A R0577 QUALITY CONTROL DATA ATI I.D. TEST : VOLATILE

/ \ AnalyticolTechnologies, I

SFUND RECORDS CTR

88015265 SFUND RECORDS CTR

0222-00712

QUALITY CONTROL DATA

TEST : VOLATILE ORGANICS (EPA 624)

CLIENT PROJECT # PROJECT NAME

MONTGOMERY & ASSOCIATES 661D HASSAYAMPA

ATI I . D .

TyiUi- SUA

A R0577 : 807002

REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS

80700201 07/13/88 AQUEOUS UG/L

COMPOUNDS

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

1,1-DICHLOROETHENE TRICHLOROETHENE CHLOROBENZENE TOLUENE BENZENE

ND ND ND 9 ND

50 50 50 50 75

44 54 54 53 78

88 46 108 68 108 55-88 54 104 83

92 136 110 90 111

:v.;.:,- C'}^-î'ri. G.-ir^^l

'vi -::!-. /-^r r - > : ^ U j ^ / ^ ^5l4-;</3o":>-

>l>r-t^

4 23 2 2 7

//\ r,-•/ . : 6 . - • - • . < • . . , ; - , . ^ ; < - 3 -

% Recovery = (Spilce Sample Result - Sample Result)

Spike Concentration 100

RPD (Relative % Difference) = (Spiked Sample - Duplicate Spike) Result Sample Result

X 100 Average of Spiked Sample

TR - Compound detected at an unquantifiable trace level

' i o l OOZ

DATA! 88t12U4988 i l SCANS CALI: 88t12U498e 12

RIC * 07/13/88 16!45!e9 SAMPLE: 8e7108-iriS ^ COHOS.: SML " ^ RAH(£: G 1,1888 LABEL: H 8, 4.8 QUAN: A 8, 1.8 J 8 BASE: U 28/ 3

38 TO 1888

180.8-1

RIC

n od n

m 00 00

n

<

UJ

z UL

»•• •>"'v< 427

591

-T 288 6:48

—T 488

13:28

U ^

748

785

L 638 / W L ,

868

*

T 688

28:88

1 " — 888

26:48

184328.

1 1888 SCAN 33:28 TIME

ROCEDURE: TCA lATA F ILE: 88MSV4980 lEFERENCE: B8M2V4980 lAME L IST: VQN IN IT IAL IZATION OPTION: 2

REPORT: VQSTDS

l l ' l l l [ 1 1 I l - l IT II T ' ..,.—.—»...•»•. •..>.vr.-..»-rJ-.:'—„J„i-.- , - v ' , l , ,. ^ M'k: iaJ. .Jf t ;nnmi! . -Vgl f ( ,

DIA0N08TIC REPORT 7 / 1 3 / 8 8 2 1 : 3 3 : 9 4

PROCESSING OPTION: 3

: STANDARDS X PLUS UNKNOWNS >< - L IST NAMES - > PROC USED POSS RMS PROC USEO POSS RMS STANDARD/UNKNOWN

6 6 1 93 18 8 1 67 VQSTDS/VQl 6 6 1 53 21 9 3 70 VQSTD8/VQ2 6 6 1 93 14 8 1 49 VQ8TD8/VQ3

41 COMPOUNDS PROCESSED. 13 FOUND

COMPOUND X NO L I B ENTRY

1 VQ 1 2 VQ 2 3 VQ 3 4 VQ 4 9 VQ 9 6 VQ 6 7 VQ 7 8 VQ 8 9 VQ 9

10 VQ 10 11 VQ 11 12 VQ 12 13 VQ 13 14 VQ 14 19 VQ 19 16 VQ 16 17 VQ 17 18 VQ 18 19 VQ 19 20 VQ 20 21 VQ 21 22 VQ 22 23 VQ 23 24 'VQ 24 29 VQ 29 26 VQ 26 27 VQ 27 28 VQ 2 8 29 VQ 2 9 10 VQ> 30 )1 VQ 3 1 )S VQ 32 13 VQ 3 3 14 VQ 34 19 VQ 39 ' 16 VO 3 6 17 VQ 3 7 , , 18 VQ 3 8 »9 VQ 3 9 O VQ 40 1 VQ 41

REF 279 990 738 360 703 868

39 64 89

119 178 208 229 267 302 327 338 363 372 399 410 424 424 696 469 476 494 906 912 913 919 949 969 616 669 664 709 740 800 914 948

PRED 276 990 738 361 703 868

39 64 89

119 178 208 229 267 302 327 338 363 373 400 411 429 429 697 470 477 499 907 913 914 916 990 966 616 669 664 709 740 600 914 948

— SEARCH SEL DELTA PEAKS 279 -3 391 3 738 361 703 868

177

267

499 908

• 914

709 740

^

• •

L 1 L 1

1 1 1 1

I 1

1

1 1 3 • •

1

1 I

• • , ,

• •

>< SAT X F I T PEAKS M/Z 987 921 997 997 999 997

974

992

1000 876

• 991

99*9 983

• * •

126 114 117 69 98 99 90 94 62 64 84 43 76 96 63 96 83 62 72 97

117 43 83 83

• 63 79

130 129 97 76 79 63

173 43 43

164 92

112 106 104 106

TOP DELTA PEAKS 279 991 738 361 703 868

178 1

267 • • •

339

427

496 906

• 914 914

, . • • •

709 741

• • •

1 1 1 1 I 1

I 1

1

1

1

1 1 1

• • 1 1

1 1 1 • •

• • • •

I N

luan'

19V 29 26 27 28 29 30 31 32 33 34 33 36 37 38 39 40 41

No I 2 3 4 3 6 7-8 9 10 11 12 13 14 19 16 17 18 19 20 21 22 23 24 29 26 27 26 29 30 31 32 33 34 39 36 37 38 39 K> \ i - .

tltation Report File

1* 32V 33VT 87V 91V 14V 4V

33VC 19V 47V 17H 16H 89V 86V 7V 38V 18H 20H

m/z 128 114 117 69 98 99 NOT NOT NOT NOT 84 NOT NOT 96 NOT NOT 83 NOT 'NOT NOT NOT NOT 83 NOT NOT NOT 130 129 NOT 78 79 NOT NOT NOT NOT NOT 92 112 NOT NOT NOT

i: 88n2V

1* 2,2-TETRACHLOROETHANE 1.2-DICHLOROPROPANE

^4980

TRAN8-1*3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1. 2-TRICHLOROETHANE BENZENE

I CIS-l. 3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTAN0NE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

Scan Ti«e Ref 279 9: 10 I 991 19:42 2 738 24:36 3 361 12:02 1 703 23:26 3 868 28:96 3

FOUND FOUND FOUND FOUND

178 9:96 1 FOUND FOUND

267 8: 94 1 FOUND FOUND

339 11:18 1 FOUND FOUND FOUND FOUND . FOUND i

427 14:14 2 FOUND V i POUND FOUND

496 16:32 2 908 16:96 2

FOUND 914 17:08 2 914 17.08 2

FOUND FOUND FOUND FOUND FOUND

709 23:38 3 741 24:42 3

FOUND POUNO POUMD

RRT 1.000 1.000 1.000 1.313 0.993 I. 176

0.647

0.971

1.233

0. 723 , V,

0.839 0.660

0.870 0.870

0.961 1.004

Meth A BB A BB A BB A BB A BB A BB

A BB

A BB

A BB

A BB

A BB A BB.

- • - . , .

A BB A BB

A BB A BB

: • . • • • r .

Area(Hght) 38330. 171149. 141196. 64069. 166941. 101733.

,

2608.

36919.

1838.

2133.

70003. 2119.

197846. 3679.

93100. 131477.

- • , • ' • ; • • •

^ 1 ) ^

i V f l ' ^ ' ' ^

Amount 90. 000 UO/L 90. 000 UG/L 90. 000 UO/L 91.210 X 99. 908 X 99. 278 X

2. 439 UO/L

44. 117 UG/L

1. 077 UG/L

•

1.420 UO/L

93. 779 UO/L 1. 741 UO/L

76.239 UO/L 6. 449 UO/L • • - .

92.606 UO/L 94. 363 UO/L

' - . • ^ ^ ' • , ' ,

L 3 - ^

XTot 7.09 7.09 7.09 12.86 13. 93 13.44

0.34

6.22

0. 19

0.20

7.96 0.29

11.03 0.91

7.42 7.67

^ 0 7 0 0 - Z ,

^ / U J - S U ^ p,.Lrrô - U t r^ c h l h l -W T. .

DATA: 88t12U4981 i l CALI: 88t12U4981 i 2

PA) b Z RIC 8Zzl3z8a 12U2:88 SAMPLE: 887188-1 MSQ^ COHOS.: 511. *£^^-RAH(X: G 1.1808 LABEL: N 8. 4.8 QUAN: A 8. 1.8 J 8 BASE: U 28,

188.8-1

RIC

275

J ^""*^'*— •".»»Â.-..A.....^^^

361

V ^ W A A J 427 • • 1 n i T ^ • m n • !

SCANS 38 TO 1808

739

590

- | 200 6:40

—T 400

13:20

L 558

102016.

785

868

—I 600

20:00

I 831 J *"! I' •/IT" —I nnnrnn~''n*

V 946 1

800 26:40

~-1 1000 SCAH 33:20 TINE

^TA FILE: 88M2V4981 r^— EFERENCE: 88H2V4981 ^ - * AME LIST: VQN INITIALIZATION OPTION: 2

REPORT: VOSTDS ; vj y r

' ' " 7/13/88 21r; 39; S3

PROCESSINQ OPTION: 3

-STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

X PLUSv UNKNOWNS RMS PROC .USED POSS 40 18 8 I 40 21 ' 9 I 40 14 .6 1

— X - LIST NAME8 - > RM8 STANDARD/UNKNOWN 42 VQ8TD8/VQ1 43 VQ8TDS/VQ2 33 VQ8TDS/VQ3

41 COMPOUNDS PROCESSED. 13 POUND

COMPOUND X NO LIB ENTRY 1 VQ 2 VQ 3 VQ 4 VQ 9 VQ 6 VQ 7 VQ 8 VQ 9 VQ 10 VQ 11 VQ 12 VQ 13 VQ 14 VQ 19 VQ 16 VQ 17 VQ 18 VQ 19 VQ 20 VQ 21 VQ 22 VQ 23 VQ 24 VQ 29 ,VQ 26 VQ 27 VQ 28 VQ 29 VQ K) VQ 11 VQ> 12 V8- G VQ 14 VQ 19 VQ 6 VQ 17 VQ

e va^ 9 VQ O VQ 1 VQ

1 2 . 3 4 9 6 7 8 9 10 11 12 13 14 19 16 17 18 19 20 21 22 23 24 29 26 27 26 29 30 31 32 33 34 39 36 37 38 39 . 40 41

REF 279 990 738 360 703 868 39 64 89 119 178 208 229 267 302 327 338 363 372 399 410 424 424 696 469 476 494 • 906 912 913 919

. 949--. 969 616 669 664 709 740 800 914 948

— — - —

PRED 279 990 738 360 703 868 40 69 86 116 179 209 230 267 302 327 338 363 372 399 410 424 424 696 469 476 494.; 906 918

>/;':913: 919'

^^-949*^ 969 616 669-

.;.. 664;.,

- SEARCH — SEL DELTA 279 990 736 361 1 703 866

, ,

, ,

• •

• •

179 a a

• •

267 , ,

• •

4 a

• • , a

, ,

• •

• • , ,

• • ^ ,

, ^

494 907 1

• ' ' • •

913 '•'•••'•'•• • • • •"

h k ^ ^ ''.-• •••.•••.. - ' ' ' \

. .

' . • ' ' • ' • •

• • • • ' » • .

- V : : , ^ ^ x . ' . •••••

•.'•'709». iyT09 740

:. .600.^ 914 948

740 •;:V£'.-••. . • ' •/.•

*. • ; r "• • •' • .

» •

. — — . . .

PEAK8 1 1 1 1 1 1

1

1

1 1 •

1

• • '

i I •

• • " • . ' • * . • " .

•

X SAT FIT PEAKS 989 923 994 1000 999 998

•

• ,

,

974 ,

,

997 ,

998 874

• '

986 • ,

•

•

•

•

994 989

•

• ,

X M/Z 128 114 117 69 98 99 90 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63

• 79 130 129 97 78 79 63 173 43 43 164 92 112 106 104 106

— CHRO — >

TOP DELTA PEAKS 279 990 737 -1 360 -1 703 868

• •

• •

• * •

177 -J • •

, «

266 -] • •

327 339

494 906

,

913 913

•

«

• ,

664 709 741

•

•

•

4

1

•

•

• •

2 1 • ,

I 1 •

1 1

1 1 1 > •

1 1

• •

• •

• •

• •

1 1

1 1 • •

• •

• •

U U I l b v n 7 0 x

ata: 88I12V4981. Tl 7/13/88 17:32:00 aiipla: 807108-1 MSD ond ft. : 9ML /

, ' V - * . . . . ' ' • ' • ' " ; • V •'''..'-'•

• • . • ' . ' . • • • , ' ' ,

• • - • • . ; , , ; •

tandard ID: Instrunent: 1090 ensitivity ID: 4969 Analyst:

MOUNT-AREA • REF AMNT/(REF AREA • RESP esp. fac. from Library Entry NO NAME 1 181 BROMOCHLOROMETHANE 2 181 1.4-DIFLUOROBENZENE 3 183 CHL0R0BENZENE-D9 4 881 1.2-DICHL0RbETHANE-D4 9 682 T0LUENE-D8 6 883 BROMOFLUOROBENZENE 7 49V CHLOROMETHANE 8 46V BROMOMETHANE . 9 88V VINYL CHLORIDE 10 16V CHLOROETHANE 11 44V METHYLENE CHLORIDE 12 13H . ACETONE 13 19H CARBON DISULFIDE 14 29V 1.1-DICHLOROETHENE 19 13V 1,1-DICHLOROETHANE 16 30V TRANS-1, 2-DICHLOROETHENE 17 23V CHLOROFORM 18 IOV 1.2-DICHLOROETHANE 19 14H 2^BUTAN0NE 20 IIV I.l.l-TRICHLOROETHANE 21 6V CARBON TETRACHLORIDE 22 19H VINYL ACETATE 23 46V BROMODICHLOROMETHANE 24 19V 1.1.2. 2-TETR ACKLOROETHANE 29 32V 1.2-DICHLOROPROPANE 26 33VT TRANS-l.3-DICHLOROPROPENE 27 87V TRICHLOROETHENE 28 91V DIBROMOCHLOROMETHANE 29 14V 1.1.2-TRICHLOROETHANE 30 ' 4V BENZENE 31 33VC CIS-I. 3-DICHLOROPROPENE . 32 19V 2-CHLOROETHYL VINYL ETHER 33 47V BROMOFORM 34 17H 4-METHYL-2-PENTAN0NE 39 16H 2-HEXANONE 36 69V TETRACHUJROETHENEv.i 37 66V TOLUENE 38 7V CHLOROBENZENE 39 38VL ETHYLBENZENE K) 18H STYRENE U 20H .TOTAL XYLENES :t

4o m/x Scan Ti«e Ref RRT Math 1 128 279 9: 10 1 1.000 A BB 2 114 990 19:40 2 1.000 A B B 3 117 737 24:34 3 1.000 A B B 4 69 360 12:00 1 1.309 A BB 9 96 703 23:26 3 0.994 A BB 6 99 f 666 28:96 3 1.178 A B B 7 NOT FOUND 8 NOT FOUND

cs Inst Call:

FACT)

• y . -

. - • . - • • ' • "

' • , , ' ; " . / " '

' V . r * ^ ^ '

' . * < ' ' ' " ' '

;• . V . - ..;:

Area (Hght l;- 36716. 199011. 137702. 64376. 199841. 100919.

.. • •- - • ' . ' • • - • i ' - - I

;

.

.

-• • • • - . • ' •

' . • • • ; •

Aatoufit 90.000 90.000 90. 000 99.684 94. 199 96. 926

• . ' • " ' : • • . - .

• • .-. • . \

• • . - :

UO/L UO/L UO/L X. z X

XTot 6.79 6.79 6.79 12.99 12.78 13. 11

9 10 11 12 13 14 19 16 17 18 19 20 21 22 23 24 29 26 27 28 29 30 31 32 33 34 39 36 37 38 39 40 41

NOT NOT

64

FOUND FOUND

177 NOT FOUND NOT

96 NOT

96 83

NOT NOT NOT NOT NOT NOT NOT NOT NOT 130 129 NOT

78 79

NOT NOT NOT NOT 164 92

112 NOT NOT NOT

FOUND 266

POUND 327 339

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

494 906

FOUND 913 913


664 709 741

FOUND FOUND FOUND

" : ' ; ' • . • • ~ ~ ~ ^

" • . • " •

9: 94

8: 92

10:94 11: 18

16:28 16:92

17:06 17:06

22:08 23:38 24:42

- . - • • ' . .

•''.:.

'"v

1

1 1

2 2

2 2

3 3 3

:"•:'.: , : ^ : ^ V j ^ .

• • • • ' ' • . •

0.644 . - • . - . ^ -

0 . 9 6 7

1. 189 1.233

0 . 8 3 7 0 . 8 9 8

0 . 8 6 9 0 . 8 6 9

0 . 9 0 1 0 . 9 6 2 1.009

_.. "

A BB

A BB

A BB A BB

A BB A BB

A BB A BB

A BB A BB A BB

2379.

36214.

2709. 1909.

81704. 1787.

194149. 3434.

309. 93387.

129711.

2 . 914 UO/L

4 9 . 6 7 2 UG/L

3 .283 UG/L 1. 169 UO/L

67. 999 UG/L 1. 983 UG/L

62. 636 UG/L 6 .479 UG/L

0. 269 UG/L 94 .107 UG/L 94. 994 UG/L

. ...>.>. .

0 . 34

6 . 2 0

0 .49 0. 16

9. 17 0 . 2 1

11 .22 0 . 8 8

0 . 0 4 7 . 3 9 7 . 4 7

— ,

AjS AnolyticalTechnologies, Inc

h i u ) • S'UA

ACCESSION: 807002

QUALITY CONTROL DATA: 188 METHOD 624 & 8240

CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 7/13/88

1,1-DICHLOROETHANE CHLOROFORM 1,1,1-TRICHLOROETHANE BROMODICHLOROMETHANE BROMOFORM TETRACHLOROETHENE

FOUND

39 58 58 21 34 48

ACTUAL

3 9 . 8 4 8 . 6 4 9 . 6 1 9 . 2 2 8 . 8 3 9 . 6

/ i yl'^c^

^f //'J i n J d'i

/ys / X l

PROJECT MANAGER: (^.U. DATE: 8/18/88

9o-?oozL

EP/I / ^ 2 ^

SCANS DATA: 88M2U4971 »1 CALI: 88M2U4971 12

100.0-1

RIC 07/13/88 10:04:00 SAMPLE LBBa=^ CONOS.:"5ML RANGE:'G 1.1008 LABEL: N 0. 4.8 QUAN: A 8. 1.0 J 0 BASE: U 20. 3

663

30 TO 1888

RIC

o ri

QD 00

n

<

Q Ul X 0)

363008.

947

A I A F I L E : EFERENCE: AME L IST :

REPORT:

8eM2V4971 88M2V4971 VQN INIT IALIZATION OPTION: VQSTDS

^/^^C PROCESSING OPTION: 3

STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

X PLUS UNKNOWNS X - L IST NAMES - > RMS PROC USED POSS RMS STANDARD/UNKNOWN

96 18 9 1 63 VQSTDS/VQl 96 21 19 2 94 VQSTDS/VQ2 96 14 7 1 91 VQSTDS/VQ3


COMPOUND X NO

I 2 3 4 3 6 7 8 9

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 23 26 27 28 29 30 31 32 13 )4 19 16 17 » 19 ^0 ^1

L I B VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

•VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ VQ

ENTRY 1 2 3 4 9 6 7 8 9

10 11 12 13 14 19 16 17 18 19 2 0 2 1 2 2 2 3 2 4 2 9 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 3 4 3 9 3 6 3 7 3 8 3 9 4 0 4 1

- . - . — REF 2 7 9 990 7 3 8 3 6 0 703 8 6 8

3 9 64 8 9

119 178 2 0 8 2 2 9 2 6 7 3 0 2 3 2 7 3 3 8 3 6 3 3 7 2 3 9 9 4 1 0 4 2 4 4 2 4 6 9 6 469 4 7 6 4 9 4 9 0 6 9 1 2 9 1 3 9 1 9 9 4 9 9 8 9 6 1 6 6 6 9 6 6 4 7 0 9 7 4 0 8 0 0 9 1 4 9 4 8

PRED 2 7 9 989 7 3 7 3 6 0 7 0 2 8 6 7

4 0 6 9 8 6

116 1 7 8 2 0 8 2 2 9 2 6 7 3 0 2 3 2 7 3 3 8 3 6 3 3 7 2 3 9 9 4 1 0 4 2 4 4 2 4 6 9 9 4 6 9 4 7 6 4 9 4 9 0 6 9 1 2 913 9 1 9 9 4 9 9 8 4 6 1 9 6 6 4 6 6 3 7 0 8 7 3 9 7 9 9 9 1 2 9 4 6

- SEARCH — SEL 2 7 9 989 7 3 7 3 6 1 7 0 2 8 6 7

, , , ,

179 , , ,

3 0 2 a

3 3 7 , ,

3 9 8 , ,

4 2 4 6 9 4 4 6 8 4 7 7 4 9 9 9 0 6

• ,

9 1 6 •

9 6 3 , ,

6 6 3 • • ,

••

•

DELTA

1

1

- 1

- 1

- 1 - 1

1 1

1

- I

PEAKS 1 1 1 1 1 1

1

1

1

1

1 2 1 1 1 I , • 1 « 1 ,

• 1 • ,

• • ,

X SAT X F I T PEAKS M/Z 9 8 8 9 9 6 9 9 9 9 9 9 9 9 7 9 9 7

.

• • , , , ,

9 7 4 , ,

, , ,

9 9 7 , ,

9 7 8 , , .

9 9 6 , , , ,

9 9 9 9 8 8 9 9 7 9 7 0 9 9 6 8 7 2

• ,

9 9 9 «

9 9 7 • ,

9 9 6 • « « • ,

128 114 117

6 9 9 8 9 9 9 0 9 4 6 2 6 4 8 4 4 3 7 6 9 6 6 3 9 6 8 3 6 2 7 2 9 7

117 4 3 8 3 S3 6 3 7 9

* 1 3 0 129

9 7 7 6 7 9 6 3

173 4 3 4 3

164 9 2

1 1 2 106 104 106

— CHRO — TOP DELTA 2 7 9 989 7 3 6 - 1 3 6 1 7 0 2 8 6 6 - 1

, , , , , , ,

179 , , , ,

2 6 8 3 0 2 3 2 9 3 3 7

, ,

a ,

3 9 8 ,

, ,

4 2 4 6 9 4 4 6 9 1 4 7 7 4 9 9 9 0 7 1

• • 9 1 9 9 1 6 948 9 8 2 - 1

, .

6 6 2 - 1 7 0 6 7 3 9 8 0 0 9 1 2 9 4 7

> PEAKS

1 »

, ,

. ,

1 , ,

1 1 1 1 , ,

1 , ,

1 1 1 1 1

I I ,

1 1 1

L " I ^ ^

I 1 1 1 1 1 1

VINYL ACETATE 0/^ CiC

3 4 3 6 7 8 9 0 1 2 3 4 9 6 7 8 9 0 1

o I 2 3 4 5 6 7 8 9 0 I 2 3 4 5 6 7 8 9 0 1 2 3 4 3 6 7 B 9 0 1 2 3 4 3 & 7 3 ?

48V 13V 32V 33VT 87V 31V 14V 4V 33VC 19V 47V 17H 16H a9V 86V 7V 38V 18H 20H

m/i 128 114 117 69 98 95

NOT NOT NOT NOT 84 NOT NOT 96 63 96 83

NOT NOT 97

NOT NOT 83 83 63 73 130 129 NOT 78 73 63 173 NOT NOT 164 92 112 106

BROMODICHLOROMETHANE 1, l.a .2-TETRACHLOROETHANE 1.2-DICHLOROPROPANE TRANS t-1. 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1. l.s •-TRICHLOROETHANE BENZENE CIS-1, 3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTANONE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

Scan 273 389 736 361 702 866


179 FOUND FOUND

268 302 323 337

FOUND FOUND

398 FOUND FOUND

424 694 469 477 499 507

FOUND 919 916 948 982

FOUND FOUND

662 708 739 BOO

Time Ref 9: 10 19:38 24:32 12:02 23: 24 28: 32

9:98

8:96 10: 04 10:90 11: 14

13: 16

14:08 21:48 19:38 19:94 16:30 16:94

17: 10 17:12 16:16 19:24

22:04 23:36 24:38 26:40

1 2 3 1 3 3

1

1 1 1 1

2

2 :2 2 2 2 2

2 2 2 2:

3 3 3 3

RRT 1.000 1. 000 1. 000 1. 313 0.954 1. 177

0.691

0.973 1.098 1. 182 1.223

0. 676

0.720 1. 110 0.796 0.810 0.840 0.861

0.874 0.876 0.930 0.988

0.899 0.962 1. 004 1.087

Meth A BB A BB A BB A BB A BB A BB

A BB

A BB A BB A BB A BB

A BB

A BB A BV A BB A BB A BB A BB

A BB A BB A BB A BB

A BV A BB A BB A BB

V t . / < ^

Aree(Hght) 40667. 190282. 153007. 71693. 1S3613. 114471.

5448.

707. 302124.

1023. 321353.

402010.

177670. 1016.

73049. 69306. 9932. 1037.

3162. 34089. 2903.

199798.

300801. 2064. 2678. 844.

^ U - ^

Z ^

Amount 50. 000 UG/L 30. 000 UO/L 50. 000 UG/L 96. 203 X 98. 403 X 98. 932 X

4. 802 UO/L

0. 809 UG/L 194. 400 UO/L

1. 121 UG/L 287. 879 UG/L

«

288. 831 UG/L

106. 396 UG/L 0.801 UO/L

63. 604 UG/L 39. 999 UG/L 6. 986 UG/L 0. 768 UO/L

1. 129 UG/L 93. 713 UO/L 4. 772 UO/L

169. 918 UO/L

238. 387 UO/L 1.087 UG/L 1. 022 UO/L 0.641 UG/L

XTot 2.64 2.64 2.64 9.09 5. 21 5.23

0.25

0.04 10. 28 . 37 0.06 15.23- c^

•0 ^

19.28 r?

9. 63 - 1 0.04 3.36 2. 11 0.39 0.04

0.06 2.84 0.29 8. 99 - 3 V

. •I

12. 61 - H'i 0.06 0.09 0.03

40 104 912 30:24 3 1.239 A BB 397. 41 106 .947 31:34 3 1.287 A BB 406.

0. 177 UG/L 0. 01 0. 298 UG/L 0. 02

9^)7. oo-z.

y^^ - Siji/i pu^yo^î. ^ôu^^c^-t. SCANS 30 TO 1000 RIC

07/13/88 9:12:00 SAMPLE: 50PPB STD CONDS.: 5ML - " ^^^ RANGE: G 1.1000 LABEL: N 0. 4.0 QUAN: A 0. 1.0 J 0 BASE: U 28. 3

DATA: 88M2U4970 il CALI: 88M2U4970 i2

100.0-1 740

RIC

IO n hr-m

it-CJ z D OD D 00 l l . N^

n

d .. Hi H . r < [n ^ Q Z Ui H X i i . U) »-t

121216.

«/»/»« r r - ^ w

CONTINUING CALIBRATION CHECK - VOLATILE HSL COMPOUNDS

CASE NO: -LABORATORY ID: ATI CONTRACT NO: -INSTRUMENT ID: 1090 SENSITIVITY ID: 4969

STANDARD DATE: 07/13/88 TIME: 9:12:00 STANDARD ID: 88M2V4970 CALIBRATION DATE: 06/27/88

« MAXIMUM XD FOR CCC IS 29J •• MINIMUM AVE RRF FOR SPCC

COMPOUND

CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1.1-DICHLOROETHENE 1,1-DICHLOROETHANE TRANS-1.2-DICHLOROETHENE CHLOROFORM 1.2-DICHLOROETHANE 2-BUTANONE 1.1,1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1,1,2, 2-TETRACHLOROETHANE 1.2-DICHLOROPROPANE TRANS-1. 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1.1. 2-TR ICHLOROETHANE BENZENE CIS-1,3-DICHLOROPROPENE 2-fCHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTAN0NE 2-HEXANONE TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

IS 0. 300

AVE RRF

1. 422 I. 919 1. 460 0.797 1. 297 0. 524 3. 300 1. 110 1.866 I. 141 2. 125 1. 585 0. 138 0. 403 0. 403 0. 447 0. 469 0.375 0. 330 0. 544 0. 451 0. 474 0.285 0. 755 0. 193 0. 145 0.343 0. 338 0.289 0. 934 0.639 0.968 0.481 0.899 0. 994

RF90

1. 939 1. 992 1.409 0.832 1.393 0. 333 2. 341 1.080 1.911 1. 122 2.227 1.942 0. 016 0. 366 0. 362 0.376 0. 439 0.333 0.302 0.436 0. 380 0. 355 0.255 0. 739 0. 167 0. 138

^ ^ 0.299 0.412 0.627 0.896 0. 430 0. 732 0.445

XD

-7 •» -1 4 # -9 -7 -1 23 3 •

-1 »* 2 -4 • -21 88 9 10 16 6 11 «« 9 • 16 16 25 11 2 14 9

30 •» 1

-2 23 1 •

12 •* 11 • 18 20

AVERAGE XD FOR CCC IS: 4.0

AVE RRF - AVERAGE RESPONSE FACTOR FROM INITIAL CALIBRATION RF - RESPONSE FACTOR FROM DAILY CALIBRATION XD - PERCENT DIFFERENCE •* - SPCC - SYSTEM PERFORMANCE CHECK COMPOUNDS * - CCC - CALIBRATION CHECK COMPOUNDS

'ROCEDURE: TCA DIAGNOSTIC REPORT MTA F ILE: 88M2V4970 REFERENCE: 88M2V4970 viAME LIST: VQN INIT IAL IZATION OPTION: 2

REPORT: VQSTDS

7/13/88 - 9: 94:24


: STANDARDS -PROC USED POSS

6 6 1 6 6 1 6 6 1

X PLUS UNKNOWNS RMS PROC USED POSS 73 18 18 1 73 21 20 1 73 14 13 1

X - LIST NAMES - > RMS STANDARD/UNKNOWN 279 VQSTDS/VQl 64 VQSTDS/VQ2 99 VQSTD8/VQ3


COMPOUND X NO LIB ENTRY 1 VQ 2 VQ 3 VQ 4 VQ 9 VQ 6 VQ 7 VQ S VQ 9 VQ 10 VQ 11 VQ 12 VQ 13 VQ 14 VQ 19 VQ 16 VQ 17 VQ 18 VQ 19 VQ 20 VQ 21 VQ 22 VQ 23 VQ 24 VQ 29 'vQ 26 VQ 27 VQ 28 VQ 29 VQ 30 VQ 31 VQ 32 VQ 33 VQ 34 VQ 39 VQ 36 VQ 37 VQ 38 VQ 39 VQ 40 VQ 41 VQ

I 2 3 4 9 6 7 8 9 10 11 12 13 14 19 16 17 18 19 20 21 22 23 24 29 26 27 28 29 30 31 32 33 34 39 36 37 38 39 40 41

REF 279 590 738 360 703 868 39 64 89 113 178 208 229 267 302 327 338 363 372 399 410 424 424 696 469 476 494 906 912 913 919 949 989 616 669 664 709 740 800 914 948

PRED 278 392 739 363 704 868 49 74 93 124 186 216 236 274 308 333 344 368 374 401 412 426 426 637 471 478 496 308 314 919 917 991 986 618 667 666 711 742 801 919 949

- SEARCH SEL DELTA PEAKS 279 991 739 362 704 869 91 77 99 128 187 216 236 271 309 330 341 366 379 401 412

,

426 697 470 478 496 907 914 919 916 992 986 619

,

669 710 741 801 916 991

1 1 -1 1 , ]

-1 1 , ]

1 1 2 1 3 1 4 1 4 1 1 ]

J

, J

-3 1 -3 1 -3 1 -3 1 -2 1 1 ] , . , , ,

-1

-1

-1

-1 —1 -1

2

X SAT X FIT PEAKS M/Z 988 991 999 999 997 997 962 1000 992 970 1000 924 942 997 997 999

L 979 L 998 L 947 L 996 L 980

.

L 996 L 998 L 962 I 974 L 997 I 998 I 998 I 989 I 996 L 988 I 997 1 1000

^

1 999 1 997 1 983 1 994 1 998 1 996

128 114 117 69 98 99 90 94 62 64 84 43 76 96 63 96 83 62 72 97 117 43 83 83

. 63 79 130 129 97 76 79 63 173 43 43 164 92 112 106 104 106

— CHRO TOP DELTA PEAKS 279 991 738 362 704 869 92 77 99 128 187 219 236 272 309 330 341 366 379 401 412 427 426 697 470 478 496 907 913 919 916 992 989 619 667 669 710 742 801 916 991

-1 3

1 1

-1 3

1 :

-I

-I

i

>

)ata: 88M2V4970. TI )7/13/88 9: 12: 00 Sample: 90PPB SID ;onds. : 9ML

—

itandard ID: Instrument: 1090 Sensitivity ID: 4969 Analyst:

^MOUNT-AREA • REF AMNT/(REF AREA • RESP lesp. fac. NO NAME 1 ISl 2 ISl 3 IS3 4 SSI 5 SS2 6 SS3 7 49V 8 46V 9 88V 10 16V 11 44V 12 13H 13 19H 14 29V 19 13V 16 30V 17 23V 18 IOV 19 14H 20 IIV 21 6V 22 19H 23 48V 24 13V 23 32V 26 33VT 27 87V 28 51V 29 14V 30 , 4V 31 33VC 32 19V 33 47V 34 17H 33 16H 36 69V 37 86V 38 7V 39 38V 40 18H 41 20H

No M/z 1 128 2 114 3 117 4 69 9 98 6 99

from Library Entry

BROMOCHLOROMETHANE 1.4-DIFLUOROBENZENE CHL0ROBENZENE-09 1.2-DICHL0R0ETHANE-D4 TOLUENE-DS BROMOFLUOROBENZENE CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULFIDE 1.1-DICHLOROETHENE 1.1-DICHLOROETHANE TRANS-l. 2-DICHLOROETHENE CHLOROFORM 1.2-DICHLOROETHANE 2-BUTANONE 1.1.1-TRICHLOROETHANE CARBON TETRACHLORIDE VINYL ACETATE BROMODICHLOROMETHANE 1. 1. 2. 2-TETRACHLOROETHANE 1. 2-DICHLOROPROPANE TRANS-1, 3-DICHLOROPROPENE TRICHLOROETHENE DIBROMOCHLOROMETHANE 1,1, 2-TR I CHLOROETHANE BENZENE CIS-I. 3-DICHLOROPROPENE 2-CHLOROETHYL VINYL ETHER BROMOFORM 4-METHYL-2-PENTANONE 2*TÊXANONc TETRACHLOROETHENE TOLUENE CHLOROBENZENE ETHYLBENZENE STYRENE TOTAL XYLENES

Scan TiMe Ref RRT Meth 279 9: 16 1 1. 000 A BB 991 19:42 2 1.000 A BB 738 24:36 3 1.000 A BB 362 12:04 1 1.297 A BB 704 23:28 3 0. 994 A BB 869 28:98 3 1. 178 A BB

JV Inst Cali:

FACT)

«

Area (Hght) Aeiount 44319. 90. 000 197863. 90. 000 162118. 90.000 81207. 100. 000 199897. 100. 000 122996. 100.000

.

UG/L UG/L UG/L X X X

...'"

XTot 2.49 2.49 2.49 4.90 4.90 4.90

7 90 8 94

92 1: 1 0. 186 A BB 77 2:34 1 0.276 A BB

68043. 90.000 UG/L 2. 49 68769. 90.000 UO/L 2.49

'^ 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 20 29 30 31 32 33 34 35 36 37 38 39 40 41

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28

î-64 84 43 76 96 63 96 83 62 72 97 117 43 83 83 63 75 130 129 97 78 75 63 173 43 43 164 92 112 106 104 106

Ret(L) 9: 18 19:42 24:36 12: 04 23: 28 28: 58 ' 1:44 2:34 3: 18 4: 16 6: 14 7: 10 7:52 9:04 10: 10 11:00 11:22 12: 12 12:30 13:22 13:44 14: 14 14: 12 21:54 19:40 13:56 16:32 16:94

'?'/ 128 187 219 236 272 309 330 341 366 379 401 412 427 426 697 470 478 496 907 913 919 916 992 989 619 667 669 710 742 801 916 991

J.'/5 4: 16 6:14 7: 10 7:92 9:04 10: 10 11:00 11:22 12: 12 12:30 13:22 13:44 14: 14 14: 12 21:94 19:40 19:96 16:32 16: 94 17:06 17: 10 17: 12 18:24 19: 30 20:38 22: 14 22: 10 23:40 24:44 26: 42 30:32 31:42

) Ratio RRT(L] 1. 1. 1. 1. I. 1. I. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. I. 1. I. 1. 1. 1.

00 1. 000 00 1. 000 00 1.000 00 1. 297 00 0. 994 00 1. 178 00 0. 186 00 0. 276 00 0. 399 00 0. 499 00 0. 670 00 0. 771 00 0.846 00 0. 979 00 I. 093 00 1. 183 00 1. 222 00 1.312 00 0.639 00 0. 679 00 0.697 00 0. 723 00 0. 721 00 1. 112 00 0. 799 00 0.809 00 0. 839 00 0. 898

1 0 . 3 5 S ~ 1 0. 499 1 0. 670 1 0. 771 1 0. 846 1 0. 979 1 1.093 1 1. 183 1 1.222 1 1. 312 2 0. 639 2 0. 679 2 0. 697 2 0. 723 2 0. 721 2 1. 112 2 0. 799 2 0. 809 2 0. 839 2 0. 898 2 0. 868 2 0. 871 2 0. 873 2 0. 934 2 0. 990 3 0. 839 3 0. 904 3 0. 901 3 0. 962 3 1. 009 3 1.089 3 1.241 3 1. 289

1 Ratio 1.00 1. 00 1. 00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 l.OO 1.00 1.00 1.00 l.OO 1. 00 1. 00 1.00 1.00 l.OO

j^6ys A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A VB A BB A BB A BB A BB A BB A BB A BB A VB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB A BB

Amnt 90.00 90. 00 90. 00 100. 00 100. 00 100. 00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90. 00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90.00

â2V.<7 .36691. 61810. 23637. 112600. 47891. 84678. 49716. 98674. 86093. 3116. 72369. 71988. 74316. 86821. 65962. 59709. 90177. 79248. 70238. 50398. 146171. 32997. 27268. 47699. 54163. 48953. 66848. 101600. 138843. 69736. 118745. 72106.

Amnt(L) 50. 00 50.00 50. 00 100. 00 100.00 100. 00 50. 00 90.00 90.00 90.00 90.00 90.00 90.00 90.00 90. 00 90.00 90. 00 90.00 90.00 90.00 90.00 90.00 90.00 30.00 30. 00 50.00 30.00 30.00

S'C. ooo as/L 30.000 UO/L 30.000 UG/L 30. 000 UO/L 30.000 UO/L 50. 000 UO/L 50. 000 UG/L 50. 000 UG/L 50. 000 UG/L 50. 000 UO/L 50. 000 UG/L 50. 000 UO/L 50. 000 UO/L 50. 000 UO/L 50.000 UO/L 50.000 UG/L 50. 000 UO/L 50. 000 UO/L 50.000 UO/L 30. 000 UO/L 50. 000 UO/L 50.000 UO/L 30. 000 UO/L 50. 000 UO/L 50.000 UO/L 30. 000 UO/L 50.000 UO/L 50.000 UO/L 50. 000 UO/L 50.000 UO/L 50. 000 UG/L 50. 000 UO/L 50. 000 UO/L

R. Fac R. Fac(L) 1.000 1.000 1.000 1.000 1.000 1.000 0. 916 0. 916 0.616 0.616 0. 378 0. 378 1.539 1.939 1.992 1.992 1.409 1.409 0. 832 0. 832 1. 399 1. 399 0. 933 0. 933 2. 941 2. 941 1. 080 I. 080 1.911 1.911 1.122 1.122 2. 227 2. 227 1.942 1.942 0. 016 0. 016 0. 366 0. 366 0. 362 0. 362 0. 376 0. 376 0. 439 0. 439 0. 333 0. 333 0. 302 0. 302 0. 496 0. 496 0. 380 0. 380 0. 399 0. 399

•2. ^LT 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2.49 2. 49 2.49 2.49 2. 49 2.49 2.49 2.49 2.49 2.49 2.49 2.49

Ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

, : V m - ^ - V ^ .•^y::V-:::VV.,V

17: 06 17: 10 17: 12 18:24 19: 30 20:38 22: 14 22: 10 23:40 24:44 26:42 30:32 31:42

1.00 l.OO 1.00 1.00 1.00 l.OO l.OO 1.00 1.00 1.00 1.00 1.00 1.00

0. 868 0.871 0.873 0. 934

990 839 904 901 962

1. 009 1. 089 1. 241 1. 289

0. 0. 0. 0. 0.

1. 00 1.00 1.00 I. OO 00 00 00 00

1. 00 1. 00 1. 00 1. 00 1.00

90.00 90. 00 90.00 90. 00 90. 00 90. 00 90.00 90. 00 90. 00 90.00 90.00 90.00 90. 00

90.00 90.00 90.00 90.00 90.00 90.00 90.00 50. 00 50.00 90.00 90.00 50.00 50. 00

0. O 0 O 0 0

,;•,:• J . . ' ; , ; - i i -J . - iL| iv; .i-. • • • • v •^•'

- ^ ^ ^ ^ ^ ^ ' ^ • ^ ^ - ^ • ' ^ • • : - : -,..i:-^rWiliSi<ij--/'V-fc • . . - . .X-. .- . .^^. .^, .- : . -

1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

iMiMMl 0.259 0. 739 0. 167

138 241 334 299 412 627

0.896 0.430 0.732 0. 449

0.299 0.739 0. 167 0. 138 0.241 0.334 0.299 0.412 0.627

896 430 732 449

0. 0. 0. 0.

>jJi^ AnolyticalTechnologies, Inc

Ti^ld WanM

QUALITY CONTROL DATA

TEST : SEMI-VOLATILE ORGANICS (EPA 625)


MONTGOMERY & ASSOCIATES 661D HASSAYAMPA

ATI I.D.

REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS

807002

80700203 08/11/88 AQUEOUS UG/L

COMPOUNDS

DUP. DUP. SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

1,2,4-TRICHLOROBENZENE ACENAPHTHENE 2,4-DINITROTOLUENE PYRENE N-NITROSO-DI-N-PROPYLAMINE 1,4-DICHLOROBENZENE PENTACHLOROPHENOL PHENOL 2-CHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 4-NITROPHENOL

ND ND ND ND ND ND ND ND ND ND ND

50 50 50 50 50 50 100 100 100 100 100

38 58 40 58 49 54 64 45 60 44 31

76 116 80 116 98 108 64 45 60 44 31

33 56 32 53 42 58 54 56 66 45 27

66 112 64 106 84 116 54 56 66 45 27

14 4 22 9 15 7 17 22 10 2 14

% Recovery = (Spike Sample Result - Sample Result)

Spike Concentration X 100


Average of Spiked Sample

TR - Compound detected at an unquantifiable trace level

X 100

RIC 08/11.^88 0:33:00

DHTH: 8o7ti023t'lS #1 C H L I : S070023MS #2

JCAHS 1 TO iyy

S A W i m O B 807002-3 MATRIX SPIKE e r ^ • COHDS.: o

RANGE: G 1.2300 LABEL: N 0, 4.0 QUAH: A 0. 1.0 J 0 BASE: U 20. 3

100.0-1

RIC

Uu I I J^4=Ay w M IL^

•500 8:20

1000 16:40

1500 25:00

I' ^ ^ . ->>€

323584.

2000 33:20

SCAN TIME

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

J- OT X.

PROC 2 2 2 2 2 2 2 2 1

Vj 1 1

USI

TCA a070023MS 9070023MS Kl XI

rvKir\ADr\c_

DIAGNOSTIC

INITIALIZATION

• *

îMUftKL/ta LD POSS 2 2 2 2 2 2 2 2 5

2

0

%/-y ^

RMS 302

0 0 0 0 0 0 0 0

r

OPTION-

tl 1 i n ri_\yi9

PROC 11 9 9 9 12 12 11 10 7

1 IML

REPORT 8/11/88

2 PROCESSING OPTION: 3

/Kini.lKIC UINKi>iuinii>iij

USED 7 5 2 5 3 7 5 5 0

POSS

e 6 1 1 1 2 1 1 1

^ RMS 1191 105 0

76 71

346 60 52 0

<: - LIST NAMES - > STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6

9: 5B: 4-'.

80 COMPOUNDS PROCESSED, 29 FOUND

COMPOUND X NO LIB ENTRY 1 SV 1 2 SV 2 3 SV 14 4 SV 15 5 SV 16 A RW 17

REF -399 -589 -256 -381 -366 -ri7n

PRED 402 593 252 377 362 r TA

SEARCH SEL DELTA PEAKS 404 2 2 591 -2 1

386 9 1

— >< SAT FIT PEAKS 990 985

, 993

, -1 ,

•

X M/Z 152 136 42 94 93 93

— CHRO TOP DELTA PEAKS 404 1 591 1 251 1 386 1

9 10 11 12 13 4 .5 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 0

41 42 43 44 45 46 47 40 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72

SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73

-427 -437 -427 -380 -241 -464 -458 -464 -480 -471 -857 -490 -529 -538 -563 -603 -573 -581 -487 -585 -591 -614 -626 -702 -697

-1078 -735 -753 -753 -769 -800 -839 -831 -872 -861 -881 -763 -979 -923 -886 -902 -902 -949 -946 -938

-1357 -1483 -962 -968

-1018 -1033 -1067 -1087 -1087 -1200 -1293 -1689 -1333 -1763 -1293 -1424 -2007 -1486 -1524

423 433 423 385 249 468 462 468 483 474 858 492 531 540 565 605 575 583 491 588 594 617 629 704 699 1079 737 755 755 771 802 841 833 873 862 882 766 982 926 889 905 905 952 949 941 1360 1484 964 970 1020 1035 1069 1089 1089 1202 1295 1691 1335 1765 1295 1426 2009 1488 1526

411 -12

411 -12 385 250 1

482 -1

858

, ^ , , , ^

491 588

.

705 1

1079

.

.

.

.

863 1

765 -1 982 933 7

904 -1 904 -1

.

1484

.

1069

.

1202 1295 1691 1335

1295 ,

.

.

1526

2

2 2 3

1

1

.

1 1 .

1

1

.

.

1

1 1 2

1 1

1

1

1 1 1 1 .

1 .

1

996

998 993 991

977

993

.

994 995

967

982

994

997 992 981

986 891

993

983

985 972 989 993

979

917

14t> 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142

1 188 237, 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149

385 250

482

858

491 588 594

705

1079

835

863

765 982 933

904 904 951

1484

1069 1090 1090 1202 1295 1691 1335

1295

1526

75 76 77 78 79 ^0

sv SV

sv SV

sv SV

76 77 78 79 80 81

-1640 -1680 -1680 -1935 -1890 -1935

1640 1680 1680 1935 1890 1935

252 252 252 276 278 276

Quantitation Report File: 8070023MS

Data: a070023MS. TI 08/11/88 0:38:00 Sample: JOB 807002-3 MATRIX Conds. : 5 Formula: IUL INJECTION Submitted bg:

SPIKE

Instrument: 1050 Analyst: RGM

Ueight: Acct. No.

0. 003

AMOUNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

Name ISl IS2 61B 65A 5H 18B 24A 26B 27 B 6H 25B SS2 SSI 2H 42B

1,4-DICHL0R0BENZENE-D4 (SV#1> NAPHTHALENE-DS (SVtt2> N-NITROSODIMETHYLAMINE (SVttl4) PHENOL (SV#15) ANILINE (SV#16) BIS(2-CHLOROETHYL)ETHER (SV#17) 2-CHLOROPHENOL (SV#18) 1,3-DICHLOROBENZENE (SV#19) 1,4-DICHLOROBENZENE (SV#20) BENZYL ALCOHOL (SV#21) 1,2-DICHLOROBENZENE (SV«22) PHENaL-D5 (SV#7) 2-FLUOROPHENOL (SVI»8) 2-METHYLPHENOL (SV#23) BIS(2-CHLOROISOPROPYL)ETHER (SV#24)

18 19 20 21 22 "23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

12B I S3 56B 54B 57A 34A IH 43B 31A SS3 8B 55B 7H 52B 22A 9H IS4 53B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SS5 SBA

HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SV#3) NITROBENZENE (SV#28) ISOPHORONE (SV#29) 2-NITROPHENOL (SV#30) 2,4-DIMETHYLPHENOL (SV#31) BENZOIC ACID (SVtt32) BIS(2-CHLOROETHOXY)METHANE (SV#33) 2,4-DICHLQROPHENOL (SV#34) NITR0BENZENE-D5 (SV#9) 1,2,4-TRICHLOROBENZENE (SV#35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SV#37) HEXACHLOROBUTADIENE (SV#38) 4-CHL0R0-3-METHYLPHENDL (SV#39) 2-MeTHYLNAPHTHALENE (SV#40) PHENANTHRENE-DIO (SV#4) HEXACHLOROCYCLOPENTADIENE (SV#41) 2,4,6-TRICHLOROPHENOL (SV#42) 2.4,5-TRICHLOROPHENOL (SV#43) 2-CHLORONAPHTHALENE (SV*»44) 2-NITROANILINE (SV#45) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SV#47) 3-NITROANILINE <SV#48) ACENAPHTHENE (SV#49) 2,4-DINITROPHENOL (SV#50) 2-FLUOROBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SVtt51)

No Name 48 8H DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITROTOLUENE (SVtt53) 50 36D 2,6-DINITROTOLUENE (SVtt54)

Nu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

m/z 152 136 42 94

NOT NOT 128 NOT NOT NOT NOT 99 112 NOT NOT NOT 70

NOT 164 NOT NOT

Scan 404 591 251 386

FOUND FOUND

384 FOUND FOUND FOUND FOUND

385 250

FOUND FOUND FOUND

482 FOUND

858 FOUND FOUND

Time 6: 44 9: 51 4: 11 6: 26

6:24

/ 1 - ( ^ ^

6: 25 4: 10

8:02

14: 18

Ref 1 2 1 1

1

ôL

1 1

1

19

1. 1. 0. 0.

0.

0. 0.

1.

1

RRT 000 000 621 955

950

953 61.9

193

, 000

Me A A A A

A

A A

A

A

th BV BB BB BB

BB

BB BV

BV

BB

Area(Hg 68200.

331493.

71948.

79013.

^ \ Z G

45172. 26833.

39146.

190798.

ht)

l -

Amount 100. 000 100. 000 58. 012 44. 913

60. 124

33. 729 29. 102

48. 751

100. 000

NG/UL NG/UL NG/UL NG/UL

NG/UL

NG/UL NG/UL

NG/UL

NG/UL

r.Tot 6. 61 6. 61 3. 83 / 2.97*/^

3. 9 7 ^

^ ^ • \

=- ^ c ^ 1.92 5-

3. 22 ^ ' '

6. 61

24 25 26 27 28 ->9 JO 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

NOT NOT NOT 82 180 128 NOT NOT 107 NOT 188 NOT NOT NOT NOT NOT NOT 152 NOT 153 NOT 172 330 139 NOT 89 165

FOUND FOUND FOUND

491 588 594

FOUND FOUND

705 FOUND 1079

FOUND FOUND FOUND FOUND FOUND FOUND

835 FOUND

863 FOUND

765 982 933

FOUND 904 904

8: 9: 9:

11:

17:

13:

14:

12: 16: 15:

15: 15:

11 48 54

45

59

55

23

45 22 33

04 ;04

2 2 2

2

34

19

19

19 19 19

19 19

0. 0. 1.

1.

1.

0.

1.

0, 1, 1.

1 1

831 995 005

193

000

973

006

892 145 087

, 054 . 054

A A A

A

A

A

A

A A A

A A

BB BB BB

BB

BB

BB

BB

BB BB BB

BB BB

46577. 53224.

670.

48805.

295169.

445.

94284.

115528. 10229. 6130.

14953. 24849.

41. 37. 0.

43.

100.

0.

57.

46. 35. 30.

39. 38.

856 576 193

971

000

133

899

010 359 937

670 ,X07

NG/UL NG/UL NO/UL

NG/UL

NG/UL

NG/UL

NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL

2. 2. 0.

2.

6.

0.

3.

3. 2. 2.

2, 2,

77 <.V'-48 01

91

61

01

83»/V^

04 '\^ 34 V 0 4 / ^

62>/^ 51

Quantitation Report File: 8070023MS

Data: B070023MS. TI 08/11/88 0:38:00 Sample: JOB 807002-3 MATRIX Cond 6. : 5 Formula: IUL INJECTION Submitted by:

SPIKE


AMOUNT=AREA * REF AMNT/(REF AREA « RESP FACT) Resp. fac. from Library Entry

Weight: Acct. No.

0. 003

No 51 52 53 54 55 56 57 ^8 59 60 61 62 63 64 65

Name 70B 40B SOB 12H IS5 60A 62Q 41B 9B 64A 81B 78B 68B 39B IS6

DIETHYL PHTHALATE (SVtt55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SVtt57) 4-NITR0ANILI,NE (SVtt58) CHRYSENE-D12 (SVtt5) 2-METHYL-4,6-DINITRQPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SVtt61) HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE (SVtt65) DI-N-BUTYL PHTHALATE (SVtt66) FLUORANTHENE (SVtt67) PERYLENE-D12 (SV«6)

6B 84B PYRENE (SVtt69) 69 67B BUTYL BENZYL PHTHALATE (SVtt70) 70 28B 3,3'-DICHLOROBENZIDINE (SVtt71) 71 72B BENZO(A)ANTHRACENE (SV#72) 72 66B BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) •3 76B CHRYSENE (SVtt74) ,4 69B DI-N-OCTYL PHTHALATE (SVtt75) 75 74B BENZO(B)FLUORANTHENE (SVtt76) 76 74B BENZO(K)FLUORANTHENE (SVtt77) 77 73B BENZO(A)PYRENE (SVtt78) 78 83B INDENOd, 2, 3-CD)PYRENE (SVtt79) 79 82B DIBENZO(A,H)ANTHRACENE (SVttSO) 80 79B BENZO(G,H, DPERYLENE (SVttBl)

No 51 52 53 54 55 56 57 58 59 60 61 62 63

m/z 149 NOT NOT NOT 240 NOT NOT NOT NOT 266 178 178 149

Scan Time Ref RRT Meth

24: 44 55 1. 000 A BB

951 15: 51 19 1. 108 A BB FOUND FOUND FOUND 1484

FOUND FOUND FOUND FOUND 1069 1090 1090 1202

17:49 18: 10 18: 10 20:02

34 34 34 34

991 010 010 114

A A A A

BB BQ BQ BB

Area(Hght) 292.

156963.

22381. 434. 434.

135230.

Amount ' / .Tat 0. 177 NG/UL 0. 01

100. 000 NG/UL 6. 61

64. 274 NG/UL 4. 25 0. 138 NG/UL 0. 01 0. 138 NG/UL 0. 01

61.890 NG/UL 4 09 y

No 64 65 66 67 68 69 70 71 72 73 74 75 76 77 7B 79 80

m/z Scan Time Ref RRT Meth

264 244 NOT 202 NOT NOT NOT 149 NOT 149 NOT NOT NOT NOT NOT NOT

1295 1691 1335

FOUND 1295

FOUND FOUND FOUND 1526

FOUND 1615


21: 35 28: 11 22: 15

34 65 55

1. 200 1. 000 0. 900

BB BB BB

21: 35 55 0. 873 A BB

25: 26 55 1. 028 A BB

26: 55 65 0. 955 A BB

Area(Hght) 121006. 140729. 94744.

121006.

1057.

168.

Amount 58. 062

100. 000 54. 099

r.Tot NG/UL 3. 84 NG/UL 6. 61 NG/UL 3. 57

57. 764 NG/UL 3. 32

0. 922 NG/UL 0. 06

0. 098 NG/UL 0. 01

4

•0

n (> n ri

Q Z 00 3 00

o v 0 -^

00

Q •• LU \ -1 < tn f-< Q Z Ul •-< I u. tn < t z o »-<

(^^25- S

RIC gg/11/88 1:43:00

DATA: 8070023f1SD #1 CALI: 8070023MSD #2

SCANS 1 TO 2022 (it f^

SAMPLE: JOB 807092-3 MATRIX SPIKE DUPLICATE CONDS.: GCl - ^ ' RANGE: G 1..2022 LABEL: N O.. 4 .8 QUAN: A

(^

0.. 1.0 J 0 BASE: U 20.. 3

100.0-1 39014^

RIC

fOi 500 8:20

jLiJl T

' 000 :^:40

Li ±. u. iA 1500 25:00

2000 33:20

SCA-

PROCEDURE DATA FILE REFERENCE NAME LIST

REPORT

y ' ^ ^ C T

PROC 2 2 2 2 2 2 2 2

1 1

^ 11

USI

TCA 8070023MSD 8070023MSD Kl XI

^MnADr\c_

DIAGNOSTIC

INITIALIZATION

'^NUAKUb — ED POSS 2 2 2 2 2 2 2 2 . 5

2

2 1 0

_. "sy ^\.

RMS 219

0 0 0 0 0 44 0 0

r

OPTION

1 t If?

ruwcj PROC

11 9 9 9 12 12 11 10 7

1 IKII-

REPORT 8/11/88


/ kirî ikir*

UINKMUWINO USED

7 5 2 5 3 7 6 5 0

POSS 8 8 1 2 1 3 2 1 1

__ -v. y- i T * - » ^ » •kiAk^r~r*t •*. >N. — i_iai iMMiico — y

RMS 1203 81 0 94 0

353 151 0 0

STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6

10:


COMPOUND >< NO LIB ENTRY 1 SV 1 2 SV 2 3 SV 14 4 SV 15 5 SV 16 6 SV 17

REF -399 -589 -256 -381 -366 -378

PRED 401 592 250 376 361 373

SEARCH SEL DELTA PEAKS 403 2 2 591 -1 1

385 9 1

— >< SAT FIT PEAKS 993 984 -1

.

992

X M/Z 152 136 42 94 93 93

-— CHRO TOP DELTA PEAKS 403 1 591 1 250 I 385 1

9 10 11 12 13 4 .5 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 .0 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 b5 66 67 68 69 70 71 72

SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv BV

sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

20 21 22 7 8

23 24 25 26 27 3

28 29 30 31 32 33 34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73

-427 -437 -427 -380 -241 -464 -458 -464 -480 -471 -857 -490 -529 -538 -563 -603 -573 -581 -487 -5B5 -591 -614 -626 -702 -697

-1078 -735 -753 -753 -769 -800 -839 -831 -872 -861 -881 -763 -979 -923 -886 -902 -902 -949 -946 -938

-1357 -1483 -962 -968

-1018 -1033 -1067 -1087 -1087 -1200 -1293 -1689 -1333 -1763 -1293 -1424 -2007 -1486 -1524

422 432 422 384 246 467 461 467 483 474 859 492 531 540 565 605 575 583 490 588 594 617 629 705 700 1080 737 755 755 771 802 841 833 874 863 883 766 983 927 890 906 906 953 950 942 1362 1485 966 972 1021 1036 1070 1090 1090 1203 1295 1691 1335 1765 1295 1426 2009 1488 1526

410 -12

410 -12 383 -1 247 1

•

482 -1

859

, ,

490 588

.

706 1 .

1080 . ,

863

765 -1 983 934 7

, 905 -1 905 -1

,

1485

974 2

1069 -1

1202 -1 1295 1691 1335

1295

^ 1526

2 . 2 2 4

1

1

.

1 1

2

1

.

. 1

1 1 3

1 1

2

1

2

1 1 1 1

1

1

996 ,

995 979 992

974 .

996 .

.

.

. 996 997

969

990 .

.

994

997 998 910

984 892

995

752

979

981 979 991 994

986

O A O

146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142

1 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 1 / l a

411 1

411 1 383 247

482

859

490 588

706

1080

835

863

765 983 934

905 905

1484 -]

974

1069

1202 1295 1691 1335

1295

4 K'n.C

75 76. 77 78 79 0

sv SV sv sv sv sv

76 77 78 79 80 81

-1640 -1680 -1680 -1935 -1890 -1935

1640 1680 1680 1935 1890 1935

252 252 252 276 278 276

Quantitation Report File: 8070023M5D

Data: 8070023MSD. TI 08/11/88 1:43:00 Sample: JOB 807002-3 MATRIX SPIKE DUPLICATE Conds. : GCl Formula: IUL INJECTION Instrument: 1050 Submitted by: Analyst: RGM

AM0UNT=AREA • REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

Weight: Acct. No.

0. 003

No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15

Name ISl IS2 61B 65A 5H 18B 24A 26B 27B 6H 25B SS2 SSI 2H 42B

1,4-DICHL0R0BENZENE-D4 (SVttl) NAPHTHALENE-DB (SVtt2> N-NITROSODIMETHYLAMINE (SVttl4) PHENOL (SVttl5) ANILINE (SVttl6) BIS(2-CHLORaETHYL)ETHER (SVtt17) 2-CHLOROPHENOL (SVttlB) 1,3-DICHLOROBENZENE (SVttl9) 1,4-DICHLOROBENZENE (SVtt20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLOROBENZENE (SVtt22) PHEN0L-D5 (SVtt7) 2-FLUORDPHENOL (SVttB) 2-METHYLPHENOL (SVtt23) BIS(2-CHL0R0IS0PR0PYL>ETHER (SVtt24)

18 19 20 21 22 '3 ci4 25 26 27 2B 29 30 31 32 33 34 35 36 37 38 ,39 40 41 42 43 44 45 46 47

12B I S3 56B 54B 57A 34A IH 43B 31A SS3 8B 55B 7H 52B 22A 9H IS4 53B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SS5 5BA

HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SVtt3) NITROBENZENE (SVtt28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SVtt30) 2,4-DIMETHYLPHENOL (SVtt31) BENZOIC ACID (SVtt32) BIS(2-CHLDROETHOXY)METHANE < SVtt33) 2,4-DICHLOROPHENOL (SVtt34) NITR0BENZENE-D5 (SVtt9) 1,2,4-TRICHLOROBENZENE (SVtt35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SVtt37) HEXACHLOROBUTADIENE (SVtt38) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) 2-METHYLNAPHTHALENE (SVtt40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2,4,6-TRICHLOROPHENOL (SVtt42) 2. 4, 5-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SVtt44) 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SVtt46) ACENAPHTHYLENE (SVtt47) 3-NITRDANILINE (SVtt4B) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SVtt50) 2-FLUOROBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SVtt51)

No Name 48 BH DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITROTOLUENE (SVtt53) 50 36B 2,6-DINITROTOLUENE (SVtt54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

m/z 152 136 42 94

NOT NOT 128 146 146 NOT 146 99 112 NOT NOT NOT 70

NOT 164 NOT NOT

Scan 403 591 250 385

FOUND FOUND

383 411 -AM

FOUND 411 383 247

FOUND FOUND FOUND

482 FOUND

859 FOUND FOUND

Time 6: 9: 4: 6:

6: 6:

,V^ 6: 6: 4:

8:

14:

43 51 10 25

23 51 51

51 23 07

02

19

Ref RRT Meth 1 1. 000 A BV 2 1. 000 A BB 1 0. 620 A BB 1 0. 955 A BB

1 0. 950 A BB 1 1.020 A VB 1 1. 020 A VB

1 1.020 A VB 1 0. 950 A BB 1 0. 613 A BB

1 1. 196 A BV

19 1. 000 A BB

Area(Hght) Amount JiTot 71018. 100. 000 NG/UL 6. 67 351876. 100. 000 NG/UL 6. 67

^ 6 . 51.856 NG/UL 3.46 93566. 56. 089 NG/UL 3. 74 >V7.'

90718. 13567.

-4^567-.

13567. 57323. 32461.

35371.

190829.

66. 291 NG/UL 8. 597 NG/UL 8. 597 NG/UL

8. 597 NG/UL 41. 103 NG/UL 33. 810 NG/UL

42. 302 NG/UL 2. 82

100. 000 NG/UL 6. 67

4. 0. 0.

0. 2. 2.

42 y

57V^^

57 74 26 6i

24 25 26 27 2B ''9 jO 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

NOT NOT NOT 82 180 NOT NOT NOT 107 NOT 188 NOT NOT NOT NOT NOT NOT 152 NOT 153 NOT 172 330 139 NOT 89 165

FOUND FOUND FOUND

490 588

FOUND FOUND FOUND

706 FOUND 1080


835 FOUND

863 FOUND

765 983 934

FOUND 905 905

8: 10 2 0. 829 A BB 9: 48 2 0. 995 A BB

11:46 2 1. 195 A BB

18: 00 34 1. 000 A BB

13: 55 19 O. 972 A BB

14: 23 19 1. 005 A BB

12: 45 19 0. 891 A BB

16: 23 19 1. 144 A BB 15: 34 19 1. 087 A BB

15:05 19 1. 054 A BB 15: 05 19 1. 054 A BB

44563. 49395.

52934.

277077.

239.

91537

111229 9582 5404

12094 22233

37. 726 NG/UL 2. 52 32. 853 NG/UL 2. 19 " ^

44, 928 NG/UL 3. 00 '^

100. 000 NG/UL 6. 67

0. 071 NG/UL 0. 00

56. 203 NG/UL 3. 75 "

44. 291 NG/UL 2. 96 33. 117 NG/UL 2. 21 27. 271 NG/UL 1. B2 ^

32, OBO NG/UL 2. 14^-34. 001 NG/UL 2. 27

Quantitation Report File: 8070023MSD

Data: 8070023MSD. TI 08/11/88 1:43:00 Sample: JOB 807002-3 MATRIX SPIKE DUPLICATE Conds. : GCl Formula: IUL INJECTION Instrument: 1050 Submitted by: Analyst: RGM

AM0UNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

DIETHYL PHTHALATE (SVtt55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SVtt57) 4-NITROANILINE (SVttSB) CHRYSENE-D12 (SVtt5) 2-METHYL-4,6-DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SVtt61> HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63) PHENANTHRENE (SVtt64> ANTHRACENE (SVtt65> DI-N-BUTYL PHTHALATE (SVtt66) FLUORANTHENE (SVtt67) PERYLENE-D12 (SVtt6)

Weight: Acct. No.

0. 003

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65

Name 70B 40B BOB 12H 185 60A 62B 41B 9B 64A BIB 78B 68B 39B 186

68' 84B PYRENE (SV#69) 69 6*78 BUTYL BENZYL PHTHALATE (SVtt70)

28B 3,3'-DICHL0R0BENZIDINE (SVtt71) 72B BENZO(A)ANTHRACENE (SVtt72) 66B BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) 76B CHRYSENE (SVtt74> 69B DI-N-OCTYL PHTHALATE (SVtt75) 74B BENZO(B)FLUORANTHENE (SVtt76> 74B BENZO(K)FLUORANTHENE (SVtt77) 73B BENZO(A)PYRENE (SVtt78) B3B INDENOd, 2, 3-CD)PYRENE (SVtt79) 82B DIQENZO(A,H)ANTHRACENE (SVttSO) 79B BENZO(G,H, DPERYLENE (SVttBl)

70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63

m/z Scan NOT FOUND NOT FOUND NOT FOUND NOT FOUND 240 1484 NOT FOUND 169 974 NOT FOUND NOT FOUND 266 1069 NOT FOUND NOT FOUND 149 1202

Time Ref RRT Meth

24: 44 55 1. 000 A BB

16: 14 34 0. 902 A BQ

17:49 34 0. 990 A BB

20:02 34 1. 113 A VB

Area(Hght) Amount r.Tot

146098. 100. 000 NG/UL 6. 67

522. 0. 428 NG/UL 0. 03

17494. 53. 520 NG/UL 3. 57

118279. 57.666 NO/UL 3.85

No 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 NOT NOT NOT 149 NOT NOT NOT NOT NOT NOT NOT NOT

Scan 1295 1691 1335

FOUND 1295

FOUND FOUND FOUND 1526

FOUND FOUND FOUND FOUND FOUND FOUND FOUND FOUND

Time 21: 28: 22:

21

25

35 11 15

35

26

Ref 34 65 55

55

55

1. 1. 0.

0.

1

RRT 199 000 900

873

028

Meth A A A

A

A

BB BB BB

BB

BQ

Area(Hght) 103498. 120900. 81217.

103498.

3754.

Amount r.Tot 52. 904 NG/UL 3. 53 100. 000 NG/UL 6. 67 49. 824 NG/UL 3. 33

53. 081 NG/UL 3. 54

3. 517 NG/UL 0. 23

AjS AnalyticalTechnologies, Inc

/7«r/^ :S/ia/,i

" p i i d - S U A ~l>ijuf>.

ACCESSION: 807002

QUALITY CONTROL DATA: 482-3 & 985 METHOD 625 & 8270

CLIENT: MONTGOMERY & ASSOCIATES UNITS: UG/L ANALYSIS DATE: 8/5/88

1,4-DICHLOROBENZENE BIS (2-CHLOROISOPROPYL) ETHER HEXACHLOROETHANE NITROBENZENE NAPHTHALENE DIMETHYLPHTHALATE ACENAPHTHENE FLUORENE 4-CHLOROPHENYL PHENYL ETHER 4-BROMOPHENYL PHENYL ETHER ANTHRACENE FLUORANTHENE BUTYLBENZYLPHTHALATE CHRYSENE BIS (2-ETHYLHEXYL) PHTHALATE BENZO (b) FLUORANTHENE BENZO (a) PYRENE DIBENZO (a,h) ANTHRACENE BENZO (g,h,i) PERYLENE PHENOL 2-CHLOROPHENOL 2-NITROPHENOL 2,4-DIMETHYLPHENOL 2,4-DICHLOROPHENOL 4-CHLORO-3-METHYLPHENOL 2,4,5-TRICHLOROPHENOL 4-NITROPHENOL 2-METHYL-4,6-DINITROPHENOL PENTACHLOROPHENOL

FOUND

24 42 30 45 21 32 17 42 73 42 29 22 48 83 27 32 20 33 76 75 90 79 85 68 72 110 98 25 92

ACTUAL

2 5 3 9 3 0 7 6 2 5 4 0 2 0 5 1 7 6 4 2 4 0 3 0 5 1 7 0 2 9 4 0 2 5 4 1 8 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0

a ^ c

^6 / O t

/oe>

^9 SI go i s

xz <?i j e t ,

73 73 ^y / /f f j

fft

t£> •?t>

#r 75-

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7 ^

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^ i

xsr QZ

PROJECT MANAGER: <<7u^ DATE: 8/18/88

RIC 08/05/88 14:10:00 SAMPLE rpC 8/05/88 1-F482-3+UP385 1:1 COHDS.: GC5 RANGE: G

DATA: QC805 tl CALI: QC805 #2

SCAN: 1 TO 2300

1..2300 LABEL: N 0.- 4.8 QUAN: A 8.. 1.8 J 8 BASE: U 28.. 3 100.0n 23384?

RIC

hJL. ^ H L LJ 500 8:20

T 1000 16:40

-r—"-r t 1500 25:00

iX -1-' 2000 33:20

SCAN TINE

F'ROCEDURE DATA FILE "EFERENCE . ME LIST REPORT

DIAGNOSTIC REPORT TCA QC805 QC805 Kl INITIALIZATION OPTION: XI

B/03/88 14: 47; 34


: STANDARDS PROC USED POSS

2

><

2 2 2 2 2 2 2 2 1 2 2 2 2 2 2 2 2 1 2 2 2 2

2 2 2 2 2 2 2 6 2 2 2 2 2 2 2 2 10 2 2 2 2 2 2 2

RMS 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

PLUS UNKNOWNS PROC USED POSS

7 2

X

11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

4 6 4 6 4 7 6 4 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

RMS 1184 48

214 183 480 81 252 268 232 883 39 162 99 304 42 189 190 147 883 39 162 99

304 42 189

: - LIST NAMES - : STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4

80 COMPOUNDS PROCESSED, 38 FOUND

COMPOUND >< NO LIB ENTRY REF 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23

SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv

1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31

-415 -600 -256 -398 -382 -393 -396 -408 •-417 -451 -442 -397 -263 -480 -471 -503 -493 -485 -864 -503 -541 -550 -575

PRED 418 602 262 401 385 396 399 410 419 452 444 400 S67 483 474 505 495 488 866 506 544 553 578

- SEARCH — SEL DELTA 418 602

406

, 401 420 420

420

,

474 .

487 866 505

,

553 578

5

, 2 10 1

-24

, ,

-1 ,

-1 .

,

PEAKS 1 1 .

2

1 1 1

1

1 . .

1 1 1

1 1

>< SAT ><: FIT PEAKS M/Z 981 979

987

987 985 990

987

938

955 986 957

961 993

152 136 42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122

CHRO TOP DELTA PEAKS 418 602

406

401 420 420

420 401

474

487 866 505 545 553 578

1 1

1

1

1 1

1 1

1

1 1 1 1 1 1

26 27 28 29 30 31 .2 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 7 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

SV SV SV SV SV SV SV SV SV SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

34 9

35 36 37 38 39 40 4

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-595 -500 -596 -602 -628 -636 -713 -707

-1084 -744 -761 -773 -778 -809 -847 -839 -881 -868 -891 -772 -986 -940 -893 -853 -909 -956 -953 -945

-1337 -1486 -970 -975

-1025 -1039 -1074 -1087 -1093 -1205 -1266 -1692 -1337 -1763 -1297 -1427 -2007 -1483 -1527 -1489 -1616 -1643 -1643 -1683 -1886 -1898 -1942

598 503 599 605 631 639 716 710 1085 743 760 772 777 808 847 839 881 868 891 775 988 942 895 856 911 958 955 947 1337 1487 974 979 1028 1042 1077 1090 1096 1207 1268 1694 1339 1765 1299 1429 2009 1485 1529 1491 1616 1643 1643 1683 1886 1898 1942

602

604 , .

718 ,

1085 ,

764 764

848

870

956 947

, 1487

, 1027

1077 1095 1095

1268 1694

.

, 1428

, 1490 1528 1490

1642 1642 1686

1942

4

-1

2

4 -8

2

1

-1

5 -1

-1

5 -1 -1

-1 -1 3 . . ,

1

1

1

1

1 1

1

1

1 1

1

1

1 1 1

1 1

1

1 1 1 . 1 1 1

1

827

996

978

951

995 985

998

994

,

967 991

. 928

981

987 983 983

973 932

989

958 977 956

862 937 894

899

162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

600 -2 1

604

717 -1

1085

764 764

848

870

955 947

1487 975

1027

1077 1095 1095 1206 1268 1694

1301 1428

1490 1528 1490

1642 1642 1686

1942

4 1

L 1

1

1 1

1

1

1

Quantitation Report File: QCB05

lta: QC805. TI 3/05/88 14: 10: 00

Sample: QC 8/05/88 WP4B2-3+WP985 1:1 Conds. : GC5 Formula: Instrument: 1050 Submitted by: Analyst: RGM

Weight: Acct. No.

50. 000

AM0UNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 b6 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63

Name 70B 40B BOB 12H IS5 60A 62B 41B 9B 64A BIB 78B 68B 39B IS6 SS6 5B 84B 67B 28Q 72Q 66B 76B 69Q 74Q 74Q 73B 838 82B 79B

m/z NOT 204 166 NOT 240 198 NOT 248 NOT 266 178 178 149

DIETHYL PHTHALATE (SVtt55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SVtt57) 4-NITROANILINE (SVtt5B) CHRYSENE-D12 (SVtt5) 2-METHYL-4,6-DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SVtt61) HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE (SVtt65) DI-N-BUTYL PHTHALATE (SVtt66) FLUORANTHENE (SVtt67) PERYLENE-D12 (SVtt6) TERPHENYL-D14 (SVttl2) BENZIDINE (SVtt68) PYRENE (SVtt69) BUTYL BENZYL PHTHALATE 3,3'-DICHL0R0BENZIDINE

(SVtt70) (SVtt71)

BENZO(A)ANTHRACENE (SVtt72) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SVtt74) DI-N-OCTYL PHTHALATE (SVtt75) BENZO(B)FLUORANTHENE (SVtt76) BENZO(K)FLUORANTHENE (SVtt77) BENZO(A)PYRENE (SVtt7B) INDENOd, 2, 3-CD)PYRENE DIBENZO(A,H)ANTHRACENE

(SVtt79) (SVttBO)

BENZO(G,H, DPERYLENE (SVttBl)

Scan Time Ref RRT FOUND

955 15: 55 19 1. 103 947 15:47 19 1.094

FOUND 1487 24:47 55 1.000 975 16: 15 34 0. 899

FOUND 1027 17:07 34 0.947

FOUND 1077 17:57 34 0. 993 1095 18: 15 34 1. 009 1095 18: 15 34 1. 009 1206 20:06 34 1. 112

Meth

A BQ A BQ

A BQ A BB

A BB

A BB A BB A BB A BB

Area(Hght)

25539. 28746.

110093. 1030.

8519.

8880. 27714. 27714.

873.

Amount

36. 20.

100. 12.

21.

46. 14. 14. 0.

773 954

000 288

090

194 678 968 664

NG/UL NG/UL

NG/UL NG/UL

NG/UL

NG/UL NC/UL NG/UL NG/UL

XTot

2. 1.

7. 0.

1.

3. 1. 1. 0.

67 52

25 89

53

35 06 09 05

15'V 4^

^'"'

4i ' ^ ..... y 9Z, ^

9 T

No Name 48 8H DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITROTOLUENE (SVtt53) 50 36B 2,6-DINITROTOLUENE (SVtt54)

Mo 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 IS 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46

48 49 50

m/z Scan 152 418 136 602 NOT FOUND 94 406

NOT FOUND NOT FOUND 128 401 146 420 146 420 NOT FOUND 146 420 99 401

NOT FOUND NOT FOUND 45 474

NOT FOUND NOT FOUND 117 487 164 866 77 505 82 545 139 553 122 578 NOT FOUND NOT FOUND 162 600 NOT FOUND NOT FOUND 128 604 NOT FOUND NOT FOUND 107 717 NOT FOUND IBB 1085 NOT FOUND 196 764 196 764 NOT FOUND NOT FOUND 163 848 NOT FOUND NOT FOUND 153 870 NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND NOT FOUND

Time 6: 58

•10:02

6: 46

6: 41 7:00 7:00

7:00 6: 41

7: 54

8: 07 14:26 8: 25 9:05 9: 13 9: 38

10:00

10:04

11: 57

18: 05

12:44 12: 44

14:08

14: 30

K'h^ ®

Ref 1 2

1

1 1 1

1 1

1

1 19 2 2 2 2

2

2

2

34

19 19

19

19

< \ ^ ^

1. 1.

0.

0. 1. 1.

1. 0.

1.

1. 1. 0. 0. 0. 0.

0

1

1

1

0 0

0

1

RRT 000 000

971

959 005 005

005 959

134

165 000 839 905 919 960

997

003

191

000

882 882

. 979

. 005

Meth A BB A BB

A BB

A QB A BQ A BB

A BQ A BB

A BB

A BB A BB A BB A BB A BB A BB

A BB

A BB

A BB

A QQ

A BB A BB

A BB

A BB

Area(Hght) 53594.

197642.

18712.

23916. 13367. 13367.

13367. 1369.

23599.

4966. 102380. 22048.

468. 9887. 17905.

14117.

22679.

15727.

172507.

15175. 15175.

21519.

7990.

Vl

Amount 100. 000 100. 000

37. 344

44. 9B4 11. 954 12. 210

12. 922 2. 264

20. 826

15. 084 100. 000 22. 612 0. 289

39. 641 42. 314

33. 930

10. 390

36. 019

100. 000

55. 104 45. 489

16. 126

8. 709

NG/UL NG/UL

NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

NG/UL

NG/UL

NG/UL

NG/UL

NG/UL NG/UL

NG/UL

NG/UL

r.Tot 7. 25 7. 25

2. 71

3. 26 0. 87 0. 89

0. 94 0. 16

1. 51

1. 09 7. 25 1. 64 0. 02 2. SB 3. 07

2. 46

0 75

2. 61

7. 25

4. 00 3. 30

1. 17

0. 63

' \ ' ^

15^

qo/ -7^ 24^

i

\ ^ ^

-»« l y ^

20 ^ J -

H /

' ^ . y g& ^

Ub/

1 y %>>

% ^

lio

, y '

i v "

\ 1 ^

'

Quantitation Report File: QC805

ta: QCB05. TI -J/05/B8 14: 10: 00 Sample: QC 8/05/88 WP482-3+WP985 1:1 Conds. : GC5 Formula: Instrument: 1050 Weight: 50. 000 Submitted by: Analyst: RGM Acct. No. :

AM0UNT=AREA * REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

1,4-DICHL0R0BENZENE-D4 (SVttl) NAPHTHALENE-DB (SVtt2) N-NITROSODIMETHYLAMINE (SVttl4) PHENOL (SVttl5) ANILINE (SVttl6) BIS(2-CHLOROETHYL)ETHER (SVtt17) 2-CHLOROPHENOL (SVttlB) 1,3-DICHLOROBENZENE (SVttl9) 1,4-DICHLOROBENZENE (SVtt20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLOROBENZENE (SVtt22) PHEN0L-D5 (SVtt7) 2-FLUOROPHENOL (SVttB) 2-METHYLPHENOL (SVtt23) BIS(2-CHLOROISOPROPYL)ETHER (SVtt24) 4-METHYLPHENOL (SVtt25) N-NITROSO-DI-N-PROPYLAMINE (SVtt26) HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SVtt3) NITROBENZENE (SVtt28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SVtt30) 2,4-DIMETHYLPHENOL (SVtt31) BENZOIC ACID (SVtt32) BIS(2-CHLOROETHOXY)METHANE (SVtt33) 2,4-DICHLOROPHENOL (SVtt34) NITR0BENZENE-D5 (SVtt9) 1,2,4-TRICHLOROBENZENE (SVtt35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SVtt37) HEXACHLOROBUTADIENE (SVtt3B) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) 2-METHYLNAPHTHALENE (SVtt40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2, 4, 6-TRICHLOROPHENOL (SVtt42) 2,4,5-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SVtt44> 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SVtt46) ACENAPHTHYLENE (SVtt47) 3-NITROANILINE (SVtt48) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SVtt50) 2-FLUORDBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SVtt51)

Mo 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl IS2 61B 65A 5H 18B 24A 26B 27B 6H 25B SS2 SSI 2H 42B 4H 63B 12B I S3 56B 54B 57A 34A IH 43Q 31A SSS BQ 55Q 7H 52B 22A 9H IS4 53Q 21A 4H 20Q lOH 71B 77B IIH IB 59A SS4 SS5 5BA

No 4

o5 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 NOT NOT 202 149 NOT 228 149 228 NOT 252 252 252 NOT NOT 276

Scan 1268 1694

FOUND FOUND 1301 1428

FOUND 1490 1528 1490

FOUND 1642 1642 1686

FOUND FOUND 1942

Time 21: 08 28: 14

21: 41 23: 48

24: 50 25:28 24: 50

27: 22 27: 22 28: 06

^ n d 32: 22

Ref 34 65

55 55

55 55 55

65 65 65

\ ^ 0 65

1. 1.

0. 0.

1. 1. 1.

0. 0. 0.

!> 1.

RRT 169 000

875 960

002 028 002

969 969 995

146

Me A A

A A

A A A

A A A

A

>th BB BB

BB BB

BB BB BB

BB BB BB

BB

Area(Hght) 16753.

114947.

276. 7527.

38973. 5811.

38973.

19135. 19135. 10319.

\\ "fCÔ 27993.

Amount 11. 117

100. 000

0. 218 24. 002

32. 113 13. 254 41. 421

8. 204 8. 204 9. 753

37. 795

NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL

NG/UL NG/UL NG/UL

^ ^

NG/UL

XTot 0. 81 1-' 7. 25

0. 02 1. 74

2. 33 IM 0. 96 a1 3. 00 <l>

0. 60 \^ 0. 60 0.71 1^

/ AL

2.74 "^

l ^

^ / "^ ^Zs-P

DATA: 88M3B2647 #1 CALI: 8SM3B2647 #2

SCANS 300 TO 2G00 RIC 08/10/88 22:37:00 SftHPLE: 50/80NG BHA STD COHDS.; HJL "' RAHGE: G 1,2680 LABEL: H 0, 4.0 QUAH: A 0.. 1.0 J 0 BASE: U 20, 3

100.0-1 664576.

RIC

J' I'd u /I IA. 1 ll

500 P!70

1 1080 16:40

U VJUJ Lu. • I u VJV,

1500 25:00

r 2000 33:20

UJ L „ 2500 41; .18

jantitation Report File: 88M3B2647

i t a : 88M3B2647. TI 3/10/88 22:37: 00 a m p l e : 50/aONG BNA STD j n d s . : I U L tandard ID: 2-BNA-7-1B Instrument: 5100 snsitivity ID: 2646 Analyst: RJT Inst Cali:

iOUNT=AReA » REF AMNT/(REF AREA * RESP FACT) fac. from Library Entry

NAME 151 1,4-DICHL0R0BENZENE-D4 (SVttl) 152 NAPHTHALENE-D8 (SVtt2) 153 ACENAPHTHENE-DIO <SV»3) 154 PHENANTHRENE-DIO (SVtt4) 155 CHRYSENE-D12 (SVtt5) 156 PERYLENE-D12 (SVtt6) 552 PHENaL-D5 (SV«7) SSI 2-FLUOROPHENOL (SVttB) 553 NITR0BENZENE-D5 (SVtt9) 554 2-FLUOROBIPHENYL (SVttlO) 555 2.4, 6-TRIBROMOPHENOL (SVttll) 556 TERPHENYL-D14 (SVtt12) 6IB N-NITROSODIMETHYLAMINE (SVttl4) 65A PHENOL (SVttlS) 5H ANILINE (SVttl6) 18B BIS(2-CHLOROETHYL)ETHER (SVtt17) 24A 2-CHLOROPHENOL (SVttlB) 26B 1,3-DICHLOROBENZENE (SVttl9) 27B 1,4-DICHLOROBENZENE (SV«20) 6H BENZYL ALCOHOL (SVtt21) 25B 1,2-DICHLOROBENZENE (SVtt22) 2H 2-METHYLPHENOL (SV«23) 42B BIS(2-CHLOROISOPROPYL)ETHER (SVtt24) 4H 4-METHYLPHENOL (SVtt25) 63B N-NITROSO-DI-N-PROPYLAMINE (SVtt26) 12B HEXACHLOROETHANE (SVtt27> S6B NITROBENZENE (SVtt28) 54B ISOPHORONE (SVtt29) S7A 2-NITROPHENOL (SVtt30) 34A 2,4-DIMETHYLPHENOL (SVtt31) IH BENZOIC ACID (SVtt32) 43B BIS(2-CHLOROETHOXY)METHANE (SVtt33) 31A 2,4-DICHLOROPHENOL (SVtt34) BB 1,2,4-TRICHLOROBENZENE (SVtt35) SSB NAPHTHALENE (SVtt36) 7H 4-CHLDROANILINE (SVtt37) 52B HEXACHLOROBUTADIENE (SVtt38) 22A 4-CHLDRD-3-METHYLPHEN0L (SVtt39) 9H 2-METHYLNAPHTHALENE (SVtt40) 53B HEXACHLOROCYCLOPENTADIENE (SVtt41) 21A 2,4,6-TRICHLOROPHENOL (SVtt42) 4H 2,4,5-TRICHLDRDPHENOL (SVtt43) 20B 2-CHLORONAPHTHALENE (SVtt44) lOH 2-NITRDANILINE (SV«4S) 7 IB DIMETHYL PHTHALATE (SVtt46) 77B ACENAPHTHYLENE (SVtt47) IIH 3-NITRDANILINE (SVtt48) IB ACENAPHTHENE (SVtt49) S9A 2,4-DINITROPHENOL (SVttSO) SBA 4-NITROPHENOL (SVttSl)

m/z 152 136 164 188 240 264 99 112 82 172 330 244 42 94 93 93 128 146 146 108 146 108 45 108 70 117 77 82 139 122 122 93 162 180 128 127 225 107 142 237 196 196 162 65 163 152 138 153 184 139

Scan 673 894 1219 1494 1998 2247 640 483 773 1102 1369 1809 283 642 630 645 646 666 676 710 706 739 738 765 762 758 777 822 833 855 898 870 878 890 898 924 938 1017 1025 1070 1086 1093 1112 1144 1192 1189 1144 1225 1241 1268

Time 11: 13 14: 54 20: 19 24: 54 33: 18 37:27 10: 40 8:03 12: 53 18:22 22: 49 30: 09 4: 43 10: 42 10:30 10: 45 10: 46 11: 06 11: 16 11: 50 11: 46 12: 19 12: 18 12: 45 12: 42 12:38 12: 57 13:42 13: 53 14: 15 14: 58 14:30 14:38 14: 50 14: 58 15:24 15:38 16: 57 17:05 17: 50 18:06 18: 13 18:32 19:04 19: 52 19: 49 19:04 20:25 20:41 21:08

Ref 1 2 3 4 5 6 1 1 2 3 3 5

2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3

RRT 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 0. 718 0. 865 0. 904 1. 123 0. 905 0. 421 0. 954 0. 936 0. 958 0. 960 0. 990 1. 004 1. 055 1. 049 1. 098 1. 097 1. 137 1. 132 1. 126 0. 869 0. 919 0. 932 0. 956 1. 004 0. 973 0. 982 0. 996 1. 004 1. 034 1. 049 1. 138 1. 147 0. 878 0. 891 ' 0. 897 0. 912 0. 938 0. 978 0. 975 0. 938 1. 005 1. 018 1. 040

Meth A BB A BD A' BB A BV A QQ A QQ A BB A BB A QQ A BB A BB A BB A BB A BQ A QV A VB A QB A BV A VB A QQ A QQ A QQ A QQ A BB A QV A BQ A VB A QV A QQ A BB A QQ A QV A QQ A QQ A QB A QB A BB A QB A VB A QB M XX A VB A BB A QB A BB A BB A QB A QB A QV A BB

Area(Hght) 88930.

358628. 211617. 348336. 241414. 89276. 121189. 68867. 156647. 193838. 41664.

223608. 36965. 164279. 69024. 175485. 120928. 139112. 143100. 54354. 129571. 110225. 259727. 114623. 125053. 72413. 195978. 325249. 59453. 94943. 78072. 197554. 97228. 115975. 370777. 40973. 72955. 127863. 237298. 45634. 64988. 97634.

221915. 90388. 269398. 297278. 64289.

246542. 38206. 53321.

Amount 40.000 NG/UL 40.000 NG/UL 40.000 NG/UL 40.000 NG/UL 40.000 NO/UL 40.000 NO/UL 50. 000 NG/UL 50.000 NO/UL 50.000 NG/UL 50.000 NO/UL 50.000 NG/UL 50.000 NG/UL SO. 000 NO/UL SO. 000 NG/UL SO.000 NO/UL SO.000 NG/UL SO. 000 NO/UL 50. 000 NG/UL SO. 000 NO/UL SO. 000 NG/UL SO.000 NG/UL SO. 000 NG/UL SO.000 NG/UL SO. 000 NO/UL 50.000 NO/UL SO.000 NG/UL SO. 000 NG/UL SO.000 NG/UL SO. 000 NG/UL SO.000 NG/UL 80.000 NG/UL SO.000 NO/UL SO. 000 NG/UL SO. 000 NG/UL SO. 000 NG/UL SO. 000 NG/UL SO. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 80. 000 NG/UL 50. 000 NO/UL 80. 000 NO/UL 50. 000 NG/UL 50.000 NG/UL 80. 000 NO/UL 50. 000 NG/UL 80. 000 NG/UL SO. 000 NO/UL

•/.Tot 0. 87 0. 87 0. 87 0. 87 0. 87 0. 87 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 73 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. 08 1. OS 1. 08 1. 08 1. 73 1. 08 1. 73 1. 08 1. 08 1. 73 1. 08 1. 73 1. 73

No 1 2 3 4 5 6 7 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3 0 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 SO

Ret(L) 11: 13 14: 54 20: 19 24: 54 33: 18 37:27 10:40 8:03 12: 53 18:22 22:49 30:09 4: 43 10:42 10:30 10:43 10:46 11:06 11: 16 11: SO 11:46 12: 19 12: 18 12:45 12:42 12:38 12: 57 13:42 13: 53 14: 15 14: 58 14:30 14:38 14: 50 14:58 15:24 15:38 16:57 17:05 17: 50 18:06 18: 13 18:32 19:04 19: 52 19:49 19:04 20:25 20:41 21:08

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 0 0 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 0 0 1. 00 1.00 1. 00 1. 00 1.00 1.00 1. 00 1. 00 1. 00

RRT(L) I. 000 1. 000 1. 000 1. 000 1. 000 1. 000 0. 951 0. 718 0. 865 0. 904 1. 123 0. 905 0. 421 0. 954 0. 936 0. 958 0. 960 0. 990 1. 004 1. 055 1. 049 1. 098 1. 097 1. 137 1. 132 1. 126 0. 869 0. 919 0. 932 0. 956 1. 004 0. 973 0. 982 0. 996 1. 004 1. 034 1. 049 1. 138 1. 147 0. 878 0. 891 0. 897 0. 912 0. 938 0. 978 0. 975 0. 938 1. 005 1. 018 1. 040

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

Amnt 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 SO. 00 50. 00 SO. 00 50.00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 50. 00 80. 00 SO. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 SO. 00 80. 00 SO. 00 80. 00 50. 00 SO. 00 80.00 50. 00 80. 00 80. 00

Amnt(L) 40. 00 40. 00 40. 00 40. 00 40. 00 40. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50.00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 50. 00 80.00 SO. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 80.00 50. 00 50. 00 80. 00 50. 00 80. 00 80. 00

R. Fac R. 1.000 1. 000 1. 000 1. 000 1. 000 1.000 1.090 0. 620 0.349 0.733 0. 158 0. 741 0.333 1.478 0. 621 1. 379 1.088 1.251 1.287 0. 489 1. 166 0. 992 2.336 1. 031 1. 125 0. 651 0.437 0. 726 0. 133 0.212 0. 109 0. 441 0.217 0. 259 0. 827 0.091 0. 163 0. 285 0. 529 0. 173 0.246 0.231 0. 839 0.214 1.018 1. 124 0. 152 0. 932 0.090 0. 126

,Fac(L) 1. 000 1. 000 1. 000 1. 000 1. 000 1. 000 1. 090 0. 620 0. 349 0. 733 0. 158 0. 741 0. 333 1. 478 0. 621 1. 579 1. 088 1. 251 1.287 0. 489 1. 166 0. 992 2.336 1. 031 1. 125 0. 651 0. 437 0. 726 0. 133 0. 212 0. 109 0. 441 0. 217 0. 259 0. 827 0. 091 0. 163 0. 285 0. 529 0. 173 0. 246 0. 231 0. 839 0. 214 1. 018 1. 124 0. 152 0. 932 0. 090 0. 126

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1.00 1. 00 1. 00 1. 00 1. 00

i u a n t i t a t i o n R e p o r t F i l e : 88M3B2647

l a t a : 8SM3B,2647. TI ' 8 / 1 0 / 8 8 2 2 : 37 : 00 ; a m p l e : 50 /80NG BNA STD : o n d s . : IUL I t a n d a r d ID: 2 -BNA-7-1B ' i e n s i t i v i t y ID: 2 6 4 6

I n s t r u m e n t : 5 1 0 0 A n a l y s t : RJT I n s t C a l i

tM0UNT=AREA • REF AMNT/(REF lesp. NO 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69

fac. NAME BH 35B 36B 70B 40B SOB 12H 60A 62B 41B 9B 64A BIB 78B 68B 39B SB 84B 67B 28B 72B 66B 76B 69B 74B 74B 73B 83B 82B 79B

ffl/z

168 89 165 149 204 166 138 198 169 248 284 266 178 178 149 202 NOT 202 149

from Librar\j

DIBENZOFURAN 2,4-1 2, 6-1

• AREA » RESP FACT) 1 Entry

(SVtt52) DINITROTOLUENE (SVtt53) DINITROTOLUENE (SVtt54)

DIETHYL PHTHALATE (SVttSS) 4-CHLORDPHENYLPHENYL ETHER (SVtt56) FLUORENE (SV«S7] 1 4-NITROANILINE (SVttSB) 2-METHYL-4, 6--DINITROPHENOL (SVtt59) N-NITRDSDDIPHENYLAMINE (SVtt60) 4-BROMDPHENYLPHENYL ETHER HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE (SVtt6S) DI-N'

(SVtt61)

-BUTYL PHTHALATE (SVtt66) FLUDRANTHENE (SVtt67) BENZIDINE (SVtt68) PYRENE (SVtt69) BUTYL BENZYL 3,3'

PHTHALATE -DICHLOROBENZIDINE

(SVtt70) (SVtt71)

BENZO(A)ANTHRACENE (SVtt7S I) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SVtt74; DI-N-

I -OCTYL PHTHALATE (SVtt75)

BENZO(B)FLUORANTHENE (SVtt76) BENZO(K)FLUORANTHENE (SVtt77) BENZD(A)PYRENE i INDENOd, 2, 3-

[SVtt78) -CD)PYRENE

DIBENZO(A, H)ANTHRACENE (SVtt79) (SVttBO)

BENZO(G,H, DPERYLENE (SVttBl)

Scan 1256 1271 1200 1328 1328 1320 1346 1346 1353 1418 1439 1477 1498 1506 1639 1723

FOUND 1763 1919

Time Ref 20: S6 21: 11 20:00 22:08 22:08 22:00 22:26 22:26 22:33 23:38 23: 59 24:37 24: 58 25:06 27: 19 28: 43

29:23 31: 59

3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4

5 5

RRT 1. 030 1. 043 0. 984 1. 089 1. 089 1.083 1. 104 0.901 0. 906 0. 949 0. 963 0. 989 1. 003 1. 008 1. 097 1. 133

0. 882 0. 960

Me A A A A A A A A A A A A A A A A

A A

fth BB BB BB BV BB BV BQ BB BB BB BB BB BV VB QV QV

QQ QB

Area(Hght) 342028. 77272. 58553.

296901. 124904. 253497. 14108. 59753. 75222. 79254. 115498. 75228. 360211. 362624. 364579. 351359.

355765. 98593.

Amount 30. 50. 30. 30. 30. 30. 80. 80. 30. 50. 30. 80. 30. 30. 30. 30.

30. 30.

000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000

000 000

NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NO/UL NO/UL NG/UL NG/UL NG/UL NG/UL

NG/UL NG/UL

7.Tot 08 08 08 08 08 08 73 73 08 08 08 73 ,08 08 08 08

08 08

73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

228 149 252 252 252 276 278 276

2002 2152 2187 2191 2238 2445 2451 2499

33:22 35: 52 36: 27 36:31 37: 18 40: 45 40: 51 41: 39

5 6 6 6 6 6 6 6

Ret(L) 20: 56 21: 11 20: 00 22: 08 22: 08 22:00 22:26 22:26 22: 33 23: 38 23: 59 24:37 24: 58 25:06 27: 19 28: 43 29: 25 29:23 31: 59 31: 59 33: 14 34:02 33: 22 35: 52 36:27 36:31 37: 18 40: 45 40: 51 41:39

Ratio 1. 00 1. 00 1; 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 030 1. 043 0. 984 1. 089 1. 089 1. 083 1. 104 0. 901 0. 906 0. 949 0. 963 0. 989 1. 1. 1. 1. 0. 0. 0.

003 008 097 153 883 882 960

0. 960 0. 998 1. 022 1. 002 0. 958 0. 973 0. 975 0. 996 1. 088 1. 091 1. 112

1. 002 0. 958 0. 973 0. 975 0. 996 1. 088 1. 091 1. 112

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 00 00 00

1. 00 1. 00 1. 00

VB BQ BV VB BB QV BB QB

00 00

Amnt 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 80. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00

50. 00 50. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 SO. 00 SO. 00 50. 00 50. 00 50. 00 50. 00

245065. 212601. 197973. 189083. 157507. 125364. 122998. 123093.

Amnt(L) 50. 00 50. 00 50. 00 50: 00 50. 00 50. 00 80. 00 80. 00 SO. 00 50. 00 50. 00 80. 00 50. 00 SO. 00 50. 00 50. 00

50. 00 50. 00 50. 00 50. 00 SO. 00 50. 00 SO. 00 SO. 00 SO. 00 50. 00 50. 00 SO. 00 SO. 00

30. 000 SO. 000 so. 000 50. 000 50. 000 50.000 50. 000 50. 000

R. Fac 1. 293 0. 292 0. 221 1. 122 6. 472 0. 958 0. 033 0. 086 0. 173 0. 182

265 108 827 833 837 807

R.

0. 0. 0. 0. 0. 0.

1. 179 0. 327 0. 016 0. 791 0. 502 0. 812 1. 905 1. 774 1. 694 1. 411 1. 123 1. 102 1. 103

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

Fac(L) 1. 293 0. 292

221 122 472

0. 958 0. 033

086 173 182 265

0. 108 0. 827 0. 833 0. 837 0. 807

1. 179 0. 327 0. 016 0. 791 0. 502 0. 812 1. 905 1. 774 1. 694 1. 411 1. 123 1. 102 1. 103

0. 1. 0.

0. 0. 0. 0.

08 08 08

1. 08 1. 08 1.09 1. 08 1.08

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

00 00 00 00 00

1. 00 1. 00 1. 00 1. 00 1.00 1. 00 1. 00 1. 00

CONTINUING CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDS ( PAGE 1 )

CASE NO: 7287 LABORATORY ID: ATI CONTRACT NO: -INSTRUMENT ID: 5100 SENSITIVITY ID: 2646

STANDARD DATE: 08/10/88 TIME: 22:37:00 STANDARD ID: 88M3B2647 CALIBRATION DATE: 06/21/88

* MAXIMUM r.D FOR CCC IS 257. ** MINIMUM AVE RRF FDR SPCC IS 0. 05

COMPOUND AVE RRF RFSO 7.D

N-NITROSDDIMETHYLAMINE (SVttl4 PHENOL (SVttlS) ANILINE (SV«16) BIS(2-CHLOROETHYL)ETHER (SVttl 2-CHLOROPHENDL (SVttlB) 1,3-DICHLOROBENZENE (SV»19) 1,4-DICHLDROBENZENE (SVtt20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLOROBENZENE (SVtt22) 2-METHYLPHENOL (SVtt23) BIS(2-CHLDR0IS0PR0PYL)ETHER ( 4-METHYLPHENOL (SVtt25) N-NITROSO-DI-N-PROPYLAMINE (S HEXACHLOROETHANE (SVtt27) NITROBENZENE (SVtt28) ISOPHORONE (SVtt29) 2-NITROPHENDL (SV#30) 2,4-DIMETHYLPHENOL (SVtt31) BENZOIC ACID (SVtt32) BIS(2-CHL0R0ETHDXY)METHANE (S 2, 4-DICHLOROPHENOL (SVtt34) 1, 2, 4-TRICHLOROBENZENE (SVtt35 NAPHTHALENE (SV»36) 4-CHLOROANILINE (SVtt37) HEXACHLOROBUTADIENE (SVtt38) 4-CHL0R0-3-METHYLPHEN0L (SVtt3 2-METHYLNAPHTHALENE (SV*40> HEXACHLOROCYCLOPENTADIENE (SV

0. 519 1. 557 1. 126 1. 752 1. 160 1. 419 1. 547 0. 672 1. 438

147 476 097 199 689 460 762 143 266 088 514 228 321 014 152 215

0. 369 0. 901 0. 152

1. 2. 1. 1. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0.

0. 333 1. 478 0. 621 1. 579 1. 088 1. 251 1. 287 0. 489 1. 166 0. 992 2. 336

031 125 651 437

0. 726 0. 133 0. 212 0-068-»«o1 0. 441 0. 217 0. 259 0. 827 0. 091 0. 163 0. 285 0. 529 0. 173

1. 1. 0. 0.

36 5 *

45 10 6 12 17 • 27 19

. 14 6 6 6 «•»

6 5 5 7 • 20 23 14 5 » 19 18 40 24 » 23 * 41 -13 *•

AVE RRF - AVERAGE RESPONSE FACTOR FROM INITIAL CALIBRATION RF - RESPONSE FACTOR FROM DAILY CALIBRATION y.D - PERCENT DIFFERENCE *• - SPCC - SYSTEM PERFORMANCE CHECK COMPOUNDS • - CCC - CALIBRATION CHECK COMPOUNDS

CONTINUING CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDS ( PAGE 2 )

CASE NO: 7287 LABORATORY ID: CONTRACT ND: -INSTRUMENT ID: SENSITIVITY ID:

ATI

5100 2646

STANDARD DATE: 08/10/88 TIME: 22:37:00 STANDARD ID: 38M3B2647 CALIBRATION DATE: 06/21/88

• MAXIMUM 7.D FOR CCC IS 257. *•» MINIMUM AVE RRF FOR SPCC IS 0. 05

COMPOUND

2,4,6-TRICHLOROPHENOL (SVtt42) 2,4,5-TRICHLOROPHENOL (SVtt43> 2-CHLORONAPHTHALENE (SV»44) 2-NITROANILINE (SVtt4S) DIMETHYL PHTHALATE (SV#46) ACENAPHTHYLENE (SVtt47) 3-NITROANILINE (SVtt48) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SVttSO) 4-NITRDPHENOL (SVttSl) DIBENZOFURAN (SVttS2) 2,4-DINITROTOLUENE (SVttS3) 2,6-DINITROTOLUENE (SV#S4) DIETHYL PHTHALATE (SVttSS) 4-CHLDROPHENYLPHENYL ETHER (S FLUORENE (SV#57> 4-NITRDANILINE (SVttSS) 2-METHYL-4,6-DINITROPHENOL (S N-NITRDSDDIPHENYLAMINE (SVtt60 4-BROMDPHENYLPHENYL ETHER (SV HEXACHLOROBENZENE (SVtt62) PENTACHLDRDPHENDL (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE (SVtt65) DI-N-BUTYL PHTHALATE (SVtt66) FLUORANTHENE (SVtt67> BENZIDINE (SVtt68) PYRENE (SV#69>

BUTYL BENZYL PHTHALATE (SVtt70 3,3'-DICHLOROBENZIDINE (SVtt71 BENZO(A)ANTHRACENE (SV»72> BIS(2-ETHYLHEXYL)PHTHALATE (S CHRYSENE (SVtt74> DI-N-OCTYL PHTHALATE (SV#7S) BENZO(B>FLUDRANTHENE (SVtt76) BENZD(K)FLUDRANTHENE (SVtt77) BENZO(A)PYRENE (SVtt78) INDENDd, 2, 3-CD)PYRENE (SVtt79 DIBENZD(A,H)ANTHRACENE (SVttBO BENZO(G,H,I)PERYLENE (SVttB1)

AVE RRF

0. 302 0. 328 1. 005 0. 495 1. 276 1. 518 0. 322 1. 086 0. 106 0. 174 1. 486 0. 358 0. 229 1. 327 0. 536 1. 182 0. 040 0. 097 0. 343 0. 210 0. 298 0. 122 0. 928 0. 917 1. 184 1. 003 0. 020 1. 738 0. 765 0. 143 1. 101 1. 087 0. 995 1. 745 1. 360 1. 456 1. 132 1. 178 0. 869 0. 927

RF50

0. 246 Q -IHW-, 0. 839 iJ.-t33 • 1. 018 1. 124 g j M ^ . 0. 932 Q--^&6 . fl,j55»8-, 1. 293 0. 292 0. 221 1. 122 0. 472 0. 958 o>oeo. CL-^^&a-. 0. 173 0. 182 0.265 i>-0€7-0. 827 0. 833 0. 837 0. 807 0. 000 1. 179 0. 327 0. 016 0. 791 0. 502 0.812 1. 905 1. 774 1. 694 1.411 1. 123 1. 102 1. 103

,-231

.•2.1M

,132.

O0|o , I-3.C

o33 .oS6>

[O'b

y.D

19 • -56'o 17 73-5-? 20 26 ^ S 3 14 4^ *# I S •&5 ••» Z'i

13 18 4 15 12 19 ^ /» 45 " 50 • 13 11 '49-//» 11 9

29 20 • 100 32 57 89 28 54 18 -8 •

-29 -15 -24 *

5 -26 -18

AVERAGE 7.D FOR CCC IS: 15. 2

AVE RRF - AVERAGE RESPONSE FACTOR FROM INITIAL CALIQRATIDN RF - RESPONSE FACTOR FROM DAILY CALIQRATION 7.D - PERCENT DIFFERENCE «• - SPCC - SYSTEM PERFORMANCE CHECK COMPOUNDS

r rt n A-^ T #-** • *^.»#—/^#^ / ^ ^ ^ ^ ^ I ^ ^ ^ M

RIC 08/05/88 10:12:00 SAMPLE: STD MIX 50NG •:8/5.''SS> COHDS.: RANGE: G

DATA: STDS0550 <»1 CALI: STD80550 #2

SCHKS 1 TO 2300

1,2300 LABEL: N 0> 4.8 QUAN: A 8, 1.8 J 8 BASE: U 28, 3 100.0-1

RIC

Li iliii \A pL 500 R:20

T 1000 16:40

I M lU

/ \ 1308670.

rst\. 1500 25:00

2000 33:20

"CAN IME

Quantitation Report File: STD805S0

ta: STD80550.TI __)/05/88 10: 12: 00 Sample: STD MIX SONG (8/5/88) Conds. : GCS Formula: Instrument: 1050 Weight: 50. 000 Submitted by: Analyst: RGM Acct. No. :

AMOUNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

1,4-DICHL0R0QENZENE-D4 (SVttl) NAPHTHALENE-DB (SVtt2) N-NITROSODIMETHYLAMINE (SVtt14) PHENOL (SVttlS) ANILINE (SVttl6) QIS(2-CHLORQETHYL)ETHER (SVttl7) 2-CHLOROPHENOL (SVttlS) 1,3-DICHLOROQENZENE (SVttl9) 1,4-DICHLDRDQENZENE (SVtt20) QENZYL ALCOHOL (SVtt21) 1,2-DICHLOROQENZENE (SVtt22) PHENOL-DS (SVtt7) 2-FLUOROPHENOL (SVttB) 2-METHYLPHENOL (SVtt23) BIS(2-CHL0R0IS0PR0PYL)ETHER (SVtt24) 4-METHYLPHENOL (SVtt25) N-NITROSO-DI-N-PROPYLAMINE (SVtt26) HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SVttB) NITROBENZENE (SVtt28) ISOPHORONE (SVtt29) 2-NITROPHENOL (SVtt30) 2,4-DIMETHYLPHENOL (SVtt31) BENZOIC ACID (SVtt32) BIS(2-CHLOROETHOXY)METHANE (SVtt33) 2,4-DICHLOROPHENOL (SVtt34> NITROBENZENE-DS (SVtt9) 1,2,4-TRICHLOROBENZENE (SVtt35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SVtt37) HEXACHLOROBUTADIENE (SVtt3B) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) 2-METHYLNAPHTHALENE (SV»40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2,4,6-TRICHLOROPHENOL (SVtt42) 2,4,S-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SVtt44) 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SVtt46) ACENAPHTHYLENE (SVtt47) 3-NITROANILINE (SVtt4B) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SVttSO) 2-FLUOROBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENOL (SVttSl)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 .6 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 M 42 43 44 45 46 47

Name ISl IS2 61B 65A SH 18Q 24A 26B 27B 6H 25B SS2 SSI 2H 42B 4H 63B 12B 183 56B 54B 57A 34A IH 43B 31A SSS BB SSB 7H 52B 22A 9H 184 53B 21A 4H 20B lOH 71B 77B U H IB 59A SS4 SSS SBA

No .fl'

. 50

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21

kJ 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 - —

49 50

Name 8H 35B 36B

m/z 152 136

DIBENZOFURAN (SVtt52) 2,4-DINITROTOLUENE (SVtt53) 2,6-DINITROTOLUENE (SVtt54)

Scan 418 603

NOT FOUND 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165

401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578 617 587 597 503 599 605 628 639 715 710 1087 747 764 774 781 811 850 842 878 871 892 775 989 934 896 856 913

Time 6: 58 10:03

6:41 6:24 6:36 6:39 6: 51 7:00 7:34 7:25 6:40 4:27 8:03 7: 55 8:26 8: 16 8:08 14:27 8:26 9:04 9: 13 9:38 10: 17 9: 47 9: 57 8: 23 9: 59 10:05 10:28 10:39 11: 55 11: SO 18: 07 12:27 12:44 12: 54 13:01 13:31 14: 10 14: 02 14:38 14:31 14: 52 12:55 16:29 15:34 14: 56 14: 16 15: 13

Ref 1 2

19 2 2 2 2 2 2 2 2 2 2 2 2 2 2

34 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19

RRT 1. 000 1. 000

0. 959 0. 919 0. 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1. 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 6. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Meth A BB A BB

A VB A BV A VB A BB A BV A VB A BB A BQ A BV A BB A BB A BB A BB A BV A BB A BB A BQ A QQ A QB A BV A BV A BB A BV A BB A BB A VB A BB A BG A BV A BV A BQ A QB A BV A VB A VB A BB A BV A BB A BV A BB A BB A BB A BB A BV A BB A BB A BB

Area(Hght) 122297. 344107.

57172. 53632. 97776. 60660. 127580. 124912. 25664. 118029. 68979. 50476. 43710. 129287. 39430. 46195. 37563. 190572. 84883. 140885. 21712. 36836. 12150. 80444. 36219. 62868. 73546. 190013. 43169. 51238. 38010. 99119.

339482. 11401. 25631. 31048. 116922. 22827. 124200. 161212. 14059. 85391. 3759.

125076. 24995. 5797.

172903. 14633. 30288.

Amount 100. 000 NG/UL 100.000 NG/UL

50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL SO. 000 NG/UL 50. OOO NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 100.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50.000 NG/UL 100.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NG/UL 50. 000 NC/UL 50.000 NG/UL 80.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL 50.000 NG/UL 50.000 NG/UL 50. 000 NG/UL

r.Tot 2. 39 2. 39

1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 2. 39 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1, 19 1. 19 1. 19 2. 39 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 91 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 )7 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Ret(L) 6: 58 10:03 4: 16 6:41 6:24 6: 36 6:39 6: 51 7:00 7: 34 7:25 6: 40 4: 27 8: 03 7: 55 8: 26 8: 16 8:08 14:27 8:26 9:04 9: 13 9: 38 10: 17 9: 47 9: 57 8: 23 9: 59 10: 05 10:28 10: 39 11: 55 11: 50 18:07 12:27 12: 44 12: 54 13: 01 13: 31 14: 10 14:02 14:38 14: 31 14: 52 12: 55 16: 29 15: 34 14: 56 14: 16 15: 13

Ratio 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

RRT(L) 1. 000 1. 000 0. 610 0. 959 0. 919 0. 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1. 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 0. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Ratio 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

Amnt 100. 00 100. 00

50. 00 50. 00 50. 00 50. 00 SO. 00 SO. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 50. 00 SO. 00 50. 00 50. 00

100. 00 50. 00 SO. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00

, 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Amnt(L) 100. 00 100. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 80. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50.-00 50. 00

R. Fac R 1. 000 1. 000

0. 935 0. 877 1. 599 0. 992 2. 086 2. 043 0. 420 1. 930 1. 128 0. 825 0. 715 2. 114 0. 645 0. 755 0. 614 1. 000 0. 493 0. 819 0. 126 0. 214 0. 071 0. 468 0. 211 0. 365 0. 427 1. 104 0. 251 0. 298 0. 221 0. 576 1. 000 0. 120 0. 269 0. 326 1. 227 0. 240 1. 303 1. 692 0. 092 0. 896 0. 039 1. 313 0. 262 0. 061 1. 815 0. 154 0. 318

.Fac(L) 1. 000 1. 000

0. 935 0. 877 1. 599 0. 992 2. 086 2. 043 0. 420 1. 930 1. 128 0. 825 0. 715 2. 114 0. 645 0. 755 0. 614 1. 000 0. 493 0. 819 0. 126 0. 214 0. 071 0. 468 0. 211 0. 365 0. 427 1. 104 0. 251 0. 298 0. 221 0. 576 1. 000 0. 120 0. 269 0. 326 1. 227 0. 240 1. 303 1. 692 0. 092 0. 896 0. 039 1. 313 0. 262 0. 061 1. 815 0. 154 0. 318

Ratio 1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00


• 9ta: STD80550. TI 3/05/88 10:12:00

Sample: STD MIX SONG Conds. : GCS Formula: Submitted by:

(8/5/88)


Weight: Acct. No.

50. 000

AM0UNT=AREA » REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 •j6

67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 60 61 62 63

Name 70B 40B BOB 12H ISS 60A 62B 41B 9B 64A 81B 7BB 68B 39B IS6 SS6 5B 84B 67B 28B 72B 66B 76B 69B 74B 74Q 73B 838 82Q 79Q

m/z 149 204 166 138 240 198 169 248 284 266 178 178 149

DIETHYL PHTHALATE (SVttSS) 4-CHLOROPHENYLPHENYL ETHER (SVtt56) FLUORENE (SVttS7) 4-NITRDANILINE (SVttSB) CHRYSENE-D12 (SVtt5> 2-METHYL-4, 6-DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SVtt60) 4-BROMOPHENYLPHENYL ETHER (SVtt61) HEXACHLOROBENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63> PHENANTHRENE (SVtt64) ANTHRACENE DI-N--BUTYL

(SVtt65) PHTHALATE (SVtt66)

FLUORANTHENE (SVtt67) PERYLENE-D12 (SVtt6) TERPHENYL-D14 (SVttl2> BENZIDINE (SVtt6B) PYRENE (SVtt69) BUTYL BENZYL PHTHALATE 3,3'--DICHLOROBENZIDINE

(SVtt70) (SVtt71)

BENZD(A)ANTHRACENE (SVtt72) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SVtt74) DI-N--OCTYL PHTHALATE (SVtt75) BENZO(B)FLUORANTHENE (SVtt76) BENZO(K)FLUORANTHENE (SVtt77) BENZO(A)PYRENE (SVtt78) INDENOd. 2, 3-CD)PYRENE DIBENZO(A,H)ANTHRACENE

(SVtt79) (SVttSO)

BENZO(G, H, DPERYLENE (SVttBl )

Scan 959 956 948 1340 1490 973 978 1028 1042 1077 1090 1097 1208

Time 15: 59 15: 56 15:48 22: 20 24: SO 16: 13 16: 18 17:08 17:22 17: 57 18: 10 18: 17 20:08

Ref RRT 19 1. 106 19 1. 103 19 1.093 19 1. 546 55 1.000 34 0. 895 34 0. 900 34 0. 946 34 0. 959 34 0. 991 34 1.003 34 1. 009 34 1. Ill

Meth A BB A QQ A QB A BB A BB A BB A BV A BB A BB A BB A BV A VB A BB

Area(Hght) 105178. 64638. 127682.

1565. 259637.

8248. 78006. 39745. 65266. 18915. 185789. 182188. 129453.

Amount SO. 50. 50. 80. 100. 50. 50. 50. 50. 50. 50. 50. 50.

000 000 000 000 000 000 000 000 000 000 000 000 000

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NO/UL NG/UL NG/UL NG/UL NG/UL NG/UL

r.Tot

2.

19 19 19 91 39 19 19 19 19 19 19 19 19

No 64 J5

66 h i 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 "8 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 149 NOT 228 149 228 149 252 252 252 276 278 276

Scan T 1270 21 1697 28 1341 22

FOUND 1301 21 1431 23

FOUND 1487 24 1531 25 1493 24 1621 27 1647 27 1647 27 1687 28 1892 31 1902 31 1946 32

Ret(L) 15: 15: 15: 22: 24: 16: 16: 17: 17: 17: 18: 18: 20: 21: 28: 22: 29: 21: 23: 33: 24: 25: 24: 27: 27: 27: 28: 31: 31: 32:

59 56 48 20 50 13 18 08 22 57 10 17 08 10 17 21 23 41 51 27 47 31 53 01 27 27 07 32 42 26

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1.00 1. 00

1. 00 1. 00

1. 00 1. 00 1. 00 1. do 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

ime Re^ 10 34 17 65

.21 55

:41 55 : 51 55

:47 55 : 31 55 : 53 55 :01 65 :27 65 : 27 65 : 07 65 : 32 65 : 42 65 :26 65

RRT(L) 1. 106 1. 103 1. 093 1. 546 1. 000 0. 895 0. 900 0. 946 0. 959 0. 991 1. 003 1. 009 1. Ill 1. 168 1. 000 0. 900 0. 904 0. 873 0. 960 1. 003 0. 998 1. 028 1. 002 0. 955 0. 971 0. 971 0. 994 1. 115 1. 121 1. 147

F RRT 1. 168 1. 000 0. 900

0. 873 0. 960

0. 998 1. 028 1. 002 0. 955 0. 971 0. 971 0. 994 1. 115 1. 121 1. 147

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

Meth A BQ A BB A BB

A BB A BB

A BV A BB A VB A BB A BB A BB A BB A BB A BB A BB

Amnt SO. 00 50. 00 50.00 80. 00 100. 00 50. 00 SO. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 100.00 50. 00

50. 00 50. 00

. 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Area(Hght) 148280. 248821. 139815.

149583. 36978.

143108. 51697. 110947. 70928.

252434. 252434. 114510. 114068. 74260. 80165.

Amnt(L) 50. 00 50. 00 50. 00 80. 00 100. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

100. 00 50. 00

50. 00 50. 00

50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00 50. 00

Amount 50. 000

100. 000 50. 000

50. 000 50. 000

50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50. 000 50, 000 50. 000

R. Fac R. 1. 104 0. 678 1. 340 0. 010 1. 000 0. 049 0. 460 0. 234 0. 385 0. Ill 1. 095 1. 073 0. 763 0. 874 1. 000 1. 077

1. 152 0. 285

1. 102 0. 398 0. 855 0. 570 2. 029 2. 029 0. 920 0. 917 0. 597 0. 644

NG/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

Fac(L) 1. 104 0. 678 1. 340 0. 010 1. 000 0. 049 0. 460 0. 234 0. 385 0. Ill 1. 095 1. 073 0. 763 0. 874 1. 000 1. 077

1. 152 0. 285

1. 102 0. 398 0. 855 0. 570 2. 029 2. 029 0. 920 0. 917 0. 597 0. 644

XTot 1. 19 2. 39 1. 19

1. 19 1. 19

1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19 1. 19

Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1, 00 1. 00 1. 00

1. 00 1. 00

1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

PROCEDURE DATA FILE -•^FERENCE iME LIST REPORT

.-.;

PROC 2 2 2 2 2 2 2 2 1 2 2 2 2 2 2 2 2 1 2 2 2 2 2 2 2

TCA STD80550 STD80550

DIAGNOSTIC

Kl INITIALIZATION XI

STANDARDS US ED POSS

2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 8 0 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 10 C 2 1 2 1 2 ] 2 ] 2 ] 2 1 2 1

X RMS

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

) 0 0 0 0 0 0 0 0

•PTION:

REPORT 8/05/88


PLUS UNKNOWNS -PROC

11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

USED 10 9 9 9 11 11 11 8 7 11 9 9 9 12 12 11 10 7 11 9 9 9 12 12 11

POSS 48 8 3 3 4 1 4 4 4

— >< - LIST NAMES - > RMS 50 39 53 128 196 295 48 25 105 47 39 53 128 186 280 48 25 105 47 39 53 128 186 280 48

STANDARD/UNKNOWN Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4 X5/Z5 X6/Z6 Xl/Zl Xl/ZA X2/Z2 X2/ZB X3/Z3 X3/ZC X4/Z4

11:17 06


< COMPOUND X NO LIB ENTRY REF 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23

SV SV SV SV SV SV SV SV SV SV SV SV SV SV

sv sv sv sv sv sv sv sv sv

1 2 14 15 16 17 18 19 20 21 22 7 8

23 24 25 26 27 3

28 29 30 31

-415 -600 -256 -398 -382 -393 -396 -408 -417 -451 -442 -397 -263 -480 -471 -503 -493 -485 -864 -503 -541 -550 -575

PRED 418 603 259 401 385 396 399 411 420 454 445 400 267 483 474 506 496 488 867 506 544 553 578

- SEARCH — SEL DELTA 418 603

, 401 384 396 399 412 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578

-1

1

1

PEAKS 1 1

2 1 1 2 2 3 1 2 2 2 2

>< SAT >< FIT PEAKS M/Z 985 981

, 960 995 992 963 996 1000 985 1000 993 973 993 948 809 903 982 989 953 942 973 998

. —

152 L 136

42 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122

— CHRO TOP DELTA PEAKS 418 1 603

, 401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578

1 1

26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 37 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

S V • SV SV SV SV SV SV SV SV SV SV SV SV SV sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv sv

34 9

35 36 37 38 39 40 4 •

41 42 43 44 45 46 47 48 49 50 10 11 51 52 53 54 55 56 57 58 5

59 60 61 62 63 64 65 66 67 6 12 68 69 70 71 72 73 74 75 76 77 78 79 80 81

-595 -500 -596 -602 -628 -636 -713 -707 -1084 -744 -761 -773 -778 -809 -847 -839 -881 -868 -891 -772 -986 -940 -893 -853 -909 -956 -953 -945

-1337 -1486 -970 -975

-1025 -1039 -1074 -1087 -1093 -1205 -1266 -1692 -1337 -1763 -1297 -1427 -2007 -1483 -1527 -1489 -1616 -1643 -1643 -1683 -1886 -1898 -1942

598 503 599 605 631 639 716 710 1088 746 763 775 780 811 849 841 883 870 893 774 988 942 895 855 911 958 955 947 1340 1490 973 978 1028 1042 1077 1090 1096 1209 1270 1697 1341 1768 1301 1431 2012 1487 1531 1493 1620 1647 1647 1687 1891 1903 1947

597 503 600 605 628 640 715 710 1088 747 764 775 781 811 850 842 878 871

775 989 934 896 855 913 959 956 948

.

1490 973 978 1028 1043 1077 1090 1097 1208 1270 1697 1341

1301 1431

,

1487 1531 1493 1621 1647 1647 1687 1892 1901 1947

-1 ,

-3

-1

-5

-8

2

.

. ,

1 ,

1 -1

1

1 -2 .

3 - 9 9 5 1 963 1 995 1 997 -1 1 984 1 997 1 977 3 988 1 962 1 990 2 994 2 986 1 998 1 975 1 1000 1 987 1 959 1 980

1 993 1 991 1 970 1 977 1 946 1 906 1 987 1 986 1 983

1 919 1 986 1 873 1 983 1 994 1 993 2 970 2 971 1 972 1 962 1 889 1 981

1 966 1 988

2 955 1 987 2 950 1 956 2 893 2 943 1 940 1 957 1 924 1 933

162 82 180 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165 149 204 166 138 240 198 169 248 284 266 178 178 149 202 264 244 184 202 149 252 228 149 228 149 252 252 252 276 278 276

597 i 503 1 599 -1 1 605 1 628 1 639 -1 1 715 1 710 ] 1087 -1 1 747 1 764 . 1 774 -1 1 781 1 811 1 850 1 842 1 878 1 871 J 892 1 775 1 989 1 934 1 896 ] 856 1 1 913 ] 959 1 956 ] 948 1 1340 1 1490 J 973 1 978 1 1028 1 1042 -1 1 1077 1 1090 J 1097 1 1208 I 1270 1 1697 1 1341 1

1301 ] 1431 1

1487 1 1531 1 1493 1 1621 1 1647 1 1647 1 1687 J 1892 1 1902 1 1 1946 -1 J

Quantitation Report File: STD80330

ata: STD80550. TI ^8/05/88 10:12:00 Sample: STD MIX SONG (8/5/88) Conds. : GCS Formula: Instrument: 1050 Weight: 50. 000 Submitted by: Analyst: RGM Acct. No. :

AMOUNT=AREA • REF AMNT/(REF AREA » RESP FACT) Resp. fac. from Library Entry

1,4-DICHL0R0BENZENE-D4 (SVttl) NAPHTHALENE-DB (SVtt2) N-NITRDSODIMETHYLAMINE (SVttl4) PHENOL (SVttlS) ANILINE (SVttl6) BIS(2-CHLOROETHYL)ETHER (SVtt17) 2-CHLOROPHENOL (SVttlB) 1,3-DICHLOROBENZENE (SVttl9) 1,4-DICHLDROBENZENE (SVtt20) BENZYL ALCOHOL (SVtt21) 1,2-DICHLORDBENZENE (SVtt22) PHENOL-DS (SVtt7) 2-FLUDROPHENOL (SVttB) 2-METHYLPHENOL (SVtt23) BIS(2-CHL0R0IS0PR0PYL)ETHER (SVtt24) 4-METHYLPHENOL (SVtt25) N-NITROSO-DI-N-PROPYLAMINE (SVtt26) HEXACHLOROETHANE (SVtt27) ACENAPHTHENE-DIO (SVttS) NITROBENZENE (SVtt28) ISOPHORONE (SVtt29) 2-NITRDPHENOL (SVttSO) 2,4-DIMETHYLPHENOL (SVtt31) BENZOIC ACID (SVtt32) BIS(2-CHLOROETHOXY)METHANE (SVtt33) 2.4-DICHLOROPHENOL (SVtt34) NITROBENZENE-DS (SVtt9) 1,2.4-TRICHLOROBENZENE (SVtt35) NAPHTHALENE (SVtt36) 4-CHLOROANILINE (SVtt37) HEXACHLOROBUTADIENE (SVttSB) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) 2-METHYLNAPHTHALENE (SVtt40) PHENANTHRENE-DIO (SVtt4) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2,4,6-TRICHLOROPHENOL (5Vtt42) 2,4,5-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SVtt44) 2-NITROANILINE (SVtt45) DIMETHYL PHTHALATE (SVtt46) ACENAPHTHYLENE (SVtt47) 3-NITROANILINE (SVtt4B) ACENAPHTHENE (SVtt49) 2,4-DINITROPHENOL (SVttSO) 2-FLUDROBIPHENYL (SVttlO) 2,4,6-TRIBROMOPHENOL (SVttll) 4-NITROPHENDL (SVttSl)

No 1 2 3 4 5 6 . 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name ISl IS2 61B 65A 5H IBB 24A 26B 27B 6H 25B SS2 SSI 2H 42B 4H 63B 12B 183 56B 54B 57A 34A IH 43B 31A SS3 BQ 55B 7H 52B 22A 9H 184 53B 21A 4H 20B lOH 71B 77B IIH IB 59A SS4 SSS SBA

No Name 48 8H DIBENZOFURAN (SVtt52) 49 35B 2,4-DINITRDTOLUENE (SVttSS) 50 36Q 2,6-DINITROTOLUENE (SVtt54)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 12 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 M ,8 49 50

m/z 152 136

Scan 418 603

NOT FOUND 94 93 93 128 146 146 108 146 99 112 108 45 108 70 117 164 77 82 139 122 122 93 162 82 IBO 128 127 225 107 142 188 237 196 196 162 65 163 152 138 153 184 172 330 139 168 89 165

401 384 396 399 411 420 454 445 400 267 483 475 506 496 488 867 506 544 553 578 617 587 597 503 599 605 628 639 715 710 1087 747 764 774 781 811 850 842 878 871 892 775 989 934 896 856 913

Time 6: 58

10: 03

6: 41 6:24 6:36 6:39 6: 51 7:00 7:34 7:25 6: 40 4:27 8:03 7: 55 8: 26 8: 16 8:08 14:27 8: 26 9:04 9: 13 9: 38 10: 17 9: 47 9: 57 8: 23 9: 59 10: 05 10: 28 10:39 11: 55 11: 50 18: 07 12: 27 12: 44 12: 54 13: 01 13: 31 14: 10 14: 02 14:38 14:31 14: 52 12: 55 16: 29 15: 34 14: 56 14: 16 lSrl3

Ref 1 2

19 2 2 2 2 2 2 2 2 2 2 2 2 2 2

34 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19

RRT 1. 000 1. 000

0. 959 0. 919 0. 947 0. 955 0. 983 1. 005 1. 086 1. 065 0. 957 0. 639 1. 156 1. 136 1. 211 1. 187 1. 167 1. 000 0. 839 0. 902 0. 917 0. 959 1. 023 0. 973 0. 990 0. 834 0. 993 1. 003 1. 041 1. 060 1. 186 1. 177 1. 000 0. 862 0. 881 0. 893 0. 901 0. 935 0. 980 0. 971 1. 013 1. 005 1. 029 0. 894 1. 141 1. 077 1. 033 0. 987 1. 053

Meth A GB A BB

A VB A BV A VB A BB A BV A VB A BB A BB A BV A BB A BB A BB A BB A BV A BB A BB A BB A BB A BB A BV A BV A BB A BV A BB A BB A VB A BB A BB A GV A BV A BG A GG A QV A VG A VG A QB A BV A BB A BV A BB A BB A BB A BB A BV A BB A BB A BB

Area(Hght) 122297. 344107.

57172. 53632. 97776. 60660. 127580. 124912. 25664. 118029. 68979. 50476. 43710. 129287. 39430. 46195. 37563. 190572. 84883. 140885. 21712. 36836. 12150. 80444. 36219. 62868. 73546. 190013. 43169. 51238. 38010. 99119.

339482. 11401. 25631. 31048. 116922. 22827. 124200. ^ 161212. 14059. 85391. 3759.

125076. 24995. 5797.

172903. 14633. 30288.

Amount 100. 000 NG/UL 100. 000 NG/UL

41. 369 NG/UL 57.817 NG/UL 40. 688 NG/UL 44.991 NG/UL 51.227 NG/UL 51. 540 NG/UL 40. 875 NG/UL 50.643 NG/UL 38.349 NG/UL 45. 278 NG/UL 37.401 NG/UL 32. 220 NG/UL 36.414 NG/UL 38. 406 NO/UL 40. 960 NG/UL 100.000 NG/UL 35. 091 NG/UL 41.208 NG/UL 43. 825 NG/UL 42. 799 NG/UL 53. 693 NG/UL 41. 132 NG/UL 51.038 NG/UL 33. 377 NG/UL 53. 907 NG/UL 47.373 NG/UL 60. 887 NG/UL 59. 461 NG/UL 45. 576 NG/UL 42. 753 NG/UL 100.000 NG/UL 46. Oil NG/UL 55. 575 NG/UL 62. 922 NG/UL 44.447 NG/UL 49.689 NG/UL 55. 135 NG/UL 46. 274 NG/UL

237. 797 NG/UL 38. 692 NG/UL 69.043 NG/UL 44.787 NG/UL 74.116 NG/UL 104. 760 NG/UL 52. 784 NG/UL 42. 609 NG/UL 53. 663 NC/UL

r.Tot 2. 30 2. 30

0. 95 1. 33 0. 93 1. 03 1. 18 1. 18 0. 94 1. 16 0. 88 1. 04 0. 86 0. 74 0. 84 0. 88 0. 94 2. 30 0. 81 0. 95 1. 01 0. 98 1. 23 0. 94 1. 17 0. 77 1. 24 1. 09 1. 40 1. 37 1. 05 0. 98 2. 30 1. 06 1. 28 1. 44 1. 02 1. 14 1. 27 1. 06 5. 46 0. 89 1. 59 1. 03 1. 70 2. 41 1. 21 0. 98 1. 23


- ata: STD80550. TI a/05/88 10: 12: 00

Sample: STD MIX SONG Conds. : GCS Formula: Submitted by:

(8/5/88)


Weight: Acct. No.

50. 000

AMOUNT=AREA » REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 36

67 68 69 70 71 72 73 74 75 76 77 78 79 80

No 51 52 53 54 55 56 57 58 59 oO 61 62 63

Name 70B 40B BOB 12H ISS 60A 62B 4iB 9B 64A BIB 78B 68B 39B IS6 SS6 SB 84B 67B 28B 72B 66B 76B 69B 74B 74B 73B 83B 82Q 79Q

m/z 149 204 166 138 240 198 169 248 284 266 178 178 149

DIETHYL PHTHALATE (SVtt55) 4-CHLOROPHENYLPHENYL ETHER (SVtt56> FLUORENE (SVttS7) 4-NITROANILINE (SVttSB) CHRYSENE-D12 (SVttS) 2-METHYL-4, 6-DINITROPHENOL (SVtt59) N-NITROSODIPHENYLAMINE (SVtt60) 4-QROMDPHENYLPHENYL ETHER (SVtt61) HEXACHLDRDQENZENE (SVtt62) PENTACHLOROPHENOL (SVtt63) PHENANTHRENE (SVtt64) ANTHRACENE DI-N--BUTYL

(SVtt65) PHTHALATE (SVtt66)

FLUORANTHENE (SVtt67) PERYLENE-D12 (SVtt6) TERPHENYL-D14 (SVttl2) QENZIDINE (SVtt68) PYRENE (SVtt69) GUTYL QENZYL PHTHALATE 3,3'--DICHLOROBENZIDINE

(SVtt70) (SVtt71>

QENZO(A)ANTHRACENE (SVtt72)

•

B is(2-ETHYLHEXYL)PHTHALATE (SVtt73) CHRYSENE (SVtt74) DI-N--OCTYL PHTHALATE (SVtt75) BENZO(B)FLUORANTHENE (SVtt76) BENZO(K)FLUORANTHENE (SVtt77) BENZO(A)PYRENE (SVtt7B) INDENOd, 2. 3-CD)PYRENE DIBENZO(A,H)ANTHRACENE

(SVtt79) (SVttSO)

BENZO(G,H. DPERYLENE (SVttBl)

Scan 959 956 948 1340 1490 973 978 1028 1042 1077 1090 1097 1208

Time 15: 59 15: 56 15: 48 22:20 24: 50 16: 13 16: 18 17:08 17:22 17: 57 18: 10 18: 17 20:08

Ref RRT 19 1. 106 19 1. 103 19 1.093 19 1. 546 55 1. 000 i34 0. 895 34 0.900 34 0. 946 34 0. 959 34 0. 991 34 1.003 34 1.009 34 1. Ill

Meth A BB A BB A BB A BB A BB A BB A BV A BB A BB A BB A BV A VB A BB

Area(Hght) 105178. 64638. 127682.

1565. 259637.

8248. 78006. 39745. 65266. 18915. 185789. 182188. 129453.

Amount 54. 62. 50. 108. 100. SB. 47. 54. 60. 70. 50. 49. 46.

735 298 512 269 000 496 607 676 102 355 716 773 241

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

XTot 1. 1. 1. 2. 2. 1. 1. 1. 1. 1. 1. 1. 1.

26 43 16 49 30 34 09 26 38 62 16 14 06

No 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

m/z 202 264 244 NOT 202 149 NOT 228 149 228 149 252 252 252 276 278 276

Scan 1270 1697 1341

FOUND 1301 1431

FOUND 1487 1531 1493 1621 1647 1647 1687 1892 1902 1946

Time 21: 28: 22:

21: 23:

24: 25: 24: 27: 27: 27: 28: 31: 31: 32:

10 17 21

41 51

47 31 53 01 27 27 07 32 42 : 26

Ref 34 65 55

55 55

55 55 55 65 65 65 65 65 65 65

1. 1. 0.

0. 0.

0. 1. 1. 0. 0. 0. 0. 1. 1. 1.

RRT 168 000 900

873 960

998 028 002 955 971 971 994 115 121 147

Me A A A

A A

A A A A A A A A A A

} t h BB BB BB

BB BB

BV BB VB BB BB BB BB BB BQ OQ

Area(Hght) 148280. 248821. 139815.

149583. 36978.

143108. 51697.

110947. 70928.

252434. 252434. 114510. 114068. 74260. 80165.

Amount 62. 100. 47.

41. 35.

60. 38. 41. 25. 41. 41. 45. 80. 78. 41.

083 000 003

113 902

334 056 470 674 098 098 575 968 722 967

NG/UL NG/UL NG/UL

NG/UL NG/UL

NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL NG/UL

r.Tot 1. 43 2. 30 1. 08

0. 94 0. 82

1. 39 0. 87 0. 95 0. 59 0. 94 0. 94 1. 05 1. 86 1. 81 0. 96

CPA (f^s tl vvz^

%ouio

D H T H : S T D S U 4 « 1

C A L I : STD384 #2 SCANS RIC

88/04/88 3:59:00 SAMPLE: STD MIX SONG <08/04.^88) CONDS.: GCS RANGE: G 1,2308 LABEL: H 0, 4.8 QUAN: A 8, 1.8 J 0 BASE: U 28, 3

1 TO 2300

100.0-

iv

n

in

d o -< z D 00 O 00 U. -v

n o t v V.

CO

Q . . UJ I -X < cn •-< Q

' Z UJ M l U. U)

y- t

< z H U.

RIC

1875%!;

I If I l l l r l l \a. -=i~ 1000 16:40

1500 25:00

2000 33:20

SLTltl T! !€

Quantitation Report File: 5TDS04

Data: STD804.TI 08/04/88 9: 59: 00 Sample: STD MIX 50NG (08/04/88) Conds. : GCS Formula: Instrument: 1050 Weight: 50.000 Submitted by: Analyst: RGM Acct. No. :

AMOUNT=AREA # REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

2-FLUOROPHENOL (SVttB) ANILINE (SVttl6) BIS(2-CHLOROETHYL)ETHER (SVttl7) 2-CHLOROPHENOL (SVttlB) PHENDL-DS (SVtt7) PHENOL (SVttlS) 1,3-DICHLOROBENZENE (SVttl9) 1, 4-DICHLDR0BENZENE-D4 (SVttl) 1,4-DICHLOROBENZENE (SVtt20) 1,2-DICHLDROBENZENE (SVtt22) BENZYL ALCOHOL (SVtt21) BIS(2-CHLORDISOPROPYL)ETHER (SVtt24) 2-METHYLPHENDL (SVtt23) HEXACHLOROETHANE (SVtt27) N-NITROSD-DI-N-PRDPYLAMINE (SVtt26) LJRDBENZENE-DS (SVtt9)

NITROBENZENE (SVtt2B) 4-METHYLPHENOL (SVtt25) ISOPHORONE (SVtt29) 2-NITROPHENOL (SVttSO) 2,4-DIMETHYLPHENDL (SVttSl) BIS(2-CHLORDETHOXY)METHANE (SVtt33) 2,4-DICHLORDPHENOL (SVtt34) 1,2,4-TRICHLORODENZENE (SV#35) NAPHTHALENE-DB (SVtt2) NAPHTHALENE (SVtt36) BENZOIC ACID (SV#32> 4-CHLORDANILINE (SVtt37) HEXACHLOROBUTADIENE (SVttSB) 2-METHYLNAPHTHALENE (SVtt40) 4-CHL0R0-3-METHYLPHEN0L (SVtt39) HEXACHLOROCYCLOPENTADIENE (SVtt41) 2,4,6-TRICHLOROPHENOL (SVtt42) 2-FLUDROBIPHENYL (SVttlO) 2,4,S-TRICHLOROPHENOL (SVtt43) 2-CHLORONAPHTHALENE (SVtt44) 2-NITRDANILINE (SVtt45) ACENAPHTHYLENE: (SVtt47> DIMETHYL PHTHALATE (SVtt46) 2,4-DINITROTDLUENE (SVtt53) ACENAPHTHENE-DIO (SV4(3) ACENAPHTHENE (SVtt49) 3-NITROANILINE (SVtt48) 2,4-DINITROPHENOL (SVttSO) DIBENZOFURAN (SVtt52) 2,6-DINITROTDLUENE (SVtt54) 4-NITROPHENaL (SVttSl)

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47

Name SSI SH IBB 24A SS2 65A 26B ISl 27B 25B 6H 42B 2H 12B 63B SS3_ 56B 4H 54B 57A 34A 43B 31A 8B IS2 SSB IH 7H 52B 9H 22A SSB 21A SS4 4H 20Q lOH 77Q 71B 35Q I S3 IB U H 59A 8H 36B 58A

No 48 49 50

No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Name BOB 40B 70B

m/z 112 93 93 128 99 94 146 152 146 146 108 45 108 117 70 82 77 108 82 139 122 93 162 ISO 136 128. 122 127 225 142 107 237 196 172 196 162 65 152 163 89 164 153 138 184 168 165 139 166 204 149

FLUORENE (SVtt57) ^

4-CHLOROPHENYLPHENYL ETHER (SVtt56) DIETHYL

Scan 263 382 393 396 397 398 408 415 417 442 451 471 480 485 493 500 503 503 541 550 575 584 595 596 600 602 613 628 636 707 713 744 761 772 773 778 809 839 847 853 864 868 881 891 893 909 940 945 953 956

PHTHALATE

Time 4: 6: 6: 6: 6: 6: 6: 6: 6: 7: 7: 7: 8: 8: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9:

10: 10: 10: 10: 10: 11: 11: 12: 12: 12: 12: 12: 13: 13: 14 14 14. 14-14 14 14 15 15 15 15 15

23 22 33 36 37 38 48 55 57 22 31 51 00 05 13 20 23 23 01 10 35 44 55 56 00 02 13 28 36 47 S3 24 41 52 53 58 29 59 07 13 24 28 41 51 53 09 40 45 53 56

Ref 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8

25 25 8

25 25 25 25 25 25 25 25 25 25 25 25 25 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41

0. 0. 0. 0. 0. 0. 0.

0. 0. 1. 0. 0. 0. 0. 0. 0.

0. 0. 0. 0. 0. 0. 0. 0. 0.

(SVttSS)

RRT 634 920 947 954 957 959 983 000 005 065 087 135 157 169 186 833 838 212 902 917 958 973 992 993 000 003 022 047 060 178 188 861 881 894 895 900 936 971 980 987 000 005 020 031 034 052 088 094 103 106

Me A A A A A A A A A A A A A A A A A A A A A A A A A A A M A A A A A A A A A A A A A A A M A A M A A A

'th BV BV VB BV BV VB BV BB VB BB BB BV BB QB BV BB BB BB BB BB BV VB BB DB BB VB BB XX BB BV BB BB BV BB VB BB BB BV BV BB BB BB BV XX BB BB XX BB BB BQ

Area(Hght) 79297. 65983. 170935. 95905. 127945. 98304. 177151. 173983. 172392. 165778. 44661.

285420. 83132. 65232. 85557. 146169. 187713. 77023.

265314. 38446. 66790. 151771. 55070.

105874. 534072. 311265. 17560. 55020. 66871. 179916. 64720. 18064. 33621.

203587. 35972. 191772. 33490.

253975. 164218. 25036.

277855. 160888.

6896. 3969.

238798. 41146. 4034.

184274. 75638. 140085.

Amount 50. 50. 50. 50. 50. SO. 50.

100. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50.

100. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50.

100. 50. 80. 50. 50. 50 50. 50. 50. SO.

000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000 000

% •

NG/UL 1. NG/UL 1. NG/UL 1. NG/UL 1. NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 2. NG/UL 1 NG/UL 1 NG/UL 1. NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NO/UL 1 NG/UL 1 NG/UL 1 NG/UL 2 NG/UL 1 NG/UL 1 NO/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NO/UL 1 NO/UL 1 NG/UL 1 NO/UL 1 NG/UL 1 NG/UL 1 NG/UL 1 NG/UL 2 NG/UL 1 NO/UL 1 NO/UL 1 NO/UL 1 NG/UL 1 NO/UL 1 NG/UL 1 NO/UL 1 NG/UL 1

rot 17 17 17 17 17 17 17 34 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 34 17 17 17 17 17 17 17 17 17 17 17 17 17

. 17

. 17 34

. 17

. 88

. 17 17

. 17

. 17

. 17

. 17 17

No 1 2 3 4 5 6 7 B 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50

Ret(L> 4: 6: 6: 6: 6: 6: 6: 6: 6: 7: 7: 7: 8: 8: 8: 8: 8: 8: 9: 9: 9: 9: 9: 9:

10: 10: 10: 10: 10: 11: 11: 12: 12: 12: 12: 12: 13: 13: 14: 14: 14: 14: 14: 14: 14: 15: 15: 15: 15: 15:

23 22 33 36 37 38 48 55 57 22 31 51 00 OS 13 20 23 23 01 10 35 44 55 56 00 02 13 28 36 47 53 24 41 52 53 SB 29 59 07 13 24 28 41 51 S3 09 40 45 53 56

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

RRT(L) 0. 0. 0. 0. 0. 0. 0.

0. 0. 1. 0. 0. 0. 0. 0. 0.

0. 0. 0. 0. 0. 0. 0. 0. 0.

634 920 947 954 957 959 983 000 005 065 087 135 157 169 188 833 838 212 902 917 958 973 992 993 000 003 022 047 060 178 188 861 881 894 895 900 936 971 980 987 000 005 020 031 034 052 088 094 103 106

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

Amnt 50. 50. 50. 50. 50. 50. 50.

100. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50.

100. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. SO. 50. 50. 50.

100. 50. 80. 50. 50. 50. 50. SO. 50. 50.

00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

Amn t < L ) 50. 50. 50. 50. 50. 50. 50.

100. 50. 50. 50. 50. 50. SO. 50. 50. 50. SO. 50. 50. 50. 50. 50. 50.

100. 50. 50. SO. 50. SO. 50. 50. 50. SO.

' 50. SO. SO. SO. SO. SO.

100. SO. 80. 50. 50. SO. 50. 50. SO. 50.

00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

R. 0. 0. 1. 1. 1. 1. 2. 1. 1. 1. 0. 3. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 0. 1. 1. 0. 1. 1. 0. 0. 1. 0. 0. 1. 0. 1.

Fac H. 912 758 965 102 471 130 036 000 982 906 513 281 956 750 984 547 703 885 994 144 250 568 206 396 000 166 066 206 250 674 242 130 242 465 259 380 241 828 182 180 000 158 031 029 719 296 029 326 544 008

, Fs 0. 0.

1. 1. 1. 2. 1. 1. 1. 0. 3. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1. 0. 0. 0. 0. 0. 0. 0. 1. 0. 1. 0. 1. 1. 0. 1. 1. 0. 0. 1. 0. 0. 1. 0. 1.

*;(.L) 912 758 965 102 471 130 036 000 982 906 513 281 956 750 984 547 703 885 994 144 250 568 206 396 000 166 066 206 250 674 242 130 242 465 259 380 241 828 182 180 000 158 031 029 719 296 029 326 544 008

na'i

• 1.

:io 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

•_- U.C. n t . t - i .OT\ :epD- F: ll STD30A

Data: STDE04. TI 08/04/BB 9: 59: 00 Bample: STD MIX SONG (08/04/88) Conds. : 005 Formula: Instrument: 1050 Submitted by: Analyst: RGM

Weight: Acct. No.

50. OOQ

AM0UNT=AREA * REF AMNT/(REF AREA * RESP FACT) Resp. fac. from Library Entry

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79

No 51 52 53 54 55 56 57 58 59 60 61 62 63 64

Name 60A 62Q SSS 41G 9G 64A IS4 BIG 78B 68Q 39Q B4B SS6 12H 67B 72B ISS 76B 66B 69B 74B 74B 74B 74B 73B IS6 83B 82B 79B

m/z 198 169 330 248 284 266 188 178 173 149 202 202 244 133

2-METHYL-4, 6-DINITROPHENOL (SV#59) N-NITROSODIPHENYLAMINE (SVtt60) 2, 4, 6-TRIBRDMDPHENOL (SVttll) 4-BROMDPHENYLPHENYL ETHEF HEXACHLOROBENZENE PENTACHLOROPHENOL

(SVtt62) (SVtt63)

PHENANTHRENE-DIO (SV#4) PHENANTHRENE (SV#64) ANTHRACENE DI-N-BUTYL

(SVtt65)

I (SVtt61)

PHTHALATE (SVtt66) FLUORANTHENE (SVtt67) PYRENE (SVtt69) TERPHENYL-D14 (SVttl2) 4-NITROANILINE (SVttSB) BUTYL QENZYL PHTHALATE (SVtt70) QENZD(A)ANTHRACENE (SVtt72) CHRYSENE-Dl 2 (SVtt5) CHRYSENE (SVtt74) BIS(2-ETHYLHEXYL)PHTHALATE (SVtt73) DI-N-DCTYL PHTHALATE (SVtt75) BENZ0(B)FLU0RANTHENE (SVtt76) BENZO(K)FLUDRANTHENE (SV#77) BENZO(K)FLUORANTHENE (SVtt77) BENZO(B)FLUORANTHENE (SVtt76) BENZO(A)PYRENE (SVtt7B) PERYLENE-Dl INDENOd, 2,

2 (SVtt6) 3-CD)PYRENE (SV#79)

DIBENZO(A, H)ANTHRACENE (SVttSO) BENZO(0, H, DPERYLENE (SVttBl)

Scan Time 970 16:10 975 16:15 986 16:26 1025 17:05 1039 17: 19 1074 17: 54 1084 18:04 1087 18:07 1093 18:13 1205 20:05 1266 21:06 1297 21:37 1337 22:17 1337 22:17

Ref 57 0. 57 0. 41 1. 57 0. 57 0. 57 0. 57 1. 57 1. 57 1. 57 1, 57 1. 67 0. 67 0. 41 1.

RRT Me 895 A 899 A 141 A 946 A 958 A 991 A 000 A 003 A OOB A 112 A 168 A 873 A 900 A 547 A

>th BB BV BB BB BB BB BB GV VB BB BB BB BB BB

Area(Hght) 7849.

91211. 24585. 40465. 60449. 14966.

377953. 203923. 203761. 155837. 132954. 132565. 108381.

1686.

'

Amount 50. 50. SO. 50. 50. 50.

100. 50. 50. 50. 50. 50. 50. 80.

000 000 000 000 000 000 000 000 000 000 000 000 000 000

r.-NO/UL 1 NG/UL 1 NO/UL 1 NO/UL 1 NG/UL 1 NG/UL 1 NG/UL 2 NG/UL 1 NO/UL 1 NO/UL 1 NO/UL 1 NO/UL 1 NO/UL 1 NO/UL 1

Tot 17 17 17 17 17 17 34 17 17 17 17 17 17 83

Nc? 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79

No 51 52 53 54 55 56 57 SB 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79

m/z Scan Time Re 149 1427 23 228 1483 24 240 3 228 J

.486 24

.489 24 149 1527 25 149 1616 26 252 1640 27 252 1643 27 252 1643 27 252 : L643 27 252 1683 2E 264 1692 2E 276 ] L886 31 278 1898 31 276 1942 32

Ret(L; 16: 10 16: 15 16:26 17:05 17: 19 17: 54 18:04 18:07 18: 13 20:05 21:06 21:37 22: 17 22: 17 23: 47 24: 43 24:46 24:49 25:27 26: 56 27:23 27:23 27:23 27:23 28: 03 28: 12 31:26 31:38 32:22

\ Ratio 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00 1. 00

1:47 67 :43 67 : 46 67 :49 67 ':27 67 .: 56 76 :20 76 :23 76 :23 76 ':23 76 1:03 76 1: ; L2 76 :26 76 : 38 76 !:22 76

RRT(L) 0. 0. 1. 0. 0. 0. 1. 1. 1. 1. 1. 0. 0. 1. 0. 0. 1. 1. 1. 0. 0. 0. 0. 0. 0. 1. 1. 1. 1.

895 899 141 946 958 991 000 003 008 112 168 873 900 547 960 998 000 002 028 955 971 971 971 971 995 000 115 122 148

f RRT 0. 960 0. 998 1. 000 1. 002 1. 028 0. 955 0. 969 0. 971 0. 971 0. 971 0. 995 1. 000 1. 115 1. 122 1. 148

Ratio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

Meth A BB A BV A BB A VB A BB A BV M XX M XX A BQ A QQ A BB A BB A BB A BB M ; <X

Amnt 50. 50. SO. SO. 50. 50.

100. 50. SO. SO. 50. SO. 50. 80. 50. 50.

100. 50. 50. 50. 20. 35. 50. 50. 50.

100. 50. 50. 50.

00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 33 89 00 00 00 00 00 00 00

Are£(Hght; 37 5£ 17. 86423. 189200. . 97477. 49496. 65974. 59648.

105276. 1466B1. 146681. 60001. 118839. 33643. 22527. 45616.

Amnt(L) 50. 50. 50. 50. SO. SO.

100. 50. SO. SO. 50. 50. SO. 80. 50. 50.

100. 50. SO. 50. 50. SO. 50. 50. 50.

100. 50. 50. SO.

00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00

)

1

Amourit 5C. coo 50. 000 .00. 000 50. 000 50. 000 50. 000 20. 333 35. 886 50. 000 50. OOC 50. OOC

100. OOC

R. 0. 0. 0. 0. 0. 0. 1. 1. 1. 0. 0. 1. 1. 0. 0. 0. 1. 1. 0. 1. 1. 1. 2. 2. 1. 1. 0. 0. 0.

50. OOC 50. OOC 50. OOC

Fac R. 042 483 177 214 320 079 000 079 078 825 704 401 146 008 397 914 000 030 523 110 004 772 469 469 010 000 566 379 768

' UG/UL NO/UL

i l\JS/UL ' NQ/VL ' NG/UL ' NO/UL 1 NG/UL . NG/UL > NG/UL » NG/UL 1 NG/UL • NG/UL • NG/UL > NG/UL 1 NG/UL

Fac(L) 0. 042 0. 483 0. 177 0. 214 0. 320 0. 079 1. 000 1. 079 1. 078 0. 825 0. 704 1. 401 1. 146 0. 008 0. 397 0. 914 1. 000 1. 030 0. 523 1. 110 2. 469 2. 469 2. 469 2. 469 1. 010 1. 000 0. 566 0. 379 0. 768

l 4 1 .

1 ^

1. 1. i. .

0. 0.

Rai

0. 0.

• ,-, •-

*i "7

17 34 17 17 17 48 84 17 17 17 34 17 17 17

bio 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 41 72 00 00 00 00 00 00 00

A \ AnalyticalTechnologies, Inc

7rno-Su.A 7r)UJ-S'u.A> olu^

QUALITY CONTROL DATA ATI I.D.

TEST : ORGANOCHLORINE PESTICIDES AND PCB'S (EPA 608)


MONTGOMERY 661D HASSAYAMPA

& ASSOCIATES REF. I.D. DATE ANALYZED SAMPLE MATRIX UNITS

807002

80700402 07/14/88 AQUEOUS UG/L

COMPOUNDS

DUP. DUP, SAMPLE CONC. SPIKED % SPIKED % RESULT SPIKED SAMPLE REC.SAMPLE REC. RPD

GAMMA BHC HEPTACHLOR ALDRIN DIELDRIN ENDRIN DDT

ND ND ND ND ND ND

2.0 2.0 2.0 2l0 2.0 2.0

1.95 1.86 1.83 1.67 2.71 2.50

75 93 92 84 136 125

2.38 2.22 2.12 1.90 2.99 2.73

119 111 106 95 150 137

20 18 15 13 10 9

% Recovery = (Spike Sample Result - Sample Result)

Spike Concentration X 100


Average of Spiked Sample X 100

L-nHk 1 s P t - t U y . o UCU I'l l N ATTEN: 16 ZERO: 10% 1 MIN/TICK ATTEN: ZERO: 5% 1 MIN/TICK

TITLE

CHANN

P •<

1 2 3 4 5 6 7 R

: PESTICIDES

EL NO: 2

PEAK NAME

LINDANE B BHC

HEPTACHLO n-Pi-in

>ic7oc^-S A M P L E :

RESULT UG/ML 0,0000 0.0000 0.0000 0.2712 0.0007 0.0000 0.2184 (?) . (?I(?»«R

2. /y?5

21

TIME CMIN) 7. 745 9. 025 10.467 10.981 1 1 .418 11.726 12.020 1 • ? . C O i ^

MET

TIME OFFSET

-0.079 0.098

-0.080 -P). 1 T;S

3:

HOD

10 14

: DB60B

AREA COUNTS

2371 543

3042 502227

llll 1B69

359175 I 4.^0

JUL 88

SEP CODE BB BB BV VV VV VV VV VV

-

?

7

Wl/2 CSECD 7.95 8.75 7.55 6.45 13.40 8.60 7.60 1 4.00

TITLE: PESTICIDES

CHANNEL NO: 2 i07OC)U--Z. ry>s

SAMPLE: 21

3:10 14 JUL 88

METHOD: DB608

AK

1 2 3 4 5 6 7 e 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 1<d

PEAK NAME

LINDANE B BHC

HEPTACHLO D-BHC

ALDRIN ISODRIN

ENDO I DIELDRIN

ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

, ALS:

RESULT UG/ML 0.0000 0.0000 0.0000 0.2712 0.0007 0.0000 0.2184 0.0008 0.0000 0.2311

108.9400 0.0000 0.0007 0.2271 0.0000 0.0000 0.3202 0.0107 0.0049 0.2423 0.0475 0.0040 0.0000 0.0000 0.0000 0.0000 0.0159 0.0510 0.0000 0.0000

110.5860

TIME CMIN) 7.745 9.025 10.467 10.981 1 1 .418 1 1 .726 12.020 12.405 12.767 13.094 14.526 15.464 15.977 17.058 17.543 17.823 18.231 18.670 19.195 19.601 19.896 20.717 20.871 21.165 21.318 22.002 22.225 22.691 24.845 25.802

TIME OFFSET

-0.079 0. 098

-0.080 -0.135

-0.086 -0.134

-0.183 -0.092

-0.089 -0.080 0.275

-0.089 -0.094 0. 347

-0.255 -0.099

-0.775

AREA COUNTS

2371 543

3042 502227

llll 1869

359175 1460 1059

420202 384947

2950 991

334016 2834 3275

152493 12618 6635

252345 62482 6098 4608 2259 7071 3146 3676

77333 887 1083

2614810

SEP CODE BB BB BV VV VV VV VV VV VV VB BB BV VB BV VV VV VV VV VV VV VV VV VV VV VV vv vv VB BV VV

?

?

? ?

? ?

? ? ? ? ? ?

? ?

Wl/2 CSEC) 7.95 8.75 7.55 6.45 13. 40 8.60 7.60 14. 00 6.60 8.00 7.85 7.30 5.80 7.85 9.20 10.50 8.00 16.55 13. 90 4.85 8.75 17.40

14. 70 12.40 7. 90

27.90 27.60

" DETECTED PKS: 47 REJECTED PKS: 17 a ''DIVISOR: 1.00000 MULTIPLIER: 1.00000 J NOISE:

^ RACK: 16

8.5 OFFSET:

VIAL: 13 INJ: 1

ERRORS:

COL TEMP

-~ NOTES: u DB608 PRIMARY COLUMN X

3 TITLE: PESTICIDE CONFIRMATORY

-* C'ANNEL NO: 1 o D P._AK g. NO i2- 1

PEAK NAME

2 LINDANE 3 4 ALDRIN

.t n I CTI n o ! kl

SAMPLE: SAME

RESULT UG/ML 15.3282 0.3840 15.2363 14.6491 14.CC73 1 0 -7Q 1 0

TIME CMIN)

10,652 1 1 .310 12.956 14.074 1 , o-»>-» l i t V i \ J

1 7 0 0 1

3:

METHOD

TIME OFFSET

0.070

-0.226

Ol 1 Q-7

10 14

: DBS

AREA COUNTS 336763

8437 334744 321843 ^ ^ ^ ^ 0 •

o v r 1 o<j •3nr?in 1 <3

JUL 88

SEP CODE BB BB BB BB rt r\ u U R R

Wl/2 CSEC) 9.00 6. 90 9.70 10.05 .-» .-, n, 7 . U V 0 Pt^

TLE: PESTICIDE CONFIRMATORY

lANNEL NO: 1 SAMPLE: SAME

AK PEAK 0 lAME 1 2 LINDANE 3 4 ALDRIN

6 DIELDRIN 7 ENDRIN 8 DDD 9 ENDO S04 10

iTALS:

RESULT UG/ML 15.3282 0.3840 15.2363 14.6491 4 ~f • *• .z / w

12.7819 8.6968 3.5086 10.9648 4.4409

99.9999

TIME CMIN)

10.652 11.310 12.956 14.074 1 ^ O "* <"«

17. 17. 18. 19, 20,

227 896 730 506 869

3:

METHOD

TIME OFFSET

0. 070

-0.226

0. 197 0. 066

-0.030 0. 196

0. 273

10 14

: DBS

AREA COUNTS 336763

8437 334744 321843 s j <L/ r r t_ii_i

280819 191069 77084

240899 97568

2197010

JUL 88

SEP CODE BB BB BB BB T-l T->

IJ o BB BB BB BB BB

Wl/2 CSEC) 9.00 6. 90 9. 70 10.05 «-» o /\ / . Ut**

9.85 9. 30 8.85 9.60 8.85

REJECTED PKS; :TECTED PKS: I 7

I L T I P L I E R : 1 .00000

)ISE: 71.6 OFFSET: 12

^CK: 16 VIAL: 13 INJ: 1

)TES: DBS CONFIRMATORY COLUMN

-IART SPEED 0.6 CM/MIN TTEN: 16 ZERO: 10% 1 MIN/TICK

JTAT—r INJECT

ATTEN: 32 ZERO: 5% 1 MIN/TICK

5R:OFF

A BHf 9.655 10.463

)-BHgtl2.397

INDANE 1.1 , 7 M

15.462 :NDe-;l 15.970 JDE :C; -818 [NDR-l-Sb IDD --/ 18.669 rkinn—*_i i o i Q T

] 0.927

^ 10.975"

14.527

" 17.043'

18.223

SR: (7FF

0.928

5. 844

8. 675

C

" 12.947

"14.059

14.963

•:• n H t;, I o,- i. h Ll O . o 0 Cl I'l 1 N

ATTEN: *16 ZERO: 10% 1 MIN/TICK ATTEN: 32 ZERO: 5% 1 MIN/TICK

0.928

TITLE

CHANN

PF 1

1 2 3 4 5 6 7

: PESTICIDES

EL NO: 2

PEAK NAME

LINDANE

HEPTACHLO D-BHC

>(37<50V-

SAMPLE;

RESULT UG/ML 0,0000 0.0000 0.0000 0.3309 0,0000 0,2603 0,0012

Z /»IJD

22

TIME CMIN) 6.957 7. 749 10.463 10.975 1 1 .714 12.018 12.397

MET

TIME OFFSET

-0.085

-0.0B2 -0.143

3:

HOD

45 14

: DB608

AREA COUNTS

580 2953 4033

612712 2545

428048 2235

JUL 88

SEP CODE BB BB BV VV VV VV VV

? ? ?

Wl/2 CSEC) 6.40 8. 05 7. 80 6.55 1 1 .40 5.05 18.60

/%. XX i^ V d^

TITLE: PESTICIDES

CHANNEL NO: 2 SAMPLE: 22

3:45 14 JUL 88

METHOD: DB608

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 4 .5 26 27 28

PEAK NAME

LINDANE

HEPTACHLO D-BHC

ALDRIN ISODRIN

ENDO I DDE

ENDRIN DDD ENDO I I

DDT ENDRIN AL

ENDO S04

METHOXY END KETON

TOTALS:

RESULT UG/ML 0.0000 0.0000 0.0000 0.3309 0.0000 0.2603 0.0012 0.0000 0.2677

116,9290 0,0000 0,0008 0.2647 0.0000 0.3531 0.0091 0.0032 0 . 0000 0.2644 0.0422 0.0000 0.0014 0,0000 0,0000 0.0082 0.0562 0.0000 0.0000

118.7920

TIME CMIN) 6.957 7. 749 10.463 10.975 11.714 12.018 12.397 12.765 13.089 14.527 15.462 15.970 17.043 17,818 18.223 18.669 19.193 19.303 19.591 19.883 20. 1 14 20.698 21.070 21.968 22.228 22.688 24.786 24.871

TIME OFFSET

-0.085

-0.082 -0.143

-0.091 -0.133

-0.190 0. 103

-0.097 -0.081 0.273

-0.099 -0.107

0. 328

-0.252 -0.102

-0.758

AREA COUNTS

580 2953 4033

612712 2545

428048 2235 1785

486675 413176

3893 1207

379701 2996

168147 10764 4259 710

275412 55583 5450 2078 1068 727 1899

85193 2730 84 1

2957400

SEP CODE BB BB BV VV VV VV VV VV VB BV VB BB BV VV VV VV VV VV VV VV VV VV VV BV VV VB BV VB

? ? -?

?

? ? ?

? ? ? •7>

? ?

Wl/2 CSEC) 6.40 8.05 7.80 6.55 1 1 .40 5. 05 18. 60 6.35 7.95 8. 10 7.75 5.65 8.00 13.60 7.90 17.55 1 .70

4.90 8. 75

10. 30 9. 40

10. 30 7.95 7.80 12.90

DETECTED PKS:

DIVISOR: 1.00000

49 REJECTED PKS: 21

MULTIPLIER: 1.00000

o NOISE: n

--RACK: 16

8.5 OFFSET: 7

VIAL: 14 INJ: 1

h NOTES: DB60a PRIMARY COLUMN

- TITLE: PESTICIDE CONFIRMATORY 3:45 14 JUL 88

,NNEL NO: 1 SAMPLE: SAME METHOD: DBS

PEAK NO

1 2

4 3 c

PEAK NAME

I.-^NE

Al n o I kl

15 0 14 1 i;

RESULT UG/ML 0.4093

6960 249° 9059

10 1 1 12 t a

TIME CMIN) 8.675

639

TIME OFFSET

947

AREA COUNTS

9837 377267

358275

SEP CODE BB BB EB BB

Wl/2 CSEC) 6.95 9, 6, 9,

00 40 70

i t

(^ (/) C"

rv 11.

1—

o p z p DD 2. 5" o 3

5 o 0)

z p

ro (0 00

•S"

O 03 r *

z o r-t CO

o X o

o TJ Q) Q.

9 • 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28

ALDRUN iSODRIN

ENDO I DDE

ENDRIN DDD ENDO I I

DDT ENDRIN AL

ENDO S04

METHOXY END KETON

TOTALS:

DETECTED PKS:

D I V I S O R : 1 . 0 0 0 0 €

NOISE: 8.5

RACK:

V • W W

0.2677 116,9290 0.0030 0,0008 0.2647 0.0000 0,3531 0,0091 0.0032 0.0000 0.2644 0.0422 0.0000 0.0014 0.0000 0.0000 0.0082 0.0562 0.0000 0.0000

118.7920

t c > r w ^

13.089 14.527 15.462 15.970 17.043 17.818 18.223 18.669 19.193 19.303 19.591 19.883 20.114 20.698 21 .070 21.968 22.228 22.688 24.786 24.871

49 REJECTED PKS:

-0.091 -0.133

-0. 190 0. 103

-0.097 -0.081 0. 273

-0.099 -0.107

0.328

-0.252 -0.102

-0.758

21

» MULTIPLIER: 1.00000

OFFSET:

16 V I A L : 14

NOTES: DB608 PRIMARY COLUMN

7

INJ: 1

T I T L E : PESTICIDE CONFIRMATORY

CHANNEL N O : 1

PEAK NO

I 2 2 4

?i 5 i 6 4— 7

8 9 10 1 1

PEAK NAME

LINDANE

ALDRIN HEPT-EPOX DIELDRIN ENDRIN DDD ENDO S04

TOTALS:

SAMPLE:

RESULT UG/ML 0.4093 15.6960 0.3499 14.9059 15.0096 13.4672 12.7510 8.4991 3.5445 10.7999 4.5677

100.0000

SAME

TIME CMIN) 8. 675 10.639 11 -)Oi-l I 1 . . . . ^ .

12.947 14.059 14.963 17.211 17.885 18.717 19.493 20.861

486675 413176

3893 1207

379701 2996

168147 10764 4259 710

275412 55583 5450 2078 1068 727 1899

85193 2730 841

2957400

3:45 14

METHOD: DBS

TIME OFFSET

-0.241 0. 293 0.181 0.055

-0.043 0. 183

0.487

AREA COUNTS

9837 377267

S';e9 358275 360769 323695 306480 204282 85194

259584 109789

2403580

VB BV VB BB BV VV VV VV VV VV VV VV VV VV VV BV VV VB BV VB

JUL 88

SEP CODE BB BB BB BB BB BB BB BB BB BB BB

?

? ? ?

? ? ? ?

? ?

7,95 8, 10 7.75 5,65 8,00 13,60 7,90 17.55 1 .70

4.90 8.75

10.30 9.40 10.30 7.95 7.80 12.90

Wl/2 CSEC) 6.95 9.00 6.4 0 9.70 9.85 9. 95 9. 95 9. 35 8.95 9. 45 9.00

REJECTED PKS: DETECTED PKS: 25

MULTIPLIER: 1.00000

OISE: 71.6 OFFSET: 34

RACK: 16 VIAL: 14 INJ: 1

NOTES: DBS CONFIRMATORY COLUMN

14

| b g e No. 1 >(2l /a: jj ®S3l Technologies, Inc

ANALYTE

ORGANIC QUALITY CONTROL REPORT

DATE OF INIT. QC ANALYSIS NAME

VALUE TRUE UNITS ^ FOUND VALUE flee

** ACCESSION NUMBER 807002 * METHOD 608 LINDANE ENDRIN DDT

07/13/88 TMG 07/13/88 TMG 07/13/88 TMG

GC381 GC381 GC381

1.95 1.16 1.74

2.00 2.00 2.00

UG/L UG/L UG/L

'X 5? «7

HART S P E E D 0.6 CM/MIN TTEN: 16 ZERO: 10% 1 MIN/TICK

INJECT

ATTEN: 32 ZERO; 5% 1 MIN/TICK

SR:0FF

4.273

5. 550

^ 7.858

1 1 .577

ALDR4-rf 13. 125

JLSODR

-tTDE

-ETNDRIN^Wirtr

— = 20.729 ^ 21.052

— ^ 2 1 . 7 3 1 METHOX^^:—2?. ?77 -e N D K &T-on

24.636

25.816

26.837

0. 924 1 . 525

~ S R : 0 F F

10.6'^'

^ ALDJFÎN 14. 115 14.565

19.935

22.733

15.023

-ENDR-m ^

_ENDO SO^-

17.943

= " " 19.553

yy)L i ) -^ /^4

17) uJ -S 'Uy^J ju^

TITLE: PESTICIDES ,CC-«'

CK .NEL NO: 2 S A M P L E :

PEAK PEAK RESULT NO NAME UG/ML

1 0,0000 2 LINDANE 0,2713 3 0.0000 4 ALDRIN 0,0024 c icnriDiki o o T.Â~>

^ j i 1

4

TIME CMIN) 7.858 1 1 .014 11.577 13.125 1 4 =;AS

17:

METHOD

TIME OFFSET

-0.046

-0.055 -P). Ri95

31 13

: DB608

AREA COUNTS

918 502469

1209 4413

351006

JUL 88

SEP CODE BB BV

Wl/2 CSEC) 7.05 6.45

VB ? BB BB

8.05 8.00

T ITLE :: PESTICIDES ^... . ..

CHANNEL NO: 2

PEAK NO

3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 1 7 18 19 20 21 22 23 24 25

PEAK NAME

LINDANE

ALDRIN ISODRIN DDE

DIELDRIN ENDRIN DDD

ENDO I I

DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

•Ai.: / G C

SAMPLE:

RESULT UG/ML 0. 0000 0.2713 0.0000 0.0024

99.3347 0.0017 0.0000 0.0005 0.1367 0.0026 0.0000 0.0028 0.0000 0.0000 0.0000 0.1681 0.0731 0.0016 0.0000 0.0000 0.0000 0.0084 0.0734 0.0000 0.0000

100.0770

3 i \ 4

TIME CMIN) 7.858 11.014 I 1 .577 13.125 14.565 16.906 17.038 17.313 18.269 18.733 18.777 18.847 19.086 19.167 19.272 19.635 19.935 20.729 20.769 20.908 21.052 22.277 22.733 25.816 26.837

17:

, METHOD

TIME OFFSET

-0.046

-0.055 -0.095 -0.034

0. 163 -0.051 -0.017

-0.073

-0.055 -0.055 0.359

-0.203 -0.057

-0.219

31 13

: DB608

AREA COUNTS

918 502469

1209 4413

351006 2390 1528 716

65103 3062 1470 3736 924 994 988

175079 96229 2361 1 189 703 613 1939

111144 799 871

1331850

JUL 88

SEP CODE BB BV VB BB BB BV VV VB BV VV VV VV VV VV VV VV VV VV VV VV VV BV VB BB BB

?

? ? ?

? ? ? ? ? ?

? ? ? ?

? ?

Wl/2 CSEC) 7.05 6. 45

8. 05 8. 00 8. 60

25.30

8.05 10.80

8. 15 9.55 13.60

8. 40 8. 30

28. 10 21 . 00

DETECTED PKS: 32 REJECTED PKS: 7

D' SOR: 1.00000 MULTIPLIER: 1.00000

NOISE: 8.5 OFFSET: 17

RACK: 16 VIAL: 9 INj: 1

NOTES: ^ DB608 PRIMARY COLUMN

T I T L E : PESTICIDE

CHANNEL N O : 1

PEAK PEAK NO NAME

1 2 ALDRIN 3 4 ENDRIN 5 DDD 6 ENDO S04

TOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML

27,1439 0.7541

24.2273 9.6654 9.4092 17.9093 10,8908

100,0000

SAME

TIME CMIN)

10.699 14.115 15.023 17.943 18.776 19.553 20.915

17:

METHOD

TIME OFFSET

-0.185

0.113 0.016 0.243

0. 187

31 13

: DBS

AREA COUNTS 324408

9012 289551 115515 112453 214041 130161

1195140

JUL 88

SEP CODE

Wl/2 CSEC)

BB ? 9.10 BB BB BB BB BB BB

7. 15 9. 80 8. 70 10. 15 10. 20 9.75

DETECTED PKS: )

10

MULTIPLIER: 1.00000

REJECTED PKS:

DB608 PRIMARY COLUMN

TITLE: PESTICIDE CONFIRMATORY

CHANNEL NO: 1 SAMPLE: SAME

PEAK NO

1 2 3 4 5 6 7

PEAK NAME

ALDRIN

ENDRIN DDD ENDO S04

RESULT UG/ML

27.1439 7541 2273 6654 4092 9093 ,8908

0. 24. 9. 9, 17, 10,

TIME CMIN)

10.699 14. 115 15.023 17.943 18.776 19.553 20.915

TOTALS; 100.0000

17:

METHOD

TIME OFFSET

-0.185

0.113 0.016 0.243

0. 187

31 13

: DBS

AREA COUNTS 324408

9012 289551 115515 112453 214041 130161

1195140

JUL 88

SEP CODE

Wl/2 CSEC)

BB ? 9.10 BB BB BB BB BB BB

7. 15 9.80 8.70 10. 15 10. 20 9.75

DETECTED PKS: 10 ) MULTIPLIER: 1.00000

NOISE: 58.3 OFFSET;

RACK: 16 VIAL: 9

REJECTED PKS:

0

INJ: 1

N -.S: £35 CONFIRMATORY COLUMN

CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: 10% l MIN/TICK

~5TAT~T INJECT

2. 937

4. 277 ^ 4.823

SR:0FF

BHf 9.682

B BH 10.867 1 1 .280


0.922

- S R : 6 F F

CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: 10% 1 MIN/TICK

-5TAT- INJECT

^

%:m SR:0FF

DDE ~

-DDD"

17.050

ENDgiN 18.275

\%' . l \% "DDT 1 1 9 . 9 6 1 _ENDCr-fe04 2 0 . 4 0 9

~ [ 21.481 21.901

^ND-KfeTON 22.632

24.605

25.788

26.976

ATTEN: 32 ZERO;

0. 927 1 .527

5% 1 MIN/TICK

-~SR: CTFF

TITLEi PESTICIDES , ^, / l i ^ . ( 6 l a y i ^

CHANNEL NO: 2 'SiWPLE: 6

> '< PEAK RESULT TIME NAME UG/ML CMIN)

1 ENDRIN 0.0036 18.275 2 DDT 0.0019 19.310 3 ENDRIN AL 0.0024 19.961 4 ENDO S04 0.0017 20.409 5 0.0000 21.481 6 0.0000 21.616 7 0.0000 21.901 8 0.0000 22.154 9 METHOXY 0.0036 22.632 10 0.0000 26.976

TOTALS: 0.0132 -0.263 3 1221


DIVISOR: 1.00000 MULTIPLIER: 1.00000


RACK: 16 VIAL: 13 INJ: l

) NOTES: DB608 PRIMARY COLUMN

MET

TIME OFFSET -0.045 -0.380 -0.029 0.039

0. 152

18:

HOD

40 13

: DB608

AREA COUNTS

1709 1937 31 15 2577 12476 2985 2162 2730 825 705

JUL 88

SEP CODE BB VV VV VV VV VV VV VV VB BB

? ? ? ? ? ? ? ? ? ?

Wl/2 CSEC) 15.75 27.70 5.00

26.80 16.80

34. 10

TITLE: PESTICIDE CONFIRMATORY 18:40 13 JUL 88

CHANNEL NO: 1 SAMPLE: SAME METHOD: DBS

PEAK PEAK RESULT TIME TIME AREA SEP Wl/2 NO NAME UG/ML CMIN) OFFSET COUNTS CODE CSEC)

TOTALS: 0.0000 0


MULTIPLIER: 1.00000

NOISE: 71.6 O F F S E T : -7

RACK: 16 V I A L : 13 INJ: 1

ERRORS: NO PEAKS


CHART SPEED 0.6 CM/MIN ATTEN: 16 ZERO: 10% 1 MIN/TICK ATTEN: 32 ZERO: 5% 1 MIN/TICK

CHART SPEED 0.6 CM/MIN ATTEH: 16 ZERO: 10% 1 MIN/TICK

"2:0.898.

4. 281

SR:OFF ~ ^ 7.006

~riNDAt4: =r-

^

D-BUil,

1/

11.010

^^2.493

14.989

16.103 l- . 900

22.452

hTTEN: ZERO: S% 1 MIN/TICK

-8R:crFF

13.013

"ALDfWI 14.119

DIE

-&DD END

16.484 17.277

18.232 18.800

4 19.550

20.942

' TITLE: PESTICIDES

5 C. .NNEL NO: 2 n

: PEAK PEAK •' NO NAME 2 1 •) 2 A BHC

3 LINDANE D 4 B BHC — _ . . . . . - ^ * . ^ A , , , ^

0 . 0 \ S f iXnUarU

SAMPLE: 1

RESULT UG/ML 0.0000 0.0193 0.0184 0,0072 ~ ^ . , m

TIME CMIN) 7.006 9.683 1 1 .010 1 1 .275 A —* n . c r i

7>)iV'SUA 7y)uJ-SZi :^ <Mt^

13:

METHOD

TIME OFFSET

-0 -0 -0 — rs

047 050 045 rt/11

45 13

: DB608

AREA COUNTS

748 37147 33999 1 1983 1 O.^ D T

JUL 88

SEP CODE BB BB VV VB -D\l

Wl/2 CSEC) , 5.95 6. 80 6.55 6,80 -7 -70,

1 1 1 l_C rc.3 1 1 L- 1 u c

CHANNEL NO: 2

PEAK NO

1 2 3 4 S 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19

PEAK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN

ENDO I DDE DIELDRIN ENDRIN ENDO I I DDT ENDRIN AL ENDO S04 METHOXY END KETON

TOTALS:

= O.ol

SAMPLE:

RESULT UG/ML 0.0000 0.0193 0.0184 0.0072 0.01 18 0.0154 0.0132 2.1907 0.0000 0.0138 0.0078 0.0144 0,0114 0.0204 0,0082 0.0116 0.0075 0.0965 0.0141

2.4817

1

TIME CMIN) 7.006 9.683 11.010 1 1 .275 12.058 12.493 13.133 14.451 14.989 16.103 16.900 17.089 18.263 18.880 19.652 19.950 20.335 22.452 22.747

13: 45 13 JUL 88

METHOD: DB608

TIME OFFSET

-0.047 -0.050 -0.045 -0.042 -0.047 -0.047 -0.209

-0.057 -0.040 -0.061 -0.057 -0.040 -0.038 -0.040 -0.035 -0.028 -0.043

-0.926

AREA COUNTS

748 37147 33999 1 1983 19483 28513 23934 7741

22529 19941 1 1 129 21220 5436

27549 8587 15274 1 1314-' 22289 21343

350159

SEP CODE BB BB VV VB BV VV VB BV VB BB BV VB BV VV VV VV VB BV VB

Wl/2 CSEC) 5.95 6. 80 6.SS 6.80 7. 70 6.70 7.95 14.75 7.90 8.00

? 8. 20 8.90 12.15 10.50 8. 35 8.40 9. 15 9. 10 8.90

D "CTED PKS: 24 REJECTED PKS:





•JTITLE: P E S T I C I D E CONFIRMATORY o

CHANNEL NO: 1 S A M P L E : SAME

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 t 4

PEAK NAME

* •

LINDANE

ALDRIN ISODRIN

DIELDRIN ENDO I I DDD ENDO S04

rkin kTxnKi

RESULT UG/ML 10.6045 3.6965 10.5355 8.6491 6.9967 6.6049 7.0489 6.1026 10.3400 4.2057 7.71 15 6.0649 4.7688 .C A A O f ^

TIME CMIN) 9. 679 10.458 10.699 11.384 13.013 14. 1 19 IS.339 16.484 17.277 18.232 IB.800 19.550 20.942 o 1 •:>-?a

13:45 13 JUL 88

METHOD: DBS

TIME OFFSET

0. 144

-0. -0.

0. -0, 0. 0,

181 181

247 278 040 240

-Pl 7(7l7

AREA COUNTS 64915 22640 64493 52945 42830 40432 43150 37357 63296 25745 47206 37126 29192 <1P|R5 1

SEP CODE BB BV VB BB BB BB BB BB BB BV VV VB BV vn

Wl/2 CSEC)

? 6. 85 6.50 6.95 7. 10 7.15 6.80 7.80 7. 90

? 12.75 . 8.50 9.60 10.00 8.55

1 « 4(?l

TI'YLE: PESTICIDE CONFIRMATORY 13: 45 13 JUL 88

CHANNEL NO: 1 SAMPLE: SAME METHOD: DBS

PEAK bin

3

PEAK NAME

4 LINDANE 5 6 ALDRIN 7 ISODRIN 8 9 DIELDRIN 10 ENDO I I 1 1 DDD 12 ENDO S04 13 14 END KETON

RESULT UG/ML 10.6045 3.6985 10.5355 8.6491

9967 6049 0489 1026

10.3400 4. 2057

7115 0649 7688 6685

6. 6, 7, 6,

7, 6, 4, 6,

10 10 1 1 13 14 15 16 17 18 18 19 20 21

TIME CMIN) 9. 679

458 699 384 013 1 19 339 484 277 232 800 550 942 278

TIME OFFSET

0. 144

-0, -0,

0, -0 0 0

181 181

247 278 040 240

-0.202

AREA COUNTS 64915 22640 64493 52945 42830 40432 43150 37357 63296 25745 47206 37126 29192 40821

SEP CODE BB BV VB BB BB BB BB BB BB BV VV VB BV VB

Wl/2 CSEC) 6.85 6 6 7 7 6 7 7 12 8 9 10 8 10

50 95 10 15 80 , 80 , 90 , 75 , 50 , 60 , 00 . 55 . 40

TOTALS: 100.0000 -0.171 612148

DETECTED PKS: 15

MULTIPLIER: 1.00000

NOISE: 131.1 O F F S E T ;

R A C K : 16 VIAL: 6

REJECTED PKS;

39

INJ: 1



-STAT—T

ATTEN

I N J E C T

1 . 3 3 9

— : 4 . 2 9 1

5 . 159 - S R : 0 F 4 :

C ^

3 2

0 . 9 7 2

ZERO; 5% 1 M I N / T I C K

S R : P F F 7 . 0 1 7

8 . 286 C J ^

: " C I N D A N

'TACWtec BHQ_.r

ISOD

1 1 . 0 1 9

= ^ - 2 . 0 6 4 J ,2 . 500 .

1 0 , 4 6 3

9 . 6 9 5

^ ~ R E P T _ ^ » X ^ 1 4 . 4 5 3

5 . 5 1 3 ENDO ^ —

-TTDE

1 4 . 9 9 8

= < 6 . 1 1 7 ' = • ^ 6 . 9 0 3 -

CZZ

1 3 . 0 1 8

3 3 B CHART SPEED 0.6 CM/MIN D A - ^ T E N : 16 ZERO: 10% 1 MIN/TICK >

* -STAT-T INJECT

1 . 339

4.291

^ 5.159 - S R : O F ^

A T T E N : 32 Z E R O : 5% 1 MIN/TICK

0. 972

7.017

—f 8.286

SR:fDFF

p "TlNDANtu:

l y

11.019

/ ^ 9.695 -le-. 46-3

' HEPTACWiaa > D-BHC_

^ 2 . 0 6 4 L 2 . S 0 0 r

c = < 6 . 1 1 7 ~ £ 1

^•=16.903 ' ^

1 3 . 0 1 8

, y 1 4 . 9 9 8

L Z . 9 0 4

1 9 . 9 4 1 — 0 . 3 2 7

2 2 . 4 3 7

ENDO

1 ^ E : PESTICIDES

)CHANNEL NO: 2

PEAK PEAK NO NAME

1 2

SAMPLE: 2

RESULT UG/ML 0.0000 0, 0000

TIME CMIN) 6, 286 7,017

14:19 13 JUL 88

METHOD: DB608

TIME OFFSET

AREA COUNTS

530 2.1Z1

SEP CODE

BB BB

• W l / 2 CSEC) 1 8 , 5 5

6 . 5 0

TITLE : P E S T I C I D E S

CH'^NNEL N O : 2

PL,,,< NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 -'8

1

^0

PEAK NAME

A BHC

LINDANE B BHC HEPTACHLO D-BHC ALDRIN

ISODRIN HEPT EPX

ENDO I DDE DIELDRIN

ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

0 . IO

S A M P L E :

RESULT UG/ML 0.0000 0.0000 0.0000 0.1596 0.0000 0.0000 0.1433 0.0559 0.1135 0.1235 0.1317 0,0000 2.2524 0.1346 0,0000 0,1256 0.0844 0.1485 0.0000 0,0769 0,0574 0,1462 0,0953 0,1069 0,1141 0.0000 0.0000 0.0000 I.4199 0.1424

5,6321

2

TIME CMIN) 6.286 7.017 8.286 9. 690 10.515 10.720 11.019 1 1 .286 12.064 12.500 13.138 14.453 14.552 14.998 15.513 16.117 16.903 17.100 17.689 18.275 18.710 18.872 19.641 19.941 20.327 21.117 21 .504 21.640 22.437 22.744

14:

METHOD

TIME OFFSET

-0.040

-0.041 -0.034 -0.036 -0.040 -0.042

-0.108 -0.042

-0.043 -0.037 -0.050

-0.045 -0.040 -0.048 -0.049 -0.049 -0.043

-0.043 -0.046

-0.876

19 13

: DB608

AREA COUNTS

530 2707 1 188

306942 3805 1930

265287 92387 186625 228645 239478

8377 7959

200953 4970

182044 121048 218430

4668 36613 67565 197513 99291 140594 172877 1 1645 10509 14442

327931 215798

3372750

JUL 88

SEP CODE BB BB BB BV VV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv VB

?

? ?

'> 7

?

?

9

? ? ? 7

Wl/2 CSEC) 18.55 6.50 12. 15 6.70 13.50 8. 10 6.90 6.85 7.70 6.65 7.80 10.80 10.55 7.55 9. 60 7.80 7.40 8.30

8.20 9.00 9.10 8. 00 8.35 8.65 9.30 15.80

5.70 8.20






TITLE: P E S T I C I D E

C H A N N E L NO: 1

p ; PEAK N^ NAME

1 2 3 4 L I N D A N E 5 6 7 ALDRIN

CONFIRMATORY

S A M P L E :

RESULT UG/ML 7.9136 3,1995 6,9896 6,4039 6.8121 0.4793 7.4965

SAME

flME CMIN) 9.695 10.463 10,707 11,392 13.018 13.904 14.1P9

14:

METHOD

TIME OFFSET

0, 152

-Pl . 17 1

19 13

: DBS

AREA COUNTS 255183 103171 225387 206502 219665 15456

r>/ l 1 •7T'3

JUL 88

SEP CODE BB BV VB BB BB BV y / a

Wl/2 CSEC)

? 9,20 7,50 8,80

• 8.50 9,30

? 10.10 a -5c

TITLE

CHANN

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18

: PESTICIDE

EL NO: 1

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN

ENDRIN

ENDO I I DDD ENDO S04

END KETON

TOTALS:

CONFIRMATORY

SAMPLE:

RESULT UG/ML 7.9136 3,1995 6,9896 6.4039 6.8121 0.4793 7.4965 6,4267 6,0393 3,4927 6,7345 1,7118 4.5300 3.3970 5.3572 8.0858 5,1350 9,7954

99.9999

SAME

TIME CMIN) 9.695 10.463 10.707 1 1 .392 13.018 13.904 14.129 15.352 16.484 17.148 17.287 17.960 18.224 18.423 18.788 19.543 20.934 21.258

14:

METHOD

TIME OFFSET

0. 152

-0.171 -0.168

0.118

0. 130

-0.087 0.028 0.233

-0.222

0.013

19 13

: DBS

AREA COUNTS 255183 103171 225387 206502 219665 15456

241732 207236 194744 112627 217161 55198 146076 109540 172750 260734 165584 315862

3224610

JUL 88

SEP CODE BB BV VB BB BB BV VB BB BB BV VB BV VV VV VV VB BV VB

Wl/2 CSEC)

? 9.20 7.50 8,80 8,50 9.30

? 10.10 9.75 9.45 9.40

? 9.30 ? 12,50

7.55 9.75

? 10,95 10.65 11.45 9.70 10.90

DETECTED PKS: 20

ML .IPLIER: 1.00000

NOISE: 108.0 OFFSET;

RACK: 16 VIAL: 7

REJECTED PKS;

28

INJ: 1




. 932

^SR:

7.006 7.767 8, 178

9. 120 " 9.693



~^TAT~TINJECT

SR:OEFj

7. 767 8. 178

"TINDANE

^ HEPTACHLO-^ r '3HC

= 4-.412 "REPT EPX_

15.509

-DDE

-DDT ENDO S04

METHOXY

25.551


.932

-SR:C)rF

7.006

9. 120

D

11.020

12-065' 12.499

14.994'

1 .657

13.854

^ ENDO -f 16.899—

-16.062

19.645 20.325

^—I 22.427

-ENDRIN -©DD ENDO S04

9.693 10.459

13.024

16.486 17.281

1 17.957

20.927

TITLE: PESTICIDES sS^ 14:54 13 JUL 88

TITLE : PESTICIDES

CHANNEL NO: 2

P._ .x NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 ?

.,0 31 32 33

^ 34

PEAK NAME

A BHC

LINDANE B BHC HEPTACHLO D-BHC ALDRIN

ISODRIN HEPT EPX

ENDO I DDE DIELDRIN ENDRIN DDD ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

oTOTALS: .

/•o 5A> SIMPLE:

RESULT UG/ML 0,0000 0.0000 0.0000 0.0000 0.0000 1.1490 0.0000 0.0000 1.1150 0.6123 1.0477 1.0942 1.1104 0.0000 18.6542 1.1175 0.0000 1,1004 0,9313 1.2541 1.1728 0.8221 1.2165 1.0787 1 .0347 1 .0681 0.0000 0,0000 0.0000 0.0000 11.2733 1.1066 0.0000 0,0000

47.9589

n f l - A r ^ 3

TIME CMIN) 6. 280 7.016 1 . 1 6 1 8. 178 8.289 9.690 10.508 10.720 1 1 .020 1 1 .285 12.065 12.499 13.135 14.412 14.568 14.994 15.509 16. 113 16.899 17.096 18.276 18.698 18.873 19.645 19.938 20.325 20,543 21.107 21.472 21.726 22.427 22.740 25.SD1 25.751

14_ :54 13

M E T H O D : DB608

TIME OFFSET

-0.040

-0,040 -0.035 -0.035 -0.041 -0.045

-0.092 -0.046

-0.047 -0.041 -0.052 -0.044 -0.052 -0.047 -0.045 -0.052 -0.045

-0.053 -0.050

-0.902

AREA COUNTS

3184 13367 2630 3108 6377

2209690 2304 1 15050

2064900 1012110 1723140 2026310 2018950

20286 65916

1667940 59519

1594750 1336120 1844190 558472 967149 1643970 1123620 1361410 1618310 236825 106604 91547 95744

2603540 1676590

157 1 121 1

29797200

JUL 88

SEP CODE BB BB BV VV VB BV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv VB

? ?

?

?

? ?

? ?

? ? ? ?

? ?

Wl/2 CSEC) 9.95 7.20 7.00 8,00 14,20 9.20 1 1 .25 10. 10 9. 15 6,95 9.35 8.60 10.05 12.40 9. 45 9. 40 10. 10 9.35 8. 60 10.85 8.40 8.70 10. 50 8,85 8,95 8,80

34,20 13,70 14. 40 3.50 1 1 .00 10. 10





NOTES:

DB608 PRIMARY COLUMN

" LE: PESTICIDE CONFIRMATORY


-PEAK 0 NO ' 1

i \

PEAK NAME

RESULT UG/ML 0.2096 0.0865 6.6436

TIME CMIN) 7,006 9. 120 9,693

14:54 13

METHOD: DBS

TIME AREA OFFSET COUNTS

27312 I 1267

865774

JUL 88

SEP CODE BB BB BV

Wl/2 . CSEC)

? 7.55 ? 7.20

10.90

DETECTED- PKS: 45 REJECTED PKS: 11

DIVI'SOR: 1.00000 MULTIPLIER: 1.00000

ic z : 9 . 7 O F F S E T : 6

R A C K : 16 V I A L : 8 I N J : 1

NJOTES: DB608 PRIMARY COLUMN



14:54 13 JUL 88

METHOD: DBS

PEAK NO

1 2 3 4 5 6 7 8

- J 1 1 12 13 14 15 16 17 16 19 20 21 22 23 24 25 26 27 28 29 30

PEAK NAME

B BHC LINDANE

D-BHC

ALDRIN

ISODRIN ENDO I

DIELDRIN

ENDRIN


DDT

END KETON

TOTALS:

RESULT UG/ML 0.2096 0.0865 6.6436 3.1261 5.8580 0.8408 5.6680 0.2254 0.4860 0.0834 0.5023 0,3794 5.2602 0,1883 6,0367 0.5686 5,5894 0.6118 5.5637 3,7645 6.0360 3.0972 4.4312 4.1025 5.9364 1 .3355 8.5120 0,9877 5,2570 8.6121

99.9999

TIME CMIN) 7.006 9. 120 9.693 10.459 10,707 11,030 11.390 11.657 11.718 11.909 12.100 12,208 13.024 13.854 14.131 15.040 15.351 16.082 16.466 17.153 17.281 17.957 18.218 18.413 18.779 19.259 19.535 20.322 20.927 21.243

TIME OFFSET

0.050 0. 150

-0.011

-0.169

-0.169 0.202

0. 123

0. 127

-0.097 0.019

-0.051

0. 272

-0.237

0.209

AREA COUNTS 27312 11267

865774 407383 763395 109567 738629 29372 63340 10870 65458 49440

665494 24534

786682 74101

728393 79734

725041 490581 786587 403613 577463 534623 773611 174041

1109260 128716 685073 1122300

13031700

SEP CODE BB BB BV VV VV VV VV VV VV VV VV VB BB BV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv VB

? ?

?

? ? ? ? ?

?

? ?

? ?

?

? ?

Wl/2 CSEC) 7.55 7.20 10.90 8.95 10.80 17.70 10.35

22.60

8. 10 27.30 10.60 8.00 1 1 .35 8.30 11.15 9.60 1 1 .35 1 1 .80 13.45 10.10 1 1 .20 12. 75 12. 20 14.40 14. 35 10. 70 8. 45 15.20

REJECTED PKS; DETECTED PKS: 33

MULTIPLIER: 1.00000

NO'SE: 108.0 OFFSET: 12

Rh,<<: 16 VIAL: 8 INJ: I


J

'STAT ' : { I N J E C T

S R : O F F

0 . 9 2 1 1 . 5 2 2

4 . 2 7 4

~HR; OFF

— 6 . 9 9 5

i: 9 . 6 6 7

"CINDAI^ 1 1 . 0 0 0

~HEP:PAetdzrn D-BHCC

_L2,04 1 12,476

-h^m^ .14. SS9 '-X 14.969

i^m

4=e=*-440

12.994

ALDlRlN 14. 102

22.435

yjOlLi-S-U-yi

Z

s) VJ JO

-t

T 3

• >

,.*. D 3

-fl

TITLE : PESTICIDES

CHANNEL NO: 2

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 1 P

PEAK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN HEPT EPX

ENDO I nnr

o. o ppp^

SAMPLE:

RESULT' UG/ML 0.0000 0.0283 0.0261 0.0093 0,0195 0,0205 0,0237 0,5170 0.0261 0.0000 0,0249 Ol O i \ & O i

sro

7

TIME CMIN) 6,995 9,673 11.000 11.267 12.041 12.476 13.112 14.559 14.969 15.467 16.093 1 A R-7-7

19:

METHOD

TIME OFFSET

-0.057 -0.060 -0.053 -0.059 -0.064 -0.068 -0.101 -0,071

-0,067 -ft (?lAT

14 13

: DB606

AREA COUNTS

634 54404 48291 15329 31997 37992 43074 1827

38914 2277

36034 r>o,o,Ci->

JUL 88

SEP CODE BB BB BV VB BV VV VB BV VV VV VB • a \ i

Wl/2 CSEC) 5.90 6.75 7.00 6.60 7.80 6.60 7.95 10.05 7.75

? 7.35 7.85

' i -> o/>

\ i 0 0 >> •J

r )

5 4.

3 3

)

CD

• ' ' • ' •

PEAK NO

1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 IS 16 17 18 19 20 21 22 23 24

*-- •' - • -

PE-AK NAME

A BHC LINDANE B BHC HEPTACHLO D-BHC ALDRIN ISODRIN HEPT EPX

ENDO I DDE DIELDRIN ENDRIN ENDO I I DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

o m i t - i_ l_ .

RESULT UG/ML 0.0000 0.0283 0.0261 0.0093 0.0195 0.0205 0.0237 0.5170 0.0261 0.0000 0,0249 0.0140 0.0262 0.0161 0.0360 0.0155 0.0201 0.0201 0.0000 0.0000 0.0000 0.0000 0.1965 0.0236

1.0635

TIME CMIN) 6.995 9.673 1 1 .000 1 1 .267 12.041 12.476 13.112 14.559 14.969 15.467 16.093 16.877 17.080 19.258 18.855 19.627 19.926 20.307 20.676 21.146 21.267 21.517 22.435 22.727

lie. 1 \-V^'Ll

TIME OFFSET

-0.057 -0.060 -0.053 -0.059 -0.064 -0.068 -0.101 -0.071

-0.067 -0.063 -0.070 -0.062 -0.065 -0.063 -0.064 -0.063

-0.045 -0.063

-1.158

. ij b o y d

AREA COUNTS

634 54404 48291 15329 31997 37992 43074 1827

38914 2277

36034 20087 38501 7650

48643 16125 26457 30529 3095 3124 1566 1013

45371 35812

568746

SEP CODE BB BB BV VB BV VV VB BV VV VV VB BV VB BV VV VV VV VV VV VV VV VB BV VB

Wl/2 CSEC) 5.90 6.75 7.00 6. 60 7.80 6.60 7.95 10.05 7.75

? 7..35 7.85

? 7.20 8.80 8. 55 9.75 8.90 9.05 9.40

? ? 6.80 ? ? ? 5.40

8.75

DETECTED PKS: 28 REJECTED PKS:

DIVISOR: 1.00000 MU L T I P L I E R : 1.00000

NOISE: 8.5. O F F S E T : 13

K: 16 VIAL: 14 INJ: 1


- T I T L E : P E S T I C I D E CONFIRMATORY

' CHANNEL NO: 1 SAMPLE: SAME

19: 14 13 JUL 88

METHOD: DBS

) PEAK NO

1 2 3 4 5 6 7 6 9 10 1

i2 13 14 15 16

PEAK NAME

LINDANE

ALDRIN ISODRIN

DIELDRIN ENDRIN


END KETON

TOTALS:

RESULT UG/ML 9.1852 2.5603 8.0957 6.8043 7.1590 7.5009 . 6.7999 6.1905 10.8689 1 .4254 4.5528 2.6530 4.4280 6.3268 5.4327 10.0169

100.0000

TIME CMIN) 9. 667 10.440 10.685 11.369 12.994 14.102 15.319 16.463 17.258 17.936 16.205 18.395 18,768 19.520 20.915 21.257

TIME OFFSET

0. 129

AREA SEP COUNTS CODE

-0. -0.

0. 0,

-0, 0, 0,

198 201

228 106

1 15 008 210

•0. 223

-0.056

82349 22954 72581 61003 64183 67249 60964 55500 97444 12779 40818 23785 39699 56722 48706 89806

896542

BB BV VB BB BB BB BE BB BB BV VV VV VB BB BV VB

Wl/2 CSEC) 6. 80 S. 6. 6. 7. 7. 7, 7, 1 1 . 7, 8, 13, 10, 9, 6, 10,

95 90 60 25 55 35 55 10 60 90 15 40 70 90 80

: H i i t f J : 1 f Z E R u : 10% 1 l'l 1 H . T 1 i:.f- h- f •• L I i : • 0 . i ZERO i MI N / T I CK

H E P T A C H t J ^ D-BHC _ ,

ISODR. "~REPT_£I

7>~ IT: ^ - D D E D n T - D D D

1 3 . 6 7 8

M . 5 5 4

1 5 . 4 9 4

1 7 . 6 2 1

^'TDRIN AL DO S ' • S04

J,_eND KETOJÛ-

2 4 . 1 1 7

2 5 . 5 5 2

t ^ 0 . 9 2 2

- S R : Of

6 . 9 9 4

u ^

. y <1 . 002" U . 04 9

2 . 4 8 4

1 4 . 9 8 0 '

c

3 « / 1 6 . 8 8 0

ENDO

1 8 . 6 8 3 3 ENDO S04

î:ur

2 2 . 7 15-

9 . 6 6 3

1 0 . 4 3 5

1 2 . 9 9 4

2 0 . 8 9 4

;JTITLE: PESTICIDES o ^CHANNEL N O : 2

7 PEAK

I ^ 2

0 3 3 4 1 5 1 6

7

PEAK NAME

A BHC

6 L INDANE Cl r t n t t r -

o . S o pp>^

SAMPLE:

RESULT UG/ML 0.0000 0.0000 0.0000 0,0000 0,7270 0.0000 0.0000 0,7008

STh

8

TIME CMIN) 6.272 7.006 7.757 8.260 9.676 10.490 10.704 11.002

19:

METHOD

TIME OFFSET

-0.054

-0.056

yy) io -S ' i jU / i

Tnuj

48 13

: DB606

AREA COUNTS

912 5766 1343 3644

1398160 10691 7298

1297700

- s i M

JUL 88

SEP CODE BB BB BV VB BV VV VV VV

dup

?

Wl /2 CSEC) 7. 70 6.75 6.85 10.35 7.60 10.65 9. 70 1 . l < d

/ \ ' S t - t ^ t

TITLE: PESTICIDES M

CHANNEL NO: 2

PEAK N

2 3 4 S 6 7 8 9 !0 1 1 12 1 3 14 IS 16 1 7 18 19 20 21 22 23 24 25 26 27 28 29 30

. 33 34 35 36 37 3B

PEAK NAME

A BHC

LINDANE B BHC HEPTACHLO D-BHC

ALDRIN

ISODRIN HEPT EPX

ENDO I

DDE DIELDRIN

ENDRIN DDD ENDO II DDT ENDRIN AL ENDO S04

METHOXY END KETON

TOTALS:

o. S o p/"-" -:>"

SAMPLE: 8

RESULT UG/ML 0.0000 0.0000 0.0000 0.0000 0.7270 0.0000 0.0000 0.7006 0.2871 0.5643 0.6363 0.0000 0.6335 0.0000 0.0000 8.8203 0.6439 0.0000 0.6079 0.0000 0.4901 0.6847 0.0000 0.0000 0.5491 0.3921 0.6738 0.5552 0.5482 0.5308 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 6.9734 0.6204

25.6569

' i '

TIME CMIN) 6.272 7. 006 1 . I S l 8.280 9.676 10.490 10.704 11.002 11.270 12.049 12.484 12.817 13.118 13.678 13.979 14.554 14.980 15.494 16.097 16.403 16.880 17.083 17.621 17.679 18.258 18.683 18.849 19.622 19.917 20.301 20.527 21.072 21.435 21.637 21.705 22.045 22.407 22.715

19:48 13 JUL 88

METHOD: DB608

TIME OFFSET

-0.054

-0.058 -0.050 -0.051 -0.056

-0.062

-0.106 -0.060

-0.063

-0.060 -0.067

-0.062 -0.067 -0.071 -0.066 -0.073 -0.069

-0.073 -0.075

-1.245

AREA COUNTS

912 5766 1343 3844

1398160 10691 7298

1297700 474586 960962 1178370

15061 1151820

9191 5289

31 167 961111 23966

880957 6352

703180 1006910

4832 2441 1

261466 461236 910608 578339 721298 804248 139163 54665 45930 10638 36526 4556

1610480 939995

16743000

SEP CODE BB BB BV VB BV VV VV VV VV VV VV VV VV VV VV VV VV VV vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv vv

7

? 7 7 ?

7

7 7

7 7

7 7 7 7 7 7 7

Wl/2 CSEC) 7.70 6. 75 6.85 10.35 7.80 10.85 9. 70 7. 70 6.40 8. 00 7. 20 0. 90 5. 80

8. 40 8.25 6.65 8.35

28.20 8. 85 9. 30 0. 60 1 . 20 7. 90 6.30 10.20 8.35 8.55 8. 10

34.35 9. 90 17.50 0.20

6.60 9.15








19:48 13 JUL 88

METHOD: DBS

PEAK NO

1

PEAK NAME

RESULT UG/ML 0,1344

TIME CMIN) 6. 994

TIME OFFSET

AREA COUNTS 12669

SEP CODE BB

Wl/2 CSEC) 6.65



,TI T L E : PESTICIDE CONFIRMATORY

.'CHANNEL NO: 1 SAMPLE: SAME

PEAK :

>

i

i

A

r ) c ) .1

3 |]

n

C'J

o

NO 1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 'S 6 17 18 19 20 2! 22 23 24 25 26 27

PEAK NAME

B BHC LINDANE

D-BHC

ALDRIN

ISODRIN ENDO I

DIELDRIN

ENDRIN

ENDO !I DDD ENDO S04

DDT

END KETON

TOTALS:

RESULT UG/ML 0.1344 6.6679 3.1267 6.1066 0.5933 5.8558 0.1573 0.4706 0.2972 0.2355 5.6479 5.961 1 0.4636 5.5512 0.4600 5.4831 3.5405 6.2463 2.8646 4.4226 3.9574 5.7444 1.1819 8.8039 0.8002 5.3005 10.0210

99.9999

TIME CMIN) 6.994 9.663 10.435 10.679 11.012 1 1 .364 1 1 .608 1 1 .694 12.077 12.164 12.994 14.104 15.012 15.322 16.058 16.458 17.133 17.254 17.932 18.191 ie.3?2 16.756 19.235 19.510 20.293 20.894 21.217

19:

METHOD

TIME OFFSET

0.032 0. 124

0. 157

-0.196

-0.198 0. 178

0. 103

0. 102

. .c < ' 7

-0.'004 -0.075

0. 243

-0.263

0. 086

48 13

: DBS

AREA COUNTS 12669

628620 294962 575704 55938

552053 14625 44367 28023 22202

532453 561988 43709

523343 43366

516922 333781 S890S7 270081 416960 363653 541552 111427 829986 75438

499709 944735

9427520

JUL 88

SEP CODE BB BV VV VV VV VV VV VV VV VB BB BV VV VV VV VV VV VV VV VV K i \ i

\l\ l VV vv vv vv VB

7

7 7 7 7

7 7

? o

7

7 7

Wl/2 CSEC) 6. 65 9.35 9. 15 9. 20 13.00 9.20

16. 60 4. 50 12.35 9. 80

10. 00 7.55 10.05 8.60 10.25 1 1 .70 12.50 10.05 9.90 13.30 1 1 .75 13. 10 12.50 8.90 7.65

12. 90

DETECTED PKS: 30

MULTIPLIER: 1.00000

NOISE: 71.6 OFFSET:

RACK: 16 VIAL: 15

REJECTED PKS;

6

INj: 1


(5)

CHART SPEED ATTEN: 16

0.6 CM/MIN ZERO: 10% 1 MIN/TICK

C-STAT" INJECT

ATTEN; 32 ZERO: 5% 1 MIN/TICK

Documents

A R0577 QUALITY CONTROL DATA ATI I.D. TEST : VOLATILE