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DNVGL FEB 7 th 2019 Bunker Fuel Quality Ian Workman Account Manager VPS Testing & Inspection Inc

Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

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Page 1: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Bunker Fuel

Quality

Ian Workman

Account Manager

VPS Testing & Inspection Inc

Page 2: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Veritas Petroleum Services - Using Established Knowledge to Solve Problems

Established in 1981, VPS pioneered marine fuel testing industry

Test Volume: > 100 million tons Marine Fuels bunkered annually. Aprox. 50%

Highly Experienced Personnel

24/7 Advisory Service

250 Employees

Worlds Largest Fuel Quality Database

VPS supply IMO with Sulphur Data from worldwide supplies

Represented at IMO, CIMAC, IBIA, ISO, ASTM, IP and other Associations

Page 3: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

VPS Services

Marine Fuel Quality Testing (FQT & FSM)

• 4 x ISO17025 Accredited Laboratories

Oil Condition Monitoring (OCM)

• Fully independent lubricating and hydraulic/gear oil testing

Technical Advisory Service

• Expert team of marine engineers that understands the application

• Interpretation of every OCM and FQT report

• Investigative Analysis and Troubleshooting

Bunker Quantity Survey (BQS)

• Mass Flow Meter Investigations

Data Analytics Software and Reporting

Sampling Equipment

In House Training & Fuel Management Courses

Bunker Alerts & Circulars

Page 4: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

The Fuel Supply Chain

• Today’s Marine Fuel Supply Chain can be very complex, with many participants:

• Refining Trading Blending Supply Shipping

• As fuels pass through this chain there is little in the way of:

• Regulation

• Traceability

• Transparency

• Quality Control/Assurance checking

Page 5: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Crude Oil & Refining

• On average, crude oils are made of the following elements or compounds: • Carbon - 84%

• Hydrogen - 14%

• Sulphur Species- 1 to 3%

• Nitrogen compounds- <1%

• Oxygen - <1% (organic compounds such as carbon dioxide, phenols, ketones, carboxylic acids)

• Metals - <1%

• Salts - <1%

• Global Crude Composition varies widely

• Crude Oil is a very poor fuel:• Wide boiling range…can’t burn cleanly or effectively

• Wide variation in composition & quality

• Contains many impurities ( S, N, metals)

• Refining is necessary to convert crude oil into useable and marketable products:

• Shipping - LNG, MGO/Distillate, Residual & Lubricants

0

10

20

30

40

50

60

70

80

90

100

West Texas Brent Arab Lt Maya Duri

Perc

ent

%

Crude Oil Composition

Residue Gas Oil Kerosene Gasoline Gas/LPG

Page 6: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Marine Fuel Production: Complex Refinery

Processes (Catalytic Cracking & Vis-breaking)

• Crude Oil Atmospheric

Distillation

Unit

Vacuum

Distillation

Unit

Visbreaker

Fluidised

Bed

Catalytic

Cracking

Residue

Distillates

Light Cycle Oil

Heavy Cycle Oil

Residue

Typical Blending Components:

Light Cycle Gas Oils (60% Aromatics)

Heavy Cycle Gas Oils

Additional Processing:

Hydro-desulphurisation

Can also remove O & N species

affecting

Fuel lubricity & stability.

Page 7: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Blending

• At the Refinery stage & onwards, marine fuels

are subject to blending processes, as the fuel

moves through the supply chain.

• Cutter stocks, diluents, additives can all be

added to achieve certain specification limits,

comply with legislation, improve performance,

improve profit margins.

• “Too many cooks spoil the broth !!”

• Also the big questions: are such cutter stocks,

diluents, additives quality control checked,

traceable, regulated, or even known to the next

person in the chain?

• Are potential “side-effects” of what’s been

blended known?

• Do suppliers really know what they are adding?

• Blending can change the chemistry of the

original fuel, causing instability, sludging &

unexpected chemical reactions.

Page 8: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Fuel Oil composition

Aromatics:

•Improves stability

•Negative impact on ignition properties

Paraffins:

•May disturb stability

•Improves ignition properties

•Expensive product

GOAL: Balance between Paraffins and Aromatics

Page 9: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Fuel Stability & Compatibility

• Residual fuels contain long chain heavy molecules,

“Asphaltenes”, which are polycyclic aromatic

compounds held within the solution of the fuel as they

are soluble in aromatic solvents but not in aliphatic

ones.

• The ability of residual fuel to retain asphaltenes in

solution is known as the fuels “Stability Reserve”.

• Mixing with other fuels can upset the fuel chemistry and

cause the asphaltenes to fall out of solution forming a

sludge. ie, the fuels are not compatible with each other.

• Similarly adding various cutter stocks or blending

products can alter the fuel’s chemistry and also cause

asphaltenic drop-out and sludging.

• In addition, such cutter stocks may lead to “side-

reactions” dependent upon fuel handling, storage,

temperatures, engine-types, etc. and Styrene

polymerization leading to blocked piping and filters.

Page 10: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Separability Number

• Two separate stable fuels when mixed can completely de-stabilise.

• In addition when, blending fuel to meet ISO8217, stability is a concern.

• What is it?

• Separability number (SN), or Reserve Stability Number (RSN), indicates the

resistance of a residual fuel oil to form sludge.

• What does it tell us?

• Hot filtration methods such as TSP will indicate the amount of sediment present

in a fuel oil. SN will indicate the likelihood that this sediment will flocculate

and form fuel sludge.

• The results of the test are expressed on a scale from 0 to 15, where:

• <5 = Good stability reserve

• >5 - <10 = Intermediate stability reserve

• >10-15 = Poor stability reserve

Page 11: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Separability Number

• Why is it requested?

• Separability number is an excellent accompaniment to the routine hot filtration

methods. It can identify potentially troublesome fuels (unstable) even when the

HFT method is indicating a low sediment content. Conversely, it may indicate

that a high sediment fuel is in fact quite stable and unlikely to form sludge.

This information in combination, is extremely useful from an operational

perspective, as it will indicate in advance if and what mitigation steps are

appropriate.

Separability Number

TSP

%

Operational Problems Likely

Operational Problems

Unlikely0.01

0.20

5 10 15

0.10

Page 12: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Enviro-Legislation & Blending Impact on Fuel Quality

0

10

20

30

40

50

60

70

2013 2014 2015 2016 2017

No.

of

Ale

rts

VPS Past 5-year Bunker Alert History

Residual Distillate Total

ECA Change to 0.1% Sulphur

ECA Limit 1.0% sulphur

Page 13: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Global Fuel Quality• Currently 15% of all residual fuels and

9% of all distillates fuels tested exceed

the ISO8217 test specification for at

least one parameter.

• In 2017 VPS released 58 “Bunker Alerts”

of which 36 (62%) were related to

Residual fuel & 22(38%) related to

Distillate fuel quality.

• This was a 70% increase on 2016

Distillate Bunker Alerts, and a 30%

increase on 2016 for Residual Bunker

Alerts

• 2017: More fuel issues in Europe &

Americas than AMEA.

• H1-2018: 33 Bunker Alerts

• 18 x Residual (55%), 15 x Distillate (45%)

• 14 x Americas, 13 x Europe, 6 x AMEA

• Key Parameters, Contaminants, Cat-Fines, FP

0

2

4

6

8

10

12

14

No.

of

Ale

rts

VPS Bunker Alerts by Test Parameter - 2017

Residual Distillate

0

1

2

3

4

5

6

7

Residual Distillate Residual Distillate Residual Distillate Residual Distillate

Q1 Q1 Q2 Q2 Q3 Q3 Q4 Q4

No.

of

ale

rts

VPS Bunker Alert Volumes by Region - 2017

Americas Europe Middle East Asia

Page 14: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Forensic Detection of Fuel Contaminants

• 2020 will see an increase in Number & Types of Fuel, wider use

of Diluents, Cutter Stocks, Additives, Blending.

• All the above can alter the fuels chemistry, potentially

destabilising, and even damaging side-effects.

• Original Fuel source and refining also influences fuel quality:

• Eg Crude types and regions, Shale Oil, Tall Oil etc.

• There will be an increase in fuel quality issues.

• Estimated Average Cost of each fuel Mgmt issue = $300K

• Laboratories are now using many high-end analytical techniques

and methods to identify the cause of fuel problems:

• Gas Chromatography- Mass Spectrometry (GCMS): Chemical Screening,

Extended Head-Space, Acid Extraction, Vacuum distillation

• Fourier Transform Infrared – (FTIR), Solids contamination, Polymers

• Microscopy – Solids and polymer identification

• Separability No., Reserve Stability No. (RSN) – Compliment TSP/TSA/TSE

• CHNO Analysis (Carbon, Hydrogen, Nitrogen, Oxygen)

• Steel Corrosion

Page 15: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Potential Fuel Contaminants

Chemical Group Comment

CHLORINATED

HYDROCARBONS

Chlorinated hydrocarbons do not originate from any refinery processes and are therefore an indication

that the fuel is possibly contaminated. Based on VPS experience, these contaminants may result in

damages to fuel injection equipment.

ALDEHYDEAldehydes do not originate from normal petroleum refining and are therefore an indication that the

fuel is possibly contaminated. Based on VPS experience, these contaminants may result in damages to

fuel injection equipment.

ALCOHOLAlcohol does not originate from normal petroleum refining. Based on VPS experience, these

contaminants may result in increased sludge formation and possibly laquering and/or deposit

formation.

STYRENESStyrenes do not originate from normal petroleum refining but are known to be present in some blend

stocks for fuel oils. Based on VPS experience, these contaminants may result in increased sludge

formation and possibly laquering and/or deposit formation.

TERPENESTerpenes do not originate from any refinery processes and are therefore an indication that the fuel is

possibly contaminated. Based on VPS experience, these contaminants may result in increased sludge

formation and /or damages to fuel injection equipment.

CYCLOPENTADIENEDCPD does not originate from normal petroleum refining but are known to be present in some blend

stocks for fuel oils. Based on VPS experience, these contaminants may result in increased sludge

formation and possibly laquering and/or deposit formation.

PHENOLSPhenols do not originate from normal petroleum refining. Based on VPS experience, these

contaminants

may result in increased sludge formation and /or damages to fuel injection equipment.

KETONESKetones do not originate from any refinery processes and are therefore an indication that the

fuel is possibly contaminated. Based on VPS experience, these contaminants may result in

damages to fuel injection equipment.

Page 16: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

The Common Denominator – Probable Culprit

4-Cumyl-Phenol CAS # 599-64-4

Industrial uses for cumyl phenol include the manufacture of epoxy resins

and as an emulsifier in pesticides, both of which utilise the adhesive

(sticky) qualities 4-cumyl-phenol exhibits.

Component is only detectable using the sophisticated GCMS technique,

GCMS acid extraction

Page 17: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Fuel Specification – ISO 8217Test Parameters Test Methods Residual Fuel

Distillate

DMA DMZ DMB

Density, kg/m3 @ 15C ISO12185/ASTM D7042 X X X X

Viscosity, mm2/s at 50oC ISO 3104/ASTM D7042 X

Viscosity, mm2/s at 40oC ISO 3104/ASTM D7042 X X X

Water content, % V/V ISO 3733/ASTM D 6304 Proc.C X XB

Micro Carbon Residue, % m/m ISO 10370 X X

Micro Carbon Residue,

10% distillation residue, % m/mISO 10370 X X

Sulphur, % m/m ISO 8754 X X X X

Total Sediment Potential, % m/m ISO 10307-2 * X

Total Sediment Existent, %m/m ISO 10307-1 XB

Ash, % m/m LP 1001 ** X X X X

Vanadium, mg/kg LP 1101/IP 501 X XA

Sodium, mg/kg LP 1101/IP 501 X XA

Aluminium, mg/kg ISO 10478/IP 501 X XA

Silicon, mg/kg ISO 10478/IP 501 X XA

Iron, mg/kg LP 1101/IP 501 X XA

Nickel, mg/kg LP 1101/IP 501 X XA

Calcium, mg/kg LP 1101/IP 501 X XA

Magnesium, mg/kg LP 1101 *** X XA

Zinc, mg/kg LP 1101/IP 501 X XA

Phosphorus, mg/kg LP 1101/IP 501 X XA

Potassium, mg/kg LP 1101 *** X XA

Flash Point, Deg C ISO 2719 - (A / B)/LP 1503 X X X X

Pour Point, Deg C ISO 3016/LP 1304/LP 1305 X X X X

Visual Appearance Proprietary (LP 1902) X X X

Specific Energy (net), MJ/kg ISO 8217 Annex A X X X X

Calculated Carbon Aromaticity Index ISO 8217, Annex B X

Calculated Cetane Index, CCI ASTM D4737 X X X

Fatty Acid Methyl Ester (FAME) EN 14078/LP 2403 X X X

Acid NumberLP 2403/LP 2404/ASTM

D664/LP 2003X X X X

FTIR Screening LP 2403 X X X

Typical specification tables do not address

individual chemical contaminants by name.

Protections against harmful chemical

contaminants are contained in the verbiage of

ISO-8217. Important for buyers and

consumers to understand the specification.

Page 18: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

ISO-8217:2017 Edition5.2 The fuel shall be free from any material at a concentration that causes the

fuel to be unacceptable for use in accordance with Clause 1 (i.e. material not at

a concentration that is harmful to personnel, jeopardizes the safety of the ship,

or adversely affects the performance of the machinery).

Your shield against chemically contaminated

fuels.

Review Your Purchasing Contract Terms and

Language

Page 19: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

What is or rather isn’t happening?

Page 20: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Identification of Fuel Oil Contaminants by GC-MS

Chromatography = SeparationMas Spec = Identification

Page 21: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

GCMS-HS Screening & Extended HS

• GCMS-Head Space Screening

detects only volatile organic

components within residual fuels

• GCMS-HS Screening should detect

around 70% of most fuel

contaminants

• In 2018, YTD Samples tested show:

• 92% “PASS”

• 8% “Caution”

• The distribution of detected

component groups based on GCMS

HS-Extended testing where

Screening shows “Caution”:

Page 22: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Five Flavors of GCMS Testing

Test Turnaround Time Description

GCMS Screen Headspace 2 Working Days

This is a quick and economical test used to detect the

presence of the most common chemical contaminants in

fuels. It does not identify the contaminant nor provide

quantification

GCMS Extended Headspace 3 Working DaysThis test identifies the names of the contaminants but does

not quantify the concentration level.

GCMS Vacuum Distillate 5 Working DaysThis test identifies the contaminants and also quantifies the

concentration level in most cases of the above 2 tests.

GCMS Acid Extraction 10 Working Days

This test is used for isolating organic acids from a sample. The

concentrated acid extract is then analyzed by GCMS. This

method will identify the names of the contaminants but will

not provide concentration level

GCMS Acid Extraction With Quantification 10 Working Days

This test is used for isolating organic acids from a sample. The

concentrated acid extract is then analyzed by GCMS. This

method will identify the names of the contaminants and will

also provide concentration level of each contaminant in %

m/m

Page 23: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

VPS Technical Focus:

ASTM test method for contaminated bunkers ‘limited’

ASTM D7845-17, also known as the Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by

Multidimensional Gas Chromatography/Mass Spectrometry (GCMS), has been developed to quantify chemical species at low

levels in marine fuels oils and cutter stocks. However, it seems there are certain limitations of this test method.

Dr Malcolm Cooper, the Group Managing Director of marine fuel testing and inspection agency Veritas Petroleum Services (VPS)

explains to Manifold Times readers the limitation of using ASTM D7845-17 as a test method for detecting 4-cumyl phenol found

in contaminated marine fuel:

The test method ASTM D7845 lists 29 specific chemicals that may be detected and measured within the test method, and this is a

good method when looking for these compounds. However, this is not an exhaustive list and does not cover how to handle any

“unknowns” which may be present in the fuel sample.

Since there are literally thousands of possible organic contaminants that may be present in the fuel, the specific 29 chemicals

named in the test method is a major limitation. Also, since 4-cumyl phenol is not amongst the 29 named chemicals, and this was

the major compound we detected in the Houston fuel issue, this indicates another of the limitations of using this method. These

limitations are the reason that VPS does not use this method.

ASTM D7845-17 uses direct injection onto a GCMS via a Deans valve-switching arrangement, whereby a sample is injected onto a

pre-column prior to an analytical column, with the pre-column being back-flushed to remove heavy fuel oil components (as the

only sample preparation prior to analysis). This valve-switching pre-column arrangement eliminates the higher boiling

hydrocarbons in the fuel oil and can prevent high boiling chemicals from reaching the analytical column.

The D7845 method detects 4-isopropyl phenol (Boiling Point 212C), but not 4-cumyl phenol (Boiling Point 335C). The method lists

29 specific compounds that can be detected, which are quantified using Single Ion Monitoring (SIM). In order to apply SIM then the

organic compound must be known prior to analysis (in order to identify the SIM mass number) and when dealing with problem fuel

samples then this organic contaminant is not known, which is a limitation of the method.

It should be noted that the VPS Acid-Extraction GCMS method, transfers all acidic compounds from the fuel oil through extraction

as a sample clean-up and extraction treatment prior to the sample being directly injected into the GCMS. This sample pre-

treatment method eliminates all hydrocarbon compounds in the fuel oil since they are not acidic and do not enter the aqueous

phase during extraction. The method is semi-quantitative and highly selective for acidic compounds such as carboxylic acids,

phenols, etc. Also, the total acidic content in the fuel oil is quantitatively measured.

Page 24: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Quality Issues - HOUSTON

• Jan-May over 100 vessels suffered fuel pump failure issues from fuel supplied in Houston

• To date, approximately 150 vessels affected.

• VPS investigated fuel-pump failures >50 vessels on our testing programme

• VPS Bunker Alerts released, 26th April, 29th May, 25th June.

• Fuel is not single supplier specific.

• 10 suppliers

• 20 Delivery Barges

• Indications suggest Upstream somewhere between Refinery but before final supplier?

• 4-Cumyl Phenol found in Concentration range 300-1000ppm.

• Detected by VPS “In-house” proprietary method utilising Acid Extraction/Gas Chromatography Mass

Spectrometry.

• Findings Verified in two VPS laboratories (Singapore & Fujairah)

• Verified 4-cumyl phenol only seen in Houston fuels.

• 4-cumyl phenol used to manufacture resins and emulsifiers due to its “sticky” properties.

• Phenolic compounds found in fuel since 2007. All resulted in sticking fuel pumps.

Page 25: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

VPS Issued a Number of Bunker Alerts

Page 26: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Page 27: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Other Quality Issues

• Corpus Christi

• Sludging of Fuel/filter blocking: 4 vessels with Petroleum Coke contamination

• Panama

• Poly-methacrylate found in fuel via solids contamination analysis - sticking fuel pumps.

• Plus 20 vessels affected by Houston-type contaminants

• Singapore

• 10 vessels affected by Houston-type contaminants

• Colombo

• Contaminated fuel but limited number & low concentrations of chemicals.

• Of all the AE-GCMS tests undertaken by VPS in 5 months: 17% cases were linked

to serious damage on the associated vessels.

• Columbia: 10 cases of (very) high sediment fuels

• Not all vessels having these fuels have already burnt the fuel, the majority do not report problems.

• Feedback from one vessel (out of 10 high sediment fuels) is that they needed to clean the separators more

often, but other than that, experienced no problems burning the fuel.

Page 28: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Seized Fuel Pump

Page 29: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Barrels Require Forced “Jacking” To Remove

Page 30: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Heavy Deposits On Screw Pump

Page 31: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Distillates

• As a result of local and global emissions

legislation the demand for distillate fuels

in the marine market will increase

substantially.

• The perception has been, Distillates are

“Problem Free”???

• Not All Distillates are Low in Sulphur and

require some degree of treatment.

• On 1st Jan 2015 VPS saw sample submissions

move from: 80:20 Residual:Distillate to

60:40 Residual:Distillate.

• What will we see on 1st Jan 2020?

• Fuel Change-over issues• Low viscosity issues • Hydro-desulphurisation

o Decreased Lubricityo Reduced Stability

• Wax Precipitation due to Cold-flow properties• Low Flash Point

• FAME: Increase in oxidative capabilities Instability Erosion of metal Deterioration of engine seals

Increases fuels affinity for water leading to

microbial growth & corrosion Microbial contamination Distillate quality problems may become much

more common with increased demand.

Page 32: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

ULSFO/Hybrids

• The 0.1% S ECA limit was an opportunity for suppliers who have direct

contact with refineries to launch a number of new fuels

• In many cases these fuels were just heavier grades of gas oil that have been

around for a long time

• The principle purpose of these new grades was to provide a fuel that met

the ECA sulfur limit but had a relatively high viscosity, overcoming the

potential risks associated with very low viscosity gas oils

• A significant characteristic of some of these new ECA fuels is that the cold

flow properties, stability and compatibility, could present a challenge on

some ships.

• Density 860-920Kg/m3, Viscosity 8-50 CSt

• Low Metals, Low Sediment Potential

• High Energy Content, High Pour Point

• Compatibility? Stability?

Page 33: Bunker Fuel Quality - DNV GL Workman_Bunker Fuel Quality_t… · Established in 1981, VPS pioneered marine fuel testing industry Test Volume: > 100 million tons Marine Fuels bunkered

DNVGL FEB 7th 2019

Typical Specs – All Over The Board

Density @ 15°C kg/m³ max 895-915 936 850-890 923 858 870 910

Kin. Visco @ 40°C / 50°C mm²/s min/max 40-75/25-45 17 6-13 61 17 8 65

Ash % m/m max <0.01 0.01 0.04 0.006 0.003 0.001 0.07

Micro carbon residue % m/m max <0.30 2.2 4 4 <0.1 0.29 -

Al + Si mg/kg max <0.3 5 LT15 12 3 15 2

Pour point °C max 9-15 15 27 18 -20 21 20

Flash point °C min >70 91 65 110 79 94 60

Total sediment % m/m max <0.01 - 0.02-0.07 0.01 0.01 - 0.1

CCAI 795-810 841 - 806 - 792 860

Density @ 15°C kg/m³ max 790-910 928 888 917 869 920 901

Kin. Visco @ 40°C / 50°C mm²/s min/max 10-60 30-40 19 67 26 100-120 13

Ash % m/m max 0.01 0.05 0.01 <0.1 0.003 0.09 <0.001

Micro carbon residue % m/m max 2 6 2.07 <10 3.80 5.70 0.20

Al + Si mg/kg max 12-20 10-20 21 5 3 <15 <15

Pour point °C max 18 20-25 18 0 -6 30 9

Flash point °C min >60 70 >70 >70 >65 60 >110

Total sediment % m/m max 0.01-0.05 0.02 0.01 - 0.01 0.01 -

CCAI 800 790-800 791 799 795 802 811*Above obtained results are typical results hence subject to changes and therfore connot by guarenteed by VPS.

Fuel F Fuel G

Fuel N

Fuel A Fuel B Fuel C Fuel D Fuel E

Parameter Unit limit

Parameter Unit limit

Fuel H Fuel MFuel LFuel KFuel JFuel I

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DNVGL FEB 7th 2019

ULSFOs - 2020?

• As we approach 2020, its likely more new fuels will come to the market offering

compliance at <0.5% S

• Like New ECA fuels these will likely be Blended products (ULS distillates + LS residues)

• Hydro treated vacuum gas oils

• Hydrocracker fractionator bottoms

• Potentially more residual-based materials may be used and therefore:

• Higher viscosity to normal distillates which eliminates fuel pump leakage and

damage issues

• Normal flash point

• Blending residual components with proportions of distillates could result in

Reserve Stability issues and sludging.

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DNVGL FEB 7th 2019

Testing Recommendations – Circular Friday 11th Jan 2019

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DNVGL FEB 7th 2019

Testing Recommendations

• Residual Fuels

• ISO8217:2010/12,17

• Chemical Screening (GCMS-HS)

• Separability Number (RSN)

• TSA/TSE

• Asphaltenes

• Fuel System Checks

• Distillate Fuels

• ISO8217:2010/12,17

• Cold-Flow (CP, CFPP)

• Lubricity (Sulphur<500ppm)

• FTIR – Bio/FAME

• Emergency Equipment Testing

• VLSFO’s/ULSFO’s

• Since 2015 tested to RMD80 spec.

• Depends upon constituent make-up of fuel.

• Can be a mix of the Residual & Distillate tests

• Compatibility & stability always a concern.

• No ISO8217 Specification at present

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DNVGL FEB 7th 2019

Oil MajorsBP displayed 2 samples of new Hybrid Fuels that they have developed. They

performed nearly 100 hand blends in the research process. One of them is a

cracked aromatic with very low pour (-30C ?). The other is highly paraffinic

with high pour (18 C ?) Paraffinic fuel has better combustion characteristics.

BP wants the industry to look at the possibility of developing Aromaticity and

Paraffinic ratings that could be assigned to hybrid fuels in order to help predict

compatibility among them.

ExxonMobil has announced that all of their hybrid fuels will be compatible with

each other.

ExxonMobil has also advised that some of the new 0.5% sulfur fuels could

contain elevated levels of catfines.

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DNVGL FEB 7th 2019

FSC Sample Points

A recommended set of Fuel System Check samples consists of one sample taken from each of the following

locations:

As a minimum before and after separator samples should be drawn and forwarded to the laboratory for analysis.

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DNVGL FEB 7th 2019

Handling / Operational Issues

• Always segregate bunker lots. No mixing.

• New fuel should not be used before analysis results are known

• If mixing is unavoidable perform a compatibility test beforehand.

• Use empty tanks or ensure tanks are drained as much as possible before

loading a new fuel

• Be aware of specific heating requirements for hybrid fuels due to varying

viscosities. Minimum storage temp should be 10°C above pour point.

• Low viscosity ECA distillates may require chilling for proper viscosity

control prior to injectors.

• Some ECA fuels have a “cleansing” effect on storage tanks and pipelines.

Suggest cleaning tanks in advance. If not possible, be prepared for

additional sludge at the purifier. Consider reducing sludge cycle time at

purifiers during initial changeover.

• In-line auto filters may backwash more frequently due to cleansing

effect.

VPS DATA SHOWS THAT HYBRID FUELS ARE MORE SENSITIVE TO MIXING

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DNVGL FEB 7th 2019

BlockChain

BlockChain Processes:

Applied to fuel supply could assist

with improving:

• Product Quality

• Transparency & Traceability

• Identification of end-user

problem by identifying common

source in fuel supply chain

• Corporate Governance

• Ethics & Integrity

• Health & Safety

• Environmental Protection

• Insurance Implications

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DNVGL FEB 7th 2019

Summary

• Heading towards 2020 & Beyond…

• Fuel Supply Chain Challenges will only increase and become more complex.

• Greater regulation with higher levels of Traceability & Transparency of all fuel

treatments and blending components would help safeguard both suppliers and

purchasers of fuel.

• We are already seeing a major increase in fuel quality issues, which will continue.

• Wider range/choice of fuels available with many technical considerations.

• Greater understanding of the Stability & Compatibility of fuels will assist fuel

management, ie TSP/TSA/TSE/RSN.

• The increasing and widening types of base fuels, cutter stocks, blending agents &

additives will lead to wider chemistry issues and the need for higher analytical

testing techniques.

• Work with a Fuel & Oil Management Partner to effectively measure and monitor

fuel quality, to improve operational efficiency, protect your assets, comply with

legislation and ultimately save money!!

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DNVGL FEB 7th 2019

YOUR FUEL MANAGEMENT PARTNER

Thank you for your attention!

Questions?? Please drop me an e-mailIan Workman

[email protected]

914 764 7053762