Brochure Dry Cleaning En

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    ON END OPEN

    Cleaning anddry cleaning sector

    www.chemicalscampaign.eu

    SLIC

    Senior Labour

    Inspectors

    Committee Financed by the European Union

    Hazardous substances:

    Be aware, assess and protect

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    This leaflet provides information on the risks of exposure to hazardous substances used in dry

    cleaning and other cleaning operations (for example, domestic cleaning).

    Workers may be exposed to various hazardous substances during cleaning operations. Some

    of them contain high risks, such as the organic solvent perchloroethylene, which may enter

    the human body when the vapours are inhaled or when it comes into contact with the

    skin. Symptoms of exposure include: Loss of memory

    Dizziness

    Headaches

    Irritation of the eyes and respiratory tract

    What should employers doto assess the health and safety risks to exposed workers and to

    decide on the necessary preventive measures?

    1. Identify the hazards and assess the types of risk resulting from operations carried

    out in their workplace.2. Select the preventive or risk control measures they should use.

    3. Always re-examine these measures to check whether they remain adequate and

    whether any new risks have emerged.

    WHAT MEASURES?These may be collective protection, work organisation or personal protective equipment (PPE)

    measures.

    How are collective protection measures implemented? By fitting specially adapted devices to the work equipment or premises.

    NOTE:When designing premises or purchasing equipment, you should ensure that safety

    features are fully integrated.

    How can work be organised in order to eliminate or reduce risk?

    For example, by reducing the exposure time of each worker, exposing fewerworkers to risk, removing risks from areas where workers are present and storing

    products and materials correctly.

    What kind of personal protective equipment (PPE) should be used?

    It should be borne in mind that PPE is always an additional or supplementary

    measure. The best solutions are those which opt for fully integrated safety,

    collective protection or work organisation measures.

    There are various types of PPE, such as masks, gloves, goggles, aprons and boots.

    Consult the product label or material safety data sheet to find out which should

    be used (see the final page).

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    Is there any document that provides information on the substances used?

    Yes. You can find detailed information in the material safety data sheets.

    Additionally, the labels on the packaging of each product contain information

    which should be studied. Read them carefully!

    How can exposure to hazardous substances be reduced in dry cleaning premises?

    There are technologies which enable exposure to perchloroethylene to be reduced, such as

    the use of a wet cleaning process whenever possible.

    DRY CLEANING EQUIPMENTDry cleaning equipment should be kept as far away from workers as possible to ensure that they

    only remain close to it for short periods of time.

    The greatest source of exposure for workers occurs when the dry cleaning machines are loaded

    and unloaded. When new machines are purchased, preference should be given to those fitted

    with refrigeration and carbon absorbers.

    Maintenance of the equipment is very important, since it not only increases their useful life

    and performance but also reduces the exposure of workers, as a machine in poor conditioncan result in greater exposure to solvents.

    During maintenance, great attention should be paid to the vapour recovery systems and

    checks should be carried out to ensure that liquids and vapours are not escaping into the

    tubes and pipes of the equipment itself. Whilst carrying out maintenance work, workers

    should wear individual protective equipment (gloves, goggles and mask).

    No. Why?There is no separation between the

    equipment and the areas where workers arebased, meaning that they are always exposed

    to vapours.

    Yes. Why?The dry cleaning equipment is

    installed in an area which workers only go tofor short periods of time.

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    What preventive measures should be implemented?

    The workplace should be ventilated and maintained at a constant temperature.

    The ventilation should be installed in a way that prevents vapours from reaching

    the respiratory tract of workers.

    Ventilation should be supplemented by capturing and eliminating vapours close

    to the area where they are produced or released (local exhaust ventilation) or by

    systems to dilute the vapour concentrations (general exhaust ventilation).

    Work equipment should not be allowed to release vapours.

    The best solution is a machine with integrated exhaust ventilation, which employers may opt

    for when purchasing new equipment. A vacuum system fitted near the door may be used on

    older machines to capture vapours whenever it is opened and to prevent the door from being

    opened when the vapour concentration in the drum is above 300 ppm.

    WARNINGKeep workplaces ventilated and at

    temperatures suitable for the physical well-

    being of workers. Expose only the minimum

    number of people to vapours.

    No. Why? The pipes are not properly installed

    and the equipment is not checked regularly. The

    vapours released into the workplace are harmful

    to workers.

    Yes. Why? The equipment is insulated, the

    pipe leads directly to the exterior and is in

    good condition. Maintenance is efficient.

    Workers are protected.

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    GOOD WORKING PRACTICES

    Prevention of exposure to vapours also involves adopting good practices. The employee is

    responsible for training workers and informing them about the risks to which they are exposed

    and the working practices they should adopt to avoid exposure. The following are examples

    of good practice:

    Do not open the door when the machine is running.

    Do not reduce the drying time.

    Keep the door closed whenever you are not loading or unloading clothes.

    When loading or unloading clothes, keep your head as far away from the machine

    door as possible.

    Never put your head inside the machine. If an article of clothing becomes stuck in

    the machine, use a suitable tool to remove it.

    HOW CAN EXPOSURE TO HAZARDOUS SUBSTANCES BE REDUCEDIN OTHER CLEANING OPERATIONS?When cleaning, workers may be exposed to:

    Perchloroethylene, if they are cleaning clothes

    Ammonium compounds, if cleaning floors, glass, toilets or when waxing Isopropanol and acids, when cleaning glass and toilets

    Surface-active agents, which are considered the main active component in most cleaning

    agents, may cause skin problems. Cleaning products used in the most common operations

    are usually mixtures of different chemicals, including respiratory and dermatological irritants

    and sensitising agents.

    The use of diluted bleach, air fresheners and aerosols by domestic cleaners who have asthma

    or chronic bronchitis has been associated with a worsening of pulmonary diseases. Carpet

    shampoos and floor cleaning products which contain ethanolamine as an active substance

    are the main cause of respiratory diseases.

    No. Why?The door of the machine should only

    be left open for the minimum amount of time

    necessary.

    Yes. Why? The worker is waiting for the

    machine to end the cleaning cycle and will

    only open the door when the sign is displayed.

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    WHAT IS STATED ON THE LABELS?All containers for hazardous products or preparations must be duly labelled.

    Labels must be legible and contain the following information:

    Name of product

    Identity of manufacturer

    Importer or distributor

    Risk warnings

    Safety warnings

    Hazard pictograms or symbols

    HOW DO YOU READ THE LABEL?

    WHICH SYMBOLS ARE USED ON LABELS?In Europe, hazards are identified in accordance with Annex II of Directive 67/548/EEC.

    The symbols mean the following:

    1. Highly flammable (F) and Extremelyflammable (F+)

    2. Toxic (T) and Very toxic (T+)

    3. Corrosive (C)

    4. Oxidising (O)

    5. Harmful (Xn)

    6. Irritant (Xi)

    7. Explosive (E)

    8. Dangerous for the environment

    1 2 3 4 5 6 7 8

    IDENTIFYING HAZARDS (in accordance with Annex II of EC Directive 67/548)

    IDENTIFICATION OF PRODUCT(Substance or preparation)

    ABCDE-33Contains...

    XXX Plc

    ABY St.

    Tel: ...

    COMPOSITION

    (List of hazardous

    substances contained

    in the preparation,

    according to concentration

    and toxicity)

    NAME OF ENTITY

    RESPONSIBLE

    FOR SALES

    (Name, address and

    phone number)

    R 11-23/25:

    Toxic by inhalation and if swallowed

    Highly flammable

    S7-16-24-45:

    Keep container tightly closed

    Keep away from sources of ignition no smoking

    Avoid contact with skin

    In case of accident or if you feel unwell, seek medical advice

    immediately (show the label where possible)

    PREVENTION

    MEASURES(S phrases)

    (In accordance with

    Annex IV of EC

    Directive 67/548)

    DESCRIPTION

    OF RISK(R phrases)

    (In accordance with

    Annex III of EC

    Directive 67/548)

    NOTE:In addition to symbols indicating toxic,

    harmful and irritant substances, you may also

    find carcinogenic, sensitisation, mutagenic

    or reproductive toxicant symbols identified

    by means of a characteristic R phrase.a

    T

    Toxic

    F

    Highly

    flammable

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    For further information, please contact:

    The new classification system for hazard symbols shown below, developed in order to create

    the Globally Harmonized System of Classification and Labelling, may already appear on some

    labels.

    Physical hazards

    1 - Explosive / Self-Reactive / Organic peroxides2 Flammable / Self-Reactive / Pyrophoric / Self-heating

    / Emits flammable gas / Organic peroxides3 Oxidiser

    4 Gas under pressure

    5 Corrosive

    Health Hazards

    1 - Acutely toxic2 Irritant / Skin sensitisation / Acutely toxic / Narcotic effect

    / Respiratory tract irritant

    3 Carcinogenic / Respiratory sensitisation / Reproductive toxicity

    / Specific organ toxicity / Mutagenic / Inhalation toxicity

    4 Corrosive

    Environmental hazards

    1 - Toxic for the environment

    What are l safety data sheets?

    The safety data sheet enables you to identify whether hazardous

    chemical agents are present in the products used and helps you assess

    the risks to the health and safety of workers resulting from the use ofthese agents.

    When delivering a hazardous substance, or even before doing so, every

    manufacturer, importer and/or distributor must send the user a safety

    data sheet containing the information needed to protect human life and the environment. The

    information contained in the safety data sheet must be written in the official language of the

    Member State in which the workplace is located.

    If this is not the case, you should demand this from your manufacturer or supplier.

    The ACT is solely responsible for the contents of this publication

    Examples only. For further information, consult the labels.