Certificate of Complianced284f45nftegze.cloudfront.net/WATERBOY/15-27356_Ozarka Drinkin… · Page 1 of 7 Burlington, WA Corporate Laboratory (a) 1620 S Walnut St Burlington, WA 98233

Certificate of ComplianceThis is to certify that

EDGE ANALYTICAL, Inc.,An Accredited Drinking Water Laboratory,

Certification number 046, has completed the analysis of

FIZZ-O WATER COMPANY“Ozarka Drinking Water”

on January 15, 2016, according to the FDA testing requirements for bottled drinking water.All parameters were found to be in compliance with 21 CFR 165 and 21 CFR 129

published limits for bottled drinking water.

Burlington, WA Corporate Laboratory (a) 1620 S Walnut St Burlington, WA 98233 800.755.9295 • 360.757.1400

Bellingham, WA Microbiology (b) 805 Orchard Dr Ste 4 Bellingham, WA 98225 360.715.1212

Portland, OR Microbiology/Chemistry (c) 9150 SW Pioneer Ct Ste W Wilsonville, OR 97070 503.682.7802

Corvallis, OR Microbiology (d) 540 SW Third Street Corvallis, OR 97333 541.753.4946

January 15, 2016 Page 1 of 1

Mr. Rick Doerner

809 N Lewis AvenueTulsa, OK 74110

Fizz-O Water Company

The following comments are reported for your project:

Your project: Ozarka Drinking Water, was received on Monday December 21, 2015.

Dear Mr. Rick Doerner,

RE: 15-27356 - Ozarka Drinking Water

Bottle was opened at 13:35 on December 21, 2015. USP MonXXIII ran at 10:05 on December 23, 2015.

Respectfully

If you have questions phone us at 800 755-9295.

Director of Laboratories, Vice PresidentLawrence J Henderson, PhD

Chain of CustodyQC ReportsData ReportEnclosures:

FORM: COVER Rev 2

Page 1 of 7





BOTTLED WATER STANDARD OF QUALITY REPORT

15-27356Reference Number:Fizz-O Water CompanyClient Name:


Authorized by:

Lawrence J Henderson, PhDDirector of Laboratories, Vice President

Project:

Field ID:

Sample Description:

Sampled By:

Sample Date:

Lab Number:

Report Date:

6140901/15/2016

Ozarka Drinking Water

151214

Ozarka Drinking Water

Rick Doerner

12/21/2015

Approved By: bj,co,fm,hy,ljh,mcs,mvp,pdm,rjk

Inorganic Chemicals (IOCs)COMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

7440-36-0 ANTIMONY ND 0.006 0.001 mg/L 200.8 a

7440-38-2 ARSENIC ND 0.010 0.001 mg/L 200.8 a

7440-39-3 BARIUM ND 1.0 0.001 mg/L 200.8 a

7440-41-7 BERYLLIUM ND 0.004 0.001 mg/L 200.8 a

7440-43-9 CADMIUM ND 0.005 0.001 mg/L 200.8 a

7440-47-3 CHROMIUM ND 0.05 0.005 mg/L 200.8 a

16984-48-8 FLUORIDE ND 2 0.10 mg/L 300.0 a

7439-92-1 LEAD ND 0.005 0.001 mg/L 200.8 a

7439-97-6 MERCURY ND 0.001 0.0002 mg/L 245.1 a

7440-02-0 NICKEL ND 0.1 0.001 mg/L 200.8 a

14797-55-8 NITRATE-N ND 10 0.10 mg/L 300.0 a

14797-65-0 NITRITE-N ND 1.0 0.10 mg/L 300.0 a

E-10128 TOTAL NITRATE/NITRITE ND 10 0.10 mg/L 300.0 a

7782-49-2 SELENIUM ND 0.010 0.005 mg/L 200.8 a

7440-28-0 THALLIUM ND 0.002 0.001 mg/L 200.8 a

Notation:

A Result of "ND" indicates that the compound was not detected above the Lab's Reporting Limit - MRL.

MRL - Method Reporting Limit .

These test results meet all the requirements of NELAC, unless otherwise stated in writing, and relate only to these samples.If you have any questions concerning this report contact us at the above phone number.FORM: cFDA.rpt

An * in front of the parameter name indicates it is not NELAP accredited but it is accredited through WSDOH or USEPA Region 10.

SOQ - Standard of Quality, maximum permissible level of a contaminant in water established by EPA, NPDWR or IBWA.

Reference Number:

Lab Number:

Report Date: 01/15/2016

61409

15-27356

Page 2 of 7BOTTLED WATER STANDARD OF QUALITY REPORT

COMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

57-12-5 CYANIDE, FREE ND 0.2 0.005 mg/L OIA-1677-DW a

7429-90-5 ALUMINUM ND 0.2 0.010 mg/L 200.7 a

16887-00-6 CHLORIDE ND 250 0.1 mg/L 300.0 a

7440-50-8 COPPER ND 1.0 0.005 mg/L 200.8 a

7439-89-6 IRON ND 0.3 0.050 mg/L 200.7 a

7439-96-5 MANGANESE ND 0.05 0.001 mg/L 200.8 a

7440-22-4 SILVER ND 0.025 0.001 mg/L 200.8 a

14808-79-8 SULFATE ND 250 0.2 mg/L 300.0 a

E-10173 TOTAL DISSOLVED SOLIDS (TDS) 10 500 10 mg/L SM2540 C a

7440-66-6 ZINC ND 5.00 0.005 mg/L 200.8 a

Notation:



These test results meet all the requirements of NELAC, unless otherwise stated in writing, and relate only to these samples.

FORM: cFDA.rpt



Reference Number:

Lab Number:


61409

15-27356


Volatile Organic Chemicals (VOCs)COMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

71-55-6 1,1,1 - TRICHLOROETHANE ND 30 0.4 ug/L 524.2 a

79-00-5 1,1,2 - TRICHLOROETHANE ND 5 0.4 ug/L 524.2 a

75-35-4 1,1 - DICHLOROETHYLENE ND 2 0.4 ug/L 524.2 a

120-82-1 1,2,4 - TRICHLOROBENZENE ND 9 0.4 ug/L 524.2 a

107-06-2 1,2 - DICHLOROETHANE ND 2 0.4 ug/L 524.2 a

78-87-5 1,2 - DICHLOROPROPANE ND 5 0.4 ug/L 524.2 a

71-43-2 BENZENE ND 1 0.4 ug/L 524.2 a

56-23-5 CARBON TETRACHLORIDE ND 2 0.4 ug/L 524.2 a

156-59-2 CIS - 1,2 - DICHLOROETHYLENE ND 70 0.4 ug/L 524.2 a

156-60-5 TRANS - 1,2 - DICHLOROETHYLENE ND 100 0.4 ug/L 524.2 a

100-41-4 ETHYLBENZENE ND 700 0.4 ug/L 524.2 a

75-09-2 METHYLENE CHLORIDE (DICHLOROMETHANE)ND 3 0.4 ug/L 524.2 a

108-90-7 MONOCHLOROBENZENE ND 50 0.4 ug/L 524.2 a

95-50-1 O - DICHLOROBENZENE ND 600 0.4 ug/L 524.2 a

106-46-7 P - DICHLOROBENZENE ND 75 0.4 ug/L 524.2 a

100-42-5 STYRENE ND 100 0.4 ug/L 524.2 a

127-18-4 TETRACHLOROETHYLENE ND 5 0.4 ug/L 524.2 a

108-88-3 TOLUENE ND 1000 0.4 ug/L 524.2 a

79-01-6 TRICHLOROETHYLENE ND 1 0.4 ug/L 524.2 a

75-01-4 VINYL CHLORIDE ND 2 0.4 ug/L 524.2 a

1330-20-7 XYLENES (TOTAL) ND 1000 0.4 ug/L 524.2 a

75-27-4 BROMODICHLOROMETHANE 1.7 0.4 ug/L 524.2 a

124-48-1 CHLORODIBROMOMETHANE ND 0.4 ug/L 524.2 a

67-66-3 CHLOROFORM 5.0 0.4 ug/L 524.2 a

75-25-2 BROMOFORM ND 0.4 ug/L 524.2 a

E-14471 TOTAL TRIHALOMETHANE 6.7 80 0.4 ug/L 524.2 a

Notation:




FORM: cFDA.rpt



Reference Number:

Lab Number:


61409

15-27356


Synthetic Organic Chemicals (SOCs)COMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

93-72-1 2,4,5 - TP (SILVEX) ND 10 0.2 ug/L 515.4 a

94-75-7 2,4 - D ND 70 0.1 ug/L 515.4 a

15972-60-8 ALACHLOR ND 2 0.2 ug/L 525.2 a

1912-24-9 ATRAZINE ND 3 0.1 ug/L 525.2 a

1563-66-2 CARBOFURAN ND 40 0.9 ug/L 531.2 a

57-74-9 CHLORDANE ND 0.5 0.2 ug/L 508.1 a

96-12-8 DIBROMOCHLOROPROPANE (DBCP) ND 0.2 0.02 ug/L 504.1 a

88-85-7 DINOSEB ND 7 0.2 ug/L 515.4 a

72-20-8 ENDRIN ND 0.2 0.01 ug/L 525.2 a

106-93-4 1,2 - DIBROMOETHANE (EDB) ND 0.05 0.01 ug/L 504.1 a

76-44-8 HEPTACHLOR ND 0.4 0.04 ug/L 525.2 a

1024-57-3 HEPTACHLOR EPOXIDE "B" ND 0.2 0.02 ug/L 525.2 a

58-89-9 LINDANE (BHC - GAMMA) ND 0.2 0.02 ug/L 525.2 a

72-43-5 METHOXYCHLOR ND 40 0.1 ug/L 525.2 a

23135-22-0 OXAMYL (VYDATE) ND 200 2 ug/L 531.2 a

87-86-5 PENTACHLOROPHENOL ND 1 0.04 ug/L 515.4 a

1918-02-1 PICLORAM ND 500 0.1 ug/L 515.4 a

1336-36-3 POLYCHLORINATED BIPHENYLS (PCBs) ND 0.5 0.1 ug/L 508.1 a

75-99-0 DALAPON ND 200 1 ug/L 515.4 a

122-34-9 SIMAZINE ND 4 0.07 ug/L 525.2 a

8001-35-2 TOXAPHENE ND 3 1 ug/L 508.1 a

41903-57-5 DIOXIN (2,3,7,8-TETRACHLORODIBENZO-P-DIOXIN)ND 30 5 pg/L 1613 Analyzed by PACE_MN

85-00-7 DIQUAT ND 20 0.4 ug/L 549.2 a

145-73-3 ENDOTHALL ND 100 9 ug/L 548.1 a

1071-83-6 GLYPHOSATE ND 700 6 ug/L 547 a

50-32-8 BENZO(A)PYRENE ND 0.2 0.02 ug/L 525.2 a

103-23-1 DI(ETHYLHEXYL)-ADIPATE ND 400 0.6 ug/L 525.2 a

118-74-1 HEXACHLOROBENZENE ND 1 0.1 ug/L 525.2 a

77-47-4 HEXACHLOROCYCLO-PENTADIENE ND 50 0.1 ug/L 525.2 a

E-10253 TOTAL RECOVERABLE PHENOLICS ND 1 1 ug/L 420.4 Analyzed by NSF

Notation:




FORM: cFDA.rpt



Reference Number:

Lab Number:


61409

15-27356


Water PropertiesCOMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

E-10139 HYDROGEN ION (pH) 6.41 pH Units 150.1 a

E-11712 COLOR ND 15 5 COLOR UNITSM2120 B pH: 6.5a

E-11734 ODOR ND 3 1 TON SM2150 Temperature: 39.7a

E-10617 TURBIDITY 0.26 1 0.10 NTU 180.1 a

Notation:




FORM: cFDA.rpt



Reference Number:

Lab Number:


61409

15-27356


Disinfectants/DBPCOMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

NA HAA(5) ND 60 0 ug/L 552.3 a

15541-45-4 BROMATE ND 0.010 0.001 mg/L 300.1 a

10049-04-4 CHLORINE DIOXIDE ND 0.10 mg/L SM4500-ClO2 D* a

7758-19-2 CHLORITE ND 1.00 0.010 mg/L 300.1* a

CHLORAMINES TOTAL ND 4.0 0.05 mg/L SM4500-Cl G Opn'd 12/21/15 1335* a

7782-50-5 FREE CHLORINE RESIDUAL ND 4.0 0.05 mg/L SM4500-Cl G Opn'd 12/21/15 1335a

Notation:




FORM: cFDA.rpt



Reference Number:

Lab Number:


61409

15-27356


Radiological ContaminantsCOMMENTMethodUnitsMRLSOQRESULTCOMPOUNDSCAS ID# Lab

12587-46-1 GROSS ALPHA ND 15 0 pCi/L 900.0 Analyzed by Pace

12587-47-2 GROSS BETA ND 50 0 pCi/L 900.0 Analyzed by Pace

13982-63-3 RADIUM 226 ND pCi/L 903.1 Analyzed by Pace

15262-20-1 RADIUM 228 ND 5 5 pCi/L 904.0 Analyzed by Pace

7440-61-1 URANIUM ND 0.030 0.001 mg/L 200.8 a

Notation:




FORM: cFDA.rpt



Page 1 of 1





Certificate Of AnalysisFizz-O Water CompanyClient Name:


15-27356Reference Number:

Project: Ozarka Drinking WaterReport Date: 1/15/16

Date Received:

Approved By:

12/21/15bj,mvp

Authorized by:


Sample Description:

Lab Number: 61409

151214 - Ozarka Drinking Water Sample Date: 12/21/15

Rick DoernerCollected By:

AnalyzedParameter RESULT CommentMethod Analyst Batch

HYDROGEN ION (pH)* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

OXIDIZIBLE SUBSTANCES* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

AMMONIA-N* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

HEAVY METALS* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

CARBON DIOXIDE* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

CALCIUM* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

TOTAL SOLIDS* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

SULFATE* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

CHLORIDE* PASS USP Mon. XXIII 12/23/15 MMH USP_151223

TOTAL COLIFORM* ABSENT SM9223 B/Colilert-1812/22/15 BJ M_151221BUR

E. COLI* NEG SM9223 B/Colilert-1812/22/15 BJ M_151221BUR


These test results meet all the requirements of NELAC, unless otherwise stated in writing, and relate only to these samples.If you have any questions concerning this report contact Allen French at the above phone number.

Form: cCOA_USP23.rpt

PQL = Practical Quantitation Limit is the lowest level that can be achieved within specified limits of precision and accuracy during routine laboratory operating conditions.

Notes:

ND = Not detected above the listed practical quantitation limit (PQL) or not above the Method Detection Limit (MDL), if requested.

Page 1 of 1

Burlington, WA Corporate Laboratory (a)1620 S Walnut St - Burlington, WA 98233 - 800.755.9295 • 360.757.1400

Bellingham, WA Microbiology (b)805 Orchard Dr Ste 4 - Bellingham, WA 98225 - 360.715.1212

Portland, OR Microbiology/Chemistry (c)9150 SW Pioneer Ct Ste W - Wilsonville, OR 97070 - 503.682.7802

Corvallis, OR Microbiology/Chemistry (d)540 SW Third Street - Corvallis, OR 97333 - 541.753.4946

Bend, OR Microbiology (e)20332 Empire Blvd Ste 4 - Bend, OR 97701 - 541.639.8425

Data Report

Fizz-O Water CompanyClient Name: 15-27356Reference Number:

Project: Ozarka Drinking Water



Date Received:

Approved by:

12/21/15bj,mvp

Authorized by:


Sample Description:

Lab Number: 61409

151214 - Ozarka Drinking Water Sample Date: 12/21/15 1:30 pm

Rick DoernerCollected By:Sample Comment:

AnalyzedParameter Result PQL Units CommentMethod Analyst BatchCAS ID# DFMDL Lab

CALCIUM mg/L0.5ND 200.7 12/29/15 BJ 200.7_151229A7440-70-2 1.00.009 a

HARDNESS as Calcium Carbonate mg/L3.3ND 200.7 12/29/15 BJ 200.7_151229AE-11778 1.00.01 a

MAGNESIUM mg/L0.5ND 200.7 12/29/15 BJ 200.7_151229A7439-95-4 1.00.001 a

POTASSIUM mg/L1.0ND 200.7 12/29/15 BJ 200.7_151229A7440-09-7 1.00.1 a

SODIUM mg/L0.500.6 200.7 12/29/15 BJ 200.7_151229A7440-23-5 1.00.05 a

ELECTRICAL CONDUCTIVITY uS/cm10ND SM2510 B 12/22/15 MMH EC_151222E-10184 1.0 a


These test results meet all the requirements of NELAP, unless otherwise stated in writing, and relate only to these samples. Estimates of uncertainty are not included in this report. If this information is required please contact us at the phone number listed in the report header.If you have any questions concerning this report contact us at the above phone number.Form: cRslt_2.rpt

PQL = Practical Quantitation Limit is the lowest level that can be achieved within specified limits of precision and accuracy during routine laboratory operating conditions.

Notes:

ND = Not detected above the listed practical quantitation limit (PQL) or not above the Method Detection Limit (MDL), if requested.

D.F. - Dilution Factor

Page 1 of 13

SAMPLE INDEPENDENT

QUALITY CONTROL REPORT

Reference Number:

01/15/16Report Date:

15-27356Calibration Check

Batch Analyte Result

True

Value Units Method

%

Recovery Limits* Qualifier Comment

QC

Type

QC

1677_151228 CYANIDE, FREE 0.205 0.200 mg/L OIA-1677-DW 103 90-110 CAL 0

200.7_151229A ALUMINUM 1.02 1 mg/L 200.7 102 90-110 CAL 2

CALCIUM 10.9 11 mg/L 200.7 99 90-110 CAL 2

HARDNESS as Calcium Carbonate 74.2 72.8 mg/L 200.7 102 90-110 CAL 2

IRON 1.01 1 mg/L 200.7 101 90-110 CAL 2

MAGNESIUM 11.4 11 mg/L 200.7 104 90-110 CAL 2

POTASSIUM 10 10 mg/L 200.7 100 90-110 CAL 2

SODIUM 11.4 11 mg/L 200.7 104 90-110 CAL 2

200.8_160104 ANTIMONY 0.0002 0.0002 mg/L 200.8 100 80-120 CAL 0

ARSENIC 0.00106 0.001 mg/L 200.8 106 80-120 CAL 0

BARIUM 0.001 0.001 mg/L 200.8 100 80-120 CAL 0

BERYLLIUM 0.00105 0.001 mg/L 200.8 105 80-120 CAL 0

CADMIUM 0.00106 0.001 mg/L 200.8 106 80-120 CAL 0

CHROMIUM 0.00095 0.001 mg/L 200.8 95 80-120 CAL 0

COPPER 0.00096 0.001 mg/L 200.8 96 80-120 CAL 0

LEAD 0.00095 0.001 mg/L 200.8 95 80-120 CAL 0

MANGANESE 0.00098 0.001 mg/L 200.8 98 80-120 CAL 0

NICKEL 0.00102 0.001 mg/L 200.8 102 80-120 CAL 0

SELENIUM 0.00105 0.001 mg/L 200.8 105 80-120 CAL 0

SILVER 0.00096 0.001 mg/L 200.8 96 80-120 CAL 0

THALLIUM 0.00094 0.001 mg/L 200.8 94 80-120 CAL 0

URANIUM 0.00094 0.001 mg/L 200.8 94 80-120 CAL 0

ZINC 0.00107 0.001 mg/L 200.8 107 80-120 CAL 0

245.1_151230 MERCURY 0.00198 0.00200 mg/L 245.1 99 95-105 CAL 0

MERCURY 0.000188 0.0002 mg/L 245.1 94 95-105 CAL MRL 1

300.1_160104A BROMATE 0.00093 0.001 mg/L 300.1 93 75-125 CAL 0

CHLORITE 0.0099 0.010 mg/L 300.1 99 75-125 CAL 0

*Notation:

% Recovery = (Result of Analysis)/(True Value) * 100

NA = Indicates % Recovery could not be calculated.

Limits are intended for water matrices only. These criteria are for guidance only when reported with soils/solids.

FORM: QCIndependent3.rpt

Page 2 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Calibration Check


True

Value Units Method

%


QC

Type

QC

CL_151221 FREE CHLORINE RESIDUAL 0.05 0.05 mg/L SM4500-Cl G 100 70-130 CAL 0

EC_151222 ELECTRICAL CONDUCTIVITY 1413 1413 uS/cm SM2510 B 100 85-115 CAL 0

ELECTRICAL CONDUCTIVITY 16.0 15.0 uS/cm SM2510 B 107 85-115 CAL 1

I151221A CHLORIDE 1.1 1 mg/L 300.0 110 90-110 CAL 0

FLUORIDE 0.94 1 mg/L 300.0 94 90-110 CAL 0

NITRATE-N 0.97 1 mg/L 300.0 97 90-110 CAL 0

NITRITE-N 1.02 1 mg/L 300.0 102 90-110 CAL 0

SULFATE 1.9 2 mg/L 300.0 95 90-110 CAL 0

TOTAL NITRATE/NITRITE 1.99 2 mg/L 300.0 100 90-110 CAL 0

TURB_151221 TURBIDITY 9.89 10.0 NTU 180.1 99 80-120 CAL 0

*Notation:





Page 3 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Laboratory Fortified Blank


True

Value Units Method

%


QC

Type

QC

200.7_151229A ALUMINUM 0.52 0.5 mg/L 200.7 104 85-115 LFB 0

CALCIUM 13.2 13 mg/L 200.7 102 85-115 LFB 0

HARDNESS as Calcium Carbonate 88.6 86 mg/L 200.7 103 85-115 LFB 0

IRON 0.5 0.5 mg/L 200.7 100 85-115 LFB 0

MAGNESIUM 13.5 13 mg/L 200.7 104 85-115 LFB 0

POTASSIUM 17.8 17.5 mg/L 200.7 102 85-115 LFB 0

SODIUM 13.4 13 mg/L 200.7 103 85-115 LFB 0

245.1_151230 MERCURY 0.00172 0.00167 mg/L 245.1 103 90-110 LFB 0

504_151228 1,2 - DIBROMOETHANE (EDB) 0.26 0.25 ug/L 504.1 104 70-130 LFB 0

DIBROMOCHLOROPROPANE (DBCP) 0.25 0.25 ug/L 504.1 100 70-130 LFB 0

515.4_151222 PENTACHLOROPHENOL 0.12 0.125 ug/L 515.4 96 70-130 LFB 0

2,4 - D 0.58 0.5 ug/L 515.4 116 70-130 LFB 1

2,4,5 - TP (SILVEX) 0.55 0.5 ug/L 515.4 110 70-130 LFB 1

DINOSEB 0.47 0.5 ug/L 515.4 94 70-130 LFB 1

PENTACHLOROPHENOL 0.5 0.5 ug/L 515.4 100 70-130 LFB 1

PICLORAM 0.41 0.5 ug/L 515.4 82 70-130 LFB 1

2,4 - D 2.58 2.5 ug/L 515.4 103 70-130 LFB 3

2,4,5 - TP (SILVEX) 2.41 2.5 ug/L 515.4 96 70-130 LFB 3

DALAPON 2.78 2.5 ug/L 515.4 111 70-130 LFB 3

DINOSEB 2.24 2.5 ug/L 515.4 90 70-130 LFB 3

PENTACHLOROPHENOL 2.47 2.5 ug/L 515.4 99 70-130 LFB 3

PICLORAM 2.07 2.5 ug/L 515.4 83 70-130 LFB 3

524_151223 1,1 - DICHLOROETHYLENE 3.5 4 ug/L 524.2 88 70-130 LFB 0

1,1,1 - TRICHLOROETHANE 3.9 4 ug/L 524.2 98 70-130 LFB 0

1,1,2 - TRICHLOROETHANE 4.0 4 ug/L 524.2 100 70-130 LFB 0

1,2 - DICHLOROETHANE 4.0 4 ug/L 524.2 100 70-130 LFB 0

1,2 - DICHLOROPROPANE 3.9 4 ug/L 524.2 98 70-130 LFB 0

1,2,4 - TRICHLOROBENZENE 4.0 4 ug/L 524.2 100 70-130 LFB 0

*Notation:





Page 4 of 13

SAMPLE INDEPENDENT


Reference Number:




True

Value Units Method

%


QC

Type

QC

524_151223 BENZENE 3.9 4 ug/L 524.2 98 70-130 LFB 0

BROMODICHLOROMETHANE 3.5 4 ug/L 524.2 88 70-130 LFB 0

BROMOFORM 3.6 4 ug/L 524.2 90 70-130 LFB 0

CARBON TETRACHLORIDE 3.8 4 ug/L 524.2 95 70-130 LFB 0

CHLORODIBROMOMETHANE 3.6 4 ug/L 524.2 90 70-130 LFB 0

CHLOROFORM 3.5 4 ug/L 524.2 88 70-130 LFB 0

CIS - 1,2 - DICHLOROETHYLENE 3.8 4 ug/L 524.2 95 70-130 LFB 0

ETHYLBENZENE 3.7 4 ug/L 524.2 93 70-130 LFB 0

METHYLENE CHLORIDE (DICHLOROMETHANE)3.8 4 ug/L 524.2 95 70-130 LFB 0

MONOCHLOROBENZENE 3.8 4 ug/L 524.2 95 70-130 LFB 0

O - DICHLOROBENZENE 3.6 4 ug/L 524.2 90 70-130 LFB 0

P - DICHLOROBENZENE 3.7 4 ug/L 524.2 93 70-130 LFB 0

STYRENE 3.5 4 ug/L 524.2 88 70-130 LFB 0

TETRACHLOROETHYLENE 3.9 4 ug/L 524.2 98 70-130 LFB 0

TOLUENE 3.8 4 ug/L 524.2 95 70-130 LFB 0

TRANS - 1,2 - DICHLOROETHYLENE 3.9 4 ug/L 524.2 98 70-130 LFB 0

TRICHLOROETHYLENE 3.9 4 ug/L 524.2 98 70-130 LFB 0

VINYL CHLORIDE 3.6 4 ug/L 524.2 90 70-130 LFB 0

525_151228 ALACHLOR 1.1 1 ug/L 525.2 110 70-130 LFB 0

ATRAZINE 1.26 1 ug/L 525.2 126 70-130 LFB 0

DI(ETHYLHEXYL)-ADIPATE 1.01 1 ug/L 525.2 101 70-130 LFB 0

HEPTACHLOR EPOXIDE "B" 1.04 1 ug/L 525.2 104 70-130 LFB 0

SIMAZINE 1.07 1 ug/L 525.2 107 70-130 LFB 0

531_151228 CARBOFURAN 20.7 20 ug/L 531.2 104 70-130 LFB 0

OXAMYL (VYDATE) 19.7 20 ug/L 531.2 99 70-130 LFB 0

CARBOFURAN 28.5 30 ug/L 531.2 95 70-130 LFB 1

OXAMYL (VYDATE) 28.6 30 ug/L 531.2 95 70-130 LFB 1

547_151221 GLYPHOSATE 9.7 10 ug/L 547 97 70-130 LFB 0

GLYPHOSATE 21 20 ug/L 547 105 70-130 LFB 1

*Notation:





Page 5 of 13

SAMPLE INDEPENDENT


Reference Number:




True

Value Units Method

%


QC

Type

QC

548_151222 ENDOTHALL 21.6 20 ug/L 548.1 108 65-113 LFB 0

549_151222 DIQUAT 16.2 20 ug/L 549.2 81 70-130 LFB 0

*Notation:





Page 6 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Low-Level Lab Fortified Blank


True

Value Units Method

%


QC

Type

QC

504_151228 1,2 - DIBROMOETHANE (EDB) 0.02 0.02 ug/L 504.1 100 60-140 LLFB 0

DIBROMOCHLOROPROPANE (DBCP) 0.02 0.02 ug/L 504.1 100 60-140 LLFB 0

515.4_151222 2,4 - D 0.15 0.125 ug/L 515.4 120 50-150 LLFB 0

2,4,5 - TP (SILVEX) 0.17 0.125 ug/L 515.4 136 50-150 LLFB 0

DALAPON 0.16 0.125 ug/L 515.4 128 50-150 LLFB 0

DINOSEB 0.11 0.125 ug/L 515.4 88 50-150 LLFB 0

PICLORAM 0.17 0.125 ug/L 515.4 136 50-150 LLFB 0

DALAPON 0.55 0.5 ug/L 515.4 110 50-150 LLFB 1

PENTACHLOROPHENOL 0.024 0.04 ug/L 515.4 60 50-150 LLFB 2

525_151228 ALACHLOR 0.04 0.1 ug/L 525.2 40 50-150 LLFB 0

ATRAZINE 0.09 0.1 ug/L 525.2 90 50-150 LLFB 0

DI(ETHYLHEXYL)-ADIPATE 0.12 0.1 ug/L 525.2 120 50-150 LLFB 0

HEPTACHLOR EPOXIDE "B" 0.09 0.1 ug/L 525.2 90 50-150 LLFB 0

SIMAZINE 0.11 0.1 ug/L 525.2 110 50-150 LLFB 0

531_151228 CARBOFURAN 0.85 1 ug/L 531.2 85 50-150 LLFB 0

OXAMYL (VYDATE) 1.2 1 ug/L 531.2 120 50-150 LLFB 0

548_151222 ENDOTHALL 5.4 5 ug/L 548.1 108 50-150 LLFB 0

*Notation:





Page 7 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Laboratory Reagent Blank


True

Value Units Method

%


QC

Type

QC

1677_151228 CYANIDE, FREE ND mg/L OIA-1677-DW 0-0 LRB 0

200.7_151229A ALUMINUM ND mg/L 200.7 0-0 LRB 0

CALCIUM ND mg/L 200.7 0-0 LRB 0

HARDNESS as Calcium Carbonate ND mg/L 200.7 0-0 LRB 0

IRON ND mg/L 200.7 0-0 LRB 0

MAGNESIUM ND mg/L 200.7 0-0 LRB 0

POTASSIUM ND mg/L 200.7 0-0 LRB 0

SODIUM ND mg/L 200.7 0-0 LRB 0

200.8_160104 ANTIMONY ND mg/L 200.8 0-0 LRB 0

ARSENIC ND mg/L 200.8 0-0 LRB 0

BARIUM ND mg/L 200.8 0-0 LRB 0

BERYLLIUM ND mg/L 200.8 0-0 LRB 0

CADMIUM ND mg/L 200.8 0-0 LRB 0

CHROMIUM ND mg/L 200.8 0-0 LRB 0

COPPER ND mg/L 200.8 0-0 LRB 0

LEAD ND mg/L 200.8 0-0 LRB 0

MANGANESE ND mg/L 200.8 0-0 LRB 0

NICKEL ND mg/L 200.8 0-0 LRB 0

SELENIUM ND mg/L 200.8 0-0 LRB 0

SILVER ND mg/L 200.8 0-0 LRB 0

THALLIUM ND mg/L 200.8 0-0 LRB 0

URANIUM ND mg/L 200.8 0-0 LRB 0

ZINC ND mg/L 200.8 0-0 LRB 0

245.1_151230 MERCURY ND mg/L 245.1 0-0 LRB 0

300.1_160104A BROMATE ND mg/L 300.1 0-0 LRB 0

CHLORITE ND mg/L 300.1 0-0 LRB 0

I151221A CHLORIDE ND mg/L 300.0 0-0 LRB 0

*Notation:





Page 8 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Laboratory Reagent Blank


True

Value Units Method

%


QC

Type

QC

I151221A FLUORIDE ND mg/L 300.0 0-0 LRB 0

NITRATE-N ND mg/L 300.0 0-0 LRB 0

NITRITE-N ND mg/L 300.0 0-0 LRB 0

SULFATE ND mg/L 300.0 0-0 LRB 0

TOTAL NITRATE/NITRITE ND mg/L 300.0 0-0 LRB 0

*Notation:





Page 9 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Method Blank


True

Value Units Method

%


QC

Type

QC

1677_151228 CYANIDE, FREE ND mg/L OIA-1677-DW 0-0 MB 0

200.7_151229A ALUMINUM ND mg/L 200.7 0-0 MB 0

CALCIUM ND mg/L 200.7 0-0 MB 0

HARDNESS as Calcium Carbonate ND mg/L 200.7 0-0 MB 0

IRON ND mg/L 200.7 0-0 MB 0

MAGNESIUM ND mg/L 200.7 0-0 MB 0

POTASSIUM ND mg/L 200.7 0-0 MB 0

SODIUM ND mg/L 200.7 0-0 MB 0

508_151228 CHLORDANE ND ug/L 508.1 0-0 MB 0

TOXAPHENE ND ug/L 508.1 0-0 MB 0

515.4_151222 2,4 - D ND ug/L 515.4 0-0 MB 0

2,4,5 - TP (SILVEX) ND ug/L 515.4 0-0 MB 0

DALAPON ND ug/L 515.4 0-0 MB 0

DINOSEB ND ug/L 515.4 0-0 MB 0

PENTACHLOROPHENOL ND ug/L 515.4 0-0 MB 0

PICLORAM ND ug/L 515.4 0-0 MB 0

524_151223 1,1 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB 0

1,1,1 - TRICHLOROETHANE ND ug/L 524.2 0-0 MB 0

1,1,2 - TRICHLOROETHANE ND ug/L 524.2 0-0 MB 0

1,2 - DICHLOROETHANE ND ug/L 524.2 0-0 MB 0

1,2 - DICHLOROPROPANE ND ug/L 524.2 0-0 MB 0

1,2,4 - TRICHLOROBENZENE ND ug/L 524.2 0-0 MB 0

BENZENE ND ug/L 524.2 0-0 MB 0

BROMODICHLOROMETHANE ND ug/L 524.2 0-0 MB 0

BROMOFORM ND ug/L 524.2 0-0 MB 0

CARBON TETRACHLORIDE ND ug/L 524.2 0-0 MB 0

CHLORODIBROMOMETHANE ND ug/L 524.2 0-0 MB 0

CHLOROFORM ND ug/L 524.2 0-0 MB 0

*Notation:





Page 10 of 13

SAMPLE INDEPENDENT


Reference Number:




True

Value Units Method

%


QC

Type

QC

524_151223 CIS - 1,2 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB 0

ETHYLBENZENE ND ug/L 524.2 0-0 MB 0

METHYLENE CHLORIDE (DICHLOROMETHANE)ND ug/L 524.2 0-1 MB 0

MONOCHLOROBENZENE ND ug/L 524.2 0-0 MB 0

O - DICHLOROBENZENE ND ug/L 524.2 0-0 MB 0

P - DICHLOROBENZENE ND ug/L 524.2 0-0 MB 0

STYRENE ND ug/L 524.2 0-0 MB 0

TETRACHLOROETHYLENE ND ug/L 524.2 0-0 MB 0

TOLUENE ND ug/L 524.2 0-0 MB 0

TRANS - 1,2 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB 0

TRICHLOROETHYLENE ND ug/L 524.2 0-0 MB 0

VINYL CHLORIDE ND ug/L 524.2 0-0 MB 0

1,1 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB TB 15-27550 1

1,1,1 - TRICHLOROETHANE ND ug/L 524.2 0-0 MB TB 15-27550 1

1,1,2 - TRICHLOROETHANE ND ug/L 524.2 0-0 MB TB 15-27550 1

1,2 - DICHLOROETHANE ND ug/L 524.2 0-0 MB TB 15-27550 1

1,2 - DICHLOROPROPANE ND ug/L 524.2 0-0 MB TB 15-27550 1

1,2,4 - TRICHLOROBENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

BENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

BROMODICHLOROMETHANE ND ug/L 524.2 0-0 MB TB 15-27550 1

BROMOFORM ND ug/L 524.2 0-0 MB TB 15-27550 1

CARBON TETRACHLORIDE ND ug/L 524.2 0-0 MB TB 15-27550 1

CHLORODIBROMOMETHANE ND ug/L 524.2 0-0 MB TB 15-27550 1

CHLOROFORM ND ug/L 524.2 0-0 MB TB 15-27550 1

CIS - 1,2 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB TB 15-27550 1

ETHYLBENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

METHYLENE CHLORIDE (DICHLOROMETHANE)ND ug/L 524.2 0-1 MB TB 15-27550 1

MONOCHLOROBENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

O - DICHLOROBENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

P - DICHLOROBENZENE ND ug/L 524.2 0-0 MB TB 15-27550 1

STYRENE ND ug/L 524.2 0-0 MB TB 15-27550 1

TETRACHLOROETHYLENE ND ug/L 524.2 0-0 MB TB 15-27550 1

*Notation:





Page 11 of 13

SAMPLE INDEPENDENT


Reference Number:




True

Value Units Method

%


QC

Type

QC

524_151223 TOLUENE ND ug/L 524.2 0-0 MB TB 15-27550 1

TRANS - 1,2 - DICHLOROETHYLENE ND ug/L 524.2 0-0 MB TB 15-27550 1

TRICHLOROETHYLENE ND ug/L 524.2 0-0 MB TB 15-27550 1

VINYL CHLORIDE ND ug/L 524.2 0-0 MB TB 15-27550 1

525_151228 ALACHLOR ND ug/L 525.2 0-0 MB 0

ATRAZINE ND ug/L 525.2 0-0 MB 0

DI(ETHYLHEXYL)-ADIPATE ND ug/L 525.2 0-0 MB 0

HEPTACHLOR EPOXIDE "B" ND ug/L 525.2 0-0 MB 0

SIMAZINE ND ug/L 525.2 0-0 MB 0

547_151221 GLYPHOSATE ND ug/L 547 0-0 MB 0

EC_151222 ELECTRICAL CONDUCTIVITY ND uS/cm SM2510 B 0-10 MB 0

TDS_151223 TOTAL DISSOLVED SOLIDS (TDS) ND mg/L SM2540 C 0-3 MB 0

TURB_151221 TURBIDITY ND NTU 180.1 0-0 MB 0

*Notation:





Page 12 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Quality Control Sample


True

Value Units Method

%


QC

Type

QC

1677_151228 CYANIDE, FREE 0.149 0.147 mg/L OIA-1677-DW 101 90-110 QCS 0

CYANIDE, FREE 0.249 0.250 mg/L OIA-1677-DW 100 90-110 QCS 0

200.7_151229A ALUMINUM 1.95 2 mg/L 200.7 98 95-105 QCS 0

IRON 2.04 2 mg/L 200.7 102 95-105 QCS 0

CALCIUM 19.7 20 mg/L 200.7 99 95-105 QCS 1

HARDNESS as Calcium Carbonate 132.4 132.3 mg/L 200.7 100 95-105 QCS 1

MAGNESIUM 20.2 20 mg/L 200.7 101 95-105 QCS 1

POTASSIUM 20.3 20 mg/L 200.7 102 95-105 QCS 1

SODIUM 20.3 20 mg/L 200.7 102 95-105 QCS 1

200.8_160104 ANTIMONY 0.038 0.040 mg/L 200.8 95 90-110 QCS 0

ARSENIC 0.042 0.040 mg/L 200.8 105 90-110 QCS 0

BARIUM 0.039 0.040 mg/L 200.8 98 90-110 QCS 0

BERYLLIUM 0.040 0.040 mg/L 200.8 100 90-110 QCS 0

CADMIUM 0.043 0.040 mg/L 200.8 108 90-110 QCS 0

CHROMIUM 0.038 0.040 mg/L 200.8 95 90-110 QCS 0

COPPER 0.040 0.040 mg/L 200.8 100 90-110 QCS 0

LEAD 0.037 0.040 mg/L 200.8 93 90-110 QCS 0

MANGANESE 0.039 0.040 mg/L 200.8 98 90-110 QCS 0

NICKEL 0.041 0.040 mg/L 200.8 103 90-110 QCS 0

SELENIUM 0.043 0.040 mg/L 200.8 108 90-110 QCS 0

SILVER 0.020 0.020 mg/L 200.8 100 90-110 QCS 0

THALLIUM 0.037 0.040 mg/L 200.8 93 90-110 QCS 0

URANIUM 0.101 0.102 mg/L 200.8 99 90-110 QCS 0

ZINC 0.044 0.040 mg/L 200.8 110 90-110 QCS 0

245.1_151230 MERCURY 0.00264 0.00265 mg/L 245.1 100 90-110 QCS 0

300.1_160104A BROMATE 0.0099 0.010 mg/L 300.1 99 85-115 QCS 0

CHLORITE 0.0215 0.020 mg/L 300.1 108 85-115 QCS 0

*Notation:





Page 13 of 13

SAMPLE INDEPENDENT


Reference Number:


15-27356Quality Control Sample


True

Value Units Method

%


QC

Type

QC

504_151228 1,2 - DIBROMOETHANE (EDB) 0.575 0.613 ug/L 504.1 94 70-130 QCS 0

DIBROMOCHLOROPROPANE (DBCP) 1.29 1.38 ug/L 504.1 93 70-130 QCS 0

CL_151221 FREE CHLORINE RESIDUAL 1.21 1.25 mg/L SM4500-Cl G 97 90-110 QCS 0

COLOR_151221 COLOR 10 10 CU SM2120 B 100 0-10 QCS 0

EC_151222 ELECTRICAL CONDUCTIVITY 148.3 146.9 uS/cm SM2510 B 101 90-110 QCS 0

I151221A CHLORIDE 6.5 6 mg/L 300.0 108 90-110 QCS 0

FLUORIDE 3.99 4 mg/L 300.0 100 90-110 QCS 0

NITRATE-N 6.34 6 mg/L 300.0 106 90-110 QCS 0

NITRITE-N 6.51 6 mg/L 300.0 109 90-110 QCS 0

SULFATE 31.2 30 mg/L 300.0 104 90-110 QCS 0

TOTAL NITRATE/NITRITE 12.85 12 mg/L 300.0 107 90-110 QCS 0

TDS_151223 TOTAL DISSOLVED SOLIDS (TDS) 502 500 mg/L SM2540 C 100 80-120 QCS 0

TURB_151221 TURBIDITY 1.00 1.00 NTU 180.1 100 80-120 QCS 0

*Notation:





Page 1 of 8

Reference Number: 15-27356


SAMPLE DEPENDENTQUALITY CONTROL REPORT

Duplicate, Matrix Spike/Matrix Spike Duplicate and Confirmation Result Report

Batch AnalyteSample

Duplicate

UnitsResultResult

QC

CommentsQualifierLimits%RPD Type

Duplicate150.1_151221

59287 HYDROGEN ION (pH) 6.56 pH Units6.57 0.2 0-50 DUP

1677_151228

59287 CYANIDE, FREE ND mg/LND NA 0-20 DUP

200.7_151229A

59287 ALUMINUM ND mg/LND NA 0-20 DUP

59287 CALCIUM ND mg/LND NA 0-20 DUP

59287 HARDNESS as Calcium Carbonate ND mg CaCO3/LND NA 0-20 DUP

59287 IRON ND mg/LND NA 0-20 DUP

59287 MAGNESIUM ND mg/LND NA 0-20 DUP

59287 POTASSIUM ND mg/LND NA 0-20 DUP

59287 SODIUM ND mg/LND NA 0-20 DUP

200.8_160104

58653 COPPER ND mg/LND NA 0-20 DUP

58653 LEAD ND mg/LND NA 0-20 DUP

60186 COPPER 0.023 mg/L0.023 0.0 0-20 DUP


60434 COPPER ND mg/LND NA 0-20 DUP


61244 ANTIMONY ND mg/LND NA 0-20 DUP

61244 ARSENIC 0.0036 mg/L0.0036 0.0 0-20 DUP

61244 BARIUM 0.186 mg/L0.185 0.5 0-20 DUP

61244 CADMIUM ND mg/LND NA 0-20 DUP

61244 CHROMIUM 0.0004 mg/L0.0004 0.0 0-20 DUP

61244 COPPER 0.0003 mg/L0.0003 0.0 0-20 DUP

Matrix Spike (MS)/Matrix Spike Duplicate (MSD) analyses are used to determine the accuracy (MS) and precision (MSD) of a analytical method in a given sample matrix. Therefore, the usefulness of this report is limited to samples of similar matrices analyzed in the same analytical batch.

NA = Indicates %RPD could not be calculated

%RPD = Relative Percent Difference

Only Duplicate sample with detections are listed in this report


FORM: QC Dependent.rpt

Reference Number:Report Date:

Page 2 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

UnitsResultResult

QC



61244 NICKEL 0.0013 mg/L0.0014 7.4 0-20 DUP

61244 SELENIUM 0.0006 mg/L0.0005 18.2 0-20 DUP

61244 ZINC 0.00062 mg/L0.0007 12.1 0-20 DUP


61304 ARSENIC 0.0009 mg/L0.0009 0.0 0-20 DUP

61304 BARIUM 0.016 mg/L0.016 0.0 0-20 DUP


61304 CHROMIUM 0.001 mg/L0.001 0.0 0-20 DUP

61304 COPPER 0.0013 mg/L0.0013 0.0 0-20 DUP


61304 NICKEL 0.0008 mg/L0.0009 11.8 0-20 DUP

61304 SELENIUM 0.001 mg/L0.001 0.0 0-20 DUP

61304 ZINC 0.0012 mg/L0.0012 0.0 0-20 DUP


61849 ARSENIC 0.0056 mg/L0.0053 5.5 0-20 DUP

61849 BARIUM 0.001 mg/L0.001 0.0 0-20 DUP

61849 BERYLLIUM ND mg/LND NA 0-20 DUP


61849 CHROMIUM 0.0027 mg/L0.0025 7.7 0-20 DUP

61849 LEAD 0.0014 mg/L0.0014 0.0 0-20 DUP

61849 MANGANESE 0.004 mg/L0.004 0.0 0-20 DUP

61849 NICKEL 0.0073 mg/L0.008 9.2 0-20 DUP

61849 SELENIUM 0.023 mg/L0.022 4.4 0-20 DUP

61849 SILVER ND mg/LND NA 0-20 DUP

61849 THALLIUM ND mg/LND NA 0-20 DUP

61849 URANIUM 0.013 mg/L0.013 0.0 0-20 DUP

61849 ZINC 0.029 mg/L0.030 3.4 0-20 DUP

245.1_151230

59287 MERCURY ND mg/LND NA 0-20 DUP

60948 MERCURY ND mg/LND NA 0-20 DUP

300.1_160104A

60406 BROMATE ND mg/LND NA 0-20 DUP

61849 BROMATE ND mg/LND NA 0-20 DUP








Page 3 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

UnitsResultResult

QC


61849 CHLORITE ND mg/LND NA 0-20 DUP

524_151223

61849 1,1 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61849 1,1,1 - TRICHLOROETHANE ND ug/LND NA 0-30 DUP


61849 1,2 - DICHLOROETHANE ND ug/LND NA 0-30 DUP

61849 1,2 - DICHLOROPROPANE ND ug/LND NA 0-30 DUP

61849 1,2,4 - TRICHLOROBENZENE ND ug/LND NA 0-30 DUP

61849 BENZENE ND ug/LND NA 0-30 DUP

61849 BROMODICHLOROMETHANE ND ug/LND NA 0-30 DUP

61849 BROMOFORM ND ug/LND NA 0-30 DUP

61849 CARBON TETRACHLORIDE ND ug/LND NA 0-30 DUP

61849 CHLORODIBROMOMETHANE ND ug/LND NA 0-30 DUP

61849 CHLOROFORM ND ug/LND NA 0-30 DUP

61849 CIS - 1,2 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61849 ETHYLBENZENE ND ug/LND NA 0-30 DUP

61849 METHYLENE CHLORIDE (DICHLOROMETHANE) ND ug/LND NA 0-30 DUP

61849 MONOCHLOROBENZENE ND ug/LND NA 0-30 DUP

61849 O - DICHLOROBENZENE ND ug/LND NA 0-30 DUP

61849 P - DICHLOROBENZENE ND ug/LND NA 0-30 DUP

61849 STYRENE ND ug/LND NA 0-30 DUP

61849 TETRACHLOROETHYLENE 10.7 ug/L10.8 0.9 0-30 DUP

61849 TOLUENE ND ug/LND NA 0-30 DUP

61849 TOTAL TRIHALOMETHANE ND ug/LND NA 0-30 DUP

61849 TRANS - 1,2 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61849 TRICHLOROETHYLENE 0.6 ug/L0.6 0.0 0-30 DUP

61849 VINYL CHLORIDE ND ug/LND NA 0-30 DUP

61849 XYLENES (TOTAL) ND ug/LND NA 0-30 DUP

61860 1,1 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP



61860 1,2 - DICHLOROETHANE ND ug/LND NA 0-30 DUP

61860 1,2 - DICHLOROPROPANE ND ug/LND NA 0-30 DUP

61860 1,2,4 - TRICHLOROBENZENE ND ug/LND NA 0-30 DUP








Page 4 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

UnitsResultResult

QC


61860 BENZENE ND ug/LND NA 0-30 DUP

61860 BROMODICHLOROMETHANE 1.6 ug/L1.6 0.0 0-30 DUP

61860 BROMOFORM ND ug/LND NA 0-30 DUP

61860 CARBON TETRACHLORIDE ND ug/LND NA 0-30 DUP

61860 CHLORODIBROMOMETHANE 0.8 ug/L0.9 11.8 0-30 DUP

61860 CHLOROFORM 2.1 ug/L2.0 4.9 0-30 DUP

61860 CIS - 1,2 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61860 ETHYLBENZENE 0.4 ug/L0.5 22.2 0-30 DUPJJ

61860 METHYLENE CHLORIDE (DICHLOROMETHANE) ND ug/LND NA 0-30 DUP

61860 MONOCHLOROBENZENE ND ug/LND NA 0-30 DUP

61860 O - DICHLOROBENZENE ND ug/LND NA 0-30 DUP

61860 P - DICHLOROBENZENE ND ug/LND NA 0-30 DUP

61860 STYRENE ND ug/LND NA 0-30 DUP

61860 TETRACHLOROETHYLENE ND ug/LND NA 0-30 DUP

61860 TOLUENE ND ug/LND NA 0-30 DUP

61860 TOTAL TRIHALOMETHANE 4.5 ug/L4.5 0.0 0-30 DUP

61860 TRANS - 1,2 - DICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61860 TRICHLOROETHYLENE ND ug/LND NA 0-30 DUP

61860 VINYL CHLORIDE ND ug/LND NA 0-30 DUP

61860 XYLENES (TOTAL) 3.7 ug/L3.9 5.3 0-30 DUP

CL_151221

59287 CHLORAMINES TOTAL ND mg/LND NA 0-20 DUP

59287 FREE CHLORINE RESIDUAL ND mg/LND NA 0-20 DUP

EC_151222

60948 ELECTRICAL CONDUCTIVITY 173 uS/cm172 0.6 0-20 DUP

61409 ELECTRICAL CONDUCTIVITY ND uS/cmND NA 0-20 DUP

I151221A

59287 CHLORIDE ND mg/LND NA 0-20 DUP

59287 FLUORIDE ND mg/LND NA 0-20 DUP

59287 NITRATE-N ND mg/LND NA 0-20 DUP

59287 NITRITE-N ND mg/LND NA 0-20 DUP

59287 SULFATE ND mg/LND NA 0-20 DUP

59287 TOTAL NITRATE/NITRITE ND mg/LND NA 0-20 DUP

61546 NITRITE-N ND mg/LND NA 0-20 DUP








Page 5 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

UnitsResultResult

QC


61546 NITRATE-N 0.71 mg/L0.72 1.4 0-20 DUP

61546 CHLORIDE 1.7 mg/L1.7 0.0 0-20 DUP

61546 SULFATE 18.9 mg/L18.8 0.5 0-20 DUP

TDS_151223

59287 TOTAL DISSOLVED SOLIDS (TDS) ND mg/LND NA 0-10 DUP

61548 TOTAL DISSOLVED SOLIDS (TDS) 136 mg/L133 2.2 0-10 DUP

TURB_151221

59287 TURBIDITY ND NTUND NA 0-20 DUP








Page 6 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

SpikeSpikeSpike

Result Result Result Conc Units

Percent Recovery

Limits*%RPDMS MSD Limits*

QC

Qualifier Type Comments

Laboratory Fortified Matrix (MS)1677_151228

59287 CYANIDE, FREE 0.054 mg/LND 0.0500.055 108 110 70-130 1.8 0-20 LFM

200.7_151229A

59287 ALUMINUM 0.51 mg/LND 0.500.51 102 102 70-130 0.0 0-20 LFM

59287 CALCIUM 12.8 mg/LND 13.012.9 98 99 70-130 0.8 0-20 LFM

59287 HARDNESS as Calcium Carbonate 85.1 mg CaCO3/LND 86.085.8 99 100 70-130 0.8 0-20 LFM

59287 IRON 0.49 mg/LND 0.500.50 98 100 70-130 2.0 0-20 LFM

59287 MAGNESIUM 12.9 mg/LND 13.013.0 99 100 70-130 0.8 0-20 LFM

59287 POTASSIUM 17.1 mg/LND 17.517.2 98 98 70-130 0.6 0-20 LFM

59287 SODIUM 12.9 mg/LND 13.013.0 99 100 70-130 0.8 0-20 LFM

200.8_160104

58653 COPPER 0.145 mg/LND 0.150 97 70-130 NA 0-20 LFM

58653 LEAD 0.150 mg/LND 0.150 100 70-130 NA 0-20 LFM

60186 COPPER 0.171 mg/L0.023 0.150 99 70-130 NA 0-20 LFM

60186 LEAD 0.153 mg/LND 0.150 102 70-130 NA 0-20 LFM

60434 COPPER 0.148 mg/LND 0.150 99 70-130 NA 0-20 LFM

60434 LEAD 0.152 mg/LND 0.150 101 70-130 NA 0-20 LFM

61244 ANTIMONY 0.0096 mg/LND 0.010 96 70-130 NA 0-20 LFM

61244 ARSENIC 0.0139 mg/L0.0036 0.010 103 70-130 NA 0-20 LFM

61244 BARIUM 0.190 mg/L0.185 0.010 50 70-130 NA 0-20 LFMIS

61244 CADMIUM 0.0098 mg/LND 0.010 98 70-130 NA 0-20 LFM

61244 CHROMIUM 0.0083 mg/L0.0004 0.010 79 70-130 NA 0-20 LFM

61244 COPPER 0.0097 mg/L0.0003 0.010 94 70-130 NA 0-20 LFM

61244 LEAD 0.0094 mg/LND 0.010 94 70-130 NA 0-20 LFM

61244 NICKEL 0.0098 mg/L0.0014 0.010 84 70-130 NA 0-20 LFM

61244 SELENIUM 0.0106 mg/L0.0005 0.010 101 70-130 NA 0-20 LFM

61244 ZINC 0.0109 mg/L0.0007 0.010 102 70-130 NA 0-20 LFM



61304 BARIUM 0.026 mg/L0.016 0.010 100 70-130 NA 0-20 LFM



61304 COPPER 0.010 mg/L0.0013 0.010 87 70-130 NA 0-20 LFM








Page 7 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

SpikeSpikeSpike


Percent Recovery


QC


61304 LEAD 0.0093 mg/LND 0.010 93 70-130 NA 0-20 LFM

61304 NICKEL 0.0098 mg/L0.0009 0.010 89 70-130 NA 0-20 LFM


61304 ZINC 0.012 mg/L0.0012 0.010 108 70-130 NA 0-20 LFM



61849 BARIUM 0.012 mg/L0.001 0.010 110 70-130 NA 0-20 LFM

61849 BERYLLIUM 0.011 mg/LND 0.010 110 70-130 NA 0-20 LFM



61849 LEAD 0.0112 mg/L0.0014 0.010 98 70-130 NA 0-20 LFM

61849 MANGANESE 0.013 mg/L0.004 0.010 90 70-130 NA 0-20 LFM

61849 NICKEL 0.016 mg/L0.008 0.010 80 70-130 NA 0-20 LFM


61849 SILVER 0.007 mg/LND 0.010 70 70-130 NA 0-20 LFM

61849 THALLIUM 0.010 mg/LND 0.010 100 70-130 NA 0-20 LFM

61849 URANIUM 0.023 mg/L0.013 0.010 100 70-130 NA 0-20 LFM

61849 ZINC 0.037 mg/L0.030 0.010 70 70-130 NA 0-20 LFM

245.1_151230

59287 MERCURY 0.00174 mg/LND 0.001670.00173 104 104 70-130 0.6 0-20 LFM

60948 MERCURY 0.00176 mg/LND 0.001670.00176 105 105 70-130 0.0 0-20 LFM

300.1_160104A

60406 BROMATE 0.010 mg/LND 0.010 100 NA 75-125 NA 0-20 LFM

61849 BROMATE 0.004 mg/LND 0.020 20 NA 75-125 NA 0-20 LFMIM

504_151228

61853 1,2 - DIBROMOETHANE (EDB) 0.24 ug/L0.25 96 NA 65-135 NA 0-20 LFM

61853 DIBROMOCHLOROPROPANE (DBCP) 0.25 ug/L0.25 100 NA 65-135 NA 0-20 LFM

515.4_151222

61409 2,4 - D 2.8 ug/LND 2.52.89 112 116 70-130 3.2 0-20 LFM

61409 2,4,5 - TP (SILVEX) 2.65 ug/LND 2.52.84 106 114 70-130 6.9 0-20 LFM

61409 DALAPON 2.84 ug/LND 2.52.54 114 102 70-130 11.2 0-20 LFM

61409 DINOSEB 2.86 ug/LND 2.53.14 114 126 70-130 9.3 0-20 LFM

61409 PENTACHLOROPHENOL 2.68 ug/LND 2.52.96 107 118 70-130 9.9 0-20 LFM

61409 PICLORAM 2.37 ug/LND 2.51.8 95 72 70-130 27.3 0-20 LFM








Page 8 of 8

1/15/201615-27356

Batch AnalyteSample

Duplicate

SpikeSpikeSpike


Percent Recovery


QC


525_151228

61810 ALACHLOR 1.1 ug/LND 1 110 NA 70-130 NA 0-20 LFM

61810 ATRAZINE 1.16 ug/LND 1 116 NA 70-130 NA 0-20 LFM

61810 DI(ETHYLHEXYL)-ADIPATE 0.98 ug/LND 1 98 NA 70-130 NA 0-20 LFM

61810 HEPTACHLOR EPOXIDE "B" 1.08 ug/LND 1 108 NA 70-130 NA 0-20 LFM

61810 SIMAZINE 1.02 ug/LND 1 102 NA 70-130 NA 0-20 LFM

531_151228

59444 CARBOFURAN 18 mg/LND 2018.9 90 95 70-130 4.9 0-20 LFM

59444 OXAMYL (VYDATE) 17.9 mg/LND 2018.5 90 93 70-130 3.3 0-20 LFM

547_151221

58347 GLYPHOSATE 30 ug/LND 30 100 NA 70-130 NA 0-20 LFM

61409 GLYPHOSATE 45 ug/LND 50 90 NA 70-130 NA 0-20 LFM

548_151222

61409 ENDOTHALL 5.6 ug/L5 112 NA 65-113 NA 0-20 LFM

549_151222

61409 DIQUAT 16.5 ug/LND 20 83 NA 70-130 NA 0-20 LFM

CL_151221

59287 FREE CHLORINE RESIDUAL 0.48 mg/LND 0.500.48 96 96 80-120 0.0 0-20 LFM

I151221A

59287 CHLORIDE 1.1 mg/LND 1 110 NA 90-110 NA 0-20 LFM

59287 FLUORIDE 0.94 mg/LND 1 94 NA 90-110 NA 0-20 LFM

59287 NITRATE-N 0.98 mg/LND 1 98 NA 90-110 NA 0-20 LFM

59287 NITRITE-N 1.01 mg/LND 1 101 NA 90-110 NA 0-20 LFM

59287 SULFATE 1.9 mg/LND 2 95 NA 90-110 NA 0-20 LFM

59287 TOTAL NITRATE/NITRITE 1.99 mg/LND 2 100 NA 90-110 NA 0-20 LFM

61546 NITRITE-N 0.99 mg/LND 1 99 NA 90-110 NA 0-20 LFM

61546 NITRATE-N 1.71 mg/L0.72 1 99 NA 90-110 NA 0-20 LFM

61546 CHLORIDE 2.8 mg/L1.7 1 110 NA 90-110 NA 0-20 LFM

61546 SULFATE 20.8 mg/L18.8 2 100 NA 90-110 NA 0-20 LFM







Page 1 of 1

Qualifier Definitions Reference Number:

Report Date: 01/15/1615-27356

Qualifier Definition

IM Matrix induced bias assumed

IS The ratio of the spike concentration to sample background was too low to meet performance criteria

JJ The amount detected is below the Method's Reporting Level but equal or greater than the lab's Practical Quantitation Level.

LR Low recovery can not be accounted for. However, there is adequate sensitivity to detect the compound at the lower PQL. No sample detections so no further action for this analysis batch.

FORM: QualifierDefs

Note: Some qualifier definitions found on this page may pertain to results or QC data which are not printed with this report.

Page 1 of 1

Prep Method Definitions Reference Number:

Report Date: 01/15/1615-27356

Prep Method Definition

3511 ORGANIC COMPOUNDS IN WATER BY MICROEXTRACTION

3535 Solid-Phase Extraction (SPE)

5030B Purge and Trap for Aqueous Samples

Colilert-18 18 hour test for bacteria

FILTER0.2 Filtration for Organic Analyses (531.2, 547)

FORM: PrepMethDefs.rpt

Documents

Certificate of Complianced284f45nftegze.cloudfront.net/WATERBOY/15-27356_Ozarka Drinkin… · Page 1 of 7 Burlington, WA Corporate Laboratory (a) 1620 S Walnut St Burlington, WA 98233