AUG 271997 - Fermilab · This report contains all Grotrian diagrams for V IV through V XXIII. The Grotrian diagrams show energy levels and the principal transitions. Typical examples

\ J I JAERI-DatajCode

FERI\l!I lAfl 97-023 AUG 271997

LIBRARY

GROTRIAN DIAGRAMS FOR HIGHLY IONIZED VANADIUM

VIV THROUGH VXXIII

"-.l

~ .",'/"."""""""""

~ .'.•,'••,'.>'•• ,'>< I

&-'." ..."."" .. >=~-'~ •. '....·.'....'· ...i .. F.,.,.,.. ···... ,.. , 1

t

Toshizo SHIRAI, Jack SUGAR' and WOlf~~~~~~~~L~,~ -.~, .... ~ ..............---............ ---.'~-.--'-',--.II

8*!l=f:1JIHJtfili

Japan Atomic Energy Research Institute

*v ~ - r 'i, B*Jm-1-1J~Jf~PJfiJ):JF)tWH=iH1J L-rt \.Ql1Jf~¥fH5.-c'To A~O)rl:t'~b-tt 'i, B*Jm-1-1J~Jf'9'£pJf~Jf~fi!f¥R~~Jf'9'£fi!f¥R~ (=r 319-11 ~iJ£~»~JilJmt*

mtlj) ;lry -r, to$ L~ L

JAERI-Datalcode 97-023

Grotrian Diagrams for Highly Ionized Vanadium

V IV through V xxm

Toshizo SHIRAI, Jack SUGAR * and Wolfgang L. WIESE*

Department of Reactor Engineering,

Tokai Research Establishment,

Japan Atomic Energy Research Institute

Tokai-mura, Naka-gun, Ibaraki-ken

(Received June 9, 1997)

Grotrian diagrams are presented to provide graphical overviews for 1,953 spectral lines of highly

ionized vanadium, V IV through V xxm. In the usual diagram display such as that by Bashkin and Stoner[North-Holland, Amsterdam, 1975], the density of transitions is often too high to allow each

transition to be drawn separately. Here in our modified diagrams, the transitions are also repre

sented by lines connecting the upper and lower energy levels, but the lower energy levels are

extended and repeated for successive configurations as needed. As a sequence, dense packing is

avoided and all lines in a multiplet can be accommodated.

Keywords: Energy Levels, Wavelengths, Vanadium Ions, Grotrian Diagrams

*National Institute of Standards and Technology

JAERI-Data/Code 97-023

8*~rn~~m*ffl~~m~r~I~$

B# ~-=.. Jack SUGAR· • Wo If gang L. WI ESE·

(1997$ 6 Jj 9 8~!m)

reu ••)'~j-~.::L ryb., V N V xxmO)l, 953*0).A""'~ ,,)v • .-a:-.x.*)v¥-~ULcil~O) *It.-a:-mJt1'I:-t Q ~"o " .) 7 /~H: '£ c fbt:o Bashkin and Stoner [North-Holland, Amsterdam,

1975J I: ~ Q)i1ito) ~"o " .) 7 /~O)~~m-c'j:, ~n~·tLO)jB~.-a:-~-t.O)lf;!t~


Contents

I.Introduction ......................................................................................................................................... 1

Acknowledgements .............................................................................................................................. 1

References ............................................................................................................................................ 2

2.Grotrian Diagrams ............................................................................................................................... 3

2.1 Explanation of Grotrian Diagrams ............................................................................................... 3

§

1. *' § ... ... ... ...... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ...... ... ... ... ... ... ... ... ... ... 1

~ i!i$ ...........••....•..........•...•....•.......................•.........•••.....•.......••...•.....•...........• 1

~~X~ ............................................................................................................ 2

2. 7"0 ~ I) 7 /~ ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... 3

2. 1 7"0~· I) 7 /~(J)maJJ ................................................................................. 3

iii

lAERI-Data/Code 97-023

1. Introduction

During the last 10 years we have published a series of spectroscopic data table for highly

ionized heavy atoms that occur either as impurities in fusion energy devices or which have

been injected into these hot plasmas for diagnostic purposes. These spectroscopic data are

required both for modelling the energy balance and impurity cooling effects in such plasmas as

well as for applying non-perturbing spectroscopic techniques to determine plasma parameters.

In addition, spectroscopic data needs for highly ionized atoms exist in astrophysics, especially

the physics of the solar corona, and in atomic physics research. A good bit of new spectral

analysis work, both observations and calculations, had been done in recent years, and the

results had not been tabulated conveniently before. We have thus critically compiled these

spectroscopic data into single monographs for each element and have published, in order of

nuclear charge, such tables for the spectra ofTi, V, Cr, Mn, Fe, Co, Ni, Cu, Kr, and Mo ions.

Since we have now compiled this series, we are presenting all these data in a single

volume [1] to provide users with the convenience of a single source. However, we do not

include the extensive Grotrian diagrams to provide graphical overviews because these would

make this volume very large and unwidely.

This report contains all Grotrian diagrams for V IV through V XXIII. The Grotrian

diagrams show energy levels and the principal transitions. Typical examples of such diagrams

are found in the book published by Bashkin and Stoner [2]. In the usual diagram display such

as that by Bashkin and Stoner, the density of transitions is often too high to allow each

transition to be drawn separately. Here in our modified diagrams, the transitions are also

represented by lines connecting the upper and lower energy levels, but the lower energy levels

are extended and repeated for successive configurations as needed. As a sequence, dense

packing is avoided and all lines in a multiplet can be accommodated. The diagrams thus allow

a quick survey of the principal features of the levels and transitions in the various ions.

Acknowledgments

The present research was organized and inspired by Dr. M. Nakagawa, Chairman of the

Research Committee on Atomic and Molecular Data of the Japan Atomic Energy Research

Institute, to whom the authors owe special thanks. This work was undertaken under the U. S.

Japan Fusion Cooperation Program and partially supported by the Office ofFusion Energy of

the U. S. Department ofEnergy .

- 1


References

[1] T. Shirai, J. Sugar and W. L. Wiese,1. Phys. Chern. Ref. Data, Monograph 8 (1997).

[2] S. Bashkin and 1. O. Stoner, Jr., Atomic Energy Levels and Grotrian Diagrams, Vol. II,

Sulfur I - Titanium XXII (North-Holland, Amsterdam, 1975).

- 2


2. Grotrian Diagrams

2.1 Explanation of Grotrian Diagrams

V IV, V XXIII, etc.

According to spectroscopic convention, V I indicates the first spectrum, i.e., the

spectrum of neutral atom; V II denotes the second spectrum, belonging to the singly

ionized atom; and so on.

H-Sequence, C-Sequence, etc.

Indicates that the respective V ion has the same number of electrons as neutral

hydrogen, neutral carbon, etc.

Abscissa

Energy in the levels in cm·1•

Short vertical lines

Energy levels are indicated as the vertical lines. The electronic configuration (with the

parentage in parentheses) and the level energy in cm·1 are given to the right of the

vertical line, and at the top is the J value. A symbol "?" after the level value indicates

level was derived from a tentatively classified line. Theoretical levels are given in square

brackets. Energy levels with the same LS label for the upper term are grouped together.

The term designation is given at the right of the diagram; the ordering is by increasing

multiplicity and orbital angular momentum. For the lower level, the term is adjacent to

the configuration.

Horizontal lines

Transitions between levels. The number below each line gives the transition wavelength

in Angstrom (lO·scm). Heavier dashed lines indicate resonance transitions with gf >

0.01, where gf denotes the product ofthe statistical weight (g) of lower level and the

absorption oscillator strength (j).

C,T,P,S

Superscripts to the right of a wavelength value have the following meanings:

C wavelength calculated from energy level data using the Ritz combination principle.

T wavelength tentatively identified.

P wavelength predicted along a isoelectronic sequence.

S wavelength smoothed along a isoelectronic sequence.

Limit

Principal ionization limit in cm·1 and eV.

3


1.0 2.0 3.0 4.0 I I I

~__~~~__-4L3d4d 1212.972 234121.8

13 d h Ipo

L 155565.5

-3833. H "------------.3d5d ~ 2U36S.71

+---:-:t"'lI~"I"':----+L3 d U1601.91S 217990.7

~__~~~__~L3d4d 1356.529 217990.7

13 d h Ipo'll3dh Ipo L 258288.8L lSSS6S.S

144273.1

II)

4841.26 ~ 3cl5p ~ 258288.8

4136.72 ~ 3cl5p ~ 258288.8

3077 • .n6 ...t ----....L3cl5P 258288.8

2480.739 ...t__-+L3cl5p 258288.8

~~....-:""lI~-+L3d4 p1806.184 155565.5

~--~~~__-4L3cl4P 884.146 155565.5

~----------~~~------~L3cl4P702.035 155565.5

~----------~r.-~------~L3cl.P 691.530 155565.5

r I

=

IS

-

Ip

I CoO ..CI. '0

-

I I I I

v IV(Ca-Sequence)

- 4

http:2U36S.71


1.0 2.0 3.0 4.0

2899.515 I

2850.160 I

2610.323 I

U19.195

L346s 292166.1

L346s 292166.1

L346s 292166.1

~ 3454 ~ 281221.(

3455.325 +--l3454 281221.(

3385.336 ~ 3454 r----t.. 2812 21. (

3052.346 ....__-+L345d 281221.(

+--..............-:"II!"r"---+l34 Sa119(.(62 231638.8

+-----r"lnl"l''"'"lI'''I,..,.---tL34 5.1096.375 231638.8

t----.,...,..,...,......,..."..,...---+l34 SalOU.OU 231638.8

3d(dt---:l:-:'('Z"lUr-.7'"1"9--+L 225 8 0(.1

+--~r:;-:--;-n:----+L3 4( d 1211.153 22580(.1

~-~~Tr---+L34(41226.523

v IV(Ca-Sequence)

- 5

r 3

.1:10 -W -.J~ en-.J=-.J

t.I:IW ~=

--

lAERI-DataiCode 97-023

1.0 2.0 3.0 4.0 I I I

NN

2584.636 t L3dH 264482.8

- N L3dHt 2150.231 264482.8 N... L3d4ft 2060.113 264482.8 N

N

t 394.441

NN

2268.298 t L3 d h N N

2105.'09 ~::2088.737 .:2079.300

NN

L3d ht 750.110

;3dh 1i1l3.lli:1I

V N

CoO CI. N

C

100200.7f9p9f·O"- 9 41 .1- 96196.1.... 10959.3; 0 I

L3dH 264482.8

NN

+--l3d5P 254468.8

5940.12

NN

+--l3d5p 254468.8

5509.19

NN

3487.63 t-----l3 d 5 P 254468.8

- N L3d5P

254468.8 2740.545 t

N... 2595.858 I L3d5P

254468.8

144273.1

144273.1

144273.1

144273.1

V,..

~l['" 'D 237638.8

/36322.422 804.1

217990.7 215957.7

I I

v IV(Ca-Sequence)

- 6

I r 3_. ...

~w

~-:I

. -:I en o -:I co w CD 0


1.0 I

2.0 I

5

IAERI-Data/Code 97-023

1.0 2.0 3.0 4.0 I I I

4985.653 ~ 3dSp r-L,.. 257690.8 ..

3334.79 L---l3dSp ~ 257690.8

3135.192 +-t----.l3d 5p

247 8 .119

2395.450

"""""K"'II"lr-lO""l!row---+l3 d 4p1861.558 153918.7

t-------~~~------~l3d4P 737.854 153918.7

... +--------~~T.n------~L3d4P

699.491 153918.7

257690.8

+-1----+L3d 5p257690.8

+-t----tL3d Sp257690.8

-

I

4643.985 ~ 3d5d ~ 288127.6

3284.560 ~ 3d5d ~ 288127.6

t----rIl"ll"ll"-rr.r----tLH H1355.131 227712.5

G153918.1 I J

v IV(Ca-Sequence)

-8


Energy (in 105em-1)

4.01.0 2.0 3.0 II II r

9- ... 2824.131 I L34U """w

263111.4 -:n-.J -.J CJ')

-.Jw.. CI «:IW

2511.317 ~CIIt L;


1.0 2.0 3.0 I I I

w ...

4450.75 "'------.l 3d5d ~ 287733.4

3268.077 ~t:---4"': 32 29.92 tt----t.: 28 77 33. "

II> ...

3096.226 t=::tW ~ 3067.85 ::

287733.4

4.0 r I

3 ..........

Ac..:I ~~ ~ en C~ co c..:I etC

JAERI-Data/Code 97 -023

3.0 4.01 0 2 0 III

0

4906.280 ~NWN: 4886.36 .:4855.05 4845.21 4801.54

a

3333.986 CI~-NN: 3318.188 .:3314.115 3303.719 3294.259 3274.931

2743.523 9: 2716.594 .: 257143.2

256781.8 ° NW

2519.803 E1-N: 2512.242 .:2509.606 2506.969 2497.049

2P143.!hlfU:1

N

t L3d4p1946.772 151567.3

-ON

NWI' . ..,

1 •

1 •• UU2I:f ~ :

15142tO

CI_ a N

N

Co>

724.809 A-.. 724.068 .., 723.652 713.537 723.045 722.912 I.-

I.... l...-

151567.3 19l449'6I 1427.

N L3d4 Pt 711.911 151427 .0

I / Co> Co> A- ..AN .. ... "0 -

1:1

- 100200.7 - 31 798 0 '-- '12.1.- 9 196.1-..... lun:~ I.... .... 10~35192J8

I I I

r I

9

II t•. 'D 3d411 3D

3dU 3D

3dU 3p

I

v IV(Ca-Sequence)

- 11


1.0 2.0 3.0 4.0 I I I

28H.089 ~3d6s _

I\l '" 100.. 100

2164.2191=1:2763.860 :' 2751.528

"'100

21.(0.966 ~"'W: 2121.180 :' 2718.122 2103.933 2703.933

nU17.6

UUll:f 291196.0

nU17.6

UUU:L

2669 •.&83 t-I-----tl3d 6a 291918.1

4899.56 ~_t3d5d r--t. 284226.1

- "'100

3691.236 #={'": 3681.0.. ::

iUiU:l

284226.1 2839


1 0 2.0 3.0 4.0 I I I r I

:3......

++-Jt--;lTn131"'iTi'n!~--;H ;lIn.l!! ~ 236166.9

236322 •• N ...

iun§:!136148.6

N

t-I---nTr'n"S---tl3c1 s1086.312 236322•• N ...

1424.191 ~ iHUB:8

1I+--:"1'"'l".u~9~__6=-=:8":""1~Itt := 1+t-~1~.3~9';':'.aT':3.:---1+1 :

1434.842

1.u.114

- 216905.0

NN ...... .•~"II"I~r---"""II+-~t!.,.,~~rr-:

1tt---rl'T'l.l~.lU'll";lr---t1i : 141 .:/;,

141.tiS 1'10.01 1408.639

:=

... 217350.0 -= iUA8I:%

ilPBB:8 216Ao5.0

III.... 'D' 3c1., 30°

3c1., 3,0

I I I

V IV(Ca-Sequence)

- 13


1.0 2.0 3.0 I I I

2532.982 ...t ----+l3d4f 265271.6

N N wW

" II ... If 2086.073 II!

, II 2014.'33 265271.6 265067.'

l:l 3ctU ......2...0....21-•....,14"""'.---+ 265271.6

N w

:9;.122~~-------""';3~:'::':6:~~:~i----------+III ~ 26§~H:1

iho19.7

3d4f l'-------------r3§n3~.1'"1.....,----------+ 265271.6

w

2378.290 '-I----+l3d4f _ 265067 ••

C_ N W

2603.213 EtN::2599.983 ~ 2598.287

2596.761 ll~iH:1 !d019.7

I~c.o 392.602 I :;

~-----------n319~12~.•~2!r-8--------------i ~ 255445.5 254824.1

N N

"--.-1 34 Sp5710.10 ~ 255146.8

N w

3504.10 ~N: 3.89.51 ~

~ 255445.5 255146.8

2550.971 f L34Sp _ 255146.8

N

5353.090 ijNWw: 5352.320 : 5310.77 5262.164 5227 .89

251445.5n.utf II /Ih,

III. 11,., 'F

N 34 2 10

c.o

w "Q ~1"'''~:38'8UnUJ

22H't~i·6 22661 .1 226521.6

1- 225804.1- 2Y033.0l.I.- ii 3iO'8 - 2l!9!7~i

I I I

4.0 r- I

:3

3dH

34,d

3d H

l... 'F 34H 30

3F 10

3p

3d5. 30

I

v IV(Ca-Sequence)

- 14


3.0 4.01 0 2 0 III

-4828.990 +-lc3dSp

N _ 2541204.1 w ...

3121.3U~·: 3110.416 .: 30U.36

UUU:t N

W-N",

2650.613 ~--~II: 26U.946 : 2636•.01 6U---.1I 2628.090 ~--Wol 26204.213 II.....-~I-W 2614.IU 6U----Wo1 2607 .633 M+--~I-W 25 2 5 5 I... U.

I.... 25 146.8 i.- 2U8U.l

~1__________~~~__---__~L3d4P 778.433 146855.1

N

2162.498 ....t ---4L3HP -N 146429.3

-N wW

2014.199 11+--------01+1: 2011.180 ; 2002.480 ++1----.11

1999.320 1*--------oitI

1997.722 1It----Ht

1990.712 oIoU----.Wo1

1982.4221*----1oWo

~ U1211:1 i.- 14 117.1

. -N...w ~-----------6i-84~.~45~'0~----~1 : 11+-----------..,.6ioi-84~.-:-:36"i8~------.I-W ;

684.!f"8 ~--------------li2~irr---------

ti8Z.4~:; 146855.1 146429.3 146117.7

146855.1

UItU:¥

II /' roo

....'" ..

_- 100200.73P9f·O

~ dU6:l I... 18391.2 - 13458.3

I.... 13239.2 - 13122.8

- 734.7 '- 325.4 ,- 0

I I I

v IV(Ca-Sequence)

15

t"" I

:3

I U·,'.', 3d.. 30

3d4cl '0

3cl4cl 'F

I

http:1----.11http:6U---.1I


1.0 2.0 3.0 4.0 I I I r I

3

N

32U.460 E:tUUU:i %85198.9

W

3234.251 : :

3221.501

.. W

4616.51 nt(/l": 4608.15 :216%86.5

2 6056.9

4565.63 4518.58

286286.5 %85'798.9

CoO a.

3F

1It---;-:~""'lI'Tlr--"""",,1

II+-~;-;;-:-'"'Tln;---m ::

.... nUQ!;8 .::: 222194.6

N w""

.... 223304.6

iU¥U:3

L3d4d +-----:~;--r.;;r_-_t 22 21 94.6

~

~ 148369.2

1111..,. 'D' 3d4, JD

3d5, 3Do

..... 141656.5 - 14'7135.2

"- 146855.1 - 146429.3"- 146117.1

I.... 144273.1

J I .1

v IV(Ca-Sequence)

16


1 0 2.0 3.0 4.0 I I I

2160.222 ...t----....L3d..41N.... 26.4113.1

IIJI~T~-----------------~31~7rg~.T.6;8nI2~-----------------ffl:~TI~-----------------43~79~.~3'7~r2~----------------~II~ lIT 379.353 [IT 379.093 .: . iU1U:~

- 263593.0 N

N ......

2U9'852~'": 21.41.199 ~ 2137.1.41

N

UU.720 N~W...... : U63.796 ~ U50.329 2H9.723 2H9 •.4U U33.530

;.-------------------~__----------------_4l3d.5p391.362 N

W .. 256251.7

w co. N

... "Il

' 7304.7 - 325 . .4;-0

I

5267. U5 11N ... :5222.93 :

5175.950 51.46.502 5130.78

5608.71 5520.63

N ..... N ..... 3060.1.46 Et:3055.86.4 : 303.4.27

N

UnH:I 255.463.3

UUU:I

iH;H:l2gSH3.3

2667. 83 7 "------.l 3 d. 5p ~ 255.463.3

I I

v IV(Ca-Sequence)

- 17

t"'" I

IUdd4,d

c 3d..4d. I P

3d..4d. JF

3d.h 3D

I

'O


Energy (in lO5 cm-l)

1.0 2.0 •

+---------~mr~--------~Lid.16S

2129.934 1 2106.560 "'1--

N ... N

l+l-:l=9-::-:71~.4~7~1....Il+-il~9;iri66~.2~4:-":-4-t

1953.103

+-1--------t!r17"TT7------------1L3d134.344 N

IM------T6i'5"1Sllr.1Ml,urT"'""-----t1II+------ii'i680r.~63ri2-----H

.11 tl :

3d4P

...

-b

1 : 1 :

U9.U7 618.HO 677.345 675.469

-

~: ......

~ ...

:

....-

w ...

.... -

1/ / 0.. w ..

w "CI

.... 13458.3 - 10959.3

.:: ~U:I - °

I

I

... N ...... ...

1I+-~1~("l:"'3(:-.nO:'T 1 Z--I+I :

1I+--;Ii-T(i"Iz: IS~.SiiTT,( -otft : 14Z4.~ti


1.0 2.0 3.0 4.0

.....

I II r- I .. ... :3

""ClIO ""

50H.90 m=[:5035 . .(60 :: (971.9(1 28(699.3

28(101.1

nUU:f 28(101.1

... 3(52.7(1 ~ 3d5d ..... ~ 28(101.1

N ..... ""

211100.0 217836.3

.:: UUI~:i 1(7135.2

UUU:l -

.:: -

N ........ "" 2U6.802l=[:2446.017 ~ 2431.885 unn·.\ ..

""

~~;~:~:! +tlf----+L; 264161.8 IIlltl-----------------~31~9~.~~~r----------------~: ~11I-----------------~37~~~.. 3~19T5------------------+I· I" 378.929

N ...

t L3d4r2136.330 263902.3

l I I I

v IV(Ca-Sequence) - 19


1.0 2.0 3.0 4.0 I I r I

w -cJt ca 3

2167.200 ~'" :... 2159.055 ~ 2155.336 2150.231 2146.828

264&.&5.7 264591.9 26,u01.9

~ . 1111'~________________-'~~r-________________~I~W ~1Ir-________________-;J~1'rB'T9'~9tJ~________________-+III!

J11:I.011:l

.. 2432.518 9......"';2421.317 2416.552

264591.9 26,uOl.9

I 2063.563 L3d4'264401.9

I l... 'F 3d4d 30

-.

2351.934 +-1__-tL3d(ZDl/z)5r 306327.7

. 2313.236 +-1_____-+L3d(ZD uz )5r

306327.7

... 2384.729 ...1_---tL3d(ZDl/z)5r

306323.1 ..... 2356.624 ~...3d( ZD uz)5r 2356.369

306327.7306323.1

1112 I Ill... 'G'

3d4' 3FO

3d4r (2)·

3d4r 30' 3dU 3 Ho

I I I

v IV(Ca-Sequence)

- 20


3.0 4.01.0 2.0 III r

!II

2338.032 ...t __---4L3d(ZDI/Z)h 306871.0

/R;;.

II Ut~IF.(2)· 3d4' 3 0 ~~r' :.,':.;.:.1:" 3d4' 3 H ~ !WS!:l 264161.8 3d4' IF· 264113.1

263902.3 - 263822.4

-w,.

~!:~:~:~ tIoll-----IoL; 263822.4 ..

~~;::::: tIou----'L; w..

263822.4

t 13d4' 21$1.087 L 263822.4

..... .. WIU~:::::::::::::::::::~38~0~.~10~1::=::::::::::::::::j':.. 379.512 263822.4

I Lu 3D 3d4cl 3 0 ~r:,::...,2~3033.0 21,100.0 2rhU~ci3

7H.7 325.4

I I I I

v rV(Ca-Sequence)

- 21

I


1.0 2.0 3.0 4.0 5.0 I I I I I

r:

- 3 .... en en ~to.:) to.:) en oc en .... ~ ....;j to.:)

nto

--


1 0 . 2 0 3 0 4 0 5.0 6.0 II I II I C""

3 .

enc.n ;nC..:) C..:) en C)O c.n -

--


N "'0.

, 897.124 NI ...

6188.907 3p 64N(I"'!:1''''e

6020.741

2774.997 .:

N~iw N~'t411

2780.139 El!: 2740.669 Do 388043.69

387977.07

Nt'" Nt ...

~3pe5d1962.154 ~ 387977.07

It-NI-"'-------_---,fnR"~r_--------rlzoo.zJ!.! zoo.u:;,u

199.1l1ll

1.0 2.0 3.0 4.0 5.0 6.0 I I I I I I

r 3

O')U'I

~N NO') co U'I -W -.J N CD n


- ....enCJ"l:"N N en 00 CJ"I

~N-"" C'O C"I


1.0 2.0 3.0 4.0 5.0 6.0 I I I I I I

t""

9 -.,... en

CTI?,,,, '" en00 CTI-W ~ '" (to n

I

II


1.0 2.0 3.0 4.0 5.0 6.0 II .,- I I .._.

3 -O)c.nc:"'N NO) 00 c.n -w -.:sN ('0 n


1.0 2.0 3.0 4.0 5.0 6.0 I I I I I I

r 3

........... c:n~ ?'N N c:n 00 ~ -~ -.:3N ~ n



1.0 2.0 3.0 4.0 5.0 6.0 I I I I I I

t""

3 ,.......

e':I (II?' C-.::I C-.::I e':I 00 (II-W -.J C-.::I CD n


0.2 0.4 0.6 0.8 1.0 1.2 I I I I I I

-.... .. NC ~c.:t o .... c.:t c.:t ...

+-1_"""'7"'l~~_-+L3.23p5(2pOl4P CIIC509.260 641800.3

--


1.0 1.20.2 0.4 0.6 0.8 I II I

N

l3s2h 5(2 p O )4p367 .543 6227204.5

N

lh23 p5(2 p O )4p 360.741 6227204.5

N

lh2h!5(2 p O ).4p360.2$0 6227204.5

N'" N Lh23p!5(2 p' ).p

It In::;f 6227204.5 N-N

II nt~a 826.458 t

463.418 w

N

·n·487 • .660 " 451.890

418.041

392.990

'" N

L3.23 p5( 2pO). p

622724.5 N

l3she3d 566U3.0

N

l31 he 3d 56U33.0

N

L3s3pe 3d

56U33.0 N

l3.3pe3d 566433.0

N

lh3pe 3d 56U33.0

N

lh3pe3d 56U33.0

-

111 ~:!:l4~3 .11

l"'3"('P'''' 602974.3

~"3"('P"3d 3 p.

L

311977.9 3093U.8 308149.8

I I I

II t""

3 .... ....N c:::>

~ c:.:J

-c:.:J

c:.:J """ ('D c:::>

c:::>< n- 3 I-

I t.'3"('P',3< 'po 3s2h!l(2p' )3d 3F'

h Z3p!i(2po )3d I DO

3. z3p 5(Zpo )3d 3 0 0 3s 23p!l(2p' )3d IF·

3s 23p!l(zP· )3d lpo

3sZ3P!i( ZP 3/2)4. 2Ci)O

-

I I

V VICAr-Sequence)

- 31


0.2 0.4 0.6 0.8 1.0 1.2

1--_____________............,.....,....,........________-+1 h3 p !J4p

118.767 841980

-1--__--=..".."...."..."...,,....-.__-1' 311 23p 5( 2 p' )3 d

323.209 309394.8

C)

C'''' 's I 0

I I I I I I

V VICAr-Sequence)

- 32

I I I I

1466.460 1404.376 1380.105 1293.483

N_

w

II~Nf--___""""""""''''''--+IJ 3.z3p s(2p. )(, 13

• 16 13

• 15 :1 §23S,4.S

IlHd:A

.9 :5

.1 4 1 .2 i5 I .OU5 623f,4.S

IHd6:A

I I r_.

-.... :3 ...

~ .... COO • W .... w W ... 0

I


1.0 1.2o 2 o4 o 6 o8 II I

o - 2 !l 21629.186 ~ h 3p ( pO).&p

r-t... 615111.8

15U.942 1511.931 1515.020 1512.655 1.451.511

W w N N

111f---_1F'l�''""IMI"":.------t11 3a Z3p$(ZpO '4P fll. 4 fS. :1 rII. 1 4. 1

f4. ,1 3 4.115 61Bn.8

UnIt' .. W N w mN..--__""'%"':',......,;':-:-__.1I 3 s 2 3 p 5( ZP 0 )4 p

I

- 3 ....-~-.~~ -w W 001lIo (1) 0


0.2 0.4 0.6 0.8 1.0 1.2 I r I I , I

r_. 3_....w

I -.L3I3pS 34

SOO.6U C\::I550384.6 QClCI "'w • W

'" -w w ... ('0 CII 488 . .(62 ~h"'"


0.2 0.4 0.6 0.8 1.0 1.2 I I I I

-N I 640.135

l3s23p5( 2p! /2)SI 1789U.O

- -f 631.1U

lh23p5(2p t /2 )5s 1789U.0

- 2t--------------:"Inr"'"lI"II"l~---------_+1 h 3p 5(2p! /2)SI 1Z8.319 1189U.0

o

1085.142 t-1__-iL3.23p5(2 P S/2)H 101280.3

-p---------.-----------------,~-www---------j 3.

23 5(2Pt/2).'Illf • .,.,U L. 551636.1

o N N

I r:

•.3 .-. .. ..... ..... :0 N = w -w W.l:loo. ell = < = n-3

.!.

-r-h-2-3-P5-(-2P-S-/-2-)4-c:\-2(-2~-1.-----,1 :2 5 2 3. 3p (

[,"""P"" 709147.4[ ~ i8nu:~

U\ntl 308149.8

I I I I I

V VI(Ar-Sequence)

- 35

I

-

2 I P 3/2 )(c:\ ( :2 )4

I


0.2 0.4 0.6 0.8 1.0 1.2 I I I I I I

t"'"

- :I -. ...I 31 2a,5(2pS/2>51 .... ....lZ!l.UU N771123.1 CI:» ~... N

N_ .... ~ ,Il1o.

< CI CI

~"2""2P'. l/ 2 lSI ~6 09 ~ n6 .OU :I

. iiAli1:& ~ "I- Lh2a,5(2p~/2 )51I 596.947 7704U.5

CI 1225.178 +----l3l 23 p5(2pt/2>4d

723421.6

-- L3I 2a, 5( 2pt /2)(d971.700t 723421.6

-13123p5(2pt/Z),ld

138.Z3:1 723421.6 N N_CI

10......~..2.P.'2PI/2 ,.. 1001.714

983.632 964.341

HUll:1 0

1334.039 +---lliZa,5( 2P3/2)(d 716760.4

- 2(! )0 716760.,( 2

1038.953 ~3123p5(2PS/2)'(d

13I23p 5(ZP3/2)(d 139.:111 716760 •.(

"1_N

, ..... " ti:=t3.23P.,2PI/2'" 1052.591

716760 • .(709747 •.(

"1_N

1057.... ~••2...'2PI/2'"984.419 958.156

7A676O •.(7 9747 •.(

- N Lh23p5(2 pj/2)(d936.557 t 709747.4

--------------------------111-rrr----------1-3s23p5(Zp3/2>.(s

• 549298.8

0 /,,,;;; Co>..

N Il." .."P'''' 's~1'2""2P'14P IS Co>..., 3I 23p5(2p' )4, 3D co

641800.3 h23p5(2p'>.(, 1pri ~~3¥H:r 3123,5(2p').(p 3p

62 !09.2 1u9O •0I'e1- Inn:,.8

10... 602914.3 0

110...

I I I I I I

V VI(Ar-Sequence)

36

2


1.0 1.20.2 0.4 0.6 0.8 II II I I t:"'"

N W 2 5 2 ---:; . U32.593 L--13. 3p ( P3/z)'U

c-:I~ 779550.9 00=• c.::I _c.::I c.::I ..

~ =

I


0.2 0.4 0.6 0.8 1.0 1.2 I I I I I

r 3

II> ... 2 5 2 U 26 .335 ""-----...l 3s 3p ( P3/Z )U --~ 783852.1 N00=..... • c.J

- c.Jc.J ... ('0 = ......


0.2 0.4 O.S 0.8 1.0 1.2 1.4 III I -. Ie-I

:3 t;:23 p 4(lp).(d .... -. .U'I

~C .812550 en U'I (lIC


0.2 0.4 0.6 0.8 1.0 1.2 1.4 ( I I I I IIr

N~'!tt_ --3 N. 113.23p4(3PU. -- ... If 164.523 II c.n-II 164.302 II

QN)-c.n163.182 IL C'O Q'--


1.40.2 0.4 0.6 0.8 1.0 1.2 I I I I I I r_.

S 0

t:---.t3s2

3P4 1830.4 c -,......

60Ul .... -c:.:Ic:.:I :r. :g lS(DC

0.2

lAERI-DatalCode 97-023

0.4 0.6 0.8 1.0 1.2 1.4 r

.... -- :I ,.. -:I .... c;...)c;...)• c.c ... c.c QO

< ~3So -n

3 I

N

2 3 p3( 2 00 ). d 903350

N

-+L3s23p3(2pO ).lI

7366

lAERI-DataiCode 97-023

1.40.2 0.4 0.6 0.8 1.0 1.2 , I I I I I r-"

w 3- N _. 1 as Z3,l(ZOO).(d - .... 11 LII I ..... -110.00 I c.:Ic.:I . = 110.38 .L ~Ung

... = c-.o-

lAERI-Data/Code 97 -023

. 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 I I I I I I I I I

r NI NI- a Nlw

II l3s h' ..... -U!:UI N CI-U'l en 319184 +x • en

QOCI ct CI 2S

1.8


0.2 0.4 0.6 0.8 1.0 1.2

N'N'W 2a. 3p' 16U.l c

1633.3 c

n~Ut~

----------1

lN'W

llh".' '0' ~ ~. unm ~

N''''N'W

t-------T!.r,I!~::;.;.j-------Ur'~~;~~';;

N'W N''''N'''' N'W

+tlt-------+:1g:i~..:;:~;.;,.~;..:______t3.23P2( 1 D )4. 126.765 823570 +X

823290 +X

N'''' 9--__-.,.....,..........__--~la.23p2(' P )3d

240.30 477370+X N~iw

N''''N''''

.UU20+X 438070 +X

N'''' t------.....,..-~ 3.2 3p2( ID )3d

228.27 438070 +X N'W

N,W NI N''''

Hh3p'II ::tiM ~ 265835+X 265160 +X

1+---:-:=--:0,.,..."...--61 ';' 1t---;";;";":";i-:O-i--4+ ~

..... N'W I 3.z3pl 'So

3. z3p' 2Do

v IX(P-Sequence)

- 45

1.4 1.6

.......... N=enU1• en co = 19=

I


0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 T I I I I I I I

c0

EI"', ..."''',. --. .... t l3s23p2(3 p )3d N235.12 C460550 + X enU'l• en 2FCOC C't C

C -n

EIL"'"

----


2.0

(,)

3s2 3pz

67751

1573.0(;

0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8

+-______---:I"TT""'Ml'_______--+L3I1Z 3p h 118.18 878700

~-~~n_-4L3113p3323.811 3~1335

U1335

~_..,....,...,......,..,...,.._~3113p3

I l"3•• 'p 31 2 3p2 10

N

~-""'~""'U'!"".""'10""'6....-....L313 ~; 9 9 69

... +-___________'!""7__--------~L3123P~d

94.96 1085600 ...

~--.."..,..___--.....Lh23P3d 245.35 ~~0090

... 1t---------,_-~L312 3p3d

232.20 t 440090

327902

v X(Si-Sequence) - 47

......._--------------------

IAERI-Data/Code 97 -023

0.2 0.4 0.6 0.8 1.0 1.2 1.6 1.8 2.0 I I I I I I I I I I r_.

-N -N 3 ... .-. ....

II IU.II:) .. N

N c.:I coII 115.111

... 0 "IS Con

II 115.58 - Con co II 115.09 .. (I> 0 ... 873100


558.329' ...t __--4l3l23p3d w

+-1______--....

271.22 e -N W

1I~----~2Sn.5~.5r..~---#lt :~:::::t.25~i5~.2~.t::::t:t ;;:

253.21~-----T.25~2~.1~.7~--~1 ~

250.53

11....- .......,2~.-/;;7-',.........II ~ j '2 T7fl C " 4 0.183 ... 4 1.245

222104221072 220984

II ..".' 'D ["., 'D'

0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 I 1 I I I I

I I

... pt__________________~rTr-----------------~L3.23P.d -- ...N_

U.23 1070600 Woo ~CJ"I CJ"ICC roC... ...


0.5 1.0 1.5 2.0 2.5

NIW

~__________~~Tr__________~3s24S

.4 939500

r3- ....

NN U'Q ~cn .... N C'O Q


0.5 1.0 1.5 2.0 2.5 I I I I r

3

-'-----;~~..__-I+U 3. 3 :;::7":3 d .... Htn! ~ 6:3911

NI

Nlw

It 305 945~ L~ 302.500 506695

NI-N'- Ntw

515.796 c ~NI'":: 513.315 Col 502.602

500.265 c

gSUU

I U:,'P:o'P 3s3p2 2S

3s3p2 zp

I I I I I

V XI(Al-Sequence)

- 51


Energy (in l06 cm-1 )

0.5 1.0 1.5 2.0 2.5 II I II

r 3

II a-z"d N

1\)~"CIt .. N 0

61.ISIHI II c.n ISLltHi en

11"12.&0 ~N 11"7770

c.n

('110 011>1""11>1", 11>1'" < 0- n•.- r"('P13d 3II ..!.U::::; unn

11>1""

Lh Z(lS}3dI 315.391 2n861032 NI'"

Lh Z(l S }3d

281."85 86195"

,... zp. Ia-h(lp. }3d z,.rl["'('P')3d

~ 211111

U350UUO

9696

l~

° -NI""

L3 p Z(l D}3d318.09 821098

NI""

NI""

NI'" NI'"

If ~.,.~;;;;ntH~

II 212.332 ~. 2JJ·_113----Tn7Ur---·

NI'"NI


Energy (in lO6 cm-1)

0.5 1.0 1.5 2.0 2.5 , I C""'

I I I

NO ... :INO ... NIli' ...... .... NN '"C~3'''''P'l3.• 1 ~cn -.3 N

337.790 6~2939 etC 6 1902



0.5 1.0 1.5 2.0 2.5 II I I I

t"'"

:3N''''N',",N''''N'''' -- .... 1:\:)1:\:)C.7'I~"." QII l1~'nn. 1215500 ~= -4 I:\:)1215300 C'O Q


o5 1 0 1.5 2.0 2.5 II II I r

Ntw N~'f'w Nt.., HIN.'" 2 3

367. 813 l==lh ( P)3d. 367.126 366.028

82867S +X

Inln!~

N,,,, N''''L3p 2( 3p )3d.t 357.8U 82H52+X Nt'"Ntw 4p

I Ntw

H!:n: r'~~~;~~a

:3

-NINJ~~

NtW Nt~

11I"1T~1~-----------1~0~6~.0=O-------------f1 ~ ImlllT------------~1~0~5,.3~4-------------H~ ~rrlll~-----------1~0~15~,.O~3~-----------+I: ITI 104.14 ....

-113HOO+X 1128300 +X

211.512 261.658 266.656

unu!~ 548037 +X

I I

-

I I I

V XI(AI-Sequence)

- 55


0.5 1.0 1.5 2.0 2.5 II I I I

I:'"'

9_.NI ....NI'"

I La,a,(lp. )3d -NN.... 310. H7 e NNIW 555583 +X U'l c NI .... ~cnNrl7w NIIII -:I NNI'"

a,3p(3pO)3d CD c


0.5 1.0 1.5 2.0 2.5 I I II t

_.:3..- .........

L3 S(S c:.:I

IN)t 105.14 1Z27300 0 oo\lIoo. 00

00 .. .. en- CTI 0L3p2 (09.64I < 0525745 ......

0

n IS :3 .!.

[" 'po

281627

--1 3s10p

(3.358 2306400

-13sh

H.03 2271200

-13sSp

(5.071 22187 00 -l3sh

(6.913 2131600 -13sh

~o.u~o 1997800

-~------------------------------------117rrr---------------_~3S5~765100

-~--------------------rf.'1,-------------_____~3S(~310500 Ipo

N L3p3d

861555

402.90 I

.. l3p3dI 297.13 861555

N L3p3dI HO.512 t 861555

-~________ 355.07~3S3p

281627

..

r r~ ['3d 'D o ,1335( H5~n (5

I

0

I I I I I

V XII(Mg-Sequence)

- 57


0.5 1.0 1.5 2.0 2.5 I I I I

r 9

r-----------------~~~--------------~L3.5d64.920 1822000

r---------------~~~----__iL3.'d17.363 1'26300 N 3d Z

382.'62 ...1----tL 1123022 N

t---:ii:"i"~~-+L3d Z273.215 1123022

t--"lI"A'T-rr--tL3I3 d 301.'S 61335'

-696.0Ue ~ h3d ~ 757015

I 321.30

-

83.611 Lh'd16(0800 LhU 1FO 113.78 1(92100

n.S8 LhU U92100 I I J I I

V XII(Mg-Sequence)

-58

http:r-----------------~~~--------------~L3.5d

JAERI-DatalCode 97-023


0.5 1.0 1.5 2.0 2.5 I I I I i'r

3 ....

L3P3d w421.02 •N

850811 = ~-co c.n(1=

l3p3d =

Hun


V XII(Mg-Sequence)

- 60

0.5 1.0

396.53 392.53 385.47 383.53 380.78 373.17

r.

0w .. 3'2."~::301.46 .. 296.72

N -N0

301.68 .. 301.68 295.U302·"it~r

295.40

L3 p 4d82.024 1678600

ON -N

11

N Q

w

411.05 ~::398.498 c ~ 397.72

:: 9 • A.

• 1~ h3p 522.4

191509

iU::l

795499 795010 788448

nun 788448

1.5 2.0 2.5 r 9 ....

c:.,) =N co-""'" co 1126966 -<(t1126208

lUUU

~¥ 145 918 0 144 0

c.n= = =(') 9 .!.

3p


Energy ( in lO6 cm-l)

-N

It


2.0 2.50.5 1.0 1.5 , I I lit'"'I 3

16f2400 thUSS

+--..,.2=86,......'71'105!""'""'"-t~L3p34795 356 W

,.08.65 §tNWN: 399.70 :

3ge.624 c

397.72 795927

795356

789199

-~---........."",""".,;-------tL3p 41

108.93 1713400

......----"l"'ll"'O'~-_---iL3pH105.49 1705000

N ..... N W.. c.:o

• 1 c:. 282.88 1099356~ 18na11

W ... N ..

330'486~N:328.954 N 324.014

lUUr: 1097824

330.78 II N

tI W

: 322.513'-~---W~ l8~UUN

Ill.3d ','!P3d 1 0.

3p34 3 p '

I IL I

V XII(Mg-Sequence)

- 62


0.5 1.0 1.5 2.0 2.5 I I I I

59.092 l ~----------------=~~------------~L3.7t61.921

t--------------,...,IO'""X"lnr----------tlh6t 66.806 2U2000

t-------------.:r-r:ro:------....l3.S t76.960 18HSOO

N

~·--------------~~~~l3P4d 82.348 f 16601001 ......

1480800 1480600

N ...

S02.147 ...::: e ~N'"

SOO.H8e : 499.38 490.08 488.47 476.78

N

l3P3dt 334.91 7H314

t=(lh3d 3D c L 145169

H493 H068

HS77S

...... '"

1712300HoUSS

I II

V XII(Mg-Sequence)

- 63

- .... ~ ~ ;:Ceo_ c.n (lQ

< gC"l

S I

3.8t 2237400

21.60100

-

I

5.0 I



1.0 2.0 3.0 4.0 I II I r

S .- .... C.:) C.:) N en -.:I-NN -.:INenCJ'1 ('II 0

< n S "u- -I L2pe l1s

43.268 2547800 NI

L2pe I OS H.013 2508600

SL2p 9s

H.919 2462800 NI_ NI

N'W e 199.37 c L2p S. 198.SSc U

2393000 N'- NINI'" e

L2p a.ss,flla~n 99.543 2393000 NI

NIW

II 4S.!§5 L2pe as

46.118 2393000 NI NI-

c IINIW

L2p S7.

249.3S c

2S0.65

2290400 NI NINI'" S

L2p 7.It III .I~ 110.87 2290400 NI

NIW 2S 48.682 l2pe

7s ~I 48.435 2290400

N.- Nt

424.S0c ~2pe6S 420.80c

2127000 NI

NIW S

L2p &SII 13&.2g~135.39 2127000 NI

NIW

LZpe&sn.ur 2127000 N~,w " S220.S9 c L2p S'

218.49 c it 1846100

NI-l'll'"

LZpe s s It ~~.1~~1.7 1846100 N~7w

LZpSh~ ~3'n43. 5 1300490

["" 'po

1891430 1889360

1392780 ~~~ 1388410 UU~8

1 I -.l I I

V XIIICNa-Sequence)

-64


1.0 2.0 3.0 4.0 5.0 J I r I I I

:I-~N ~-:a ~ .... NN -:a N en en etC


1.0 2.0 3.0 4.0 5.0

NI ... NI'"

:tU:: ~ ~ IttI-----...l!-'62~.2~0'!7r1~----It~~ InU88

N.NI ... 1101 ...

110''''

~ ~~~:n~ 1U.68 l~ 21..... 2151.400

11011101 ...

~.....117 52~ 117.38 InUB8

1101110''''

--------------------------------(~11--t2pe6P

E:l--------------------------417460'- 215 UOO

2151.400 Nlw N~7w

N

260.78 c

'''' ::

259.77 c .: 259.38 c ~

1891430 1889360

110.110 ....

110.110 ....

------------------------------~r~f28--t2pe5P------------------------------~-1'~--

N

~..

Co>..

110 CI'I

. lllA1iS

,.. L ~

.. '" CIt ~ 'Dff lr"110 19.6500 110 o 1u\1U23 0 CI'I 1l8U881300U UH88 V XIII(Na-Sequence)

- 66


1.0 ,

N' ... N'N' ...

N'III IN

Ii 118.50 1·(11 11 118.08 1:" 117.91'" ,L UUlf8....

N~iw

.------------------rr.11~-~"··' ·-----------------'T~~---- 1392780

1388410 NIN' ...--t"'" .....".--- U2.7Us nun

2.0 I

r :1

-.. -c..:I Nc..:I C') .....-N N ..... N C') c:J"I

ct Q

< n :1 o!.

3.0 I

4.0 I

5.0 I

2po

N'

~ 0 ["'. 'D

5(5,50U. 00

-NIN''''

II U:UI N' ... N'III

~"'I1' UU888

N'''' f

N~iw

II

43.141

4i'n~.t..

N'IIILh110d 2522800

N'III

Lh l 9d 2479000

2n

["3' 'po 23U3O22 20

I I I I I

V XIIICNa-Sequence)

- 67


0.5 I

1.0 I

Energy (in

1.5 I

N~Y'..,

II

N'N'W

lO6 cm-l)

2.0 2.5 3.0 II I

r

9 ..........

c:.:I c:.:I N -.:Ien -NN -.:IN

U1en

l N.",

N.1Il

< 0

3 N -~ I

..,GO

- CIt A.HtU~

115.33 2416500 2416300

N.",Ntlll N.1Il N''''

11 ~U:~~~ 222.91 l~ !111m N .... N,IIlN~7'w

:n:~;~ l~ 11 189.77 2416100 2416 00 .,,, ... Ntlll

"'.N''''

It

11 n:Ui~ 97.287

il'Dif4 .8 3 4 .64

l~ N''''

N'1Il

l~

2416500 2416300

2416500 2416300

NIIIl N''''NI

3.0


0.5 1.0 1.5 2.0 2.5 I I I I T I r:

:3

NIWNI'"NI .. N''''

at::: l~11M---....Il~5~1.~83~~--"""" A. 2183000 2182800

Nt- N~';'c.fII

343.21 c !==IN'W: 342.91 c .: 340.19 C A.

2183000 2182800

N'W Nt'"

It ~U:;::t+----~1~2~5.~88~~--......l~ 2183000A. 2182800

N' NtW NI'"NtW

t ~1.39oe ~:I6I-1-------------------5r;g~.;.;::;.,;..9.;...:---+:. 2183000 2182800

NIW NI'"

tt nt:f~ l~ 251.83 A. 1946500 1946230

NIW

Nlw NI Nt'"

if

NIWNt N,CI'N.W

58 490(; ~: 11 1946500M------------------i-i~:~:4~1:'-i-:--+:'

1946230

NI- N~'i'""

884.02 c ~NIW: 819.51 c .: 851.H c A.

U8U88 N'W

NI'"

+1-11--------.r~i-=:::.:-:H:-::~--------t~,~ 1506'"~ 1505900 ---------------.L

N

-0 t: ~~ lr':!:::18 ~.. .... 1891430 -0 1889360 .. 1549620 1549410 1392180 '- 1388410

I I I I I I

V XIII(Na-Sequence)

- 69


Energy (in lO6cm-l)

0.5 1.0 1.5 2.0 2.5 3.0 I I I I I

t"'" I

3 ....... ,.. c.:I

Nc.:I en -:I-N N -:IN enc.n

N'WNI N'''' ('/j Q

li'"m:m: l~ !"'''


0.5 1.0 1.5 2.0 2.5 3.0 I I I I I I

3

"'I ..."I'"

2332800

Ul:n: U~ 1t++----~120~.98~.......-f~- lunss

N~Y'....,

~~~~~~~~~~~~~~~~~~~!!~:~!!~!e~~ HHH! NIW N,lcr....,

c 19:N1 402.58 402.25 c

'" :

.: 402.14(; -

2195100

I,.. ", 2194900

"I'"

Ht;~: l~

+t----""""14It .....5 ......14..,..~---i - 2195100

2194900

,,'w N''''NI ... .. I'"

1~1---~nJ1M--r---ttij ~ '1951" ~ 2194900

NI ... .. ,'".., ... "''''

II NI'" NI ...

+1--11---------;~~~JHr---t'H~ 1981'"~ 1967880

~~ 1506480 1505900 I I I I I I

V XIII(Na-Sequence)

-71


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 I I I I I I

-~________________________-n~~______________________--112.2ps3p

18.782 53UOOO

-Lh2p

S3PI 109.67e 5299000 -

~________________________~~~______________________~1212ps3p

18.870 5299000

12s22p5(2 PS/2}3p 2Ci)

L U87211

~----------------------------------23~-90-------___--_-1L2.2~~~~~~~2}31

-~r"'('Ph)"


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 I I I I I I I I

t"""

:I ...... -CIO-.,3 CDN) ~N)= -.,3 C'O =


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 I I I I I I r

:3

C;;;: ~~ Q-.:a 1'\1 Q

I I


Energy (in l06 cm-1)

1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 I I I I I I

N ...-N

Jt i1•29O 0.573 -N

II i!::n

70.,(87

_ N ...

339.8" i:t'.',.'('P1 /,'"328.3.(2

HUiH N ...

....... i:t"''''('PI/''''

336.177

'(732~77,(726 16

".;

V XIV(Ne-Sequenee)

-75

~2"2' '('p1 /2'" 5889715 5886695

N ...

r'~~~~':al;' '4d N

lhZ2p!5(2 P J/Z).u 5833302

r

- :I .... co -.:a(Q N N

en CI -.:a roCl

JAERI -Data/Code 97-023


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 II I I I I I I r

3

....

00 3d "l)'

4P846~4 1 10

I I I I I I I I

V XIV(Ne-Sequence)

-76


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0

r 3

.-. .1+--------------r:!!"""1!i"-.-------------i h22p4( 10)34 co~1. 1 ~oo c:n~------------------------------'l~iiJ---------------------------- 5143200 CII 0


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 t I I I I I I r.!-.

3_.N''''Nt- Ntw ........1t-------------rlI:-lI'lI~----------__t+1 hZ2p4( IS l3d cc .... .... CI) ....~-------------------------------tr.lli------------------------------l "c co ------------------------------------~----------------------------18.991 5265600


1.0 I

-138.168 t

-t 103.0-43

_ CI

~2a22p4 529.9 237105

2.0 I

CI

L2p1l 1169360

CI

L2Pll 1769360

3.0 I

4.0 I

5.0 I

6.0 I

7.0 I

8.0 I

r :I

...... ...-Q QO 0') U'I Q ",.

n co < Q Q- Q n

:I ~

9.0 I

IS

~ "..

lL'''' Ip' 10.45590 798899 48937

I..... N 'a


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 I I I I I I I I

'" Lh22p 3( 2p" )34I 18.265

w -5596000 Q cr.o Q...

'" Lh22p3(2 0 0)34 ~ f 18.525 < 5518000 -...

~------------------------------iii23t-------------------______~2.2~~:~:~~)34

10 Nt.. Nt'" '0.,l

'" "..

r"'" I

...o121039 -g

-0 -1 z.22p3('So )3.

III 20.659 1

~-------------------------t~ii1-----------------------~ 4891000

N

1"'" 3p

iUn 0

r 3 .... 00 C.11 ~ CD Q Q Q n 3 ~

I

IFo

-

3So

--+h ....

22p' 20.u.7 48937

3p

-'" 1 h22p3(200 )34

11l.4lti U76000

N '" f 20.2Uc

Lh22p3{2 p ")3s 5068000

'" 11 I h 22p l(2p")3.

~----------------------------1i~;f&~---------------------1L 5068000

3po

I I I I I I I I I

v XVI(O-Sequence)

- 80

------

-0


1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 , , ,I I I I I I I:"'"

:3-e 5 .........

+---lh2p 178.191


0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 I I I I I I I I I I

r 3

....... ,...

131.687 .... .... cc126.832 en "'" 00 C\:)

no


0.5 0.6 0.7 0.8 0.9 1.00.1 0.2 0.3 0.4 I I I I I I I II

:I ........

162... C +l2p5

_ CD

1698100 =0Il00 QON

N~'1_ ~ CI


0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 I I I I I I I I I

r 3

+---_______--:....-:"'l!"r"_________.....L2. 22 p2( I D )34

NIUI -- .... 17.490 5958000 ..- cc en .;..

co NN,UI C'O Ct-__________~.,...,.....~--------.....Lh22p2(3p )34


0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 I I I I I I I I I I

r

NIW :3 2 ......... _ f:Ot------------.I"'II'""';;?'II"-----------t' 28 2p2( 3 P )3d 11.1~11 I CD .;:..

11.1~11 5828000 eeN C1I 0


0.1 0.2 0.3 I I I

0

+=----t..2p4 152.933 1668300

0-t L2p4 129.71 c

1668300 0-L2p4 107.19 ct

1668300 0

~h22p2 '(U.2 T 269000

0.4 •

0.5 •

0.6 •

0.7 I

0.8 I

0.9 •

1.0 I

r :I--... N)en O

0CD en

I


1.0 1.1o 1 o2 o.3 0.4 0.5 0.6 0.7 0.8 , 0.9 I I

i ' h 22P 1078.2 8l3.Uc 160910

["2" 'p nus

'" '" I Lh( 2S )2P 3(20')

908420 -", '" I h(2S )2P 3(20 o ) IT I

908420

-4 h (2S )2P 3('SO) 897330

-",

I h(2S )2p3('S')II IT 1

n.------l 897330 ,..

01['20' 's ~,2Ai9S000

I 0 I I

.....

r'2.' '0 61860990103lA60

'" I

, I T I I I I r-S· -- ,...-~-c:r.!0

0Qc:r.!


...... N...

"IiI N

0.1

"'

la

0.2

290.(5C 252.30 c

1410770 1358710

222.08 C

199.06c

UUH8

162.53 160.40 149.86 U8.07 c

147.30 146.91 C

UI8H~ 1318710

138.168 136.30 c

136.08 c

127.27 127.079 126.411

1416110 1410770 1358710

0.3

III Ls",,,'S') 'So h(2S)2p3(200) 30°

h(2S)2p3(2p.) 3po

h(2S )2pJ(4So) JS·

h(2S)2p 3(20°) I D 0

v XVIII(C-Sequence)

-88

0.9 1.0 1.1 r EI

1:'1:) ....

CDC cet CD


0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 I

I:"" I I I I I I I I I I

- :I I 2a 22p3d

IS .32" I -N = -c:::> 16.%(" 6195000 c:::> -CD = c:::>N < c:::>II 2a 22p31 -c:::> 11.11111 c:::>1 n11 •.uZ I l1..(uu L =l- HU88S

2U •.(Oc

1H.06 c

11l.69c

U9.86 U8.113 IH.111 1.(3.311 U1.13 136.00

I L."·,,

2s 22p2 1 D

L2s 2p2{2 D )31 11.545 6323300

lD·

L2a 22p3d16.378 61 HOOO

280.81 c

216.01 c

215.46 c

210.95 c

119.96 c

119.5S c

116.440 110.618 110.33 c

159.991

I I I I I I I I I

3po

-N

3D

-'"

3Do

-N

IT n

-N

II 11 n

-~2a(2S)2pl(2PO) 135.(20

-N

~"('S""('P" HUU

C

-N -N

2a(2S )2 pl(2p.)

---- ..... HUU..... -~

0

~['.'.. IS 161000 1 0 10 nns

0

N

I

L'('S)"'(' D" 623860

N

I

c -~h{2S )2p3{2DO)

N_ 625040

E=i"('S ".'('D" 6343 50

~U8U N

-N '" ~

h{2S)2pl(2DO )

~

r--

--- .... 634950..... iUU8'--

I I

v XVIII(C-Sequence)

- 89

JAERI -Data/Code 97-023


0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 I I I I I I I I I I I r

3~ ....LZs2p2(2 0 )3d -N16.558 6674000 -0) -c Cw -0)

cLZs2p2(4 p )3d ~

c<17.018 6500000 - c c 3F

(")

3

3 D"["'S".', 'D') l

unu -

N

LZs22p3d16.9il 6073000

3FO

["'" 'D .

160910

-- N

334.81 cit""S"""S' ) 304.03 c

(366870 )

5So

["'., '. 68190 37960

'w

LZs2p2(4 P )3d16.3.&1 64860001

w

LZs2p2(4 p )3a 17.H2 61000001 5p

L" 's ".','S') 55" e366870)

I I I I I I I I I I I

V XVIII(C-Sequence)

-90

1.2


0.2 0.4 0.6 0.8 1.0 r 3

2a2pZ 139.59 716310

N .....

't----------...,...,..'"'lI/"lr....---------......L2a2 p ( 3 pO)3p15.333 6590000

N'N ..... II N

1+--......[11::. 138.84 136.25+-_____ ["N 1U •60c

2p'- UlisS

108.3c 104.5' 104.1'

1318200 1292800

204.0' 198.51 193.93

1318208129280

143.82 140.25 138.18linus

N ....

2s 2

2p 1451.6 68610

2po

V XIX(B-Sequence)

- 91

--


0.2 0.4 0.6 0.8 1.0 1.2 I I I I

N,(..J Nt""

l+-t----------"""'i'T~r_--------__+L2s2P( I p.)3p14.636 6901000

Nt'" NI""

l+-t----------""":lT5'.OT3:r"'9---------+Lh2:~::~~!P NI ...

NI

I



0.2 0.4 0.6 0.8 1.0 1.2 I I I I I

t""

:3 Nt'" -q h 3 43S.0e

c.:I 1030S50+X (.nO

(.nc.o

Nt'" Nt'" 3 (tc.:l

t---i..h 230.se

3


0.2 0.4 0.6 0.8 1.0 1.2 I I I I I

r

I IN. IN 'a

-

·------------------------------------r~~1nr----------------------------------~2··:1.0000

~--------------------~~----------------~L2p3d15.639 7571900

~------------------------~--------------~L2P3d15.l76 e 7571900

-::--_-------------------------------i4:!Il----------------~2.3:96.000

N:;, 396.0c lpo:: 328.0c

308.3clt 627 500 ____1282P 159.355'

1- 627500

I N

-c~II~ l~..W.'.'"[t illm 'a IN

o 303100

-L28H1l.615 9237100

L2Ph 7453900

686.8 c +-l283d 7109600

ID l2$3d.

15.4027 7109600

Ih2P Ip. L·3P • p' 6964000L 627500

I I I I I I

V XX(Be-Sequence)

- 94


Energy (in lO1cm-1)

0.2 0.4 0.6 0.8 I I I I

-NN

1064. cUl;;: 195.5 c 982600

2

+=-lh 281.62

982600

i=::t: 16(.59 N 151.5c

982600

';tIII'"

l2sh lp.

2s2p Ip.II ~21I,!.!.m I nU88

11.378

N

Lh3dt 15.526 e 1423300 -N

" ~ 982600lUng

I N

'ON

... "'0

u:ur L~ 1423300

11.523

15.216 Lh3d

1554600

-N

14.159¢ L2p3p

1402900

II i4.U§ 14.1ue L~ 1402900 I I I I

V XX(Be-Sequence)

- 95

1.0 I

1.2

r 3- ... .... -Ao. co .... c.t::Ien c.t::ICl c< c ....... c c n 3

I

-In

-LbH

9645800

In°

-Lb4d

9660900 IF O

-

3p

I I


0.2 0.4 0.6 0.8 1.0 1.2

3154. e 2117. e

888600 856900

207.51 201.02 194.74 187.17 180.58 176.68

nU88 820100

IL. 'p' 2.2p Ip.

lh4d11.d1 9639800

lh3d15.332


0.2 0.4 0.6 0.8 1.0 1.2 II I I r

.-3

~__--____________--______~~__--________--______--__~L2p.p 10.838 N... 9601800

00 co CI en co

N C'II

....... 0 o (")~lli~~~~~~~~~~~i~~~~ii~!~~~~~~~~~~ID~ !!~1~


0.2 0.4 0.6 0.8 1.0 1.2 1.4 , I I I I I I

".,NIW

NIN'W

II Lh2h

*---------------------~t~~.~:!~~~:"1":"~--t (9565060)

N'NOW

*II________--r..;~:Lt..~~:~~~~T~--------+Lh23a

(7118330)

.U5935 340435

-N.W

~----------------Dl~----------------_111.27p8.516 I 8.516 11660000

NIW

~-----------------------Dlr.T-------------------------_1111.26P8.8·43 11308000

N,l'iw 1 ______________________~~~~--------------__1"11.25p ... g .3385710 TI

N,J-______________________---::-;:-:-:-:-::1:----,-.llt~;24P

10.4116'" II 10.4014" (9614130)

(96046901

I I I I I I I

V XXI(Li-Sequence)

- 98


0.2 0.4 0.6 0.8 1.0 1.2 1.4 I I I I I I I r

-.... :I .... CJ"I

NI- en N NI'" =en

en 0 ________________________la~-------------------- (11 0~------------------------------~-----------------_--tl,z3p • en



0.2 0.4 0.6 0.8 1.0 1.2 1.4 I I I I I I I

r S

-c.n NNI0)0) _NI'"

Q •8.703 Q N -QQ Cl.C~Jf :J~i n 11906000SNI

NI ... I

Jf n:u~ li 1161S~"48.30 N~7w

1·ln It .882 8.826

N.N''''

If U:~f~ U.38 N~iw

If i:1H

NINIW

If U:nH~ li28.5049 NIW

NINIW NI'"

If ::nH~ l~

NINIW

NI ... N''''

90.234(; .: 89.594c Cl.

NIW NI'"

.Ill

90.'51' 19::;

9.6335

r" P235050 l ~~ ~! 7212670

HUn

NIW N~7w NI'"

11 ~~ :H~:~ ~£41.3808 NIW

N':'7"" NI'"

If :t:~~~~ ~i10.7656 NIW

N' N'''''N'W

If :t~g~~14.·1290" ~~ P217990 S7270940 I I I I

V XXI(Li-Sequence)

- 100

li 11675000

li 11315000 l~ 2n11315000

flSiUUS ~

P0722360 J10720140

HSHUUJ

'po

f9614130 196046901

-

f9632220~9629250

2n f~unu~

I J


1.0 2.0 3.0 4.0 5.0 I

r I I I I

:3 - -c:,n".I!_ en N ... , .... ; _____----::-~....,....------------__+Lh(2S)Z,2(lS)N_'W ~_______ ~ ~ 2.3901:_ _

.:: ~ 2.3864 (42U5000) o:."'W:3 "U- 2

,--------..---------------tLlsh 2 US2~u 2.4408 (41312000)

-

2p

-""_

N,W

t--________________~-----__--__-__+111 1s(2S)2tz,(lpO) 2.3915(; 11

2.3906\; t:: ~ :UU8881 ""

~---------

NIW(2 O)_______________________________________________ __________________________t )282P(3 1S S P

~-----------------------------------------~J~~ie------------------------------------ (41714000)2.3973 (41614000)

-NI_ NIW

-

4p

I I I I I

V XXI(Li-Sequence)

- 101



1.0 2.0 3.0 4.0 5.0 I r I II r

3

c:,n-

CD N NIco CD NI~ • CD

CD = ~l'('S'''''('P''(0= 2'4156~


1.0 2.0 3.0 4.0 5.0 6.0

r 3

& S SI:~ laSa 2 • 2 ~ (S3119800)

liaS. 8.9787 e (53119800)

o

39.0UI: ~ la4a r---t- (519110001

o

. 'po

Cool[:. l L'" " Cu3~\\~~i200) "tJ ( 41982380)

0

+lla5P (53132100] o

81.891: U laSp'""L C 53132100)

2&.0461: ~ laSp ~ (53132100)

llaSp8.81S0 e (S3132100) 1po

·---··----------------------------i788i~--------------------------------1-1a5~53132100)

.......

V XXII(He-Sequence)

- 103


1.0 2.0 3.0 4.0 5.0 6.0 I I I I I

r :3- ....

g;~;:!r-.:I• c.n to) (0 to) -.1 en to) (t 0

~S 0 l

4130' .a1 Ish 1L (51935200)

38.742' ~ lIh ~ (51935200)

37.8""'~ Ish ~ (51935200)

~----------'·---------------------i:-92547-----------------------------1..114 p( 51935200 )

Ipo

....-----------------------------i:-oi;;5~-----------------------------1..1.3~49349800) .,

514.0' .a1 liZ,1L (41982380)

241.84' .u 1.Z,'L (41982380)

~------------------------------2~3ii95i~------------------~112~41982380)

,..------::;"'''_ La4.~:::====~=1s====;--"11L.. 's : 1131 IS

o (51911000)(49354000 )

(41787830] (49292800) [. ~ (415688801 -

38.653' L-.l h4d r--~ (51936900)

+-------+Lh 4 d 10.046c (51936900)

II'" ['3' 'po'po L (41982380) (49349800)

I I I I I I

V XXII(He-Sequence)

- 104


1.0 2.0 3.0 4.0 5.0 6.0 I I I I

,t

8 883Q~ L:: 8.8298 • (5310HOO 1

38.nO c I~ '; 38.567 c +I--l:

(51886700)

9 9634~ L: 9.8965 .. (51886700)

-r--------------------~~~~-----------------_11 Is2.

2.405646 v (41568880)

--..,

(53124400 )(53120000 )

-8l.08 c +-lls5p

(53120000 )

-..,

e25.73gc t--tl,; 2.5.710 ~- ( 53124400)

(53120000) ..,

~'O;:~__.lI.J8•.w.6 >1..15 7 2.,...~--H.... _. 8.6539 (53124400 )(53120000)

.. ......

I I I I I I

V XXII(He-Sequence)

- 105


1.0 2.0 3.0 4.0 5.0 6.0 I I I I I I

r 9- ....

~~ U'l

N • U'I wc:.o W -:/ en w c-.o

1.0


2.0 3.0 4.0 5.0 6.0 I I I I I I

3

~~lUUg8~tS1932700~

--'-

,851S\; ,8S1S"

9.UOO'"

49352200~{ 49344500 49344200

I II I I I

V XXII(He-Sequence)

107



1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 I I I II I I I I r

:I ...... ~ c:r.I(.TI QO(.TI

~N (.TI

c:.:I c:.o c:.:I~ c:r.I c:.:I ClIO

1.0 I


2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 , , ,I I , r"' I I 3

o -N

Sp

L.. Nl

" ... "'0.

-o

+-t-----~=~----+Lh2P2.307S e 0_ (85123000)

N

~:i:!~~ ~~ +-------~2.~29"""2~2...------iH" ~ 85195000 ~ 85123000 85098000

iL-1s2-'-IS---~~

~ ((:11576887888300i (t J I I I I I I I I

V XXII(He-Sequence)

109

_____________________________________ __________________ _

______________________________________ ___________ _


1.0 2.0 3.0 4.0 5.0 6.0 r 3

(56117320)

(56117320 )

-----------------------....-----------------------------------------------~---~:7ii9i~----1-: (56117320)

(5"807770)

(5"807770)

-----------------------------------------------------------------i:iussse'---1-: (5.4807770)N'N'W

(51978720 )

(51978720)N'N'W

1~~-------------------------------------------------------------~-------------------------------------~~ 1.92386

JAERI-DatalCode 97-023


1.0 2.0 3.0 4.0 5.0 6.0 I I I I "1 r-I

:3-- ,...-.:Ic.n

~~ ~ ... -

Documents

AUG 271997 - Fermilab · This report contains all Grotrian diagrams for V IV through V XXIII. The Grotrian diagrams show energy levels and the principal transitions. Typical examples