Calibration and Reference Sample for AC DHA classic analyzer

Calibration and Reference Sample

forAC DHA classic analyzer

For reordering samples use the Boxno. mentioned above.

AC Analytical Controls BVInnsbruckweg 35

3047 AG RotterdamThe Netherlands

Phone: +31-(0)10-462 4811Fax: +31-(0)10-4626330

E-mail: [email protected]

PAC LP8824 Fallbrook Dr.

Houston, Texas 77064USA

Phone: +1-281 940 1803Fax: +1-281 580 0719


AC Analytical Controls Asia Pacific Pte Ltd61, Science Park Road, #03-09/10 The Galen, Singapore Science Park III, Singapore 117525Phone: +65-6412 0890Fax. +65-6412 0899E-mail: [email protected]

Revised, April 2009

Box no. Sample no. Lot no. Sample name

25115.610 51.15.610 008 n-Paraffin Calibration Standard

25115.520 50.16.512 011 Quantitative Reference Standard

25116.510 51.16.501 005 Qualitative RFA sample

2

Expiry date samplesBox no. Sample no. Lot no. Sample

nameDate prepared

Expiry Date

25115.610 51.15.610 008 n-Paraffin Calibration Standard

March 2008

March 2013

25115.520 50.16.512 011 Quantitative Reference Standard

April 2009 April 2009

25116.510 51.16.501 005 Qualitative RFA sample

Aug 2008 Aug 2013

3

Index Page

Sample verification 4

Important sample information 4

System Configuration 5

n-Paraffin Calibration Standard Sample Part no. 51.15.610 6

Quantitative Reference StandardSample Part no. 50.16.512 9

Qualitative RFA SampleSample Part no. 51.16.501 14

Material Safety Data Sheet 39

4

Sample verificationEach AC standard is carefully manufactured and shipped using our high quality procedures. A sample booklet is included with the standards and contains detailed chromatographic information about the sample. To overcome any wrong interpretation of the results it is necessary to check your actual AC standard run performed on site with the example chromatogram in the booklet. If any discrepancy is found, we advise you to contact AC before continuing analyzing your samples.

Important sample informationStore the ampoules in a freezer. They contain a mixture of low boiling components. So once opened, the lifetime is limited!WARNING - Light hydrocarbons are toxic. Avoid inhaling fumes and contact

with any part of the body.

WARNING - Light hydrocarbons are extremely flammable. The fumes and vapors from light hydrocarbons are easily ignited. Keep this material away from flames, sparks and other sources of heat.

WARNING - Oxygenated hydrocarbons, such as alcohols and ethers, may be harmful or toxic and are extremely flammable.

CAUTION - The broken glass ampoule has sharp edges which may cause cuts to the skin. Take care when breaking the top of this ampoule.

WARNING - Carbon Disulfide (CS2) is highly toxic. Utilize this chemical only in a Fume hood. Avoid inhaling fumes. CS2 is easily absorbed through the skin. Avoid any contact with any part of your body.

WARNING - Carbondisulfide (CS2 ) is extremely flammable. The flash point of CS2 is very low:-30°C. Fume and vapors are heavier than air and will travel long distances. Do not use CS2 nearopen flames, sparks or sources of heat. Do not use open containers or vials of CS2 near hot injectors or detectors on the gaschromatograph.

WARNING - Carbondisulfide (CS2 ) boils at very low temperature: 45°C. When storing or working with CS2 never expose a container or vial containing CS2 to temperature excee ding 45°C.

WARNING - Carbon Disulfide evaporates very quickly. Handle one vial at the time and seal the vial immediately after preparation.

5

System configuration

All information illustrated in this sample booklet is obtained by configuring the GC to the following setup and by making the adjustments given below.The obtained RFA data is the average of approximately 50 RFA analyses on different AC Detailed Hydrocarbon Analyzers (AC DHA).

System : AC DHA analyzerColumn : 100 meter x 0.25 mm ID x 0.5 mSample size : 0.2 lSplit ratio : 100:1Inlet temperature : 250 CDetector temperature : 250 COven : Initial temperature 35 C

Initial time 13 min First Program Rate 10 C/min First Hold Temperature 45 C First Hold Time 15 min Second Program Rate 1 C/min Second Hold Temperature 60 C Second Hold Time 15 min Third Program Rate 1.9 C/min Third Hold Temperature 200 C Third Hold Time 5 min

6

n-Paraffins Calibration StandardBox no. 25115.610

7

n-Paraffins Calibration Standard

Storage instructionsThe n-paraffin mix is shipped as a concentrated liquid suspension of normal alkanes. The vial contains approximately 1.0 grams, and must be diluted with Carbon Disulfide prior to use. Store the mixture in the refrigerator prior to preparation. Do not heat the concentrated liquid suspension.

Sample preparationThe DHA analysis is based on the principle of referring component retention times to the retention times of n-paraffins according to the Kovats index. The retention times of n-paraffins are measured with two standards, a natural gas standard and a n-paraffin standard. The n-paraffin standard, part number 25115.610, consists of n-paraffins from C5 to C14. This measurement should be carried out on a regular basis to prevent erroneous storage of retention times of the n-paraffins.

Preparing a n-paraffins C5 to C14 standard Fill a 2 ml vial with 0.1 gram of the n-paraffins standard Add to the vial approximately 1 ml CS2. This will give a solution of approximately 1

mass% per component Seal the vial and shake well Place the vial in the desired position of the automatic liquid sampler tray

8

n-Paraffins Calibration Standard

9

Quantitative Reference StandardBox no. 25115.520

10

Quantative Reference Standard

Storage instructionsStore the ampoules in a freezer. They contain a quantitative mixture of low boiling components. So once opened, lifetime is limited!

Sample information# Component Category Mass % BP °C BP °F1 n-Pentane C5nP 1.10 36.1 97.02 Cyclopentane C5N 1.10 49.2 120.63 2,3-Dimethylbutane C6iP 2.05 58.0 136.44 1-Hexene C6nOP 1.45 63.3 145.95 n-Hexane C6nP 2.05 69.0 156.26 Benzene C6A 2.20 80.1 176.27 Cyclohexane C6N 2.05 80.7 177.38 4-Methyl-1-Hexene C7iOP 1.60 87.1 188.89 2,2,4-Trimethylpentane C8iP 5.00 99.2 210.610 n-Heptane C7nP 3.50 98.4 209.111 Methylcyclohexane C7N 4.15 101.0 213.812 Toluene C7A 2.20 111.0 231.813 1t,2-Dimethylcyclohexane C8N impurity of 15 123.0 253.414 n-Octane C8nP 5.00 126.0 258.815 1c,2-Dimethylcyclohexane C8N 5.00*16 Ethylbenzene C8A 4.50 136.0 276.817 1c,2t,4t-Trimethylcyclohexane C9N 4.15* 138.0 280.418 1c,2t,3c-Trimethylcyclohexane C9N impurity of 1719 1c,2t,4c-Trimethylcyclohexane C9N impurity of 1720 o-Xylene C8A 4.15 144.0 219.221 1,1,2-Trimethylcyclohexane C9N impurity of 1722 n-Nonane C9nP 4.50 151.0 303.823 n-Propylbenzene C9A 5.00 159.0 318.224 1,2,4-Trimethylbenzene C9A 4.50 169.0 336.225 n-Decane C10nP 4.25 174.0 345.226 1,2,3-Trimethylbenzene C9A 5.00* 176.0 348.827 2,3-Dihydroindene C9A impurity of 2628 t-Decahydronaphtalene N 4.25 187.0 368.629 n-Undecane C11nP 3.55 196.0 384.830 1,2,4,5-Tetramethylbenzene C10A 4.95 197.0 386.631 n-Dodecane C12nP 3.30 216.0 420.832 Pentamethylbenzene C11A 4.95 232.0 449.633 n-Tetradecane C14nP 4.50 254.0 489.2

* Adding the main component and its impurities gives the total mass% per component.

NOTE - Maximal acceptable deviation of analysis results is 0.3% mass absolute per component.

11

Quantitative Reference Standard

(1 of 3)

12


(2 of 3)

13


(3 of 3)

14

Qualitative RFA SampleBox no. 25116.510

15

Qualitative RFA Sample

Part no. 25116.510

This sample can be used for peak identification only.

Storage instructionsStore the ampoules in a freezer prior to use. Once opened, lifetime is limited!

Analysis Mode: PIANOTotals by Group Type & Carbon Number (in Weight Percent).

Carbon Paraffins I-paraffins Aromatics Naphthenes Olefins TotalsNumber1 0.000 0.000 0.000 0.000 0.000 0.0002 0.000 0.000 0.000 0.000 0.000 0.0003 0.000 0.000 0.000 0.000 0.000 0.0004 4.134 0.080 0.000 0.000 0.000 4.2145 3.249 4.256 0.000 0.192 2.569 10.2666 2.389 9.990 1.923 1.111 2.444 17.8577 1.170 5.739 6.838 1.404 2.097 17.2488 0.827 8.532 13.741 1.899 0.386 25.3869 0.240 2.730 9.548 0.767 0.270 13.55610 0.094 1.067 5.230 0.201 0.069 6.66211 0.066 0.213 1.143 0.075 0.031 1.52712 0.067 0.377 0.576 0.000 0.000 1.02013 0.242 0.017 0.000 0.000 0.020 0.27914 0.026 0.000 0.000 0.000 0.000 0.026

Totals 12.504 33.001 38.999 5.649 7.886 98.041

Oxygenates 0.000Total C13+ 0.000Total Unknowns 1.959

Grand Total 100.000

16

ID Component name Index1 Propane 300.02 i-Butane 361.63 n-Butane 400.04 2,2-Dimethylpropane 413.05 3-Methylbutene-1 454.76 i-Pentane 473.27 Pentene-1 487.98 2-Methylbutene-1 494.99 n-Pentane 500.010 Isoprene 504.711 t-Pentene-2 507.212 c-Pentene-2 515.213 2-Methylbutene-2 520.214 1t,3-Pentadiene 522.515 1c,3-Pentadiene 534.616 2,2-Dimethylbutane 536.817 Cyclopentene 554.718 4-Methylpentene-1 558.019 3-Methylpentene-1 559.720 Cyclopentane 566.121 2,3-Dimethylbutane 567.522 2,3-Dimethylbutene-1 569.523 2-Methylpentane 571.424 2-Methyl-1,4-pentadiene 580.525 3-Methylpentane 584.326 2-Methylpentene-1 588.527 Hexene-1 589.428 2-Ethylbutene-1 599.029 n-Hexane 600.030 t-Hexene-3 601.831 c-Hexene-3 603.032 t-Hexene-2 604.533 2-Methylpentene-2 606.834 3-Methylcyclopentene 609.435 3-Methyl-c-pentene-2 610.236 O13 612.437 c-Hexene-2 613.938 O14 616.239 3,3-Dimethylpentene-1 620.040 2,2-Dimethylpentane 624.4

17

ID Component name Index41 Unidentified 626.042 Methylcyclopentane 626.943 2,4-Dimethylpentane 630.544 2,3,3-Trimethylbutene-1 631.845 Cyclic Diolefin or Triolefin 633.946 Unidentified 635.247 2,2,3-Trimethylbutane 636.048 Cyclic Diolefin or Triolefin 637.649 O17 642.150 3,4-Dimethylpentene-1 643.451 4,4-Dimethyl-c-pentene-2 646.452 2,4-Dimethylpentene-1 647.853 1-Methylcyclopentene 648.954 Benzene 649.755 2-Ethylpentene-1 650.856 3-Methylhexene-1 652.157 3,3-Dimethylpentane 655.358 5-Methylhexene-1 656.759 Cyclohexane 659.060 2-Methyl-t-hexene-3 660.361 Diolefin (hexadiene) 661.562 2-Ethyl-3-methylbutene-1 662.263 Unidentified 663.064 4-Methylhexene-1 663.865 4-Methyl-t/c-hexene-2 666.166 2-Methylhexane 667.667 2,3-Dimethylpentane 669.368 1,1-Dimethylcyclopentane 672.1

/TAME69 Cyclohexene 674.170 3-Methylhexane 676.171 3,4-Dimethyl-c-pentene-2 679.472 1c,3-Dimethylcyclopentane 682.373 1t,3-Dimethylcyclopentane 685.074 3-Ethylpentane 686.075 1t,2-Dimethylcyclopentane 687.676 2,2,4-Trimethylpentane 689.377 3-Methyl-c-hexene-3 694.678 t-Heptene-3 698.179 n-Heptane 700.0

18

ID Component name Index80 c-Heptene-3 701.481 2-Methyl-2-hexene 702.282 3-Methyl-t-hexene-3 703.483 t-Heptene-2 705.484 3-Ethylpentene-2 707.385 c-Heptene-2 710.986 2,3-Dimethylpentene-2 714.887 3-Ethylcyclopentene 715.788 Unidentified 719.489 O29 720.190 1c,2-Dimethylcyclopentane 721.591 Methylcyclohexane 722.492 1,1,3-Trimethylcyclopentane 725.793 O35 729.994 O36 732.295 Ethylcyclopentane 735.296 2,5-Dimethylhexane 736.897 2,2,3-Trimethylpentane 737.798 2,4-Dimethylhexane 738.899 Unidentified 740.2100 O37 742.2101 1c,2t,4-Trimethylcyclo- 744.4102 3,3-Dimethylhexane 745.9103 Unidentified 750.5104 Unidentified 751.1105 1t,2c,3-Trimethylcyclo- 751.8106 O39 752.6107 2,3,4-Trimethylpentane 754.6108 O40 756.5109 Toluene 758.1110 O41 759.9111 O42 761.0112 O43 759.7113 Unidentified 762.6114 2,3-Dimethylhexane 765.3115 2-Methyl-3-ethylpentane 766.4116 1,1,2-Trimethylcyclopentane 767.3117 O44 768.2118 2-Methylheptane 771.1119 4-Methylheptane 772.4

19

ID Component name Index120 3-Methyl-3-ethylpentane 773.3121 3,4-Dimethylhexane 773.7122 1c,3-Dimethylcyclohexane 775.9123 3-Methylheptane 777.8124 1c,2t,3-Trimethylcyclopentane 778.6125 3-Ethylhexane 779.3126 1t,4-Dimethylcyclohexane 780.3127 1,3-Octadiene 782.1128 1,1-Dimethylcyclohexane 784.9129 2,2,5-Trimethylhexane 787.2130 3c-Ethylmethylcyclopentane 788.0131 Unidentified 789.0132 3t-Ethylmethylcyclopentane 789.8133 2t-Ethylmethylcyclopentane 790.8134 1,1-Methylethylcyclopentane 791.4135 2,2,4-Trimethylhexane 792.9136 1t,2-Dimethylcyclohexane 794.5137 t-Octene-4 795.5138 1c,2c,3-Trimethylcyclopentane 797.8139 1t,3-Dimethylcyclohexane 799.0140 n-Octane 800.0141 Octene-2 804.0142 I2 805.9143 i-Propylcyclopentane 807.6144 O52 810.0145 Unidentified 810.6146 O53 812.8147 N1 814.1148 2,2,3,4-Tetramethylpentane 815.8149 2,3,4-Trimethylhexane 817.8150 N2 819.4151 Unidentified 821.0152 N3 821.8153 2,3,3-Trimethylhexene-1 823.7154 2,3,5-Trimethylhexane 826.2155 2,2-Dimethylheptane 827.9156 Unidentified 828.8157 1,1,4-Trimethylcyclohexane 831.4158 N4 832.5159 2,2,3-Trimethylhexane 833.6

20

ID Component name Index160 2,4-Dimethylheptane 835.4161 Unidentified 836.4162 4,4-Dimethylheptane 837.6163 2,6-Dimethylheptane 840.8164 2,5-Dimethylheptane 842.2165 3,5-Dimethylheptane 843.5166 3,3-Dimethylheptane 844.8167 1,1,3-Trimethylcyclohexane 846.5168 N7 849.7169 N8 850.7170 Ethylbenzene 851.3171 N11 852.6172 1c,2t,4t-Trimethylcyclohexane 853.5173 Unidentified 854.4174 I3 856.5175 N12 895.5176 m-Xylene 861.3177 p-Xylene 862.4178 2,3-Dimethylheptane 863.9179 3,4-Dimethylheptane 865.8180 3,4-Dimethylheptane 866.7181 I4 869.0182 4-Ethylheptane 870.6183 4-Methyloctane 872.0184 2-Methyloctane 877.8185 3-Ethylheptane 873.0186 3-Methyloctane 879.0187 1c,2t,4c-Trimethylcyclohexane 880.2188 I5 881.1189 o-Xylene 882.1190 I6 883.4191 Unidentified 884.6192 I7 885.7193 N18 887.4194 N19 888.2195 I8 889.9196 N20 890.7197 Nonene-1 892.0198 i-Butylcyclopentane 892.9199 Unidentified 893.5

21

ID Component name Index200 N22 895.6201 I9 897.0202 N24 898.2203 t-Nonene-3 899.2204 n-Nonane 900.0205 1,1-Methylethylcyclohexane 902.7206 Unidentified 904.1207 N25 905.5208 t-2,2,5,5-Tetramethylhexene-3 906.8209 i-Propylbenzene 912.1210 N27 914.4211 c-Nonene-3 915.7212 I10 916.7213 i-Propylcyclohexane 917.8214 I11 918.7215 2,2-Dimethyloctane 922.0216 2,4-Dimethyloctane 924.8217 N29 929.4218 2,6-Dimethyloctane 931.8219 2,5-Dimethyloctane 933.0220 n-Butylcyclopentane 936.9221 I13 937.7222 N30 938.7223 3,3-Dimethyloctane 942.7224 Unidentified 944.6225 n-Propylbenzene 946.3226 3,6-Dimethyloctane 948.1227 3-Methyl-5-ethylheptane 948.8228 N32 952.6229 Unidentified 953.6230 1,3-Methylethylbenzene 954.3231 1,4-Methylethylbenzene 956.2232 1,3,5-Trimethylbenzene 961.8233 I15 963.9234 Unidentified 964.0235 I16 965.8236 I17 968.0237 1,2-Methylethylbenzene 970.3238 2-Methylnonane 971.9239 Unidentified 973.2

22

ID Component name Index240 3-Ethyloctane 974.7241 3-Methylnonane 977.5242 Unidentified 981.1243 I19 981.8244 1,2,4-Trimethylbenzene 983.5245 I20 985.0246 i-Butylcyclohexane 986.2247 I21 987.1248 I22 988.1249 N37 991.2250 Decene-1 992.8251 I24 993.5252 i-Butylbenzene 995.9253 I25 996.6254 sec-Butylbenzene 997.9255 n-Decane 1000.0256 N38 1002.9257 1,2,3-Trimethylbenzene 1007.0258 1,3-Methyl-i-propylbenzene 1009.5259 1,4-Methyl-i-propylbenzene 1013.2260 I28 1018.0261 I29 1019.0262 2,3-Dihydroindene 1019.7263 I30 1024.9264 Unidentified 1026.4265 1,2-Methyl-i-propylbenzene 1028.1266 Unidentified 1032.1267 N40 1033.5268 Unidentified 1037.9269 1,3-Diethylbenzene 1039.8270 1,3-Methyl-n-propylbenzene 1042.5271 I33 1045.0272 1,4-Diethylbenzene 1045.8273 1,4-Methyl-n-propylbenzene 1046.4274 n-Butylbenzene 1047.5275 1,3-Dimethyl-5-ethylbenzene 1049.6276 1,2-Diethylbenzene 1051.8277 N41 1054.4278 Unidentified 1056.5279 1,2-Methyl-n-propylbenzene 1058.0

23

ID Component name Index280 I36 1059.4281 I37 1062.9282 I38 1065.8283 1,4,Dimethyl-2-ethylbenzene 1068.0284 1,3-Dimethyl-4-ethylbenzene 1069.7285 I39 1071.3286 1,2-Dimethyl-4-ethylbenzene 1075.2287 I41 1079.8288 1,3-Dimethyl-2-ethylbenzene 1080.8289 I43 1084.4290 Unidentified 1087.1291 Undecene-1 1090.6292 1,4-Methyl-t-butylbenzene 1091.9293 1,2-Dimethyl-3-ethylbenzene 1093.2294 1,2-Ethyl-i-propylbenzene 1097.4295 n-Undecane 1100.0296 Unidentified 1102.2297 1,4-Ethyl-i-propylbenzene 1103.4298 1,2,4,5-Tetramethylbenzene 1105.1299 1,2,3,5-Tetramethylbenzene 1109.0300 Unidentified 1112.2301 Unidentified 1113.5302 Unidentified 1116.2303 Unidentified 1118.6304 Unidentified 1120.5305 Unidentified 1121.6306 5-Methylindan 1127.8307 I43 1132.2308 4-Methylindan 1133.2309 Unidentified 1134.7310 1,2-Ethyl-n-propylbenzene 1136.1311 2-Methylindan 1138.6312 1,2-Methyl-n-butylbenzene 1141.3313 1,3-Di-i-propylbenzene 1143.3314 n-Pentylbenzene 1149.4315 1,2-di-i-Propylbenzene 1153.9316 Unidentified 1157.7317 1,4-di-i-Propylbenzene 1159.5318 Tetrahydronaphthalene 1163.5319 Unidentified 1166.3

24

ID Component name Index320 Naphthalene 1168.6321 4-Ethyl,1-t-butylbenzene 1174.1322 I45 1178.3323 I46 1179.9324 I47 1184.1325 I48 1187.6326 1,3-di-n-Propylbenzene 1188.7327 A5 1190.3328 Unidentified 1194.1330 n-Dodecane 1200.0331 Unidentified 1204.6332 Unidentified 1208.6333 Unidentified 1210.0334 Unidentified 1214.3335 Unidentified 1215.4336 Unidentified 1217.4337 Unidentified 1223.3338 Unidentified 1225.6339 Unidentified 1228.7340 1,2,4-Triethylbenzene 1231.6341 Unidentified 1233.4342 Unidentified 1236.3343 Unidentified 1238.0344 1,4-Methyl-n-pentylbenzene 1242.9345 Unidentified 1244.3346 Unidentified 1246.5347 Unidentified 1249.2348 Unidentified 1252.1349 n-Hexylbenzene 1253.7350 Unidentified 1257.2351 Unidentified 1261.1352 Unidentified 1263.1353 Unidentified 1264.9354 Unidentified 1266.3355 Unidentified 1267.8356 I49 1269.8357 Unidentified 1272.0358 Unidentified 1274.3359 1,2,3,4,5-Pentamethylbenzene 1275.9360 Unidentified 1281.6

25

ID Component name Index361 2-Methylnaphthalene 1284.6362 Unidentified 1288.2363 Unidentified 1290.8364 Unidentified 1295.6365 Unidentified 1297.2366 n-Tridecane/1-Methylnaphthalene 1300.0

NOTE - The index can slightly differ per system due to system and column configuration.

26

Qualitative RFA samplePart no. 251160.510

(1 of 13)

27


(2 of 13)

28


(3 of 13)

29


(4 of 13)

30


(5 of 13)

31


(6 of 13)

32


(7 of 13)

33


(8 of 13)

34


(9 of 13)

35


(10 of 13)

36


(11 of 13)

37


(12 of 13)

38


(13 of 13)

39

Material safety data sheetDate Prepared: September 2007

Qualitative RFA SampleChemical Product Information: Qualitative RFA SampleAC Analytical Controls Part number: 25116.510

Gravimetric standard (naphtha)Chemical Product Information: Gravimetric standard (naphtha)AC Analytical Controls Part number: 25115.520

n-Paraffin MixtureChemical Product Information: n-Paraffin MixtureAC Analytical Controls Part number: 25115.610

Mixbox 20002.001 contains all samples mentioned above, 1 each.

Section 1 - Manufacturer data

AC Analytical Controls BVInnsbruckweg 35

3047 AG RotterdamThe Netherlands

Phone: +31-(0)10-462 4811Fax: +31-(0)10-4626330


PAC LP8824 Fallbrook Dr.

Houston, Texas 77064USA

Phone: +1-281 940 1803Fax: +1-281 580 0719


AC Analytical Controls Asia Pacific Pte Ltd61, Science Park Road, #03-09/10 The Galen, Singapore Science Park III, Singapore 117525Phone: +65-6412 0890Fax. +65-6412 0899E-mail: [email protected]

Section 2 - Chemical identity/hazardous ingredients

n-Paraffin Calibration Standard

Chemical name CAS#OSHA

PEL/TWAACGIH

TLV/TWA%MassMass

Petroleum-Paraffin Mixture consisting of:

8030-30-6 300ppm 300ppm Mixture

Alkanes Mixture 110-54-3 50ppm 50ppm0-6n-Hexane

40


Chemical name CAS#OSHA

PEL/TWAACGIH

TLV/TWA%MassMass

Petroleum Naphthaconsisting of:

8030-30-6

300ppm 300ppm Mixture

Alkanes, Cycloalkanes, Alkanes and Aromatic Hydrocarbons Mixture BalanceBenzene 71-43-2 1 ppm 10 ppm 1-3Toluene 108-88-3 100 ppm 100 ppm 2-3Ethylbenzene 100-41-4 100 ppm 100 ppm 4-6n-Propylbenzene 103-65-1 NE NE 4-60-Xylene 95-47-6 100 ppm 100 ppm 4-51,2,3-Trimethylbenzene 95-63-6 25 ppm 25 ppm ** 4-61,2,4-Triemthylbenzene 95-63-6 25 ppm 25 ppm ** 4-61,2,4,5-Tetramethylbenzene

95-93-2 25 ppm 25 ppm ** 4-6

n-Pentane 109-66-0 1000 ppm 600 ppm 4-6n-Hexane 110-54-3 50 ppm 50 ppm 4-6n-Heptane 142-82-5 400 ppm 500 ppm 4-6n-Octane 111-65-9 300 ppm 300 ppm 4-6n-Nonane 111-84-2 200 ppm 200 ppm 4-6Cyclohexane 110-82-7 300 ppm 300 ppm 4-6

Classified by ACGIHasa “Suspected Human Carcinogen” (A2) ** for Trimethylbenzenes

Chemical Families: Hydrocarbons-Chemical Synonyms: NA

Qualitative RFA Sample

Chemical Name: Petroleum Naphtha, consisting of hydrocarbons C4 - C12

CAS Number: 86290-81-5

41

Section 3 - Physical/chemical data

n-Paraffin Calibration StandardSpecial Gravity [H2O=1]: 0.72 - 0.76Melting Point [°C]: NAEvaporation rate [n-butyl acetate=1]: NABoiling Point [°C]: 36 - 280Vapor Pressure [PSI (Reid)]: 7 - 15 Vapor Density [Air = 1]: 3.5Solubility in Water: Insoluble: ( X ) Soluble: ( )Appearance and Odor: Clear to light colored liquid with gasoline

like odor

Quantitative Reference StandardSpecial Gravity [H2O=1]: 0.72 - 0.76Melting Point [°C]: NAEvaporation rate [n-butyl acetate=1]: NABoiling Point [°C]: 36 - 280Vapor Pressure [PSI (Reid)]: 7 - 15 Vapor Density [Air = 1]: 3.5Solubility in Water: Insoluble: ( X ) Soluble: ( )Appearance and Odor: Clear to light colored liquid with a

gasoline like odor

Qualitative RFA SampleSpecial Gravity [H2O=1]: 0.7 - 0.8Melting Point [°C]: < -20Boiling Point [°C]: 38 - 205Vapor Pressure [mbar, 20°C]: 50 - 400 Vapor Density [Air = 1]: 4Solubility in Water: Insoluble: ( X ) Soluble: ( )Appearance and Odor: Clear to light colored liquid with typical odor

Disclaimer: This Material Safety Data sheet is offered without charge to the customers of AC Analytical Controls. Data is the most currently available to AC Analytical Controls at the time of preparation and is issued as a matter of information only, no warranty as to its accuracy or completeness is expressed or implied.

42

Section 4 - Fire/explosion data

This product is extremely flammable! Flash Point: <-40 °CFlammable Limits: LEL: (1.3 ) UEL: ( 7.6 )

Extinguishing Media: Carbon dioxide, dry chemical powder, foam or water fog. Mixture will float on water and can reignite on surface.

Special Fire Fighting Procedures: Wear full protective clothing and self contained positive pressure breathing apparatus certified by NIOSH when fighting chemically related fires.

Unusual Fire and Explosion Hazards: Volatile and highly flammable. Vapor may travel a considerable distance to the source of ignition and flash back. Container explosion may occur under fire conditions.

Section 5 - Reactivity data

Stability: Stable: ( X ) Unstable: ( )

Conditions to avoid: Heat, sparks, open flames, open containers and poor ventilation.

Incompatibility (materials to avoid): Oxidizing agents. Hazardous Decomposition or By-products: Incomplete combustion may

generate carbon monoxide and other toxic materials.

Hazardous Polymerization:May Occur: ( ) Will Not Occur: ( X )

Section 6 - Health hazard/emergency first aid

Route(s) of Entry: Inhalation? (Yes) Skin? (Yes) Ingestion? (Yes)

Inhalation: Harmful if inhaled. Vapor or mist is irritating to the mucous membranes and upper respiratory tract. May produce liver and kidney damage. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting and CNS depression. If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Contact Physician.

43

Eye Contact: Vapor or mist is irritating to the eyes. Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water by separating the eyelids with the fingers. Contact Physician.

Skin Contact: Causes skin irritation. In case of contact, immediately wash the skin with soap and copious amounts of water. Remove and wash contaminated clothing promptly.

Ingestion: Harmful or fatal if swallowed. Call “Poison Control Center” for assistance. Contact Physician immediately.

Health Hazard Acute/Chronic: This chemical is an eye and mucous membrane irritant and central nervous system depressant. Acute exposure causes irritation, gastrointestinal tract discomfort and narcosis.

Medical Conditions Generally Aggravated by Exposure:Preclude from exposure those persons susceptible to dermatitis.

Section 7 - Spill/disposal data

Spill Control: Shut off all sources of ignition. Wear full protective clothing and self contained positive pressure breathing apparatus certified by NIOSH. Absorb spilled chemical in an absorbent recommended for solvent spills of this type and remove to a safe location for disposal. Comply fully with all federal, state and local regulatory notification requirements.

Waste Disposal: Burn in a chemical incinerator equipped with an afterburner and scrubber. Comply fully with all federal, state and local regulations.

Section 8 - Safety measures/equipment

Ventilation: Adequate ventilation is required to protect personnel from exposure to chemical vapors exceeding PEL and to minimize fire hazards.

Respiratory: Use NIOSH approved respirator equipment.

Eyes: Safety glasses are considered minimum equipment. Chemical safety goggles or face shield may be necessary depending on quantity of material and conditions of use. Emergency eye wash fountains should be available in the vicinity of any possible exposure.

44

Skin: Chemical-resistant protective gloves and clothing are recommended. The choice of protective gloves or clothing must be based on chemical resistance and other user requirements. Generally, BUNA-N offers acceptable chemical resistance. Individuals who are acutely and specifically sensitive to this chemical may require additional protective clothing.

Storage: Store in a cool dry place. Keep away from heat, sparks and oxidizing agents. Proper storage must be determined based on other materials stores and their hazards and potential chemical incompatibility. Store in an acceptable protected and secure flammable liquid storage cabinet or room.

Section 9 - Special precautionsUnless otherwise noted, the above information pertains only to the solvent and similar types of components in the sample.

When no toxicity data is provided, it is prudent to handle this chemical as hazardous. Furthermore, since individual chemical hypersensitivity cannot be predicted, every chemical should be handled with due respect.

Section 10 – Transport informationBy air:The samples are transported as excepted quantity.UN code: UN 3316Proper shipping name: Chemical kitClass: 9

Key to abbreviationsACGIH American Conference of Governmental Industrial HygienistsCAS Chemical Abstract ServiceIARC International Agency for Research on cancerLEL Lower Exposure LimitNA Not AvailableND No DataNE Not EstablishedNIOSH National Institute for Occupational Safety and HealthNTP National Toxicology ProgramOSHA Occupational Safety and HealthPEL Permissible Exposure LimitTLV Threshold Limit ValueTWA Time Weighted AverageUEL Upper Exposure Limit

45

Notes................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................

46

Notes................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................

47

Notes................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................

48

Notes................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................

ACG66510.001: 00.01.110

CopyrightThis document is property of AC Analytical Controls, Rotterdam, the Netherlands. No part of this document may be reproduced, stored in a retrieval system and/or transmitted in any form without prior written permission of the publisher.

Documents

Calibration and Reference Sample for AC DHA classic analyzer