CASE NO. 2493F: STANDARDS PACKET, CHLOROPHENOLS; … · Page 1 of 1 Quant ID File: M5248::D3 Title! ID FILE FOR SAS 3101-2493F Last EDIT Date; 861015 12:01 Last Calib Date: 861020

STANDARDS PACKET \ CY^

INITIAL CALIBRATION DATA

Case No: ^

Initial Calibration DataSemivolatile HSL Compou "*s

(Page!)

_Region:_y_[J_____ Instrument ID: 5^^

Calibration Date:Contractor:

Contract No: SAS 9^-^F

Minimum RF for SPCC is 0.050 Maximum % RSD for CCC is 30%

Laboretory ID

Compound

Phenolbis(-2-Chloroethyl)Ether2-Clilorophenol1, 3-Dichlorobenzene1, 4-0ichloroben2eneBenzyl Alcohol1 . 2-Dichlorobenzene2-Methylphenolbis(2-chloroisopropyl)Ether4-MethylphenolN-Nitroso-Di-n-PropylammeHexachloroethaneNitrobenzeneIsophorone2-Nitropheno)2. 4-DimethylphenolBenzoic Acidbis(-2-ChloroethoxvtMfithane2.4-Oichlorophenol1 , 2. 4-Trich)oroben2eneNaphthalene4-ChloroaniNneHexachlorobutadiene4-Chloro-3-M ethyl phenol2-MethyfnaphthaleneHexachlorocyclopentadiene2.4, 6-Tnchlorophenol

2-Chlofonaphthalene2-NitroanitineDimethyl PhthalateAcenaphthylane3-NitroanilineAcenaphthene2, 4-Dinitrophenol4-NnrophenolDibenzofuran

^ p I u-o-tto l Lr o 1

3,4, lo —KJLtoôrtô ^^

^w^"FZO

O.-IiS

+0,31^

C>.V\^.

Q^l.5,5t)l

t

+ •~

t+ -

0.>»o^t 0.3.10

f\W\

"FSO

O.L,-il<;

0.3,01

o.'a-ha

o.imD,5&.^

O.'sq Io.ao^

A5^b

"FBO

O.(o^

o.-y^

o.-au^-

n.4<tt0.53.^

v.-s^s0-\b^

/k6^si

"FIZO

o. ira-i

O.-^L,

0,3-fcO

n.so-i0,S4b

0.5blb, 1-5-1

A625'2-

"Fl60

O.ioOS

O.- 'f?

n. -a^

o.sa0,S4l

0.5'1»3 O.ST1 '3.3Ô.isq 0,''S5 13..1

RF

0.1,3?

0-aq'?

0.353

0,4430,5:3.9

%RSD

b.l

A.G

^ , 1

.^.^3.3

spec"«

*

* *

«

if

*

* «

»

i*

* *

* *

Responso Factor (subscript is the amount of nanograms)RF -Awage Refponse Ftctw%RSD -Percent Relativ« Standard DeviationCCC -Calibration Check Compounds (•I

SPCC •Svstem Performance Check Cornpounds (••)t -Not detectable at 20 ng

10/86

S«mivolatil« HSL Compound*(PUB* 2)

Car Ho: 31 ___Region-_.ijj____ ln»tru... nt ID; .Contractor &-N \J| B_^t-VM&_________ Calibration Oaf:.Contract No: SI\S ft-^.">f-_________

Minimum RP (or SPCC i« 0.050 M»xinwm % RSD (or CCC i» 30H

LabOflOfy IP

CofflpOtJ—d .

2.4-OiiwirotoluMM ;2. 6-Dinitfololiwr0>»lt>ylp>iih*l*u4-ChloR«h»ny)-ph*ny)«hwFluorfM <4-NnroJnittn*4. 6-'Oi'»tro-2-M«niyiph«rH>lN'Nffrowdiph»ftvt»mtn« <1)*-Brofnqp*>»oy*.prwiyt»thwHeK»clltoro6*nz*n«PeniKllOfootwrKXPnenaniftrtn*Antnr»c«r«OrN.ButylpOiniltnPluoranthtn*Pyr»n« iBucirlb«nxylphih«1«f ;3.3*-0fch)probftwdif>«Btnt0<« ihf»c«f>« :lxy2-flhy)h»tyl)Pn:h«Hl« ;r;-hfy»«n« •Orn-Octyl pnttrrra«n»c<a)fluw"lh«f>« •B«fuo<i»fluof»nth«o«B*nio(i|Py'«n«lro«Bc<l. 2. 3-0>Pyr»r>«Diboull. h^nihr*c*n*Bermxa h i|»»fyl»n«

Rftlponw f»elor (ubKrtpi r thW -A»w»fl» ftrioonM FictorSASO •^fctnl RtUiin Sun<ttCCC •C41>brBii4n Crfcfc Co<np<H

(•t 'i'-l^

" 20

i

;

f},h^s

wmountof

naOtvulionuxttl.l

A&a^0!"Fao ,

•

1

R. 1 0

ii

nanoor*fn»|

A5^S^

"FW

h, \\ o

•.

i

A53SI

WiIO

n.r^

S^CC •S»*lfi> fw<9fmw>c» Oxrt Cin'iminJl l—t '"• N« a*i*cfU* •i 20 r>f ^

1 .Ctniiot tx MMfltO Iw <<iw>yl*m»»C

A5a-53-

'"'IM

0.1"3)

w

n<•\Qcl

%nsD

•S.S-?

tree"

•

• •

(

Form VI

Initial Calibration DataSemivolatile HSL Compoup '-

(Pagel)Case No: ^T Ragion: V'l Instrument ID: 5' '°

Contractor: &'NV iR-Oty/M^ Calibration Date: 10 - IS-'?^'

Contract No: SA5 M^ F

Minimum RFfor SPCC is 0.050 Maximum % RSD for CCC is 30%

Laboratory ID

Compound

Phenolbis(-2-Chlofoe»hYl)EthT2-Chlorophenol1. 3-OichlorobenzerM1,4-DichlonibenzeneBentyl Alcohol1. 2-Oichlorobenzene2-Methyfphenolbis(2-chloroisopropyi)Elhsr4-MetnylphenolN-Nitroso-Oi-n-PropylamineHexachloroethaneNitrobenienaIsophorone2-Nitrophenoi2, 4-0im«thv<pheno(Benzoic Acidbis(-2-Chki<-ixthoxy (Methane2. 4-OichlofOphenol1, 2,4-Trichloro6enun«Naphthalene4-ChloroaniNiwHeicachtorobutBdIene4-Chloro-3-M«thY<ph«r>ol2-Melhy(naphtnal8tMHexachlorocydopentadiorw2.4. e-Trkhloroptw'nol2,4. 5-Trichlorophenol2-ChloronaphUialene2-Nitroan>lin«Dimethyl PhthalaleAcenaphthvfene3-NitroanilineAcenaphthena2. 4-Ojnitrophenol4-NitrophanolDibenzofurana-^nnopt .ai 0.<o0l 0.(o0^ &,S^-S O-55'4 0.<><4-3 O.-SI S-.R3,-1,1,-^ôwoftl^nc, 0.11^ 0.3S4 0-ÔT O.'^l 0.1?3> O.SC^ ':^.14

A6^%k

"F20

O-llS

+D.STS

O. SI

&.W0.660-

+t+t

^S33>-7

"FSO

0.'^5^

0-5SH

ft.^fl'i

0,5'090-S4^

A5S51

"FBO

OilO'3)

O.SI'?

0,1-TD

O.S^0.5^^

A6l3q

'"'120

o.to-a-k

o.2>au-

o.aô

0,55?b.S-kl

ASô

BF160

O.k04

0.30?,

O.S55

0.5->3-0.&'3?>

RF

O.blfc

D,?>12

h.-^b

ft.&fln.^sz

SRSO

•7.t^

n's

1 1 . i

3.q.n

ccc-SPCC-

*

»

4 *

«

«

4i

«1 •

*

«

* «

* *

SPCC •Sysfm Perfonranc* Chack Compoundi (••It -Not detectable at 20 ng

10/86

S—nivototll* HSL Compounds

Of No: .£d3- -——R.owl:—Contractor t-N\/n2.0tWM&

(Pao-2)lil_____ lnstru*..<nt ID:

Calibration n.... lO-IS-'gtoContract No: -Jo^-Oi- '?0-?{'7

Minimum RF for SPCC i« 0.050 Maximum % RSO for CCC is 30%

LriwtorylD

Compound ,

2,4'OinnrotohMo*2. 6-OinnroUllMn*0-thytphih*l«M4-Chlon>(iftiiyi-J)hw>y>th»<f)uof»n*4*Nitro«m1m«». 6-Oinitro-2-M*i<iyiphw>ol;N-NitRMOdiptMnvlMnm* (1 >4-Bro(nop>Mnyl-p«i*nyltr>*fHeifchlor6b*nrn«P>nt*cn(Mopn*nolPnenantnr«n« cAnthfcww ;O-N.BulyiphlhtldHFlwo'*niMn«Pyr.r>.ButYlb«niyiph)h*l«r ;3.3--3B^»)p.a>-B'<l<0«B«fua;l>ikathr*e«h* :tlil42 •fthy)h*«y))Ph^*l*t*C iym« 'Dm-ow pnitui*ra*nw(b)F1u6f>mh*h* iBouodil luofntlwB«nioc>PyT«n*ln0*n«(l. 2. 3-cdlPyrtn*Oitunai. ht*nihr»c«n«BtlUUf r iPtryttn*

A%2-31tf

RFjg

rt

o*ot^

ASis-iMSO

o.\^

ASSS?

»F»o

n.isl

a

A6231

HF»2o

n^'+f,

ff.

•

:

.

A 6 340

"^•0

0,1^ \

.

,

nr.

ft.-(3^.

•

%RSO•

• 1 4 . - 1

:

tefi.xrcc-

•

- ••

•

•

• •

Btioont* ficw |>ubKn«t ii in* •mourn o* >una«r*nnlBT •A«w9* Hfioom* FtctorVISO •f«»c«m AtlJinw Sundird 0*v>Ji>anCCC -CJIitVttian Clwco Ca<neoun<» I.I

w ChtCk CMn»M>n4* 1—1S^CC-Snt •NM dfcfbl* M 20n«

(11-C*nnM 6* W»*(*IM <m» 4w>Mnv«wnin*

"•3—M0•^—1

0

STANDARDS CHROMATOGRAMS

Cal ib ra t ion Report

T i t l e ; ID FIIEFDR SAS 3101-2493FCalibrated: 861020 11:;;

Files;

Coipound

l-FLUOIiOfWa (SUKROBffE)2-ChIorophenQi2,4-Oichlorophenol4-Chloro-?'i«thy[phenol2,4,6-TRlBaWHBa. (SURR)2,4,(-Trichlor<l phenol2,4,5-Trichloropheni)lPEntichlorophfnol

: >fl5248RF

U.tt

.((1393

.71453

.28879

.272511

.20953

.UW

.50110

.8(490

XB249RF

25.1)0

.59U4

.684(1

.30138

.2(34<

.20765

.47784

.52805

.10252

>05250RF

40.110

.57477

.(4926

.29815

.24176

.16637

.49830

.52907

.11002

)d525IRF

60.00

.56B58

.62079

.30444

.25964

.18663

.50672

.54634

.13477

>ft5252RF

80.00

.56323

.60513

.29486

.22815

.15660

.51270

.54147

.13115

RRT

.643

.952

.9831.1871.142.877.884.989

RF

.57871

.654(6

.2975;

.25310

.18536

.49271

.52920

.10867

« RSD

3.2DO6.8762.0347,061

12.8523.8793.321

25.793

RF - Re»pon5e Factor (Subscript n amount in LIE/MIFE)

RRT - ftveraqt Relative Retention Tine (RT Std/RT Istd)

RF - Average Response Factor

Page 1 of 1

Q u a n t ID F i l e : M5248::D3

T i t l e ! ID F ILE FOR SAS 3101-2493F

Last EDIT D a t e ; 861015 12:01 Last C a l i b D a t e : 861020 11:54

RT Uindou (•*•/- m i n )Max Hi ts/ 'Compound

M i n i m u m AreaPeak/Base Peak R a t i o

Slope S e n s i t i v i t y - . 200S u b t r a c t i o n M e t h o d

A u t o Odsl M e t h o dU n i t s of Cone

N u m b e r of Compounds

Comp Compound R e t e n t i o nNo. Name

1) *04 1,4-DICHLOROBENZENE2 ) 2-FUJOROPHENaL (SURROGATE)3) 2-Chloropheno14) »D8 NAPHTHALENE ll .e2(5) 2 , 4 - D i c h l o r o p h e n o l6) 4 -Chloro-3-n>e thy lphenol71 *D10 ACENAPHTHENE 17.2K8) 2,4,6-TRIBROMOPHENOL (SURR)9) 2 , 4 , 6 - T r i c h I o r o p h e n o I

10) 2 , 4 , 5 - T r i c h l o r o p h e n o l11) •D10 PHENANTHRENE12) P e n t a c h l o r o p h e n o l

.503

30050. 00 fi

15

UG/UIPE

12

Mi n

8.5.7.

11.14.

19.15.15.21.21.

•

16 (25C77 (

62(03(

66 (09 (22(63(40 (

(Re

1.

1.

1.1.1..

1.

Time1 )

0 0 0 )643)952)0 0 0 )983)187)0 0 0 )142)877)884)0 0 0 )989)

R.F .

1 . 0 0 0 0 0.57971.65486

1.00000.29752.25510

1.00000.18536.49271.52920

1.00000.10867

Cone

40.50.60.40.60.60.40.50.60 .60.40.60.

^000000000000000000000000

:'3-^0—1

0

* Compound is [STD

O p e r a t o r ID; USE-R8O u t p u t F i l e : '••Ab24U: ; L3D a t a F i l e ; > f t 5 2 4 8 : ; E 2N a m e ; lOPPM STD 1873M I S C ! LnC 5996 3101-2493F

QURNT REPUKT

Uuant Ke'v': 4 Quant T i m e :I n ] e c t e d a t :

U l l u t ion Fac to r - :

8 6 1 0 1 5 22 :3a9 6 1 0 1 5 21 :b5

1 . OU

BIHtl'?

I D F i l e : »ftb248T i t l e : I U F I L E FOK SflS 3101-2493FLast La 1 i b r a t i o n ; U61015 12:3?

Compound R . T . Scan# Cone U n i ts

1)2 )3)4)5)6)7)8)9)

10)11)12)

»D4 l ,4-OtCHLQKOH£NZEN£2~FLL)ORQPHLNGl C SURROGATE)2 ~ C h l o r o p h e n o 1

*D8 NftPHTHflLENE2 , 4 - D i c h l o r o p h e n o 14~Ch lo ro -3 -me th 'y ' l pheno 1

*D10 ACENAPHTHENE2 , 4 , 6 - T R I B R Q M O P H E N O L t S U R R )2 , 4 , 6 - T r i c h l o r o p h e n o 12 , 4 , 5 - T r i c h l o r o p h e n o 1

*010 PHENANTHRENEP e n t a c h l o r o p h e n o 1

8.5.7 .

11.11.14.17.19.15.15.21.21.

1322737957O U196406216?38

49 U20741?!B4682';'

1061137116U9116411.7818021779

2321B1175273

41475479246

3461)032649

220531577602580027627

4272136931

4056

840

7.20

4059

66

403

.00

.02

.70

.00

8 ' '. 3 D. 0 0.88.47.83.00. 10

UG/U1PEUG/U1PEUG/U1PEUG/UIPEUG-'UIPEUG/N1PEUG/UIPEUG/mPEUG/HIPEUG/U1PEUG/-UIPEUG/UIPE

9310099

10U9/'

10U10Ul ou9799

10U10U

Compound \s ISTD

TflTOL IQN CHBnHOTnCRBIIFilt >n624e 41.0-588.0 aftu. 18PPM STD 1873 LMC E996 31fll-2493F

TIC

seeeee-

788899-

fci' 5600800- g g

Q; 0^

seaaHB- & 5

: ^ ^ T

4eaeea- ^ •J- t

388Bee- "' Mo

SBBBBB-

leueâ-

8-

180 288 380 488 588' ' ' ' ' • • • • ' • • • • • • • • • ' • • • - ' • • - • ' • - • • • • • • - • • - • - • - • • • • • - • — — — — — — — — — —

a0

'"-———^4le ' s'.e ' 6'.e ' 7'.e ' a'.e ' y'.e ' l8.8

I . AJ^ . i1l ill

6BB 788

,

.î

i

Oat a File; >P|$248; : E2Name; IDPPtI STD 1873nisc: LMC 'V9V6 3101-249.»h'

Id F i l e : W52^QT i t l e : I D FILE FOR SftS 3101-2493FLast C a l i b r a t i o n : 861015 12:3^

Operator ID; USEK8Quant T ime: 8 6 1 U 1 5 2 2 : 3 aIn jec ted a t : a6^01 t > 2 1 : c ' 5

r i C page 1 of '7

Tnrni in^ rnpnfioTncffoMT;!- > ° 5 2 4 S 4 1 . » - 5 9 B . e a«u. 1 9 P P M STB 1B73

T I CLHC fc99A 3tai-*4*3f

TICaee iaea laee i48e

saeeea-j—'—'——u^————' 1 • • ' ' — — — — i . i . . i i . . . . . . . . i . .

7QflAAA-

bO^tfUU-

S488888^

3ARRA9-4- - - - ^ „

2BB39B-

lueukJu-

ai i . a ' 12.e 1 3 . B ' 14'.e ' is'.e ' i6.e ' i7'.B ' le.e

UJ |JJ•K a

1

1.11 ? 13

|ll 1 |t=1 ji c ^-y| i

li MA .1 IM i i,

1 -sS iRi? -Si

j

§a€.

j

1

IJ

Data Pi la: ;W1W. : E2Name: 1UPPH fciTD ia?3Misc: LI-IC 5996 3101-2493F

Id Fi le; #W2WTi t le ; ID l-'lLE FOR SftS 3101-2493FLast Ca l i b ra t i on ! 9 6 1 0 1 ? 1 2 : 3 3

Opera tor ID: USEK8Quant T ime: 9 6 1 1 1 1 5 22 :38I n j e c t e d a t : 8 6 1 U 1 5 2 1 : 5 5

T I C page 2 o t 5

TOTfli.. inn rMpnuOTriRppMFl;- >S5245 4i .B- s^^.9 aau. 1BPPW STD 1873 LPIC SW6 3181-2493F

T I C1603 1888 2888

e e B B a e - i — ^ ^ — ' ' • • • 1 • • • • ' • — • • ' • •—^-1—'—'—' ' • ' ' ' ' ' '

raeieee-

60BBCB- ^ g

snayua- ^ S

488908-1 g 0

13aBeeB4 S1 ™

soeaoB-

IBBeUB-

Ju^te'.B

» ,±

g 3s S

fi •S

V

lhJ' l19.0 20.0 ' 21.0 22.0 23.0 24.0 25.8

I ne l l ,

1^

1 1 1 ! ! 11 I I! -'L", \ i \

Data F i l e ; ?(W248: : E2N a m e : 10PPM STO iy73M i s c : Lrit: 5996 3101-2493F

Id F i l e : »ft5249T i t l a : I D F I L E FOR SftS 7101-2495FLast C a l i b r a t i o n : 861016 12:^3

O p e r a t o r I D : USER8Q u a n t T i m e ; 86101^ 2'2:?9I n j e c t e c ) a t : B61U15 21; t;6

T I C page } of ?

TflTOI InN rHRnMOTnCRQMlr,i. •.acma—\ i r-CBO n .„,——IBPlM tTB Ifl-f?—————l.Ht- 64^? Al 61 -i4W I

TIC 12288 2488 2680 28.88

s e B e e B - i — ' ' ' ' ' • ' ' • ' ' 1 ' • • • ' • ' ' • ' • ' • • ' ' ' ' • ' • ' ' •

17a«199B-

6B03BO-

SBBaue-

488898-

aeeeee-

zesieoB-

'^l t1 1 11 11 1 fll .1, 1. ^

e^,-, ."•p.,, i ^ , , , , , , , , , , . , , , , , [•;,,,.,.,,.,^,. i,,,",,,.. i . ,..,....,, ' ; . ,,!. ' ,26.0 27.B 28.0 39.B 3B.0 3 1 . 6 32.6

(1

11

i L i i

Data Fi le: >ft9248::E2Name; lOPPII STD 1B73nisc: 1-M(- 5996 3101-2493F

Ic) F i l e ! tft624aT i t l e ; 10 F I L E FOR SftS 51U1-2493.FLast Lal ibrat ion: 8 6 1 0 1 5 1 2 ; 3 ?

Opera tor ID: USERSQuant T ime; 8 6 1 U 1 5 22 :3aI n j e c t e d a t : 8 6 1 0 1 5 21: I7b

T [ C page 4 of 5

T"TOI, 1 Q H fHBnMOTnMnMIf;'- \awm;HA-C(»a o •_,.——1 ri M ^yft—I"???

caaooa-

kUBBaH-

4ee9B8-|

3BBaB»l

U J

33.» 34.6 38.6

Data Fi le! >A^2'»8;:E2Name: lOPPn STD 18/'?Misc: LtH- 5996 3101 -2493F

I d F i l e : *W24aT i t l e ; 10 F I L E L FOK SflS 3101-24y^FLast C a l i b r a t i o n : a610l5 12 ; J3

Operator ID; USERSQuant T ime : 8 6 1 U 1 5 22:?8I n j e c t e d a t : 8 6 1 U 1 5 21 :5 ' ' ?

T I C page •? of 5

O p e r a t o r 10: USER8O u t p u t F i l e ; •~f t5249; ;L3U a t a F i l e : > f l 5 2 4 9 : ; E 2Name! 25PPI-1 STO 1874M i s c ; LFIC 5996 3101-2493F

QURNI Rfcr'URT

Quant Reu: 4 Quan t T i m e ;I n ) e c t ed a t :

D i l u t i o n F a c t o r ;

861U15 23:2hS61U15 22:4?

1 . UU

H1L*l6

10 F i l e : 1tft5248T i t l e : I D FILE. FOR SflS 31Ul-2493r'Last C a l i b r a t i o n : U61015 12:33

Compound R . T . Scanlfr Cone Units

•D4 1,4-UICHLOROBENZENb 8 .17 487 266U19 40 .00 UG/UlPt-1 )2 )3 )4)5 )6 )71B )9 )

1 0 )1 1 )12)

2-FLUUROPHENOL ISURROGflTE) 5 . 2 6 204 197127 54.82 Ul37l«)lPE2-Chlorophenol 7.77 44U 114167 2U.85 U13/U1PE

»08 NRPHTHftLENE 1 1 . 8 4 843 514915 40 .00 UG7U1PE2,4-Oichlorophenol 1 1 . 6 3 823 96992 1B.78 UG/WiPL4-Chloro-3-methylphenol 1 4 . U 5 1U58 94788 2a .07UG7UlPE

•D10 ACENftPHTHENE 17.24 1368 222614 4 U . O O Uli/UlPb2,4,6-TRlBRDmPHENOL tSURR) 19.70 1606 57781 b9 . 34 UG/UtPE2,4,6-Tnchlorophenol 1 5 . 1 1 1 1 6 1 66484 16 .53 UG/UIPL2,4,5-Tnchlorophenol 15.24 1174 73469 17.99 UG7UIPE

•Dia PHENMNTHRENE 21 .67 1798 4U3663 4 0 . 0 0 UGÛIPEPentachlorophenol 21 .43 1775 25864 12 .22 LIG7U I PE

* Compound is ISTD

TOT01 I D H CHRflMOTflCROMF i l » > n

sooaae-

768666-

boaaea-

seaeae-

dARAA^ fe 6 -3

^3S88BB- ^

ieaeaa-

isaeM-J

£249 4i.e-see.e .»u. zsipt-H STB iS?4 • -T I C

188 zee 368 486 SBB

HJ

g s1 1& 1 I§ ? .

^ ^ L . u4 .B ' s.e ' s.'e ' 7'.» ' e'.e y'.e ' le.fl

!i

\ v

LHt S'19<i 5iai-i4»31'

609 789

J i ' 1i!<J!!l I'

Data F i l e ; >fl5249!:£2Name; 25PPM STD 1874Miac: LMC 5996 31U1-2493FId F l l a : »Pl6^4aT i t l e : ID FILE. FOR SftS 3101-2493FLast La 1 i b r a t i o n ; B61U15 12;33Operator I D : USEKaQuant l i m e : 861015 23:25Injected a t ! B6101? 22:43TIC page 1 of 5

TnTni IQH rHPOHpTncBOM__________fiie > H 5 2 4 9 4 1 . e - 5 B B . f l ami. ?gt'p'h i+fl 16?4—————LMC !;SS6 3181-2403F

TICaae la eg izee , , i489

eaeeee-l

PufiBBB-

1 a K6BBB8B-1 a l ^

] F IEaaeee-l ;g g

I s i I sJ ; s f i^40eaR«-l ! a. gsB )ti f a 130^ 5^1 > £§!,

I -1 ! •:'1! i 1 c.-s—^ r^ ( ?i! i S -oI in i î ij ti 8 -+i188888-1 l j ( | ||(1 | , ) |||( I 1 1 M S 1 0

ii h i» i r[|j (| fi nn , j ..-iJJULJW, 11 , , . [ ''L'LJJLL'lHiL o

11.B 12.B ' 13.8 ' 14.8 15.8 16.9 ' 17.8 18.8

D a t a F i l e : > f t ' > ^ 4 9 : ; E 2Name: 25PPn STD ia74Misc: LMC 5996 3101 -24931 - B1L1H6

I d F i l e : WW^âT i t l e : 10 F I L E FOR SW 3101-i493FLast C a l i b r a t i o n : 861015 12:-?3

Opera to r ID: USERSQuant T ime: B 6 1 U 1 5 23:25I n ) e c t e d a t : 861B15 2 2 : 4 3

T I C page 2 o t 5

-^

-£D

O

r-1

^-

n Z

0-

"3

C

"0

tt - &

>-

Qi

an

^

-OlC

B

W'-

*-

V

3

i-f(

B3

-1

rt

.—

T1

Ot

IC

B-o

n '•+

Q) (P

- ••

"a,

„„

(-

)"

- "n

tQ

(11

-fO

Ql

(I r

~N

J^

(D

Q.-

-)

—

—

••

3's

Tl—

3 '-

o

n -o

(t^

ai

(D-—

cr

•#

x"

^"

o

^-Î

? ^

3o

.. ..

ai

— iJ

i •<;

••^

-r-

^ r

K:

^ (

J: J

>co

ix-c

^r

i-fc

- o'

-isr

-Jl

Ch

Ch

UI

0

CC-

0^

3»-*

^ n

3

~n ^

^<

OO

X

"0

(-

'•h

^'O

»->

1-*

CC

;C

0 f

fi

••J1

•J1

CC

. t-

\J

••

Cr'

U3

1 ^ n

^ K

; h-

* I>

hJ

M

M ^

0

U"J

-

'JJ t

s3<>

J £•

•-

ro

tJ

Ai

n^

î

to

,^

®a

<

B®

O®

O

oL

(O

C.

Gl

-S

OO

CE

-a

i,

,S

Oi

CS

iS

SO

Ci

O

-®

si

m

.»

®

si

a'

<&

^?.

...?

....

?...

.?..

..?.

...y

....

?.^.

?,..

.?0).;

a>'

(B ^

N •

Sl.;

5 :

r\) •

0) N rJ- a

^

"- 0 ^

M *„ a ro 01..

Q

^ S-l

'""

^sss

——

——

——

2.4

,6-T

R6f

BMO

PHO

H)L

(SUR

H(

=:=

.—=

——

—

/==—

Fan

tach

loro

phtm

ol

ro -fr tD -fr 'D (DS

;°g

" (• El

(:

.

-I'M

i-«.J

10

T> •O

®

^B »

. 'B l— •ZN

'~

>

g <"

S S 'T

-

•JJ <S 1 M 4. •J U

TOTOI ION rHffOMOTni;ffOM

seeaee-

786866-

6eeeae-

seaeae-

4aaeap-

388888-

1zeeaea- | | j| 1

leaaee-

0.

524? A ! .9-5S2288

I - 11 11I []1 1 11 1 1 III 11 1 1 1111J I , i [ (i n ('[ ,)! ,ll )1

26. e

aa.a .,., t'EfipM <Yti l6?4 Lht; 6<>9(> S)61-a49SFTIC

Z498 26BB 2688; . . . J . 1 . . . . 1 - . . . r . . . . i . . . .

1 ll i 1

{ l1 S 1 ia7'.e ' ae'.B ' 29.e ' 3a'.e ' BI'.B ' 32'.e

Data Fi le: >fl5249;:E2Name: '25PP(1 STD 1874Misc: LMC 5996 3101-2493F

Id Fi le: M5248T i t l e : ID FiLE FOR SAS 3101-24y3FLast Ca l i b ra t i on : 8 6 1 0 1 5 1 2 : 3 3

Operator ID: USER8Quant T i m e : 8 6 1 U 1 5 23:25In iectea a t : 8 6 1 0 1 5 22:43

TIC page 4 of 5

TOTai IOM l-HPnHPTOGBOMF l l s >flS24? 41.B-S8B.e

saaaBs-

reeeee-

fcaeeaa-

EBB9B8-

48MeB-

388666-

zeoeea-

leaeee-

B.

3Bee

.)). ll At A33.6 '"34;e"

a»u. ZSfrPM ift 18?4TIC

. , 32Ba

3S'.e ! 36.9 ' 37.B

——LHC 6^6 Sl6l-^4il3r

34ee

3B'.B ' 39'.0 ' 4B.e

Data Fi le: >f t5249; :E2Name: 25PPn STD 1874Misc: LriC 5996 3101 -2493F

Id F i l e : tA5248T i t l e : I D F I L E FOR SftS 3101-2493FLast Ca l i b ra t i on ; 861015 1 2 : - 5 3

Opera tor ID; USBKUQuant Time: 8 6 1 1 1 1 5 23 :25I n j e c t e d a t : 8 6 1 0 1 5 22:43

T I C page 5 of 5

O p e r a t o r I D ; USERSO u t p u t F i l e : ''Pi^ZSQ::!^Data F i l e : >f t5250: ! E2Name: 40PPM STO 1875Misc : LHC 5996 31U1-2493F

QUftNT RtPURT

Quant Kev: 4 Quant T i m e ;In jected a t ;

D i l u t i o n Factor:

861U16 00:13861015 23:51

l . U U

BTL1H7

ID F i l e : 4W5248T i t l e : ID FILE FOR SAS 3101-2493FLast Cali b r a t i o n : H61015 12:33

Compound R. 1. Scan* Area Cone

1)2 )3)4)5)6)7)9)9)

10)11)12)

*D4 1,4-OlCHLOROBENZENt:.2-FLUOR13PHLNOL (. SURRQGftI £32 - C h l o r o p h e n o 1

*U8 NftPHTHftL£NE2 , 4 - D i c h l o r o p h e n o 14-Ch l o r o - 3 - m e t h ^ J i p h e n o 1

*D10 ACENAPHTHENE2,4 ,6 -TRlBROnOPHENQL t S U R R )2 , 4 , 6 - T r i c h l o r o p h e n o 12 , 4 , 5 - T r i c h l o r o p h e n o 1

*D10 PHENANTHRENEPen tach t o r o p h e n o 1

9.5.7.75

11.11.14.17.19.15.15.21.21.

14W

U O60U O206507206139

4BS207450843824

1U67136716D51161117317961774

27610919837317926649702314S1891201601936834028096512

102472284848

31340

4053314029294047.5427.57284020

. 0 0

.31

.64

. 0 0

.73

.47

. 00

.83

.00

.99

UG/'UIPEUG7U1PEUE7U1PEUG/U1PEUE/U1PEUG/-U1PEUG/UIPEUG/UIPEUG/U1PEUG/U1PEUG/U1PEue/UIPE

9'>10U99

1 U U9^-

louolOU,.^

'"B99",9 7 ^

loP10U

• Compound is ISTD

3N3ZH

3aa)31H3iO

'

|OJi|dttn)|io-?

-

bwsoifens) "lONBHdoawnJ-z -

TOTBI ION CHROMOTORBflnf";!" >B5aS8 4!.e-5B".B anu. 4(i^•llt1 STt l6?S LMI* 5*96 31B1-2493F

TICeae laea izea ioe

i'eutjidki-1

6aaB8B-l f

..a-sae-

40euk!i0-:

saBBea-

2Beeee-

leeeea-

ll.B l£.0 13 .0 14'.e 15.8 1 6 . 0 1 7 . 0 18.0

0

" ^•3§ : i |

laI! Es fs!.sa

A"H

i t| » ]{jy^Li1111H'lIII

! S 1

\ ^fK

'• JC |

\

5aSai•nl'•i

i'I1

1A 1 1 III 1 1n'UluLii

s.

1

3cr

,1 Hi

11 fl! !

~*i

Data Fi le! >A5250 : :E2Name: 40PPn aTD 1875tlisc: LriC 5996 3 1 0 1 - 2 4 9 ? F

Id F i l e : *fl524BT i t l e ; I D FILE FOR SflS 3101-2493FLast C a l i b r a t i o n ; 861015 12:35

O p e r a t o r I D : USEKaQuant T i m e : 861016 U 0 ; 1 3I n i e c t e d a t : B6101? 23:31

T I C page 2 of 5

TOTOL inn CHBriMflTOGRnMr;ie >R525S fl.S-sse.9 axu . TIC

70EJU00-

bBBBBB-

Eeeeee- S •••

4eeiaaB- B g

j|300^0^

238886-B

lliUBUH-

1 [ IH 1

1 8 . 0

i j liii ll | s-m11 1 1 1 1 1 1 1 11 J 1 1 1 1 1

1

1600

19.e ' ze.e ' 21 .e ' 22.8 23.B

§

Ei (A

!?;1

1 1 »'teiu

4B|l'»iM STtiaae 2e.eB ^

1 ? 1 1 1

1 '1 'I'lll

•&•a g• '=!a U1 1,11,•s Bl

K ! "

iS-'fc LMt e'l*6 i)»l-24?SF

124.8 ' 25.e

D a t a F i l e ; > r t5 '250 : :E2Name: 40PPM STD 18751-lisc: LMC 5996 3101-2493F

Id Fi I e ; ^Pi524aT i t l e : I D F I L E FOR SflS 3101-2493FLast C a l i b r a t i o n : a61Ul? 12:35

Operator ID: USERt)Quant T ime: B 6 1 U 1 6 U U : 1 3I n j e c t e d a t : 861U1'; 2 3 : 3 1

T I C page 3 of '?

TOTOI ION l-HPOHOTnCBQII

?eeeee-

688908-

Eeaaee-

ieaaee-

seaaea-

2BBBBe- 1 | 1

iBMiiBB-

0-

5253 ^,.a-6oii.9 û. 4ftPpM ST11 1 6 7 6 LMC e9yi> 3W-mMTIC

2288 ^ 24.88 ^ 2688 , 2683

1 J I 11 Jli l l i n" , fi, " n \'[ i26.8 27.8 ze.8 25.8 38.8 ' 31.8 ' 32.B

iLI'I

Data FiIe: > A 5 2 5 0 : : E 2Name: 40PPM STD 1875MISC! LMC 5996 31U1-24931-

Id F i l e : tft^248T i t l e : ID FILE FOR SAS ?101-2493FLast C a l i b r a t i o n ; 861015 l2:?3

Operator ID: USERBQuant Time: 861016 00:13In)ected a t : 861015 23:31

T1C page 4 ot •7

TOTRL IQH CHBQMBTOegOM| File > f lS25941 .B-5M.9 ru. 4«PPH STD~]e7E1 TICI 3e0B 3298

Lht EW Sl6l-54*9r3400

40UUhm-(

380889-

34.e 3S'.B 34.8 37.9 ' 33.

Data F i l e ! >ft5250::E.2Name: 40PPM STD 1H75Misc: LMC 5 9 9 6 3101-249-SF

Id F i l e ; <M524BT i t l e ! ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n : 861015 1 2 ; - ? 5

Operator ID: USER8Quant Time: B61U16 U U : 1 3Iniected a t : 861015 2 3 : ? 1T I C page 5 of 5

O p e r a t o r I D ; USERS U u a n t Keu: 4O u t p u t F i l e ! "R'7251: :LjDa ta F i l e : XW251 ; : L2Name: 60PPM STD 1876nisc: LMC 5996 3101-2493F

Uuant Time:In jected a t :

Dilution Factor;

ID F i l e : M5248T i t l e : 10 FILE FOR SAS ?101-2493FLast C a l i b r a t i o n : 861015 12:?3

ti61Ul6 01:111861016 00:18

1. U O

BTLtIB

Compound R.T. Scanft ftrea Cone

•04 1,4-01C1-ILOROB£N2ENE 8 . 1 6 49U 2'''0754 4 U . O O U13/U1PE1 )2 )3 )4)5 )6 )7)8 )9 )

10)11)12)

2-FLUOROPHENOL (SURRaGATE) 5.25 207 20573.7 52.00 UG/U1PE2-Chloropheno 1 7.77 452 270745 4'?. )8 UG-'UIPE

•08 NftPHTHALENE 11.82 U45 539647 40.00 UG/U1PE2,4-Dichlorophenol 1 1 . 6 3 827 246433 45.53 UG/U1PE4-Chloro-3-methylphenol 14.03 1U59 210171 47.47 U6-'U I PE

•D10 ACENflPHTHENE 17.21 136B 224154 40.00 UGÛIPE2,4,6-TRIBROMUPHENOL (SURR) 1 9 . 6 7 1606 52292 53.33 UG71-IIPE2,4,6-TnchtQrophenol 15.10 1163 170376 42.06 UG/UIPE2,4,5-Tnchlorophenol 15.22 1175 185696 44.66 UG/U1PE

•010 PHENflNTHRENE 2 1 . 6 3 1797 341638 4U.OO UG7U1PEPantachlorophenol 21.41 1775 69064 38.57 UG7WIPE

• Compound is ISTO

c, fo T s6ed 3;^

8T:00 910198 :ie paiaatu;T01TO 9TOT.9B :s"'il luen|3

aM3sn :ai JoêJsdoti'-ZI STOT98 :UQI le-iqi IBÎ ise-|

d£6t'?-TOT£ SWS a0d 3"11 .-1 01 : s 11 11

B^7.W* :ai IJ PI

df6t'S-TOT£ 966S Dy"! :3si^9<;8T. QIS UddD9 :»U1BN

S3! !TSSW< iai IJ eêQ

a-.ai ^ a-^ ^ a's , e;^ a-^ ^ a-^s ^ e^»

EM ^ faeaea?

@ r 3 heeeee^^ -§ â • a t-eBBBBB

-eeaeeb

-eaaBBBi

1-rancxaoT T

•eaeBBS!

Jesrz-iBie S663 3in 9Z8I ais uddei •"»* a-aBS-a-n- rsssb< *IIJ

''iini\.r~\r

eez

^W ? inil ,i»

I1

a " a

ea9 eas ' eat- eee aes ' aei311

niir\ ("vî———--r1iiiEQ

11 1-668001

t-aaBBBS

';' t-eeeeecp§ -Boesot'

n•eeeees

TOTfll rOH rMROMOTnKPOKf-ilr ^BKS! 41.9--=9e.e MU (.WM STt l5^ LMt SM6 aiAl-S49Sr

TICsae ^ ieee . izee 1499

izeeaea-jj

116363,1j

lUBHBljB-j •5

9eeaee-| -^

aeeeeB^ ,i &

?eeeee^ iy

fiaaasaJ

5Mee9-^

•isaasa'j

5y680B-

28HMBB-

leeeee-

1 1 . B 12 .a 13.e 1 4 . e is.e I&.B 17.3 is.e

llfi

s .11|iillM

llll'l11 1 1 1 ' 1

J l ,mi

?' £») 0^ LiJ

î

i

-ii§1

in uill jilll?ii! ifin n A |iiiiiiimi

E

1 1111 Idi nSi

U 1»l-(

InData F i le : >Pl5251: : E2Name; 60PPM STD 1876Misc: LCtC 5996 31t)l-2495F

Id F i l e ; W?2âT i t l e : 10 F ILE FOR SftS 3101-2493FLast Ca l i b ra t i on ; 861U15 1 2 : ^ 3

Opera tor ID; USER8Quant T ime! 8 6 1 0 1 6 0 1 : 0 1In iec ted a t : 8 6 1 0 1 6 0 0 : 1 8

T I C page 2 of 5

TOTOl. ION CHROHSTnBROMni- •>B5"' 4' o-sen.e mu. 69PP" STD 1876 L M C

T I C16.69 ^ ie»e ^ 2BBB ^

izeBBae-j

liaeeae-

l aUBBUU-

998088-

saeBBB-

788888-•

MBBBC-

SBeeae-:

4S8SSS-

389889-

zeeiaee-

ieeee8-

e - ' " l • • • • l • • • • l • • • • l • • • • l • • • • l • •le .e 19.8 ze.e

•sz-

t1

1

1JJ

52

IIIus-^1

1 , 1 ^ ll!1 It

•g^g-

^ t's r

21'.B ' 22.B ' 23.6

1

1

]

;

E996 3181-Z4?3F

24.0 ' 25.6

Data F i i s : >ftS251::E2Name! 60PPM STD 1876tlisc: LMC 5996 3101-2493F

Id F i l e : »ft5246T i t l e : ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n : 861015 12:33

Operator ID: USERSQuant T ime: 8 6 1 1 ) 1 6 0 1 : 0 1I n i e c t e d a t : 861016 00:18

T I C page 3 of 5

c, .40 f a6ed 3U

6T!00 9TOT98 ••t" p3»3a[uiTn:TO 9TDT98 : am i i »uenQ

flassn :ai JoieJadoif.ZI 6'IOT98 ;uoi»BJqi(B3 »se-|

J<:6<7Z-TnT<- sys yod 3"iid ai :si»iie^SfiO* !STId PI

Jf6t'?.-TOT£ 9665 OMI :ostM9^8T QIS Udd09 :auJBN

S3::lfiSSy< :ai'd e»ea

e-ze B'IE: a'.BS e'sz . e'sz a'/z e'n

U li li ^ll? T tl' ~'tl ll

l! I 1 &! 1 i 11P 1 1 R ( 11 1

r i ( [

ee'ez ' aess ' aBts ' aasz311

J£6»Z-IBie 9663 3U1 9;81 ais midH-? •— « Boa-S'ir iSe3HOiClUlCflilOaHJ M

rB

•eeeeel

•eafiRe;•eaeeer

•caaaat-

•aeeoes

•aeaee9

•aeaBB^

•eeeaes

•aaeaB6

•BBBBBal

-BBBBBI!

•00000!!

0 «. • I f d

Ui "IU1U1

SM'O

TO

QUflNr RE-PORT

Operator ID: USEK8Output Fi le; '•A5252: : L3Data Fi le: >fl5252: :E2Name: BOPPII STD 1877Misc: LMC 5996 3101-2493F

Lluant Kev: 4 Quan t T i m e ;In jectad a t ;

Dilution Factors

361016 01 :4o861016 0 1 : 0 6

l .OU

BTMH9

I D F i l e : »ft524aT i t l e : ID FILE FOR SAS 3101-2493FLast Ca l ib ra t ion ; B 6 1 0 1 5 12 :33

Compound R.T. Scant flre Cone

1 )213)4)5)6 )7)6 )9)

1 U )1 1 )1 2 )

«

»D4 1,4-DICHLQRQBENZENE2-FLUOROPHENUL (SURROGATE)2-Chlorophenol

•09 NflPHTHftLbNE2,4-Oichlorophanol4-Chloro-3-methylphenoI

*D10 ACENSPHTHENE2,4,6-TRlBROnOPHENQL (SURR)2,4,6-Tnchlorophenol2,4,5-Tr ichloropheno1

•DID PHENRNTHRENEPentachloropheno1

Compound is ISTD

B.5.7.

1 1 .1 1 .14.17.19 .16.15.21.21.

17247985681)6276912246643

4892U4462B46929

1060136816061163117517971775

2B59712013353460995109613U132523315219U205

37233195036205930246546

64669

40.52.58.40.58.55.40.44.56.59.40.50.

002498007961007574010004

UG7U1PEUS/WIPEUG/1>)IPEUG/U1PEUG/WIPEUG/1>11PEUG/U1PEUG/UIPEUG/U1PEUG/M1PEUG/UIPEUG/MIPE

951 0 0

9910098

1 0 01001 0 U9997

loipSiou>-^0»•-)0

TOTBL 10" rmiflllOToeBRMF i l r >BS2Si 41.8-S8B.9 MU. M^h STt 167? LHt EWC. Sitll-^W

TIClee . zee ^ 3?a . 490 see ^ 6?e ^ 78B

neeeefrj

leeeaee-

êeeBe- g

SBOBOB-:

7S«UW-

seeaee.

seaeea-

499966-

seeeoa.

ZUBBBB-

leeeee-

' 4'.8 ' sle ' 6.e ' 7'.a ' e'.e ' f'.a ' la.B

P 1 ?g "

&

1ssi

1'"• ,. ,. Iw j

.1 '}I

•t

1l l

j

IP 111i M (I 111fli 'tv^J '1

i

Ji

j

Ii (i

Data F i I e ! >ft5252;;E2Name: SOPPtI STO 1877MISC! LMC 5996 3101-2493F

Id F i l e : ftfl5248T i t l e ; ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n : 3611)15 12:33Operator I D ; USER8Quant Time! 861016 01:48Injected a t ; S61016 01:06

TIC page 1 of 5

TOTfll. II-IM CHPOMBTOCBOMF i l s >H52S2 41.B-SB9.B a.u. SaPM FT!) IS?? LHC E99A Siai-S44Sr

TIC899 ^ t8,89 1288 ^ 14BB

neeeee-

iBBeeeeQaaaao-

800000-

.•eaeMe-

oeeeaa-

eeeaea-

«99B9a-

308888-

286066- j j

180888- p |

it'.e ' 12'.e ' i3'.e ' 14'. a ' 15.8 ' is'.e

1 1

li i h'!

fz11'

1

J

i •s§'

•

L.

1 ' -5 l"54i•V js

fl1. 1 1

^

17.8 ' ie.®

c

1 1 )n f,11 ijil," i

Data F i l e : >fl52<?2: : E2Name: BOPPn STD 1877MISC! LriC 5 9 9 6 3101-2493F

Id Fi I e : 9M2ABT i t l e ; ID FILE FOR SAS 3101-249?FLast C a l i b r a t i o n : 961015 l2!33

Operator ID: USER8Quant T i m e ; 861016 01:48Injected a t ; 861016 0 1 : 0 6

TIC page 2 of 5

File 'SS252 41.8-SeB.B a.u. eSpP" 4T< 18?7 LM(' SMA SlBt-i4<iSPTIC

i6ea laee

iiaeBaa-

leaBeae-

9BBBB9-

8B0600

peeBBB-

660089-

Eeeeiea-

dflAnnn-

aesaao-

^BBU»»-

IBBBBe-

^ • . • • • • . • • • • r . . . l . . . . . . . . . l . .18.8 19.0 23.e

1

1IU t V j

a

^

11 .f|iii wyii oV'l" UlA^

1w

f

^

1 III1 S.W& 1 1 1 1 1 1 1

•s.

!i21 .8

|j31

1 1 1 1hnV!22.e ' aa'.e

2883

24'. e ' 2S.B

Data F i l e ! > f t 5 2 S 2 ; : E 2Name; 80PPM HTD 1877Misc : L«C 5996 3101-2493F

Id F i l e : »fl5248T i t l e : ID FILE FOR SAS 3101-2495FLast C a l i b r a t i o n : 861015 12:33

Operator [ 0 ; USERSQuant T i m e ; 861016 01:48Injected a t ; 861016 0 1 : 0 6

TIC page 3 of 5

TOTQI. TON r'HBriHdTnftRQHfir >s

iiaaeea-

laaaBBa-

SBBBB?-

sccooo-

r-BBMuu-

saaaee-

seeeea-4RRnRA.

aoBBBe.

ÎdUUtfO-

loeeee-

a-

5252 41.8-56822ee

|

JL,JL i!26.8 ' 27.e ' ze'.e ' 29'.a ' 3e'.e ' 31'.a

11 I11

a a»u. aSM'H 'Sl'l 1*7? LHC WTIC

24BB ^ 2688

,i 1AS I!1

L. "^ }[

6 3l61-i4^SF

zeee

1 li

1 1111jl

L H32.B '

Data Fi Ie: >fl5252::E2Name; BOPPM STD 1877tlisc; LrIC 5996 3101-2493F

I d F i Ie: »W248T i t l e : I D FILE FOR SAS 3101-2495FLast Ca l i b ra t i on ; 861015 1 2 : 3 3

O p e r a t o r I D : USEK8Q u a n t Tune; U61016 01:48I n j e c t e d a t : 861016 01 :U6

TIC page 4 of 5

Ml,..,

tieaeae

leaaeae-9BB8B9-

seoaao-

,'aaeee-

seaeae-

EBeeae-

488999-

3ee0Be.

zeeaae-

laBaae-

«•

5352

il 1

L33. e

———————4!.»-5»9.° MU.seee

11-. y,^,^ m., .1, ,,,

34.0 35.0

fiefTIC

pirynr3200

36.6ft

-re77—

A1 37.0

———LMI; SW Sl8l-£4$3F

3408

' 3B'.e ' 39.e ' 4e'.e

Data F i las >ft5252::E2Name; aOPPM STO 1877I-lisc: LrIC 5996 3101-249^F

Id Fi le! »fl5248T i t l e ; ID FILE FOR SAS 5101-2495FLast Ca l ib ra t ion ; 9 6 1 0 1 5 12 !33

Opera tor ID; USERaQuant Time: 8 6 1 U 1 6 01:48In jec ted a t : 861016 0 1 ; 0 6

TIC page 5 of 5

• Ctlihration Rtport

Title; ID Fll£ FOB SftS 3101-2493FCalibnted: 86101; 17:06

Files:

Coipound

2-FUJORaPHEHX (SURROGATE)2-Chlorophtnol2,4-OichlorophtfMl*-Chloro-3-«8thylph«nol2,4,6-TCiaiCTOPHEin. (SURR)2,<,(-Trichlorophtnol2,<,S-TricliltrBpl»nolPenttchlorophenol

: ><smSF

10.01

.60066

.71511

.27495

.23740

.22251

.4;9;6

.BIB.mw

>«2!7RF

2;. 00

.606!;•Tim.33400.30479.23387.50750.54402.13390

>W238RF

40.00

.58523

.7029B

.31755

.27036

.20838

.52575

.56640•136B1

>ft5239KF

60.00

.55431

.62574

.32407

.27960

.19882

.53800

.56672

.14744

>A5240RF

BO.OO

.54283

.60368

.31836

.23539

.18341

.52197

.55314

.14121

RRT

.643

.952

.9841.1671.142.877.884.990

RF

.57792

.67649

.31179

.26551

.20940

.51852

.55236

.13150

HSSO

4.8768.6117.255

11.0B29.4282.9452.727

14.699

1,50.0,511.0,50.0,50.0)

1,50.0,50.0)

'.••3W—-rl

0——I0

RF - RtsponsB Factor (Subscript is mount in UG/MIPE)

RRT - Avrigi Relatiue Rettntion Tit (RT Std/RT Istd)

RF - Avnge Rgiponfe Factor

Paaf 1 of 1

Ouwt 10 Fllf. <fl5236i:DI

Tit Ie; 10 FILE FBI SftS 3111-2493F

Lut EDIT Datti 861115 17:12 Lilt Cilib Date: 86101; 17:118

B T lrii

Paak,Sl

Sul(

Nud

CoupNo.

1)215)4)5)6)7)8)9)

W11)12)

lindow (»/- •in): .50ix Hits/CoiflMffld: 3

niniu Aru: 310'Biit Peik Ratio: 50.(11 «lope Seraitivityi -.21111itriction Hfthild: 1kito Qdtl Method; 1

Unit t of Coot: UK/WIPE

ler of CofKimIs! 12

CcapDundHIM

•04 1,4-OI(X(1RDBEN2DC2-FUJOHlFtBCL (SURHlEfflE)2-Oiloroptnnol

•DB WHTWflC2,4-0ichlor<iph«nol4-Oiloro-J-ithylphtiiol

•DID ACOWHnBC2,4,(-TRieKn]ptea. (SURR)2,4,<-Trichloroph«nol2,4,5-Trichli>ropt>«ni>l

•DIO PtBWTHBCPenlachlocophenol

Retentinin.

8.10(5.2117.711

11.79(11.60114.01K17.20119.<5(15. M(15.2K21.64(21.4K

Bi>Ti«e(Rel)

1.010).643).952)

1.0001.984)

1.187)1.080)1.142).877).884)

1.0011).9911)

R.F.

1.00000.57792.67649

1.88010.31179.26R1

1.08108.28940.51852.55236

1.88100.13158

Cone.

48.0058.8068.8848.8868.8868.8848.8858.8868.8868.8848.0868.00

• Coipound if 1STD

QUANT REPORT

Operator ID ; USERS Quant Revs 4Output F i l e ! ' • ' A 5 2 3 6 ; : L 2Data File: >A5236::E1Name: lOPPII STD #1873MISC ! LnC 5996

Quant Time;In jected at i

D i l u t i o n Factor:

ID F i l e ! »A5236T i t l e s 10 FILE FOR SftS 3101-2493FLast Calibration: 861015 12!53

861015 13:29861015 12:47

1.00

BTLt 3

Compound R . T . Scan* Area Cone Units1)2)3)415)6)7)8)9)

10 )1 1 )1 2 )

*D4 1,4-OICHLOROSENZENE2-FLUORQPHENQL (SURROGATE)2-Chlorophenol

•09 NAPHTHALENE2,4-Dichlorophenol4-Chloro-3-ineth'>>lphenol

•DID ACENAPHTHENE2,4,6-TRlBRanQPHENQL (SURR)2,4,6-Tnchlorophenol2,4,5-Tnchlorophenal

•D10 PHENANTHRENEPentachlorophenol

B.5.7.75

1 1 .1 1 .14.17.2219.15.15.21.21.

1525

806003

6707236339

488206449843823

1059136916071161117617981775

229996172693

41003440909

3030726168

170203473392124822617

3161257757

40.55.8.

40.6.7.23

40.63.6.7.24

40.4.68

0072690085

005891

00

UG/UIPEUG/'UIPEUG/U1PEUG/'UIPEUG/UIPEUGÛIPEUG/'k)IPEUGÛ1PELtG/'UIPEUG./U1PEUG/U1PEUGÛIPE

9510099

10099

1001 0 01009998

100100

* Compound is ISTO

TOTBL IOM CHROMBTOSPBMFil. >a

seeeee-.

7eeeee-

608003-

seeaaa-

486886-

3eeeee'

zeeeaa-

leeeae-

B-

6236 -u.e-sea.e ••u. iSPPM STB •ifl75 LHC ewiTIC

iea 2;e 398 48e . see 6ee pee

1 11 ?1 1 2

C-

' 4 Ie ' 5^3 1 6^3 t 7 ê ' sle 9 Ie ' le'.e

11

,. ^ 1

s

|

JLALJData F i l a : >ft5236;!ElNamB: lOPPn STD »1875tlisc: LMC 5996

Id F i l e : tASaSAT i t l e ! ID FILE FOR SAS 3101-2493FLast Calibration! B61015 12:33Operator I D ; USER8Quant Time: 861015 13:29I n j e c t e d a t : B61015 12:47

TIC page 1 of 5

TOTBI. inn CHROMBTOeRBMFil- >B

aBeeea-i

paaaae-

o33333" y

seaaee- p ^

1 s s

4BBeee- 0

3B?a?9-

saaeaB-

leaeae-

e-

5;

n.e 12.8 i.3.a K. a 15.B i6. e i7.e

»36 4l.B-5BB.e MU. l ePPM STt .i67S LMC E.99ATIC

Bê ^ ieee ^ izêa ^ i4ee

]

h tf

& ?T

t 1- g

.1 I ill < lh!

aQ

iis .e

Data Fi I e : >pi5236: :ElName; 1DPPM STD »1873Misc: LriC 5996Id F i l e : *ft5236T i t l e : ID FILE FOR SAS 3101-2493FLast Calibration: 861015 12:33Operator I D ; USERSQuant Times 861015 1 3 : 2 9I n j e c t e d a t : S61015 12:47TIC page 2 of 5

Fi'.s >»

eeeaee-.

7M889-

SBeeae-

SBBBHB-

4eeae&-

3aeaa&-

sseaaa-

laeeee-

e-

S33S 4'!.a-5SB.B asu. l^^PH STt "1979 LHC SWTIC

isee ^ isee ^ zeee ^

5 Ld

•"' §

| IE1 S

|

?- Ti

" 1

( 1 g

l JuLJJu-4,tJiIB.B 19.8 za.e 21 .e

3

1 I tII,,,,,,,.,,,,.,,,,,,, ,,,,,,J22.B ' 23.0 24.B 25.8

Data F i I e : > f l 5 2 3 6 ; : E 1Name: 10PPM STD +1B73Misc: LtIC 5996

Id F i l e : tft5256T i t l e ; ID FILE FOR SflS 3101-2495FLast Ca l i b r a t i o n : 861015 12:33Operator ID: USER8Quant Time: 861015 13:29Injected a t : 861015 12:47TIC page 7 of 5

TOTBL IQH CHPOMflTOeBflM___________________.'"!!• >f l523S41.B-SBB.B a«u. 19PPH STB •1873

T T f *TIC24,ee

G'3—+l

0'.-)0

Data File: >fl5236: -.ElNama: 10PPM STO »1873Misc: LI-IC 5996

Id F i l e ; 1K=l5236T i t l e ! ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n s 861015 12:33

Operator ID: USERSQuant Time: 9 6 1 0 1 5 13 :29In jected a t : B 6 1 0 1 5 12 :47

T I C page 4 of 5

BTLt 3

TOTBL ION CHROMBTOeROMFil- >W3f 4i.S-589.B

seeeee-

raeeeB-

6BOOOB-

saBuee-

oeeee-

aeeBee-

^06003-

leBeaa-

fri

3090

A^J33.e ; -34 ;e"'

axu. 1T

35.8

5WT mr «ie?s - Lht M»Ac

3298 ^ 34.89 ,

. M... ^-- ,

' 36'.B ' 37.6 ' 38.B ' 39.8 ' 48'.8

Data F i l e : >P|5236: :E1Name: 10PPM STD »1B73flisc: L11C 5996

Id F i l e : tft5256T i t l e : ID F I L E FOR SAS 3101-2495FLast C a l i b r a t i o n : 861015 12:33

Opera to r I D ; USERSQuant T i m e ; 961015 13:29I n j e c t e d a t ; 961015 12:47

T I C page 5 of 5

H5Sj83 *'~.T^ jjw'a jg:i' x ,

BURNT REPORT

Operator 10; USERBOutput File: •"•A5237::L3Data Fi le: >fl5257::E1Name! 25PPM STD #1874Misc: LMC 5996

Quant Rev: 4 Quant Time:Injected a t :

Dilution Factor;

861015 15:32861015 13:34

1 . 0 0

BTL* 4

ID F i l e i »A5236T i t l e : ID FILE FOR SftS 3101-2493FLast C a l i b r a t i o n ; 861015 12:33

Compound R.T. Scan* flrea Cone Units

1 )2)3)4)5)6)7)8)9)

1 0 )1 1 )1 2 )

»

»D4 1,4-OICHLOROBEN2ENE2-FLUOROPHENOL (.SURROGATE)2-Chloropheno1

•D8 NftPHTHflLENE2,4~D ichloropheno14-Chloro-3-methylphenoI

»D10 ACENAPHTHENE2,4,6-TRIBRODOPHENOL (SURR)2,4,6-Trichloropheno12,4,5-Tr ichloropheno1

•D10 PHENfWTHRENEPentachloropheno1

Compound is 1STD

e57.75

111114 .01171915152121

.15

.22

.80

.59

.20

.65

.07

.20

.63

.39

491208452847827

1062157216101165117818021779

225551170S53105795506753105781

96531249684

729927919784896

47475139731

405622402023406617.55184015

.00

.26

.44

. 00

.81

.22

.00

.83

.S5

. 00

.97

UG/U1PEUG/'U I PEUG/-U1PEUG/-MIPEUG/U1PEUG/'UIPEUG/UIPEUG/U1PEUGÛIPEUS/'U 1 PEUG/'UIPELJG/U1PE

951 0 0

98100

99100100100

9896

100100—)

0')•<-0v-i0

TOTflL I OH CHROMBTOeRBH4i.e-sea.e —u. ^BPPH

TIClee , zee . 308iTt .1S74

408

LMt Ei»&598 608

Fll. >flS237

783888-)

eseeaa-jeaaeae-

sseeee-

4seeae-

4aaeee-SBBBBO-

368688-

2Eeaae-

aeaaea-ISUBUO-

leeeee-68889-

e-

Data FiIe: >ft5237;:ElName! 25PP11 STD »1874Misc: LMC 5996

Id F i l e : ^tf:l5236T i t l e ; ID FILE FOR SflS 3101-249IFLast C a l i b r a t i o n : 861015 12:33

Operator ID: USERSQuant Time: B61015 1 5 : 5 2I n jec ted a t : 8 6 1 0 1 ? 13 :34

T I C page 1 of 5

TOTBL ION CHROMBTOeRBHF i l e >fl5237 4l.B-5Be.B a«u. iSPPM STt •l674 LMC 6596

peeeee-

6S9B8B- ^SBBoaa- y

EES2S&- 3

seeeea-469886-1 § ..

401)008-

353680- S

seeeee- :5

aseeeB-

280990-

1SBB89-

188889- 1 ) H

EBaaa- » I

£ a •« 1

i . 1 1 "?

eJ"M

TICeee ^ ioee ^ izee , KBB

S

1 1

IfliJww.0 12.B 13.B 14.8 15.0 16.0 17.0 16 .0

'i; Sf£i E *3i

'? ^\ k sl!i

in

1

€ ^ 1"

f ^

, ^

1 ill

|

EB

Jll

|§0&

8 !1 , 1

i

(iData FiIe: >A5237:!ElName: 25PPM STD 1H874nisc! LMC 5996

Id F i I e ; »a52?6T i t l e : I D FILE FOR SftS 3101-2493FLast C a l i b r a t i o n : 861015 12:33

Operator ID: USERSQuant T ime ; 8 6 1 0 1 5 1 5 : 3 2In jec ted a t : B 6 1 0 1 5 1 3 : 3 4

T I C page 2 of 5

Fil- >S

peaeae-eseeea-600008-

SEBBBe-

eeeeea-4saeee-4eaeae-368330-

39898B-

zseeee-2aeeee-150886-

iseeee-seeeei-

6-

5S3? ••i.B-Se".e ssu. SKPPM STI "i*74———LHC EMA————————TIC

1609 , 1888 2868 ^

IJlle.e i9.e 2B.e 21 .e 22.e 23.0 24. e 25.0

1 <a g |

a , 1I •a H

j

3. a

S. 5d |S o§ 5

| 1

(

A/I

liui•1- H

iiLtiiData F i l e : >A5237;:E1Name: 25PPM STD #1874Misc: LHC 5996

Id F i l e : tft52;6T i t l e : ID FILE FOR SftS 3101-2493FLast Calibrations 961015 12:33Operator I D ; USERSQuant T i m e : 961015 15:32Injected a t : 861015 13:34TIC page 3 of 5

TOTnL I OH CHROMflTOSRBM

708888-

eseeee-eeeaaa-ssaeee-saeaaa'45aaaa-4081380.

aeeaae-aseeee-zsaaaa-zeeeBa-iseeae-iBaeae-69999-

e-

523? 1i.B-5»e.B s»u. 26FPM STB .1*74———LhC 5«A————————TIC

22ee ^ 24ee , 26ee , zeee

26'.e ' 27'.e ' aa'.e ' 2»'.e ' 3B.B si'.e ' az'.eA

ffl

/' i

1 ,

1 1LJJData F i I e : >A5237!iElNaine: 25PPM STD #1874Misc; LMC 5996

Id F i l a : *A5236T i t l e ! ID FILE FOR SftS 3101-2493FLast Calibration! 861015 12:33Opera tar I D ; USERBQuant T i m e ; 861015 15:32Injected a t : B61015 13:34TIC page 4 of 5

TOTBL ION CHROHBTqeRflHFile >B

peaeee-6EBBee-eeeeee-ESMBB-seaeae-4saeea-4aaaae-3SBBOB-3see99-258088-saeeaa-isaaee-leeeee-saaea.

B-

5237 4i .e-5Be.eMu.2EPPMSTB.1674———Lrt t B99*————————|TIC

aeee ^ 3200 ^ 34ee ^

i il ... ^ A A33'.e ' 34'.e ' 35.B ' 36.8 ' 37'.B ' 38'.9 ' 39'.B ' 48.0

Data Filas >A5237i:E1Name: 25PPM STD »1874Hisc; LMC 5996

Id F i l e : tW236T i t l e ; ID FILE FOR SAS 3101-2493FLast Calibration; 861015 12:33Operator ID: USERBQuant Time; B61Q16 15:32Injected a t ! 861015 13:34TIC page 5 of 5

BTL» 4

QUANT REPORT

Operator ID; USERSOutput File; "ft5238!!L3Data File! >A523B ! !E lName; 40PPM STD #1875disc! LtIC 5996

Quant Rev: A Quant Time!In jected a t !

Dilution Factor!

B61015 15:33961015 14822

1.00

BTL» 5ID F i l e : »Fl5236T i t l e ! ID FILE FOR SAS 31Q1-2493FLast Calibration! 661015 12:33

Compound R.T . Scan* Cone Uni ts

1 ) •D4 1,4-DICHLOROBENZENE2 ) 2-FLUOROPHENOL (SURROGATE)

2-Chloropheno1*D8 NftPHTHftLENE2,4-0ichloropheno14-Chloro-3-methylpheno1

3)4)5)6)7) •D10 ACENflPHTHENEB ) 2,4,6-TRIBROnOPHENOL (SURR)

2,4,6-Trichlorophenol2,4,5-Ti-ichloropheno1

9)1 0 )1 1 ) •D10 PHENflNTHRENE12) Pentachloropheno1

* Compound is ISTD

8.155.247.76

11.8211 . 6 214.0317.211 9 . 6 615.0915.2321.6521.42

49Q208452846B27106113701609116411771800177B

23316917057116391247716915152612900920448853264107509115823336875460B8

40. 0054.2834.2640. 003 1 . 6 632.9540. 0059.552 9 . 0 930.8740.002 6 . 1 0

UG/UIPEUG/U1PEUG/UIPEUG/U1PEUG/U1PEUG/U1PEUG/UIPEUG/U1PEUG/U1PEUG/'ttlIPEUGÛIPEUG./U1PE

\

1-1 £

33

C -

0^

Or

0 3

0

f*

1> -)

Q. -

^ <•+•

••

GO C

O C

»-

&- 0

<h-

* I-

1

0 C

3h-

* 1-

*sn

•JI

i-* i-"

t. •J

1

Kl

M S

>1

^ M

*^

0 q ^ 0 ^ ^ D Ul m TO CO

sn *

^

r & u ,-fl n a cr a 0 3 (D IT. h-* 0 1-* M

-i —

^- a

rr — -n

(1

»- a

5#

-n 3>

—i

•J1r

Mm

i"'

0--n 0i (n D U) t-* 0 *-* '0

3 Z

0.

B •

B

3 t

0

9 tf T|

r ^ -

30

—"5

?.•J

l 3

'O

v<l

VI T

>0.

-1

•Jl

0 M k/1

•ft cc

t-* •

•03

••

M cn

^ »-

*

^

* .

0

-

<n e»" , "

01 a>

"•M a a \o <B ®

.a)

(n

<B

(n

s)

tn

a)

(n

'B

tn

ot

ns

» 0

11

0i

B<

BO

®a

i®

a-

'3

»<

BO

o®

aa

a)

oe

3i

B(

Ba

>i

D3

ia

>c

gs

<(

s (D

(&o

ao

o

aa

)B

a>

a>

(B

C9

a*

s is'

is

r.'y

.f.p

.'F

.T.T

.y.T

. f .

a .f .f

. '? .a

{

'.

....

. J—

——

l-FL

UORC

PHEN

OL

(SU

RKW

TE)

-=s. f^ "==

=:==

—s—

——

—U

l4-»

,1-O

ICH

LOR

OB

EH

ZE

HE

'T"—

'—==

=—^—

^••"

C—— r=E

SZ"

2 ^ % 0 a> •»"<B .

a>

o U1 a» <aN

®

-® a 3 C

-I*

.. a

^ M -J

•fc ?

•S <r

U) 0 <D

<- ?i 01.s

^»

»•

-^ -•a (D

01

0:0

0

TOTBL IOH CHROMBTOGIiflMFile >S

7eeeae-issaaee-600806

sseeee-

530380

4E8B8B-

4eeew3EB00B

aeaaae.zseeae-seaeee-1EBBBB-

1BBB9B-

SeBBB-

ii'.e ' iz'.a ' 13'.e ' K.B ' is'.e IS.B ' 17.e

5238 41.8-SBB.e MU. 46PF>M STB .1676 LHC e55i

saa laee i2ee 1408• • • • T , , , , i , . , , i , , , , i , . , , i , . , . i , , , . i . .

a , îtil

11

j

||3

j

>»

"U A,

1]S<4

?!

| i

|

1 ,

1

Ii

11

Ii

|it

18.0

Data Files >A5238!!EINama: 4CPPM STD tia75Misc: LMC 5996

Id F i l e : »fl5236T i t l e : 10 FILE FOR SftS ?101-2493FLast Calibration; B61015 12:33Operator ID: USERSQuant Time: 861015 15s33Iniected a t : 861016 14:22TIC page 2 of 5

TOTBL ION CHROrtBTOCRBMFi le >nS238 41.8-SB9.B wu. 46FPH ST11 •1876

TICi6ee isee

7nnnnn. ' ' • ' • • • • ' • • • • ' • • •——' • • ' • ' •fowov

658899-

seeeee-sseeee-saaaaa-4Eeaee-4eeeee-3seeee-seeeea-zseoae-ZBaeee-isaaoB-leeees-seaaa-

18.BIJ\.,

|i !

19.0 20.0 21 .0 2S.C 23.e 24.8 25.8

5 ^1 s!1 il

1^

5r<

|

•

0.111111

1

^.HC ^?96

zeae

Data F i l e ! >Pl5238::ElName: 40PPM STD »1875Misc: LMC 5996Id Fl I e : *W236T i t l e : ID FILE FOR SAS 3101-2493FLast Calibration: 861016 12;33Operator I D ; USERSQuant T i m e : 861015 15:33Iniected a t : B61015 14:22TIC page 3 of 5

TOTBL (OH CHRoriBTOGPBMFi;- >ff5

709888-1

eseeaa-68ZBBB-

ssueee-SOBBBB-

459889-

400088-3seeee-3eeeoB-zseaee-263838-

iseeee-196999-

SBaae-J

239 •(l.B-SSS.e MU. 4aPPH STt •14?e LriC 655ATIC

22aB ^ 2489 ^ 2680 ^ 2888

.-Jl -J26'.B ' 27',B ' 28.8 29.8 ' 3B'.e 31'.8 ' 32'.B

|

1

1 1!

»>

t81

1

Data F i I e : >A5238::E1Name: 40PPM STD *ia75Misc; LMC 5996

Id F i l e ; »fl5236T i t l e ! ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n ; 861015 12:33Operator ID! USERSQuant Time: 861015 l?^?Injected a t : 861015 14:22TIC page 4 of 5

Fll- >R

7B089B-

seeeee-688390-

sseaae-SOCOBC-

4seeBe-4eeee9-3EBB8&-

seeeoe-2SBeea.zaaeae-isaeBB- ileeeee-

BBBBa-

»-

S238 11.6-5BB.B

3886

i ((33.e • 34.e"'

MU. 4ePllM STt •1676TIC

3298

—JLL3S.B ' 36.8 ' 37'. e

——LHi EÂ3400

' as'.e ' 39. e ' 4e.a'•"-I

0

Data F i l e ! >A523B;:ElName! 40PPM STD »1875Misc; LfIC 5996

Id Fi Ie! *Pl5236T i t l e : ID FILE FOR SftS 3101-2493FLast Calibration: B61015 12:33

Operator I D : USERSQuant Tiine: 861015 15!33Injected a t : 861015 14:22TIC page 5 of 5

BTL* 5

Operator ID: USERSOutput File: "W239::L3Data File! >A5239; !ElName! 60PPM STD 41876riiscs Lnc 5996

QUANT REPORT

Quant Reu; 4 Quant TimeiIn jectsd a t :

Oilution Factor!

861015 15;52661015 15:10

l . O U

BTL* 6

ID F i I e ! »A5236T i t l e ! ID FILE FOR SAS 3101-2493FLast Calibration; 961015 12:33

Compound R . T . Scan# Cone Un i ts

1 )2)3)4)5)6)7)8 39)

10 )1 1 )12)

«

•D4 1,4-DICHLOROBENZENE2-FLUORaPHENOL (SURROGATE)2-Chlorophenol

•DB NAPHTHALENE2,4-Dichlorophenol4-Chloro-3-methylphenol

•D10 ACENAPHTHENE2,4,6-TRIBROMOPHENOL (SURR)2,4,6-Tnchlorophenol2,4,5-Trichloropheno1

*D10 PHENANTHRENEPen tachlarophenol

Compound is ISTD

a57.77

11111417.231915152121

. 15

.25

.83

.65

. 04

.67

.11

.23

.64

.42

491209454949931

10631372160911661178IS CD1779

280077194058262B82529501257396222074235744

58587190247200401367867

81359

405145404851405644.66464042

.00

.41

.74

.00

.46

. 12

.00

.81

.32

.00

. 19

UG./UIPEUG/U1PEUG/UIPEUG/U1PEUG/UIPEUG/U1PEUGÛIPEUG/UIPEUG/UIPEUGÛIPEUG-'UIPEUG/U1PE

94100

991 0 098

100100100

9898

100100•.'3

01 . 30. -]0

TOTBL ION CHROHRTOGRflH

iBeeeee-

9BBB88-

380888-

pBeeee-

ieasae- £ ^ S

seaeee-

400000-

3flaBB&-

zeeeeo-

ieeeee-

e-

5239 41.B-5BB.B uu. ASPPH 4TB •1S?A LrtC; B99ATICiee sae see 498 see 6ae T^B

1 t §

1|

"

'"-——- ^4le ' s'.a ' i'.e ' ?'.»

^ Aâ.a

' |

\.

9'.» ' le^TeU

11

1

Data File: >S5239::ElName: 60PPM STD #1876tlisc: LMC 5996

Id F i l e : #ft5236T i t i o : ID FILE FOR SftS 3101-2495FLast C a l i b r a t i o n : 861015 12:35

Operator ID: USERSQuant Time; 8 6 1 0 1 5 15 :52In jected a t : B 6 1 0 1 5 1 5 : 1 0

T I C page 1 of 5

TOTOL ION CHPOHRT06RBMFil- >R

laeeeea-

aeeaae-

eeaeeo-

769869-

068368-

SBeeea-

4BBBaB-

3B9eee-

seeBae-

iBeaee-

B-

523? 41.B-5BB.e MU. WPH ST1 nl6?A LHC BMiTIC

see ieee izee , l4ee

|

1|j11

1ll11^•i^" IZ'.B ' 13.e i4.e ' IB'.B ' it'.e ' 17.e ' le'.e

u

\ L; §j

J U l .

1•<?<3<

<l

I

l l j|t ^ 1 *.

Data F i I e : ?ft5239!:E1NamB! 60PP11 STD *1876Misc! LMC 5996

Id FiIe: *a?236T i t l e : ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n : 961C15 12!3?Operator ID! USERSQuant Time: 861015 15:52Injected a t ! 861015 15-.10TIC page 2 of 5

TOTRL IOM CHROMUTOeRflM

iBMeee-

iBBeao-

reeeee-

eoaBSo-

saeeeo-

4eeeeB-

389899-

zaaeea-

iBeeea-

e-

5239 -!.S-588.» aeu. A"^ 5Tt •167< LHC SWi6ee ^ iBBa ^ seee ^

?&S S

,ui8'.e ' 19.B ' za'.e ' 2 1 . e ' ZZ'.B ' 23.e ' 24.e ' zE.e

1 li

1'8w

tsl

Sf|Sillfilllun . 1

Data Fi lai >f l5239!:E1Nama: 60PPM STD 1H.876Misc: LMC 5996

Id Fila: »ft5236Tit la! ID FILE FOR SAS 5101-2493FLast Ca l ib ra t ion; 861015 12 :33

Operator ID; USERSQuant Tima: 8 6 1 0 1 5 1 6 : 6 2In jected at : B 6 1 0 1 5 1 6 : 1 0

T I C page 3 of 6

TOT01. IOM CHBOMBTOGBOHFi l e >fl5

laeaeee-

9Beeee-

saaeee-

7B9ees-

oBBBBa-

seoBoe-

4eeeea-

39?BBB.

2BBeea-

leeaaa-

z.

239 41.6-588.6 a«u. AAI»Pn sTB .lS?S LHC E99ATIC

zzee 24ea 26ee zaee

. -J26'.e 27.e ' zs'.e ' 29.e ' ae'.B 3i'.a ' az'.e

1 1

^ ^

ll1i ,

Data F i l a ; > A5239;:E1Name! 60PPM STD 1H876MISC! LI-IC 5996

Id F i l e : »A5236T i t l e : ID FILE FOR SAS 3101-2493FLast Calibration; 861015 12:33Operator I D ; USERSQuant Time: 861015 15:52injected a t : 861015 15:10TIC page 4 of 5

TOTflL 10H CHl»ClMflT06RB»<File >B

IBBBBBB-

9eaeee-

seeeee-

pesaaB-

saaaae-

5BBBBB-

400800-

39eeee-

2BBBBB. M 1 ,S B , 11 i

laeaee-

B-

523

Ji33. e ' 34'.a '' 3S'.B ' 36'.e ' 37'.a ' 38.8 ' 39'.B ' 4B.e

9 41.B-see.6 uu. WW STI •16?<———LHC WiTIC

3eee ^ 32B9 , 34ee ^

ill nData Fil e : >ft5259!:ElName! 60PPM STD <1876Misc! LMC 5996

Id F i I e : *ft5236T i t l e : ID FILE FOR SAS ?101-249?FLast Calibration! 861015 12:33

Operator ID: USERSQuant T i m e : 861015 16:52Injected a t : 861015 15:10TIC page 5 of 5

Operator ID: USERSOutput Fi le! Â5240::L3Data FiIe; >A5240: ••ElNome: BOPPCI STD *l877Misc: L11C 5996

QUANT REPORTQuant Rev: 4 Quant Time:

In)ected a t ;Dilution Factor:

861015 16:40B61015 15:57

1.00

BTL* 7

ID F i I e : »A5236T i t l e : ID FILE FOR SAS 3101-2493FLast Calibration: 861015 12:33

Compound R.T. Scan* Cone Units

1 )2)3)4)5)6)718)9)

1 0 )1 1 )12)

*D4 1,4-DICHLQROBENZENE2-FLuaRQPHENQL (SURROGATE)2-Chlorophenol

•OB NAPHTHALENE2,4-Dichlorophenol4-Chloro-3-met hylpheno1

*010 ACENAPHTHENE2,4,6-TRIBROtlOPHENOL (SURR)2,4,6-Tr ichloropheno12,4,5-Tnch lorophenol

•010 PHENANTHRENEPentachlorophenoI

8. 155.227.78

11 .831 1 . 6 514. 0317.2119.661 5 . 1 015.2321.6321.41

491207455848931

1062137016081166117817991778

26399017914231873048900530157623021219255744146

2 0 1 0 1 921302125837672970

40.0050 .3558.8340. 0061 .4957.3940.0052.4157.7760.2840.0053.88

UGÛIPEUG/U1PEUG/U1PEUG/UIPEUG/U1PEUG/UIPEUG/UIPEUG/UIPEUG/UIPEUE/U1PEUG/UIPEUGÛIPE

9510097

10099

1 0 01 0 0100

9996

1001 0 0

* Compound is 1STD

TOTBL IOH CHROMPTOGRBMr i i» >B

i3BBBee-âaaao.

119B989-

leaeeaa-

999999- •;

899889- g" •& W

78eaaa- § g 5

6Beee8- 3. ft' g

SBeBee' 1 §4BeaeB. | j:Q |i

aaeaae- ? H (l1

zeaaea-

laeaae-

B-

624B 41.®-5Be.e aau. sSPPH iTI •WT -"rH6 ES4iTIC

. i?e ^ zee ^ 398 ^ 4ea ^ EBB ^ sae 798

-..•L.4.B s.e t.e 7.e e.e 9.e ie.a

,jUl.itl f

Data Fi Ie; >l=l5240: :E1Name; aoPPri STO 1HB77tliac: LMC 5996

Id F i l e : *fl5236T i t l e : ID FILE FOR SAS 3101-2493FLast C a l i b r a t i o n : 861015 12:33

Operator ID: USERSQuant T i m e : 861015 16:40I n j e c t e d a t : 861015 15:57

T I C page 1 of 5

TOTBL IOM CHBOMBTneRRMrile .-•BS24e 41.0-598.8 u»u. MPPh 5TB .1677 LHi »46

TICeae ^ ieee ^ isee , i4ea

OBeeee-12BBB8e-

iiBeaeB.1 (tRRRnR.

qeeaae-

8M999-

paeeaa-

6eeeae-ceeeee-4eeeee-3BBeea-seeeaa-

leaeee-

ti.e t2.a

-s4

1^5

1

ll11 ii

11

&

i

i

Jl minnpJ,....,...13.B 14.a

». •B§

; ».

l S Jrt»

is'e'

1

|

|LLIIS'.e^'.B"'' 18.8

1

1:

sJi i11 li

Data F i I e : >fl5240;:E1Name: 80PPM STD 41B77MISC! LMC 5996

Id F i l e : »ft5236T i t l e ; ID FILE FOR SAS 3101-2493FLaat Calibration: B61015 12:33Operator ID! USERSQuant T i m e ; 86101? 16:40Injected a t : 86101S 15:57TIC page 2 of 5

TOTBL lOMCHROMBTOeRBH

Data File! >ft5240:!ElName: 80PPM STD #1677Misc: LfIC 5996

Id FiIe! »fl5236Tit le: ID FILE FOR SflS 3101-2493FLast Cal ibrat ion: B61015 12 :33

Operator ID: USERSQuant Time: 861015 1 6 S 4 0Iniected at : 86101? 15 !?7

T I C page 3 of 5

1369906-1299989-

iiaeeee-

leeeeea-9B998&eaanaa.

zeeeee-6eeeea-saBeea-400000-aaeeea-

2ee«e»leaaae- 1 in 11 i

zzee

•'••^.e 1

""." M... flWM STt .16TIC. . . . " M . . . . . . .

1

127.e 28.B 29.0

77 ' LHC E9M 'zsea , zeee

t3B.8 ' 31'.B ' 32'.e '

;Data Fi Is: >l=l5240: ! ElName: 80PPM STD *1B77Hisc: LMC 5996

Id F i l e : »(15236T i t l e ; ID FILE FOR SAS ?101-2493FLast C a l i b r a t i o n : 861015 12:33Operator I D ; USERSQuant Tims; 861015 16:40Injected a t : 861015 15:57TIC page 4 of 5

tNffliaflffigiflaa^—

TOTflL ION CHROHBTOeRRMFlit >S

1389888-

izeeBee-

neaeee-

igeeieee-

9?eee»-

eeeeee-peeeee-

6eeeeo-

seeeeci-4BBeeB-

3eeaea-

zeeeee-leeeee-

e-

5249 41.8-5BB.B aw. 6Wf'ri STS •1S77 LHC WiTIC

1 ^^le9 , 32ee

1 34ea ,

ij ,Mi A A

'"SSTa"7"'"' 34'. e ' 35.8 ' 36.0 ' 37.8 ' 38.0 ' 39'.® ' 49.8

Data F i I e : >A5240 : :E1Name; SOPPn STD »IS77Iliac: LnC 5996

Id F i l e : tW236T i t l e : ID F ILE FOR SftS 3101-2493FLast C a l i b r a t i o n : 861015 12:33

O p e r a t o r ID: USERSQuant Time: 861015 16:40In jected a t : 8 6 1 0 1 5 15:57

T I C page 5 of 5

Documents

CASE NO. 2493F: STANDARDS PACKET, CHLOROPHENOLS; … · Page 1 of 1 Quant ID File: M5248::D3 Title! ID FILE FOR SAS 3101-2493F Last EDIT Date; 861015 12:01 Last Calib Date: 861020