LAMPIRANeprints.undip.ac.id/53041/8/LUKLUK_MAHYA_RAHMAH... · 2017-04-13 · 73 LAMPIRAN IV-1 DATA PIROLISIS ROCK -EVAL DAN TOC SUMUR LUK 2 Formation Lithology TOCSample S1 S2 S3

72

LAMPIRAN

73

LAMPIRAN IV-1 DATA PIROLISIS ROCK-EVAL DAN TOC SUMUR LUK-2

Sample Formation Lithology Sample TOC S1 S2 S3 HI OI OPI Tmax PY S2/S3

Depth (m) Type Wt% mg/g mg/g mg/g mg/gC mg/gC (°C)

160 Muara Enim Carb clyst CUTT 7,35 0,10 3,53 4,33 48 59 0,03 431 3,63 0,82

180 Muara Enim Carb clyst CUTT 1,99 0,06 1,68 1,68 84 84 0,03 428 1,74 1,00

440 Muara Enim Coal CUTT 43,52 1,21 77,56 19,75 178 45 0,02 428 78,77 3,93

520 Air Benakat Coal CUTT 44,74 1,18 78,98 13,89 177 31 0,01 426 80,16 5,69

540 Air Benakat Carb clyst CUTT 13,26 0,41 14,65 5,67 110 43 0,03 427 15,06 2,58

710 Air Benakat Clyst CUTT 0,70 0,02 0,62 0,86 89 123 0,03 429 0,64 0,72



1130 Air Benakat Sst CUTT 0,10

110












TOC = Total Organic Carbon

HI = Hydrogen Index =

100*(S2/TOC)

Tmax = Temperature of

Maximum S2

S1 = Free Hydrocarbons

OI = Oxygen Index =

100*(S3/TOC)

*TOC by Leco

Analyser

S2 = Pyrolysable Hydrocarbons

Oil Production Index =

S1/(S1+S2)

74

LAMPIRAN IV-2 DATA REFLEKTANSI VITRINIT

Sample Age Population 1 (Indigenous) Population 2 (Caved/Suppressed) Population 3 (Oxidised/Reworked) Depth

(m) Mean No. of Min Max Mean No. of Min Max Mean No. of Min Max

Ro. (%) Readings Ro. (%) Ro. (%) Ro. (%) Readings Ro. (%) Ro. (%) Ro. (%) Readings Ro. (%) Ro. (%)

160 Muara Enim 0,26 20 0,21 0,33

0,38 2 0,37 0,38

180 Muara Enim 0,26 2 0,25 0,27 0,22 6 0,21 0,23

440 Muara Enim 0,28 26 0,27 0,30

520 Air Benakat 0,30 27 0,28 0,33

540 Air Benakat 0,31 17 0,28 0,34 0,24 3 0,22 0,25

710 Air Benakat 0,36 8 0,33 0,39 0,27 5 0,24 0,30

840 Air Benakat 0,37 7 0,34 0,39 0,27 10 0,25 0,30 0,60 6 0,55 0,66

950 Air Benakat 0,40 19 0,34 0,49

1130 Air Benakat

1200 Air Benakat 0,43 10 0,36 0,52 0,30 4 0,29 0,31

1300 Air Benakat 0,45 10 0,38 0,53 0,31 3 0,30 0,33

1400 Air Benakat 0,46 13 0,38 0,53 0,35 1 0,35 0,35

1500 Air Benakat 0,48 12 0,40 0,55

1600 Air Benakat 0,51 14 0,44 0,56 0,40 1 0,40 0,40

1700 Air Benakat 0,53 16 0,48 0,58

1800 Air Benakat 0,55 11 0,49 0,60 0,46 2 0,45 0,46

1900 Air Benakat 0,57 8 0,52 0,62

2080 Air Benakat 0,59 10 0,56 0,63

2150 Air Benakat 0,60 8 0,56 0,63 0,52 1 0,52 0,52 0,69 4 0,67 0,72

2210 Air Benakat 0,61 13 0,58 0,65

75

LAMPIRAN IV-3 HISTOGRAM REFLEKTANSI VITRINIT

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0

Vitrinite Reflectance

Read

ings

Sample depth : 160 m Indigenous Ro (%) Average : 0,26 Range : 0,21-0,33 Std. Deviation : 0,04 No.of Readings : 20 Readings : 0,21 0,21 0,22 0,22 0,22 0,22 0,23 0,24 0,24 0,24 0,25 0,25 0,27 0,28 0,28 0,28 0,29 0,31 0,33 0,33

Reworked

Ro (%) Average : 0,38 Range : 0,37-0,38 No.of Readings : 2 Readings : 0,37 0,38

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 180 m Indigenous Ro (%) Average : 0,26 Range : 0,25-0,27 Std. Deviation : 0,01 No.of Readings : 2 Readings : 0,25 0,27

Cavings

Ro (%) Average : 0,22 Range : 0,21-0,23 No.of Readings : 6 Readings : 0,21 0,21 0,21 0,22 0,23 0,23

: indigenous

: reworked

: cavings

76

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 440 m Indigenous Ro (%) Average : 0,28 Range : 0,27-0,30 Std. Deviation : 0,01 No.of Readings : 26 Readings : 0,27 0,27 0,27 0,27 0,27 0,27 0,27 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,30 0,30 0,30

Sample depth : 520 m Indigenous Ro (%) Average : 0,29 Range : 0,28-0,31 Std. Deviation : 0,01 No.of Readings : 11 Readings : 0,28 0,28 0,28 0,28 0,29 0,29 0,29 0,29 0,31 0,31 0,31

Cavings

Ro (%) Average : 0,25 Range : 0,24-0,25 No.of Readings : 4 Readings : 0,24 0,24 0,25 0,25

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

77

Sample depth : 520 m Indigenous Ro (%) Average : 0,30 Range : 0,28-0,33 Std. Deviation : 0,01 No.of Readings : 27 Readings : 0,28 0,28 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,30 0,30 0,30 0,30 0,30 0,30 0,30 0,30 0,31 0,31 0,31 0,32 0,32 0,32 0,32 0,33 0,33

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 540 m Indigenous Ro (%) Average : 0,31 Range : 0,28-0,34 Std. Deviation : 0,02 No.of Readings : 17 Readings : 0,28 0,29 0,29 0,29 0,29 0,30 0,30 0,30 0,30 0,30 0,30 0,31 0,32 0,34 0,34 0,34

Cavings

Ro (%) Average : 0,24 Range : 0,22-0,25 No.of Readings : 3 Readings : 0,22 0,25 0,25

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

78

Sample depth : 710 m Indigenous Ro (%) Average : 0,36 Range : 0,33-0,39 Std. Deviation : 0,02 No.of Readings : 8 Readings : 0,33 0,33 0,35 0,36 0,37 0,37 0,38 0,38 0,39

Cavings

Ro (%) Average : 0,27 Range : 0,24-0,30 No.of Readings : 5 Readings : 0,24 0,26 0,27 0,29 0,30

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 840 m Indigenous Ro (%) Average : 0,37 Range : 0,34-0,39 Std. Deviation : 0,02 No.of Readings : 7 Readings : 0,34 0,36 0,37 0,38 0,39 0,39 0,39

Cavings

Ro (%) Average : 0,27 Range : 0,25-0,30 No.of Readings : 10 Readings : 0,25 0,26 0,26 0,26 0,26 0,27 0,28 0,28 0,29 0,30

Reworked

Ro (%) Average : 0,6 Range : 0,55-0,66 No.of Readings : 6 Readings : 0,55 0,56 0,59 0,61 0,62 0,66

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

79

Sample depth : 950 m Indigenous Ro (%) Average : 0,40 Range : 0,34-0,49 Std. Deviation : 0,05 No.of Readings : 19 Readings : 0,34 0,34 0,34 0,35 0,35 0,36 0,37 0,37 0,39 0,39 0,41 0,41 0,46 0,47 0,48 0,48 0,49

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 1200 m Indigenous Ro (%) Average : 0,43 Range : 0,36-0,52 Std. Deviation : 0,06 No.of Readings : 10 Readings : 0,36 0,36 0,38 0,40 0,42 0,43 0,45 0,48 0,49 0,52

Cavings


28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

80


Cavings


28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 1400 m Indigenous Ro (%) Average : 0,46 Range : 0,38-0,53 Std. Deviation : 0,05 No.of Readings : 13 Readings : 0,38 0,39 0,40 0,42 0,43 0,46 0,48 0,50 0,50 0,51 0,52 0,52 0,53

Cavings

Ro (%) Average : 0,35 Range : 0,35-0,35 No.of Readings : 1 Readings : 0,35

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

81

Sample depth : 1500 m Indigenous Ro (%) Average : 0,48 Range : 0,40-0,55 Std. Deviation : 0,05 No.of Readings : 12 Readings : 0,40 0,41 0,43 0,43 0,45 0,47 0,49 0,52 0,53 0,53 0,54 0,55

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 1600 m Indigenous Ro (%) Average : 0,51 Range : 0,44-0,56 Std. Deviation : 0,04 No.of Readings : 14 Readings : 0,44 0,46 0,47 0,48 0,49 0,49 0,51 0,53 0,53 0,53 0,54 0,54 0,55 0,56

Cavings


28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

82

Sample depth : 1700 m Indigenous Ro (%) Average : 0,53 Range : 0,48-0,58 Std. Deviation : 0,03 No.of Readings : 16 Readings : 0,48 0,49 0,49 0,51 0,51 0,52 0,53 0,54 0,54 0,55 0,55 0,56 0,56 0,56 0,57 0,58

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 1800 m Indigenous Ro (%) Average : 0,55 Range : 0,49-0,60 Std. Deviation : 0,04 No.of Readings : 11 Readings : 0,49 0,49 0,49 0,53 0,55 0,56 0,56 0,58 0,59 0,59 0,60

Cavings

Ro (%) Average : 0,46 Range : 0,45-0,46 No.of Readings : 2 Readings : 0,45 0,46

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

83

Sample depth : 1900 m Indigenous Ro (%) Average : 0,57 Range : 0,52-0,62 Std. Deviation : 0,03 No.of Readings : 8 Readings : 0,52 0,54 0,54 0,56 0,57 0,59 0,60 0,62

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings


28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

84

Sample depth : 2150 m Indigenous Ro (%) Average : 0,60 Range : 0,56-0,63 Std. Deviation : 0,03 No.of Readings : 8 Readings : 0,56 0,57 0,58 0,60 0,60 0,62 0,63 0,63

Cavings


Reworked


28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

Sample depth : 2210 m Indigenous Ro (%) Average : 0,61 Range : 0,58-0,65 Std. Deviation : 0,02 No.of Readings : 13 Readings : 0,58 0,59 0,59 0,60 0,60 0,61 0,61 0,61 0,62 0,63 0,64 0,65 0,65

28

21

14

7

0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0


Read

ings

85

LAMPIRAN IV-4 DATA REFLEKTANSI VITRINIT, KOMPOSISI KEROGEN, DAN TAI

Fluo. Non Fluo.

1 160 DC 20 0,21 - 0,33 0,26 2 0,37 - 0,38 0,38 NDP - lt.yell 0 95 tr 5 0 Good

2 180 DC 6 0,21 - 0,23 0,22 2 0,25 - 0,27 0,26 NDP - lt.yell 0 90 tr 10 0 Good

3 440 DC Coal 26 0,27 - 0,30 0,28 Whole Rock NDP yell lt .yell/yell tr 20 2 78 tr Good

4 520 DC Coal 27 0,28 - 0,33 0,30 2- lt .yell lt .yell/yell tr 20 5 75 tr Good

5 540 DC 3 0,22 - 0,25 0,24 17 0,28 - 0,34 0,31 2- - lt .yell/yell 0 25 4 71 tr Good

6 710 DC 5 0,24 - 0,30 0,27 8 0,33 - 0,39 0,36 Whole Rock 2- to 2-/2 - lt .yell/yell tr 65 3 32 tr Good

7 840 DC 10 0,25 - 0,30 0,27 7 0,34 - 0,39 0,37 6 0,55 - 0,66 0,60 2- to 2-/2 yell lt .yell/yell 0 20 4 74 2 Good

8 950 DC 19 0,34 - 0,49 0,40 2-/2 to 2 - yell 0 30 3 67 0 Good

9 1130 DC 2-/2 to 2 - yell tr 15 3 82 tr Very Poor Poor

10 1200 DC 4 0,29 - 0,31 0,30 10 0,36 - 0,52 0,432-(*); 2-/2

to 2lt .yell/yell yell tr 25 4 71 0 Good

11 1300 DC 3 0,30 - 0,33 0,31 10 0,38 - 0,53 0,45 Barren 2-/2 to 2 lt .yell yell 0 30 3 67 0 Good

12 1400 DC 1 0,35 - 0,35 0,35 13 0,38 - 0,53 0,46 2 - yell 0 10 2 85 3 Good

13 1500 DC 12 0,40 - 0,55 0,48 2 to 2/2+ - yell 0 5 2 90 3 poor Poor

14 1600 DC 1 0,40 - 0,40 0,40 14 0,44 - 0,56 0,51 2 to 2/2+ - yell 0 40 2 56 2 Mod

15 1700 DC 16 0,48 - 0,58 0,53 2 to 2/2+ yell yell 0 45 3 50 2 Mod

16 1800 DC 2 0,45 - 0,46 0,46 11 0,49 - 0,60 0,55 2/2+ to 2+ - yell 0 65 2 30 3 Mod

17 1900 DC 8 0,52 - 0,62 0,57 2/2+ to 2+ - yell 0 60 2 34 4 Good

18 2080 DC 10 0,56 - 0,63 0,59 2/2+ to 2+ - yell 0 70 2 25 3 Good

19 2150 DC 1 0,52 - 0,52 0,52 8 0,56 - 0,63 0,60 4 0,67 - 0,72 0,69 2+ - - 0 65 3 28 4 Good

20 2210 DC 13 0,58 - 0,65 0,61 2+ - - 0 20 3 71 6 Good

Notes :

DC : Ditch Cuttings NDP : No Determination Possible Fluo. : Fluorescene lt.yell : light yellow/yellowish tr : trace (< 1%) Kerogen Residue : Barren (0); Very Poor (VP); Poor (P)

TAI : Thermal Alteration Index Barren : No or Poor Vitrinite and/or Lipt : Liptinite wht : white/whitish * : cavings

# R : Number of Readings No Measurable Vitrinite Vit. : Vitrinite gn : green/greenish ** : reworked/oxidized Additive Contaminant : + (trace < 1%); +++ (minor 1-5%);

Preparation : KC (Kerogen Concentrates); WR (Whole Rock) Inert. : Inertinite o : orange/orangish NA : Not Analysed ++++ (moderate 5-10%); +++++ (major >10%)

Scale :

1 - 5

Fluo.

Amorph.

Liptinite

(Herb.)

Mu

ara

En

im F

m.

Air

Ben

akat

Fm

.

# R Range Mean

Cavings/Suppressed Insitu Rework/Oxidized

# R Range Mean #R Range Mean

AmorphousLipt. Vit. Inert.

Remarks

(%)

No. F

orm

atio

nDepth (m)

Sam

ple

T

yp

e

An

alis

ed

Lith

olo

gy

Vitrinite Reflectance Kerogen Composition and TAI

Ker

ogen

Lev

el

Ro% Values

Remarks

TAIFluorescene Colors

(in Blue-Light Excitation)

86

LAMPIRAN IV-5A KEROGEN APPRAISAL SUMMARY : LUK-2

87

LAMPIRAN IV-5B GEOCHEMISTRY LOG/PETROLEUM SOURCE ROCK SUMMARY : LUK-2

88

LAMPIRAN IV-6A DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 1840

Peak Label Compound Name Peak Ht Norm %

nC5 Normal Alkane C5 ` #VALUE!

n C6 Normal Alkane C6 0 0,00










n C16 Normal Alkane C16 324 6,71 Pristane: 673

n C17 Normal Alkane C17 662 13,70 Phytane: 244

n C18 Normal Alkane C18 464 9,60 Pristane/Phytane: 2,76

n C19 Normal Alkane C19 290 6,00 Pristane/nC17: 1,02

n C20 Normal Alkane C20 255 5,28 Phytane/nC18: 0,53


n C22 Normal Alkane C22 166 3,44 n-Alkanes:

n C23 Normal Alkane C23 144 2,98 A. Total C25-C33 Odd: 1041,00

n C24 Normal Alkane C24 142 2,94 B. Total C24-C32 Even: 893,00

n C25 Normal Alkane C25 155 3,21 C. Total C26-C34 Even: 871,00

n C26 Normal Alkane C26 195 4,04 CPI* : 1,18


n C28 Normal Alkane C28 163 3,37 D. Total C23-C27 Odd: 526,00

n C29 Normal Alkane C29 189 3,91 E. Total C25-C29 Odd: 571,00

n C30 Normal Alkane C30 176 3,64 F. Total C24-C28 Even: 500,00

n C31 Normal Alkane C31 339 7,02 CPI2* : 1,10




n C35 Normal Alkane C35 0



4831 100,00

4831* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961

CPI2= (D+E)/;(2*F), after Marzi et al, 1993

WHOLE OIL GC DATA SHEET

n-AlkaneIsoprenoids

2 .0 0 4 .0 0 6 .0 0 8 .0 0 1 0 .0 0 1 2 .0 0 1 4 .0 0 1 6 .0 0 1 8 .0 0 2 0 .0 0

6 5 0 0

7 0 0 0

7 5 0 0

8 0 0 0

8 5 0 0

9 0 0 0

9 5 0 0

1 0 0 0 0

T i m e

R e s p o n s e _

S i g n a l : W B - 1 8 4 0 .D \F ID 1 A .C H

nC

14

nC

15 nC

21

nC

16 n

C17

nC

18

pr

ph nC

20

nC

19

nC

22

nC

23 nC

24nC

25

nC

26

nC

27

nC

13

nC

28 nC

29

nC

30

nC

31

nC

32

nC

33

nC

34

nC

35

89

LAMPIRAN IV-6B DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 1900 m

90

LAMPIRAN IV-6C DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2080 m


nC5 Normal Alkane C5 0























n C28 Normal Alkane C28 159 D. Total C23-C27 Odd: 517,00

n C29 Normal Alkane C29 187 E. Total C25-C29 Odd: 550,00

n C30 Normal Alkane C30 141 F. Total C24-C28 Even: 465,00

n C31 Normal Alkane C31 272 CPI2* : 1,15







4232 100




n-AlkaneIsoprenoids

2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0

6 0 0 0

6 5 0 0

7 0 0 0

7 5 0 0

8 0 0 0

8 5 0 0

9 0 0 0

9 5 0 0

T im e

R e s p o n s e _

S ig n a l: W B -2 0 8 0 . D \ F I D 1 A . C H

nC

14

nC

15

nC

21

nC

16

nC

17

nC

18

pr

ph

nC

20

nC

19

nC

22

nC

23

nC

24 n

C2

5nC

26

nC

27

nC

13

nC

28

nC

29

nC

30

nC

31

nC

32

nC

33

nC

34

91

LAMPIRAN IV-6D DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2150 m



































4057




n-AlkaneIsoprenoids

2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0

6 0 0 0

6 2 0 0

6 4 0 0

6 6 0 0

6 8 0 0

7 0 0 0

7 2 0 0

7 4 0 0

7 6 0 0

7 8 0 0

8 0 0 0

8 2 0 0

8 4 0 0

8 6 0 0

8 8 0 0

9 0 0 0

T i m e

R e s p o n s e _

S i g n a l : W B - 2 1 5 0 . D \ F I D 1 A . C H

nC

14

nC

15 nC

21

nC

16

nC

17

nC

18

pr

ph n

C2

0

nC

19

nC

22

nC

23 nC

24 n

C25

nC

26

nC

27

nC

13

nC

28

nC

29

nC

30

nC

31

nC

32

nC

33

92

LAMPIRAN IV-6E DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2210 m



































2995 100



Isoprenoids

WHOLE EXTRACT GC DATA SHEET

n-Alkane

2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0

6 0 0 0

6 2 0 0

6 4 0 0

6 6 0 0

6 8 0 0

7 0 0 0

7 2 0 0

7 4 0 0

7 6 0 0

7 8 0 0

8 0 0 0

8 2 0 0

8 4 0 0

8 6 0 0

8 8 0 0

T i m e

R e s p o n s e _

S i g n a l : W B - 2 2 1 0 . D \ F I D 1 A . C H

nC

14

nC

15

nC

21

nC

16

nC

17

nC

18

pr

ph

nC

20

nC

19 nC

22

nC

23 nC

24nC

25

nC

26

nC

27

nC

13

nC

28

nC

29

nC

30

nC

31

nC

32

nC

33

93

LAMPIRAN IV-7 DATA GC SUMUR LUK-2 SAMPEL OIL 1130 m


nC5 Normal Alkane C5

n C6 Normal Alkane C6

































1023079,00* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961



n-AlkaneIsoprenoids

2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0

5 0 0 0

1 0 0 0 0

1 5 0 0 0

2 0 0 0 0

2 5 0 0 0

3 0 0 0 0

3 5 0 0 0

4 0 0 0 0

4 5 0 0 0

5 0 0 0 0

5 5 0 0 0

6 0 0 0 0

6 5 0 0 0

7 0 0 0 0

7 5 0 0 0

8 0 0 0 0

8 5 0 0 0

9 0 0 0 0

9 5 0 0 0

1 0 0 0 0 0

T i m e

R e s p o n s e _

S i g n a l : B T 4 7 4 9 8 W . D \ F I D 1 A . C H

nC

14

nC

15

nC

16

nC

17

nC

18

pr

ph

nC

19

nC

20

nC

22

nC

24

nC

26

nC

27

nC

28

nC

29

nC

30

nC

31

nC

32

nC

33

nC

34

nC

35

nC

36

nC

37

nC

13

nC

21

nC

23

nC

25

94

LAMPIRAN IV-8 DATA GC-MS SATURATES SUMUR LUK-2

GC-MS PEAK ABUNDANCE* DATA - TERPANES (m/z 191)

Peak ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil

1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m

Tricyclics

A 82 20 49 10 12 6049 B 106 30 82 15 26 4238

C 76 24 70 14 23 2214

D 107 35 129 20 56 1672

E 64 20 62 7 24 2042 F 119 42 231 24 78 1739

G 68 27 195 13 48 1678

H 20 24 45 8 19 3117

I 32 12 98 5 15 1091

K 0 0 0 0 0 4324 L 0 0 0 0 0 6329

Total 674 234 961 116 301 34493

Tetracyclics

X1 192 33 256 21 84 7356

X2 207 172 480 58 146 435 X3 243 60 291 23 94 505

X4 18 12 0 0 0 2858

X5

X6 118 34 264 17 68 578

X7 0 0 0 0 0 1223 X8

Total 778 311 1291 119 392 12955

**Bicadinanes

R1 5 0 21 0 0 730

R2 10 0 21 0 0 466

R3 23 0 110 0 16 3056

R4 27 0 37 0 0 803 R5 42 0 182 0 30 7213

R6 18 0 37 0 10 1364

R' 34 0 67 0 21 1329

Total 159 0 475

77 14961

Tricyclics: A,B = C19

C = C20

D,E = C21

F = C23

G = C24

H = C25

I = C26

K = C28 pair

L = C29 pair

X1 = 10ß(H)-des-A-Oleanane Bicadinanes:

X2 = 10ß(H)-des-A-Lupane R1 - R6 = C30 Resin Derived Alkanes X3 = C24 Tetracyclic (Unidentified) R' = C31 Resin Derived Alkane X4 = 10ß(H)-des-A-Ursane

X5 = C24 Tetracyclic (Coals)

X6 = C24 17,21-Secohopane



95

* Peak

Abundance in units

See Terpane Peak Identification Table for Normal Peak ID's

C30 = Unidentified Higher Plant Related (Non-Bicadinane) Terpanes

C27ß = 17ß(H)-22,29,30-Trisnorhopane (Immature)

C30/C31 ßß = ßß Hopanes (Immature)

GC-MS PEAK ABUNDANCE* DATA - TERPANES (m/z 191)

Peak

ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil

1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m

C30 Terpanes

C30 699 226 1889 66 342 3570

C30

C30

Total 699 226 1889 66 342 3570

Hopanes and Moretanes 1 117 24 562 16 62 6701

2 318 166 818 44 181 2443

3'

3 0 0 0 0 0 0

4 503 329 1600 79 352 4114

5 195 23 199 12 68 16137 6 699 226 1889 66 342 3570

7 239 115 505 28 112 2830

8 97 63 369 20 59 3294

9 254 281 661 46 156 253

10 100 74 145 11 38 2109 11 21 10 151 0 18 1392

12 43 34 157 0 29 742

13 0 0 65 0 0 492

14 0 0 80 0 0 417

15 0 0 39 0 0 272 16 0 0 35 0 0 97

17 0 0 0 0 0 0

18 0 0 0 0 0 0

Total 2586 1345 7275 322 1417 44863

Other Terpanes Cy 226 131 718 33 146 1395

Cz 366 242 663 58 211 3528

Cx 50 17 165 10 24 1923

C30 ßß

C31 ßß Total 642 390 1546 101 381 6846

Ol 296 48 560 26 171 24802

Tx 124 0 119 12 74 4570

Gm 0 0 0 0 0 0

96

GC-MS PEAK ABUNDANCE* DATA - STERANES

Peak

ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil

1840 m 1900 m 2080 m 2150 m 2210 m

DST-2 1130

m

Steranes (m/z 217)

1 25 8 119 6 22 498

2,3 13 4 101 2 8 415

4 22 6 129 4 10 423 5 76 26 187 13 50 563

6 46 8 53 3 14 425

7,8 35 12 130 3 18 544

9 19 18 94 4 13 1287

10 55 19 103 5 30 223 11 27 17 92 6 15 793

12,13 76 28 194 9 38 932

14 41 40 106 9 27 463

15 253 69 363 24 109 1120

Total 688 255 1671 88 354 7686

Steranes (m/z 218)

1 19 9 49 4 12 247 2,3 20 7 179 5 11 525

4 16 10 154 4 11 455

5 45 21 93 9 27 318

6 37 24 84 5 20 204

7,8 96 49 175 13 42 570 9 143 124 297 26 84 467

10 70 66 256 72 245 364

11 218 192 479 43 122 667

12,13 153 175 566 53 117 1268

14 592 201 944 73 246 2080 15 1361 1151 2333 192 816 1055

Total 2770 2029 5609 499 1753 8220

See Sterane Peak Identification Table for

Peak ID's

* Peak Abundance in units

GC-MS PEAK ABUNDANCE* DATA - DIASTERANES

Peak ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil

1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m

Diasteranes (m/z 217)

A 15 8 193 3 13 551 B 14 7 138 3 9 503

C 6 5 91 2 6 282

D 7 4 88 2 7 285

E 25 7 138 4 13 554

F 24 9 108 5 15 498 a

b

c 6 4 54 2 4 314

d 8 4 84 2 8 529

e f

Total 105 48 894 23 75 3516

See Sterane Peak Identification Table for

Peak ID's

* Peak Abundance in units

97

LAMPIRAN IV-9 DATA GC-MS AROMATICS SUMUR LUK-2

GC-MS PEAK ABUNDANCE* DATA - AROMATICS

Peak ID

Cuttings Cuttings Cuttings Cuttings Cuttings LUK- 2

1840 m 1900 m 2080 m 2150 m 2210 m DST-2 [oil , 1130 m]

Dimethylnaphthalenes (m/z 156)

1,2 (2,6 + 2,7-DMN) 39 11 22

162736

3 (1,3 + 1,7-DMN) 41 12 17

93334

4 1,6-DMN 105 27 40

196185 5 (2,3 + 1,4-DMN) 20 8 10

44216

6 1,5-DMN 9 4 6

16893 7 1,2-DMN 12 4 7

38761

Total

226 66 102 0 0 552125 Max Abundance

1 1 1 1 1 1

Trimethylnapthalenes

(m/z 170) 8 1,3,7-TMN 63 20 28

4 74474 9 1,3,6-TMN 91 32 42

7 81039

10 (1,3,5+1,4,6-TMN) 65 23 31

5 84907

11 2,3,6-TMN 73 21 31

5 53182 12 1,2,7-TMN 65 23 34

6 59540

13 1,6,7-TMN 61 20 30

4 47098 14 1,2,6-TMN 46 15 22

2 37297

15 1,2,4-TMN 10 4 8

7 19967 16 1,2,5-TMN 66 23 33

2 73126

Total

540 181 259 0 42 530630 Max Abundance

1 1 1 1 1 1

Phenanthrenes (m/z 178, 192)

17 P 639 93 173 43 45 10027

18 3-MP 44 7 25 7 8 1930 19 2-MP 43 9 25 9 9 1664 20 9-MP 60 12 33 12 12 2001 21 1-MP 46 8 25 8 8 1166

Total

832 129 281 79 82 16788 Max Abundance

1 1 1 1 1 1

Triaromatic Steranes (m/z 231)

C20 C21 C2620S C2620R+C2720S

C2820S C2720R C2820R

Total

0 0 0

0 Max Abundance

1 1 1

1

Monoaromatic Steranes (m/z 253)

C28a20R + C29b20R

C29a20R Max Abundance

1 1 1

1

Intermediate Stages in Calc. of Ro1 and Ro2

F1

0,45 0,44 0,46 0,44 0,46 0,53 F2

0,22 0,25 0,23 0,25 0,24 0,25

98

LAMPIRAN IV-10 HASIL PERHITUNGAN DATA GC-MS SATURATES SUMUR LUK-2

GC-MS BIOMARKER DATA: TERPANES (m/z 191)

Sample ID C19 Tri (B) % C28-C29 Tri Des-A-Lup % C24-C26 Sec Cy C29 Hop Tot Bicad Ol Gm x 100

C23 Tri (F) Tot Tri Des-A-Ol Tot Tetr C29 Hop C30 Hop C30 Hop C30 Hop C30 Hop

a,b,c

a

a,b

a

a,b

a,b

a,c

a,c

a,c

Cuttings 1840 m

0,89

0,00

1,08

15,17

0,45

0,72

0,23

0,42

0,00

Cuttings 1900 m

0,71

0,00

5,21

10,93

0,40

1,46

0,00

0,21

0,42

Cuttings 2080 m

0,35

0,00

1,88

20,45

0,45

0,85

0,25

0,30

0,00

Cuttings 2150 m

0,625

0,00

2,76

14,29

0,42

1,20

0,00

0,39

0,00

Cuttings 2210 m

0,33

0,00

1,74

17,35

0,41

1,03

0,23

0,50

0,00

DST-2 Oil 1130 m

2,44

30,88

0,06

4,46

0,34

1,15

4,19

6,95

0,00

Type of Parameter: a = Source

b = Maturity

c = Biodegradation

GC-MS BIOMARKER DATA: STERANES (m/z 217)

Sample ID Tot Hop Tot Pregn C27 Dia % Total Steranes* 15B Drim

Tot Ster Tot Ster Tot Dia C27 C28 C29 Homodrim Homodrim

a,b,c

a,b,c

a,b,c

a,b,c

a

a,b

Cuttings 1840 m

3,76

0,00

0,28

19,7674

22,53

57,70

0,04

0,11

Cuttings 1900 m

5,27

0,00

0,31

17,25

22,35

60,39

0,07

0,14

Cuttings 2080 m

4,35

0,00

0,37

32,08

22,74

45,18

0,06

0,15

Cuttings 2150 m

3,66

0,00

0,26

28,41

17,05

54,55

0,01

0,19

Cuttings 2210 m

4,00

0,00

0,29

25,42

21,19

53,39

0,50

0,31

LUK- 2 DST-2 [oil, 1130 m]

5,84

1,95

0,30

24,71

32,25

43,04

1,93

0,87

99

GC-MS BIOMARKER DATA: DISTRIBUTION OF TERPANE CLASSES ON m/z 191

Sample ID % % % % % % % % %

C19-C22 C23+ C24 Des-A C24-C26 C30-C31 C30* Ol Hopanes & Gm

Tricyc Tricyc Tetracyc 17,21-Secohop Bicad Terpanes Moretanes

a,b,c a,b c b a,c a,c c b b,d

Cuttings 1840 m 7,30 4,01 11,08 1,98 2,67 11,73 4,97 54,18 0,00

Cuttings 1900 m 5,05 4,11 10,85 1,33 0,00 8,85 1,88 67,93 0,00

Cuttings 2080 m 2,78 4,03 7,28 1,87 3,36 13,38 3,97 62,49 0,00

Cuttings 2150 m 8,66 6,56 13,39 2,23 0 8,66 3,41 55,51 0,00

Cuttings 2210 m 4,47 5,07 10,27 2,16 2,44 10,84 5,42 56,99 0,00

LUK- 2 DST-2 [oil, 1130 m] 11,03 12,43 7,58 1,22 10,17 2,43 16,87 35,16 0,00

Predominant Source: a = Maturity dependent

b = Bacterial/algal

c = Higher plant

d = Salinity indicator

100

LAMPIRAN IV-11 HASIL PERHITUNGAN DATA GC-MS AROMATICSS SUMUR LUK-2

GC-MS AROMATICS MATURITY PARAMETERS*

Sample ID DNR-

1 DNR-

6 TNR-

1 TNR-

3 TNR-

4 MPR-

1 MPR-

2 MPI-

1 MPI-

2

Calculated Ro.

Vit. (%)**

# Ro. Vit.

Rc1 Rc2 Ro1 Ro2 (%)

Cuttings 1840 m

4,33

1,95

1,12

6,60

1,41

1,89

0,72

0,18

0,17

0,51

0,80 0,84

0,72

0,55

Cuttings 1900 m

2,75

1,38

0,91

5,75

1,53

2,00

0,75

0,21

0,24

0,53

0,82 0,83

0,82

0,57 Cuttings 2080 m

3,67

2,20

1,00

4,13

1,55

2,00

0,76

0,32

0,32

0,59

0,82 0,87

0,75

0,59

Cuttings 2150 m

0,00

0,00

0,00

0,00

0,00

2,00

0,75

0,38

0,43

0,63

0,82 0,83

0,82

0,60 Cuttings 2210 m

0,00

0,00

1,00

0,29

3,00

2,13

0,75

0,39

0,42

0,64

0,82 0,86

0,80

0,61

DST-2 Oil 1130 m

9,63

3,68

0,63

3,66

1,60

3,08

0,83

0,41

0,38

0,65

0,86 1,03

0,81

-

DNR = Dimethylnaphthalene Ratio

MPR = Methylphenanthrene Ratio

* See Appendices for calculations and references

TNR = Trimethylnaphthalene Ratio

MPI = Methylphenanthrene Index

** From published formulae: see Appendices for derivation

TA = Triaromatic Sterane

and references

# Measured (sediments)

101

LAMPIRAN IV-12 KETERANGAN PUNCAK KROMATOGRAM

TERPANE PEAK IDENTIFICATIONS (m/z 191)

Peak No. Carbon No. Identification

A,B 19 Tricyclic terpane C 20 Tricyclic terpane D,E 21 Tricyclic terpane F 23 Tricyclic terpane G 24 Tricyclic terpane H 25 Tricyclic terpane I 26 Tricyclic terpane

X1 24 10(H)-de-A-Oleanane

X2 24 10(H)-de-A-Lupane

X3 24 Tetracyclic Terpane

X4 24 10(H)-de-A-Ursane

X5 24 Tetracyclic Terpane (coals)

X6,X7,X8 24-26 17,21-Secohopane

J 27 Tricyclic terpane K 28 Tricyclic terpanes L 29 Tricyclic terpanes R 30 Bicadinane

1 27 18(H),21(H)-22,29,30-trisnorneohopane (Ts)

2 27 17(H),21(H)-22,29,30-trisnorhopane (Tm) R' 31 Homobicadinane

3’ 28 17(H),21(H)-29,30-bisnorhopane C27 27 17(H),21(H)-22,29,30-trisnorhopane

3 28 17(H),21(H)-28,30-bishorhopane

4 29 17(H),21(H)-30-norhopane Cy 29 18(H),21(H)-30-norhopane (C29 Ts)

Cz 30 15-methyl-17(H)-27-norhopane (diahopane)

Cx 30 Pentacyclic Terpane

5 29 17(H),21(H)-30-normoretane Ol 30 18(H)-Oleanane

6 30 17(H),21(H)-hopane

7 30 17(H),21(H)-moretane Gm 30 Gammacerane

8 31 17(H),21(H)-30-homohopane (22S)

9 31 17(H),21(H)-30-homohopane (22R)

10 31 17(H),21(H)-30-homomoretane 11 32 17(H),21(H)-30,31-bishomohopane (22S)

12 32 17(H),21(H)-30,31-bishomohopane (22R)

13 33 17(H),21(H)-30,31,32-trishomohopane (22S) 14 33 17(H),21(H)-30,31,32-trishomohopane (22R)

102

15 34 17(H),21(H)-30,31,32,33-tetrahomohopane (22S)

16 34 17(H),21(H)-30,31,32,33-tetrahomohopane (22R)

17 35 17(H),21(H)-30,31,32,33,34-pentahomohopane (22S) 18 35 17(H),21(H)-30,31,32,33,34-pentahomohopane (22R) MH 28-36 Methylated Hopane (m/z 205)

103

STERANE PEAK IDENTIFICATIONS (m/z 217, 218, 259)

Peak No. Carbon No. Identification

A 27 13(H),17(H)-Diacholestane (20S) B 27 13(H),17(H)-Diacholestane (20R)

C 28 24-Methyl-13(H),17(H)-Diacholestane (20S)

D 28 24-Methyl-13(H),17(H)-Diacholestane (20R)

E 29 24-Ethyl-13(H),17(H)-Diacholestane (20S)** ¹F 29 24-Ethyl-13(H),17(H)-Diacholestane (20R)

a 27 13(H),17(H)-Diacholestane (20S)

b 27 13(H),17(H)-Diacholestane (20R) c 28 24-Methyl-13(H),17(H)-Diacholestane (20S)

d 28 24-Methyl-13(H),17(H)-Diacholestane (20R)

e 29 24-Ethyl-13(H),17(H)-Diacholestane (20S) f 29 24-Ethyl-13(H),17(H)-Diacholestane (20R)

1 27 5(H),14(H),17(H)-Cholestane (20S)

¹2 27 5(H),14(H),17(H)-Cholestane (20R) ¹3 27 5(H),14(H),17(H)-Cholestane (20R)

4 27 5(H),14(H),17(H)-Cholestane (20S)

5 27 5(H),14(H),17(H)-Cholestane (20R)** 6 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20S)**

²7 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)**

²8 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)** 9 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20S)

10 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)

11 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20S)

12 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R) 13 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R)

14 29 24-Ethyl-5(H),15(H),17(H)-Cholestane (20S)

15 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R) R 30 Bicadinane R' 31 Homobicadinane

DI- AND TRINUCLEAR AROMATIC HYDROCARBON

PEAK IDENTIFICATIONS

Peak No. Dimethylnaphthalenes (m/z 156) 1 2,6-DMN 2 2,7-DMN

104

3 (1,3 + 1,7)-DMN 4 1,6-DMN 5 (2,3 + 1,4)-DMN 6 1,5-DMN 7 1,2-DMN Trimethylnaphthalenes (m/z 170) 8 1,3,7-TMN 9 1,3,6-TMN 10 (1,3,5 + 1,4,6)-TMN 11 2,3,6-TMN 12 1,2,7-TMN 13 1,6,7-TMN 14 1,2,6-TMN 15 1,2,4-TMN 16 1,2,5-TMN

Tetramethylnaphthalenes (m/z 184) 17 1,3,5,7-TeMN 18 1,3,6,7-TeMN 19 1,2,4,6-TeMN 20 1,2,5,7-TeMN 21 2,3,6,7-TeMN 22 1,2,6,7-TeMN 23 1,2,3,7-TeMN 24 1,2,3,6-TeMN 25 1,2,5,6-TeMN 26 DBT

Cadalenes (m/z 198) C Cadalene iC iso-Cadalene

105

Phenanthrenes (m/z 178, 192) 17 P 18 3-MP 19 2-MP 20 9-MP 21 1-MP

Dimethylphenanthrenes (m/z 206) 32 (3,5 + 2,6)-DMP 33 2,7-DMP 34 (1,3 + 3,9 + 3,10+2,10)-DMP 35 (1,6 + 2,9 + 2,5)-DMP 36 1,7-DMP 37 (2,3 + 1,9)-DMP 38 (4,9 + 4,10)-DMP

Triaromatic Steranes (m/z 231) 39 C20 TAS 40 C21 TAS 41 C26 20S TAS 42 C26 20R + C27 20S TAS 43 C28 20S TAS 44 C27 20R TAS 45 C28 20R TAS

Monoaromatic Steranes (m/z 253) 46 5b-Stigmastane 20R+Diastigmastane 20R MAS 47 28a20R+C29b20R MAS

106

GC-MS AROMATICS MATURITY PARAMETER CALCULATION

Parameter Compounds Peak No's DNR-1 = 2,6-DMN+2,7-DMN 1+2 1,5-DMN 6 DNR-6 = 2,6-DMN+2,7-DMN 1+2 1,4-DMN+2,3-DMN 5 TNR-1 = 2,3,6-TMN 11 1,3,5-TMN+1,4,6-TMN 10 TNR-2 = 1,3,7-TMN+2,3,6-TMN 8+11 1,3,6-TMN+1,3,5-TMN+1,4,6-TMN 9+10 TNR-3 = 1,2,5-TMN 16 1,2,4-TMN 15 TNR-4 = 1,2,7-TMN 12 1,2,6-TMN 14 *MPR-1 = 2-MP+3-MP 19+18 1-MP 21 *MPR-2 = 2-MP 19 9-MP 20 MPI-1 = 1.5 * (2-MP+3-MP) 1.5 * (19+18) P+1-MP+9-MP 17+21+20 MPI-2 = 3 * (2-MP) 3 * (19) P+1-MP+9-MP 17+21+20 DNR and TNR after Alexander et al, 1985, 1986, Radke et al, 1986 MPR and MPI after after Radke et al, 1982, 1983 *Radke, 1987: MPR-1 = 1-MP/P; MPR-2 = 2-MP/P; MPR-3 = 3-MP/P; MPR-9 = 9-MP/P.

107

CALCULATION OF EQUIVALENT VITRINITE REFLECTANCE

Parameter : MPI-1 = 1.5 * (2-MP + 3-MP) P + 1-MP + 9-MP MPR-2 = 2-MP 9-MP F1 = 2-MP + 3-MP 2-MP + 3-MP + 1-MP + 9-MP

F2 = 2-MP 2-MP + 3-MP + 1-MP + 9-MP

Equivalent Reflectance (%) :

Rc1 = 0.6 MPI-1 + 0.4 (for Ro. <

1.35%) = -0.6 MPI-1 + 2.3 (for Ro. > 1.35%)

Rc2 = 0.99 (Log10 MPR-2) + 0.94

Ro1 = -0.166 + 2.242F1

Ro2 = -0.112 + 3.739F2

Rc1 and Rc

2 after Radke et al, 1983, 1984

Ro1and Ro

2 after Kvalheim et al, 1987

108

109

110

111

112

113

Documents

LAMPIRANeprints.undip.ac.id/53041/8/LUKLUK_MAHYA_RAHMAH... · 2017-04-13 · 73 LAMPIRAN IV-1 DATA PIROLISIS ROCK -EVAL DAN TOC SUMUR LUK 2 Formation Lithology TOCSample S1 S2 S3