-on t o p o f pad . %peat $teps 5 - 9. A t t h i s p o i n t p a d h a s a l l orgalnics removed.and I n r \ t h e v o l u m e t r i c f l a sk . ' . .. Volumi-ze 100 m l v o l u m e t r i c f l a s k . , - , Check t h e f r e o n 1 1 3 as i n d i c a t e d in t h e s t a n d a h P r o c e d u r e s se t o u t on n e x t page . ~ c l d i f ~ a 250 nl sample i n a 500 ml s e p a r a t o r y f u n n e l 4 t o less t h a n p~ 2 w l t h c o n c e n t r a t e d s u l f u r i c a c i d , u s u a l l y 250 u l 1s a d e q u a t e . E x t r a c t w i t h 3 0 m l of f r e o n 113, l e t t i n g t h e sample s i t f i v e m i n u t e s between e x t r a c t i o n s . , D r a i n each f r e o n ex t rac t i n t o a 50 ml v o l u m e t r i c f l a s k by filtering ,

t h r o u g h a s m a l l f u n n e l w i t h a GF/C paper a n d f l v e gm anhydrous so&um s u ' l f a t e . *

Rinse f u n n e l and sodium s u l f a t e w i t h f r e o n 113 and make s o l u t l o n t o e x a c t l y 50 m l . Measure t h e a b s o r b a n c e a t 4000 and 2935 cm-1 on a P e r b n - E l m e r Model 8 8 2 I n f r a r e d S p e c t r o p h o t o m e t e r , u s i n g a p p o p r i a t e d i l u t i o n s o n samples t o f a l l w i t h i n t h e r p n g e o f t h e c a l i b r a t i o n l i n e a r i t y . Us+ng 2 0 ml of t h e d e c a n t e d s o l u t i o n from t h e O i l and G r e a s e Q m n t i t a t l o n 6

( s t e p s 14 - 171, a d d three gm s i l i c a g e l and s h a k e f o r 30 r m n u t e s . C e n t r i f u g e a t 2000 RPM f o r t e n r m n u t e s , t h e n c a r e f u l l y d e c a n t i n t o f i v e cm cylindrical c e l l . Measure t h e a b s o r b a n c e a t 4 0 0 F a n d 2935 cm-1 on a ~ e r k l n - ~ l m e r Model 8 8 2 S p e c t r o p h o t o r r e t e r to o b t a l n H y d r o c a r b n w a n t i t a t i o n v a l u e s .

STANDARDS PRDC EDURES

Make a "Standard O i l " w i t h e x a c t l y 15 m l hexadecane, 15 m l im-octane , and 10 m l chlorobenzene. Determine t h e & n s i t y by *lei*t, normally around 0.823 Wml. Prepare a s tock s o l u t i o n us ing 2500 mg "Standard O i l " made up t o e x a c t l y 50 m l wi th f r eon 113 (50,000 mg/l) . Prepare a n in t e rmed ia t e s tock s o l u t i o n by d i l u t i n g 1 ml of t h e a b w e t o 100 m l (500 mg/l). Prepare s t anda rd s o l u t i o n s of 100, 75, 50, 25, and 10 mg/l by appropr i a t e d i l u t i o n s and a f r eon 113 b lank . Measure t h e absorbance a t 4000 and 2935 cm-1 a g a i n s t a i r on a n I n f r a r e d Spectrophotometer . Typ ica l f i v e cm cell va lues o k a i n e d are a s f o l l o s :

Concent ra t ion . ( i n f r eon, m g / l ) Absorbance (2935-4000 an-1 )

Slope = O.l/839 O f f s e t = 7.4443 Cor re l a t ion = 0 -99999

P l o t t h e s t anda rd curve and perform r e g r e s s i o n a n a l y s i s on t h e I n f r a r e d Spectxophotometer . The l i n e a r c o e f f i c i e n t of c o r r e l a t i o n should be a t l e a s t 0.99995. Unless t h e r e is a change i n t h e absorbance of t h e f r e o n 113, t h e n r e c a l i b r a t i o n w i l l be neces sa ry only p e r i o d i c a l 1 y. Each b o t t l e of s o l v e n t should be checked as a sample a g a i n s t t h e s t anda rd curve. I f any b o t t l e g ives a r e a d i n g equ iva l en t t o mr e t h a n +/-0.1 mg/l i n t h e *eon, t h e n t h e s tandard curve must be redone. More t h a n 1 mg/l i n d i c a t e s probable contaminat ion and t h e f reon should not be used.

CALCULATIONS

1. P l o t va lues obta ined from "Standard O i l n v s concen t r a t ions of sample. 2. Determine t h e f reon concen t r a t ion of t h e unknowns. 3. For O i l and Grease Concent ra t ions

( f r eon concen t r a t ion x 50 ml)/(sample volume i n m l ) = mg/l 4. For Hydrocarbon Concentrat ion

C a l c u l a t e as above. I n t h i s ca se , t h e r e s u l t i n g va lue r e p r e s e n t s t h e q u a n t i t y of diesel o i l i n a sorbent pad i n mg.