24
Boiler Cqlculotions A. Whntis equivalent evaporation? Ans It is thequantity of water evaporated from and at 100'Cto produce dry saturated steam at 100"C by absorbing the same anount of heat as usedin the boilerunder actual operating conditions. M"q= Mn (H - Hwt)/539 where M"n - equivalent evaporation Mact = actualmassof steam generated per unit mass of fuel burnt I/ - total specifrc enthalpy of steam under operat- ing conditions, kcaUkg H*, = specific enthalpy of feedwater, kcaVkg Latent heat of dry, saturated steam at 100"c is 539 kcaVkg. A. What is factor of evaporation? Ans, It is the factorto bemultipliedwith thequan- tity of steam generated underworkingconditions to get the equivalent evaporation. Equivalentevaporation - Actual evaporation x (f) or M"n= M*.(f ) or M$(H - Hwt)/539 = M*rf f=(H_H*t)/539 a. Wtut is boiler eftcienq? Ans. It is lhe ratio of theheat load of he generated steam to the heatsupplied by the fuel overthe same period. Heatloadof generated steam = G"(H - H*,) kcaVs where G, = rateof steam generation, kg/s Rate of heat supplied by fuel - Gf X (CV)lkcaVs where Gr - rateof fuel buming, kgls n. .. - G' (H - H*t) 'rnoiler Gf (Cv), = Mnr(H-Hnr)/(U)1 where G"/G1- actual evaporation - M*t O. What is ecornmizer eficiency? Ans. It is dcfined as the ratio of the heat absorbed by theBFW in theeconomizer to theheat supplied by the flue gases in the economizcr, the temperature of flue gases beingreckoned above the temperature of theair supplied to the boiler 6 - MactA@ rleon = MrrCn (@1- @6) where AO - rise in BFW temperature in the economizer M1, = r[&SS of flue gases per unit mass of fuel Cp - sPecific heat of flue gases @f - flue gas temperature at inlet to economizer O"ir - temperature of air delivered to theboiler Ptoblem 6.1 A boiler generates 4.5 t of super- heated steam (500'C,9}kgflcmz abs.) pertonof coal feed. The BFW temperature - 45'C What is the equivalent evaporation from and at 100'C pcr tonofcoal? Solution Specific Enthalpy = 809 kcaVkg

Boiler-Calculation

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Page 1: Boiler-Calculation

Boiler Cqlculotions

A. Whnt is equivalent evaporation?

Ans It is the quantity of water evaporated from andat 100'C to produce dry saturated steam at 100"C byabsorbing the same anount of heat as used in theboiler under actual operating conditions.

M"q= Mn (H - Hwt)/539

where M"n - equivalent evaporationMact = actual mass of steam generated per unit

mass of fuel burntI/ - total specifrc enthalpy of steam under operat-

ing conditions, kcaUkgH*, = specific enthalpy of feedwater, kcaVkg

Latent heat of dry, saturated steam at 100"c is 539kcaVkg.

A. What is factor of evaporation?

Ans, It is the factor to be multiplied with the quan-tity of steam generated under working conditions toget the equivalent evaporation.

Equivalent evaporation - Actual evaporationx (f)

or M"n= M*.(f )or M$(H - Hwt)/539 = M*rf

f=(H_H*t)/539

a. Wtut is boiler eftcienq?

Ans. It is lhe ratio of the heat load of he generatedsteam to the heat supplied by the fuel over the sameperiod.

Heat load of generated steam

= G"(H - H*,) kcaVs

where G, = rate of steam generation, kg/s

Rate of heat supplied by fuel - Gf X (CV)lkcaVswhere Gr - rate of fuel buming, kgls

n. .. - G' (H - H*t)'rnoiler

Gf (Cv),

= Mnr(H-Hnr)/(U)1

where G"/G1- actual evaporation - M*t

O. What is ecornmizer eficiency?

Ans. It is dcfined as the ratio of the heat absorbedby the BFW in the economizer to the heat supplied bythe flue gases in the economizcr, the temperature offlue gases being reckoned above the temperature ofthe air supplied to the boiler

6 - Mac tA@

rleon =MrrCn (@1- @6)

where AO - rise in BFW temperature in theeconomizer

M1, = r[&SS of flue gases per unit mass of fuel

Cp - sPecific heat of flue gases

@f - flue gas temperature at inlet to economizerO"ir - temperature of air delivered to the boiler

Ptoblem 6.1 A boiler generates 4.5 t of super-heated steam (500'C,9}kgflcmz abs.) per ton of coalfeed.

The BFW temperature - 45'CWhat is the equivalent evaporation from and at

100'C pcr ton ofcoal?

Solution

Specific Enthalpy= 809 kcaVkg

Page 2: Boiler-Calculation

82 Boller Operolion Englneedng

Sensible heat of feedwater at 45"C - 45 kcal/kg ̂Heat required to produce 4.5 t steam (90 kgflcm'

abs.,500"C)

= 4.5 x f03 x (809 - 45)

= 3 438 x 103 kcal

Ijtent heat of dry, saturated steam at 100'C

- 539 kcaVkg - 539 x ld kcaUt

Therefore, equivalent evaporation from and at100'c

3 438 x td tcat= __:_ _ 6.379 t per ton of coal539 x 105 kcat/t

Ans.

Problem 5.2 A steam boiler generates 7.5 tons ofsteam per ton of coal burned. Calculate the equivalentevaporation ftom and at 100'C per ton ofcoal fromthe following data

Steampdssure - 10 kgflcm2. abs.Dryness fraction - 0.95Feedwater temperature - 50"C

fulution Working formula

Mg(H - H*,)M.s=-B-

Mnr- 7'5 Ut of coal

"*,'S kcaUkg - 50 x 103 kcaVt

Hr" = 181.3 x 103 kcal /t

.r - 0.95L-483x 103kcaVt

H = H* + x L =t181.3 + 0.95 (483)l x 103

= 640 x lG kcal/t

M.n=1.5 (6<O.tS - 50) x rc3/fi9

= 8.211 t of steam/t of coalAns.

Problem 6.3 A boiler is working at 14 bar andevaporates 8.5 kg of water per kg of coal fired fromBFW entering at 39"C. Determine the equivalentevaporation fromand at 100"C if the steamis 0.96 dryat the stop valve.

Solution The equivalent evaporation from and at100"C is

M"q=Mn (H-Hwt)/Lrco

Now

Mrct- 8.5 kg steam Per kg of coal

H*r'163'4kl&;g

H,r, - 830 kJ/kg (at 14 bar)

-r - 0.96

L - 1957.7 kJ&g (at 14 bar)

H = H w + x L

= 830 + 0.96 (1957.7)

=27W.39kJ/kg

Itoo - 2257 klkg

M"q = 8.5 Q7w.39-163'4)/2257= 9.588 kg stearn/kg of coal

= 9.59 kg steam,zkg of coalAns.

Prcblem 6.4 A boiler produces 220 t o^f drysaturated steam pcr hour at a pressure 60 kgflcm', abs.from feedwater at a temperature of 120"c.

Coal consumption - 1200 VdaYCalorific value of coal - 42O0 kcaVkg1% of coal escapes unbumt.Determine(a) the equivalent evaporation per ton of coal

fred(b) the eff,rciencY of the boiler(c) the overall efficiency of the boiler

SolutionStep (I) Heat l-oad of Steam/Ton

inrhalpy of dry, saturated steam at 60 kgflcm2 abs.:665.4 kcaVkg

Enthalpy of water at 120"C = 120 kcaVkgTherefore, heat required to raise I ton of steam

= td (66s.+- l2o) = 545.4x 103 kcal

Step (II) Equivalent EvaPorationCoal consumption - 1200 VdaY = 59 Y6Steam gencrated per ton ofcoal fred-22U50 - 4.4t

Page 3: Boiler-Calculation

Therefore, equivalent evaporation

= 4.4 (545.4 x to3)

539 x 103- 4.452 ton of steam/t of coal

Ans,Step (IID Boiler Efficiency

Energy output =220 (545.4 x 103) kcaVhCoal charged to the boiler = 50 t/hActual coal bumt - 50 (l - l/lm) - 49.5tJhTherefore, energy input - 49.5 x I 03 (4200) kcaUh

_ 220 (s4s.4x rd)'rboiler - 49.5 x lo3 x42oo

= 0.577 i.e. 57.7VoAns.

Step (IV) Overall Efficiency of the Boiler

r- 1 220 (545.4x t03)r - -

L'rboilerl- 5ox lo3 x42cn

= 0.5713

= 57.137oAns.

Problem 6.5 A boilerconsurrc,s224tons of coalto produce 1864 tons ofsteamperday. The steam isdry, saturated at 90 afrrr abs. Calculate the boilerthermal efficiency, and the equivalent evaporationper ton of coal if the calorific value of coal is 5400kcal/kg of coal, the specihc enthalpy of feedwaterbeing a25.036 U/kg of water.

SolutionStep (I) Rate of Evaporation

Mass of steam produced - 1864 tonMass of coal consumed -224tonActual evaporation capacity = 1864/224

= 8.321 t /t of coalStep (II) Equivalent Evaporation

Evaporation capacity, M^= 8.321tlt of coal

Sp. enthalpy of dry, satd. steam (90 atm. abs.),

H =2705kJ/kg

=2705 x t03 kJttSp. enthalpy of BFW, Hw = 425.036W1k1

= 425.036 x l0r U/t

Boller Colculoflont 83

Equivalentevaporation, M"= M^(H - H)/L= 8.321 (2705 - 425.036) x r03 /Q257 x t}l)- 8.405 ton stearn/ton of coal

Ans.Step (III) Boiler Thermal Efficiency

Working Formula: Boiler ttrermal efficiency- energy to stearn/energy from fuel

Energy to steam

= 8.32r (2705 - 425.03Ox t03 U

Energy from fuel

= 5400 x t03 kcavt ofcoal= 5400 x 4.1868 x 103 kJ/t of coal

B oiler thermal effi ciency

_8.32r (2705 - 425.036)x rO35 4 0 0 x 4 . 1 8 6 8 x 1 0 3

= 0.8391=83.91%

- 8 4 %Ans.

Problem 6.6 A boilersenerates 7.5 tons of steamper hour at 18 bar ( 1 b; - td ttlm2. The steamtemperature is 598K and the feedwatertemperature is328K.

When fired with oil of calorific value 47 250kJkg,the boiler plant achicves an efficiency of 85%.

The generated steam is fed to drive a turbine whichdevelops 0.75 MW and exhausts at 1.8 bar, the dry-ness fraction of the steam being 0.97.

Determine the rate of fuel consumption and thefraction of enthalpy drop, through turbine, convertedto useful work.

If the turbine exhaust is directed for process heat-ing, estimate the heat transfer available per ton ofexhaust steam above 322.4K.

SolutionStep (I) Energy to Raise Steam

Specific enthafy of generated steam= 3 106 - 0.84(3 105 - 3083)= 3 086.6 kJAg (by interpolation)

Specific enthalpy of BFW at 328 K

Page 4: Boiler-Calculation

&1 Boller Operotlon Englneedng

-230.TlakJkE

Specific energy to nrise steam= 3086.68 -230.274

=2 856.4kJ&g.

Step (II) Rate of Fuel Oil ConsumptionRale of steam generation -7.5 tlh - 7500 kg/hsp. energy to raise steilrl - 2856.a kJ&gEnergy input to steanr/h - 7500 (2 856.4) kJ

Boilerefficien"y=:ry4Energy from fuel./h=85*�= 0.85

Rate of firel consumption (Energy from oiVh)

- 7500 Q856.4Y (0.85)(47250)- 533.408 kg

Ans.

Step (III) Rate of Sp. Enthatpy Drop in Turbine

Sp. enthalPY of exhaust steam'

H 2 = H n + x ' L

= 49O.7 + 0.97 Qzrl)=2635.37 kJ/kg

Sp. enthalpy of inlet steam, Hr - 3086.68 kJlkg

Sp. enthalPY droP in turbine,.

A , H = H t - H z

= 3086.68 -2635.37

= 451.31 kJAg of steam

Steam feed - 7 .5 tlh - 7500/3600 kdsRate of sp. enthalpy drop in turbine

- 451.31 (7 500/3 600) kJ/s

-940.229kJ|s

Step (IV) Fraction of Enthalpy Converted to Use'

fulWorkEnergy output ftom turbine-0.75 MW- 0.75 x 103 kw- 0.75 x 103 U.zsRate of enthalpy drop in turbine '94O'229 kJls

Fraction of enthalpy drop converted to useful work

- 0.75 xro3/90.229- 0.7976 - 0.8

Step (V) Heat Transfer Available in ExhaustSteam Above 322.4K

Sp. enthalpy of exhaust steam - 2635.37 kJftgSp. enthalpy of water at322.4 K = 207 kJ/kBHeat transfer available in exhaust steam above

322.4K-2635.37 -207

-242E.37 kl/Kg Ans.

Problem 6.7 The following observations weremade in the case of a boiler fitted with an economizen

Rate of steam generation - 5 Vt of coalEquivalent evaporation from and at 100'C= 5.5 Vt of coalBoiler feedwater temp. inlet to economizer= 100"CTemperature of BFW inlet to boiler - 180"CTemlrrature of air supplied to the boiler - 30'CTemperature of flue gases entering the economizer- 4O0"CWeight of flue gases produced per ton of dry coal= 1 5 tMean specific heat of flue glses - 0.20 kcaVkg "C

Calorific value of coal - 5400 kcal/kgDetermine(a) the boiler efficiencY(b) the economizer efficiencY(c) lhe combined efficiency of the whole plant

SolutionStep (I) Heat OutPut

Steamgeneratedfromandat 100"C- 5.5 Vtof coal

burntTherefore, heat output = 5.5 x 10' (539) kcaVt of

coal burntStep (II) Heat InPut

Calorific value of coal * 5400 kcaVkgTherefore, heat input - 5400 x l0r kcaVt of coal

burntStep (lII) Boiler EfficiencY

Heat Otttotrt 5.5 x l0' (539)I . . . =l lboiler- Heatllput

- 54O0x 103

= 0.5489 i.e. 557o (approx)Ans.

Step 0V) Heat of Flue GasesHeat of the flue gases entering the economizer

Page 5: Boiler-Calculation

= 15 x 103 (0.20) (400 - 30)kcayt= 111 x t04kcaVtofcoal

Step (V) Heat Absorbed by BFW in theEconomizer

Heat absorbed by BFW in the economizer= 5 x ld (180 - 100) kcaVt of coal=40x t04fcaUtofcoal

Step (VI) Economizer Efficiency

I"-o = (e0 x t04 )/(ttl x 104)-0.3603 i.e.36%

step (vII) combined Efficiency Ans'

Heat absorbed in the boiler- 5.5 x ld (539)kcaVtofcoal

Heat absorbed in the @onomizer - 40 x 104 kcaVtofcoal

Total heat absorbed in boiler and economizercom-bined

- 5.5 x 103(539) + 40 x loa- 336.45x 104 kcaVt of coal

Energy released by burning co3l - 5a00 x ldkcaVt ofcoal

n^^-. = 336'45 x lOa -0.623 i.e.62.30%'rcornD 5aoo x ld

Ans.

Problem 6.6 A boiler produces steam at 90kgttcn? abs. at the rate 150 t/h from the feedwater at120"C. The steam is dry, saturated. What is the boilerhorse power?

Solution

Steanr,90kgflcm2abs. Dry,sanrrated Total heat - 655.7 kcal/kg

Sensible heat of BFlv at 120'C - 120 kcaVkgEquivalent evaporation from and at 100'C

- 150 x 103 (655.7 - t20)/539

- 149.08 x td fgnTherefore, boiler horse power

= 149.08 xrc3/$.653=9524.15

Ans.

Boller Cslculollonr 85

Boiler Horse Power is a very commonly used unitfor measuring the capacity of a boiler. ASME(American Society for Mechanical Engineers)defines a unitboiler horse power as the boilercapacityto evaporate 15.653 kg of BFW per hour from and at373 K into dry, satunted steam or equivalent inheating effect

Boiler h.p. - Equivalent evaporation from and at373"K per hour/l5.653

Problem 6.9 Aboilergenerates 6.5 tof steamperton of coal fired.

The steam is at l8 kgflcm2 gaugeThe boiler feedwater temperature - 110"C

downstream of deaeratorBoilerefficiency -75%Factor of evaporation - l.l5Co of steam - 0.55 kcaVkg "C

Determine(a) the tempcratxre of the steam(b) thedegree of superheat, if any(c) the equivalent evaporation per ton of coal

burnt(d) thecalorific value ofcoal

SolutionStep P (I) Steam Parameters

Pressure - 19 kgf/cm2. abs.Sensible heat, I/* - 213.1 kcakg

l,atent heat, L-455.1 kcaVkgSatrrration temp., @" - 20E.E'C

Step (II) Degree ofSuperheatTotal heat of the steam - Hw + L + Co AO

where, AO - degree of superheatSp. enthalpy of feedwater - Hrw

Therefore, the factor of evaporation

_ H * + L + C o L / g . - H r *

or 1.15 =

539

213.1 + 455.1 + 0.55 (AO) - l l0539

AO= 112.09"CAns.

Step (III) Superheated Steam TemperatureAO - lrz.Ogrc

Page 6: Boiler-Calculation

86 Boller Operollon Englneerlng

or , @-@"-112.09"C

or O=208.8+ 112.09= 320.89'C -321"CAns.

Step (IV) Heat OutputHeat required to generate stearn= 6.5 x ld (213.1 + 455.r + 0.55 AO - 110)

kcaVt of coal

= 6.5 x 103 (558.2 + 0.55 x 112.09) kcaVt of coal

= 4029.021x 103 kcavt of coal

Step (V) Heat InputCalorific value of coal - CV kcaVkgEnergy released per ton of coal burnt

- 103 x CV kcal

Step (VI) Boiler Efficiency

11. .. HeatoutDut -4029'o2lxlo'''borrer=E;ffi ld x cv

or 0.75 - 4029.021 ICY;

CY - 5372 kcaVkg ofcoalAns.

Step (VII) Equivalent Evaporation

6.5 (2r3.r + 455.1 + 0.55 x 112.09 - 110),r"q =

= 7 .474 t/t of coal bumtAns.

Prcblem 6.10 fbe following observations weremade during the trial run of a boiler.

Steam generation rate = 16 UhFeedwater temperature = 30"CSteam qualitY = 0.9 drySteam pressure - 15 kgflcm' abs.Coal consumption = 2.5 t/hCalorific value ofcoal = 6540 kcaVkgAsh + unburnt coal collected from beneath the

grrtes = 0.2llh (Calorific value - 700 kcal/kg)Weight of flue gts€s = 15 Vt of coal fredFlue gas temperature - 350"CAverage specific heat of flue gases = 0.25

kcaVkg'CAmbient air temperature - 25"CCalculate(a) the boilerefficiency(b) the percentage of heat loss to the flue gases

(c) the percentage of heat loss to the ash(d) the percentage of heat loss unaccounted for

SolutionStep (I) Steam Parameters

Sensible Heat,If* - ?frO.1 kcaVkg

l---Latent Heat, L - 466 kcakg

Step (II) Heat Output RateRate of stearn generation - 16 t/hHeatoutputrate= 16x t03 (H, +xL-Hp)

= 16 x 103 (200.7 + 0.g x 466 -30)

=9441.6x 103 kcaUh

Step (III) Heat Input RateCoal consumption - 2.5 UhCalorific value ofcoal = 6540 kcaVkgHeat input rate =2.5 x 103 x 6540 kcaVh

Step (IY) Boiler Efficiency

Iboiler = Heat output rate,/Heat input rate

= 9441.6x 103/Q.5 x 103 x 6540)=0.5774 i.e. 57.74V0

Ans.Step (V) Heat Load of Flue Gases

Flue gases generated - 15 Ut ofcoalHeat load of flue gases

= 15 x 103 x 0.25 (350 - 25)

= 1218.75 x ld kcaVt of coalStep (VI) Heat Generated By l Ton of Coal

Heatproduced by ltofcoal - 103 x 65210 kcal

Step (VID Percentage of Heat llss to Flue Gases

= Ir2t8.7 5 x r03 / 651CIx l03l (100)= 18.63%

Ans.Step (VIID Percentage of Heat Loss to Ash

Ash + unbuntt coal collected - 0.2 VhHeat loss due to ash + unburnt coal

=0.2x ld x 700 kcaVh

Heat gencratcd in the fumace=2.5x ld x 654O kcaVhTherefore, percentage of heat loss to ash

0.2 x 103 x7ffi ,__________ . _ rl00)=0.85%2.5 x 10'x 6540

Ans.

Page 7: Boiler-Calculation

Step (IX) Percentage of Unrccounted HeatUseful beat- 57.74%Heat lost to flue gases - 18.63%Heat lost to ash - 0.85%Total rccounted heat = 57.74+18.63+0.85

--77.22%.

.'. Unaccounted heat - 100 - 77.22 - 22.77 %Ans.

Ptoblem 6.ll A boiler genentes 75 t of steamper hour at pressure 1.8 MN/h' and temperature325'C ftom feedwater at 49.4"C. When fircd with oilof caiorific value 45 MJftg, the boiler attains anefficiency of 78%. The steam (325'C, is fed to ahubine that develops 650 kW and exhausts at 0.18I\,N/m2, the dryness fraction of steam being 0.95.

Determine(a) the mass of oil fired Per hour(b) the fraction of the enthalpy drop through the

turbine which is converted to useful workAlso determine the heat transfer available per kg

of exhaust steam above 49.4"C, if the turbine exhaustis used for process heating.

blutionStep (I) Specific Enthalpy of Generated Steam

H =3rM - 0.84 (3106 - 3083)

= 3086.45 kJ/ke by interpolation)

Step (II) Specific Enthalpy of BFW (49A"C)

Hr*=2A6.9tJ�/lrg

Step (IID Heat OutPut

Energy required to generate steam

= 3086.45 -206.9

=2879.55kJftg

The rate of steam generation - 7.5 Uh

.'. Heat ouput =7.5 x 103 x2 879.55 U/h

Step (IV) Rate of Oil Burning

I.et the mass of oil fired be fi vgn

Heat input - Ifr x 45 x 103 U/h

Boilerefficierc! =78%

0.78 = Heat ouput/Heat input

Boller Cdculctlonr 87

=7.5 x rG x2879.55/tfr x 45 x ld

rt =firlkelh

Step (V) Specific Enthalpy Drop in TurbineSpecific enthalpy ofelhaust steam

- H* + x L - 490.7 + 0.95 (2210.8)

- 2590.96 U/kg

.'. Specific enthalpy drop in turbine

= 3086.45 -2590.96

= 495.45kl/lrg

Step (VI) Rate of Enthalpy Drop in TurblneRate of steam fed to turbine

-7 .5 l lh

- 7.5 x 1d/3600 kgs

Specific enthalpy drop in h[bine - 495.45kJlkg.'. Rate of enthalpy drop in turbine

= 495.45 (7.5 x 1dl3600) kJls

= 1032.187 U/s

Step (YID Fraction of Enthalpy Drop Convertedto Useful l{ork

Energy outprt from trbine

- 650 kw- 650 kJ/s

Energy inputto turbine - 1032.187 U/s.'. Fraction of enthalpy drop converted to useful

work- 65Cl/1032.187

-0.629Ans.

Step (VIID Heat Transfer from Exhaust SteamThe net heat available, for process heating, from

exhaust steam above 49.4"C - ?59O.96-?n6.9 -

2384.06kI/lr9Ans.

Pr<iblem 6.12 A steam generation plant supplies8500 kg of steam per hour at pressure 0.75 MN/m".The steam is 0.95 dry.

Feedwater temlrnture = 41.5"CCoal consumption - 900 kg/h

Page 8: Boiler-Calculation

88 Bolbt Operollon Englneedng

Calorific value of coal -32450kJilrgDetermine(a) theboilerefficiency(b) the equivalent evaporation from and at 100"C(c) the saving in fuel consurnption, if by installing

an economizer it is estimated that the feed-water ternperatue could be raised to 100"C,assuming that other coditions rcmained un-changed and the efficiercy of the boiler in-creases by 6%.

blwionStep (I) Steam Generation Fer Ton of Coal

Rate of steam generation- 8500 kghCoal consumption - 900 kg/hTherefore, steam generation per kg of coal- 8500/900- 9.44 kg

.'. St€am generation/ton of coal- 9440 kg-9.44t

Step (II) Specific Enthalpy of Steam Rais€d

H -- H* + x L [email protected] + 0.95 (2055.5)

=2662.025kl/kg

Step (III) Energr Required to Generate SteamSpecific enthalpy of steamraised-262.0?5kr/ltg

Specific enfhalpy of BFW - l139kJ/lKE

Hear ouput = 26tr2025 - 173.9=2488.125 kJAg of steam

Step (IV) Boiler Efficiency

_ Heat outDut/ks of coal 2488.125 ,^tl*r",=ffi#ff=ffi(g.u't=0.7238 i.e. 72.38%

Ans.Step (V) Equivalent Evaporatbn

Steam raised per kg of coal - 9.4k9Energy required to gerrcmte this steam-9.44 (2488.125) U&g coal

Specific enthalpy of evaporation frorn and at

100"C - 2?56.9kJft:g.

Equivalent evaporation = 9.44Q488.125>/2?56.9= 10.40 ke/ke of coal

Step (YI) Energy Required to Generate SmUnder New Conditions

Specific enthalpy of BFW at 100'C - 419.1 U/kgEnergy required to generate steam when

econqnizer is incorporated

-2662.U25 - 419.1

-2242.9?5Wfrg

Energy to steury'h=2242.925 x 8 500kJ

Step (VII) Rate of Coal Consumption whenEconomizer is Fitted

Erergy output -2242.98 x 8500 kJ/h

Energy input- Ifr x32a50Hth

Boiler efficiercy -72.38 + 6 -78.38%

2242.Y25 x 85000.7838 - Nl x32450

rt =749.57 kglhStep (VIII) Saving in Fuel Consumption

Initial fuel consumption rate - 900 kg/hModified fuel consumption rate when economizer

is fiued -749.57 kglhSaving in frcl consumption = 900 - 749.57

= 150.43 kg coal,zhAns.

PtoHem 6.13 The following obsenations weremade during tbe trial run of a boilen

Rate of steam generation = 5 Uh

Steam quality: dry, saturated

Steam pressure = l0 kgf/cm2 gauge

Average specific beat of steam - 0.55 kcaUkg. "C

Redwater ternperature - 85'C

Room ternperature - 25"C

Atnospheric pressure - 1 kgflcm2

Fuel consumption - 650 kg coaVh

Calorific value ofcoal - 7500 kcaVkg ofcoal

Page 9: Boiler-Calculation

Moisture content of coal -2.5%Fuel contains: C - 86%: H - 5%: Ash - 9%Flue gas temperature - 300"CMean sp. heat of flue gines - 0.25 kcaVkg "C

Analysis of dry flue gases:

C O z - l 0 % ; O 2 - 8 % ; N 2 - 8 2 %Produce a complete heat balance sheet taking I kg

dry coal as the basis.

SolutionStep (I) Energr to Steam Per kg of Dry Coal

Steampressure = l0 kgf/cn? garye

= l1 kgflcm2 abs.

Sensible heat of steam at 1l kgflcm2 abs.- 185.7 kcaUkg

Latent beat ofevaporation at 1 I kgflcm2 abs.- 478.4 kcaVkg

Specific enthalpy of dry, saturated steam generaEd

- 185.7 + 478.4- 664.1kcal/kg

Specific enthalpy of feedwater = 85 kcal./kgCoal consumption- 650kdhDry, coal consumption = 650 (100 -2.r/lm

= 650 x 0.975kg/h

Energy to steam/kg coal- (664.r _ 85) (5000)/(650 x 0.975)- 4568.836 kcal

Step (II) Flue Gas Analysis

Basis: 100 m3 of dry flue gas

Boiler Cqlculqlions 89

Step (III) Coal AnalysisBasis: lkg dry coal

Constitu{hemicalReaction Remorksnt during combustion

C + O r - + C O ,(r2) (44)

ur+)or-+ Hro

(2) (18 )

WL of moisture fired=0.025/0.975= 0.02564 kg/kg of dry coalTotal wt. of water vapour in flue gases- 0.45 + 0.02564= 0.4756 kg/kg of dry coal.

Step (IV) Heat L,oad of Water Vapour= 0.4756 [638.8 + 0.55(300 - 90) - 251=344.5 kcaVkg of dry coalwhere 638.8 kcaVkg = total heat of water vapour

at I kgflcm2 abs. to which flue gases arc discharged

Step (V) Heat Load of Dry Flue Gases

Heat loss to flue gases

=24.741(0.25) (300 - 25)= 17N.944 kcaVkg of dry coal

Step (VI) Heat BalanceBasis: I kg of dry coal

Wt. of dry flue gasproduced- (2992n04)(86trm)- 24.741 kglkg of coalWt. of water vapourproduced- (18/2)(5/ loo)-0.a5kglkg of dry coal

Con-stituent

Volume-3

Mol.v,t. ProportionalMass

Remarks

coz

o2

10

8

82

44

32

28

44(lO)= 440

32(8\ -2s6

28(82) -229<

Carboncontent

= 410(12/44)= l2O

100 t04 2992

Heat Input % Heat Expenditure 7o

Total hcatsupplied- 7500 kcal

t00 Ijcat consumed in stearnfonnation- 4568.836 kcal

Ileat lost to flue gas- 1700.944kcalHeat lost to vapour- 344kcalHeat unaccounted for- 886.220 kcal

@.92

22.70

4.ffi

I 1 .80

7 500 kcal 100 7 500 kcal 100.00

Page 10: Boiler-Calculation

90 Bolter OPerollon Englneedng

Prcbtem 6.t4 During the tial run of aboilerthe

following data were recorded

(ii) suPerbeater(iii) air heater(iv) economizer

(e) heat lost in the flue gasSummarize the overall result on the basis of I kg

coal burnt.

SohttionStep (I) Theoretical Air Requirements

Basis: 100kg coal

Coal consumPtionSteam producedBoiler:Steam Pressure

Steam temPeraturcSuperheater:Superheated steam tempcratureEconomizer:Water inlet temPeratureWatelr outlct tcmPeratureAir heater:Air inlet temPeratureAir outlet temPeratureFIue gas inlet temPeratureFlue gas outlet temPerature

83.1 t606 t

1.461MN/m2-14.42^tn470 K

610 K

353 K400 K

320K380 K503 K405 K

Constituenl % WElement Weight

Molecular klmol

Weight

kmol of Otrequircd forcompletecombustion

62.54.25

5 . 1 It .2

cH

oN

t22

322832

IE

5.2082.r25

0.159o.o42o.o27

5.2082.12512

- 1.0625(-) 0.lse

o.027

E - 6.1385cHoNsAshMoisture

62.5%4.25%5. t t%t2%o.85%9.85%

16.24%

Coal analysis (bY weight) Fluc gas analYsis (drY basis)

13.2% (by volume)4.85% ( -do- )

81.95% ( do- )

Total rco%

S 0.85Ash 9.85Moisture 16.24

There, theoretical air requirement

= 6.1385 (100/21)

49.23 kmoV100kg coal

=29.23 (28.9) k9100 kg coal

=844.744 kglm kg coal

=8.447 kgftg of coal AnS.

(c/ The average molecular weight of air is 28'9)

Step (II) Actual Air SirPPlied

100 kg coal contains 5.208 kmol of C100 kmol of dry flue gas contains 13.2 kmol of C

Therefore, the amount of flue gas produced

- 5.208 (100/13.2)

=39.45 kmoV100 kg coal

Let r mol of air be supplied per 100 kg of coal

burnLtherefore by nitogen balance we get'

79 x 4ffi + 0.042- H (39.45)

cozo2N2

Gross calorific value - 30550 kJftg (dry coal)

Boiler house temPerature = 298 KEnthalpy of dry, saturated steam at 1.451 MN/m2=2791L<IkE.

Substances S p e c if c H e ats (kJltg'K)

Dry flue gasWater vapor in flue gasWater

1.0052.0954.t81

Determine(a) theoretical air requirements per kg of coal(b) actual air supplied per kg of coal fred(c) weight of flue gas per kg of coal bumed(d) thermal efficiencies of

(i) boiler

Page 11: Boiler-Calculation

coz

o2

N2

.'. .r - 4O.87 kmoU100 kg coal

Therefure, the weight of air supplied- 40.87 (28.9)

- l l8 l . l4kg/ l00kgcoal- 11.81 kgfu coal

Nore % excess xi1= (ll.8l -8.47)(tU.,/8.#

=39.81%

Step (III) Weight of Flue GasBasis: 100 kmol

Fluc Gas koiol Mohca- WcightConslitaen lst Weight

Wcight in39.45kaolof Fluc Gas

r3.2 4

4.85 32

81.95 28

13.2(44) 13.2(,14X39.45/100)-229.t25

4.85(32) 4.8s(32)(3e.4sll m)- 61.226

8 1.95(2E) 8 l.9s(28x39.4sl IOO)= 905.219

E= il95.57 k9

Water produced due to combustion of hydrogencontent ofcoal

-2.18 kmol - 2.125 (18) - 3E.25 kg

Free moisture - l6.24kgTherefore, the total weight of wet flue gas- 1195.57 + 38.25 + 16.24- I 250.06 kglm kg coal- 12.50 kgltg coal

Step (IV) Thermal Efliciencies Ans'

l. BoilerTotal heat content of steam at 1.461 MN/m2-279lkItkg

Total heat content of water charged to boiler=4.187 (4N-273)

= 531.749 U/kg

Therefore, the net heat tansfened to steam=2791- 531.749

Boller Colculollonc 9l

-2E9.25lU.kg

Rate of steam generation/t of coal=66/83.1r/t

-7 .292 Vt of coal (or kJlkg coal)

Therefore, the heat transferred to steany'kg of coalburned

=7.2V) (2259.251)

= 16474.458 kJ./kg coal

Gross calorific value of coal as fired= 30550 (100 - 16.24)/100= 25588.68 kI/kg coal

Therefore, thermal efficiency of the boiler= 16474.458/25588.68= 0.6438 i.e. 64.38%

2. SuperheaterAns,

Net heat tansferred to steam in the superheater=7.2T2 (2.095) (610 _ 470)=2138.74 kJ/kg coal

Therefore, thermal efficiency of lhe superheater= 2138.7 4/25588.68= 0.0835 i.e. 8.35%

Ans.3. Air HeaterWeight of air charged to the boiler- 11.81 kJ/kg coal

Heat absorbed by air in the air heater= 11.81 (1.005X380 - 320)=712.143 kJ/kg coal

Therefore, the efficiency of the air heater

=712.143/25588.68

= 0.0278 i.e. 2.78%Ans.

4. EconomizerHeattransfcncd to BFW

=7.292 (4.187X400 - 353)

: 1434.985 kJ/kg coal

Page 12: Boiler-Calculation

92 Boller Operotlon Englneedng

Therefore, thermal efficiency of the economizpr

- r434.985t25 588.68

:0.0560 i.e. 5.6VoAns.

Step (V) Heat Lost to the Flue Gas

Weight of the dry flue gas

= 11.95 kJ/kg coal

Enthalpy of the dry flue gas

= 11.95 (1.005) (405 - 298)

= 1285 U/kg coal

Water content in flue gases when 100 kg coal burnt

-38.25 + 16.24= 54.49k9

Therefore, the weight of water vapour/kg of coalburnt

- 0.5,149 kg

Therefore, the enthalpy of water in the flue gases

=0.5M9 t2.095 (405 - 311*) +24t1.2*

+ 4.187 (405 - 298)

= 1665.29kJ/kgcoal* fDew Poittt ofWet Flue Gasl

kmol

- (29 50.29 t?55 88.68)( 1 00)= 1L.52%

Tabulation of Result (Basis: I kg coal bumed)

Heatrecovered %GCV % Elficiency(kJ) t^,ct coal

BoilerAir HeaterSuperheaterEconomizerHeat to flue gasHeatunaccounted

r5762712

2t39r43529fl259r

61 .5912J8 |8.36 rs.6 lJ

I l.53\1o. t3 i

78.34

21.66

>- 100.00

Flue GasConslituent

%Composition

ProUem 5.15 A boiler generates 6000 kg steamper hour at 10 kgf/cnt2 from BFW at 4O"C. The steamis 0.97 dry. The boiler is fired with coal at the rate of700 ke/h using 16 kg ofair (at 15'C) per kg ofcoalfired.

Assuming tlre boiler efficiency to be 70%, deter-mine

(a) excess air coefficient(b) flue gas ternperaure leaving the boilerGivenThe coal is composed of carbon and hydrogen

besides its ash contcnt12%.

Combustion Heat Of Combustion

cozo2N2

Hzo

(13.2/100x39.4s) - s.2(4.82/lm)(3e.4s) - l.e(8 1.95/ 1 00)(3e .4s) - 32.33

54.49t18 -3.02

=242.46

C + O r - r C O ,Hr+ Or-+ H, O

8075 kcaVkg ofcarbon34500 kcaVkg of hydrogen

12.24

4.47

76.13

1 . t l

> - 99.95

Therefore, the vapour pressure of water vapour- (7.ru99.9s) (101.3)=7.z}kN/m2

which corresponds to the dew point 311'K andlatent beat of evaporation 241 1.2 kJ kg

Therefore, the total heat lost to flue gas

- 1285 + 1665.29=2950.29 kJ/kg coa.

Hence, the percentage of heat lost to the flue gas

Specific heat of flue gas - 0.25 kcaVkg 'C

18% of total heat generated by coal is lost tosubstances other than coal.

SolutionStep (I) Heat Content of Generated Steam

H = H w + x L - H r n

= 181 + 0.97 (482) - { = 608.54 kcal/kgStep (II) Calorific Value of Coal

It can be determined from the boiler efficiencvrelationship.

Iboil", = Heat outpuvHeat input

Now Heat Output = 6000 (608.54) kcaVh

Page 13: Boiler-Calculation

Heat input - 700 x CV where CV - calorif,rc valueofcoal

or 0.70 - 6000 (608.54)/(700 x CV)

CV - 7 4l?kcallkg

Step (IID Carbon and Hydrogen Contents of'CoalBasis: I kg coalTherefore, the coal contains (l - 0.12), i.e.

0.88 kg ofC + H per kg ofcoal fired.

If .r be the part of CYkg of coal, then

.t (8075) + (0.88 - -rX3a500) =7452

.r = 0.8669

lc-"'b* l*lHyd'os;lI kg Coal 0.8669 kg 0.0131 kg

Step (IV) Theoretical Air Requirement for Com-plete Combustion

Basis: I kg coal

Elzment

Boller Colculqllonr 93

Heat Rcceivcd by(kcaVh)

by coal: 70{l,Q452)- 521640,0

Flue gas: 16.88(700X0.25XA@)- 29s4(A@)

Steam: 6000(608.54) - 3651240

Sirbstances other than flue gas:7 OO(7 4s2)(O.r8) - 9389s2

By heat balancing

2954 (A@) + 365Qa0 + 938952 - 52164A0

. ' . AO=211.98"C *212C

Hence the ternperature of the flue gas atthe bileroutlet

-212 + L5 -227'CAns.

PtoUem 6.16 A boiler is fired with coal havingfollowing percentage composition by mass:

C45Vo; H-54o; S-lVo; O-2.59o: Incom-bustible-6.5%.

Determine the boiler efficiency from the givendata:

Excess air supplied = 407oFlue gas temperature at boiler exit = 170"CAmbient air temperature - 25"CSpecific heat of flue gas - 0.25 kcaVkg 'C

Specific heat of steam = 0.48 kcaVkg"C

Heat Generated(kcaVh)

CombustionReaction

Weight OrRequirement

C + O, -+ CO, 0.8669 kg(r2) (32)

2H, + O, + 2HrO 0.0131 kg(4) (32'�)

o.E669QAn)-2.3rr7 kg

o.or31(32t4)- 0.1048 kg

E - 2.4165 kg

Combustion Heat of CombustionSince air contains 23% Oz by mass, thestoichiometric (theoretical) air requirenrnt for com-plete combustion

-2.4165 (100/23)

= t0.506 kg

Step (V) Excess Air CoefficientExcess air coefficient = Actual air,/minimum air

= 16/10.506= I.523

AIlr.Step (VI) Enthalpy of Flue Gas

Mass of coal + mass of air = Mass of flue gas(1 - 0.12) kg + 16 kg = Mass of flue gas

or Mass of flue gas - 16.88 kg.

Unaccounted heat loss - lSVo

SolutionStep (I) Calorific Value of Coal

Cv - 8075(c) + 2220(5) + 3a500(H- O/8)

where, C, S, H & O stand for carbon, sulphur,hydrogen and oxygen percentage.

- 8075(0.85) + 2220(0.0r)+ 3a500(0.05 - 0.025/8)

- 8503 kcaUkg

C + Or--+ CO,

S + Or---r SO,

H, + Or----+ HrO

8075 kcaVkg

222Okcdlkg

34500 kcaVkg

Page 14: Boiler-Calculation

94 Boiler Operolion Englneerlng

Step (II) Stoichiometric OxygenBasis: I kg fuel

Element Oxygen Rcquircd PerKg of Fuel

C + Or --r COt(r2) (32)

S + O, ----+ SOt(32) (32)

ZHr+ Or-+ZHrO

(32t 12)(0.8 s) - 2.2666 ks

(3u32)(o.ot) - 0.01 kg

(324) (0.05) - 0.4 kg

2-2.6766k9

Since the fuel contains 0.025 kg oxygen/kg of fuel'the actualmass of 02 requirementperkg of coal burnt

-2.6766 - 0.025

=2.6516k9

Step (III) Air Supplied

Theoretical mass of air requtement

=2.5516 (1m/23)

- 11.5289 kg

40% excess air suPPlied.

Hence the actual air suPPlied

= 1.4 (11.5289)

= L6.l4kg/kg of coal

Step (IV) Mass of Flue Gas

Mass of combustibles Per kg of coal

- 1 - 0.065= 0.935 kg

Fuel + Air = Flue Gas

0.935 kg 16.14 kg = Flue Gas

Hence the total mass of flue gas (inclusive of waler

vapour) produced per kg of coal burnt

= 0.935 + 16.14

- t7.075 kg

Step (V) Mass of Dry Flue Gas

2H2 + O, ------+ 2HrO

(4\ (2 x l8)

= 2 (18\14- 9 k g

Mass of water produced/kg of coal (H-content :0.5%) burned

= 9 (0.05) kg= 0.45 kg

Mass ofdry flue gas produced/kg ofcoal burnt

= 17.075 - 0.45= 16.625k9

Step (VI) Heat Balance

Basis: I kg coal

Heat Evolved Heal Lost To

8 503 kcal Flue gas (dry)- r6.62s (0.25) (l7O-2s)- 602.65 kcal

Stcam (l atm pr€s$.) generated from

fuel burning= 0.45 [/J + Cp (A@) [email protected]]

= 0.45 [639 + 0.48 (170 - 100) - 25]=297.42kcal

Unaccountcd sourceg- (18/100) (E 503)- I 530.54 kcal

Total - 2 424.61kca|

Heat utilized = 8503 -2424.61

= 6078.39 kcalAg coal

Step (VID Boiler EfficiencyHeat utilized

TlboiLr = H*t ga"*aLd

6078.39= 8503

= 0.7 I 48 i.e. 7 1.487oAns.

fuoblem 6.17 A water tube boiler operates8400 h/year al 80o/o efficiency. The unit rated at272L5kgh operates at7.82 atm.

It burns natural gas for six months of the year andNo.2 fuel oil for the rest.

Average aurual boiler loading is 6O% with aninput of 11347303 kcaVh.

CombustionReoction

Mass of water produced/kg of H2 burned

Page 15: Boiler-Calculation

lYlthout Economlzer ^ \Natural g:rs consumption = 1274,25 Nmr/h latwoFuel oil (No.2)consumption = t.+S9 m3n,J bd

Afier Addlng An Economl,zerBFW flowate (including blowdown) at60%lofi- 17145 kg/h

Feedwater tenperature at the economizer inlet= 105"C

Feedwater temperature at the economizer outlet- 136'C

Fluegas t€mperature ateconomizer inlet = 260'CFluegas temperatur€ at economizer outlet - 149"CDetermine(a) the fuel saving using the economizer(b) totat annual fuel cost without insralling the

economizer(c) total annual saving of fuel alter installing the

economizer(d) the payback months, if the economizer cost is

Rs. 500,000 installedGiven: Nanral gas cost = Rs. 1.06 per Nm3 of

gasFuel oil (No.2) cost - Rs I 255 perm3 of F.O.

Solwion The addition of an economizqr to awater-tube boiler system reduces fuel cosl

The fuel saving using the economizer is

- Ilx 100"=___

where S- fuel saving in perceht

H= heatrecovere4 kcavh =ry

F - BFW flowrate, kg/hAO = 6z - 8l = temperaturc difference of BFW

before and after the economizerOr - BFW temperatue at economizer inlet, 'C

Oz = BFW temperaturc at the economizer outlet,'c

B = boiler efTiciency

(a) H= (17t45X136- 105)/0.8= 664368.78kca1/h

Boiler Colculotionr

Flg. 6.1 Figure to the Problem 6.17

s -664368.78 x 100:5.85%rr347303

(b) Total operating perid = 8400 hlyear Ans'

Natural gas burned for 4200 h and F.O. bumed forrest 4200 h over the year.

Annual cost of natural gas/ ^ - r \

=,zzo.zs[*l' lx +200 rj-), r.06 r-R'-)\ n / 1v .n / 1N* , . , ;

= Rs.5672961.

Annual cost of fuel oil/ r \

= r.45e f+ l,<4200 r-!-)x tzss [4)\o / \Year ; l - ' J

- Rs. 7690389

Total annual cost of fuel prior to installationof economizer

= Rs.5672961 + Rs. 7690389

F l u o g o ! o x h o u r t

Page 16: Boiler-Calculation

96 BollEr OPerollon Englneedng

- Rs. 13,363,350/-

(c) After the installation of the

5.85% saving in fuel results'

Annual saving in natural gas

= Rs. 5572961 x 5'85/100

= Rs. 331868/-

Annual saving in fuel oil cost

= Rs.76903g9 x 5.95.2100

- Rs. 449888/-

Number of operating days per year - 270

Cost of waste heat boiler installed

= Rs 3,000 000/-

Maintenance atrd overhead expenses

- 12% of the cAst of WHB

Rate of interest payable - 20% on the principal

arnount

DG Set Load StcanGeneration Rate

4O VdaY80 Uday

Ans.economizer, a

@%too%

.'. Total annual saving of fuel cost after instalation

of the economizer

= Rs. 331868 + Rs' ut49888 = Rs' 781756/-Ans.

(d) The PaYback is

o - E x 1 2r - A

whereP-paybackmonthsE - installed economizer cost' Rs

A - annual fuel savings with economizer' Rs

. p -!''9SS ,. rz' - Rs.781756

= 9.21 month, on .

Problem 6-t8 A waste heat boiler is hooked up

with a diesel generator set to produce steam from

waste heat.ATQVoDG' setload' saturated steamof l0kg/c#

g is produced in the waste heat boiler at the rate of 40

tor/daY.--- nn.tug" ebcric energy generated per day varies

from65 to 70MWH.Esttnatetui-,n" oonomics of incorporating the waste heat

boiler(b) th; payback period of the waste heat boiler

Givenih" "o.t of purchased electrical energy from the

prid - Rs l.IZKWH'- - cor, of generated electricity after the installation

of WHB - Rs0.95/KWH'- (t* includes overheads and depreciation char-

ges)

1 ton ofcoal generates 4'5 t of saturated steam at

10 kg/cm2 gCost of coal - Rs 750 Per ton

blutionia) Bco"o*ics of lncorporating y-HB,.'-'rn"

"ott of ebcricity puphased from the grid

-Rs l.l?KWH

The cost of generated electricity after the installa-

tion of WHB '0.95/KWH-- frfonetary savings per unit electricity generated

= Rs (1.12 - 0.95)/KWH = Rs 0'17/KWH

Average electricity generatior/day

=g#*MwH =67.5MwH

Number of working days per lear -270

Therefore, monetary savings with respectto power

purchased frorn the grid

- o/tl [nffr)'

67.5 x'.* [#, )

, zzo (,days')= Rs 3,098 250/- per year[vear ''1

(b) Payback Period Of WHB

Cost of waste heat boiler

= Rs 3,000'000/-

Maintenarpe ard overheads

= l2Vo of caPital cost of WHB

= Rs 360'000/-

Interest ol PrinciPal arnount

Page 17: Boiler-Calculation

= 20% of Rs.3,000,000/-= Rs 600,000./-

Total steam generated on 100% load - 80 Vday4.5t ofcoal generat€ I ton of steamAmount of coal saved - 8C/4.5 - 17.777 tldayMonetary savings, on the basis of coal, per year

- 750 f-n,-)x n.t77 (tro')" zzo [-@-)(ton/ (oayJ [vear.1

- Rs 359984?-

WHB is an energy saving equipment. So itqualifies for 100% depreciation in the lst year.

Approximate savings in corporate taxes (@ 55%)per ye:u

- Rs 3000000 x 0.55- Rs 16500004

Net Savings per year- Rs (3599842 - 360000 - 600000 + 1650000)- Rs 4289842-

Ps 3000000Payback period = ffiffi x 12 months

= 8.39 monthsAns,

Ptoilem d.l9 lretermine the(a) rate of fuel consumption in kg/h(b) efficiency of WHB of problem 6.18GivenI lt. of fuel generates 4.025 KWH of electrical

energySpecific gravity of liquid fuel - 0.90Exhaust gas flowrate and temperature at 68% load

are 7.55 kg/s and 325'C respectively.Flue gas temperature at WHB inlet - 320'CFlue gas tempenture at WHB outlet = 170'CAverage feedwater temperature to the boiler- 75'C

Specific heat of flue gas - 0.26 kcaVkg 'C

Assume 59o radiation loss suffered by the flue gasin the WHB.

Solution The determination of efficiency of thewaste heat boiler is to be made on the basis of heatbalance.

Boller Colculollons

(a) Rate of Fuel ConsumptionAverage elcclric energy generated per day:67500 KWH

Average fuel consumption per day-6750014.025

- 16770 lL

Mass rate of fuel consumption

---^ / rt ) (. r<e) I I= 16770 [dj,.

o.e [sf,j' ;i $6

- 628.875 ke/hAns.

(b) Flowrate of Flue Gas at 60% l-oad-7.55 x 3600 - 27180 kgh

(c) Useful Heat of Flue GasTotal heat rejected by hot flue gas in the WHB

= 27180 f+l'0.26 f'9)x ezl -r70) ("c)(n J [K8-u '

= 1060020 kcaVhHeat lost to radiation- 106(n20 x 5/100 kcaVh= 53001 kcaVlt

Useful heat available for steam generation= 1060020-53001= 1007019 kcaVh- Heat input rate

(d) Heat OutputAverage steanr (10 kg/cm2 g and saturated)

generation rate- 40ttday

= 40x l0ffil24kg/b= 1666.66 kg/h

Average feedwater temperature = 75'CHeat required to generate 1666.66 kg steam(10 kg/cmz g and saturated)- 1666.66 x (183 - 75) + 1666.66 x 478.4 kcal=977329 kcal

Heat output rate = 917329 kcat/hHeat input rate = 1007019 kcaVh

Page 18: Boiler-Calculation

98 Boller OPerotlon Englneerlng

.'. Efficiency of waste heat boiler

-mxLoo%-97'05%

Ans.BOILER HEAT BALANCE CALCULATIONS

Basis: lkg fuelHeat Input(A) Ilr - Gross calorific value of fuel' kcal

(B) Hz= Heat input of fuel= c ' (@r- @r) 'kcal

c - specific heat of fuel, kcaVkg "C

Ot - temperature of fuel, 'C

@r - r€ference temperature, "C

(c) tt = Heat input of air= M"cr(@" - @r), kcal

M" - mass of input dry airlkg fuel, kg airlkg fuel

ca - sP€ciltc heat of humid air

-0.24+ 0.46H, kcaVkg dry air "C

I/ - humidig of air, kg moisture&g dry air

@a - air temperature, 'C

Total heat input,I{ = Hr* Hr+ H3,kcal

Heat Output(A) Heat consumed in generating steam

l. Economizer Ho= Mw (he,, - h6r), kcal

Mw - fllass of feedwater per unit mass of fuel,

kg/kg tueliew - eothalpy of water at economizer outlet'

kcaVkgftfw = enthalpY of feedwater, kcaVkg

2. Evaporator (Boiler) Hs= M"(/t, - i"*),kcal

M. - mass of steam generation per unit mass of

fuel, kg steam/kg fuel

h, = enthalpy of steam generated, kcaVkg

3. SuPerheater Hu= M"(Hu- hr)' kcal

/rr. = enthalpy of superheated steam, kcal/kg

(B) Heat lost in flue gases

Ht =2 n; ?0, (@s, - 25)' kcal

ni - number of moles of i-th component present in

the flue gas produced due to combustion of 1 kg fuel.

En, - the mean specific heat of i-th component at

ofc

@1, = flue gas tcmPerature' "C

(C) Heat loss due to evaPoration

l. Moisture is formed due to combustion ofhydrogen in the fuel. Loss of heat to evaporate thismoisture

H8= M^L' kcal

Mm = tnilss of moisture formed by burning of

hydrogen per kg of t'uel, kg H2Olkg fuel

L = latcnt hcat of evaporalion of the moisture at thedew point of the flue gases, kcaVkg

2. Heat loss due to evaporation of moisturepresent in thc luel

Hs= M*f L,kcal

Mnrf = mass of moisture present in the fuel' kg/kg

fuel(D) Heat Loss due to incomplete combustion of

carbon as carbon monoxide.

I co l .a,o = fEofrE.]

x c x 5 636.7 kcal

CO - Vo (by volume) of carbon monoxide in theflue gas

COt- qo (by volume) of carbon dioxide in the fluegas

C = c:ubon bumt per kg fuel burnt, kglkg fuel

(E) Heat loss due to unburnt carbon

Htr= M"(7 837'5) ' kcal

M" = 62ss of unconsunred carbon in refuse, kg/kg

fuel(F) Heat loss due to blowdorvnH tz= Mt t (hu* - /t1.."), kcal

Mbl = mass of blowdown water, kg/kg fuel

ftuw = enthalpy of boilerwater, kcaVkg

(G) Unaccounted heat loss

Hrt= Hi- (Hc+ H5 + Hu+ H, + Hg

+ Hn+ Hrc+ H1.+ Hp)

Page 19: Boiler-Calculation

Prodem 6.fr A stoker-fired waterhrbe boilerburns coal-at the rate of 4 Uh to generate steam of 30kglcfl:P abs and 430"C at the rate of 30 Vhour.Evaluate the boiler performance from the followingdata

(a) Component Proximate analysis of coalAsh 12.7% (by weight)Moisture 7.9% (by weight)

(b) Gross calorific value of coal - 6 250kcaUkg

(c) Component Flue Gas Arnlysiscoz t2.85%02 6.580N2 rest

(d) Carbon present in the cinder as unburnt com-bustible -2.75%

(e) The feedwater tempenture - 90"C(f) Flue gas temperaturc at economizer outlet

- 150\CFlue gas pressure at economizer outlet- 755 mmHg

(g) Air tempqratures at burner inlet 30"C DB and22"C WB. Ignore the presence of sulphur andoxygen in coal.

blwion The boiler performance, i.e. the overallthermal efficiency of the boiler is to be evaluated onthe basis of heat balance.

Basis: 100 kmol of dry flue gas.1. Oxygen Supplied with Combustion AirN, in the flue gases

- 100 - (12.85 + 6.5)- 80.65 kmoll0Okmol aircontains 79kmol N2 and 21 kmol 02.'. 02 supplied for combustion-(21179) x 80.65 - 21.438 kmol2. Water Vapour Produced During

CombustionC + 02 -----+ CO2

I kmol I kmol I kmol

I kmol of CO2 requires I kmol of O, forcombus-tion.

12.85 kmol of CO2 require 12.85 kmol of 02for combustion.

Boller Colculotlons 99

Therefore, the oxygen utilized for hydrogen burn-ing of fuel

=21.438- (12 .85+6.5)

- 2.088 kmol

2Hz + 02 -----s 2H2O2 kmols I kmol 2 kmols

Hydrogen bumt = 2 (2.088) = 4.176 kmol

Water produced - 4.176 kmol3. Unburnt Carbon for 100 kmol of

Dry Flue GasCarbon retained in the cinder

) 1 \-ff ix 4x 1000kg/h

- l l 0 k 9 h(FC+ VM) in coal= 100 - (asb% + moistureTo) in coal= 100- (12.7 +7.9)=79.4Vo

. unbumt carbon" (FC + VM - unburnt carbon)) 7 \

===-? =0.0358't9.4 -2.75

Carbon in the flue gas

- carbon in the CO2 in the flue gas- 12.85 kmol= 12.85 x 12= 154.2 kg

Hydrogen in the flue gas

- 4.176 kmol= 4 .176x2

= 8.352 kg

Total burnt combustible- 154.2 + 8.352- r62.552kg

Carbon unburnt for 100 kmol ofdry flue gas= 0.0358 x 162552= 5.8193 kg= 0.4849 kmol

Page 20: Boiler-Calculation

100 Boller Operotlon Englneedng

4. Excess AirC + O 2 + C O 2

l kmol l kmol l kmol

I kmol of C requires I kmol . 3r for combustion

.'. 0.4899 kmol of C requires 0.4899 kmol of 02for combustion

.'. Oxygen required to bum that unbumt carbon -0.4899 kmol

.'. Excess 02 supplied= 6.5 - 0.4899 = 6.0151 kmol

Total stoichiometric 02 required= 12.85 + 2.088 + 0.4899= 15.4229lnnol

Therefore, excess air supplied

_ 6.0151 Y rf l )15.4229

" '""

=39Vo.

5. Moisture Content of the Flue Gas100 kg coal contains 7.9 kg free moisture and

ll00 - (12.7 + 7.9)l i.e. T9.4kgcombustiblesFree moisture appearing with the combustion of

162.552 kg combustibles? o

t9 .4

- 16.173kg= t6.tl3t18 kmol - 0.8985 kmol

From psychrometric chart, humidity of air at 30'CDB and 22'C WB

- 13.4 grr/kg dry air1 ? 4 I

= lg . 1000

kmol HrO$ kmol dry air

0.02158 kmol water= -- ktnol dry uit

Therefore, the total moisture entering the combus-tion zone

= 0.02158 x kmol of air containing 21.438 kmolo2

= (0.02158) r [+ x 2r.+38-]l L t I

- 2.203 kmol

Therefore, total moisture in the flue gases

- (4.176 + 0.8985 + 2.203) kmol

=7.277Sklrrol

6. Composition of Flue Gas

Component kmol mol%

12.85 rr.976.5 6.05

10*x21.$8-80.&'7 75.179z l

7.275 6.781

lm.272 D.980

7. Heat Input RateRate of fuel buming - 4 ton coaVhGross cloritic value of fuel - 6250 kcaVkgHeat input rate = 4 x 1000 x 6250

= 25000000 kcaVhIgnoring the heat input of air (at 30'C), the net heat

input rate - 25000000 kcavh8. Heat Output Rate[A] Heat absorbed in generating superheat,ed

steamHn+ Hr+ Hu- 30,000 x (787.8 - 90.04) kcaUh= 20932800kcaI/h

where 787.8 kcal/kg - enthalpy of steam at30 kgf/cm2 abs and at 4t0"C = h*

90.04 kcaVkg = enthalPY of water at 90'ClBl Combustibles left in the cinder (as C)- I l0 kgih

Calorihc value of carbon (GCV - NCV)= 94.05 kcaVmol

q4 ()5=# x 1000kcal/kg

t zHeat lost in the combustibles

Hr r=Wx 1000x l l0kcaVh

=862125 kcal,/h

lCl Total free moisture evaporated from coal

=l#x4ooo"%E= 305.055 kg/h

cozo2

N2

Hzo

Page 21: Boiler-Calculation

Now, partial pressure of water vapour in the fluegas

= 755 x rnol frrction of water vap. in the flue gas

- 7 55 (7 .I7 5l W7 .2:12) mmltg

-51.20mmH9

Dew point of flue gases - 38"C

Latent heat of water at 38"C - 575.83 kcavkg

Heat lost due to evaporation of free mois[re

- 305.055 x 575.83 - 175660 kcaYh

[D] Heat loss due to evaporation of moisturefonned due to cornbustion of hydrogen in the coalburnt

,, =l#r)G.*) [4#]

(, sx57s.s3)rca,/h

I tmot urO lI 1g coarlf ks cornbustiblesl' ' - - - - - - - - - - - - - - - - 'fkgcorrbustibleslf h lL kgcoal I

I tgHro lf r""rt| _-- ll -:- l- 815408 kcarl/hI kmol H2oll tg J

lEl Heat lost in flue gases (I/r) is evaluated m the

basis of rnean specific heat data of flue gas com-ponents:

Componcfi Mcan Sp. Hcat intlu Rangc25"-l50"C

9.5 kcal/tmol'C

8.12kcalrtmol "C

7.l2kcal/kmol "C

7.00 kcal,/kmol'C

Thercfore, for 1f/.272krnol of flue gas

r\c^ = 12.E5 (95) +7.275 (8.12) + 6.5 (7.12\' r t

+8O.&7 (7) kcaV 'C

=79l.957kcal/"C

Boiler Colculoliom l0l

Heatrost in nue 83s€s ='lrt:lrT"i!;"'

Therefore, the rate of heat loss of flue gases

- ee,ee 4.62( 4,00cy r d2. s rr> (#EJ *"ro

= t,Ag6,06aY

9. Heat Balarrce

Hcd InputRate

(kcd/h)

Heat Output Rate(kcaYh)

25,000,000 $1eam generation

Heat loss due tounburnt combustibles

Heat loss due toevaporation offreemoisture

Heat loss due to

-2W3280083.73%

-862125 3.4%

- 175660 0.70%

- El64$ 3.26%

cozHzoo2N2

evapcation of moishreformed due tocombustion ofhydrogen h thc fuel

Heat lost to flue gases - 1886064 7.54%

Unaccountedheatloss -326943 Ln%(by differerce)

Total - 25 000 000

(10) Overall Thermal Efficiency of the Boiler

_ Heat oubut rate (steam generation)Heat input rate (fuel combustion)

=#ffffix roo= 83.73%

Page 22: Boiler-Calculation

Steam tables

Pressu re

bar kPa

TemperatureSpecif ic EnthalPY I Dpecrrrc

Water (hf) | Evaporation (hfs ) lSteam (hn ) l SteamkJ/kq I kJ /ks I kJ /kg lmJ/kg

abso lu te0.30 30.0 69.10 289.23 2336.1 2625.3 5.2290.50 50.0 81.33 340.49 2305.4 2645.9 3.24Qo.7s 75 .O 91.78 384.39 2278.6 2663.0 2 .2170.95 95.0 98.20 411.43 2261 .8 2673.2 1.777

gauge0 0 100 .00 419 .04 2257 .0 2676 .0 1 .673

0.10 10.0 102.66 430.2 2250.2 2680.2 1.5330 .20 20 .0 105 .10 440 .8 2243 .4 2644 .2 1 .414

0 .30 30 .0 107 .39 450 .4 2237 .2 2647 .6 ' t . 312

0 .40 40 .0 109 .55 459 .7 2231 . 3 2691 . 0 1 .225

0 .50 50 .0 1 1 1 . 61 468 .3 2225 .6 2693 .9 1 .149

0 .60 60 .0 1 13 .56 476 .4 2220 .4 2696 .8 1 .0830.70 70 .o 115.40 444.1 2215.4 2699.s 1 .0240 .80 80 .0 117 .14 491 .6 2210 .5 2702 .1 0 .9710 .90 90 .0 1 18 .80 498 .9 2205 .6 2704 .5 0 .9231.00 100.0 120.42 505.6 2201 .1 2706.7 0.8811 .10 110 .0 121 . 96 512 .2 2197 .0 2709 .2 0 .8411 . 2 0 120.0 123.46 518.7 9 2 . 8 2 7 1 1 . 5 0 . 8 0 61 . 3 0 130.0 124.90 524.6 8 8 . 7 2 7 1 3 . 3 0 . 7 7 3'1 .40 140.0 126.28 530.5 z 84 .8 2715 .3 0 .7431 . 5 0 150.0 1 2 7 . 6 2 5 3 6 . 1 z 8 1 . 0 2 7 1 7 . 1 0 . 7 1 41 . 6 0 160.0 128 .89 541 . 6 7 7 . 3 2 7 1 8 . 9 0 . 6 8 91 . 7 0 170.0 1 3 0 . 1 3 5 4 7 . 1 73.7 2720 .8 0 .6651 . 8 0 180.0 131 .37 552.3 z 70 .1 2722 .4 0 .6431 . 9 0 190.0 132.54 557.3 z 66.7 2724.0 0.6222.00 200.0 '1 33.69 562.2 63 .3 2725 .5 0 .6032.20 220.0 135 .88 571 . 7 56 .9 2724 .6 0 .5682.40 240.O 1 3 8 . 0 1 580.7 2 50 .7 2731 . 4 0 .5362.60 260.0 140.00 589.2 2 44 .7 2733 .9 0 .509

2.80 280.0 141 .92 597.4 39.0 2736.4 0 .4833.00 300.0 143.75 605.3 33 .4 2738 .7 0 .461

3.20 320.0 145.46 612.9 24.1 2741 .O 0.440

3.40 340.0 147 .20 620.0 22.9 2742.9 0 .4223.60 360.0 148.84 627.1 I 17 .8 2744 .9 0 .405

3.80 380.0 150.44 634.0 z 12 .9 27 46 .9 0 .3894.00 400.0 151 . 96 640 .7 08 .1 2748 .4 0 .374

4.50 450.0 155.55 656.3 2096.7 2753.0 0.3425.00 500.0 158.92 670.9 2086.0 2756.9 0 .3155.50 550.0 162.08 684.6 2075.7 2760.3 0.2926.00 600.0 |65 .04 697.5 2066.0 2763.5 0 .2726.50 650.0 167.83 709.7 2056.8 2766.5 0.2557 .00 700 .0 170 .50 721 .4 2047 .7 2769 .1 0 .2407.50 750.0 173.02 732.5 2039.2 2771.7 0.2278 .00 800 .0 175 .43 743 .1 2030 .9 2774 .0 0 .2158.50 850.0 177.75 753.3 2022.9 2776.2 0 .2049.00 900.0 179.97 763.0 2015.1 2778.1 0 .1949.50 950.0 182.10 772.5 2007 .5 2780.0 0 .185

1 0 . 0 0 1 0 0 0 . 0 ' ' | 8 4 . 1 3 7 8 1 . 6 2 0 0 0 . 1 2 7 8 1 . 7 0 . 1 7 71 0 . 5 0 1 0 5 0 . 0 1 8 6 . 0 5 7 9 0 . 1 1 9 9 3 . 0 2 7 8 3 . 3 0 . 1 7 1

1 . 00 1 1 00 .0 1 88 .02 798 .8 1986 .0 2744 .4 0 .163

EDB/1splrax' tsarco 1 . 0 1

Page 23: Boiler-Calculation

tables

Pressu re

bar gauge kPa

TemperatureSpeci f ic Enthalpy Specif ic

Vo lumeSteamms/kg

Water (h1 )kJ/kg

Evaporation (h1n)kJ/kg

Steam (hn )kJ/kg

I t . 5 U

1 2 . o 01 2 5 0

ft-ooI J . 3 U

t4-oo- 1450

I C . U U.-I 3 . J U

16-001 7 .o0t s J o19-OO20^oo

E.oo22nO23^0024l�025-0026-OO27 SOZ8-oo2 9 . o 030.003 1 . 0 032 '0033.0034^OO35-OO36-OO37-OO38-0039-OO40-oo?loo

43-OO44nO45-OO46-OOnnoZs.oo49nO50s05 1 i 052-0053.0O54.oOC C . U U

56-OO

1 1 5 0 . 0 1 8 9 . 8 2 8 0 7 . 1 f f i

-

io_

ias

T

iei#r

irffi

ffiffi

ffiffi

1.02splrax' .lsarco EDB/1

Page 24: Boiler-Calculation

Steam tables

Pressu re

bar qauoe kPa

Temperature

"C

Speci f ic Enthalpy

@kJ/ks I kJ/ks

l D p e o l i l c ;Vo lume

Steam (ho) | SteamkJ/ko

- | m3/ko

57.00 s700.0 273.45 2 0 2 . 1 584.5 2786.6 0 .03375 8 . 0 0 5 8 0 0 . 0 2 7 4 . 5 5 2 0 7 . 8 577.7 2785.5 0 .033159.00 5900.0 275.65 213.4 5 7 1 . 0 2 7 8 4 . 4 0 . 0 3 2 56 0 . 0 0 6 0 0 0 . 0 2 7 6 . 7 3 2 1 8 . 9 564.4 2783.3 0 .03196 1 . 0 0 6 1 0 0 . 0 2 7 7 . 8 0 2 2 4 . 5 5 5 7 . 6 2 7 8 2 . 1 0 . 0 3 1 462.00 6200.0 278.85 2 3 0 . 0 550.9 2780.9 0 .03086 3 . 0 0 6 3 0 0 . 0 2 7 9 . 8 9 235.4 5 4 4 . 3 2 7 7 9 . 7 0 . 0 3 0 364.00 6400.0 280.92 240.8 537.3 2778.5 0 .02986 5 . 0 0 6 5 0 0 . 0 2 8 1 . 9 5 2 4 6 . 1 531 .2 2777.3 0 .029366.00 6600.0 282.95 251 . 4 5 2 4 . 7 2 7 7 6 . 1 0 . 0 2 8 86 7 . 0 0 6 7 0 0 . 0 2 8 3 . 9 5 256.7 5 1 8 . 1 2 7 7 4 . 8 0 . 0 2 8 368.00 6800.0 284.93 2 6 1 . 9 5 1 1 . 6 2 7 7 3 . 5 0 . 0 2 7 86 9 . 0 0 6 9 0 0 . 0 2 8 5 . 9 0 2 6 7 . 0 5 0 1 . 1 2 7 7 2 . 1 0 . 0 2 7 470 .00 7000 .0 28 t i . 85 272 . ' l 498 .7 2770 .4 O .A '2747 1 . 0 0 7 1 0 0 . u 2 4 7 . 4 o 2 7 7 3 4 9 2 . 2 2 7 b 9 . 5 0 . 0 2 6 672.OO 7200.0 244.7 5 2 8 2 . 3 485 .8 2768 . ' t 0 . 026273 .00 7300 .0 289 . t i 9 2 4 7 . 3 4 7 9 . 4 2 7 6 b . 7 0 . 0 2 5 874 .OO 7400 .0 290 . t t 0 2 9 2 . 3 473 .0 2765 .3 0 .02547 5 . 0 0 7 5 0 0 . 0 2 9 1 . 5 1 2 9 7 . 2 4 t t 6 . 6 2 7 6 3 . A 0 . 0 2 5 07 6 . 0 0 7 6 0 0 . 0 2 9 2 . 4 1 302.3 460 .2 2762 .5 0 .024677 .OO 7700 .0 293 .91 3 0 7 . 0 453 .9 2760 .9 Q .O2427 8 . 0 0 7 8 0 0 . 0 2 9 4 . 2 0 3 1 1 . 9 4 4 7 . 6 2 7 5 9 . 5 0 . 0 2 3 92 9 . 0 0 7 9 0 0 . 0 2 9 5 . 1 0 J t o 7 4 4 ' t . 3 2 7 5 8 . 0 0 . 0 2 3 68 0 . 0 0 8 0 0 0 . 0 2 9 5 . 9 6 321 .5 435 .0 2756 .5 0 .02338 1 . 0 0 8 1 0 0 . 0 2 9 6 . 8 1 326.2 424 .7 2754 .9 0 "02298 2 . 0 0 8 2 0 0 . 0 2 9 7 . 6 6 3 3 0 . 9 422 .5 2753 .4 0 .02268 3 . 0 0 8 3 0 0 . 0 2 9 8 . 5 0 3 3 5 . 7 416 .2 2751 . 9 0 .02238 4 . 0 0 8 4 0 0 . 0 2 9 9 . 3 5 3 4 0 . 3 4 1 0 . 0 2 7 5 0 . 3 0 . 0 2 2 08 5 . 0 0 8 5 0 0 . 0 3 0 0 . 2 0 3 4 5 . 0 4 0 3 . 8 2 7 4 8 . 8 0 . 0 2 1 78 6 . 0 0 8 6 0 0 . 0 3 0 1 . 0 0 3 4 9 . 6 3 9 7 . 6 2 7 4 7 . 2 0 . 0 2 1 48 7 . 0 0 8 7 0 0 . 0 3 0 1 . 8 1 354.2 3 9 1 . 3 2 7 4 5 . 5 0 . 0 2 1 18 8 . 0 0 8 8 0 0 . 0 3 0 2 . 6 1 3 5 8 . 8 3 8 5 . 2 2 7 4 4 . O 0 . 0 2 0 88 9 . 0 0 8 9 0 0 . 0 3 0 3 . 4 1 J O J . J 3 7 9 . 0 2 7 4 2 . 3 0 . 0 2 0 590.00 9000.0 304.20 3 6 7 . 8 372.7 27 40 .5 0 .020292.00 9200.0 305.77 3 7 6 . 8 3 6 0 . 3 2 7 3 7 . 1 0 . 0 9 794.00 9400.0 307.24 3 8 5 . 7 3 4 8 . 0 2 7 3 3 . 7 0 . 0 9 29 6 . 0 0 9 6 0 0 . 0 3 0 8 . 8 3 3 9 4 . 5 3 3 5 . 7 2 7 3 0 . 2 0 . 0 879 8 . 0 0 9 8 0 0 . 0 3 1 0 . 3 2 403.2 3 2 3 . 3 2 7 2 6 . 5 0 . 0 83

1 0 0 . 0 0 0 0 0 0 . 0 3 1 1 . 7 9 4 1 1 I 3 1 0 . 9 2 7 2 2 . 8 0 . 0 7 81 0 2 . 0 0 0200.0 313.24 420.5 2 9 8 . 7 2 7 1 9 . 2 0 . 0 74

1 0 4 . 0 0 0400.0 314.67 429.0 2 8 6 . 3 2 7 1 5 . 3 0 . 0 700 6 . 0 0 1 0 6 0 0 . 0 3 1 6 . 0 8 4 3 7 . s 2 7 4 . 0 2 7 1 1 . 5 0 . 0 1 6 60 8 . 0 0 1 0 8 0 0 . 0 3 1 7 . 4 6 445.9 2 6 1 . 7 2 7 0 7 . 6 0 . 0 1 6 21 0 . 0 0 1 0 0 0 . 0 3 1 8 . 8 3 454.3 249 .3 27 03.6 0 .0 5 81 2 . 0 0 1 2 0 0 . 0 3 2 0 . 1 7 4 6 2 . 6 2 3 7 . 0 2 6 9 9 . 6 0 . 0 5 4

1 4 . 0 0 1 4 0 0 . 0 3 2 1 . 5 0 4 7 0 . 8 224 .6 2655 .4 0 .01 6 . 0 0 1 6 0 0 . 0 3 2 2 . 8 1 4 7 9 . O 2 1 2 . 2 2 6 9 1 . 2 0 . 0 471 8 . 0 0 ' 1 8 0 0 . 0 3 2 4 . 1 0 487.2 199.8 2687.0 0 .0 442 0 . 0 0 2 0 0 0 . 0 3 2 s . 3 8 495.4 187.3 2682.7 0 .0 4 1

EDB/1sprrax' tsarco 1.03