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AnyAddy®
S A M S U N G F I N E C H E M I C A L S
is a brand name of
Methylcellulose/Hydroxypropylmethylcellulose
AnyAddy®
Technical Brochure
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
Applications
AnyAddy (Methylcellulose, Hydroxypropylmethylcellulose) Batter/coating, beverage, bakery, sauce, marinade,
meat/fish preparation, phosphate or egg replacement etc.
Reference FCC, JECFA, USP, EP, JP, KP, etc.
More Information Homepage [http://anycoat.samsung-cellulose.com]
AnyAddy, environment-friendly, uses cellulose
as primary source, which can be obtained from wood
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy ® is
AnyAddy® , a non-ionic water soluble cellulose ether, is a brand name of Samsung Fine Chemicals for HPMC (Hydroxypropylmethylcellulose) and MC (Methylcellulose)
products targeted for the food and dietary supplement applications. AnyAddy® products are derived from natural wood pulp, meeting all the requirements of the current USP, EP and JP ‘Hypromellose’ along with Kosher and Halal certifications. AnyAddy® , in compliance with FDA, EU and FAO/WHO guidelines, is produced in a GMP manufacturing facility, retaining FSSC22000(GFSI) and ISO9001 certifications as well.
AnyAddy® functional benefits in Food and Dietary Supplements: • Film Coating • Thickener • Suspension Aid • Taste Masking • Stabilizer • Emulsifier • Mouthfeel Enhancement • Moisture Retention
AnyAddy® comes in a wide variety of viscosity ranges from 3 to 100,000 cps (2% solution).
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Certificates of AnyAddy ®
Other Certificates and Statements of AnyAddy ®
- TSE/BSE certification - Non-GMO certification - Allergen statement
- Residual pesticide statement - Residual solvent statement
- Gluten-free statement
Certificate Agency Remarks
FSSC 22000:2011 Certificate
SAI global Annual inspection
ISO 9001:2000 Certificate
KSA (Korean Standards
Association) Annual inspection
OHSAS 18001:2007 Certificate
CERMET Annual inspection
KOSHA 18001 Certificate
KOSHA Annual inspection
Kosher Certificate Orthodox Union Annual inspection
Halal Certificate KMF Annual inspection
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
General Characteristics
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Product List
AnyAddy®
Viscosity (cps)
HPMC(Hydroxypropylmethylcellulose) MC (Methylcellulose)
A type(2910) B type(2906) C type(2208)
3 AN3
4 BN4
5 AN5
6 AN6
15 AN15 MC15
50 AN50 BN50
100 CN10M
400 MC40M
450 BN45M
1500 MC15H
4000 AN40H BN40H CN40H MC40H
15000 CN15U
100000 CN10T
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Grade Nomenclature of AnyAddy
Substitution type:
Normal grade
Viscosity:
AN6
CN10T
BN4
A) HPMC 2910, B) HPMC 2906, C) HPMC 2208
M) ×10, H) ×100, U) ×1,000, T) ×10,000
AnyAddy®
Chemistry of AnyAddy
Product grade AN BN CN
Substitution type 2910 2906 2208
Methoxyl
content 28.0 ~ 30.0% 27.0 ~ 30.0% 19.0 ~ 24.0%
Hydroxypropoxyl
content 7.0 ~ 12.0% 4.0 ~ 7.5% 4.0 ~ 12.0%
Gel point 60ºC 65ºC 90ºC
General
properties
Readily soluble
in mixed organic
or aqueous solvent
Good plasticity
Excellent film
formation
High emulsion
stability
Excellent gel
formation
High thermo-
gelation
temperature
High water holing
capacity
The gel point can be different depending on the measuring conditions.
(For more, refer to Rheology on page 20, 21)
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Stability and Conditions
AnyAddy is a stable non-ionic material in the face of wide range of pH from 3 to 11, the repetitive exposure to moisture, and high
temperature at less than 280 ℃. Dissolved into an aqueous solutions, the various viscosity is developed depending on the molecular weight and concentration. The solution based on substitution type goes through a temperature-dependent sol-gel transformation. The aqueous solution is enzyme-resistant, and the viscosity of solutions remains unchanged under the normal chemical reaction. However, the viscosity can be affected under the extreme pH conditions.
AnyAddy should be stored in a well-closed container, in a dry and cool place.
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Incompatibilities
Safety
AnyAddy is compatible with food ingredients due to its non-ionic and pH independent property, except highly concentrated salt or sugar solutions.
AnyAddy is widely used for food industry. Also, AnyAddy is listed as GRAS (Generally Recognized As Safe) by FDA with no specific usage defined. Since the backbone structure of AnyAddy is
similar to the dietary fiber, approx. 95% of AnyAddy is excreted without it being absorbed into the body. - LD50(mouse, IP) : 5g/kg, LD50(rat, IP) : 5.2g/kg
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy Powder
Methylation content analysis by FT-IR Spectrum
FT-IR can be applied to assess the degree of methylation in AnyAddy. In FT-IR spectra, the most intense peak appeared at 1053 cm−1, denoting the presence of the glucose ring. The ratio of peak intensities at 1452 cm−1, which represents C H absorptions, and at 1053 cm−1 (I1452/I1053) and percent methylation. And the
normalized peak intensities at 2835 cm−1 is associated with the methyl contents. The pattern of normalized peak intensities follows the order of percent methylation.
※ Reference: Haanah. “Hydroxypropyl methylcellulose substituent analysis and theological
properties”. Carbohydrate polymers 98 (2013) 276-281
FT-IR spectra of AnyAddy
Diamond crystal ATR and a DTGS detector
Powdered samples collected at 25℃ using 64 scans
NIcolet 6700 FT-IR Spectrometer
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy Powder
Moisture Absorption Rate in Relation to Relative Humidity
Moisture absorption rate is the time taken for the moisture content of powder to reach its equilibrium under specifically set relative humidity. The figure below is used as an indicator to predict the moisture content of AnyAddy stored for long.
Am
ou
nt
of m
ois
ture
ab
sorp
tio
n(%
)
Storage time(day)
Am
ou
nt
of m
ois
ture
ab
sorp
tio
n(%
)
Storage time(day)
Moisture Absorption Rate of 2906
type, 4000cps 25℃, Loss on drying
Moisture Absorption Rate of 2208
type, 4000cps 25℃, Loss on drying
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy Powder
Thermal Analysis of AnyAddy
Thermal decomposition temperature
TGA (Thermo Gravimetric Analysis) below shows the thermal decomposition under high temperature. The
thermal decomposition is seen around 280℃.
TGA of AnyAddy Inlet gas : air
We
igh
t(%
)
Temperature(℃)
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Dissolution Methods of AnyAddy ®
AnyAddy®
General info. for AnyAddy® to dissolve
In general, AnyAddy® is a highly hydrophilic polymer, especially much more hydrophilic in cold water than in hot
water. More precisely, in hot water, it is dispersed rather than dissolved. Thus to dissolve AnyAddy® adequately without lumping , using hot water is preferred.
Dispersion in hot water ⅰ. Prepare hot water above 80 ℃ and start agitating ⅱ. Add the AnyAddy into the hot water with agitation. ⅲ. Agitate the mixture until the particles are thoroughly wetted and evenly dispersed ⅳ. Cool the temperature to 20 ℃ ⅴ. The solution is transparent or slightly yellowish.
Dissolution in cold water (preferred for low viscosity AnyAddy®)
- The method is very similar to ‘Dispersion in hot water’. But, to avoid lumping the small amount of the powder has to be added evenly.
Dispersion by Dry-Blending
ⅰ. Premix AnyAddy® powder with other dry-powder ingredients thoroughly. The ratio of other dry-powder ingredients to AnyAddy® may vary from 7:1 to 4:1.
ⅱ. Add the dry mix to the water with agitation. ⅲ. Agitate until the AnyAddy® powder completely hydrates Dispersion in Oil, Syrup etc.
ⅰ. AnyAddy® can be dispersed in non-aqueous media such as vegetable oil, polypropylene glycol, corn syrup, high-fructose corn syrup, and fruit concentrate.
ⅱ. Add the AnyAddy® to the non-aqueous media. A ratio of 5 to 8 parts non-aqueous media to 1 part AnyAddy® Is recommended.
ⅲ. Agitate the mixture and AnyAddy® powder until evenly dispersed. ⅳ. Add cold water to the dispersion. ⅴ. Continue mixing until the AnyAddy® powder is completely hydrated.
⊙ methods ⊙
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy ® Solution
Concentration & Viscosity Relationship
The concentration and viscosity are interrelated, and can be predicted using the following equation.
η=(1+KC)8
η : viscosity(cps)
K : constant for each
individual polymer
C : concentration(%)
Concentration/Viscosity
Relationship 600cps under : Ubbelohde viscometer,
600cps over : Brookfield viscometer, 20℃
Vis
co
sity
(cp
s)
Concentration(wt%)
Vis
co
sity
(cp
s)
Concentration(wt%)
Concentration/Viscosity
Relationship 600cps under : Ubbelohde viscometer,
600cps over : Brookfield viscometer, 20℃
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy ® Solution
Viscosity Development as a Function of Stirring Speed
AnyAddy® is dispersed in hot water, and dissolved in cold water. When put first into cold water, lump can be formed, making it difficult to dissolve. Therefore, dispersing it into the hot water renders the dissolution easier. The faster stirring speed of impeller shortens the time of viscosity
development. To avoid air entrainment, however, proper stirring intensity should be set.
Viscosity Development of AnyAddy
as a Function of Stirring Speed AN6(8.65wt%), 30℃, Brookfield Viscometer
(LV1, 20rpm), 500g solution
Vis
co
sity
(cp
s)
Time(min)
Viscosity Development of AnyAddy
as a Function of Stirring Speed AN15(5.09wt%), 30℃, Brookfield Viscometer
(LV1, 20rpm), 500g solution
Vis
co
sity
(cp
s)
Time(min)
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy Solution
Shear Rate & Viscosity Relationship
An aqueous solution of AnyAddy displays a non-Newtonian fluid property in which its viscosity can decrease with an increasing shear rate. However, if the shear rate of AnyAddy with low concentration is more than 1/s, no change in viscosity is shown.
Shear Rate/Viscosity Relationship 20℃, Cup-cone type Rheometer
Vis
co
sity
(cp
s)
Shear rate(1/s)
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy ® Solution
Viscoelasticity in Aqueous solution
For temperature below the gelation temp., the G’ and G’’ of AnyAddy ® (HPMC and MC) have the same pattern: as temp. increases, they decline. However, above the gelation temp., HPMC have a different pattern from MC: as temp. increases, while G’’ of HPMC decreases, both MC’s G’ and G’’
increase. And also G’ and G’’ of MC are higher than those of HPMC. It means that MC’s gel is firmer than HPMC. More detailed explanation is described on the next slide. Additionally, the gelation temperature varies based on the degree of substitution. The order of increasing gelation temp. is as follows : MC < HPMC(BN) < HPMC(CN). ※ G’’ : Loss(viscous) modulus / G’ : Storage(elastic) modulus
AnyAddy®
Viscoelastic behavior by temp. change MC & HPMCs 2% solution
Parallel plate type Rheometer
<Picture of Thermal Gel>
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Properties of AnyAddy ® gel
Hydroxypropoxyl substituent & Gel firmness Relationship
In a Raman spectrum, polymers containing more amorphous regions possess broader peaks, while polymers with more crystalline regions contain narrower peaks. And, according to Young & Lovell, larger proportions of crystalline regions are associated with increased mechanical strength. In case of AnyAddy, BN40M has the narrowest spectrum, while AN6 dose the widest spectrum. The order of increasing broadening is as follows : BN40M<AN50<CN40H<CN10T<AN6. This order is closely related to the % HPO. In brief, the higher the % of HPO, the lower the crystallinity of AnyAddy, which
may relate to the strength of the gel, and thus, in this case, BN40M has the highest gel firmness.
Broadening chart of the Raman spectrum
between 1660㎝-1 and 1540㎝-1
4g powder AnyAddy in 5 mL glass scintillation vial
300mW with a spectral region of 2250㎝-1 to 250㎝-1
Sentinel Sure-Cal Spectroscopy
AnyAddy®
AnyAddy % MO %HPO
AN6 28.9 9.4
AN50 28.8 8.6
BN45M 28.5 6.4
CN40H 22.9 8.7
CN10T 23.6 8.8
※ Reference: Haanah. “Hydroxypropyl methylcellulose substituent analysis and theological
properties”. Carbohydrate polymers 98 (2013) 276-281
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
General Properties & Applications
AnyAddy®
Properties Effects Application
Water solubility AnyAddy is dissolved in water.
In detail, soluble in cold water, dispersed in hot water. -
No ionic charge
AnyAddy is nonionic and does not react with metallic salt
s to make insoluble precipitates.
However, precipitation might occur, if too much sugar or salt is
added,.
-
Thermal gelation
Unlike other gums or hydrocolloids, AnyAddy gels at a cer
tain high temperature. The gel is thermally reversible and t
here is no viscosity change after sol-gel transformation.
Frying batter, topping (bo
il-out control), confectio
nery (pancake)
Moisture control
AnyAddy retains moisture in food system and reabsorb m
oisture when food cools after heating, and prevents growi
ng ice crystals. Additionally, AnyAddy inhibits starch retro
gradation.
Confectionery (brownie,
cake etc.), frozen food (r
aw vegetable or fish, dou
gh etc.), meat product, y
ogurt (syneresis control),
gluten free product
Surface activity
(Emulsification&
Foam stability)
AnyAddy acts as surfactants in liquid solutions to provide
emulsification, protective colloid action, and phase stabili
zation by reducing interfacial tension and oil droplet coale
scence.
※ Emulsification : oil-in-water or water-in-oil system
※ Foam stability : air-in-water system
Savory (mayo., dressings
, sauces, whipping crea
m etc.), confectionery (m
eringue, pancake),
string cheese
pH stable AnyAddy is stable over a pH range of 2.0 to 13.0. Yogurts, beverages
Thickening/
Suspending
AnyAddy imparts viscosity to liquid and semi-solid system
and the viscosity stabilizes suspensions, emulsion and sol
id particles in water-based food system with high transpa
rency
Fruit juices, soups, jams
(partial pectin replaceme
nt)
Film formation AnyAddy forms flexible clear & flexible films. This film is
used to retain moisture and reduce oil-uptake.
Dietary supplement tablet
, gum or chocolate, fryin
g batter, glazing (egg whi
te replacement), brines,
bread&confectionery,
edible film
Binding AnyAddy acts as binders for structured or extruded foods
and dietary supplement tablets, etc.
Structured or extruded fo
ods (noodle, hash brown
, chips, croquette etc.),
dietary supplement tablet
, vegetarian sausage,
meat product, gluten-fre
e product
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® Eggless&Low Oil Vegan Mayonnaise
Why AnyAddy® in Mayonnaise?
- Replacing Oil and Egg to stabilize O/W emulsion : AnyAddy can act as a emulsifier and stabilize emulsions in its
solution
- Provide thickness to the solution : AnyAddy provides thickening property of its solution and Improves adhesion degree of formulations
- Prevent oil separation in High/Low temperature : Combining with ISP, the product has thermal/freezing stability, and the phase-stability can be improved.
Want to be slender while maintaining your menu?
This is the solution you are looking for.
With obesity being a major global concern, many food companies are working to
put healthier options on people’s dining tables.
Are you looking for ways to reduce the your diet calories?
Do you know mayonnaise is one of the high oil/calorie foods you have to avoid?
If you say so, All you need is Samsung fine Chemical’s Food ingredient
AnyAddy ® Oil and Egg replacer.
How to apply AnyAddy® in Mayonnaise?
Blend Isolated Soy Protein with
AnyAddy
Add dry mixtures to tap water
and mix for 10 minutes.
While homogenizing, add soybean oil little gradually for 5 minutes.
Add vinegar, salt and sugar and mix for 3 minutes..
Add AnyAddy to hot water(above
90℃) and disperse for 1.5h while cooling
Thermally Stable type Dressing type
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy Applied Vegan Mayoannaise
50% reduced Eggless
47% reduced
(%) (%) (kcal/100g)
- Nutrition Anaylsis
Control Vegan Mayo
75℃ 60min Heating
- Thermal Stability Test
After freeze-thawing, control’s phase is totally separated.
- Freeze-thaw Stability Test
Vegan Mayo Control
Ingredients Control AnyAddy
Soybean Oil 80.0 40.0
Egg york 5.0 0.0
Egg white 9.0 0.0
Vinegar 3.0 3.0
Salt 1.0 1.0
Sugar 2.0 2.0
Water 0.0 51.3
AnyAddy 0.0 2.7
Ingredients Control AnyAddy
Soybean Oil 80.0 40.0
Egg york 5.0 0.0
Egg white 9.0 0.0
ISP* 0.0 8.0
Vinegar 3.0 7.0
Salt 1.0 1.0
Sugar 2.0 2.0
Water 0.0 41.0
AnyAddy 0.0 1.0
- Formulas (Dressing type) (Thermally stable type)
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® for Yoghurt
Why AnyAddy® in Yoghurt?
- Very stable in Low pH : AnyAddy is stable in wide range of solution pH(3 to 11). It can act
as a effective emulsifier and stabilizer in yoghurt base.
- Improves the mouthfeel : AnyAddy is tasteless comparing other hydrocolloid using in yoghurt and the viscosity provided by AnyAddy can improve mouthfeel. It can also improving the taste by lowering the sourness.
- Prevent Whey-off (Syneresis) : AnyAddy can stabilize the milk protein by coating it, and prevent milk protein’s precipitation within shelf life.
How to prevent whey-off/save your cost at the same time?
This is the solution you are looking for.
AnyAddy is an effective emulsifier and thickener. A little dosage is enough to
prevent whey-off and improve the taste. AnyAddy’s β-1,4- bonds are resistant to
acid/microorganism comparing to starches or other hydrocolloids, so the viscosity
is consistent through their shelf-life.
If you are interested,, please contact us.
AnyAddy ® Yoghurt stabilizer.
How to apply AnyAddy® in Yoghurt?
Disperse a blend of AnyAddy and Fruit concentrate or sugar
into 90℃ water using a high speed mixer. Mix until AnyAddy is dissolved
Mix yoghurt base and AnyAddy solution until it is homogenous
Add flavor, rest of sugar, etc
Homogenize
at 150-200bar
Cool to eg 10-15℃
Fill
Store at 5℃
Cool to eg 10-15℃
Fill
Store at 5℃
Drinking yoghurt Stirred yoghurt
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy Applied Yoghurt
- Formulas (Drinking type) (Stirred type)
AnyAddy (High viscosity type)
Yoghurt 11.5% MSNF
Sugar
Fruit concentrate
Flavour and/or colour
Water
0.15% / 0.2%
75% (8.6% MSNF)
40% (4.6% MSNF)
6%
3.5%
To taste
To 100%
Ingredients Contents(%)
AnyAddy (High viscosity type)
Yoghurt 11.5% MSNF
Sugar
Fruit concentrate
Flavour and/or colour
Water
0.2%
80% (9.2% MSNF)
6%
3.5%
To taste
To 100%
Ingredients Contents(%)
0
5
10
15
0
20
40
60
0.00 0.05 0.10 0.15 0.20 0.25 0.30
Whey
Off
(%)
mPas
% AnyAddy
Viscosity (Before Homo) Viscosity (After Homo)
Whey Off (%, Before Homo) Whey Off (%, After Homo)
Yoghurt, 4.6% MSNF
- Viscosity, whey-off (Drinking type yoghurt)
0
5
10
15
0
50
100
150
0.00 0.15 0.20 0.25 0.30
Whey
off
(%)
mPas
% AnyAddy
Viscosity Whey Off
(Stirred type yoghurt)
Healthy functional additives
pro-biotic drinks
Lower sourness beverage type drinks
milk/juice drinks
Creamy mouthfeel/higher viscosity
“smoothie” type drinks
Lower MSNF/Starch etc
cost saving
thin mouthfeel
reduce calories
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® for Beverage/Juice
Why AnyAddy® in Beverage/Juice?
- Very stable in Low pH : Anyaddy ® is stable in wide range of solution pH(3 to 11). It can act
as a effective emulsifier and stabilizer in yoghurt base.
- Masking off-taste : AnyAddy ® can form random-coil structure in aqueous solution and taste/flavor perceptions is selectively reduced.
- Act as thickener/emulsifier : AnyAddy ® can retard the solid’s precipitation and stabilize emulsions in its solution.
Want to overcome sweetener’s aftertaste?
This is the solution you are looking for.
AnyAddy can mask various sweetener’s aftertaste and make up their lack of body
viscosity . AnyAddy’s β-1,4- bonds are resistant to
acid/microorganism comparing to starches or other hydrocolloids, so the viscosity
is consistent through their shelf-life.
If you are interested,, please contact us.
AnyAddy ® for low calorie beverage/Juice.
How to apply AnyAddy® in Beverage/Juice?
Beverage Juice
Disperse AnyAddy/sweetener
into 90℃ water using a high speed mixer.
Cool until AnyAddy is dissolved.
Mix water/flavour and AnyAddy solution until it is
homogenous
Sterilize/Pasteurize the solution and cool.
Mix AnyAddy and powder ingredients
/fruit concentrate/puree and dissolve
Into 40-50℃ water using a high speed
mixer.
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy Applied Zero-Calorie beverage
Taste Intensity
(5(Very strong) ~ 1(very weak))
0
0.5
1
1.5
2
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8
log(s
pec
ific
vis
cosi
ty)
log(c[η])
y=0.2442x + 0.1182
R2=0.9993
y=1.8982x - 1.4145
R2=0.9858
line intersect at x=0.926
i.e. log(c*[η])=0.926
Where [η]=2.2l/g
And c* = 3.84g/l(0.384% w/w)
Determination of c* concentration for AnyAddy(Low viscosity grade)
54% masked
Body viscosity improved
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® Reduced Oil uptake Fried foods
Why AnyAddy® in Fried foods?
- Reduction oil uptake in Fried foods : The unique thermogelation properties of AnyAddy can form a barrier film around substrate, preventing oil uptake
- Maintaining a batter shape in the way of gelation : Delivering viscosity to batter, forming a film which adds strength, and reduces the break-up of batter product
- Improving texture and fried foods quality : Strengthen gravy and tenderness, Post Maintaining crispness for hours
- Keep batter crisp while holding time : Adding AnyAddy into batter mix prevents fried foods becoming soggy texture
Can you imagine a Hamburger without French fries?
With obesity being a major global concern, many food companies are working to
put healthier options on people’s dining tables.
Are you looking for ways to reduce the oil uptake of your favorite fried food
product?
Do you want to grab some french fries without being obesity concerned?
If you say so, All you need is Samsung fine Chemical’s Food ingredient
AnyAddy ® Reduced Oil uptake Food hydrocolloid.
How to use AnyAddy® in Fried foods? - Add AnyAddy® powder into the flour and then make a batter
With AnyAddy , you can formulate French fries, Chicken nuggets, and a variety of fried
products that not only have lower oil uptake and, but look appealing and quality great.
Sample Batter / AnyAddy (%) Powder : Water (g)
French Fries 99.7 / .3 340 : 660
Sweet potato fries 99.7 / .3 400 : 600
Chicken nugget 99.7 / .3 460 : 540
Fish Stick 99.7 / .2 430 : 570
Substrate
Batter w/ AnyAddy®
Fat
Substrate
Batter w/o AnyAddy®
Fat
Moisture Oil AnyAddy
AnyAddy® How to work in Batter?
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy to Reduce oil uptake
Achieves 48% Oil uptake reduction compared to Product in market 16% oil uptake reduction compared to Control
Products Quality
Improvement in texture quality Retaining moisture Increase in Crispiness Preventing fried foods from becoming soggy texture after frying
AnyAddy to Improve Fried foods Quality!
With AnyAddy Control (sweet potato)
Oil uptake(%) in French Fries
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy to Reduce oil uptake
Chicken Nugget
Fish Stick
Products Quality
Retaining moisture Increase Crispiness Improve texture quality Prevent crystallization
AnyAddy to Improve Fried foods Quality!
With AnyAddy Control
Oil uptake(%) in Tempura batter Product
Oil absorption Moisture Content
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy to Improve Fried foods Quality!
Control AnyAddy®
Control AnyAddy®
Cheese Stick Prevent crystallization Reduce break-up Replace egg-white Improve texture
Hot dogs Leavening enhancer Maintain shape after frying Improve texture
AnyAddy in Fried food Applications
※ The recommendation table above entails a general recommendation, and the recommendation can be tailor-made in
accordance with customers’ specific formulation.
Application Characteristics needed Grades Using
amount
French fries Reducing oil uptake CN 0.1~0.5%
Sweet potato fries
Improving texture quality,
Retaining moisture, CN 0.3~0.5%
Potato chips Reducing oil uptake AN
CN
1.0~2.0%
0.5~2.0%
Chicken Nugget Reducing oil uptake,
Improving texture quality
AN
CN
0.3~0.5%
0.1~0.3%
Fish Stick Reducing oil uptake,
Increase moisture retention CN 0.1~0.5%
Hot dogs Improving texture quality,
Leavening enhancer CN 0.1~0.5%
Cheese Stick Reducing break-up CN 0.1~0.5%
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® The Ideal Hydrocolloid For Bakery
Why AnyAddy® in Bakery products?
From bread to cakes, AnyAddy® is helping cook up
healthier, better tasting!
AnyAddy® has a high water absorption and retention capacity.
Water is retained in the bakery products. And it forms a film around
the starch granule and delays the retrogradation of the amylose by
disturbing crystallization.
AnyAddy® is of vegetable origin(wood). Purely vegetarian products
are possible when AnyAddy® is simultaneously used as substitute
for animal protein and fat.
Affordable high quality bakery products can now be achieved usign AnyAddy®
Thermal gelation
- Keeps the shape of product
- Prevents boil-out
- Topping and Filling for bakery products
Film forming properties
- Replacement of Egg and/or Fat
- Reduces baking powder
- Contributes to the overrun
- Whipping cream, Meringue, Ice cream
Build a structural network
- High water binding capacity
- Prevents cracking
- Delay the retrogradiation amylose
- Free of gluten
Excellent freeze-thaw stability
- Crystallization control
- Frozen bakery products
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
※ The recommendation table above entails a general recommendation, and the recommendation
can be tailor-made in accordance with customers’ specific formulation.
AnyAddy in Bakery products Applications
Applications AnyAddy® Concentration
(Baker’s %) Effect
Cake - general BN type 0.6 % - Maintains moisture - Extends shelf life - Prevents cracking
Egg free bakery BN type 0.5 - 1.0 % - Replacement of egg
Low fat bakery BN type 0.5 – 1.0% - Reduces fat
Pancake CN type 1.9% - Reduction of baking powder - Increases volume
Gluten free products
AN /BN/CN type
1.0 % - Keeps the shape of products
Low fat whipping cream
BN type 0.5 – 2.0 % - Reduces fat - Contributes to the overrun
Egg free meringue BN type 0.5 – 2.0 % - Replacement of egg
Topping and filling CN type 0.7 – 2.1 % - Prevents boil-out
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients True % Baker’s %
Control AnyAddy® Control AnyAddy®
Wheat flour 30.9 30.8 100.0 100.0
Butter 7.7 7.7 25.0 25.0
Sugar 24.7 24.7 80.0 80.0
Baking powder
1.5 1.5 5.0 5.0
Whole egg 15.4 - 50.0 -
AnyAddy® - 0.2 - 0.5
Water 19.8 35.1 64.0 114.0
Total 100.0 100.0 324.0 324.5
General formula
Methods
Benefits
AnyAddy® Egg Free Muffin
1. Creaming of butter, sugar and AnyAddy® 1% solution
2. Mixing flour, baking powder and water
3. Panning & Baking
- Egg free bakery products for people who being diagnosed with egg sensitivity
- Provides moist texture
- Delay the retrogradiation amylose
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients True % Baker’s %
Control AnyAddy® Control AnyAddy®
Wheat flour 17.7 18.5 100.0 100.0
Butter 8.9 4.6 50.0 25.0
AnyAddy® - 0.2 - 1.0
Whole egg 21.3 22.2 120.0 120.0
Sugar 23.0 24.0 130.0 130.0
Salt 0.4 0.4 2.0 2.0
Chocolate 26.6 27.8 150.0 150.0
Cocoa powder 1.7 1.9 10.0 10.0
Vanilla 0.4 0.4 2.0 2.0
Total 100.0 100.0 564.0 540.0
AnyAddy®
AnyAddy® Low fat brownie
General formula
Methods
Benefits
1. Mixing melted butter, melted chocolate, egg, sugar and salt
2. Mixing flour, AnyAddy® , cocoa powder and vanilla
3. Panning & Baking
1. Low calories brownie (Reduces fat)
2. Keep the shape of products
3. Provides moist texture
4. Delay the retrogradiation amylose
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients True % Baker’s %
Control AnyAddy® Control AnyAddy®
Wheat flour 27.0 26.9 100.0 100.0
Milk 43.2 43.0 160.3 160.3
Whole egg 20.8 20.6 76.9 76.9
Sugar 7.4 7.4 27.6 27.6
Salt 0.3 0.3 1.3 1.3
Baking powder 1.2 1.2 4.5 4.5
AnyAddy® - 0.5 - 1.9
Total 100.0 100.0 370.6 372.5
1. Blend milk and egg
2. Add wheat flour, sugar, salt, baking powder and AnyAddy®
3. Mix powdered ingredients to the liquid phase mixture
4. Pour onto a lightly greased and preheated griddle
5. Cook until golden brown on both sides
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
AnyAddy® Pancake
General formula
Methods
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
AnyAddy Control
54.5mm 46mm
21% higher
1. Increase volume
Benefits
AnyAddy® Pancake
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients Control AnyAddy®
Fruits 71.4 70.4
Sugar 28.6 28.2
AnyAddy® - 1.4
Total 100.0 100.0
AnyAddy®
AnyAddy® Topping and Filling
General formula
Methods
1. Blending mixed fruits , sugar and AnyAddy®
2. Cooking
3. Topping of filling at bakery dough
4. Baking
1. Keeps the shape of products
2. Prevents boil-out
Benefits
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
Crust Crumb
Control
Crust Crumb
AnyAddy® + Water 120%
AnyAddy® Confectionery Mix
Ingredients Control AnyAddy®
Muffin mix 66.6 62.0
Water 33.4 37.6
AnyAddy® - 0.4
Total 100.0 100.0
General formula
Methods
Benefits
1. Mix muffin mix, AnyAddy ® to the water
2. Panning & Baking
1. Increase yield without changing crumb structure and crack in the
surface
2. Reduces cost
3. Provides moist texture
4. Retards staling of confectionary products
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
AnyAddy® Egg Replacement
Bread Glazing
Methods
Benefits
1. Glazing bread with AnyAddy ® solution right after baking
2. Allow ten to fifteen minutes until AnyAddy ® solution on the bread is dry
1. Replace egg white(albumen) with non-allergenic AnyAddy ®
2. Reduces cost
3. Easy to keep glazing solution
Control
Egg white AnyAddy ®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients True % Baker’s %
Control AnyAddy® Control AnyAddy®
Wheat flour 52.63 52.55 100.00 100.00
Dough enhancer 1.05 1.05 2.00 2.00
Sugar 2.63 2.63 5.00 5.00
Milk powder 1.58 1.58 3.00 3.00
Salt 1.05 1.05 2.00 2.00
Dry yeast 1.05 1.05 2.00 2.00
Shortening 2.11 2.11 4.00 4.00
Water 37.90 37.90 72.00 72.00
AnyAddy® - 0.08 - 0.15
Total 100.0 100.0 190.00 190.15
General formula
Methods
AnyAddy® White Bread
1. Mix powder ingredients, AnyAddy® and water until dough is smooth and
satiny
2. Add shortening to the dough and knead
3. Let rise in a warm place until doubled in volume, about 30 minutes
4. Form the dough round with a weight of 280g
5. Rest it at room temperature for 10 minutes
6. Shape the dough into white bread and place a baking pan
7. Let rise in a warm place until doubled in volume, about 50 to 60 minutes
8. Bake the loaves at 170℃/190℃ for 35 minutes, or until golden brown
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Benefits
AnyAddy® White Bread
1. Increase volume
2. Reduces cost
3. Soft crumb structure
S A M S U N G F I N E C H E M I C A L S
AnyAddy®
Control AnyAddy®
20% higher oven spring (8% higher finished volume)
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Ingredients True % Baker’s %
Control AnyAddy® Control AnyAddy®
Rice flour 62.9 62.4 100.0 100.0
AnyAddy® - 0.6 - 1.0
Gums - 0.2 - 0.3
Water 34.6 34.3 55.0 55.0
Oil 1.9 1.9 3.0 3.0
Salt 0.6 0.6 1.0 1.0
Total 100.0 100.0 159.0 160.3
AnyAddy®
AnyAddy® Gluten free dumpling skin
General formula
Methods
Benefits
1. Blending of dry ingredients (flour, AnyAddy® , gums , salt)
2. Mixing water and oil
3. Rolling(1mm) and Cutting
4. Steaming
1. Free of gluten for people who being diagnosed with celiac disease
2. Keeps the shape of products
3. High water-binding properties (reduced syneresis)
4. Excellent freeze-thaw stability
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Starch gel properties and syneresis
Addition of AnyAddy
Control AN50 BN40H CN40H CN10T
Properties of AnyAddy® with Corn Starch
Corn starch +
AnyAddy
Delaying starch retrogradation Inhibiting swelling of starch Reduction in syneresis
AN50
CN40H
BN40H
CN10T
Formation of starch gel with AnyAddy
- AnyAddy may inhibit starch granule swelling and gelatinization. - The reason why AnyAddy acts inhibition of starch gel formation is AnyAddy could compete with starch to get water for swelling.
Scanning electron microscopy
Microstructure studies showed that the starch granules appeared wrapped by AnyAddy especially when solution was added.
Starch is a predominant energy source and it is important in food industry. Understanding reaction between starch and AnyAddy is necessary to apply AnyAddy to food processing.
Control
Functional Effects
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® in meat products
Why AnyAddy® in meat products?
- Increase in water retention AnyAddy is attached to myofibrilar proteins,
thereby preventing water loss from meat products
- More elastic on serving temp. The thermal gelation property of AnyAddy makes it
- Inhibition of ice crystal growth Due to the high water affinity of AnyAddy,
the growth of ice crystal is restricted
How dose AnyAddy® work in meat products?
For smart consumer, smart ingredient …
AnyAddy is the easiest way to improve product quality.
It has excellent compatibility with other ingredient.
Especially, if u want juicy and elastic protein products,
AnyAddy ® will be the best choice.
water doesn’t flow freely
water flows freely
AnyAddy
Without
AnyAddy
water
myofibril filament
SEM image
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy to Improve Water Retention!
※ ERR(expressible release ratio)(%) = (Total area – sausage area) / Total area
65%
reduction
ERR(%) of Boiled Pork Sausage
32.00%
23.09%
19.45%
15.00%
20.00%
25.00%
30.00%
35.00%
No gums AnyAddy(0.1%) AnyAddy(0.25%)
Methods
Benefits
1. Mincing pork meat
2. Mixing the minced pork with salt, phosphate, and etc..
3. Aging the meat paste for 24h
4. Blending AnyAddy ® powder with other hydrocolloids or starches
5. Mixing the blended powder with the meat paste by using silent cutter.
6. Casing
7. Boiling
1. Improve water retention → Higher elasticity
2. Easy-peeling
3. Reduce syneresis
※ AnyAddy percentage in the graph is AnyAddy weight out of meat weight.
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® Surimi product application
AnyAddy ® will be an essential element for Surimi product industry.
AnyAddy ® is not only for surimi product producer, but also for customers. It makes
the producers reduce cost & the customer meet better quality product with affordable price .
AnyAddy ® enables :
• Cost cutting • Control to customize texture of product
• Improvement in gel strength • Better digestion
How & When to use …
For better and uniform quality, AnyAddy ® has to be mixed with powdery ingredients.
☆ Suggested amount : 10 % of AnyAddy ® & wheat starch mix.
(The ratio of AnyAddy ® to wheat starch has to be 1 : 9 ~ 4 :6)
Improvement in storage(elastic) modulus (G’) at 80 ℃
wheat starch 10% in SA grade surimi
AnyAddy 3% + wheat starch 7% in KB grade surimi
wheat starch 10% in KB grade surimi
• 30 % higher in G’ than SA grade
• 200 % higher in G’ than KB grade
<Surimi grading standard>
① SA grade : > 700 in gel strength
② KB grade : > 350 in gel strength ※ SA is about 40% more expensive than KB
AnyAddy ® and wheat starch interact with protein structure to a sturdy gel matrix, thereby
improving gel-strength. Additionally, in terms of workability, although G’ of surimi product
with AnyAddy ® is increased as temp. rises, it does not affect the workability since G’ is
decreased as temp. decreases.
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® phosphate replacement
Phosphate-free meat product is not an option – It’s a Requirement.
AnyAddy® phosphate-replacement application categories
• WHC (water holding capacity) enhancer
- it can be added directly into ground meat as powdery type, like other hydrocolloids.
- it can be used as liquid type, like brining solution
• Freezing-thawing stabilizer : prevents discoloration and reduces drip loss during thawing
- it can be used as liquid type, like brining solution
Innovative AnyAddy® phosphate replacement satisfies manufacturing cost cutting as well as
consumer health, while maintaining the taste and texture of meat products.
Recommended AnyAddy® phosphate-replacement usages
• AnyAddy® phosphate-replacement type 1
- for meat, poultry, or fish, it is applicable to any type of sausage.
• AnyAddy® phosphate-replacement type 2
- it is applicable to products needed to be soaked in brine solution, especially for poultry.
• AnyAddy® phosphate-replacement type 3
- it is good for frozen raw food that discoloration easily occurs, especially in fish.
AnyAddy® Phosphate Free
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
AnyAddy® phosphate replacement type 1
∙ KR 10-2013-0032121
∙ PCT patent pending.
∙ Improvement in water holding capacity
How & when to use … AnyAddy® phosphate-replacement enables :
Chopping
Mixing
Aging
Mixing
Casing
Drying
Boiling
- Ham & back fat separately
- Chopped Ham, AnyAddy® , salt, & sodium nitrite, etc..
- For 24h
- Above Mixture plus ISP, whey, spice, & sodium lactate, etc..
- For 1h at 60℃
- For 2h at 85℃
∙ Control to customize texture of product
Improvement in water holding capacity
∙ Simplification of manufacturing process
∙ Cost cutting
0.00% 20.00% 40.00% 60.00%
※ ERR (Extract-release ratio)
Sausage product on sale
0.9% AnyAddy ® phosphate replacement
0.3% Phosphate & 0.3% kappa-carrageenan
ERR(%)
The smaller the percentage, the better water holding capacity
(total area – sausage area)
(total area)
X 100
★ Recommended dosage : 9 g / 1 kg pork
AnyAddy® Phosphate Free
Patent
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
How to use …
Dissolve AnyAddy ® phosphate replacement & other curing agent in hot water, and then let
the hot solution cool until the solution is opaque.
☆ Suggested amount : 85 to 100 % of the amount of phosphate
pH Salinity
(%)
Pick-up
(%)
Cooking loss
(%)
Total Yield
(%)
Phosphate polymix (SDBNI) 6.41 0.55 13.17 -28.45 89.66
AnyAddy® phosphate replacement 6.47 0.59 13.38 -27.44 90.38
Pick-up after curing, cooking loss and total yield after cooking chicken breast
Factors affecting curing meat
• Ionic strength : as it gets higher, connections between filaments of myofibrils are weakened
• pH : the same as the effect of ionic strength
• Hydrocolloid : reduces cooking loss and improves freezing-thawing stability
• Salinity : the same as the effect of ionic strength, and additionally, affecst solubility of protein
Overall, the outcome is very similar to each other. AnyAddy ® phosphate replacement is a pre-mix
product, and it consists of pH control agent, AnyAddy ® , and salt.
AnyAddy® phosphate replacement type 2
Replacing phosphate …
The main reason using phosphate is to increase water holding capacity. Phosphate is the easiest
way to achieve the goal, but smart consumers hesitate to buy products with phosphate.
AnyAddy® phosphate replacement type 2 is the best option to satisfy them, and it completely
replace the function of phosphate.
AnyAddy® Phosphate Free
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
How to use …
Dissolve AnyAddy ® phosphate replacement & other curing agent in hot water, and then let
the hot solution cool until the solution is opaque
☆ Suggested amount : 0.5 to 1.5 % AnyAddy® phosphate replacement type 3
AnyAddy® phosphate replacement type 3
Discoloration (L value)
sodium phosphate at -40℃
sodium phosphate at -20℃
AnyAddy ® phosphate replacement type 3 at -40℃
AnyAddy ® phosphate replacement type 3 at -20℃
Drip loss (after 9 freezing-thawing cycles)
sodium phosphate
AnyAddy ® phosphate replacement type 3
control
As the freezing-thawing cycle is increased, the
color of oyster with sodium phosphate is getting
darker, but the color of oyster with AnyAddy ®
phosphate replacement type 3 almost has no
significant change. The color is measured at gills.
After 9 freezing-thawing cycles, the difference
on drip loss among them is clear. AnyAddy ®
phosphate replacement type 3 is effective in
preventing drip loss.
AnyAddy ® Sodium phosphate
Why to use …
Phosphate is widely used as freezing-thawing stabilizer and to increase the weight of raw
material before freezing raw foods. But phosphate has some negative effects, discoloration &
drip loss during thawing. Thus AnyAddy® phosphate replacement type 3 makes up for
phosphate’s shortcomings.
0 1.5 3 4.5
AnyAddy® Phosphate Free
AnyAddy®
S A M S U N G F I N E C H E M I C A L S S A M S U N G F I N E C H E M I C A L S
Physical properties
AnyAddy® bubble application (burst resistant bubble)
Schematic picture
Recommended bubble composition
Materials Weight (g)
Water 100
AnyAddy® 1.5~3
sugar 5~70
ethanol 60~110
surfactant 1~15
salt 0.01~10
Physical property figure
Surface tension 0.031 N/m
Viscosity 100~5,000 cps
the number of bubbles per
blowing
30~50 ea.
% of surviving bubble
65~80
Why is it so special?
Generally, since the bubble-layer of ordinary bubbles is composed of water, these bubbles pop as
soon as the water is evaporated. Although glycerine or other ingredients is used increase the
duration, it is limited at most within several minutes. However, AnyAddy and sugar is used as main
components of bubble-layer to overcome this shortcoming.
AnyAddy®
AnyAddy®
S A M S U N G F I N E C H E M I C A L S
Related Patents
AnyAddy®
Topic Purpose Key property
Composition for taste making • Taste masking • Thickening
• Encapsulation
Rice cake maintaining the shape at a high temp.
• Maintaining the shape • Thermal gelation
Low fat mayonnaise without egg • For vegan and reducing fat • Emulsification
• Thickening
Topping for bakery • Prevention in melting down • Thermal gelation
Frozen fried food composition and its method
• Increasing moisture contents • Oil uptake reduction
• Moisture control
• Film formation
Baking food processing method having improved workability
• Improving yield and workability • Lubrication
Glass noodle processing method having improved cooking
property and texture
• Simplification of manufacturing process
• Starch gelatinization
control
• Inhibition of
retrogradation
Glass boodle processing method
and its composition • Improving texture
Low fat whipping cream processing method
• Reducing fat • Emulsification
Foam beverage composition and its processing method
• Improving foam stability • Foam stability
Processed meat product w/o phosphate, ad method of
producing same
• Phosphate replacement • Moisture control
Composition for making liquid droplet
• Burst resistant • Thickening
• Film formation
AnyAddy®
S A M S U N G F I N E C H E M I C A L S