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M/s. Aarti Industries Ltd. (Amine Division), Vapi. M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 15 ANNEXURE I PROPOSED TERMS OF REFERENCE As per standard ToR of organic manufacturing sector issued by MoEF&CC.

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Page 1: ANNEXURE I PROPOSED TERMS OF REFERENCEenvironmentclearance.nic.in/writereaddata/Online/... · ANNEXURE I PROPOSED TERMS OF REFERENCE ... soln(23-25%) 3570 Lime(purity 80%) 580 Ammonia

M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 15

ANNEXURE I

PROPOSED TERMS OF REFERENCE As per standard ToR of organic manufacturing sector issued by MoEF&CC.

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 1

Annexure II Site Plan and Plant Layout

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 1

ANNEXURE III LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY

Sr. No.

List of Products Existing As per CCA No. AWH-62543 in MT/Month

Proposed Expansion in MT/Month

Total Quantity after expansion in MT/Month

I Amination Products 555 1500 1500 1. 4-Nitro Aniline (PNA) and/or 50 2. 2-Nitro Aniline(ONA) and/or 270 3. 2-Chloro 4 Nitro Aniline

(OCPNA) and/or 20

4. Para Chloro Ortho Nitro Aniline (PCONA) and /or

75

5. Di Chloro Ortho Nitro Aniline (DCONA) and /or

130

6. 6-Chloro Ortho Nitro Aniline and /or

10

7. 4,4-Diamino DiphenylSulfone(DADPS) and/ or

0

8. Any other amination product 0 Total 555 1500 1500 9. Co-product- Calcium chloride

solution 767 1573 1573

10. Co-product -Ammonia solution

-- 152 152

11. Co-product-Ammonium sulphate Solution/Ammonium Sulphate Solid

-- 114/40 114/40

12. Co Product-Sodium Chloride -- 709 709 13. Co Product-Copper

Hydroxide/Copper oxide -- 77 77

Total 767 2625/2551 2625/2551

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 2

LIST OF RAW MATERIALS

Sr. No.

Name of product Production quantity

Name of Raw material

Raw material consumption per ton

Raw Material consumption in MT/Month

1.

4- Nitro-Aniline (PNA) and/or

1500

ONCB/ PNCB 1.149 1724.14 Anhydrous Ammonia

0.144 216.552

Carbon 0.008 11.7241 HCl 0.172 258.621 Lime (purity 80%)

0.267 400

Total 1.741 2611.03 2.

2- Nitro Aniline (ONA) and/or

1500

ONCB/ PNCB 1.149 1724.14 Anhydrous Ammonia

0.144 216.552

Carbon 0.008 11.7241 HCl 0.172 258.621 Lime(purity 80%)

0.267 400

Total 1.741 2611.03 3.

2- Chloro 4 Nitro Aniline (OCPNA) and/or

1500

ONCB/ PNCB 1.124 1685.39 Anhydrous Ammonia

0.118 176.404

Carbon 0.006 9.5505 HCl 0.14 210.674 Lime (purity 80%)

0.18 269.663

Total 1.568 2351.69 4.

Para Chloro Ortho Nitro Aniline (PCONA) and/or

1500

ONCB/ PNCB 1.124 1685.39 Anhydrous Ammonia

0.118 176.404

Carbon 0.006 9.5505 HCl 0.14 210.674 Lime (purity 80%)

0.18 269.663

Total 1.568 2351.69

5.

Di Chloro Ortho Nitro Aniline(DCONA) and/or

1500

TCNB 1.282 1923.08 Anhydrous Ammonia

0.177 266.026

Carbon 0.006 9.6153

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 3

Sr. No.

Name of product Production quantity

Name of Raw material

Raw material consumption per ton

Raw Material consumption in MT/Month

MCB 3.077 4615.38 HCl 0.145 217.949 Lime(purity 80%)

0.171 256.41

Total 4.859 7288.46 6.

6-Chloro Orhto Nitro Aniline and/or

1500

2,3 BCNB 1.124 1685.39 Anhydrous Ammonia

0.118 176.404

Carbon 0.006 9.5505 HCl 0.14 210.674 Lime (purity 80%)

0.18 269.663

Total 1.568 2351.69 7.

DADPS and/or

1500

Ammonia 3687 3.414 Recovered Ammonia

833 0.771

DCDPS 1250 1.157 Catalyst 50 0.046 Caustic lye 725 0.671 Total 6545 6.06

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 4

ANNEXURE IV BRIEF PROCESS DESCRIPTION

1. 4-Nitro Aniline (PNA) and 2. 2-Nitro Aniline(ONA)

Chemical Reactions of PNA and ONA: PNA:

ONA:

Cl

NO2

+ 2 NH3

NH2

NO2

+ NH4Cl

Para Nitro Chloro Benzene( PNCB) M. W. 157.5

Para Nitro Aniline ( PNA ) M.W.138

Cl NO2

+ 2 NH3

NH2

+ NH4Cl Ortho Nitro Chloro Benzene( ONCB) M.W157.5

Ortho Nitro Aniline ( ONA) M.W 138

NO2

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 5

Material Balance: Input Kg Output KgONCB/ PNCB 2500Anhydrous Ammonia 314 Ammonia solution 218932% Ammonia Solution 6000 Reaction Mass 6625Total 8814 Total 8814

Reaction Mass 6625 ONA/PNA -product 2175Aqueous Layer 4450

Total 6625 Total 6625

Ammonia solution 218914% Ammonia solution 3811 32% Ammonia solution

(reuse in next batch)6000

Total 6000 Total 6000

carbon 17 Solid waste(To TSDF) 190HCl 375Aqueous Layer 4450 Calcium Chloride

soln(23-25%)3570

Lime(purity 80%) 580 Ammonia Solution 1662Total 5422 Total 5422

Loss 1290Calcium Chloride soln(23-25%)

3570 Calcium Chloride sol(Sales By Product)

2280

Total 3570 Total 3570

Ammonia Solution 1662Water 2149 14% Ammonia solution

(reuse in autoclave scrubber)

3811

Total 3811 Total 3811

Autoclave

Autoclave Scruber

Treatment and Filtration

Evaporation

Scrubber

Layer Separation

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 6

3. 2-Chloro 4 Nitro Aniline (OCPNA) and 4. Para Chloro Ortho Nitro Aniline (PCONA) and 5. 6-Chloro Ortho Nitro Aniline

Chemical Reactions of OCPNA/PCONA/6-Chloro Ortho Nitro Aniline OCPNA:

PCONA:

6-Chloro Ortho Nitro Aniline

Chemical Reaction:

NO2

Cl

+ 2 NH3

NH2

NO2

+ NH4Cl

3,4 Di Chloro Nitro Benzene ( 3:4DCNB ) M.W 192

Ortho Chloro Para Nitro Aniline ( OCPNA) M.W-172.5

Cl

Cl

+

NO2 NH2

Cl

+ NH4Cl

2,5 Di Chloro Nitro Benzene ( 2,5 DCNB ) M.W 192

Para Chloro Ortho Nitro Aniline ( PCONA) M.W-172.5

NO2

2 NH3 Cl

Cl

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 7

Material Balance:

Input Kg Output KgBNCB/PNCB/ 2,3 DCNB

3000

Anhydrous Ammonia 314 Ammonia solution 218932% Ammonia Solution 6000 Reaction Mass 7125Total 9314 Total 9314

Input Kg Output KgReaction Mass 7125 OCPNA/PCONA -product 2670

Aqueous Layer 4455Total 7125 Total 7125

Ammonia solution 2189 Ammonia 014% Ammonia solution 3811 32% Ammonia solution

(reuse in next batch)6000

Total 6000 Total 6000

carbon 17 Solid waste(To TSDF) 160HCl 375Aqueous Layer 4455 Calcium Chloride soln(23-

25%)3570

Lime(purity 80%) 480 Ammonia Solution 1597Total 5327 Total 5327

Loss 1290Calcium Chloride soln(23-25%)

3570 Calcium Chloride sol(Sales By Product)

2280

Total 3570Total 3570

Ammonia Solution 1597Water 2214 14% Ammonia solution

(reuse in autoclave scrubber)3811

Total 3811 Total 3811

Autoclave

Layer Separation

Autoclave Scrubber

Treatment and Filtration

Evaporation

Scrubber

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 8

6. Di Chloro Ortho Nitro Aniline (DCONA)

Chemical Reaction of Di Chloro Ortho Nitro Aniline (DCONA) DCONA:

NO2

+ 2 NH3

NH2

+ NH4Cl

2, 3, 4 Tri Chloro Nitro Benzene (TCNB) M. W. 226.5

2,3 Di Chloro Ortho Nitro Aniline( DCONA ) M.W.207

Cl

Cl Cl

Cl

Cl

NO2

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 9

Material Balance: Input Kg Output Kgtcnb 3000 crude DCONA 3048Anhydrous Ammonia 415 Rec Ammonia 1200Rec Ammonia 1200MCB 7200 Organic layer 7567Total 11815 Total 11815

crude DCONA 3048 DCONA 2340water 2100 Aq solution 2808Total 5148 Total 5148

carbon 15 Solid waste(To TSDF) 133Hcl 340Aq solution 2808 Calcium Chloride soln(23-

25%)3194

Lime(purity 80%) 400 Ammonia Solution sale 236Total 3563 Total 3563

Loss 1154Calcium Chloride soln(23-25%)

3194 Calcium Chloride sol(Sales By Product)

2040

Total 3194 Total 3194

Organic layer 7567 Rec MCB 6984Loss 185Residue 398

Total 7567 Total 7567

Autoclave

Washing

Treatment and Filtration

Evaporation

Distillation

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 10

7. 4,4-’ ’Diamino Diphenyl Sulfone(DADPS) Chemical Reaction:

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 11

Material Balance: Input Kg Kg Output

Liquor Ammonia 3687Recovered liquor ammonia

833

DCDPS 1250 5774 Reaction massCatalyst 50 46 Vapour lossTotal 5820 5820 Total

Reaction mass 5774 Cooling 5774 Reaction massTotal 5774 5774 Total

Reaction mass 5774 1080 DADPSWater 400 5094 MLTotal 6174 6174 Total

833 Liquor AmmoniaML 5094 55 Copper hydroxide Caustic lye 725 4931 Sodium chloride

solution Total 5819 5819 Total

510 NaClSodium chloride solution

4931 4421 Water loss

Total 4931 4931 Total

Ammonolysis

Filtration

Ammonia recovery

Evaporation

Common Process Description: An amination of corresponding Nitro Chloro Benzene produces all the Nitro Aniline and chloro

nitro Aniline manufactured in company.Amination is carried out in an auto clave and products

are isolated by layer separation

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 12

ANNEXURE V DETAILS OF WATER CONSUMPTION

DETAILS OF WASTE WATER GENERATION

Sr. No.

Section

Water Consumption IN KL/Day Existing As Per CCA No. AWH-62543

As Per Proposed Expansion

Total

1. Domestic 2 23 25 2. Industrial Process 20 31 51 Washing 15 15 30 Boiler 85 203 288 Cooling 210 85 (2.5 Fresh+ 82.5

Recovered) 295 ( 212.5 Fresh + 82.5 Recovered)

Gardening 8 7 15 Total

(Industrial) 338 341( 258.5 Fresh +

82.5 Recovered) 679 ( 596.5 Fresh + 82.5 Recovered)

Total (Domestic + Industrial)

340 364 ( 281.5 Fresh + 82.5 Recovered)

704 ( 621.5 Fresh + 82.5 Recovered)

Sr. No.

Section Waste Water Generation in KL/Day Existing As Per CCA No. AWH-62543

As Per Proposed Expansion

Total

1. Domestic 2 23 25 2. Industrial Process 0 0 0

Washing 15 15 30 DM Plant 0 40 40 Boiler 15 10 25 Cooling 20 18 38 Gardening 0 0 0 Total (Industrial)

50 83 133

Total (Domestic + Industrial)

52 106 158

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 13

WATER BALANCE DIAGRAM (EXISTING)

GIDC supply 340 KL/Day

Process 20 KL/Day

Effluent From washing

15 KL/Day

Cooling tower Blow down 20 KL/Day

Sewage 2 KL/Day

ETP 50 KL/Day

Domestic 2 KL/Day

Gardening 8 KL/Day

Cooling tower210 KL/Day

Washing 15 KL/Day

Treated effluent is sent to CETP 50 KL/Day

Boiler 85 KL/Day

Boiler blow down

15 KL/Day

Loss 70 KL/Day Loss 190

KL/Day

Soak Pit/ Septic Tank2 KL/Day

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 14

WATER BALANCE DIAGRAM (AFTER EXPANSION)

Total Water 704 KL/Day (621.5 Fresh+ 82.5 Recovered)

Process 51 KL/Day

Effluent From washing

30 KL/Day

Cooling tower Blow down 38 KL/Day

Sewage 25 KL/Day

ETP 133 KL/Day (Existing 50 KL/Day+ Proposed 83 KL/Day)

Domestic 25

KL/Day

Gardening 15 KL/Day

Cooling tower295 KL/Day

(212.5 Fresh+ 82.5

Recovered)

Washing 30 KL/Day

Existing treated effluent is sent to CETP 50 KL/Day

Boiler 248 KL/Day

Boiler blow down

25 KL/Day

R O Plant 83 KL/Day R O Permeate

58 KL/Day

R O Reject 25 KL/Day

MEE 25 KL/Day

MEE Salt 0.5 KL/Day

MEE Recovered 24.5 KL/Day

Total Recovered 82.5 KL/Day Soak Pit/

Septic Tank25 KL/Day

Discharge to Sewage line

DM Plant 288 KL/Day

Regeneration40 KL/Day

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 15

Note:

Existing and proposed effluent will be treated in unit’s own ETP. In which 50 KL/Day existing

waste water is treated in Effluent treatment plant and after treatment treated water is sent to

CETP. Vapi Waste & Effluent Management Co. Limited Membership Letter is attached as

Annexure- XI.

Proposed additional quantity 83 KL/Day of effluent will be treated in R.O. followed by MEE to

achieve zero liquid discharge of proposed quantity only.

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 16

ANNEXURE-VI DETAILS OF TREATMENT SCHEME AND DISPOSAL

DETAILS OF EFFLUENT TREATMENT PLANT (Existing) The effluent generated from the industry is received through oil and grease trap from the

Collection Pit in to the Neutralization cum equalization tank where pH is adjusted. This treated

effluent is transfer to dosing tank, where Alum, Poly Electrolyte and Lime are added so as to

neutralize the effluent and to generate the easily settable sludge. It is then taken to primary

clarifier where the sludge is allowed to settle and is removed and fed to SDB. The overflow from

primary clarifier is sent to secondary clarifier tank. The secondary sludge removed is fed to the

SDB where it is mixed with the primary sludge and the overflow is passed through sand filter

and carbon column and then taken to collection tank and then the treated effluent is discharged to

common effluent treatment plant for further treatment through underground drainage system of

G.I.D.C.

DETAILS OF ETP UNITS: Sr. No.

Name of Units Total Capacity(KL)

1. Collection Pit 13 2. Oil & Grease Trap 1.2 3. Neutralization tank 60 4. Dosing Tank 50 5. Lime Dosing Tank 0.2 6. Ferrous Sulphate Dosing Tank 0.2 7. Poly Electrolyte Dosing Tank 0.2 8. Primary Clarifier 40 9. Agitation System 7.5 HP 10. Secondary Settling Tank 40 11. Sludge Drying bed 4 m3 12. Collection Tank 4 KL 13. Sand filter 1.2 m3 14. Carbon Filter. 1.2 m3

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 17

Existing ETP Flow Diagram

Primary Clarifier 40 KL

S.D.B 4 m2

Secondary Clarifier 40 KL

SF. Collection

tank 4 KL

Dosing Tank 50 KL

P E L

L I

ME

A L U M

CETP chamber

CC

Neutralization Tank 60 KL

Oil & Grease trap

HYPO

Collection Pit 13 KL

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 18

DETAILS OF EFFLUENT TREATMENT PLANT: (Proposed) DETAILS OF ETP UNITS: Sr. No.

Name of Units Total Capacity(KL)

1. Neutralization tank 60KL 2. Filter press 1 No 3. Desilication system 4m3/Hr 4. RO plant 100KLD 5. Multi effect evaporator 30KLD Proposed ETP Process The effluent from various sections will be collected in Neutralization cum equalization tank

where pH is adjusted. This treated effluent is passed through filter press and disilcation system

before dosing into in the RO system. Treated water will be further treated in RO followed by

MEE. The condensate water from MEE and permeate water from RO is reused and the residue

from MEE is send to TSDF site.

Proposed flow diagram of ETP

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 19

ANNEXURE VII

ELECTRICITY AND FUEL CONSUMPTIONS

Sr. No.

Name of Fuel Requirement Source Existing As Per CCA No. AWH-62543

As per Proposed Expansion

Total

1. Diesel 120 Lit/Hr 110 Lit/Hr 330 Lit/Hr Local Market

2. Coal 1.5 MT/Hr 3.1 MT/Hr 4.6 MT/Hr Imported coal

3. Energy - Electricity

1225 KVA 300 KVA 1525 KVA DGVCL

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 20

ANNEXURE VIII DETAILS OF FLUE GAS EMISSIONS

Sr. No.

Stack attached to

Stack Height in meter

APCM Fuel Probable Pollutants

Permissible Limit

Existing As Per CCA No. AWH-62543 1. Boiler

(13 TPH) 30 ESP Coal:

1.5 MT/Hr PM SO2 NOx

150 mg/Nm3 100 ppm 50 ppm 2. Boiler

(10TPH) 30 Bag filter

& Multi Cyclone, Dust Collector

Coal: 1.5 MT/Hr

3. DG Set (1000 KVA)(StandBy)

11 -- Diesel

4. DG Set (625 KVA)(StandBy)

11 -- Diesel

As per Proposed Expansion 1. Boiler

(25TPH)(StandBy)

30 ESP Coal PM SO2 NOx

150 mg/Nm3 100 ppm 50 ppm

2. DG Set (625 KVA)(StandBy)

11 -- Diesel

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 21

DETAILS OF PROCESS EMISSION Sr.No.

Stack attached to

Stack Height in meter

APCM Probable Pollutants

Permissible Limit

Existing As Per CCA No. AWH-62543 1. Autoclave

Reactor & ONA day tank

11 Water Scrubbers followed by Sulphuric Acid Scrubber

NH3 175 mg/Nm3

2.

Ammonia Recovery

11 Water Scrubbers followed by Sulphuric Acid Scrubber

As per Proposed Expansion Note: There is no addition of any Process stack.

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M/s. Aarti Industries Ltd. (Amine Division), Vapi.

M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 22

ANNEXURE IX

DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL Sr. No.

Type of hazardous waste

Category no.

Quantity Facility Existing As Per CCA No. AWH-62543 in MT/Month

As Per Proposed Expansion in MT/Month

Total in MT/Month

1. ETP Waste 34.3 110 0 110 Collection, storage, transportation, disposal at TSDF

2. MEE Salt 0 15 15 3. Calcium

sludge 0 135 135

4. Process waste containing organic complex

26.1 10 250 260 Collection, storage, transportation, disposal at CHWIF/Co processing facility

5. Discarded containers/bags

33.3 What so ever generated

What so ever generated

What so ever generated

Collection, Storage, Decontamination, Disposal by sold to authorize recyclers.

6. Used oil 5.1 50 Liter/Year

550 Liter/Year

600 Liter/Year

Collection, Storage, Transportation, Disposal by selling to registered reprocessors.

7. Fly Ash -- 00 180 180 Collection, Storage, Transportation disposal by at fly ash handlers.

8. Insulation Waste

-- 00 What so ever generated

What so ever generated

Collection, Storage, Transportation disposal by at TSDF Site.

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GPCB

·1_-_'. GUJARAT POLLUTION CONTROL BOARDPARYAVARAN BHAVAN

Sector 10-A Gandhinagar 382010Phone (079) 23226295Fax (079) 23232156Website www.gpcb.gov.in

By R.P.A.D.In exercise of the power conferred under sectioll-25 of the Water (Prevention and Control of Pollution) Act-

1974, under section-21 ofthe Air (Prevention and Control of Pollution)-1981 and Authorization under rule 5(4) of theHazardous Waste (Management, Handling & Transboundary Movement) Rules-200S, framed under the Environmental(Protection) Act-1986.

And whereas Board has received CC& A application dated 27/3/2014 for the Consolidated Consent andAuthorization (CC & A) ofthis Board under the provisions / rules of the aforesaid Acts. Consents & Authorization archereby granted as under:

CONSENTS AND AUTHORISATION:(Under the provisions /rules of the aforesaid environmental acts)

. ;~~~~. AARTlINDUSTRIES LTD (AMINE DIV),

Plot No. 285, 286, PHASE-III,GIDC Estate, Vapi- 396195,Dist.Valsad.

no in ustnal ulant for manufacture a the onowln!:>: itemsl roducts:Sr.No. Product Quantity MT/Month1. 4-Nitro Aniline (PNA) 502. 2-Nitro Aniline (ONA) 2703. 2-Chloro 4-Nitro Aniline OCPNA) 204. Para Chloro Ortho Nitro Aniline (PCONA) 755. Oi Chiaro Ortho Nitro Aniline 1306. 6 Chloro Ortho -i,:TitroAniline 10Total 555By Product

1. CaC!' Solution 767

I. Consent Order No.: AWH-62543, Date of issue: 29/5/2014.2 rhe consents shall be valid up to 26/312019 for use of outlet for the discharge of trade effluent & emission due to

operatio f d . ft<·

3 CONDITIONS UNDER THE WATER ACT:3_1 The quantity of trade effluent from the industry shall not exceed 50 KL/day.32(a) The quantity of Sewage emuent from the industry shall not exceed 2 KL/day.3.2(b) The NH3 containing waste water stream (ML) shall be treated by ammonia recovery system prior to goes to ETP3.3 TRADE EFFLUENT3.3.1 The effluent from the industrial unit shall conform to the CETP inlet norms mentioned in column NO.1 below (in

case ofCETP member). The final discharge from CETP shall adhere to the prescribed standards for CETP.3.3.2 In the event, if the effluent from industrial unit not routed through eETP, the applicant shall provide adequate

effluent treatment system in order to achieve the quality orthe treated effluent as per GPCB norms mentioned incolumn No 3

IS

PARAMETERS CETP INLET NORMS GPCBNORMSpH 6.5 T08.5 6.5 T08.5Temoerature 40 C 40 CColor (pt.co scale) in umts -- lOa unitsSuspended Solids 300 mg/! 10Om!:>:/1Oil and Grease lOm.e.l1 10mg/1Phenolic Compounds 1m'] 1 m~/1Cyanides 0.2ml!!1 0.2ml!!1Fillilddes 2m!!/1 2m ItS 2m 1Ammonical Nitrogen 50ml!;/1 50m'l

J!eD;\\9llaw, .•.ro'<l1l 15< SO- :-14UOT=LU040llifiWll lea raamsa 1000 m IICOD 1000 ml!!1 250m IIChlorides 600m!!/1 600 m II

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The flue gas emission through stack shall conform to the followin" standards:Stack Stack Stack Air Pollution Parameter Permissible

no. attached to height in Control System LimitMeter

I. Steam Boiler 33 Bag Filter & Particulate matter 150mgINM(L3TPH) Multi Cyclone, S02 100 ppm

Dust Collector NO., 50 ppm2. DG sets (1 no, L1 ---

1000 KYA&I no, 65 KVA)

Sulphates 1000 m /1 1000 m /1Total dissolved Solids 2100 m /1 2100 m IBio-assay test 90% Survival of fish after 96

hour in 100% effluent.All efforts shall be made to remove color & unpleasant odor as far as practicable.

3.3.3 The final treated effluent confirming to the above standards shall be discharged into GlDC underground drainagesystem & shall ultimately be conveyed Into tidal zone of river Damanganga through CETP.

3.3.4 Domestic effluent shall be disposed off through septic tank/soak pit system or it shall be treated along withindustrial effluent or it shall be treated separately to conform to the following standards and shall discharge intoGIDC under ground drainage system.

BOD (5 days at 20» C) Less than 20 mg/ISuspended solids less than ;SO mg/IResidual Chlorine Minimum 0.5 mg/I

4 CONDITIONS UNDER THE AIR ACT:4.1 rhe following shall be used as fuel in boiler & DG Set res ectivel .

Sr.No. Fuel uantit1. Coal I.5MT/Hr

Diesel 120 Lit/Hr4.2 The applicant shall instal! & operate air pollution control system in order to achieve norms prescribed below:4.3

4.4 There shall be no any process emISSIon.4.5 The concentration of the following Sllbstances in the ambient air within the premises of the industry and at a

distance of 10 meters from the source (other than the stack / vent with height of more than 9 meters from theground level) shall nor exceed the follov.'ing levels:

PARAMETER PERMISSIBLE LIMITOxides of Sulphar· 080 Micro' am Per cubic meterOxides of Nitro 'en 080 Micro!!ram Per cubic meterPMIO 100 Microgram Per cubic meterPMos 60 Micro"ram Per cubic meter

4.6 The applicant shall provide portholes, ladder. platform etc at chimney(s) for monitoring the air emissions and thesame shall be open for inspection to/and for use of Board's staff. The chlmney(s) vents attached to varioussources of emission shall be designed by numbers such as S-I, S-2, etc. and these shall be painted'! displayed tofacilitate identification.

4.7 The industry shall take adequate measures for control of noise levels from its own sources within the premises soas to maintain ambient air quality standards In respect of noise to less than 75 dB (a) during day time and70 dB(A) during night time. Daytime IS reckoned In between 6 a.m. and 10 p.m. and nighttime is reckoned between 10p.m. and 6 a.m.

5 GENERAL CONDITIONS: -5.1. Any change in personnel, equipment or working conditions as mentioned in the consents form/order should

immediately be intimated to this Board.5.2 Applicant shall also comply with the general conditions given in annexure r

6. AUTHORISA nON FOR THE MANAGEMENT & HANDLING OF HAZARDOUS WASTES Form-2 (5(4))

6.1 Number of authorization: AWH-62543, Date of issue: 29/512014

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rs;::- " ! . Quantity [SChedtile-IWaste FacilityNo : Process No.1 ETPWaste 110 34.3 Collection. storage, transportation,

MT/Month disposal at TSDF-VWEMCL-Vapi.2 Used Oil 50 Lit/Yr 5,1 Collection, Storage, Transportation,

Disposal by selling to registeredrenrocessors.

3 Discarded What so 33.3 Collection, Storage. Decontamination.Container/Bags ever Disposal by sold to authorize recyclers.

generated4 Process waste 10 26.1 Collection. storage, transportation.

containing MT/Month I disposal at TSDF-VWEMCL-Vapi.orcranics com lex

GUJARAT POLLUTION CONTROL BOARDPARYAVARANBHAVAN

Sector 10-A, Gandhinagar 382 010Phone (079) 23226295Fax (079) 23232156Website wwwgpcbgov,in

Mis. AARTI INDUSTRIES LTD (AMINE DIY) is hereby granted an authorization to operate facility forfollowing hazardous wastes on the premises situated at Plot No. 285, 286, PHASE-In, GTDC Estate, Vapi-396 195 Dist Valsad

6.2 J'hc authonzatlOn IS granted 10 operate a faC11Lty for collectIOn, storage wlthm factor)' premises transportationand ultimate disposal of Hazardous wastes at TSDF developed by the Vapi Waste & Effluent Management CoLtd·-Vapi.

6.3 The authorization shall be valid up to 26/3/20196.4 The authorization is subject to the conditions stated below and such other conditions as may be specified in the

rules from time to time under the Environment (Protection) Act-1986.6.5 TERMS AND CONDITIONS OF AUTHORISATION

a) The applicant shall comply with the provisions of the Environment (Protection) Act -- 1986 and the rules madethereunder.

b) The authorization shall be produced for inspection at the request of an officer authorized by the Gujarat PollulionControl Board.

c) The persons authorized shall not rent, lend, sell, and transfer of otherwise transport the hazardous wastes withoutobtaining prior pennission ofthe Gujarat Pollution Control Board.

d) Any unauthorized change in personnel, equipment or working conditions as mentioned in the authorization orderby the persons authorized shall conslitllte a breach of this authorization

e) It is the duty of the authorized person to take prior permission of the Gujarat Pollution Control Board to closedown the facility.

f) An application for the renewal of an authorization shall be made as laid down in rule 7.6.6 In addition to above terms and conditions Industry shall also comply following directives issued by the Supreme

Court of India dated.14.JO,20OJ.a) Industry shall have to the relevant information with regard to hazardous waste as indicated in the

Court's order in W.P. 1410 October 2003b) Industry shall have to display' on-line data outside the main factory gate with regard to quantity and naUlre

of hazardous chemicals being, handled in the plant, induding wastewater and air emissions and solidhazardous wastes generated within the factory premises.

For and on behalf ofGujarat Pollution Control Board

(Smt. D. P. Shah)Environmental Engineer

3Ijo'Tl..toll,NO, GPCB/CCA-VSD-483nD, 229881 ~.II.<> 43,3Jssued to:Mis. AARTTINDUSTRIES LTD (AMINI!: DIV),Plot No. 285, 286, PHASE-IJI,

GIDCE,tato,)'\lOlJJ>lIU'lS. G' t G Gu' tD',tVal"d, \,;'LeUn uJara reen ':lara1••••••IS.O••-.90.0.1.-.2.0.0.8.&.IS.O.-.14.0.0.1.-.2.0.0.4.c.e.rt.if.ie.d.o.r

g

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