ANNEXURE- I PROPOSED TERMS OF REFERENCE · ANNEXURE- I PROPOSED TERMS OF REFERENCE ... Disperse violet 26 and/or 6408-72-6 V AZO Pigments 0 10 10 ... Sodium hydroxide 0.08 6.63 2-MP

M/s. Shree Colosperse Pvt. Ltd., Ankleshwar.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 1

ANNEXURE- I

PROPOSED TERMS OF REFERENCE

As per standard ToR of organic manufacturing sector issued by MoEF&CC.



ANNEXURE-II

LIST OF DIRECTORS

Name of Director Address Telephone

Number Designation

Mr. Manshukh Vekaria

Kalpvruksh, Plot No: 408/25, Opp. Shree Gattu Vidhyalaya,

GIDC, Ankleshwar.

02646 - 239830 Managing Director

Ms. Bhartiben M. Vekaria

Kalpvruksh, Plot No: 408/25, Opp. Shree Gattu Vidhyalaya,

GIDC, Ankleshwar.

02646 - 239830 Director



ANNEXURE-III

PLANT LAYOUT



ANNEXURE- IV

LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY

1) Existing Product as per CCA No: AWH-51863, Date of issue 02/02/2013

Sr. No.

Name of Products Existing quantity as per CCA No. AWH-51863 in (MT/Month)

1. Disperse navy Blue 3G (IGNS) 2 2. Disperse Golden Yellow GG 1 3. Disperse Yellow AL 0.5 4. Disperse Rubine 3B 0.5 5. Disperse Scarlet RR 0.5 6. Disperse Yellow Brown REL 0.25 7. Disperse Orange ERL 1 8. Disperse Violet B 0.25 9. Disperse Blue SE2R1 0.25 10. Disperse Yellow 7 GL 0.5 11 Disperse Rubine S2GL 0.5 12 Disperse Agent SS 1 13. Disperse Yellow FFL 0.5

TOTAL 8.75

2) Proposed Product List

Sr. No.

Name of Products CAS No. Existing Quantity as per CCA No. AWH-

51863 in (MT/Month)

Proposed Quantity in

(MT/Month)

Total Quantity

(MT/Month)

I DISPERSE DYES (AZO Group) 6.75 73.25 80 Representative Products:

1. Disperse navy blue 3G (IGNS) and/or

2537-62-4

2. Disperse golden yellow GG and/or

54077-16-6

3. Disperse rubine 3B and/or

61968-52-3

4. Disperse rubine GFL and/or

16889-10-4

5. Disperse rubine 5B and/or

99035-78-6

6. Disperse scarlet RR and/or

63439-91-8

7. Disperse yellow brown REL and/or

12270-45-0

8. Disperse orange ERL (Disperse Orange 25)

31482-56-1



Sr. No.


51863 in (MT/Month)


(MT/Month)

Total Quantity

(MT/Month)

and/or 9. Disperse violet B and/or 52697-38-8

10. Disperse blue SE2R1 and/or

2537-62-4

11. Disperse yellow 7 GL and/or

56509-56-9

12. Disperse rubine S2GL and/or

16889-10-4

13. Disperse orange 288 and/or

9662-24-7

14. Disperse scarlet 3R (Disperse Red 50)

and/or

12223-35-7

15. Disperse brown 3REL and/or

52623-75-3

16. Disperse golden yellow 2GD and/or

54077-16-6

17. Disperse yellow 119 and/or

57308-41-5


83249-52-9


86836-02-4

20. Disperse blue 291 and/or 56548-64-2 21. Disperse violet 93 and/or 52597-38-8

22. Disperse yellow 5RX and/or

6300-37-4

23. Disperse yellow M7G and/or

--

23. Disperse red 9 and/or 82-38-2 25. Disperse red 1 and/or 2872-52-8 26. Disperse red 13 and/or 3180-81-2 27. Disperse red 17 and/or 3179-89-3

28. Disperse yellow 3

(Disperse yellow G) and/or

2832-40-8

II DISPERSING AGENT 1.0 49 50 Representative Products:

1. Dispersing agent SS -- 1.0 49 50 III DISPERSE DYES

(Miscellaneous Type) 1.0 9 10

Representative Products: 1. Disperse yellow AL

(Disperse yellow 1) and/or

2832-40-8 0.5

2. Disperse yellow FFL 5124-25-4 0.5



Sr. No.


51863 in (MT/Month)


(MT/Month)

Total Quantity

(MT/Month)

and/or

IV DISPERSE DYES (Anthraquinone Group)

0 10 10

Representative Products: 1. Disperse blue FFR

and/or 2475-46-9

2. Disperse blue BN and/or 2475-46-9 3. Disperse red 11 and/or 2872-48-2 4. Disperse blue 60 and/or 12217-80-0 5. Disperse violet 26

and/or 6408-72-6

V AZO Pigments 0 10 10 Representative Products:

1. Pigment yellow 12 and/or

5102-83-0


4531-49-1


5567-15-7

4. Pigment orange 13 and/or

3520-72-7

5. Pigment orange 34 and/or

15793-73-4

6. Pigment Rubin tonner and/or

5281-04-9

7. Pigment lake red CT and/or

2379-74-0

VI. M-8 (n-cyano ethyl methyl

aniline)

94-34-8 0 10 10

TOTAL 8.75 161.25 170

NOTE: The quantities refer is for concentrated dyes. These dyes are further diluted and

standardized as per market requirement. The final sellable quantity will increase by 30-35%.



ANNEXURE - V LIST OF RAW MATERIALS CONSUMPTION

1) OVERALL RAW MATERIAL SCENARIO

Sr. No.

Name of Raw material Existing Quantity in MT/Month

Total after Proposed Expansion in MT/Month

1 6 bromo 2:4 dinitro aniline 0.3 24 2 M3 A ( 3 n n diethyl amino

acetanilide) 0.47 37.6

3 Sulfuric Acid 0.92 36.8 4 Sodium Nitrite 0.24 8 5 Dis. Agent 045 (Phenol Base) 3.0 32.8 6 Dada mol NKS (Naphthaline Base) 3.625 40.8 7 G. Salt 1.45 12 8 Para nitro aniline 0.176 14.08 9 N ethyl 4 methyl 3 cyano 6 bhydroxy

2 pyridone (EP) 0.221 17.68

10 Hydrochloric Acid 1.5 32.8 11 2:4 dinitro chloro benzene (ONCB) 0.1725 13.8 12 Para amino phenol (PAP) 0.0885 7.04 13 Sodium Acetate 0.46 36.8 14 2Cyno Para nitro aniline 0.252 20.16 15 M2 A( 3 n n diacetoxy ethyl amino

toulene 0.292 23.36

16 Ortho chloro para nitro aniline 0.302 24.16 17 2,6 dichloro para nitro aniline 18 M-7 ( n cyano ethyl n acetoxy ethyl

aniluine) 0.13 10.4

19 M-8 (n cyano ethyl n ethyl aniline) 0.231 18.48 20 M-9 n n di ethyl meta amino

propionamide) 0.06 4.8

21 M-12 (n n diethyl meta amino acetanilide) 0.052 4.16

22 2 Cyno 6 Bromo Para nitro aniline 0.03 2.4 23 Para chloro aniline 0.075 6 24 Phenol 0.21 16.8 25 Formaldehyde 0.232 18.56 26 Sodium Sulphite 0.121 9.68 27 Caustic Lye/Flacks 0.025 2 28 Terephthaldehyde 0 0.25 29 Hippuric Acid 0 0.5 30 Acetic Acid 0 3.0 31 Acetic Anhydride 0 2.5 32 Soda Ash 0 1.0 33 M-5 (3 n ndiacetoxy ethyl 4 methoxy

acetanilide) 0 1.5

34 N cyano ethy n ethyl meta amino acetanilide 0 05

35 1,4 dimethyl 3 cyano 6 hydroxy 3 0 2.5



pyridone (MP) 36 3 3 dichloro benzidine 0 1.0 37 Aceto acetanilide 0 1.25 38 1 Phenyl 3methyl pyrazolone PMP 0 1.25 39 Beta naphthol 0 0.5 40 3 carboxi 2 oxo naphthalene (BON

ACID) 0 0.5

41 M-15 (n ethyl n hydroxy ethil aniline) 0 1.2 42 1 chloro anthraquinone 0 .025 43 Quinazarine 0 1.0 44 2,3 dichloro 1,4 diamino

anthraquinone 0 1.5

45 Monomethyl amine 0 2.0 46 Monoethyl aniline 0 5.0 47 Acrylonitrile 0 2.7 48 Para amino acetanilide 0 1.0 49 Monoethyl aniline 0 3.5 50 Ethyl/butyl acrylate 0 2.0 51 Zink chloride 0 0.5

2) Raw material of some representative products:

Sr. No. Name of Product

Total Quantity in MT/month

Name of Raw Material Quantity

in Ton/Ton

Total Quantity

in MT/month

I DISPERSE DYES (AZO Group) 80

1. Disperse Golden Yellow GG and/or

4-Amino azobenzene 0.19 15.01 HCL 0.35 27.81

Sodium Nitrite 0.07 5.26Sodium hydroxide 0.08 6.10

4-hydroxyquinoline-2(1H)-one 0.15 12.27

Dadamol (Naphthalene based Dispersing agent) 0.32 25.90

Liq. Dispersing agent 045 (Phenol based) (45%) 0.71 57.14

TOTAL 1.87 149.49

2. Disperse Rubine 3B and/or

2-Cyano-p-Nitroaniline 0.13 10.03 HCL 0.28 22.46

Sodim Nitrite 0.05 4.25 Sodium hydroxide 0.06 4.92

M-2A 0.21 17.17Dadamol (Naphthalene based Dispersing agent) 0.33 26.15


TOTAL 1.79 143.14

3. Disperse Orange 25 (ERL) and/or

p-Nitroaniline 0.15 12.00 HCL 0.40 31.74

Sodim Nitrite 0.08 6.00






in Ton/Ton

Total Quantity

in MT/month

Sodium hydroxide 0.09 6.96 M-8 0.19 15.13

Dadamol (Naphthalene based Dispersing agent) 0.33 26.09


TOTAL 1.95 155.74

4. Disperse Blue – 183.1 (Blue 2RC) and/or

2-Cyano-6-Bromo-PNA 0.19 14.89 HCL 0.28 22.46


M-12 0.16 12.68 Dadamol (Naphthalene based Dispersing agent) 0.32 25.85


TOTAL 1.78 142.58

5. Disperse Yellow 119 and/or

O-Nitro Aniline 0.15 11.81 HCL 0.39 31.23


2-EP 0.19 15.23 Dadamol (Naphthalene based Dispersing agent) 0.33 26.10


TOTAL 1.94 154.87

6. Disperse Yellow 241 and/or

3,4-Dichloro Aniline 0.17 13.43 HCL 0.38 30.26


2-MP 0.17 13.60 Dadamol (Naphthalene based Dispersing agent) 0.33 26.11


TOTAL 1.92 153.78

7. Disperse Yellow M7G and/or

p-Chloro Aniline 0.14 11.29 HCL 0.41 32.44


2-EP 0.20 15.82 Dadamol (Naphthalene based Dispersing agent) 0.32 25.96


TOTAL 1.96 156.53

8. Disperse Blue 291 and/or

6-Bromo-2,4-DNA 0.18 14.46 HCL 0.25 20.14







in Ton/Ton

Total Quantity

in MT/month



TOTAL 1.74 139.42

9. Disperse Red 13 and/or

o-Chloro-p-Nitroaniline 0.17 13.76 HCL 0.37 29.20

Sodium Nitrite 0.07 5.52 Sodium hydroxide 0.08 6.40



TOTAL 1.90 152.08 II DISPERSING AGENT 50

1. Dispersing Agent SS

Formaldehyde (37%) 0.22 10.86 Phenol 0.17 8.71

Sodium Sulfite 0.12 6.08 Caustic Lye 0.01 0.45

TOTAL 0.52 26.09

III DISPERSE DYES (Miscellaneous Type) 10

1. Disperse Yellow AL and/or

Fresh IPA 0.11 1.09 Recovered IPA 2.07 20.73Sodium Acitate 0.30 2.98

2,4-DNCB 0.73 7.35 p-Amino phenol 0.40 3.96

TOTAL 3.61 36.11

2. Pigment Yellow FFL and/or

Fresh Acetic acid 0.071429 0.71 Recovered Acetic acid 0.714286 7.14

Hippuric acid 0.852381 8.52 Tere phthaladehyde 0.319048 3.19

Acetic anhydride 0.345238 3.45 TOTAL 2.30 23.02

IV DISPERSE DYES (Anthraquinone Group) 10

1. Disperse blue FFR and/or

Fresh IPA 0.101351 1.01 Recovered IPA 3.277027 32.77

Sodium hydroxide 0.27027 2.70 Quinizarine 0.810811 8.11

Mono methyl amine (40%) 0.263514 2.64

Mono ethanol amine 0.206081 2.06 TOTAL 4.93 49.29

2. Disperse blue BN and/or

Fresh IPA 0.131579 1.32 Recovered IPA 3.62782 36.28

Sodium hydroxide 0.300752 3.01 Quinizarine 0.902256 9.02






in Ton/Ton

Total Quantity

in MT/month

Mono methyl amine (40%) 0.582707 5.83

TOTAL 5.55 55.45

3. Disperse Violet 26 and/or

Fresh DMF 0.14218 1.42 Recovered DMF 3.412322 34.12

Sodium Carbonate 0.327014 3.27 1,4 Diamino-2,3

Dichloro anthraquinone 0.727488 7.27

Phenol 0.445498 4.45 TOTAL 5.05 50.55

V AZO Pigments 10


3-3’ Dichlorobenzidine 0.40 4.02 Hydrochloric acid 1.16 11.61

Sodium Nitrite 0.22 2.19 Caustic lye 0.25 2.54

Aceto acetanilide 0.56 5.63 TOTAL 2.60 25.99


DCB 0.5 5 Hydrochloric acid 0.52 5.2

Sodium Nitrite 0.15 1.5 Sulfamic acid 0.5 5

Naphthol ASIRG 0.6 6 Caustic lye 0.16 1.6

Sodium bicarbonate 0.17 1.7Total 2.6 26

3. Pigment Orange 13 and/or

3-3’ Dichlorobenzidine 0.41 4.06 HCL 1.17 11.72

Sodium Nitrite 0.22 2.22 Caustic lye 0.26 2.57

5-methyl-2-phenyl-2, 4-dihydro-3H-pyrazole-3-

one 0.56 5.59

TOTAL 2.61 26.15

VI. M-8

(n-cyano ethyl methyl aniline)

10

Acrylonitrile 0.34 3.41 Mono ethyl aniline 0.64 6.40

Zink chloride 0.06 0.57 Vacuum salt 0.06 0.64

Total 170 TOTAL 1.10 10.99



ANNEXURE- VI

BREIF MANUFACTURING PROCESS:

I) GENERAL MANUFACTURING PROCESS OF DISPERSE DYESTUFF

Disperse Dyestuff intermediate aromatic amine is diazotized using hydrochloric acid and sodium

nitrite in aqueous medium in some cases using sulfuric acid in presence of dry sodium nitrite

and coupled with coupling components like N ethyl 4 methyl 3 cyano 6 bhydroxy 2 pyridone,

1,4 dimethyl 3 cyano 6 hydroxy 3 pyridone(MP), 3 n ndiacetoxy ethyl 4 methoxy acetanilide

(M5), 3 n n diethyl amino acetanilide (M3A), n cyano ethyl n acetoxy ethyl aniluine (M7), n

cyano ethyl n ethyl aniline (M8) etc. using caustic soda/Soda Ash for adjustment of reaction pH

conditions. Generally these reactions are carried out at 0 - 10 oC. Dyestuffs thus obtained are

then filtered through filter press to remove water. The press cake thus obtained is then mixed

with dispersing agent like dadamol, inks & liq. Dispersing agent 045(dispersing agent ss)in

Kinetic dispersion mill to make smooth thick slurry which is then transferred to sand mill for

further particle size reduction. When desired particle size is achieved it is transferred to spray

drying. The dried powder is then transferred to blender for standerdisation then it is packed &

transferred to godown.

1) Disperse Golden Yellow GG Chemical Reaction:

NN

NH2

+

NH

OH

O

NN

NN

NH

OH

O

4-[(E)-phenyldiazenyl]aniline 4-hydroxyquinolin-2(1H)-oneGolden Yellow GG

C12H11N3197.23

C9H7NO2

161.15C21H15N5O2

369.37



Material Balance:

Input Kg Output KgIce + Water 40004-Amino azobenzene 197HCL 365 Reaction mass 4631Sodim Nitrite 69Total 4631 Total 4631

Reaction mass 4631 Coupling mass 9872Ice + Water 5000Sodium hydroxide 804-hydroxyquinoline-2 (1H)-one

161

Total 9872 Total 9872

Coupling mass 9872 Wet Cake 1012Washing water 2000 Washing water to recycle 2000

Effluent to ETP 8860Total 11872 Total 11872

Wet Cake 1012Dadamol (Naphthalene based Dispersing agent)

340 Wet Cake 2102

Liq. Dispersing agent 045 (Phenol based) (45%)

750


Wet Cake 2102 Water Evaporation 1020Disperse Golden Yellow – GG 1082


Disperse Golden Yellow – GG 1082 Disperse Golden Yellow –

GG 1082


Packing

Coupling

Drying

Diazotization

Filteration & Washing

K D Mill & Sand Mill



2) Disperse rubine 3B Chemical Reaction:

NH2

CN

NO2

+N

O CH3

O

O

CH3

CH3 O

NO

NN

NC

NO2

CH3

O

O

CH3 O

CH3

2-Cyano-p-Nitro anilineC7H5N3O2

163.0 C15H21NO4279.0

Disperse Rubine 3B (Violet 33)C22H23N5O6

453.0

M-2A

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50

Hydrochloric acid Water

36.5 18.0

Coupling



Material Balance: Input Kg Output KgIce + Water 30002-Cyano-p-Nitroaniline 163HCL 365 Reaction mass 3597Sodim Nitrite 69


Reaction mass 3597 Coupling mass 9956Ice + Water 6000Sodium hydroxide 80M-2A 279Total 9956 Total 9956




425 Wet Cake 2670


945


Wet Cake 2670 Water Evaporation 1370Disperse Rubine – 3B 1300


Disperse Rubine – 3B 1300 Disperse Rubine – 3B 1300Total 1300 Total 1300

Packing

Coupling



Drying

Diazotization



3) Disperse Orange 25 (ERL) Chemical Reaction:

NH2

NO2

+N

CH3

CN

N

CH3

CN

NN

NO2

p-Nitro anilineC6H6N2O2

138.0C11H14N2

174.0

Disperse Orange 25 (ERL)C1H17N5O2

323.0

M-8

+ NaNO2

Sodium Nitrite69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling



Material Balance:

Input Kg Output KgIce + Water 4000p-Nitroaniline 138HCL 365 Reaction mass 4572Sodim Nitrite 69Total 4572 Total 4572

Reaction mass 4572 Coupling mass 9826Ice + Water 5000Sodium hydroxide 80M-8 174Total 9826 Total 9826



Wet Cake 1006Dadamol (Naphthalene based Dispersing agent) 300 Wet Cake 1971


665


Wet Cake 1971 Water Evaporation 980Disperse Orange 25 (ERL) 991


Disperse Orange 25 (ERL) 991 Disperse Orange 25

(ERL) 991

Total 991 Total 991

Packing and Dispatch

Coupling



Drying

Diazotization



4) Disperse Yellow – 241 Chemical Reaction:

NH2

Cl

Cl+

N

NN

O

CH3

OH

NC

CH3

Cl

Cl

3,4-Dichloro AnilineC6H5Cl2N

162.0C8H8N2O2

164.0

Disperse Yellow 241C14H10Cl2N4O2

337.0

2-Methyl Pyridone

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling

N

CH3

CN

CH3

OH O



Material Balance:

Input Kg Output KgIce + Water 40003,4-Dichloro Aniline 162HCL 365 Reaction mass 4596Sodim Nitrite 69Total 4596 Total 4596

Reaction mass 4596 Coupling mass 9840Ice + Water 5000Sodium hydroxide 802-MP 164Total 9840 Total 9840



Wet Cake 1000

Dadamol (Naphthalene based Dispersing agent) 315 Wet Cake 2015


700


Wet Cake 2015 Water Evaporation 990Disperse Yellow – 241 1025


Disperse Yellow – 241 1025 Disperse Yellow – 241 1025Total 1025 Total 1025


Coupling


Diazotization

Drying




5) Disperse Yellow – 119 Chemical Reaction:

NH2

NO2

+

N

NN

O2N

O

CH3

OH

NC

CH3

o-Nitro AnilineC6H6N2O2

138.0C9H10N2O2

178.0

Disperse Yellow 119C15H13N5O4

327.0

2-Ethyl Pyridone

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling

N

CH3

CN

CH3

OH O



Material Balance:

Input Kg Output KgIce + Water 3000O-Nitro Aniline 138HCL 365 Reaction mass 3572Sodim Nitrite 69Total 3572 Total 3572

Reaction mass 3572 Coupling mass 8830Ice + Water 5000Sodium hydroxide 802-EP 178Total 8830 Total 8830



Wet Cake 935

Dadamol (Naphthalene based Dispersing agent) 305 Wet Cake 1915


675


Wet Cake 1915 Water Evaporation 980Disperse Yellow – 119 935


Disperse Yellow – 119 935 Disperse Yellow – 119 935Total 935 Total 935

Packing

Coupling


Drying

Diazotization




6) Disperse Yellow – M7G Chemical Reaction:

NH2

Cl

+

N

NN

O

CH3

OH

NC

CH3

Cl

p-Chloro AnilineC6H6ClN

127.0C9H10N2O2

178.0

Disperse Yellow M7GC15H13ClN4O2

316.0

2-Ethyl Pyridone

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling

N

CH3

CN

CH3

OH O



Material Balance:

Input Kg Output KgIce + Water 4000p-Chloro Aniline 127HCL 365 Reaction mass 4561Sodim Nitrite 69Total 4561 Total 4561

Reaction mass 4561 Coupling mass 9819Ice + Water 5000Sodium hydroxide 802-EP 178Total 9819 Total 9819




292 Wet Cake 2121


650


Wet Cake 2121 Water Evaporation 1121Disperse Yellow – M7G 1000


Disperse Yellow – M7G 1000 Disperse Yellow – M7G 1000Total 1000 Total 1000

Packing

Coupling


Drying

Diazotization




7) Disperse Blue - 183.1 (Blue 2RC)

Chemical Reaction:

NH2

CN

NO2

Br

+

N CH3

CH3

NH CH3

O

N CH3

CH3

NN

NC

NO2

Br

NH CH3

O

2-Cyano-6-Bromo-PNAC7H4BrN3O2

242.0C12H18N2O

206.0

Disperse Blue 183.1 (Blue 2RC)C19H19BrN6O3

459.0

M-12

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling



Material Balance:

Input Kg Output KgIce + Water 30002-Cyano-6-Bromo-PNA 242HCL 365 Reaction mass 3676Sodim Nitrite 69Total 3676 Total 3676





420 Wet Cake 2655


935


Wet Cake 2655 Water Evaporation 1355Disperse Blue – 183.1 1300


Disperse Blue – 183.1 1300 Disperse Blue – 183.1 1300Total 1300 Total 1300

Packing

Coupling



Diazotization

Drying



8) Disperse Blue 291 Chemical Reaction:

NH2

NO2

NO2

Br

+

N CH3

CH3

NH CH3

OO

CH3

N CH3

CH3

NN

O2N

NO2

Br

NH CH3

OO

CH3

6-Bromo-2,4-DNAC6H4BrN3O4

262.0C13H20N2O2

236.0

Disperse Blue 291C19H21BrN6O6

509.0

M-10

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling



Material Balance:

Input Kg Output KgIce + Water 40006-Bromo-2,4-DNA 262HCL 365 Reaction mass 4696Sodim Nitrite 69Total 4696 Total 4696


Coupling mass 11512 Wet Cake 1450Washing water 2500 Washing water to recyc 2500



470 Wet Cake 2965


1045


Wet Cake 2965 Water Evaporation 1515Disperse Blue – 291 1450


Disperse Blue – 291 1450 Disperse Blue – 291 1450Total 1450 Total 1450


Coupling



Drying

Diazotization



9) Disperse Red 13 Chemical Reaction:

NH2

Cl

NO2

+

N

CH3

OH

N

CH3

OH

NN

Cl

NO2

o-Chloro-p-Nitro anilineC6H5ClN2O2

172.0C10H15NO

165.0

Disperse Red 13C16H17ClN4O3

348.0

M-15

+ NaNO2

Sodium Nitrite

69.0

+ 2 HCl

Hydrochloric acid

36.5

Diazotization

+ NaCl HCl 2 H2O+ +

Sodium chloride

58.50


36.5 18.0

Coupling



Material Balance: Input Kg Output KgIce + Water 3000o-Chloro-p-Nitroaniline 172HCL 365 Reaction mass 3606Sodim Nitrite 69Total 3606 Total 3606





325 Wet Cake 2050


725


Wet Cake 2050 Water Evaporation 1050Disperse Red 13 1000


Disperse Red 13 1000 Disperse Red 13 1000Total 1000 Total 1000

Packing

Coupling



Drying

Diazotization



II) Dispersing Agent SS

Material Balance:

Input Kg Output KgWater 5000Formaldehyde (37%) 1340Phenol 1075 Reaction mass 8220Sodium Sulfite 750Sodium hydroxide 55


Reaction mass 8220 Wet Product 8220


Dispersing Agent 8220 Dispersing Agent 8220


S.S.Reactor Heat to 135oC

Cool 25-35oC

Packing

II) GENERAL METHOD FOR MANUFACTURING MISCELINEOUS DISPERSE DYES

In SS reactor 2 4 DNCB is condensed with para amino phenol to give disperse yellow AL. In SS

reactor terephthaldehyde, hippuric acid, acetic anhydride are reacted at reflux temp. To give

yellow FFL (yellow 124).

4 chloro,3 nitro benzene sulfonyl chloride is reacted with aniline & ethylamine to give yellow

42Dyestuffs thus obtained are then filtered through filter press to remove water . The press cake

thus obtained is then mixed with dispersing agent like dadamoL, inks & liq. Dispersing agent

045(DISPERSING AGENT S7S)in Kinetic dispersion mill to make smooth thick slurry which is

then transferred to sand mill for further particle size reduction. When desired particle size is

achieved it is transferred to spray drying. The dried powdered is then transferred to blender for

standardization then it is packed & transferred to godown.

1) Disperse yellow AL:

Chemical Reaction: Cl

NO2

NO2

+

NH2

OH

NH

NO2O2N OH

2,4 Dinitro chlorobenzene p-Amino Phenol Disperse Yellow ALC6H3ClN2O4

202.0C6H9NO

109.0C12H9N3O5

275.0



Material Balance:

Input Kg Output KgFresh IPA 30Recovered IPA 570Sodium Acitate 82 Reaction mass 9932,4-DNCB 202p-Amino phenol 109Total 993 Total 993

Reaction mass 993 Coupling mass 1423Water 1000

Recovered IPA 570Total 1993 Total 1993

Coupling mass 1423 Wet Cake 478Washing water 1000 0

Waste water to ETP 1945Total 2423 Total 2423

Wet Cake 478 Water Evaporation 245Dry Cake 233

Total 478 Total 478

Dry Cake 233 Pigment Yellow – AL 233Total 233 Total 233

Pigment Yellow – AL 233 Pigment Yellow – AL 233

Total 233 Total 233

Distillationand

Crystallization

Blending & Packing


Diazotization

Tray Dryer

Pulverization

2) Disperse yellow FFL:

Chemical Reaction:

CHO

CHO

+

NHOH

O

O

N

OO

N O

O

2

Disperse Yellow FFLTerephthaladehyde Hippuric acidC8H6O2

134.0C9H9NO3

179.0

C26H16N2O4

420.0



Material Balance:

Input Kg Output KgFresh Acetic acid 30Recovered Acetic acid 300Hippuric acid 358 Reaction mass 967Terephthaladehyde 134Acetic anhydride 145Total 967 Total 967


Recovered Acetic acid 480Total 2967 Total 2967

Coupling mass 2487 Wet Cake 707Washing water 1500



Total 707 Total 707

Dry Cake 350 Pigment Yellow – FFL 350Total 350 Total 350

Pigment Yellow – FFL 350 Pigment Yellow – FFL 350Total 350 Total 350

Blending & Packing

Diazotization

Distillationand

Crystallization


Tray Dryer

Pulverization

IV) GENERAL MANUFACTURING PROCESS FOR ANTHRAQUINONE DISPERSE

DYESTUFF

Anthraquinone derivatives such as quinazarine, 1 chloro anthraquinone, 2,3dichloro 1, 4 diamino

antheaquinone, condensed with compound such as mono methyl amine. Monoethanol amine

phenol etc. excess material is distilled out. Material is then filtered through filter press. The press

cake thus obtained is then mixed with dispersing agent like dadamoL, inks & liq. Dispersing

agent 045(DISPERSING AGENT SS)in Kinetic dispersion mill to make smooth thick slurry

which is then transferred to sand mill for further particle size reduction. When desired particle

size is achieved it is transferred to spray drymg. The dried powdered is then transferred to

blender for standardization then it is packed & transferred to godown.



1) Disperse Blue FFR:

Chemical Reaction: O

O

OH

OH

O

O

NHCH3

NHCH2CH2OH

NH2CH3

NH2CH2CH2OH

Disperse Blue FFRQuinizarinC14H8O4

240.0C17H16N2O3

296.0 Material Balance:

Input Kg Output KgFresh IPA 30Recovered IPA 970Sodium hydroxide 80 Reaction mass 1459Quinizarine 240Mono methyl amine(40%) 78

Mono ethanol amine 61Total 1459 Total 1459


Recovered IPA 970Total 2459 Total 2459




Total 839 Total 839

Dry Cake 380Disperse Blue FFR 380

Total 380 Total 380

Disperse Blue FFR 380 Disperse Blue FFR 380Total 380 Total 380

Blending & Packing

Diazotization

Distillationand

Crystallization


Tray Dryer

Pulverization



2) Disperse Blue BN:


O

OH

OH

O

O

NHCH3

NHCH3

NH2CH3

NaOH / IPA

Disperse Blue BNQuinizarinC14H8O4

240.0C16H14N2O2


Input Kg Output KgFresh DMF 60Recovered DMF 1440Sodium Carbonate 138 Reaction mass 21331,4 Diamino-2,3Dichloro anthraquinone 307

Phenol 188Total 2133 Total 2133


Recovered DMF 1440Total 3633 Total 3633





Dry Cake 450Disperse Violet 26 450

Total 450 Total 450

Disperse Violet 26 450 Disperse Violet 26 450Total 450 Total 450

Blending & Packing

Diazotization

Distillationand

Crystallization


Tray Dryer

Pulverization



3) Disperse violet 26


O

NH2

NH2

Cl

Cl

O

O

NH2

NH2

O

O+

OH

2K2CO3

DMF

Disperse Violet 261,4-Diamino-2,3-dichloro anthraquinone Phenol

C14H8Cl2N2O2307.0

C6H6O

94.0 C26H18N2O4


Input Kg Output KgFresh DMF 60Recovered DMF 1440Sodium Carbonate 138 Reaction mass 21331,4 Diamino-2,3Dichloro anthraquinone 307

Phenol 188Total 2133 Total 2133


Recovered DMF 1440Total 3633 Total 3633




Total 773 Total 773

Dry Cake 343Disperse Violet 26 343

Total 343 Total 343

Disperse Violet 26 343 Disperse Violet 26 343Total 343 Total 343

Blending & Packing

Diazotization

Distillationand

Crystallization


Tray Dryer

Pulverization



IV) GENERAL METHOD FOR MANUFACTURING AZO PIGMENTS The proposed products are “Organic pigments”. These are characterized for their

physicochemical properties.

Aromatic amines are diazo & tiezed with help of hydrochloric acid, sodium nitrite, phenols and

Nepthols are dissolved in soda ash or Caustic lye solution. These solutions are known as a

coupling solution, the diazo solution is mixed with coupling solution at 0 to 20 0C and azo

pigment is formed. The general chemical structure is given as under.



1) Pigment yellow 12: Chemical Reaction:

Aceto acetanilideC 10 H 11 NO 2

177.0C 12 H 10 Cl 2 N 2

253.0

Pigment Yellow 12C 32 H 26 Cl 2 N 6 O 4

629.0

3-3'-Dichloro benzidine

+ 2 NaNO 2

Sodium Nitrite

69.0

+ 4 HCl

Hydrochloric acid

36.5

Diazotization

+ 2 NaCl 2 HCl 4 H 2 O+ +

Sodium chloride

58.50


36.5 18.0

Coupling

NH C H 3

O O

+

C l

N H 2

N H 2

C l

C l

C l

N

N

N

C H 3

O

N HO

N

CH 3 O

NH

O

2

Material Balance:

Input Kg Output KgIce + Water 40003-3’ Dichlorobenzidine 253HCL 730 Reaction mass 5121Sodim Nitrite 138Total 5121 Total 5121

Reaction mass 5121 Coupling mass 10635Ice + Water 5000Sodium hydroxide 160Aceto acetanilide 354Total 10635 Total 10635



Wet Cake 1685Dry Cake 1685


Dry Cake 1685 Water Evaporation 860Pigment Yellow – 12 825


Pigment Yellow – 12 825 Pigment Yellow – 12 825Total 825 Total 825

Blending & Packing

Coupling


Diazotization

Tray Dryer

Pulverization



2) Pigment yellow 83:

Chemical Reaction:

C12H10N2Cl2 + NaNO2 + C12H14 ClNO4 + HCl + Na2CO3 + NH3SO3 C36H32Cl4N6O8

Dichlorobenzidine Naphthol ASIRG Pigment Yellow‐83

Material Balance:

Input Kg Output KgWater 200DCB 50HCl 52 Reaction mass 667Sodim Nitrite 15Sulfamic acid 50Ice 300Total 667 Total 667

Reaction mass 667 Coupling mass 1260Water 200Napthol ASIRG 60Caustic Lye 16Sidium bicarbonet 17Ice 300Total 1260 Total 1260

Coupling mass 1260 Wet Cake 340Washing water 500 Washing Water recycle 500


Water Evaporation 190Wet Cake 340

Cake 150Total 340 Total 340

Cake 150 Pigment Yellow 83 150Total 150 Total 150

Pigment Yellow 83 150 Pigment Yellow 83 150

Total 150 Total 150


Diazotization

Coupling

Filteration

Pulvrizing

Drying



3) Pigment orange 13: Chemical Reaction:

5-methyl-2-phenyl

C 10 H 10 NO 2174.0

C 12 H 10 Cl 2 N 2253.0

3-3'-Dichloro benzidine

+ 2 NaNO 2

Sodium Nitrite

69.0

+ 4 HCl

Hydrochloric acid

36.5

Diazotization

+ 2 NaCl 2 HCl 4 H 2 O+ +

Sodium chloride

58.50


36.5 18.0

Coupling

+

C l

N H 2

N H 2

C l2

N N

O C H 3

-2,4-dihydro-3H--pyrazol-3-one

C l

C l

N

NN

N

NN

O

CH 3

NN O

CH 3

Pigment Orange 13C 32 H 24 Cl 2 N 8 O 2


Input Kg Output KgIce + Water 50003-3’ Dichlorobenzidine 253HCL 730 Reaction mass 6121Sodim Nitrite 138Total 6121 Total 6121

Reaction mass 6121 Coupling mass 11629Ice + Water 5000Sodium hydroxide 1605-methyl-2-phenyl-2, 4-dihydro-3H-pyrazole-3-one

348






Dry Cake 829Pigment Yellow – 13 829

Total 829 Total 829

Pigment Yellow – 13 829 Pigment Yellow – 13 829Total 829 Total 829

Blending & Packing

Coupling

Pulverization

Tray Dryer


Diazotization



IV) M-8 (n-cyano ethyl methyl aniline)

Material Balance: Input Kg Output Kg

Acrylonitrile 535Mono ethyl aniline 1000 Reaction mass 1625Zink chloride 90Total 1625 Total 1625

Reaction mass 1625 Wet Product 1875Water 2000 Waste Water to ETP 1850Vacuum salt 100Total 3725 Total 1875

Product - M-8 1875 Product - M-8 1875

Total 1875 Total 1875Packing

Cool at 25-35oC. Layer separation

S.S.ReactorHeat to 70oC



ANNEXURE- VII

DETAILS OF WATER CONSUMPTION

DETAILS OF WASTE WATER GENERATION

Sr. No. Particulars Waste Water Generation in KL/Day Quantity as per

CCA: AWH-51863

Quantity as per Proposed Expansion

Total Quantity After Expansion

1. Domestic 2.5 2.0 4.5 2. Process 3.1 28.9 32 3. Boiler 0.2 1.3 1.5 4. Cooling 0.2 1.3 1.5 5. Washing 0 6 6 (Recycle to next Batch)

Total (Domestic + Industries)

6 39.5 45.5 (6 KLD recycle out of

total waste water actual waste water will be 39.5

KLD)

Note: The unit has permission from CETP (ETL) for 4 tankers per day.

Sr. No.

Particular Water Consumption in KL/Day Quantity as per CCA -

AWH-51863

Quantity as per Proposed Expansion

Total Quantity After Expansion

1. Domestic 3.5 2.5 6 2. Industrial 2.1 a) Process 5.3 48.2 53.5

(47.5 Fresh + 6 Recycle) b) Boiler 0.5 5 5.5 c) Cooling 0.5 5 5.5 d) Washing 0 6 6 e) Gardening 0.2 3.3 3.5

Total (Domestic + Industries)

10 70 80 (74 Fresh + 6 Recycle)



EXISTING WATER BALANCE DIAGRAM

TOTAL WATER BALANCE DIAGRAM (PROPOSED)

Process 5.3 KL/Day

Water Requirement 10 KL/Day

Domestic 3.5 KL/Day

Boiler 0.5 KL/Day

Cooling Tower

0.5 KL/Day

ETL 3.5 KL/Day

Septic/soak pit 2.5 KL/Day Effluent from

process 3.1 KL/Day

Loss 2.2 KL/Day

Gardening 0.2 KL/Day

0.2 KL/Day 0.2 KL/Day

Process 53.5 KL/Day (47.5 fresh +

6 recycle)

Total Water Requirement 80 KL/Day

(74 fresh water + 6 recycle to Process)

Domestic 6.0 KL/Day

Boiler 5.5 KL/Day

Washing 6 KL/Day

ETP 39.5 KL/Day

Sewage 4.5 KL/Day

Recycle to Process

6 KL/Day

Effluent 32 KL/Day

Gardening 3.5 KL/Day

Cooling Tower

5.5 KL/Day

6 KLD

To ETL 39 KL/Day

Loss 4KLDLoss 21.5

Sludge to TSDF0.5 KL/Day

Loss 1.5

Loss 4KLD



ANNEXURE-VIII

EFFLUENT TREATMENT PROCESS:

M/s. Shree Colosperse Pvt. Ltd. has an Effluent Treatment Plant (ETP) comprising of Primary

Tertiary treatment.

Washing effluent from reaction vessels cleaning, press cleaning, spray drier cleaning and from

bathing comes to Oil and Grit separator and then into equalization tank. Equalization’s tanks

Then pH is adjusted to 6.5 -7.5 with caustic lye. This solution is passed through filter press to

remove any suspended particle. The clarified effluent is sent to Enviro Technology Limited

(ETL), Ankleshwar for further treatment through tankers.

The sludge from the setting tanks is filtered through filter press the sludge obtained after

unloading filter press is dried in sludge drying bed and sent to TSDF site of M/s. Bharuch Enviro

Infrastructure Ltd. (BEIL), Ankleshwar for disposal.

NAME AND SIZE OF ETP UNITS (Proposed)

SL.

NO.

DESCRIPTION CAPACITY (KL)

1 Equalization Tank 40

2 Neutralization Tank 15

3 Filter Press 36” size

4 Final collection tank 20



EFFLUENT TREATMENT PLANT FLOW DIAGRAM

TRATED EFFLUENT STORAGE TANK

TREATED EFFLUENT SENT TO ETL.

COLLECTION CUM

EQUALIZATION TANK

SETTLING TANK

FILTER PRESS

SLUDGE TO TSDF

SITEEFFLUENT

COMING FROM PLANT

NUTRALATION

TANK



ANNEXURE-IX

ELECTRICITY AND FUEL CONSUMPTIONS

Sr.

No.

Particulars Existing

Quantity as

CCA

Proposed

Quantity

Total Quantity

after

Expansion

Source

1. Natural Gas 5500

NM3/Month

32,500

NM3/Month

38,000

NM3/Month

Gujarat

Gas

2. Diesel 40 liter/hr 60 liter/hr 100 liter/hr Local

3. Energy-

Electricity

125 KVA 175 KVA 300 KVA DGVCL



ANNEXURE- X

DETAILS OF FLUE GAS EMISSIONS

Sr. No

Source of emission

Type of emission

Stack Height (meter)

Stack Diameter (meter)

Fuel Name

And qty.

Pollution control

equipment Existing

1 Boiler (1 TPH)

PM SO2 Nox

13 0.35 Natural Gas 50 SM3/hr

Adequate stack height

2 Hot Air

Generator (1 lac kcal)

PM SO2 Nox


Wet Scrubber/Bag

Filter Proposed

3 Boiler (2 TPH)

PM SO2 NOx


Adequate stack height

4

Hot Air Generator (3 lac kcal)

(2 No.)

PM SO2 NOx


Wet Scrubber/Bag

Filter

5

D.G. Set - 200 KVA

(emergency used only)

PM SO2 NOx

10 0.15 Diesel 40 Liter/hr -

PROCESS EMISSION

There is no process emission. There will be no process emission due to proposed expansion.



ANNEXURE- XI

DETAILS OF HAZARDOUS WASTE

Sr. No.

Name Of The Waste Category Waste Generating

Process / Step State Quantity

Mode of disposal Existing Additional Total

1 ETP Sludge 34.3 Effluent Treatment Solid 00

12 MT/Annum

12 MT/Annum Collection and Storage within premises & Transportation and

Disposal at TSDF of BEIL, Ankleshwar

2 Used Oil 5.1 Maintenance and used lubricant oil generated from Maintenance

Activities

Liquid 0.006 KL/Annum

0.1 KL/Annum

0.106 KL/Annum

Collection and Storage within premises & Disposal by selling

to registered re-processor

3 Discarded Containers/ Bags/Liners

33.3 Manufacturing and Utilities

Solid 00 50, 000 Nos./Annum

50,000 Nos./Annum

Collection, Storage and Decontamination within

premises & Disposal by selling to authorized re-cycler.



ANNEXURE- XII

NAME OF HAZARDOUS CHEMICAL

Sr. No. Name of Chemicals

1. Caustic Lye 2. Hydrochloric Acid 3. Phenol 4. Acetic Acid 5. Acrylonitrile 6. Formaldehyde



ANNEXURE- XIII

Compliance report of CCA

COMPLIANCE REPORT OF CCA

1 CCA Amendment No: AWH-51863, Dated: 02/2/2013

Sr. No.

CONSENT CONDITION COMPLIANCE

2. The consent under Water Act-1974 for conveying the industrial effluent to the CETP of M/s.ETL for the treatment and disposal of treated effluent & The consent under Air Act-1981 Authorization under environment (Protection) Act, 1986 shall be Valid up to 24/10/2017 to operate industrial plant for manufacture of the following products.

The unit has manufactured the products within consented quantity. Now, unit is applying for Environment Clearance.

Sr.No Product Max. quantity Mt/month

1. Disperse navy Blue 3G (IGNS) 2.0 2. Disperse Golden Yellow GG 1.0 3. Disperse Yellow AL 0.5 4. Disperse Rubine 3B 0.5 5. Disperse Scarlet RR 0.5 6. Disperse Yellow Brown REL 0.25 7. Disperse Orange ERL 1.00 8. Disperse Violet B 0.25 9. Disperse Blue SE2RI 0.25 10. Disperse Yellow 7GL 0.5 11. Disperse Rubine S2GL 0.5 12. Disperse Agent SS 1.0 13. Disperse Yellow FFL 0.5

3. CONDITION UNDER THE WATER ACT 1974: 3.1 The quantity of industrial effluent shall not exceed

3500 Lit/day. Total quantity of industrial effluent generation does not exceed the quantity mentioned in the respective consent.

3.2 The quantity of the domestic waste water (Sewage) shall not exceed 2500 Lit/Day.

Total quantity of domestic waste water generation does not exceed the quantity mentioned in the respective consent.

3.3 The water consumption for industrial process and other ancillary operations shall not exceed 6500 Lit/day and water consumption for domestic purpose shall not exceed 3500 Lit/day as mentioned in Form-D

Total quantity of water consumption does not exceed the quantity mentioned in the respective consent.



submitted consent application under water Act-1974. 3.4 Sewage shall be disposal of through septic/soak pit

system. Noted by unit and complied with the same.

3.5 The Unit shall affix of water meters as per section 4 (1) of the water (Prevention and control of pollution) Cess Act-1977 for the purpose of measuring and recording the quantity of water consumed at such places as may be required, within 15 days and it shall be presumed that the quality indicated by the meter has been consumed by the industry unit the contrary is proved.

Noted by unit and complied the same.

3.6 The GIDC drainage connection given by the discharge of industrial effluent shall be disconnected & the outlet shall be sealed.


3.4 TRADE EFFLUENT:

3.4.1 The applicant shall be required to make storage facilities to store the effluent for at least 48 hours by providing acid proof brick lined impervious tanks/HDPE tanks.

Noted by unit.

3.4.2 The applicant shall make fixed arrangement for loading, the effluent from their collection tanks to the tanker of ETL. The unit shall not keep any by-pass line or system or loose or flexible pipe line for loading the effluent into the tanker of ETL.


3.4.3 Leachate from the hazardous solid waste, if any shall also be connected into a collection tank through leachate collection facilities and shall be conveyed along with industrial effluent to the CETP of ETL.


3.4.4 Magnetic flow meters shall be installed at the inlet & outlet of effluent collection tanks/ETP to measure the quantity of effluent lifted into the tanker of ETL.


3.4.5 The ENTIRE quantity of industrial effluent shall have to be conveyed by ETL; In no circumstances the effluent either treated or untreated shall be discharged into GIDC drain or anywhere else.

Noted by unit.

3.4.6 Disposal system for storm water shall be provided separately. In no circumstances storm water shall be mixed with industrial effluent.

Noted by unit.

3.4.7 The applicant shall be responsible for loading its effluent into the tankers of the ETL for transporting the effluent. due care shall be taken to avoid any leakage or spillage of effluent during loading the tanker.




3.4.8 If the effluent contains heavy metals, phenols & cyanide, the ETL member unit shall have to treat the effluent within its premises to conform to the following standards ( Whichever applicable ) PARAMETERS PERMISSIBLE LIMIT Zinc (Zn) 5.0 mg/l Total Chromium 2.0 mg/l Nickel (Ni) 3.0 mg/l Mercury (Hg) 0.01 mg/lCyanide (as CN) 0.2 mg/l Pesticides Absent Phenolic Compounds 1.0 mg/l Lead (Pb) 0.1 mg/l Copper (Cu) 3.0 mg/l Hexavelent Chromium 0.1 mg/l Cadmium (Cd) 1.0 mg/l Arsenic (As) 0.2 mg/l Selenium 0.05 mg/l BOD 3600 mg/l COD 11000 mg/l Free Acidity 55000 ppm Ammonia 100 mg/l

All the parameters are within the limits. Unit has membership for discharging of treated effluent. (Effluent is sent to ETL by tanker.)

3.3.9 The applicant shall keep records of quality of production of each product, quantity of water consumption, quantity of effluent generated and consumption of electricity on day to day basis and required to submit the complied record of one month to GPCB & ETL on or before fifth day of the succeeding month.


3.3.10 In case of shut-down of plant for more than three days for any reason, the ETL unit member shall intimate to ETL authority & GPCB well in advance for better operation & management of CETP.

Noted by unit.

3.3.11 The applicant shall either stop or curtail its production activities if the effluent is not adequately treated by the CETP of ETL to conform to the standards specified by G.P.C.B.

Noted by unit.

3.3.12 The applicant shall representative of ETL shall have right of entry at anytime for the purpose of inspection and monitoring the effluent collection facilities/ETP (If required) of the applicant.

Noted by unit.

3.3.13 In case of incinerators, the flow measuring devices for mother liquor/toxic effluent/Non-biodegrable effluent/Non-biodegradable effluent, light diesel oil, furnace oil, etc. i.e. fuel used for combustion, air used for combustion shall be separately provided. Incinerator temperature recording devices as well as

Incinerator facility is not required in plant promises.



gaseous flow measuring devices for scrubber shall also be provided. These data of temperature & flow should be recorded everyday & submitted to GPCB & ETL on monthly basis.

3.3.14 The GIDC drainage connection given by the GIDC for discharge of industrial effluent shall be disconnected & outlet shall be sealed.


3.3.15 If the ETL authority terminates the membership of CETP, the ETL member unit shall have to close down the manufacturing activities/industrial operation of the process plant immediately until the ETL membership is resumed.

Noted by unit.

3.3.17 The applicant shall put up at the entrance a board displaying ETL membership number & date of joining of ETL, the name of unit, particulars of the products/process and the name of proprietor /partners/directors of the unit and the electricity consumer number as on the record of GEB.


3.3.18 The Environmental management Unit/Cell shall be setup to ensure implementation on and monitoring of environment safeguards and other conditions stipulated by statutory authorities. The environmental Management Cell/Unit shall directly report to the chief Executive of the organization and shall work as a focal point for internalizing environmental issued. These Cells also coordinate the exercise of environmental audit preparation of environmental statements.

Noted by unit.

3.3.19 The Environmental audit shall be out yearly and the environmental statements pretending to the previous year shall be submitting to this state board latest by 30 th September every year.

Environment audit will be carried out once in year through GPCB recognized Environment Auditors. (This is as per directive of Hon’ble Gujarat High Court.)

3.3.20 The Board reserves the right to revoke and/or revoke the consent and/or make modifications in the conditions which seems fit in accordance with provisions of Water Act-1974.

Noted by unit.

3.3.21 In case of change of ownership/management the name and address of the new ownership / partners/directors/proprietors should immediately be intimate to the board.

Noted by unit.

3.3.22 The applicant shall have to submit EVERY MONTH the certified copies of challans (endorsed by ETL) regarding the quantity of industrial effluent (No. of Tankers) delivered per month to CETP of ETL.

Noted by unit.

3.3.23 Unit have to modify/improve performance of existing Effluent treatment facilities for efficiency & adequacy in order to comply with prescribed standards in

Noted by unit. Unit will be following the instruction.



respects of effective operation of effluent treatment plant with regards to notification No.P/111(3) Board’s standards/33129 dated 30th October 2001 in fight of High court in SCA No.4473 of 97 dated 21/02/99

4. CONDITIONS UNDER AIR ACT 1981 : 4.1 The following shall be used as fuel in Boiler.

Sr. No. Fuel Quantity 1. Natural Gas 5500

NM3/Month

Total quantity of natural gas consumption does not exceed the quantity mentioned in the respective consent.

4.2 The applicant shall install & operate a comprehensive adequate air pollution control system in order to achieve prescribe norms as to achieve standards.

Noted by unit.

4.2.1 The flue gas emission through stack attached to boiler/furnace shall conform to the following standards:

The flue gas emissions are within tolerance limit.

Stack No. Stack Attached To

Stack height in meter

Parameter Permissible Limit

1. Boiler 13 SPM 150 mg/NM3

2. Hot Air Generation 15 SO2

NOX 100 ppm 50 ppm

4.2.2 There shall be no process emission from the manufacturing process as well as any other ancillary operations.

Noted by unit.

4.2.3 The concentration of the following parameters in the ambient air within the premises of the industry shall not exceed the limits specified here under.

Unit will not cross the ambient air quality standards within the premises.

PARAMETER PERMISSIBLE LIMIT PM 10 100 mg/NM3 PM 2.5 60 mg/NM3 SOx 80 mg/NM3 NOx 80 mg/NM3

4.2.4 The applicant shall operate industrial plant/air pollution control equipment very efficiently and continuously so that the gaseous emission always conforms to the standards specified in condition no.4.2.1 & 4.2.3 above.

Unit will maintain all the equipment & industrial plant regularly so they can work efficiently and continuously.

4.2.5 The consent to operate the industrial plant shall lapse if at anytime the parameters of the gaseous emission are not within the tolerance limits specified in the condition no.4.2.1 & 4.2.3 above.

Noted by unit.

4.3 The applicant shall provide portholes, ladder, platform etc at chimney(s) for monitoring the air emissions and

Facility for stack monitoring like portholes, ladder and platform are



the same shall be open for inspection to / and for use of Board’s staff. The Chimney(s) vents attached to various sources of emission shall be designed by numbers such as S-1, S-2, etc.and these shall be painted /displayed to facilitate identification.

provided.

4.4 The industry shall take adequate measures for control of noise levels from its own sources within the premises so as to maintain ambient air quality standards in respect of noise to less than 75dB(a) during day time and 70 dB(A)during night time. Daytime is reckoned in between 6a.m and 10 p.m and night time is reckoned between 10 p.m and 6 am

Noise level is well within the standard of 75 dB (A) during day time and 70 dB (A) during night.

5 GENERAL CONDITIONS : 5.1 Any change in personnel, equipment or working

conditions as mentioned in the consents form/order should immediately be intimated to this Board.

Noted by unit.

6. AUTHORISATION FOR THE MANAGEMENT & HANDILING OF HAZARDOUS WASTES FORM-2 ( See rule 3 (C) & 5(5) )

6.1 Number of authorization : AWH-51863,date of Issue 02/2/2013

Unit has applied for Environment Clearance.

6.1.1 M/s. SHREE COLOSPERSE PVT. LTD., is hereby granted an authorization to operate facility for following hazardous wastes on the premises situated at PLOT NO:6412,GIDC ESTATE ANKLESHWAR, DIST : BHARUCH.

Noted by unit. The waste used oil generated is stored in specified manner and disposal by selling to Registered Re-refiners.

Sr.No Waste Category

Quantity/Year

Treatment & Disposal

1. Used Oil 5.1 0.006 KL

Collection, Storage Transportation, Disposal by selling to Registered Re-refiners.

6.1.2 The authorization is granted to operate a facility for collection, storage, within the factory premises and transportation and ultimate disposal of Hazardous wastes as mentioned above.


6.1.3 The authorization shall be in force for a period up to five years from the date of application.

Noted by unit.

6.1.4 The authorization is subject to the conditions stated below and such other conditions as may be specified in the rules from time to time under Environment (Protection) Act-1986.

Noted by unit

TERMS AND CONDITIONS OF AUTHORISATION



a) The applicant shall comply with the provision of the Environment (Protection) Act-1986 and the rules made there under.

Noticed by the unit.

b) The authorization shall be produced for inspection at the request of an officer authorized by the Gujarat Pollution Control Board.

Noted by unit and unit always give permission to GPCB authorized officer for inspection.

c) The persons authorized shall not rent, land, sell, transfer of otherwise transport the hazardous wastes without obtaining prior permission of the Gujarat Pollution Control Board.


d) Any unauthorized change in personnel, equipment or working conditions as mentioned in the authorization order by the persons authorized shall constitute a breach of this authorization.


e) It is a duty of the authorised person to take prior permission of the Gujarat Pollution Control board to close down the facility.


f) An application for the renewal of an authorization shall be made as laid down in rule 5 (6).


g) Industry shall submit annual report within 15 days and sub squinty by 31st January every year.


7. Industry shall have to display the revelent information with regard to hazardous waste as indicated in the court’s order in W.P.No.657 of 1995 dated 14th October 2003.


8. Industry shall have to display on-line data outside the main factory gate with regard to and nature of hazardous chemicals being handled in the plant, including waste water and air emission and solid hazardous waste generated within the factory premises.


9. Industry shall submit annual report within 15 days and subsequently 31st January every year.


10. Industry shall have to manage waste oil; discarded containers etc., process waste as per Amended Rules-2003 and shall apply Authorisation for all applicable waste as per Amended Rules-2003.

Noted by unit.





Documents

ANNEXURE- I PROPOSED TERMS OF REFERENCE · ANNEXURE- I PROPOSED TERMS OF REFERENCE ... Disperse violet 26 and/or 6408-72-6 V AZO Pigments 0 10 10 ... Sodium hydroxide 0.08 6.63 2-MP