4.2 The Quantum Atomic Model De Broglie Heisenberg Quantum Numbers Orbitals Sublevels

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4.2 The Quantum Atomic Model De Broglie Heisenberg Quantum Numbers Orbitals Sublevels Slide 2 Louis De Broglie (1924) - proposed e -s travel like a wave and not in a simple circular path. De Broglie Bohr Slide 3 Heisenberg Uncertainty Principle Heisenberg Uncertainty Principle states that it is impossible to know precisely both the velocity and position of an electron at the same time without changing it slightly. - Think of a spinning fan blade. At any moment you do not know exactly where is it but you do know the region in which it could be found. Slide 4 What happens to the size of the rows & the # of seats as you get further from the stage? Slide 5 Quantum Atomic Model Energy Level - 3-D shell around the nucleus containing e -s of similar energy. There are 7 energy levels Each energy level has a sublevel. The sublevels are s, p, d, and f Each sublevel holds a specific orbital Slide 6 Review Questions 1.What did de Broglie propose that was different than Bohr? 2.What is Heisenberg uncertain of? 3.How many energy levels are there? 4.What happens to the size of energy level and the # of electrons it can hold as you travel farther from the nucleus? 5.What are the 4 sublevels? Slide 7 Orbitals Orbital a 3-D path in which e -s travel. Each orbital holds 2 e -s (or 1 pair) 4 different orbitals - s, p, d, & f Slide 8 Sublevels - s, p, d & f s - has 1 s orbital = 2 e - (1 pair) p - has 3 p orbitals = 6 e - (3 pair) d - has 5 d orbitals = 10 e - (5 pair) f - has 7 f orbitals = 14 e - (7 pair) Slide 9 s Shapes of s & p orbitals p Slide 10 Shapes of d orbital Slide 11 Quantum Atomic Model Energy Level = The Rows: 1-7 Sublevel = The Section: s, p, d, f Orbital = The Seat 1-2, 1-6, 1-10 1-14 76543217654321 s p d 1 2 3 4 5 6 1 2 12345678910 Slide 12 Review Questions 6. How many electrons does each orbital hold? 7. What are the 4 different orbitals? 8. What type of orbitals make up the s sublevel? the p? the d? the f? 9. How many electrons are in the p sublevel? 10. How is the structure of energy levels, sublevels and orbitals of an atom like an auditorium? Slide 13 Sublevel Blocks of the Periodic Table Slide 14 How many blocks wide is the s sublevel? How many e -s can the s level hold? How many orbitals? Slide 15 Sublevel Blocks of the Periodic Table How wide is the p sublevel? Guess how many e -s the p sublevel holds? How many orbitals? Slide 16 Sublevel Blocks of the Periodic Table How wide is the d sublevel? Guess how many e -s the d sublevel holds? How many orbitals? Slide 17 Sublevel Blocks of the Periodic Table How wide is the f sublevel? How many e -s can an f sublevel hold? How many orbitals? Slide 18 Sublevel Blocks of the Periodic Table 12345671234567 If the Periodic Table was a seating chart in an auditorium, what element would be sitting in Row 2, Section P, Seat 2? Slide 19 Sublevel Blocks of the Periodic Table 12345671234567 Row 2, Section P, Seat 2 is Silicon Slide 20 Think back to our the auditorium analogy Pretend the stage is the nucleus and the elements are in their specific seats, sections & rows. Slide 21 The Quantum Atomic Model Slide 22 The 4 Atomic Models Slide 23 Compare the 4 Atomic Models Thomson, Rutherford, Bohr & Quantum 11) Which ones have protons? 12) Which ones have neutrons? 13) Which ones have a nucleus? 14) Where is the + charge in each? 15) What is wrong with the Thomson model? 16) What is wrong with the Rutherford model? 17) What is wrong with the Bohr Model?