A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

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    Maney Publishing and International Institute for Conservation of Historic and Artistic Works are collaborating witJSTOR to digitize, preserve and extend access to Studies in Conservation.

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    A Review of the Colour and Condition of Lindow Man 20 Years After ConservationAuthor(s): Susan Bradley, Philip Fletcher, Capucine Korenberg, James Parker and Clare WardSource: Studies in Conservation, Vol. 53, No. 4 (2008), pp. 273-284Published by: on behalf of theManey Publishing International Institute for Conservation of

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

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    273

    A Review of the Colour and Condition

    of

    Lindow Man

    20

    Years

    After

    Conservation

    Susan

    Bradley, Philip

    Fletcher,

    Capucine Korenberg,

    James

    Parker

    and Clare

    Ward

    The

    part

    body

    known

    as

    Lindow

    Man

    was

    found

    in

    a

    peat

    bog

    at

    Lindow Moss in

    August

    1984.

    Following

    excavation the

    body

    was

    transferred

    to

    the

    British

    Museum,

    where it

    was

    examined and

    conserved,

    and has been

    on

    permanent

    exhibition since 1986.

    Concerns about lightening of the colour

    were

    raised, irst in 1989 and on several occasions since, and in 2004

    a

    non-destructive

    examination

    was

    carried

    out.

    The

    history

    of

    colour

    monitoring

    of

    the

    body

    and associated

    experiments

    was

    reviewed,

    providing

    a

    more

    complete

    picture

    of

    the colour

    change,

    calculated

    as

    the

    CIE

    2000 colour

    difference

    (

    E00).

    The colour

    change

    was

    rapid

    in

    1989-1997,

    AEQ0

    =

    10.0,

    but much slower in

    1997-2004,

    AEQ0

    =

    3.4,

    when the

    light

    level

    on

    the

    body

    had been 30-50

    lux with

    less

    than

    50

    W.lumen?

    of

    ultraviolet

    light.

    When

    examined,

    the

    body

    was

    in

    good

    condition,

    the

    skin

    was

    flexible

    with

    no

    evidence

    of hrinkage

    r

    cracking.

    nalysis

    of amples

    f

    the

    polyethylenelycol ppliedduring

    onservation

    by

    ourier

    transform infrared

    spectroscopy

    showed that oxidation had occurred. The

    history of

    exhibition

    of

    the

    body,

    colour

    change

    over

    20

    years

    and condition

    of

    the

    body

    in

    2005

    are

    reported

    and discussed. Recommendations

    for future

    monitoring of

    the condition

    of

    the

    body

    and

    an

    approach

    to re-treatment

    are

    given.

    INTRODUCTION

    The

    part

    body

    known

    as

    Lindow

    Man

    was

    found

    in

    a

    peat

    bog

    at

    Lindow

    Moss

    (Cheshire,

    north-west

    England)

    in

    August

    1984.

    The

    body

    which

    was

    naturally

    preserved

    due

    to

    the acid anaerobic conditions

    in

    the

    bog,

    was

    dated

    to

    ad

    410-560

    [1];

    however,

    more

    recent

    radiocarbon

    dating

    has attributed the

    body

    to

    the first

    century

    ad

    [2]. Following

    excavation the

    body

    was

    transferred

    to

    the

    British

    Museum where

    it

    was

    examined

    [3]

    and

    conserved

    [4?6].

    The

    body

    was

    first exhibited

    at

    the

    British

    Museum

    between

    July

    1986

    and

    February

    1987

    in

    the

    Archaeology

    in Britain exhibition. Since

    then,

    concerns

    about

    lightening

    of the

    colour have been raised

    on

    several

    occasions. In 2004 the issue was raised again and itwas

    decided

    to

    take the

    body

    off

    exhibition

    for

    one

    day

    to

    allow

    a

    non-destructive

    examination

    to

    be carried

    out.

    The

    exhibition,

    colour

    change

    and

    the

    results

    of

    the

    examination

    of

    Lindow

    Man

    that

    was

    carried

    out

    on

    26

    January

    2005

    are

    reported

    here.

    Received

    October 2006

    CONSERVATION

    TREATMENT

    A

    detailed

    account

    of

    the conservation

    treatment

    carried

    out

    in

    1985-1986 has been

    published

    [4],

    and

    only

    a

    summary

    of

    the conservation

    treatment

    is

    given

    here.

    After

    consideration

    of the

    techniques

    in

    use

    to

    treat

    waterlogged

    materials

    it

    was

    decided

    that the

    body

    should

    be soaked

    in

    polyethyleneglycol

    (PEG)

    and then

    freeze-dried. PEG had been

    in

    use

    for the

    treatment

    of

    waterlogged

    wood for

    many years

    [7,

    8].

    Following

    immersion

    in

    a

    bath

    of 15%

    w/v

    PEG 400

    in

    distilled

    water

    for four weeks the

    body

    was

    wrapped

    in

    cling

    film

    and frozen

    at

    ?28?C. The

    cling

    film

    was

    removed

    and

    the

    body

    was

    freeze-dried

    at a

    pressure

    of

    100?200

    millitorr.

    At

    the end of the

    treatment

    the skin

    appeared

    to have generally lightened. Dark marks present on

    some areas

    of the

    skin

    were

    reminiscent

    of the folds of

    cling

    film. At the time of the

    treatment

    freeze-drying

    had

    mostly

    been used for

    the

    treatment

    of

    waterlogged

    wood,

    and after

    treatment

    wood

    was

    much

    lighter

    than

    it had been before

    treatment,

    so

    the

    lightening

    was

    not

    unexpected.

    Although

    not

    reported

    in

    the

    publication,

    the

    treatment

    record card

    [5]

    notes

    that,

    because

    of the

    studies

    in

    conservation

    53

    (2008)

    pages 273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

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    274 S.

    BRADLEY,

    P.

    FLETCHER,

    C.

    KORENBERG,

    J.

    PARKER AND

    C.

    WARD

    very

    dry

    appearance,

    presence

    of fine cracks

    on

    the

    stomach

    area

    and the

    strong

    colour

    contrasts

    of the

    body

    inJune 1986, three urfaceapplicationsof 10% PEG 400

    in

    distilled

    water

    and

    one

    application

    of 50% PEG 400

    were

    made

    to

    the driest and

    lightest

    areas

    of

    the

    body

    These

    applications

    had the

    effect of

    making

    the

    fine

    cracks

    disappear

    and the

    skin

    become

    more

    flexible,

    probably

    due

    to

    the humectant

    properties

    of PEG

    400.

    On

    completion

    of the conservation

    treatment

    the

    body

    appeared

    dark

    brown

    (see

    Figure

    1).

    SHOWCASE DESIGN

    Because

    of

    the

    high-profile

    nature

    of the Lindow

    Man

    find,

    it

    was

    important

    that the

    body

    was

    put

    on

    exhibition,

    but when

    considering

    environmental

    conditions for the

    display

    there was no

    precedent

    from

    which

    to

    work. At that time

    a

    relative

    humidity

    (RH)

    range

    of

    55

    ? 5%)

    was

    in

    common

    use

    for

    organic

    objects,

    but because of the considered

    sensitivity

    of

    the

    object

    the

    initial

    specification

    for RH

    was

    55 ?

    2%.

    Temperature

    was

    specified

    at

    19

    ? 2?C and

    light

    t

    100

    luxwith

    no

    ultraviolet

    (UV)

    radiation allowed

    [9].

    Because

    of the

    Figure

    1

    LindowMan after onservation in 1985.

    difficulty

    of

    achieving

    this

    specification,

    before Lindow

    Man

    went

    on

    display

    the H

    was

    widened

    to

    55

    ?

    5%,

    and the ambient gallery temperature was accepted. Later,

    in

    1989,

    the

    specification

    for

    light

    was

    reduced

    to

    50

    lux.

    It

    was

    decided that

    every

    effort

    should

    be

    made

    to

    keep

    theRH

    as

    stable

    as

    possible

    and

    that

    the best

    approach

    would be

    to

    control

    the RH

    inside the

    showcase.

    There

    was a

    history

    in

    the

    Museum

    of

    dehu

    midifying

    showcases and

    a

    modification

    of this

    approach

    was

    adopted

    [10].

    A

    Munters

    desiccant

    dehumidifier

    and

    a

    Defensor

    humidifier,

    both

    connected

    to

    a

    humidistat,

    were

    plumbed

    into the base

    of the showcase.

    A Rotronic

    HT 100

    humidity

    and

    temperature

    probe

    was

    positioned

    in

    the

    same

    area as

    the

    body

    and

    this

    provided

    a

    continuous record of the showcase conditions.

    Modifications have been made to the showcase

    design

    since the

    body

    was

    first

    put

    on

    exhibition,

    the

    most

    important

    being

    the installation

    of

    a

    canopy

    to

    reduce

    light

    levels

    on

    the

    body

    and

    a

    mixing

    chamber

    to

    reduced

    peaks

    and

    troughs

    in

    RH.

    The latter

    were

    caused because the

    capacities

    of the

    humidifier and

    dehumidifier

    were

    much

    greater

    than the volume of the

    showcase

    being

    controlled. The showcase

    constructed

    for the first exhibition

    of

    Lindow

    Man

    was

    in

    use

    until

    1997,

    when

    a new

    showcase

    was

    designed

    for

    a new

    gallery

    on

    the

    Bronze

    Age

    and Celtic

    Europe.

    The

    new

    showcase

    was

    made

    in

    metal and

    glass

    instead

    of

    wood

    and

    glass

    and utilized the

    same

    RH control

    system

    as

    the

    original

    showcase.

    EXHIBITION

    Lindow Man

    was

    first

    exhibited

    in

    the British Museum

    in

    July

    1986

    in

    the

    temporary

    xhibition

    Archaeology

    n

    Britain in

    galleries

    49 and

    50. There

    are no

    records of

    light

    measurements

    from the exhibition

    but the

    level

    is

    likely

    to

    have exceeded the

    specified

    100

    lux maximum.

    The relative

    humidity

    inside the showcase

    was

    between

    53 and 58%.The exhibition closed

    in

    February

    1987 and

    the

    body,

    with its showcase and RH

    control

    system,

    was

    then loaned

    to

    The

    Manchester

    Museum.

    There

    are no

    records

    of

    light

    levels

    during

    this loan

    period.

    On its return to the British Museum in 1988

    Lindow

    Man

    was

    redisplayed

    in

    the Central Saloon

    (galleries

    36 and

    37).

    The showcase

    was

    subject

    to

    light spill

    fromboth the

    skylight

    bove and

    spot

    lights,

    which illuminated

    an

    adjacent

    mosaic

    pavement.

    Light

    measurements

    made

    between 1988 and March

    1990 show that the

    body

    had been

    exposed

    to

    light

    levels

    of

    up

    to

    1200 lux.The

    daylight

    exposure

    would

    STUDIES IN CONSERVATION 53

    (2008)

    PAGES 273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

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    A REVIEW

    OF

    THE

    COLOUR

    AND

    CONDITION

    OF LINDOW MAN

    20

    YEARS

    AFTER

    CONSERVATION 275

    have been for

    up

    to

    15 hours

    per

    day

    in

    summer.

    An

    integrating

    light

    meter was

    installed in the

    showcase

    on

    17

    October

    1989.

    For

    five

    weeks

    from

    17

    October,

    assuming

    a 45 hours

    per

    week

    exposure

    to

    light,

    the

    illuminance

    on

    the showcase

    averaged

    175-302 lux

    [11].

    As

    a

    response

    to

    these

    findings,

    in

    March 1990

    the

    position

    and external construction

    of the showcase

    was

    changed.

    The back of the

    showcase

    was

    changed

    from

    two

    towers

    that

    contained information

    panels

    and

    the

    hologram

    of the

    body

    to

    a

    lower solid back with

    a

    canopy

    attached

    to

    it

    to

    reduce

    light

    spill.

    The showcase

    was

    turned

    to

    face the

    south

    wall

    of the

    gallery,

    beneath

    a run

    of three

    small

    skylights

    with

    closed louvres.

    To

    limit the number of hours of

    light

    exposure

    the

    body

    received,

    a

    cloth

    to

    cover

    the

    case

    during

    closed

    hours

    was

    introduced.

    Between March and

    August

    1990 the

    average

    illuminance

    on

    the

    showcase,

    calculated from

    the

    integrated

    light

    meter

    readings,

    was

    40?129

    lux.This

    indicated that the

    repositioning

    and

    change

    in

    design

    of the showcase had been successful

    in

    reducing

    light

    ingress,

    but the revised

    specification

    of 50 lux maximum

    was

    still

    not

    being

    achieved.

    Apart

    from

    a

    second loan

    to

    The Manchester

    Museum

    in

    1991,

    the

    body

    remained

    on

    exhibition

    in

    the Central Saloon until 1997.

    In

    1997

    the

    body

    was

    transferred

    to

    a new

    RH

    controlled showcase

    in

    gallery

    50.

    The

    new

    showcase

    had

    integrated

    sides

    and

    canopy,

    and

    was

    positioned

    facing

    into

    a

    corner.

    Since this

    redisplay

    the

    light

    levels

    measured

    at

    the surface of

    the

    showcase

    glass

    and

    on

    the

    body

    have been between 30

    and

    50 lux.

    MONITORING COLOUR CHANGE

    In

    early

    1989 the

    possible lightening

    of the

    body

    was

    raised.

    In

    the

    discussions

    which followed

    it

    was

    decided

    to

    take

    a

    sample

    of

    the

    skin,

    skin

    sample

    1,

    from

    the

    back

    of

    the

    body

    and

    this

    was

    done

    in

    July

    1989.This

    sample

    was

    for

    use

    in

    two

    light

    ageing investigations.

    First

    it

    was

    cut

    in

    half

    and

    then

    half of each of the

    pieces

    was

    covered

    with

    black

    tape

    to

    prevent

    light ingress

    so

    that

    the

    effect of

    light

    and dark

    ageing

    could be

    discriminated. One half

    of

    skin

    sample

    1

    was

    placed

    in

    the showcase

    with

    Lindow

    Man

    to

    serve as a

    monitor of

    colour

    change

    and remains

    in

    the

    showcase

    today.

    The

    other half of the

    sample

    was to be used in

    accelerated

    light

    ageing experiments.

    In

    February

    1990

    a

    second

    sample,

    skin

    sample

    2,

    was

    removed

    from the back of the

    body.

    Part

    was

    put

    into the showcase

    in

    March 1990 for

    two

    years

    and

    part

    used

    for

    experiment.

    When the skin

    samples

    were

    taken it

    was

    noted that the

    back of the

    body,

    which had

    not

    been

    exposed

    to

    light,

    was

    darker

    than

    the

    front.

    In

    a

    report

    on

    the

    light-fastness

    of the

    skin of

    Lindow

    Man

    two

    hypotheses

    for

    lightening

    of

    the

    skin

    were

    put

    forward: that the skin had

    lightened

    through

    exposure

    to

    light,

    and that it had

    lightened

    through

    rying

    out

    [12].

    In

    July

    1989

    an

    experiment

    was

    carried

    out to

    determine whether

    the

    drying

    out

    of

    the

    skin

    was

    responsible

    for

    the colour

    change.The

    moisture

    content was

    determined

    on

    a

    fragment

    of skin

    sample

    1

    by

    drying

    it

    at

    100?C

    to

    a

    constant

    weight, resulting

    in

    a

    weight

    loss of

    8.7%.

    The

    colour of the skin

    sample

    was

    measured before and after

    drying

    with

    no

    detectable

    (visible)

    colour

    change

    occurring, thereby showing

    the

    colour

    change

    on

    the

    body

    had

    been caused

    by light

    and

    not

    by

    the

    drying

    out

    of the skin.

    Colour

    measurements

    on

    skin

    samples

    inside the showcase

    In

    July

    1989 skin

    sample

    1

    was

    half covered and

    placed

    in

    the Lindow

    Man

    showcase

    to act

    as a

    monitor of colour

    change

    for

    the

    body.

    Four

    measurements

    were

    made

    on

    sample

    1,

    which

    was

    with the

    body

    on

    exhibition,

    between 1989 and

    2004

    [12-15].

    The method

    of

    monitoring

    the

    colour

    change adopted

    in

    1989

    was

    based

    on

    measuring

    the

    UV-visible reflectance

    spectrum

    of

    the

    sample

    using

    a

    Perkin Elmer

    55IS UV-visible

    spectrometer

    and

    was

    used for all of the

    measurements.

    From

    the

    UV-visible reflectance

    spectra

    the

    CIE

    1976

    L*a*b*

    values and CIE

    2000 colour difference

    (

    E00)

    for both the

    light-exposed

    and the dark

    (protected

    from light) parts of skin sample 1 have been calculated

    (see

    Table

    l).The

    errors

    associated with the method of

    calculation of

    AE0Qhave

    been estimated

    at

    ?

    1

    E00

    units.

    (For

    a

    description

    and calculation method of

    CIE1976

    L*a*b* values and CIE 2000

    E00

    see

    CIE Publication

    15:2004

    Colorimetry

    16].)

    The

    spectra

    from

    which the LVb*

    and

    AEQ0

    for skin

    sample

    1

    were

    calculated

    are

    shown

    in

    Figure

    2a

    (light

    exposed)

    and

    Figure

    2b

    (dark).

    From

    Table

    1

    the

    colour

    change

    (AEQ0)

    between

    1989 and 1997

    of

    the

    light-exposed

    area

    of

    skin

    sample

    1

    averages

    1.24

    E00

    units

    per

    year

    whereas the

    change

    between

    1997,

    when the

    light

    level

    was

    reduced

    to

    30-50

    lux,

    and 2004

    averages

    0.45

    AEQ0

    units

    per

    year.

    The

    major

    colour

    change

    appears

    to

    have occurred

    between 1989 and

    1995,

    and

    the

    biggest change

    would

    be

    expected

    to

    have occurred

    in

    the

    1989?1990

    period,

    when the

    light

    exposure

    was

    highest.

    However,

    without

    annual

    measurement

    of

    the reflectance

    spectrum

    this

    cannot

    be confirmed

    from this

    data

    set.

    The covered

    area

    of the

    sample

    (dark)

    has

    also

    changed

    colour

    with

    STUDIES

    IN CONSERVATION

    53

    (2008)

    PAGES 273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

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    A REVIEWOF

    THE

    COLOUR

    AND

    CONDITIONOF LINDOW

    MAN 20

    YEARS AFTER CONSERVATION

    277

    Table 2 CIE 1976 L*a*b* nd CIE

    2000

    AE

    for kin

    ample

    2

    exposed

    for

    238000 lux-hours

    Value Light Dark

    1990 1991 1990

    1991

    L*

    41.7

    46.3

    41.7

    43.2

    a*

    4.74

    6.08

    4.74

    4.99

    b* 2.19 5.69

    2.20

    2.71

    AEm

    0 5.30

    0 1.50

    period. Light

    levels

    on

    the skin

    sample

    were

    highest

    in

    the

    period

    between

    1989,

    when it

    was

    first taken

    from the

    back

    of the

    body,

    and March 1990

    and

    light

    fading

    could

    have

    been

    rapid during

    this

    period.

    Skin

    sample

    2

    was

    taken from the back of

    the

    body

    inMarch

    1990 and

    immediately

    put

    into the showcase. This

    was

    to

    check that the

    rate

    of

    fading

    had slowed down

    following changes

    in

    the showcase

    to

    reduce

    light

    levels

    on

    the

    body,

    but

    in

    the

    one

    year

    to

    March

    1991 E

    was

    5.3. This is

    quite

    a

    rapid change

    given

    that

    the

    light

    exposure

    the

    sample

    received

    was

    238000

    lux-hours.

    The

    average

    illuminance

    in

    the showcase

    was

    101

    lux,

    which

    was

    considerably

    lower

    than the

    light

    levels

    when

    skin

    sample

    1

    was

    first

    put

    into the

    showcase.

    Given

    thatboth

    samples

    had

    been taken from the back

    of

    the

    body

    which

    had

    not

    had

    any

    light

    exposure,

    this

    may

    be

    an

    indication that

    rapid

    change

    occurs

    when the

    conserved

    skin

    is

    first

    exposed

    to

    light

    and the

    rate

    then

    slows

    down.

    This would

    be

    expected

    as

    these

    types

    of

    reactions

    are

    exponential.

    From

    Tables

    1

    and

    2 it

    can

    be

    seen

    that the

    largest

    component

    of the colour

    change

    occurs

    in

    L*

    and

    indicates

    lightening.

    Much

    smaller

    changes

    in

    a*

    and

    b*

    indicate

    respectively

    increases

    in

    the

    red

    and

    yellow

    components

    of the colour.

    However,

    too

    few

    colour

    measurements

    were

    made

    on

    skin

    sample

    1

    to

    confirm this

    hypothesis.

    A

    graph

    of

    E()0

    versus

    date for skin

    sample

    1

    suggests

    a

    slowing

    of the

    colour

    change

    occurred

    following

    the

    redisplay

    f

    Lindow

    Man in

    1997

    (see

    Figure

    3).

    When

    the colour

    change

    which occurred

    on

    sample

    2

    in

    one

    year

    (1990-1991)

    is

    plotted

    on

    the

    graph

    at

    the

    one-year

    point

    the

    hypothesis

    that the maximum colour

    change

    occurred when the body

    was

    first exposed

    to

    light is

    further

    supported.

    Colour

    change

    was

    also noted

    on

    the covered section

    of the

    two

    skin

    samples

    put

    into

    the showcase

    with the

    body. Although

    this

    change

    was

    much smaller

    than the

    change

    which

    occurred with

    light,

    it

    was

    significant

    and

    suggests

    that

    a

    thermal

    chemical

    change

    occurred

    resulting

    in

    lightening.

    Between 1997 and

    2004 the

    -.-..?

    .

    '

    ;.?'

    -

    4

    8

    12

    16

    Date/year

    Figure

    3 E

    versus

    date

    (years)

    for kin

    ample

    1

    exposed

    in

    the

    Lindow

    Man showcase

    1989-2004

    with the

    ne-year

    ?E for

    kin

    sample

    2.

    colour

    change

    of the

    dark

    portion

    of the

    sample

    was

    just

    less than

    half

    that f the

    light

    portion.

    This

    suggests

    that

    some

    colour

    change

    would

    occur

    on

    the

    skin

    even

    if Lindow Man

    were

    kept

    in

    the

    dark

    at

    ambient

    temperature

    and

    not

    exhibited.

    ASSESSMENT

    OF

    THE

    CONDITION

    OF LINDOW

    MAN

    Lindow

    Man

    was

    removed from

    exhibition

    on

    26

    January

    2005

    for

    one

    day

    for examination.

    It

    was

    not

    considered

    safe

    to

    move

    the

    body

    to

    the

    laboratory

    and

    the examination

    was

    carried

    out

    in the

    Department

    of

    Prehistory

    and

    Europe

    area

    off

    gallery

    40. This

    meant

    that it

    was

    not

    possible

    to

    carry

    out

    any

    non-destructive

    analysis

    on

    the

    body.

    A Konica

    stereomicroscope

    and

    a

    floor stand

    were

    taken

    to

    the

    room

    to

    facilitate

    the

    examination and

    a

    Minolta 2600D

    spectrophotometer

    was

    available

    to

    make colour

    measurements

    on

    the

    body

    Agreement

    was

    obtained

    from

    the

    curator

    responsible

    for the

    object,

    Dr

    J.D.

    Hill,

    to

    remove

    surface

    samples

    for

    analysis.

    Making

    pH

    measurements

    on

    the

    skin

    was

    discussed,

    but

    no

    suitable

    method for

    this

    was

    available.

    There

    was no

    discussion

    on

    sampling

    the skin

    because

    the examination

    was seen as a

    first step in facilitating

    more

    detailed

    examination

    should this be

    necessary

    Physical

    appearance

    On initial examination

    there

    appeared

    to

    be

    a

    slight

    white

    bloom

    on

    the

    surface,

    possibly

    due

    to

    a

    layer

    of

    dust.

    Some

    small white

    specks

    were

    present (see

    STUDIES

    IN

    CONSERVATION

    53

    (2008)

    PAGES

    273-284

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    278

    S.

    BRADLEY,

    P.

    FLETCHER,

    C.

    KORENBERG,

    J.

    PARKER

    AND

    C. WARD

    Figure

    4

    Part of

    the bdomen

    withwhite

    particles

    present,

    2005.

    Figure

    4),

    and

    some

    samples

    of these

    were

    taken. Under

    the

    microscope

    the

    appearance

    of

    the white

    particles

    suggested

    that

    some

    were

    calcium

    sulphate

    (i.e.

    plaster

    dust associated with

    building

    work).

    Other

    particles

    appeared

    to

    be

    a

    textile,

    possibly

    Tyvek?,

    a

    non-woven

    fabric used

    to

    fix

    the

    body

    to

    a

    Perspex?

    support

    during

    the

    freeze-drying

    treatment,

    and

    white solid

    wax.

    The

    front

    surface

    of the

    skin

    generally

    appeared

    to

    be

    lighter

    n

    colour

    than the

    original

    photographs

    taken

    after

    completion

    of the

    treatment.

    The

    light

    areas

    of the

    skin

    appeared

    lighter,

    but

    it

    was

    not

    clear

    if

    the darker

    areas

    had

    lightened

    to

    the

    same

    extent.

    It

    was

    felt that

    it

    would

    be

    useful

    to

    see

    the

    underside

    of

    the

    body,

    which

    had

    not

    been

    exposed

    to

    light.

    Turning

    over

    the

    leg

    to

    examine

    the underside

    was

    considered,

    but

    this

    was

    very

    fragile

    with loose

    fragments

    present.

    However,

    it

    was

    possible

    to

    look

    at

    the

    underside

    of

    parts

    of the

    leg by

    gently

    lifting

    p

    selected

    areas.

    his

    revealed

    that

    the underside

    was

    exposed

    bone,

    which

    was

    dark

    in

    appearance,

    with

    no

    skin

    present,

    and

    did

    not

    provide

    a

    suitable

    comparison

    with the

    front surface. An

    attempt

    was

    made

    to

    examine the underside of the

    body

    by

    slightly

    aising

    t in the

    shoulder

    area.

    Where

    visible,

    the

    underside

    of the

    body

    was

    possibly

    slightly

    arker than

    the

    exposed

    side but there

    was not

    a

    marked

    difference,

    this

    rea

    of

    the

    body being

    dark.

    Examination under

    the

    microscope

    showed

    the

    skin

    to

    be

    coherent,

    with

    no

    sign

    of

    shrinkage

    cracks

    or

    dryness

    and

    flaking.

    In

    the

    original

    treatment

    reports

    [5], Margaret

    McCord,

    Organic

    Materials

    Conservator,

    mentions the presence of cracks in the stomach area.

    There

    were

    some crease

    lines

    in the skin

    in

    this

    area

    but

    no

    breaks

    in the surface of the

    skin

    were

    visible.

    This

    suggested

    that the PEG

    surface

    applications

    described

    on

    the

    treatment

    record card

    had been

    successful

    in

    hydrating

    the skin and

    closing

    the cracks

    seen at

    the

    time.

    It

    also

    suggested

    that the PEG

    was

    still

    acting

    as an

    humectant.

    The

    surface

    of

    the

    skin

    had

    a

    waxy

    feel

    and

    was

    supple,

    suggesting

    that

    the PEG

    had

    not

    migrated

    from

    the skin.

    Analysis

    of

    samples

    taken

    from the

    body

    Analysis

    of

    solid

    white

    surface

    deposits

    and materials

    which

    were

    readily

    extractable

    from the

    skin

    was

    necessary

    to

    establish

    the

    presence

    and condition

    of the

    PEG

    treatment. Four

    samples

    (i?iv)

    of the

    white

    deposits

    were

    taken

    by

    brushing

    them into

    a

    sample

    tube.

    The

    surface

    of

    the skin

    was

    sampled

    using

    cotton

    wool

    buds

    dampened

    with

    water,

    since

    PEG

    is

    a

    water-soluble

    wax.

    Damp

    swabs

    were

    passed lightly

    over

    the

    area

    of

    interest

    five

    times. The

    sampling

    positions

    are

    shown

    in

    Figures

    5

    and

    6.

    Examination of the white surface

    deposits

    under an

    optical

    microscope

    showed

    that

    sample

    i had

    a

    textile

    like

    structure

    suggesting

    it

    was a

    residue

    from the

    use

    of

    Tyvek?

    during

    conservation;

    samples

    ii?iv

    had

    a

    granular

    texture.

    In

    the

    laboratory,

    the

    swabs

    were

    soaked

    for

    24 hours

    in 20

    mL

    of

    water

    deionized

    to

    18.2

    to

    extract

    any

    soluble

    material.

    The swab

    was

    then removed

    and the

    solution

    evaporated

    to

    dryness.

    The residues

    were

    slightly

    brown

    in colour

    and

    all

    were

    soft,

    waxy

    materials.

    The

    colour

    was

    probably

    due

    to

    the extraction

    of colorant

    when

    sampling

    with

    a

    swab. The swab

    from

    the

    leg

    sample

    was

    redissolved

    and

    double

    filtered

    in

    the

    high-purity

    deionized

    water

    before

    allowing

    the

    solution

    to

    evaporate.

    This residue

    was

    transparent

    and

    oil-like,

    similar

    to

    new

    PEG 400.

    All of the

    samples

    were

    analysed

    using

    the

    Nicolet

    Avata 360 Fourier transform infrared

    (FTIR)

    spectro

    meter

    with

    a

    diamond cell

    attachment. The

    results

    of

    the

    analysis

    are

    shown

    in

    Table

    3.

    All

    but

    one

    of

    the

    samples

    analysed

    had

    polyethylene

    glycol

    as

    the

    major

    component,

    and

    all

    of

    the

    spectra

    showed

    the

    presence

    of

    carbonyl

    peaks

    which

    suggest

    oxidation

    of the

    PEG has

    occurred.

    Too little

    residue

    was

    extracted

    from

    the

    swab from

    the

    dark

    area on

    the

    shoulder

    for

    a

    good

    spectrum

    to

    be

    obtained.

    The

    presence

    of

    high

    levels

    of PEG

    in

    three of the

    swabs

    taken from the skin surface confirmed that, for most of

    the

    body,

    migration

    away

    from the

    skin surface

    into the

    body

    had

    not

    occurred,

    nor

    had

    the

    PEG

    degraded

    to

    a

    level

    where

    it

    volatilized

    from

    the skin surface.

    Analysis

    of the

    sample

    from the

    shoulder

    area

    did

    not

    give

    a

    good

    spectrum

    for

    PEG.

    This

    may

    indicate

    that

    migration

    from the

    surface has occurred

    in this

    area,

    or

    merely

    that

    an

    additional

    coating

    of PEG

    was

    not

    a'pplied

    at

    the

    STUDIES IN

    CONSERVATION

    53

    (2008)

    FACES

    273-284

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    A

    REVIEW OF

    THE

    COLOUR

    AND CONDITION OF

    LINDOW

    MAN 20

    YEARS

    AFTER

    CONSERVATION

    279

    Swab

    fromley

    Sample

    i

    Figure

    6

    Sampling

    positions

    on

    the

    eg,

    005.

    Table 3 Results of

    TIR

    analysis

    of

    samples

    taken from he

    ody

    Sample

    Identification Comment

    Sample

    i

    Sample

    ii

    Sample

    iii

    Sample

    iv

    Swab from

    ight

    rea on

    the bdomen

    Swab from

    ark

    area on

    the shoulder

    Internalwab

    Swab from

    ight

    rea on

    the

    leg

    Polyethylene lycol

    Polyethylene lycol

    Polyethylene lycol

    Polyethylene lycol

    Polyethylene lycol

    N/A

    Polyethylene lycol

    Polyethylene

    lycol

    Oxidation

    Oxidation

    Oxidation

    Oxidation

    Oxidation

    Not

    enough

    extracted

    for

    ood

    spectrum

    Oxidation

    High

    level f oxidation

    STUDIES

    IN CONSERVATION 53

    (2008)

    PAGES

    273-284

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    280

    S.

    BRADLEY,

    P.

    FLETCHER,

    C.

    KORENBERG,

    J.

    PARKER AND

    C.

    WARD

    end of the conservation

    treatment.

    The skin

    in

    this

    area

    did

    not

    feel

    noticeably

    less

    supple

    than the skin

    in

    other

    areas

    of the

    body.

    PEG

    400 is a low molecular

    weight liquid

    with a

    consistency

    similar

    to

    heavy

    oil. The

    presence

    of solid

    white

    particles,

    identified

    as

    PEG,

    on

    the

    surface of the

    body

    is

    puzzling

    since

    oxidation of PEG

    resulting

    in

    chain

    scission

    was

    shown

    to

    occur

    when the breakdown

    of solid PEG 6000 used

    to

    consolidate

    stone

    was

    investigated [19].

    All the

    samples analysed

    showed

    a

    peak

    at

    around

    1700 cm 1

    which

    is

    normally

    associated

    with

    carbonyl

    groups

    (carbon?oxygen

    double

    bonds).

    These

    species

    are

    not

    present

    in

    samples

    of fresh PEG

    400 which

    were

    analysed

    as a

    comparison.

    The

    presence

    of

    carbonyl

    groups

    in

    the double filtered

    sample

    from

    the

    leg

    swab

    indicated

    that

    they

    were

    not

    impurities

    and that oxidation of the PEG chain had occurred. The

    susceptibility

    of PEG 400

    to

    oxidation

    was

    investigated

    in

    an

    accelerated

    ageing

    test.

    New

    PEG 400

    was

    placed

    in

    a

    sealed

    container in

    the

    oven

    at

    60?C

    for

    two

    weeks.

    It

    was

    then

    analysed

    and found

    to

    have

    a

    similar

    peak

    at

    1700

    cm 1. The

    intensity

    was

    less

    than that

    found

    on

    the

    body

    but

    this

    s

    likely

    to

    be due

    to

    the lower level

    of

    oxygen

    available

    in

    the sealed container.

    The solid

    wax

    surface

    deposits

    on

    Lindow

    Man

    could have formed

    through

    combination of the

    reactive

    carbonyl

    group

    with

    gaseous

    or

    particulate

    materials

    in

    the

    air,

    forming

    materials

    that either

    share

    absorption

    bands with PEG

    or

    do

    not

    absorb

    in

    the infrared.

    Colour

    measurements

    on

    the

    body

    During

    the

    examination,

    two

    colour

    measurements

    were

    made

    directly

    on

    the

    body

    using

    the Minolta

    2600D

    spectrophotometer.The

    L*a*b*

    measurements are

    given

    in

    Table

    4.

    These

    measurements were

    compared

    with

    measurements

    made

    on

    the

    body

    in

    1997

    using

    a

    Minolta

    Chroma-Meter CR300

    [13].

    The

    number

    of

    measurements

    made

    at

    each location

    in

    1997

    is

    not

    known.

    However,

    the

    measuring

    equipment

    makes

    and

    averages

    multiple

    measurements

    when

    each

    measurement

    is

    taken,

    and this is

    a

    mechanism for

    averaging

    differences

    in

    results due

    to

    topography

    of the

    surface.

    The

    locations of

    the

    measurements

    made

    in

    2005

    and the

    approximate

    locations of those made

    in

    1997

    are

    shown

    as

    sampling

    points

    A?E in

    Figure

    5.

    Although

    not

    at

    identical

    locations,

    the

    measurements

    were

    made

    on

    the

    same areas

    of the

    body.

    Because

    the

    locations

    of the

    1997

    measurements

    could

    not

    be

    precisely

    located and

    because

    there

    would

    be

    an error

    between

    measurements

    with different

    equipment

    even

    if

    they

    were

    made

    at

    the

    same

    time,

    the calculated

    AEQ0

    values shown

    in

    Table 4

    have

    an

    unknown

    error.

    The value of these calculations is

    that

    they

    show whether there is

    any

    relationship

    between

    the colour

    change,

    AEQ0,

    determined

    on

    skin

    sample

    1

    and that

    on

    the

    body.

    The colour

    change

    on

    the

    light

    area

    of the

    body

    between 1997 and

    2005,

    AEQ0

    =

    1.48,

    is of the

    same

    order of

    magnitude

    as

    that determined

    on

    skin

    sample

    1

    between 1997 and

    2004,

    E00

    =

    3.4.

    Location

    masks

    were

    made for the

    measuring

    points

    used

    in

    2005

    so

    that

    repeat

    measurements

    can

    be made

    in

    the future.

    It is

    worth

    noting

    that the

    L*a*b*

    values calculated

    from the UV-visible

    spectra

    taken

    on

    the skin

    samples

    1

    and

    2

    are

    different

    to

    those determined

    directly

    on

    the

    body

    using

    the

    Minolta Chroma-Meter

    CR300,

    and

    the Minolta

    2600D

    spectrophotometer

    (e.g.,

    compare

    the 1997 and 2004 L*a*b* values for the light-exposed

    area

    of

    sample

    1

    with the

    values

    given

    for the abdomen

    area

    in

    Table

    4).

    The

    measurements

    using

    the Minolta

    spectrophotometers

    will

    always

    be different from the

    measurements

    using

    the

    UV-visible

    spectrometer,

    as

    the

    two

    spectrophotometers

    have

    a

    different

    geometry

    from

    the UV-visible

    spectrometer.

    Discussion

    The

    condition

    of the

    skin

    was

    found

    to

    be

    good.

    It

    was

    supple,

    no

    shrinkage

    cracks

    were

    observed and there

    was

    no

    physical

    evidence

    or

    smell

    suggesting

    putrefaction

    was

    in

    progress.

    This

    suggests

    that the chemical

    change

    which is

    altering

    the colour is not

    physically affecting

    the

    skin

    structure,

    only

    the

    colorant,

    the

    nature

    of which

    remains unclear. PEG

    was

    present

    at

    the surface of the

    skin and should be

    acting

    as an

    humectant

    keeping

    the

    skin

    hydrated.There

    is

    the

    potential

    for

    the

    hydration

    to

    promote

    hydrolysis

    reactions

    on

    either the colorant

    or

    the

    collagen

    in

    the

    skin

    or

    both,

    but

    there

    is

    no

    evidence

    of

    hydrolysis

    of the skin

    occurring.

    There is

    more concern

    about the chemical

    stability

    of

    the

    PEG used

    in

    the

    conservation

    process.The

    chemical

    analysis

    indicates that the

    PEG

    is

    oxidizing,

    which could

    result

    in

    chain scission and

    increasing acidity,

    but there is

    no

    evidence of

    damage occurring

    because of this.

    CONCLUSIONS

    Memory,

    photographic

    records

    and colour

    measurements

    on

    skin

    samples exposed

    in

    the showcase with the

    body

    all

    show

    that the

    colour of Lindow

    Man

    has

    changed

    and

    lightened

    since the

    conservation

    in

    1984-1986.The

    very

    high light

    evelswhich existedwhen the

    body

    was

    first

    STUDIES

    IN

    CONSERVATION

    53

    (2008)

    PAGES 273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

    10/13

    A

    REVIEW OF

    THE

    COLOUR

    AND

    CONDITION

    OF

    LINDOW MAN

    20

    YEARS AFTER

    CONSERVATION

    281

    Table

    4

    CIE 1976 L*a*b'measurements

    and CIE 2000 E

    on

    Lindow

    Man,

    1997 and

    2005

    Date

    Value Abdomen

    (Light

    rea)

    Shoulder

    (Dark rea)

    E

    1997/2005

    1997

    position

    A

    light

    rea on

    abdomen

    1997

    position

    light

    rea

    on

    abdomen

    1997

    position

    C dark

    area

    on

    shoulder

    26

    January

    005

    (position

    -

    dark

    area,

    position

    E

    -

    light

    rea)

    L*

    a*

    b*

    L*

    a*

    b*

    L*

    a*

    b*

    L*

    E

    betweenmeasurements

    34.1

    11.8

    14.3

    35.4

    12.6

    15.7

    38.6

    11.9

    20.1

    1.48

    23.9

    3.54

    1.97

    24.1

    2.30

    2.08

    0.16

    5.30

    1.59

    put

    on

    exhibition in the

    British

    Museum

    in

    1986 and

    continued until

    1997,

    although

    with

    some

    moderation

    in

    1990,

    have

    been the

    major

    cause

    of the

    lightening.

    Lightening

    is

    still

    occurring,

    even

    though

    the

    light

    level

    on

    the

    body

    has

    been 30-50 lux since

    1997.

    It

    is

    possible

    that

    a

    thermal

    ageing

    reaction,

    which is

    indicated

    by

    the

    colour

    change

    of

    areas

    of skin

    samples

    1

    and

    2

    which

    were

    protected

    from

    light,

    is

    contributing

    to

    this

    change.

    The

    average

    rate

    of

    lightening

    per

    year

    as

    measured

    on

    skin

    sample

    1,

    has

    slowed

    since 1997 from

    AEQQ

    per year

    -

    1.25 for the

    1989-1997

    period

    to

    AEQQ

    per year

    =

    0.45

    for the 1989?2005 period. When sample 2 was put into

    the Lindow

    Man

    showcase

    in

    1990

    a

    substantial colour

    change

    of

    E00

    =

    5.3

    occurred

    in

    one

    year,

    even

    though

    the

    body

    had been

    repositioned

    in

    the

    gallery resulting

    in

    a

    considerable decrease

    in

    light

    levels. Both skin

    samples

    were

    taken from the

    back of the

    body,

    which

    had

    not

    been

    subjected

    to

    light

    and should

    therefore

    represent

    the colour

    of

    the

    body

    (ignoring

    the minimal

    dark

    aging

    contribution)

    when it

    was

    first

    exhibited.The

    rate

    of

    change

    in

    the skin

    colour

    was

    highest

    when the

    samples

    were

    first

    exposed,

    which

    supports

    the

    reports

    of

    lightening

    f the

    body during

    the 1986-1989

    period

    when it

    was

    first

    put

    on

    exhibition.

    The PEG

    applied during

    the

    conservation

    treatment

    has

    oxidized,

    and this

    change

    could result in

    migration

    and

    ultimately

    have

    an

    adverse

    effect

    on

    the

    skin,

    since

    the

    pH

    of

    PEG

    becomes

    more

    acidic

    as

    it

    deteriorates.

    However,

    visual

    examination

    of

    the skin

    showed it

    to

    be in

    good

    condition with

    no

    cracks

    forming,

    and

    no

    shrinkage

    or

    drying

    out

    occurring.

    The

    leg,

    which

    was

    in

    a

    much

    worse

    condition

    than the main

    body

    when

    excavated and

    consisted

    mainly

    of

    bone,

    had

    a

    friable

    surface,

    although

    analysis

    showed

    that PEG

    was

    still

    present

    at

    the

    surface.

    In

    the

    20

    years

    since its

    conservation the Lindow

    Man

    body

    has remained

    in

    a

    good

    condition,

    the

    only

    major

    change

    being

    lightening

    of the colour.

    Recommendations for

    regular

    monitoring

    of the

    condition

    of

    the

    body,

    identification

    of the colorant

    and

    re-treatment,

    should

    this become

    necessary,

    are

    as

    follows:

    Colour

    measurements

    should be made

    on

    the

    body and on skin sample 1,which is exhibited

    with

    it,

    annually

    using

    the Minolta

    2600D

    spectro

    photometer.

    Colour

    measurements

    should be made

    on

    skin

    sample

    1

    annually, measuring

    the UV-visible

    spectrum

    with

    the Perkin Elmer

    55IS UV-visible

    Spectrometer

    and

    calculating

    L*a*b* values

    and

    E00

    from the

    graph

    to

    maintain

    continuity

    with the

    measurements

    made

    on

    the

    sample

    since 1989.

    An

    annual examination of

    the

    body

    should be

    made

    to ensure

    that

    the

    skin

    is

    not

    physically deteriorating.

    A

    protocol

    for

    doing

    this in the

    gallery

    should be

    determined.

    The

    chemical

    stability

    f

    the

    PEG

    should

    be deter

    mined

    annually

    from

    swabs

    taken

    from

    the surface of

    the

    skin.The

    potential

    for

    gas

    chromatography?mass

    spectrometry

    (GC-MS)

    as

    a

    means

    of

    analysis

    to

    provide

    a

    greater

    amount

    of

    useful

    information

    should

    be

    investigated.

    A

    more

    detailed

    survey

    of

    the

    presence

    of

    PEG

    in

    the

    skin

    should be undertaken.

    STUDIES IN

    CONSERVATION

    53

    (20?8)

    PAGES

    273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

    11/13

    282 S.

    BRADLEY,

    P.

    FLETCHER,

    C.

    KORENBERG,

    J.

    PARKER

    AND

    C. WARD

    The

    possibility

    of

    determining

    a

    chemical

    fingerprint

    of the skin

    to

    allow

    comparison

    in

    the

    future should

    be

    investigated.

    Working

    with the skin

    samples

    stored

    separately

    to

    the

    body,

    analysis

    to

    determine

    the

    colorant

    should

    be

    carried

    out.

    Any

    re-treatment

    of

    the

    body

    should be carried

    out

    using

    PEG after

    an

    investigation

    of PEG

    grades

    available

    at

    the

    time.

    ACKNOWLEDGEMENTS

    The authors would like

    to

    acknowledge

    the work of

    Vincent

    Daniels

    who carried

    out

    colour

    monitoring

    on

    Lindow

    Man

    between 1989 and

    1997,Allyson

    Rae

    for her

    support

    during

    this

    review

    and

    Dr

    J.D.

    Hill

    for

    permission to examine and take surface samples from

    the

    body.

    REFERENCES

    1

    ?tlet,

    R.L., Walker,

    A.J.,

    and

    Dadson,

    S.M.,

    'Report

    on

    radio

    carbon

    dating

    of the Lindow Man

    by

    AERJE, Harwell',

    in

    Lindow

    Man:

    The

    Body

    in

    the

    Bog,

    ed.

    I.M.

    Stead,

    J.B.

    Bourke and

    D.

    Brothwel,

    British

    Museum

    Publications,

    London

    (1986)

    27-30.

    2

    Gowlett,

    J.A.J.,

    Hedges,

    R.E.M.,

    and

    Law, I.A.,

    'Radiocarbon

    accelerator

    (AMS)

    dating

    of

    Lindow

    Man',

    Antiquity

    63

    (1989)

    71-79.

    3

    Brothwell,

    D.,

    The

    Bog

    Man

    and

    the

    Archaeology

    of

    People,

    British

    Museum

    Publications,

    London

    (1986).

    4

    Omar,

    S.,

    McCord, M.,

    and

    Daniels, V.,

    'The

    conservation

    of

    bog

    bodies

    by

    freeze-drying',

    Studies inConservation 34

    (1989)

    101-109.

    5

    McCord,

    M.,

    and

    Omar, S.,

    'Conservation

    record of

    bog

    body

    from Lindow

    Moss,

    retrieval

    by

    requisition

    number

    1984,10

    2.41.1

    (body),

    1984,10-2.41.2

    (leg)',

    Unpublished

    report,

    Department

    of

    Conservation and Scientific

    Research,

    British

    Museum

    (1985).

    6

    Daniels,V.,'Selection

    of

    a

    conservation

    process

    for

    Lindow

    Man',

    in

    Human

    Mummies,

    ed.

    .

    Spindler, H.Wilfing,

    E. Rastbichler

    Zissernig

    and H.

    Nothdurfter,

    Springer

    Wien,

    New

    York,

    (1996)

    173-181.

    7

    Barkman,

    L.,'The

    preservation

    of the

    warship

    Wasa,

    in

    Problems

    of

    the

    Conservation

    of

    Waterlogged

    Wood,

    ed.W.A.

    Oddy,

    Maritime

    Monographs

    and

    Reports

    No.

    16,

    National

    Maritime

    Museum,

    London

    (1975)

    65-105.

    8

    Rosenqvist,

    A.,'Experiments

    on the conservation of

    waterlogged

    wood

    and

    leather

    by

    freeze

    drying',

    in

    Problems

    of

    the onservation

    of

    Waterlogged

    Wood,

    ed.W.A.

    Oddy,

    Maritime

    Monographs

    and

    Reports

    No.

    16,

    National

    Maritime

    Museum,

    London

    (1975)

    9-23.

    9

    Omar, S.,

    Memo

    on

    Specification

    or

    the

    Display of

    Lindow

    Man,

    7

    fune

    ?985,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1985).

    10

    Newey,

    H.,

    '17

    years

    of

    dehumidified

    showcases

    in

    the

    British

    Museum',

    in

    ICOM

    Committee

    for

    Conservation,

    8th

    Triennial

    Meeting,

    Sydney: Preprints,

    ed.

    J.

    Bridgland,

    The

    Getty

    Conservation Institute,Los

    Angeles

    (1987) Vol. Ill 901-907.

    11

    Daniels, V.,

    Integrated

    Light

    Measurements

    on

    Lindow

    Man,

    Conservation Research internal

    report

    1991/2,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1991).

    12

    Daniels,V,

    Light

    Fastness

    of

    the kin

    of

    indow

    Man,

    Conservation

    Research internal

    report

    1989/15,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1989).

    13

    Daniels,

    V.,

    The

    Skin Colour

    of

    Lindow

    Man,

    Conservation

    Research

    internal

    report

    1996/2,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1996).

    14

    Daniels, V.,

    The

    Skin Colour

    of

    Lindow

    Man,

    Conservation

    Research

    internal

    report

    1997/17,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1997).

    15

    Fletcher, P.,

    Skin Colour

    of

    Lindow

    Man,

    Conservation Science

    and

    Analytical

    Chemistry

    internal

    report

    2004/6,

    Department

    ofConservation, Documentation and Science, BritishMuseum,

    London

    (2004).

    16 CIE Technical

    Report,

    Colorimetry,

    3rd

    edn,

    Publication

    15:2004,

    CIE Central

    Bureau,Vienna

    (2004).

    17

    Daniels, V.,

    The

    Fading

    of

    the

    Skin Colour

    of

    Lindow

    Man,

    Conservation Research internal

    report

    1991/29,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1991).

    18

    Daniels, V.,

    The

    Skin Colour

    of

    Lindow

    Man,

    Conservation

    Research

    internal

    report

    1993/22,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1993).

    19

    Thickett,

    D.,

    Removal

    of

    Polyethylene Glycol from

    Stone

    (II):

    Preliminary

    Investigation of

    Degradation of

    Polyethylene Glycol,

    Conservation Research internal

    report

    1993/11,

    Department

    of

    Conservation,

    British

    Museum,

    London

    (1993).

    AUTHORS

    Susan

    Bradley

    has

    a

    degree

    in

    chemistry

    from

    the

    University

    of

    London,

    UK.

    In

    1972 she

    joined

    the British

    Museum, UK,

    to

    work

    on

    conservation

    problems, researching

    deterioration

    mechanisms and

    conservation

    methods

    for

    a

    wide

    range

    of

    materials

    found

    in

    the

    collections.

    In

    1988 she became head of

    the

    Conservation

    Research

    Group leading

    a

    small

    team

    of

    scientists

    in

    object-centred

    research,

    and

    in

    2003

    head

    of

    Conservation

    Science and

    Analytical Chemistry

    in

    the

    Museum's

    newly

    formed

    Department

    of

    Conservation,

    Documentation and Science.

    In

    the

    last few

    years

    her

    main interest has been in implementing pragmatic

    approaches

    to

    preventive

    conservation

    underpinned

    by

    the

    results of the

    Group's

    research.

    In

    July

    2006 she

    retired from the

    British

    Museum.

    Address:

    Department of

    Conservation and

    Scientific

    Research,

    The

    British

    Museum,

    Great

    Russell

    Street,

    London WC?B

    3DG,

    UK. Email:

    [email protected]

    STUDIES

    IN

    CONSERVATION

    53

    (2008)

    PAGES

    273-284

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  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

    12/13

    A REVIEW

    OF

    THE

    COLOUR

    AND

    CONDITION OF LINDOW MAN 20

    YEARS

    AFTER

    CONSERVATION 283

    Philip

    Fletcher

    obtained

    a

    degree

    in

    chemistry

    from

    the

    University

    of

    York,

    UK,

    followed

    by

    a

    Master's

    degree

    in

    analytical chemistry

    from

    the

    University

    of

    Aberdeen, Scotland,

    and

    a

    PhD

    from the

    University

    of

    Plymouth,

    UK,

    developing

    instrumentation for

    analysing

    additives

    in

    diesel fuel.

    He

    then

    spent

    two

    years

    as a

    research

    fellow

    at

    the

    University

    of

    Pretoria,

    South

    Africa

    developing

    instrumentation

    for

    automating

    methods

    of chemical

    analysis.

    He

    joined

    the

    British

    Museum

    in

    2004

    as

    a

    conservation scientist

    analysing

    glass

    and

    other

    inorganic

    material,

    as

    well

    as

    monitoring

    pollutant

    gas

    concentrations

    in

    showcases. Address:

    as

    Bradley. Email:[email protected]

    Capucine

    Korenberg

    obtained

    a

    degree

    in

    physics

    from the Ecole Nationale

    Sup?rieure

    de

    Physique

    de Grenoble, France in 1998. She then specialized in

    the

    durability

    of adhesive

    joints

    at

    Imperial

    College

    London,

    UK,

    and

    completed

    a

    PhD

    programme

    in

    2002.

    After

    post-doctoral

    research

    at

    the

    Victoria

    and Albert

    Museum, London,

    UK

    and the Textile Conservation

    Centre,

    University

    of

    Southampton,

    UK,

    she

    joined

    the

    British Museum

    in 2003

    as

    a

    conservation scientist.

    Her

    main

    fields of work

    are

    preventive

    conservation and laser

    cleaning.

    Address:

    as

    Bradley.

    Email:

    ckorenberg@thebritishm

    useum.ac.uk

    James

    Parker

    gained

    a

    BSc

    and PhD in

    chemistry

    from

    the

    University

    of

    Kent,

    UK,

    before

    joining

    the

    British

    Museum

    in 2001. His PhD dealtwith the

    synthesis

    f

    novel

    synthetic

    polymers,

    an

    interest which

    he

    continued,

    researching

    the deterioration of

    objects

    made of

    plastics

    and

    the lifetimes

    of

    conservation materials. Recent

    research

    projects

    have been

    on

    the

    use

    of

    low-oxygen

    enclosures for the

    storage

    and

    display

    of

    objects;

    and

    pollutant

    gas

    monitoring

    in

    the

    museum

    environment

    in

    galleries,

    showcases

    and

    enclosures. This work involved

    the

    development

    of

    quantitative

    solid

    phase

    micro

    extraction

    (SPME).

    In

    September

    2006 he left

    the

    British

    Museum

    to

    take

    up

    a

    research

    post

    in

    industry.

    Address:

    as

    Bradley.

    Email:

    [email protected]

    Clare

    Ward

    gained

    a

    BSc

    (Hons)

    in

    archaeological

    conservation from the Institute of Archaeology,

    University

    of

    London

    in

    1981. She

    joined

    the British

    Museum

    in

    1982,

    and

    is

    currently

    a

    senior

    conservator

    in

    the

    Organic

    Artefacts Section of the

    Department

    of

    Conservation,

    Documentation and Science.

    She

    specializes

    in

    the

    conservation

    of

    archaeological

    organics,

    such

    as

    bone,

    ivory,

    wood and

    amber,

    and also modern

    plastics.

    Address:

    Organic Artefacts

    Section,

    Department

    of

    Conservation

    and

    Scientific

    Research,

    The

    British

    Museum,

    Creat Russell

    Street,

    London

    WC?B

    3DG,

    UK.

    Email:

    [email protected].

    uk

    R?sum?

    ?

    La

    partie

    de

    corps

    connue

    sous

    le

    nom

    de

    Lindow

    Man

    a

    ?t? trouv?e dans

    une

    tourbi?re

    ? Lindow Moss

    en

    ao?t

    1984.

    A

    la

    suite

    des

    fouilles

    le

    corps

    ut

    transport?

    au

    British

    Museum,

    o?

    il

    fut

    examin?

    et

    conserv?,

    puis

    expos?

    sur

    une

    base

    permanente

    ?

    partir

    de 1986. Des

    inqui?tudes

    concernant

    le

    palissement

    de la

    couleur

    ont

    ?t?

    exprim?es,

    d'abord

    en

    1989,

    puis

    ?

    plusieurs reprises

    depuis,

    et

    en

    2004

    un

    examen

    non

    destructif

    a

    ?t? men? ? bien.

    L'historique

    du suivi

    de la couleur du

    corps

    et

    des

    exp?riences

    associ?es

    a

    ?t?

    pass?

    en

    revue,

    ce

    qui

    a

    fourni

    une

    id?e

    plus

    pr?cise

    des

    changements

    de

    couleur,

    calcul?s

    sur

    la

    base CIE 2000 des

    diff?rences

    de

    couleurs

    (AEQQ).

    Les

    changements

    de

    couleur

    ont

    ?t?

    rapides

    en

    1989-1997,

    AEQ0

    =

    10.0,

    mais

    plus

    lents

    en

    1997-2004,

    E00

    =

    3.4,

    quand

    le niveau

    d'?clairement

    du

    corps

    ?tait

    de

    30-50

    lux

    avec

    moins

    de

    50

    pW.lumen1

    de

    rayonnement

    ultraviolet.

    Lors

    de

    son

    examen,

    le

    corps

    ?tait

    en

    bon

    ?tat,

    la

    peau

    ?tait

    flexible,

    sans

    r?tr?cissements

    ni

    craquelures

    apparents.

    L'analyse

    par

    spectrom?trie

    IRTF

    d'?chantillons

    du

    poly?thyl?ne glycol

    utilis?

    pour

    la

    conservation

    a

    montr?

    qu'une oxydation

    s'?tait

    produite.

    L'histoire

    de la

    pr?sentation

    du

    corps,

    les

    changements

    de

    couleurs

    survenus

    pendant

    20

    ans

    et

    l'?tat du

    corps

    en

    2005

    sont

    pr?sent?s

    et

    discut?s. Des

    recommandations

    pour

    le

    futur

    suivi

    de la conservation

    du

    corps

    et

    pour

    la

    mise

    au

    point

    d'un

    traitement

    sont

    ?galement fournies.

    Zusammenfassung

    ? Der als Lindow Mann bekannte

    Teilk?rper

    wurde im

    August

    1984 in einem

    Torfmoor

    bei Lindow Moss

    gefunden.

    Nach der

    Ausgrabung

    wurde der

    K?rper

    ins British

    Museum

    ?berf?hrt,

    wo er

    untersucht,

    konserviert und

    1986

    ausgestellt

    wurde.

    Schon

    1989

    wurde

    erstmals der

    Sorge

    ?ber

    Farbver?nderungen

    durch Licht Ausdruck verliehen

    und 2004

    eine

    zerst?rungsfreie Untersuchung durchgef?hrt.

    Die

    vorgestellte

    Geschichte des

    Farbmonitorings

    erweist

    die

    Farbver?nderung.

    Sie

    wird als CIE 2000

    Farbabstand

    (AEQ0)

    argestellt.

    ie

    Farbver?nderung

    rfolgte

    it

    AEQQ

    10.0

    in

    den

    fahren

    1989?1997

    sehr

    rasch,

    verringerte

    sich

    aber zwischen

    1997?2004

    auf

    AEQ0

    ?

    3.4,

    als die

    Lichtst?rke,

    der

    der

    K?rper

    ausgesetzt

    war,

    auf

    30

    ?

    50 lux sowie die ultraviolette

    Strahlung auf

    50

    .lumen'1

    gesenkt

    werden konnte.

    Bei

    der

    Untersuchung

    zeigte

    sich

    der

    studies

    in

    conservation

    53

    (2008)pages

    273-284

    This content downloaded from 84.205.227.38 on Mon, 18 Aug 2014 08:49:23 UTCAll use subject to JSTOR Terms and Conditions

    http://www.jstor.org/page/info/about/policies/terms.jsphttp://www.jstor.org/page/info/about/policies/terms.jsphttp://www.jstor.org/page/info/about/policies/terms.jsp
  • 8/11/2019 A Review of the Colour and Condition of Lindow Man 20 Years After Conservation

    13/13

    284

    S.

    BRADLEY,

    R

    FLETCHER,

    C.

    KORENBERG,

    J.

    PARKER

    AND

    C.

    WARD

    K?rper

    in

    gutem

    Zustand,

    die

    Haut

    war

    flexibel

    und

    es

    gab

    keine

    Hinweise

    auf Schrumpfungen

    oder

    Risse.

    Die

    Analyse

    einer

    Probe des

    zur

    Konservierung

    verwendeten

    Polyethylenglycols zeigte,

    dass

    eine

    Oxidation

    stattgefunden

    hatte.

    Die

    Geschichte der

    Ausstellung

    des

    K?rpers,

    die

    Farbver?nderungen

    ?ber 20

    fahre

    und der Zustand des

    K?rpers

    werden berichtet und diskutiert.

    Empfehlungen

    ?r

    zuk?nftiges onitoring

    des

    K?rpers

    und

    f?r

    eine

    m?gliche

    iederbehandlung

    erden

    gegeben.

    Resumen

    ?

    El

    cuerpo

    conocido

    como

    elHombre de Lindow

    fue

    encontrado

    en una

    turbera

    en

    agosto

    de

    ?984.

    Tras la

    excavaci?n,

    el

    cuerpo

    fue transferido

    al

    Museo

    Brit?nico,

    donde

    fue

    examinado

    y

    conservado,

    y

    ha estado

    en

    exposici?n

    permanente

    desde 1986.

    Pronto

    surgieron

    cuestiones

    problem?ticas

    como

    el

    aclarado de

    su

    color,

    primeramente

    en

    1989

    y,

    en

    diversas

    ocasiones

    m?s,

    hasta

    el

    2004,

    cuando

    se

    realiz?

    un

    examen

    no-destructivo.

    Se

    afrontaron

    cuestiones

    como

    la historia de la monitorizaci?n

    del color del

    cuerpo y

    de

    diversos

    experimentos

    asociados,

    obteni?ndose

    una

    idea clara del

    cambio

    crom?tico,

    calculados

    en

    t?rminos

    de

    diferencia

    e color

    IE 2000

    (

    E00).

    El cambio e color

    fue

    r?pido

    ntre

    989

    y

    1991,

    AE0Q=10.0,

    pero

    muchom?s lento

    entre

    1997

    y

    2004,

    AEQQ-3.4,

    cuando el nivel de

    iluminaci?n del

    cuerpo

    hab?a sido 30-50 luxes

    con menos

    de

    50pw.lumen1

    de

    luz

    ultravioleta.

    Cuando

    se

    examin?,

    el

    cuerpo

    estaba

    en

    buen

    estado,

    la

    piel

    era

    flexible

    sin

    signos

    contracci?n

    o

    cuarteado.

    Los

    an?lisis mediante

    espectroscopia

    infrarroja

    por

    transformada

    de Fourier

    del

    polietilenglicol aplicado

    durante la

    fase

    de conservaci?n

    mostraron

    que

    cierta

    oxidaci?n

    hab?a

    ocurrido.

    Se

    exponen y

    discuten

    en

    este

    estudio la historia de la

    exposici?n

    del

    cuerpo,

    el

    cambio

    crom?tico

    a

    lo

    largo

    de

    veinte a?os

    y

    su

    condici?n

    en

    el 2005.

    Se

    aportan

    tambi?n

    ciertas

    recomendaciones sobre

    una

    futura

    monitorizaci?n de

    su

    estado

    de conservaci?n

    y

    criterios

    para

    un

    futuro

    nuevo

    tratamiento

    de los

    restos.

    STUDIES

    IN

    CONSERVATION

    53

    (2008)

    PAGES 273-284