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Document Number: RCMA-02-EM-PLN-001SUMv5
Cervantes 1
Conventional
Oil Exploration Well
Environment Plan Summary
26/11/2020
RCMA-02-EM-PLN-001SUMv5 PAGE | 2 of 17
1. Terms & Abbreviations
Abbreviation Description
ALARP As low as reasonably practicable
ASL Above Sea Level
BKNR Beekeepers Nature Reserve
BOP Blow Out Preventer
DBCA Department of Biodiversity, Conservation and Attractions (formerly Department of Parks and Wildlife (DPaW))
DFES Department of Fire and Emergency Services
DMIRS Department of Mines, Industry Regulation and Safety (formerly Department of Mines and Petroleum (DMP))
EP Environment Plan
HSE Health, Safety and Environment
JPF Jingemia Production Facilities
Lead Contractor Contractor whose RCMA approved HSEMS will be utilised at the Project Location for management of the relevant phase of the Project
OSCP Oil Spill Contingency Plan
PEC Priority Ecological Community
RCMA RCMA Australia Pty Ltd
SDS Safety Data Sheet
SMART Specific, Measurable, Attainable, Relevant, Time-bound (Criteria)
VSP Vertical Seismic Profile
WBM Water Based Muds
RCMA-02-EM-PLN-001SUMv5 PAGE | 3 of 17
2. Contact RCMA Project Manager PO Box 86 WEST PERTH WA 6872 E: [email protected]
3. Introduction RCMA Australia Pty Ltd (RCMA) proposes to drill the Cervantes 1 exploration well, 11 km south of Dongara/Port Denison in Production Licence L14 (Figure 1). The proposed site is located within the vegetated Beekeepers Nature Reserve (BKNR) in the northern Perth Basin (Figure 2). The proposed well will be deviated to avoid environmental sensitivities and will be drilled to a planned depth of 2,562 mTVD (true vertical depth). The well pad will occupy an area of approximately 2.6 ha with 4.1 km of existing road and tracks utilised for access. Site preparation operations are planned to commence in early quarter 1 CY2022, with drilling operations commencing late quarter 1 CY2022. RCMA is an Australian upstream oil and gas company that own and operate the Jingemia Production Facility (JPF), an onshore Perth Basin oil production facility situated in Petroleum Production Licence L14, 3 km from the Cervantes 1 Conventional Oil Exploration Drill Site. A Cervantes 1 Development would utilise the existing JPF Facilities.
3.1 Purpose The purpose of this document is to provide a summary of the Cervantes 1 Conventional Oil Exploration Well Environment Plan (EP) [RCMA-02-EM-PLN-001]. This summary document has been prepared to in accordance with the requirements of the Petroleum and Geothermal Energy Resources (Environment) Regulations 2012.
3.2 Environment Plan Implementation RCMA is the custodian of this EP and has overall responsibility for its implementation, compliance and revision.
Project Area
290000
290000
300000
300000
310000
310000
320000
320000
330000
330000
340000
340000
350000
350000 6690
000
6700
000
6700
000
6710
000
6710
000
6720
000
6720
000
6730
000
6730
000
6740
000
6740
000
6750
000
6750
000
6760
000
6760
000
6770
000
6770
000
Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202
Author: A. Wills, 0417993734, [email protected]
Date: Jan 2020 Rev: 0 A3CAD Ref: a2750_f04_01
Scale: 1:250,000MGA94 (Zone 50)
Figure:
.Cervantes 1 Regional Location 1
0 3,000 6,000mNotesImage: GSA
LegendDevelopment Envelope
!(
!(
LOCALITY
PROJECT AREA
WESTERNAUSTRALIA
PerthKalgoorlie
Acce
ss Tr
ack
Railway Crossing
Wellpad Including:Mud SumpTurkeys NestFlare PitGroundwater Monitoring BoreAbandonment Plaque
Hamersley Rd
Dong
ara - E
neab
ba R
ailwa
y
Jingemia
L 14
L 2 R1303000
303000
304000
304000
305000
305000
6750
000
6750
000
6751
000
6751
000
6752
000
6752
000
6753
000
6753
000
Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202Date: Mar 2021 A3
CAD Ref: a2750_f09_01
Scale: 1:12,500MGA94 (Zone 50)
Figure:
. 20 150 300mNotes
Image: Landgate (Nov 2016)Petroleum Data: DMIRS
LegendSite AccessSite B Swale Access Site B Swale Access ExitDrill Site and Fire BreaksProduction Licence
Author: A. Wills, 0417993734, [email protected]
Rev: A
Cervantes 1 Conventional WellDrill Site & Access
RCMA-02-EM-PLN-001SUMv5 PAGE | 6 of 17
4. Description of the Activity RCMA plan to drill the Cervantes 1 exploration well in late Q1 CY2022. The project will include the following key stages: • Site preparation:
o Establishment of hygiene station as per Hygiene Procedure [RCMA-02-EM-PRO-001] o Clearing and preparation of access tracks and drill site o Levelling, sheeting and preparation of surfaces to support compressive loads and
limit erosion to the existing landscape o Conductor drilling o Construction of lined mud sump, turkey’s nest, vertical seismic profile (VSP) pit and
well cellar o Baseline monitoring (soil and groundwater)
• Mobilisation of drilling package, ancillary services, site office, personnel and supplies • Drilling exploration program:
o Conducting the exploration drilling activities o Completion (and test) or abandonment of well
• Demobilisation of drilling package, ancillary services, site office, personnel and supplies • Decommissioning and rehabilitation:
o Restoration of the site following the completion of activities, if not considered commercially viable
o Handover site to operations for care and maintenance o Rehabilitation of decommissioned infrastructure
4.1 Timeframe and Schedule The indicative project timeframe and schedule is presented in Table 1.
Table 1: Proposed Timeline
Activity Approximate Duration Indicative Timing
Site Preparation ~30 days Early Quarter 1 CY2022
Mobilisation ~10 days Quarter 1 CY2022
Drilling 22 to 40 days Late Quarter 1 CY2022
Demobilisation ~10 days Quarter 2 2022
*The timeframe and schedules for subsequent phases of the Project (well completion, well testing, well intervention, development, care & maintenance, decommissioning, rehabilitation) will be determined based on drilling results.
Table 2 provides an overview of the activity detailed further in the remainder of Section 2.
RCMA-02-EM-PLN-001SUMv5 PAGE | 7 of 17
Table 2: Cervantes 1 Well Summary
Feature Description
Site location ~300 km North of Perth and 11 km South of Dongara/Port Denison within the vegetated Beekeepers Nature Reserve
Permit L14
Approximate Well Surface Coordinates
Within development envelope shown in Figure 2: ~303 231 mE ~6 749 511 mN
Proposed mobilisation route
Truck movements via JPF and an upgrade to the access track along the railway line
Drilling timing Late Q1 CY2022
Estimate project duration 60 to 90 days
Planned total depth TD: ~2,562 mTVD
Project footprint
Access road: <4.0 ha (based on 4.1 km and 9 m cleared width) Workpad: <2.6 ha
Total Footprint: <6.6 ha (<4.5 ha requires clearing)
Drilling mud type Water-based mud (WBM)
Disposal of muds and cuttings
WBM and cuttings discharged into a lined sump during drilling and allowed to evaporate. Soil testing will determine appropriate method of disposal/reuse offsite
Accommodation Main camp located at an externally owned and operated camp on Pye Road, Dongara. On site camp will accommodate immediate response personnel
Hygiene Station
One vehicle and equipment hygiene station will be established on commencement of site preparation activities at the JPF. All vehicles, equipment and personnel will be required to undertake inspections when travelling to the Cervantes 1 clean on entry point
Water Supply Water will be supplied from the JPF ground water bore GWL202619(1)
Performance Bonds
• A Rehabilitation Performance Bond shall be in place prior to the implementation of the proposal until the rehabilitation has been completed
• A Post Rehabilitation Performance Bond shall be in place from rehabilitation until completion criteria are achieved
• A P&A Performance Bond shall be in place on commercial discovery of hydrocarbons until the well has been P&A
RCMA-02-EM-PLN-001SUMv5 PAGE | 8 of 17
4.2 Site Preparation Access will be provided via upgrades to existing tracks from the JPF along the railway easement track and existing railway crossing (Figure 2). The well pad will be located within the development envelope and will possibly be located in the southern end as per Figure 2. The well site will include the following elements: • Cellar for drilling rig • Flare pit • Residual drilling fluid and cuttings storage pond (sump) • Water holding pond (turkey nest) / water storage tanks • Shallow groundwater monitoring bore • Workshop area and office space • VSP pit • Smoko shack • Generator set and pump skid unit • Toilet block and sewage holding tank • Parking for light vehicles, trucks and trailers • Fuel and chemical storage areas.
The overall cleared area is approximately 2.6 ha. This includes the well site (2 ha) that will be compacted along with an external area to cater for soil stockpiling and a fire break around the perimeter. Measures will be in place to reduce impacts of the operation on native fauna: • Installing fauna egress matting within the ponds (mud sump and turkey’s nest) • Installing fencing to deter ground-dwelling native fauna accessing the mud sump, turkey’s
nest and VSP pit. Fencing will remain around the drilling sump and turkey nest and be erected around the wellhead following completion of drilling operations until the infrastructure is decommissioned.
4.3 Vehicle Movement The drilling rig, ancillary services, personnel and supplies will be mobilised by road to the project area. Access is via the JPF utilising the Brand Highway. Vehicle and equipment movement will be restricted to the designated access tracks. There will be approximately 70-80 trailer loads moved during mobilisation and demobilisation. A crew change bus will be used to move personnel between Perth and the project location for rotational crew changes and between the offsite accommodation and drill site for shift changes. Utilisation of shared vehicles and a crew change bus will minimise vehicle movement to and from the site as much as practicable, minimising local traffic and vehicle-related safety and environment risks.
4.4 Drilling Once the drill rig is assembled on location, all activities associated with drilling (e.g. refuelling, mixing of drilling muds and cement) occur on the well pad. The project involves the following key stages: • Drilling the well with a rotary drilling rig using recirculated WBM (primarily (>97%) water,
and non-toxic additives; barite, potassium chloride, calcium carbonate, sodium chloride and bentonite)
• Conducting wireline logging evaluation of the formations drilled • Cementing well steel casing strings in place
RCMA-02-EM-PLN-001SUMv5 PAGE | 9 of 17
• Plug and abandonment of the well (in a dry hole case) Rotary drilling is the process of utilising a drill string and drill bit to break small pieces of rock and remove these pieces of rock from the hole by circulating a fluid (drilling mud) down the drill string and up the annulus between the drill string and drilled hole. A blow out preventer (BOP) is installed once drilling is at a depth where it is possible for hydrocarbons to be intersected. The BOP (secondary well control) provides a mechanical means by which the well can be closed and secure the contents of the well should the mud system fail to maintain a positive pressure on the drilled hole. If hydrocarbons are intersected, and flow to surface is not prevented by the drilling mud, the BOP will be closed allowing a controlled release of these hydrocarbons to the flare pit. The flare pit and any firebreaks are constructed in compliance with any specific DFES permit requirements. All drilling fluids will be contained within the mud system. This system is constantly monitored by personnel and pit level sensors for volume changes. The chemicals proposed for use in the Cervantes 1 program are disclosed within Appendix A. The disclosure tables have been prepared in accordance with the guideline and the Chemical Disclosure Reporting template provided for within the guideline. The chemical disclosure tables cover the following ‘down-hole’ activities: • Drilling (WBMs) • Cementing
The Safety Data Sheets (SDSs) for the chemicals associated with the Cervantes 1 activities are provided in Appendix B.
4.5 Chemicals and Materials Storage, Handling and Transfers All chemicals and hazardous materials required for the project will be appropriately packaged and delivered to the rig site in tanks, pails or drums, sealed bags and where appropriate stacked and secured on pallets. All chemicals and hazardous materials will be transported as required by regulation according to the material class and associated specific transportation advice. All transported materials shall be accompanied by a current SDS. Oil, fuel, and hazardous liquid chemicals will be stored in the bunded chemical storage area on the well pad. All chemicals will be stored in accordance with the requirements of their relevant SDS. SDSs for each chemical used and stored onsite are held in the site office. On site oil, fuel, and hazardous liquid chemicals will be bunded to contain not less than 110% of the volume of the largest vessel and at least 25% of the total substance stored (where more than one storage is connected to a common compound, drainage tank or similar storage vessel)). This includes waste hydrocarbon products. Dry chemicals will be stored off the ground on pallets and covered with tarpaulins to maintain product integrity during wet conditions. Empty hazardous liquid chemical containers or drums will be stored within the waste storage area.
4.6 Well Testing If the Cervantes 1 well proves successful and further evaluation through well testing is required, the additional evaluation phases of the Cervantes 1 well operations would commence as soon as reasonably possible. These would be expected to continue over a period of 1 month during Q3 2022 with actual duration determined based on the acquired evaluation data. This would include operations such as wellbore clean out, completion installation, well test operations, production logging evaluation, and other associated well intervention activities as specified in the well completion and testing programme to complete this evaluation phase of the project.
4.7 Waste Management Waste will be segregated and stored within designated areas and disposed via an approved waste disposal contractor in accordance with Table 3. Waste receptacles will be clearly labelled and have
RCMA-02-EM-PLN-001SUMv5 PAGE | 10 of 17
adequate covering (noting that the steel recycling skip bin does not need to be covered). Records will be retained for all waste disposal events.
Table 3: Waste Disposal Details
Waste Product Method of Disposal
Casing protectors (plastic) Placed into rubbish skip and removed off site by waste contractor.
Batteries Stored in central location and removed offsite to nearest recycling centre by waste contractor.
Cigarettes Disposed to dedicated receptacle and removed off site by waste contractor.
Contaminated Soil Contained on site and removed by a licensed contractor to a licensed facility in accordance with Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009).
Cuttings/mud
Drilling muds and cuttings will be taken for offsite reuse or disposal. The water within the muds and cuttings in the drill sump will be allowed to evaporate and soil testing undertaken to determine appropriate method of disposal or reuse.
Drilling line Placed into rubbish skip and removed off site by waste contractor.
Food waste Placed into rubbish skip and removed off site by waste contractor.
Hazardous waste (solid)
Placed in appropriately labelled receptacles within a bunded area and removed off site for disposal by a licensed contractor at a licensed facility in accordance with Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009).
Metal drums Placed in central location and removed off site by waste contractor.
Mud sacks Placed into rubbish skip and removed off site by waste contractor.
Mud sump liner Taken by truck to landfill.
Plastic products Placed into rubbish skip and removed off site by waste contractor.
Refrigeration gas Recovered by licensed refrigeration electrician/mechanic and returned to authorised agent for disposal.
Sewage (greywater and black water)
Rig: Septic holding tank for offsite disposal by waste contractor.
Camp: On-site septic system (as per existing)
Steel scrap (including steel casing protectors and drill line)
Placed in one central area after use/removal. Then placed into steel bin and removed off site by waste/recycling contractor.
Tyres & rubber products Placed into rubbish skip and removed off site by waste contractor.
RCMA-02-EM-PLN-001SUMv5 PAGE | 11 of 17
Waste Product Method of Disposal
Waste oil Placed into empty oil drums and removed from site by a licensed waste contractor. While stored on site, waste oil will be stored within a bunded area.
Wooden pallets Placed into rubbish skip and removed off site by waste/recycling contractor.
4.8 Care and Maintenance If the Cervantes 1 well is successful, it will be suspended while development plans and approvals are sought. In the period prior to start-up of a new development, the Cervantes 1 well will be handed over to JPF personnel. The project area will be inspected weekly and any actions that cannot be addressed immediately will be tracked to completion. Weed control will be undertaken as part of Care and Maintenance (C&M) Activities. As per Table 4, Cervantes 1 will be under Care and Maintenance (C&M) Activities from rig demobilisation until rehabilitation has met completion criteria.
Table 4: Cervantes 1 Future Timeframe
Activity Indicative Timing
Demobilisation of Rig Q2 CY2022
Well Testing1 Quarter 3 / Quarter 4 CY2022
Commence decommissioning of the railway access track3 Quarter 4 CY2022
Well (Future) Decision for Development1 Quarter 4 CY2022
Well (Future) Decision for P&A Quarter 4 CY2022
Undertake P&A of well2 Dependent on rig availability (within 12 months from decision to P&A)
Finalise Rehabilitation Plan First summer following P&A (eg Quarter 1 CY20233)
Mud Sump Decommissioning Quarter 1 CY2023
Rehabilitation First autumn following P&A (eg Late Quarter 1 / Early Quarter 2 CY20233)
Remove marl
Deep ripping and surface cultivation
Complete, topsoil return and vegetation material spreading (March CY2023)
Initial establishment monitoring for erosion, weeds and plant establishment
(June/July CY2023)
RCMA-02-EM-PLN-001SUMv5 PAGE | 12 of 17
Activity Indicative Timing
Conduct weed control if required (August CY2023)
Establish rehabilitation performance monitoring quadrats and assess (September/October CY2023)
Year 2 Post Rehabilitation Activity – Monitoring Program
Year 3 Post Rehabilitation Activity – Monitoring Program
Year 4 Post Rehabilitation Activity
Anticipate completion criteria achieved in Year 3 Contingency for rectification and further monitoring
1 If well is suspended at time of drilling rather than P&A 2 If decision is made to P&A well 3 If well is P&A at time of drilling
4.9 Decommissioning and Rehabilitation Decommissioning will involve the removal of the mud sump contents, mud sump, flare pit and Turkey’s Nest liners and back fill of the mud sump, flare pit, VSP pit and Turkey’s Nest. The project area is to be returned to Nature Reserve with the access tracks and firebreaks reinstated, including the railway corridor access track. Activities to be undertaken during rehabilitation activities are presented in Table 5.
Table 5: Rehabilitation Activities
Activity Method
Vehicle and equipment hygiene offsite inspection and clean down
Weed control vehicle and hand spraying, hand pulling
Removal of marl from well pad and portions of track not required or to be narrowed for future DBCA access mechanical means
Respreading of topsoil then stockpiled vegetation mechanical means
Propagule introduction hand scatter
Fertilisation hand spread
Monitoring visual
Remedial Works method determined if required
Progressive decommissioning will commence based on the following factors: • provisional on prospect forecast (ie future utilisation of well) • site conditions (eg mud sump status) • ensuring resource optimisation (eg minimising mobilisation operations)
RCMA-02-EM-PLN-001SUMv5 PAGE | 13 of 17
Rehabilitation planning has been undertaken in accordance with the DMIRS Guidance Note – Decommissioning, rehabilitation, and closure of petroleum activities [DMIRSNOV19_6259] and a site-specific rehabilitation plan has been developed based on appropriate objectives, standards and methods to ensure that all disturbed areas are decommissioned and rehabilitated within a specified timeframe and in an ecologically sustainable manner such that the post disturbance environment is commensurate with the ecological and landscape values of BKNR, avoiding any significant long-term detrimental risks, impacts and liabilities. The rehabilitation plan outlines the following aspects:
o Current Conditions and Issues o Risk Assessment o Earthworks and Site Preparation to be undertaken o Propagule Introduction and Fertilising o Closure and Specific Completion Criteria consistent with specific, measurable,
attainable, relevant, time-bound (SMART) criteria o Thresholds and Triggers o Responsibility and Accountability o Supervision & Schedule o Monitoring and Maintenance o Reporting and Review
The completion criteria and performance indicators included in the rehabilitation plan have been agreed by DBCA to ensure that rehabilitation achieves a stable and functioning landform and ecological system consistent with pre-existing and surrounding landscape and environmental values. DBCA and EPA have approved the Cervantes 1 Rehabilitation Plan. Rehabilitation will be monitored annually with inspections of the rehabilitating site undertaken monthly until completion criteria are achieved. The projected timeline for decommissioning and rehabilitation is presented in Table 4. It is projected in an unsuccessful drilling case that Cervantes 1 will achieve its completion criteria in 2026.
RCMA-02-EM-PLN-001SUMv5 PAGE | 14 of 17
5. Description of the Environment Table 6 summarises the existing environment in the project area and Figure 3 presents the Environmental Sensitivities.
Table 6: Description of the Environment
Aspect Description
Landform Drill pad within development envelope 4 m ASL
Soil Quindalup dunes - sands
Surface water Nil
Groundwater Superficial aquifer approx 10 m below ground level (bgl) with 3,000 to 7,000 mg/L salinity
Conservation area Within the Beekeepers Nature Reserve
Vegetation • Two individual priority flora plants avoided outside project area • Widely mapped Priority 1 (P1) Priority Ecological Community
(PEC) in Project Area
Weeds 5 significant weeds known to occur in the region
Dieback Very low risk
Fauna • 19 conservation significant fauna species in region • No Carnaby’s Black Cockatoo breeding or roosting habitat • Negligible Carnaby’s Black Cockatoo quality foraging habitat
Aboriginal Heritage Nil
European Heritage Nil
Socio-economic
• Beekeeping • Lime sand extraction • Recreational fishing access • 11 km from twin towns of Dongara / Port Denison • Inactive freight-only railway line
Dongara - Eneabba Railway
Jingemina
Brand Highway
DONGARA
PORTDENISON
Irwin River
BeekeepersNature
Reserve
BeekeepersNature
Reserve
BeekeepersNature
Reserve
BeekeepersNature
ReserveYardanogo
NatureReserve
YardanogoNature
Reserve
Allanooka - Dongara-DenisonWater Reserve
DongaraNatureReserve
300000
300000
305000
305000
310000
310000
315000
315000
6745
000
6745
000
6750
000
6750
000
6755
000
6755
000
6760
000
6760
000
6765
000
6765
000
Drawn: CAD Resources ~ www.cadresources.com.au Tel: (08) 9246 3242 ~ Fax (08) 9246 3202Date: Jan 2020 A3
CAD Ref: a2750_f04_03
Scale: 1:75,000MGA94 (Zone 50)
Figure:
. 30 900 1,800m
NotesProject within Arrowsmith Groundwater Area and the Shire of Irwin
LegendDevelopment EnvelopeEnvironmentally Sensitive AreaPublic Drinking Water Source AreasRed Book - Northern Sandheaths
WaterwaysDBCA Estate
Author: A. Wills, 0417993734, [email protected]
Rev: 0
Environmental Sensitivities
Source: Image: Landgate (Nov 2016), Petroleum Data: DMIRS, ESA, Red Book, PDWSA, Waterways: DWER, DBCA Estate: DBCA
RCMA-02-EM-PLN-001SUMv5 PAGE | 16 of 17
6. Environmental Risk Assessment and Methodology An Environmental Risk Assessment consistent with the Australian Standard for Risk Management (AS/NZS ISO 31000:2009) was undertaken for the Cervantes 1 project. Appendix C presents the moderate and above risks identified during the risk assessment.
7. Implementation Strategy The objective of the implementation strategy is to describe how all aspects of the activity will be directed, reviewed and managed to ensure that all potential impacts and risks are continuously reduced to ALARP. The specific implementation objectives include:
1. Ensure that the agreed environmental performance objectives and standards are met
2. Identify specific systems, practices and procedures to be used to ensure that environmental risks and effects are reduced to ALARP
3. Establish a commitment to the protection of the environment
4. Establish a clear chain of command that sets out the roles and responsibilities of personnel in relation to the implementation, management and review of the EP
5. Ensure that each employee or contractor working on or in connection with the activity has the appropriate skills and training
6. Monitor, audit and review environmental performance and the Implementation Strategy
7. Maintain quantitative records
8. Develop and implement emergency and spill preparedness planning and response capability
9. Report on environmental performance
10. Provide for appropriate consultation with relevant government authorities and other interested persons or organisations
Details of RCMA systems, practices and procedures relating to the management of all potential impacts and risks of the activity are detailed in Table 7. The objective of these are to continuously reduce the potential impacts and risks of the activity to ALARP.
8. Stakeholder Engagement RCMA has consulted with key stakeholders in relation to its Cervantes 1 exploration activities. These stakeholders have included: • DMIRS • Environmental Protection Authority (EPA) • DBCA • Shire of Irwin • ARC Infrastructure • Public Transport Authority • Yamatji Marlpa Aboriginal Corporation (YMAC) • Yamatji Southern Regional Corporation • Neighbouring hydrocarbon facility and permit owners
RCMA will continue to engage with stakeholders for the life of the Cervantes 1 Project.
RCMA-02-EM-PLN-001SUMv5 PAGE | 17 of 17
Table 7: Systems, Practices and Procedures
Item Objective to achieve ALARP Document Name Location
Code of Practice for RCMA sites
To outline the main HSE criteria to be observed by RCMA and its contractors
RCMA HSE Policy [RCMA-01-PO-POL-001]
Rig Office Crib Room
Environment Plan To document environmental management of activities Cervantes 1 Conventional Well EP [RCMA-02-EM-PLN-001]
Rig Office Well Site Manager Office Drilling Project Manager Computer HSE Advisor Computer
Environment Plan Summary
To provide a public summary of the details in the Environment Plan
RCMA-02-EM-PLN-001SUM EARS2 DMIRS Website
Oil Spill Preparedness and Response To provide guidance on the management of a spill
Cervantes 1 Conventional Well OSCP [RCMA-02-EM-PLN-002]
Rig Office Well Site Manager Office Drilling Project Manager Computer
Emergency Response Plan To provide guidance on the management of an emergency situation
Cervantes 1 Civils Emergency Response Plan [RCMA-02-SAF-PLN-001]
Earthworks Supervisor Drilling Project Manager Computer
Cervantes 1 Drilling Phase Emergency Management Plan [RCMA-02-SAF-PLN-004]
Rig Office Well Site Manager Office Drilling Project Manager Computer
RCMA Australia Safety Management System
To provide a framework comprising a set of expectations and guidelines for effective management of HSE aspects and impacts of operations
[RCMA-02-SAF-SYS-001] or drilling specific subsidiary document
Well Site Manager Office Drilling Project Manager Computer RCMA Project Manager Computer HSE Advisor Computer
Hazard and Incident Reporting
To outline the processes and requirements for hazard and incident reporting
Incident Reporting & Investigation Standard [OMS-0224]
Drilling Project Manager Computer
Hygiene Management To document the completion of hygiene inspections for personnel entrance into BKNR
Cervantes 1 Hygiene Management Plan [RCMA-02-EM-PLN-003]
Earthworks Supervisor Rig Office Well Site Manager Office Drilling Project Manager Computer
Standard Operating Procedures
To guide personnel on how to conduct tasks to meet environmental performance throughout operations
Contractor Management Systems Electronic Filing System
Permit to Work System To ensure drill site is in a safe and environmentally acceptable condition before works commence and is kept in this condition until all personnel involved in the work have signed off completion
Permit to Work System Rig Office
Clearing Vegetation Recording
To guide and document the conditions, approval and details of clearing activities to ensure compliance with clearing permits and legislation
Cervantes 1 Vegetation Management Plan [RCMA-02-EM-PLN-004]
Earthworks Supervisor Office Environmental Advisor Computer
Cervantes 1 Clearing Vegetation Record [RCMA-02-EM-FM-002]
Earthworks Supervisor Vehicle Environmental Advisor Computer
Fauna Management To provide a practical guide on fauna management measures associated with the Cervantes 1 Project
Cervantes 1 Fauna Management Plan [RCMA-02-EM-PLN-007]
Earthworks Supervisor Office Drilling Project Manager Computer HSE Advisor Computer
Waste Management A guide on the segregation, handling and disposal of wastes associated with the Cervantes 1 drilling project
Cervantes 1 Waste Management Plan [RCMA-02-EM-PLN-009]
Earthworks Supervisor Office Rig Office Well Site Manager Office Drilling Project Manager Computer
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
Chemical Disclosure
A.1 Drilling Fluid and Completion Brine Chemical Disclosure
A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Drilling Fluid & Completion Brine TOTAL VOLUME OF SYSTEM (m3) 1,870 m3 (includes 100% contingency volume)
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
1. Water Onsite water bore Base fluid 78.37%
2. Barite / Newbar Newpark Weighting agent
Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. Toxicity Data: Toxicity data available for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021
7.12% 06/02/2020
3. Potassium Chloride Newpark
Shale swelling inhibition (smectite & illite clays)
Acute Toxicity: LD50 (Ingestion): 1500 mg/kg (mouse) LD50 (Intraperitoneal): 620 mg/kg (mouse) LD50 (Intravenous): 117 mg/kg (mouse) LDLo(Ingestion): 20 mg/kg (man) LDLo (Intraperitoneal):900 mg/kg (guinea pig) LDLo (Intravenous): 77 mg/kg (guinea pig) LDLo (Subcutaneous): 2120 mg/kg (frog) TDLo(Ingestion): 60 mg/kg/days (woman) Ecotoxicty Data: In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictalurus punctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronic reproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronic aquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerations the background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for further investigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulation potential for the substance. Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. Mobile in Soil: No impact if small amount is released to the soil. OCNS Rated E - 24330, Exp 11/03/2021
4.34% 03/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
4.
Calcium Carbonate (including various grades) Circal 60/16, Circal Y, Circal 1000, Stonedust, Limestone LSC Calcium Carbonate (including various grades) Omyacarb 10, 20 & 40
Newpark Bridging & weighting agent
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met. Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated to cause adverse environmental effects. Acute Toxicity: LD50 (Ingestion): 6450 mg/kg (rat) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. Dissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in the water and the carbonate will become part of the carbon cycle. This product does not bioaccumulate
3.50% 02/06/2021
5. Salt (Sodium Chloride all grades)
Newpark Weighting agent
Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours LC50 (fathead minnow) is 6.57 g/L/96 hours This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
2.87% 10/03/2017
6. Bentonite / NewGel NT / API Bentonite
Newpark Viscosifier
The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. Toxicity Data: Toxicity data available for ingredient: QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours
1.16% 20/10/2020
Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
7. NewPac LV / Drispac SL
Newpark / Newpark (Drilling Specialties Company)
Fluid loss
Acute Toxicity: Toxicity data available for ingredients: SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4) LD50 (Ingestion): 16000 mg/kg (guinea pig) LD50 (Skin): > 2000 mg/kg (rabbit) TDLo (Ingestion): 140 mg/kg (rat) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) SODIUM GLYCOLATE (2836-32-0) LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat)
0.78% 25/11/2020 / 30/07/2020
Ecotoxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. NewPac LV - OCNS Rated E - 28129, Exp 18/05/2021
8. NewZan D (Xanthan Gum) Newpark Vicosifier
Acute Toxicity: LD50 (oral) > 1000 mg/kg (mouse) LD50 (oral) > 45,000 mg/kg (rat) LD50 (oral) > 20,000 mg/kg (dog) LD50 (intraperitoneal): > 50 mg/kg (mouse) LD50 (intravenous): 100-250 mg/kg (mouse) This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. OCNS Rated E - 26280, Exp 22/02/2021
0.57% 11/02/2020
9. AvaPolymer 5050 Newpark
Encapsulating Agent - provides shale inhibition
CONSTITUENT 1 (95%) Acute toxicity: Acute oral toxicity (LD50): 9380 mg/kg [Rat]. Ecological Information: Ecotoxicity in water (LC50): 100 mg/l 96 hours [Fish]. Possibly hazardous short-term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.
0.40% 02/08/2017
CONSTITUENT 2 (5%) Acute toxicity: Dermal LD50 Albino rabbit - > 2000 mg/kg, 14 days At this dose no death occurred. LD50 Oral Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no death occurred. Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Tall Oil Fatty Acids EC50 Bacteria (Pseudomonas putida) > 10000 mg/l, 16 hr Aquatic Algae EL50 > 1000 mg/l, 72 hr Growth rate; OECD 201 Green algae (Selenastrum capricornutum) Crustacea EL50 Water flea (Daphnia magna) > 1000 mg/l, 48 hr OECD 202 Fish LL50 Zebra danio (Danio rerio) > 10000 mg/l, 96 hr
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Biodegradability: Percent degradation (Aerobic biodegradation) Tall Oil Fatty Acids 88 - 100 % CO2 Evolution Test Species: Activated sewage sludge Test Duration: 28 d Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915
10. Sodium Sulphite Newpark Oxygen scavenger
Acute Toxicity: LD50 (Ingestion): 820 mg/kg (mouse) LD50 (Intraperitoneal): 950 mg/kg (mouse) LD50 (Intravenous): 175 mg/kg (mouse) LDLo (Ingestion): 2825 mg/kg (rabbit) LDLo (Intravenous): 400 mg/kg (cat) LDLo (Subcutaneous): 600 mg/kg (rabbit) SODIUM CARBONATE (497-19-8) LC50 (inhalation) 800 mg/m³/2 hours (guinea pig) LD50 (ingestion) 4090 mg/kg (rat) LD50 (intraperitoneal) 117 mg/kg (mouse) LD50 (subcutaneous) 2210 mg/kg (mouse) SODIUM SULPHATE (7757-82-6) LD50 (ingestion) 5989 mg/kg (mouse) LD50 (intravenous) 1220 mg/kg (rabbit) LDLo (intravenous) 1220 mg/kg (mouse) TDLo (ingestion) 14 g/kg (mouse - 8-12 days pregnant) TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category and registration number E - 26232
0.23% 28/04/2021
11. FlexFirm KA Newpark Provides shale inhibition
Toxicological Information: Acute toxicity Information available for the product: No known toxicological effects from this product. Based on available data, the classification criteria are not met. Skin Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns. Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possible burns. Sensitization This product is not classified as causing skin or respiratory sensitisation. Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result in breathing difficulties. STOT – single exposure Aspiration This product does not present an aspiration hazard. Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodular lung disease caused deposition in the lungs of fine respirable particles of crystalline silica. Principal symptoms of silicosis are coughing and breathlessness. STOT – repeated exposure Reproductive Insufficient data available to classify as a reproductive toxin. Carcinogenicity Insufficient data available to classify as a carcinogen. This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1). However, there is sufficient information to conclude that the relative risk of lung cancer is increased in persons with silicosis. Therefore, preventing the onset of silicosis will also reduce the cancer risk. Mutagenicity Insufficient data available to classify as a mutagen. Ecotoxicity Information: The ecotoxicity of potassium silicate has not been tested. The following data is reported for chemically similar sodium silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance of water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm. Toxicity: The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similar Sodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour median tolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hour median tolerance for Amphipoda of 160 ppm.
0.15% 06/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Persistence and degradability: This material is not persistent in aquatic systems. Mobility in soil: Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable from natural dissolved silica. Bioaccumulative potential Neither silica nor potassium will appreciably bio-concentrate up the food chain.
12. Citric Acid Newpark pH buffer
Acute Toxicity: LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 290 mg/kg (rat) LD50 (Intravenous): 42 mg/kg (mouse) LDLo (Ingestion): 7000 mg/kg (rabbit) Ecotoxicity: LC50 (Leuciscus idus melanotus): 440 mg/L - 48 h LC 50 Daphnia magna (Water flea) - 1.535 mg/L - 24 h Biodegradation/Bioaccumulation: Readily Biodegradability. Does not bioaccumulate. If citric acid is released to water, it is expected to biodegrade rapidly. May be toxic to fish at moderately high levels (120 ppm is fatal to daphnia; 894 ppm with pH 4 is fatal to goldfish) due to acidic nature. Fairly high biological oxygen demand (BOD) which may cause oxygen depletion in large spills. Citric acid occurs naturally in many plants. OCNS category and registration number E - 24317
0.11% 05/02/2020
13. Idcide-20 Newpark
Biocide/Prevents bacterial contamination of the mud
Toxicity: Toxicity data available for ingredient: TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8) LD50 (ingestion) 248 mg/kg (rat) TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat) Ecotoxicity: 75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8): LC50 (Rainbow Trout) = 119 mg/L/96 hr LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr EC50 (Daphnia Magna) = 19 mg/L/48 hr LC50 (Brown Shrimp) = 340 mg/L/96 hr LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr LC50 (Sheepshead Minnow) = 94 mg/L/96 hr LC50 (Jevenile Plaice) = 86 mg/L/96 hr Wastewater management EC50 (Activated Sludge) = 24 mg/L/3 hr Persistence and degradability: This product is readily biodegradable. http://www.inchem.org/documents/ehc/ehc/ehc218.htm
0.11% 16/08/2019
14. Caustic Soda Newpark pH Control – prevents bacteria & corrosion
Toxicity Data: Toxicity Data available for the ingredients: SODIUM HYDROXIDE (1310-73-2): LD50 (Intraperitoneal): 40 mg/kg (mouse) LDLo (Ingestion): 1.57 mg/kg (human) SILICA, AMORPHOUS (7631-86-9): LD50 (ingestion): 3160 mg/kg (rat)
0.09% 05/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out. OCNS category and registration number E - 24316
15. AVADEFOAM NS Newpark Defaomer suitable for WBM
CONSTITUENT 1 (95%) Acute toxicity: Acute oral toxicity (LD50): 9380 mg/kg [Rat]. Ecological Information: Ecotoxicity in water (LC50): 100 mg/l 96 hours [Fish]. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.
0.08% 28/03/2019
CONSTITUENT 2 (5%) Acute toxicity: Dermal LD50 Albino rabbit - > 2000 mg/kg, 14 days At this dose no death occurred. LD50 Oral Albino Sprague-Dawley rat > 10000 mg/kg, 14 days At this dose no death occurred. Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Tall Oil Fatty Acids EC50 Bacteria (Pseudomonas putida) > 10000 mg/l, 16 hr Aquatic Algae EL50 > 1000 mg/l, 72 hr Growth rate; OECD 201 Green algae (Selenastrum capricornutum) Crustacea EL50 Water flea (Daphnia magna) > 1000 mg/l, 48 hr OECD 202 Fish LL50 Zebra danio (Danio rerio) > 10000 mg/l, 96 hr
Biodegradability: Percent degradation (Aerobic biodegradation) Tall Oil Fatty Acids 88 - 100 % CO2 Evolution Test Species: Activated sewage sludge Test Duration: 28 d Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915 Product Information: Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,010.00 mg/kg 95 % of the mixture consists of component(s) of unknown hazards to the aquatic environment. OCNS category and registration number Gold - 27915
16. Soda Ash Newpark pH / hardness control
Toxicity: LD50 (Ingestion): 4090 mg/kg (rat) LC50 (Inhalation): 800 mg/m3/2 hours (guinea pig) LD50 (Intraperitoneal): 117 mg/kg (mouse) LD50 (Subcutaneous): 2210 mg/kg (mouse) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11 (goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above.
0.07% 05/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
ATMOSPHERE: Not expected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out. OCNS category and registration number E - 26180
17. Sodium Bicarbonate Newpark
pH buffer, contamination treatment
Acute Toxicity: LD50 (Ingestion): 3360 mg/kg (mouse) LC50 (inhalation): 4.74 mg/L (rat) Ecotoxicity: Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l Ecotoxicity Data: LC50 (Oncorhynchus mykiss), 96 h, 7.700 mg/l LC50 (Lepomis macrochirus), 96 h, 7.100 mg/l EC50 (Crustaceans, Daphnia magna) 48 h, 4.100 mg/l LOEC (Crustaceans, Daphnia magna) 48 h, 3.100 mg/l Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. OCNS category and registration number E - 26175
0.05% 03/02/2020
100% 18. Barite / Newbar Newpark Weighting agent See above 5.29% 06/02/2020 19. Salt (Sodium
Chloride all grades)
Newpark Weighting agent Acute Toxicity: LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Skin): > 10000 mg/kg (rabbit) Ecotoxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
5.29% 10/03/2017
20. NDFT 376 & NDFT 377 (Dynafiber)
Newpark LCM / well bore strengthening
Acute toxicity: This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effects are not anticipated. Oral Toxicity (LD50) > 5000 mg/kg (rat) Dermal Toxicity (LD50) > 2000 mg/kg (rabbit)
1.59% 26/08/2019
21. Quickseal M/C Newpark LCM / well bore strengthening
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated Acute Toxicity: Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats). Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats). Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat). Low toxicity to aquatic organisms. This product is readily biodegradable. This product is not expected to bioaccumulate.
1.14% 03/02/2020
22. MEG Newpark Agent to free differentially stuck pipe
Toxicity Data: Toxicity data available for ingredient: ETHYLENE GLYCOL (107-21-1) LC50 (inhalation) 10 876 mg/kg (rat) LD50 (ingestion) 1650 mg/kg (cat) LD50 (skin) 9530 ug/kg (rabbit) LDLo (ingestion) 398 mg/kg (human) TCLo (inhalation) 10,000 mg/m³ (human - cough) TDLo (ingestion) 5500 mg/kg (child - anaesthesia)
0.85% 01/03/2019
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Ethylene glycol will mainly exist in the vapour phase in the ambient atmosphere where it will be degraded by reaction with hydroxyl radicals. Expected to be very highly mobile in soil. Not anticipated to volatilise from moist soil or water surfaces. Biodegradation in both soil and water is expected to be a major fate process for this compound. Not expected to bioconcentrate in aquatic organisms. Ecotoxicity LC50 (Aquatic species): >100mg/L/96hrs. Non-hazardous to aquatic organisms. Safework Australia Exposure Standards: http://hsis.ascc.gov.au/DocumentationES.aspx?ID=722 http://hsis.ascc.gov.au/DocumentationES.aspx?ID=271 CICADS Available: http://inchemsearch.ccohs.ca/inchem/jsp/search/search.jsp?inchemcasreg=1&Coll=inchemall&serverSpec=charlie.ccohs.ca%3A9900&QueryText1=107-21-1&QueryText2=&Search.x=52&Search.y=10
23. AvaGreenLube Newpark Lubricant LC50 (Fish) 48 h: > 10000 μg / L LC50 (Mollusc ) 48 h: > 10000 μg /L LC50 (Amphibious) 48 h: > 7600 μg/L Low potential for bío-accumulation in aquatic organisms or terrestrial even after repeated exposure.
0.42% 14/07/2017
24. AVAPERM NF Newpark Prevent swelling clays by blocking the site for water hydration
An equivalent product to AVAPERM NF has been registered on the CEFAS Offshore Chemical Notification Scheme with a ‘Gold’ rating & Registration # 24780 Skin corrosion/irritation: Not corrosive (B.40 Bis - Reg. 440/2008/EC). Skin contact: Harmful and irritant. Eye contact: Irritant. Inhalation: Irritant. Ingestion: Harmful. Acute oral toxicity on rats (LD50): > 500 < 1000 mg/kg.* (based on components)
0.42% 08/02/2018
Following information is confidential: Biodegradation Seawater test OECD 306 75% Bioaccumulation OECD 117 LogPow ≤ 1.36 EC 50 (Skeletonema costatum) 54.4 mg/l LC50 (Acartia tonsa) 52.4 mg/l LC50 (Scophthalmus maximus juvenile) >51.0 mg/l
25. Calcium Carbonate (including various grades) Circal 60/16, Circal Y, Circal 1000, Omyacarb 10, 20 & 40, Stonedust, Limestone LSC
Newpark Bridging agent & loss circulation material
See above 0.25% 24/02/2017
26. JK-161LV / JK-261 / JK-261HP
Newpark Encapsulating agent - provides shale inhibition
Toxicological Information: This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401). Ecological Information: (10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg]
0.21% 03/02/2020
27. Gagetrol Newpark HT Fluid Loss Additive
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.
0.19% 15/03/2017
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Low toxicity - low irritant. Under normal conditions of use, adverse health effects are not anticipated. OCNS category and registration number Gold - 27759
28. Strata-Vanguard Newpark Bridging agent Toxicity Data: Toxicity data available for ingredient: CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) POLYETHYLENE (9002-88-4) LDLo (ingestion) 3000 mg/kg (rat) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human)
0.19% 03/02/2020
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate. This product has low mobility in soil.
29. TEA Newpark Polymer stabiliser which effectively reduces the degradation of polymers at high temperatures
CONSTITUENT 1 (>60%) Oral Toxicity (LD50) 2200 mg/kg (rabbit) Dermal Toxicity (LD50) > 20 mL/kg (rabbit)
0.14% 09/06/2017
CONSTITUENT 2 (10 - 30%) Oral Toxicity (LD50) 620 uL/kg (rat), Dermal Toxicity (LD50) > 20 mL/kg (rabbit) CONSTITUENT 3 (<10%) Component is naturally occurring and not intrinsically hazardous. Environment In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil, residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
30. FlexFirm KA Newpark Inhibits dispersion of drilled shale cuttings
See above 0.13% 06/02/2020
31. Magnesium Oxide
Newpark pH buffer This product is expected to be of low toxicity. OCNS category and registration number E - 28127
0.13% 03/02/2020
32. Calcium Chloride (94% Powder)
Newpark Weighting Agent Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients: Acute Toxicity: CALCIUM CHLORIDE ANHYDROUS (10043-52-4) LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman) SODIUM CHLORIDE (7647-14-5) LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse)
0.11% 05/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate.
33. SAPP Newpark Deflocculate or disperse bentonite muds or fluids with high levels of low gravity solids
Acute Toxicity: Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation. Ingestion of large quantities may also result in serious disturbances in calcium metabolism. LD50 (Ingestion): 2650 mg/kg (mouse) LD50 (Intraperitoneal): 1 g/kg (mouse) LD50 (Intravenous): 59 mg/kg (mouse) LD50 (Subcutaneous): 480 mg/kg (mouse) Biodegradation/Bioaccumulation: Biodegradability does not pertain to inorganic substances. Does not bioaccumulate. OCNS category (actual or equivalent chemical) and Registration number. E-2449
0.11% 03/02/2020
34. Zinc Oxide Newpark H2S Scavenger Acute toxicity Information available for the product: This product is expected to be of low toxicity. LC50 (inhalation): 2500 mg/m³ (mouse) LD50 (intraperitoneal) 240 mg/kg (rat) LDLo (oral) 500 mg/kg (human) TCLo (inhalation) 600 mg/m³ (human) LD50 (oral): 7950 mg/kg (mouse) Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This product is not readily biodegradable
0.11% 03/02/2020
35. Driscal D Newpark (Drilling Specialties Company)
High temperature fluid loss control agent
LCLo (Inhalation): 300 ug/m3/10 years (human), LDLo (Intratracheal): 200 mg/kg (rat) LDLo (Intravenous): 20 mg/kg (dog), TCLo (Inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)
0.10% 20/09/2018
36. Frac Attack Newpark Prevents lost circulation
Toxicity Data: Toxicity data available for ingredient: CALCIUM HYDROXIDE (1305-62-0) LD50 (ingestion) 7300 mg/kg (mouse) CRISTOBALITE (14464-46-1) TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis) QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) CELLULOSE (9004-34-6) LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit) MAGNESIUM OXIDE (1309-48-4) TCLo (inhalation) 400 mg/kg (human)
0.08% 05/02/2020
The manufacturer reports that this product is harmful to aquatic life. 37. Defoam-AP400 Newpark Defaomer
suitable for high temperatures
Eye Low to moderate irritant. Contact may result in irritation, lacrimation, pain and redness. Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, with coughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapour pressure, an inhalation hazard is not anticipated with normal use. Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis. Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.
0.07% 03/02/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in
system fluid (mass %)
SDS Attached
Low toxicity - low irritant. This product has the potential to irritate mucous membranes. Use safe work practices to avoid eye or skin contact and inhalation. Chronic exposure to some glycols may result in liver and kidney damage. Health hazard summary 11.1 Information on toxicological effects Toxicity data POLYETHYLENE GLYCOL (25322-68-3) LD50 (ingestion) 33750 mg/kg (rat)
38. DSCO™ Defoam Newpark Defoamer Constituent 1 – (>60%) Oral Toxicity: An oral LD50 300 - 57000 mg/kg (range) This product is not expected to bioaccumulate
0.06% 08/06/2018
Constituent 2 – (remainder) No Hazard
39. Microflow Newpark Stimulation Additive
This product is not expected to bioaccumulate. 0.06% 29/01/2020 Constituent 1 – (20-60%) No Hazard Constituent 2 – (15-50%) Oral Toxicity: An oral LD50 in mice of 3600 mg/kg
40. TrueScav HD Newpark Oxygen scavenger (non-sulphur based)
Constituent 1 – (>99%) The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 5,005.00 mg/kg Oral LD50 > 5 g/kg ( Rat ) Unknown aquatic toxicity 100% of the mixture consists of component(s) of unknown hazards to the aquatic environment. Ecotoxicity: The environmental impact of this product has not been fully investigated. Persistence/Degradability: Possibly hazardous short-term degradation products are not likely; However, long term degradation products may arise.
0.03% 29/08/2018
16.95%
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
C. CHEMICAL LIST
Chemicals within products in Part B CAS # Maximum Mass
Fraction in System (%)
Water 7732-18-5 79.58% Barium Sulphate 7727-43-7 6.34% Potassium Chloride 7447-40-7 4.21% Calcium Carbonate 471-34-1 3.52% Sodium Chloride 7647-14-5 2.88% Bentonite 1302-78-9 1.09% Sodium carboxymethy Cellulose 9004-32-4 0.89% Xanthan Gum 11138-66-2 0.42% Quartz (Silica Crystalline) 14808-60-7 0.25% Sodium Sulphite 7757-83-7 0.22% Potassium Silicate 1312-76-1 0.15% Citric Acid, Anhydrous 77-92-9 0.11% Sodium Hydroxide 1310-73-2 0.09% Sodium Carbonate 497-19-8 0.08% Sodium Bicarbonate 144-55-8 0.05% Polyethylene Glycol 25322-68-3 0.04% OCTAN-2-OL 123-96-6 0.04% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) 55566-30-8 0.03% Sodium Sulphate 7757-82-6 0.01% 100% Water 7732-18-5 83.72% Sodium Chloride 7647-14-5 5.10% Barium Sulphate 7727-43-7 4.71% Cellulose 9004-34-6 2.24% Polyglycerol 25618-55-7 0.84% Methyl A-D-Glucopyranoside 97-30-3 0.84% Formic Acid 64-18-6 0.23% Hydrochloric acid 7647-01-0 0.21% Calcium Carbonate 1317-65-3 0.20% Carboxymethyl starch 9057-06-1 0.17% D-glucurono-6-deoxy-l-manno-d-glucan, Acetate, calcium magnesium potassium sodium Salt 595585-15-2 0.15% Sulphonated organic polymer 28210-41-5 0.15% Triethanolamine 102-71-6 0.14% Ethylene Glycol 107-21-1 0.13% Isopropyl Alcohol 67-63-0 0.11% Disodium Pyrophosphate 7758-16-9 0.11% Calcium Chloride 10043-52-4 0.10% Acrylamide, Sodium Acrylate Copolymer 25987-30-8 0.10% Cristobalite 14464-46-1 0.08% Zinc Oxide 1314-13-2 0.06% Methyl Oxirane Polymer 9003-11-6 0.06% Hexamethylenediamine 124-09-4 0.05% Polyethylene Glycol 25322-68-3 0.04% Octan-2-Ol 123-96-6 0.04% 2-Propenenitrile, polymer with 1,3-butadiene Rubber 9003-18-3 0.04% Calcium Oxide 1305-78-8 0.04% Methyl esters of fatty acids 68990-52-3 0.04% Natural Rubber 9006-04-6 0.03% Polyisoprene 9003-31-0 0.03% Rubber - SBR elastomers (derived from recycled automotive tyres) 9003-55-8 0.03% Organic fibres 9004-34-6 0.03% Calcium Hydroxide 1305-62-0 0.03% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) 55566-30-8 0.02% Diatomaceous Earth 68855-54-9 0.02% Magnesium oxide 1309-48-4 0.02% Dazomet (iso)[tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione] 533-74-4 0.02% Sweet Orange Oil 68647-72-3 0.02% Sodium Bicarbonate 144-55-8 0.01% Quartz (Silica Crystalline) 14808-60-7 0.01% Fuller's earth 8031-18-3 0.01% Tall Oil Fatty Acid 61790-12 0.01% Polyethylene 9002-88-4 0.01% 100%
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
A.2 Cementing Chemical Disclosure (Option A)
A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Cementing (Halliburton) TOTAL VOLUME OF SYSTEM (m3) 176 m3
B. PRODUCT LIST (OPTION A)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
1. Freshwater Onsite Water Bore Mix Water 48.511 N/A
2. Cement Class G Halliburton Cement
Constituent 1 (≤100%): After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Acute Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Static Acute Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Acute Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics
36.073 02/08/2018
Constituent 2 (≤10%): Carcinogenicity: Classified as a human carcinogen (IARC Group 1)
3. Silicalite Liquid Halliburton Light weight cement additive
Silicalite Liquid is OCNS Group: E
5.853 30/04/2020
Constituent 1 (≤60%): Water Constituent 2 (≤60%): "SiO2" is a stable substance. In the environment it occurs in different modifications and it is one of the most abundant materials on the Earth's surface. Biodegrability is "not applicable" for silica since it is inorganic. Additionally, "bioaccumulation is not expected." Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum); Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia); Acute Fish Toxicity 96h LC50 5000 mg/L (Brachydanio rerio); Source: IUCLID 2000 Constituent 3 (≤1%): LC50(96h): > 1000 mg/L (Brachydanio rerio) LC50(24h): >1000 mg/L (Daphnia magna) LC50(10d): 50566 mg/kg (Corophium)
4. Gascon 469 Halliburton Cement Additive Stabiliser
Gason 469 is OCNS Group E
3.831 30/04/2020
Constituent 1 (≤100%): Water Constituent 2 (≤60%): "SiO2" is a stable substance. In the environment it occurs in different modifications and it is one of the most abundant materials on the Earth's surface. Biodegrability is "not applicable" for silica since it is inorganic. Additionally, "bioaccumulation is not expected." Acute Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum); Acute Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia); Acute Fish Toxicity 96h LC50 5000 mg/L (Brachydanio rerio); Source: IUCLID 2000 PLONOR Constituent 3 (≤1%): The inorganic substance has a high water solubility and is not expected to bioconcentrate in organisms; "Biodegradation is not applicable." Algae toxicity (i.e. mortality) has been shown at pH >8.5. Concentration-based toxicity values were not available. Acute Fish Toxicity 96h LC50: 45.4 mg/L (Oncorhynchus mykiss); Source: IUCLID 2000 Included on the OSPAR List of Substances Used and Discharged Offshore which are considered to pose Little or No Risk to the Environment
5. Halad-413L Halliburton Fluid Loss Additive Acute Toxicity: Oral Toxicity LD50: > 5,000 mg/kg (Rat) 3.357 07/05/2018
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION A)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Dermal Toxicity LD50: > 2,000 mg/kg (Rabbit) Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated as an ingredient (10-30%) Algae Toxicity EC50 (72h): 1,102 mg/L (Skeletonema costatum) Crustacean Toxicity LC50 (48h): >2,000 mg/L (Acartia tonsa) Fish Toxicity LC50 (96h): >1,000 mg/L (Scophthalmus maximus) (juvenile turbot) Water makes up the remainder of this product. Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Slowly biodegradable. Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-terminated As an ingredient (10-30%) Log Pow: <0 (OECD 117) Biodegradation (28 Days): 6.1% (OECD 306)
6. SCR-100L Halliburton Cement Retarder
Acute Toxicity: Acrylic acid polymer with Sodium AMPS, sodium salt as an ingredient (60-100%): Algae EC50(72h): >3300mg/L (Skeletonema costatum) Crustacean LC50(48h): >2000mg/L (Acartia tonsa) Fish LC50(96h): >1000mg/L (Scophthalmus maximus juvenile) 2-Bromo-2- (bromomethyl) pentanedinitrile as an ingredient(<0.1%): LD50 Rat (male) oral 0.77 g/kg. FD&C Blue 1 as an ingredient (0.1%) Rat LD50 (oral) >5000 mg/kg. Water makes up the remainder of the product at percentages less than 100%. Biodegradation/bioaccumulation: Acrylic acid polymer with Sodium AMPS, sodium salt (60-100%) as an ingredient: Biodegradation (28 days): 39% (OECD306); CHARM Category: GOLD
0.671 28/01/2020
7. WellLife 734 Halliburton Cement Enhancer
Product is an inert, man-made substance and not intrinsically hazardous.
0.561 30/04/2020
Ecotoxicological Information: Acute Crustaceous Toxicity: TLM96: > 1,000,000 ppm (Mysidopsis bahia) Biodegradation: Readily Biodegradable (classified in the PLONOAR list) CHARM Category: GOLD
8. CFR-3L Halliburton Friction Reducer
CFR-3L is CFR-3 in solution
0.402 09/09/2020
Acute Toxicity : Retarder Algae Toxicity EC50 (72h): >100 mg/L (Skeletonema costatum) [Halliburton Funded Study] Fish Toxicity LC50 (48h): 7478 mg/L (Aphyosemion bivittatum) [SKW Trostberg] Crustacean Toxicity LC50 (48h): 1687 mg/L (Acartia tonsa) [Halliburton Funded Study] Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Slowly biodegradable Bioaccumulation Log Pow: < 0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study]; CHARM Category - GOLD
9. HR-25L Halliburton Cement Retarder
Acute Toxicity: Algae: EC50(72h): 791.25 mg/L (Skeletonema costatum) Crustacean: LC50(48h): 3753.85 mg/L (Acartia tonsa) Fish: LC50(96h): 250 mg/L (Scophthalmus maximus juvenile) Biodegradation/bioaccumulation: Log Pow: 0 - 4.7 (OECD 117) Biodegradation(28 Days): 77% (OECD 306) CHARM Category: GOLD
0.336 01/02/2021
10. Econolite Liquid Halliburton Cement Additive Stabiliser
Constituent 1 (≤100%): Water
0.191 03/12/2020 Constituent 2 (≤60%):
Crustracean Toxicity 100h EC50: 247 mg/L (Daphnia magna); Acute Fish Toxicity 96h LC50: 301-478 mg/L (Lepomis macrochirus);
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION A)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
LD50:2000-3000 mg/kg (Rat) Component is an inorganic substance with "No bioaccumulation potential"; "studies on biodegradation are not applicable." Source: IUCLID 2000 PLONOR Bioassay testing where LC50/ EC50: >100mg/L Readily biodegradable
11. Barite Newpark Weighting Agent See above 0.125 06/02/2020
12. NF-6 Halliburton Reduces air entrainment into cement slurry
Acute Toxicity: Not determined for Fish, Crustaceans and Algae as a complete mix.
0.072 11/02/2021
Acute Toxicity: Rape oil as an ingredient (60-100%) Oral Toxicity LD50: >5,000 mg/kg (Rat) Dermal Toxicity LD50: >5,000 mg/kg (Rabbit) Fish Toxicity LC50: >5,600 mg/L Algae Toxicity EC50: >3,200 mg/L Acute Toxicity: Monopropylene glycol monooleate as an ingredient (5-10%) Fish Toxicity LC50: 3,200 mg/L Algae Toxicity EC50: 990 mg/L Acute Toxicity: Sorbitan, monopalmitate as an ingredient (1-5%) Fish Toxicity LC50: >,1800 mg/L Algae Toxicity EC50: 41 mg/L Acute Toxicity: Aluminium stearate as an ingredient (1-5%) Fish Toxicity LC50: >5,600 mg/L EC50: 6,500 mg/L Water makes up the remainder of this product. Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Biodegradation/bioaccumulation: Readily biodegradable. Low bioaccumulation potential due to rapid degradation.
13. Tuned Spacer E+ Halliburton Mud / Cement Spacer
Acute Toxicity: Bentonite as an ingredient (60-100%) Oral Toxicity LD50: 5,000 mg/kg (Rat) Fish Toxicity (Marine) 96h LC50: 8-19 g/L (Salmo gairdneri) Fish Toxicity TLM96: 10,000 ppm (Oncorhynchus mykiss)
0.016 08/01/2019
Acute Toxicity: Crystalline silica, quartz as an ingredient (1-5%) Oral Toxicity LD50: 500 mg/kg (Rat) Fish Toxicity LC50: >10,000 mg/l Algae Toxicity EC50: >5,000 mg/l Acute Toxicity: Crystalline silica, cristobalite as an ingredient (0-1%) As for Crystalline silica, quartz. Acute Toxicity: Crystalline silica, tridymite as an ingredient (0-1%) As for Crystalline silica, quartz. Acute Toxicity: Sodium Lignosulfonate as an ingredient (10-30%) Oral Toxicity LD50 Rat: >6,000 mg/kg Acute Toxicity: Welan gum as an ingredient (5-10%) Fish Toxicity LC50: >750 mg/l Algae Toxicity EC50: 1240 mg/l
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION A)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Chronic Toxicity: Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes- fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis. Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline Yes silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Biodegradation/bioaccumulation: Silica is a naturally occurring, insoluble component of soil. Biodegradation is "not applicable" for crystalline silica since it is inorganic. Concentration-based toxicity values were not available.
100%
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
C. CEMENTING CHEMICAL LIST (OPTION A)
Chemicals within products in Part B
CAS # Maximum Mass Fraction in System (%)
Water 732-18-5 48.5120 Portland Cement 65997-15-1 20.8703 Water in Product 732-18-5 11.4850 Crystalline silica, quartz 14808-60-7 11.13258 Silica, amorphous 7732-18-5 4.27905 Silica, amorphous – fumed 7631-86-9 1.41988 Humic acids, sodium salts, polymers with N,N-dimethyl-2-propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfiteterminated
473268-27-8 0.80556
Glass, oxide 7440-44-0 0.46427 Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.34665 Sulfurous acid, monosodium salt, polymer with formaldehyde and acetone 40104-76-5 0.22253 Tartaric acid 7732-18-5 0.16515 Barite 13462-86-7 0.09168 Sodium silicate 1344-09-8 0.08395 Rape oil 8002-13-9 0.06062 Sodium hydroxide 1310-73-2 0.03156 Bentonite 1302-78-9 0.01140 Monopropylene glycol monooleate 1330-80-9 0.00576 Sodium lignosulfonate 8061-51-6 0.00342 Sorbitan, monopalmitate 26266-57-9 0.00286 Aluminium steareate 637-12-7 0.00286 Welan gum 72121-88-1 0.00114 FD&C Blue 1 1330-80-9 0.00061 2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.00061 Crystalline silica, tridymite 15468-32-3 0.00011 Crystalline silica, cristobalite 14464-46-1 0.00011
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
F.2 Cementing Chemical Disclosure (Option B)
A. SYSTEM DETAILS OPERATOR: RCMA Australia Pty Ltd PROJECT / WELL: Cervantes 1 SYSTEM: Cementing (Schlumberger) TOTAL VOLUME OF SYSTEM (m3) 176 m3
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
1. Freshwater Mix Water 36.472% N
2. D901 Schlumberger Cement
Constituents: PORTLAND CEMENT Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical.
26.66% 08/06/2021
3. D907 Schlumberger Cement
Constituents: PORTLAND CEMENT CLINKER The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be mutagens, or carcinogens. Can be come skin sensitizing if stored improperly. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical
15.692% 01/08/2018
4. D066 Schlumberger Silica
Constituents: QUARTZ (CRYSTALLINE SILICA) Toxicity: Acute toxicity: Quartz, Crystalline Silica: LD50 Oral (Rat): = 500 mg/kg Chronic toxicity: Product contains no components known to be sensitizing or mutagens. Crystalline silica dust is listed by IARC as Group 1 carcinogen. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. This product is not considered toxic to algae, fish, or invertebrates Biodegradation/Bioaccumulation: Not applicable – Inorganic chemical.
5.492% 02/03/2020
5. B421 Schlumberger Slag Cement Acute Toxicity: None. Chronic Toxicity: Product contains no components known to be sensitizing or mutagens. Crystalline silica dust is listed by IARC as Group 1 carcinogen. Product does not contain any known or suspected reproductive or developmental hazards.
5.492% 15/05/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulaiton: Not applicable, inorganic chemical
6. D031 Newpark Weighting Agent
Constituents: BARIUM SULPHATE QUARTZ (CRYSTALLINE SILICA) Toxicity: Low toxicity. Under normal conditions of use, adverse health effects are not anticipated. QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) Aquatic toxicity: Fish Toxicity LC50 (Rainbow trout) > 7500 ppm/96hrs. LC50 (Fresh Water Trout) > 21,000 ppm/96hrs. LC50 (Salt Water StickleBack) > 56,000 ppm/96hrs. Biodegradation/bioaccumulation: Barium sulphate (major ingredient of barite (60-100%) is insoluble in water and not biodegradable. Not expected to bioaccumulate. This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. OCNS Rated E - 24310, Exp 09/08/2021
3.376% 29/08/2018
7. D020 Newpark Extender
Constituents: BENTONITE QUARTZ (CRYSTALLINE SILICA) SODA ASH Toxicity: The main component/s of this product are not anticipated to cause any adverse effects to plants or animals. QUARTZ (SILICA CRYSTALLINE) (14808-60-7) LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis) BENTONITE (1302-78-9) LD50 (intravenous) 35 mg/kg (rat) LD50 (oral): >2000mg/kg (rat) LDLo (intravenous) 10 mg/kg (dog) Inhalation LC 50: >5.27 mg/L, 4hr (rat) Ecotoxicity Data: Bentonite (1302-78-9) EC50 Daphnia > 100 mg/l, 48 hours EC50 Freshwater algae > 100 mg/l, 72 hours LC50 Freshwater fish 16000 mg/l, 96 hours LC 50 Marine water fish 2800 - 3200 mg/l, 24 hours EC50 Coon stripe shrimp (Pandalus danae) 24.8 mg/l, 96 hours EC 50 Dungeness or edible crab (Cancer magister) 81.6 mg/l, 96 hours LC50 Rainbow trout, donaldson trout (Oncorhynchus mykiss) 19000 mg/l, 96 hours Persistence and degradability: Not relevant for inorganic substances Mobility: Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids. Bioaccumulation: Will not bio-accumulate. Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. OCNS Rated E - 26210 Exp 01/02/2021
2.280% 11/10/2018
8. D600G Schlumberger Gas Control Agent Constituents: DODECYL SULFATE, SODIUM SALT 1.574% 26/04/2021
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
1,4-DIOXANE The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity : 1,4-Dioxane (Impurity) LD50 Oral (Rat): > 4200 mg/kg Ld50 Dermal (Rabbit): >7600mg/kg LC50 Inhalation (Rat): > 46 mg/L (2h) Chronic Toxicity: May cause allergic reactions in very susceptible persons. Contains a known or suspected carcinogen. Is not known to have reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: 1,4-Dioxane (impurity) Toxicity to Fish: LC50 (Pimpehales promelas): = 9850 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 163 mg/L (48 h) Biodegradation/Bioaccumulation: Not readily biodegradable. Does not bioaccumulate.
9. D110 Schlumberger Cement Retarder
Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product is biodegradable, does not bioaccumulate.
0.553% 06/06/2018
10. S001 Schlumberger Accelerator
Acute Toxicity: Calcium Chloride LD50 Oral (Rat): > 1000 mg/kg LD50 Dermal (Rabbit): >5000mg/kg Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae. Toxicity to Fish: LC50(Lepomis macrochirus): = 10,650 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 2,400 mg/L (48 h) Contains no substance considered to be bioaccumulating or toxic.
0.553% 09/10/2018
11. D161 Schlumberger Retarder
Constituents: SODIUM PENTABORATE This product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: Sodium Pentaborate Ld50 Dermal: >2 g/kg LC50 Inhalation: > 2.03 mg/L Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product is or contains a chemical which is a known or suspected reproductive hazard. Not known to cause birth defects or have a deleterious effect on a foetus. Ecotoxicity: Sodium Pentaborate: Toxicity to Fish: LC50: = 600 mg/L (96 h) Toxicity to Invertebrates: EC50= 86 mg/L (48 h)
0.460% 15/03/2021
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Biodegradation/Bioaccumulation: The organic portion of this material is not biodegradable. Contains no substance considered to be bioaccumulating or toxic.
12. D080 Schlumberger Dispersant
Constituents: SODIUM POLYNAPHTALENE SULFONATE Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: Toxic to aquatic life with long lasting effects. Sodium polynaphthalene sulfonate: EC50 (48 hours) 1.8 mg/l Product is not considered toxic to fish or invertebrates. Biodegradation/Bioaccumulation: Product is not biodegradable. Bioaccumulation is unlikely.
0.343% 10/02/2021
13. D186 Schlumberger Accelerator
Acute Toxicity: 2,2’-oxydiethanol (Impurity) LD50 Oral (Rat): > 12,565 mg/kg LD50 Dermal (Rabbit): >11890 mg/kg LC50 Inhalation (Rat): > 4600 mg/m3 (4h) Acute Toxicity: Calcium Bromide (Impurity) LD50 Oral (Rat): > 4,100 mg/kg Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. The product component(s) are not classified as environmentally hazardous. The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms. Toxicity to Fish: LC50(Pimpehales promelas): = 75,200 mg/L (96 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 84,000 mg/L (48 h)
0.343% 23/08/2019
14. D182 Schlumberger Spacer
Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Not classified as PBY/vPvB by current EU criteria. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Bioaccumulation is unlikely.
0.125% 06/07/2020
15. D256 Schlumberger Mid-Range liquid FLAC D256
Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. No classified hazards. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Not readily biodegradable, bioaccumulation is unlikely.
0.092% 11/09/2019
16. D255 Schlumberger Mid-Range FLAC D255
Constituents: 2-METHYLPROPAN-2-OL The product contains other ingredients which do not contribute to the overall classification. Suspended dust may present a dust explosion hazard. Toxicity: Acute toxicity :
0.084% 11/07/2019
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
2-methylpropan-2-ol LD50 Oral (Rat): > 2200 mg/kg Ld50 Dermal (Rabbit): >2 g/kg LC50 Inhalation (Rat): > 10000 ppm, (4h) Chronic Toxicity: No known sensitizing, carcinogenic, reproductive, or mutagenic effects. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: 2-methylpropan-2-ol Toxicity to Fish: LC50 (Pimpehales promelas): = 6130-6700 mg/L (96 h) Toxicity to Algae: EC50 (Desmodesmus subspicatus): >1000 mg/L (120 h) Toxicity to Invertebrates: EC50 (Daphnia magna) = 4607-6577 mg/L (48 h) Biodegradation/Bioaccumulation: Not readily biodegradable. Does not bioaccumulate.
17. D168 Schlumberger Fluid Loss Additive
Constituents: Not applicable – no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product is biodegradable, does not bioaccumulate.
0.076% 23/03/2018
18. D065 Schlumberger Dispersant
Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Product not readily biodegradable. Bioaccumulation is unlikely. The product is water soluble, and may spread in water systems
0.056% 08/06/2021
19. D075 Schlumberger Extender
Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.
0.053% 19/09/2018
20. D194 Schlumberger Retarder
Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None.
0.053% 12/02/2019
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.
21. D047 Schlumberger AntiFoam Agent
Constituents: Not applicable - No classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC, Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Readily biodegradable, bioaccumulation is unlikely.
0.052% 03/03/2021
22. D095 Schlumberger Lost Circulation Material
Acute Toxicity: None. Chronic toxicity Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Not readily biodegradeable, bioaccumulation is unlikely.
0.052% 30/05/2018
23. D081 Schlumberger Retarder
Constituents: Not applicable – this product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits. Classified as Non-Hazardous according to the criteria of NOHSC. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Does not bioaccumulate
0.031% 12/05/2020
24. D175A Schlumberger AntiFoam Agent
Constituents (mixtures): NON-CRYSTALLINE SILICA The product has no classified ingredients, or those having occupational exposure limits, present above the level of disclosure. The product contains other ingredients which do not contribute to the overall classification. Toxicity: Acute toxicity: None. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, fish, or invertebrates. Biodegradation/Bioaccumulation: Contains no substance considered to be bioaccumulating or toxic.
0.031% 29/04/2020
25. D013 Schlumberger Retarder D013 Constituents: Not applicable. No classified ingredients, or those having occupational exposure limits, present above the level of disclosure. Classified as Non-Hazardous according to the criteria of NOHSC.
0.004% 15/01/2020
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
B. PRODUCT LIST (OPTION B)
# Trade Name Supplier Purpose Toxicity & Ecotoxicity Info Product in system fluid (mass %)
SDS Attached
Toxicity: Acute toxicity: aromatic polymer sulfonated derivative: LD50 oral (Rat) >40g/kg. Chronic toxicity: Product contains no components known to be sensitizing, mutagens, or carcinogens. Product does not contain any known or suspected reproductive or developmental hazards. Ecotoxicity: The product component(s) are not classified as environmentally hazardous. Product not considered toxic to algae, or invertebrates. Toxicity to Fish: LC50: aromatic polymer sulfonated derivative = 7300 mg/L Biodegradation/Bioaccumulation: No product level data available. The product is water soluble, and may spread in water systems.
100%
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
C. CEMENTING CHEMICAL LIST (OPTION B) Chemicals within products in Part B CAS number Max Mass fraction
in System (%) Portland cement 65997-15-1 ~ 66 Water (Including Mix Water Supplied by Client)* - ~ 12 Crystalline silica (impurity) 14808-60-7 ~ 9 Blast furnace slag 65996-69-2 ~ 5 Barium sulfate 7727-43-7 ~ 5 Bentonite 1302-78-9 ~ 3 Styrene butadiene copolymer 9003-55-8 ~ 1 Sulfuric acid, calcium salt 7778-18-9 ~ 1 Sodium polynaphthalene sulfonate 9008-63-3 < 1 Calcium glucoheptonate 17140-60-2 < 1 Polypropylene glycol 25322-69-4 < 1 Sulfurous acid, monosodium salt, polymer 40104-76-5 < 1 2-Propenoic acid, ammonium salt, polymer with 2- methyl-2-[(1-oxo-2-propeny)amino]-1-propanesulfonic acide moniammonium salt and 2-propenamide
99716-31-1 < 1
Sodium lignosulfonate 8061-51-6 < 1 Propane-1,2-diol 57-55-6 < 0.1 Polysaccharide biopolymer 72121-88-1 < 0.1 Sodium pentaborate 12007-92-0 < 0.1 Sodium chloride (impurity) 7647-14-5 < 0.1 C12-15 alcohol ethyoxylated 68131-39-5 < 0.1 Calcium lignosulfonate 8061-52-7 < 0.1 Silicic acid, sodium salt 1344-09-8 < 0.1 Alkyl glyceryl ether sulfonate 246867-88-9 < 0.1 2-Propenoic acid, polymer with 2-methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid and 2-propenamide, ammonium salt.
1857271-55-6 < 0.1
Sodium sulfate 7757-82-6 < 0.1 Dimethyl siloxanes and silicones 63148-62-9 < 0.1 Vinylamide/vinylsulfonated polymer 110897-64-8 < 0.1 Calcium Nitrate 10124-37-5 < 0.1 Pentasodium EDTMP 7651-99-2 < 0.01 2-methylpropan-2-ol 75-65-0 < 0.01 Sodium gluconate 527-07-1 < 0.01 Sorbitan stearate 1338-41-6 < 0.01 Tartaric Acid 87-69-4 < 0.01 Calcium chloride 10043-52-4 < 0.01 Sodium dodecyl sulphate 151-21-3 < 0.01 1,4-Dioxane (Impurity) 123-91-1 < 0.01 Sodium hydroxide 1310-73-2 < 0.01 Polyoxyethylene (40) stearic acid (monoester) 9004-99-3 < 0.01 Silicon Dioxide 7631-86-9 < 0.01 2-bromo-2-nitropropane-1,3-diol 52-51-7 < 0.001 Phosphonic acid (impurity) 13598-36-2 < 0.001 Phosphoric acid (impurity) 7664-38-2 < 0.001 2-Propenamid (impurity) 79-06-1 < 0.001 3,3'-methylenebis[5-methyloxazolidine] 66204-44-2 < 0.001 2,2' -oxydiethanol 111-46-6 < 0.001 Calcium Bromide 7789-41-5 < 0.001 2,2'-Methyliminodiethanol 105-59-9 < 0.001 Sorbic acid 110-44-1 < 0.0001
RCMA-02-EM-PLN-001SUMv5 APPENDIX A
C. CEMENTING CHEMICAL LIST (OPTION B) Chemicals within products in Part B CAS number Max Mass fraction
in System (%) 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
55965-84-9 < 0.0001
Total ~100.00%
RCMA-02-EM-PLN-001SUMv4 APPENDIX B
Safety Data Sheets
AVADEFOAM NS
EN
SAFETY DATA SHEET
Issue Date 18-Apr-2017 Revision Date 28-Mar-2019 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY1
Product identifier
Product Name AVADEFOAM NS
Product Code NDF00251
Other means of identification
Pure substance/mixture Mixture
Recommended use of the chemical and restrictions on use
Recommended Use Defoamer
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number +(61)-290372994 (Australia); +(64)-98010034 (New Zealand)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
_____________________________________________________________________________________________
UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Other hazards General HazardsNo information available
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Not applicable
Mixture
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing media Water. Carbon dioxide (CO2).
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Chemical name CAS No Weight-%Non-hazardous ingredients Proprietary
_____________________________________________________________________________________________
UGHS Page 2 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Wash thoroughlyafter handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials None known
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
_____________________________________________________________________________________________
UGHS Page 3 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Liquid
Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density 0.95-0.97 g/cm3Bulk density No information availableParticle Size No information availableParticle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity No information available.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Appearance liquid Odor Slight.Color clear Odor threshold No information available
Property Values Remarks • Method pH No data availableMelting point / freezing point No data availableBoiling point / boiling range No data availableFlash point > 100 °CEvaporation rate No data availableFlammability (solid, gas) Not applicableFlammability Limit in Air No information available
Upper flammability limit: No data availableLower flammability limit: No data available
Vapor pressure No data availableVapor density No data availableRelative density 0.95-0.97Water solubility Insoluble in waterSolubility(ies) No data availablePartition coefficient No data availableAutoignition temperature No data availableDecomposition temperature No data availableKinematic viscosity No data availableDynamic viscosity No data available
_____________________________________________________________________________________________
UGHS Page 4 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials None known.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 10,010.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity95 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
_____________________________________________________________________________________________
UGHS Page 5 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 95 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
_____________________________________________________________________________________________
UGHS Page 6 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS Does not complyIECSC CompliesKECL CompliesPICCS Does not complyAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 18-Apr-2017
Revision Date 28-Mar-2019
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Disclaimer
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
_____________________________________________________________________________________________
UGHS Page 7 / 8
_____________________________________________________________________________________________NDF00251 AVADEFOAM NS Revision Date 28-Mar-2019
This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
_____________________________________________________________________________________________
UGHS Page 8 / 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
AVA GREEN LUBE ● GREEN LUBESynonym(s)
DRILLING FLUID ● LUBRICANTUse(s)1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
AVAGREEN LUBEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%68990-52-3 273-606-8METHYL ESTERS OF FATTY ACIDS
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 14 Jul 2017
Version No: 1ofPage 1 6
AVAGREEN LUBEPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
SDS Date: 14 Jul 2017
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AVAGREEN LUBEPRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesYELLOW LIQUIDAppearanceSWEET VEGETABLE ODOUROdourCLASS C2 COMBUSTIBLEFlammability180°CFlash point> 300°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.91 to 0.92Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient260°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsAcute toxicity
11.1 Information on toxicological effects
SDS Date: 14 Jul 2017
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AVAGREEN LUBEPRODUCT NAME
are not anticipated.
Not classified as a skin irritant. Contact may cause temporary mild skin irritation.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
LC50 (Fish) 48 h: > 10000 μg / LLC50 (Mollusc ) 48 h: > 10000 μg /LLC50 (Amphibious) 48 h: > 7600 μg/L
12.2 Persistence and degradability70% 28 days (method OECD 301 B
12.4 Mobility in soil
It is not volatile and not expected to persist in the environment.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialLow potential for bioaccumulation.
13. DISPOSAL CONSIDERATIONS
For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
SDS Date: 14 Jul 2017
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AVAGREEN LUBEPRODUCT NAME
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
None allocated.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
None allocated.Safety phrases
None allocated.Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 14 Jul 2017
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AVAGREEN LUBEPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Prepared by
[ End of SDS ]
SDS Date: 14 Jul 2017
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AVAPERM NF
EN
SAFETY DATA SHEET
Issue Date 29-Jul-2016 Revision Date 08-Feb-2018 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name AVAPERM NF
Product Code NDF00185
Other means of identification
Pure substance/mixture Mixture
Recommended use of the chemical and restrictions on use
Recommended Use shale inhibitor
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Acute toxicity - Oral Category 4 - (H302)Acute toxicity - Dermal Category 4 - (H312)Skin corrosion/irritation Category 2 - (H315)Serious eye damage/eye irritation Category 1 - (H318)Skin sensitization Category 1B - (H317)Specific target organ toxicity (single exposure) Category 3 - (H335)
Label elements
_____________________________________________________________________________________________
UGHS Page 1 / 9
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
Signal wordDanger
Hazard statementsH302 - Harmful if swallowedH312 - Harmful in contact with skinH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation
Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productWear protective gloves/protective clothing/eye protection/face protectionAvoid breathing dust/fume/gas/mist/vapors/sprayContaminated work clothing should not be allowed out of the workplaceUse only outdoors or in a well-ventilated areaIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingImmediately call a POISON CENTER or doctor/physicianIF ON SKIN: Wash with plenty of soap and waterCall a POISON CENTER or doctor/physician if you feel unwellTake off contaminated clothing and wash before reuseIf skin irritation or rash occurs: Get medical advice/attentionIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingCall a POISON CENTER or doctor/physician if you feel unwellIF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellRinse mouthPrecautionary Statements - StorageStore in a well-ventilated place. Keep container tightly closedStore locked upPrecautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant
Other hazards May be harmful in contact with skinGeneral HazardsNo information available
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Not applicable
Mixture
Chemical Name CAS No Weight-%Hexanedinitrile, hydrogenated, high-boiling fraction 68411-90-5 30-50Hydrochloric acid 7647-01-0 <15Non-hazardous ingredients Proprietary
_____________________________________________________________________________________________
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Balance
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. If skin irritation or rash occurs: Get medical advice/attention.
Ingestion Do not induce vomiting without medical advice. Get medical attention if symptoms occur.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing mediaDry chemical, CO2, water spray or alcohol-resistant foam.
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
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_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Wash contaminated clothing before reuse. Handle in accordance with good industrialhygiene and safety practice. Wash thoroughly after handling.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Strong oxidizing agents Aldehydes Halogens Acids Ketone Nitrates Halogenatedcompounds Phenols Isocyanates
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits .
Chemical Name AustraliaHydrochloric acid
7647-01-05 ppm Peak
7.5 mg/m3 Peak
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Hand protection Wear suitable gloves tested to EN 374.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
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Section 9: PHYSICAL AND CHEMICAL PROPERTIES
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
Information on basic physical and chemical properties Physical state Liquid
Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableDensity 1.00-1.10 g/cm3Bulk density No information availableParticle Size No information availableParticle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity Stable under normal conditions.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Incompatible materials
Appearance liquid Odor Pungent.Color brown Odor threshold No information available
Property Values Remarks • Method pH 9 - 10Melting point / freezing point No information availableBoiling point / boiling range 100 °CFlash point > 100 °CEvaporation rate No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air Not applicable
Upper flammability limit: Not applicableLower flammability limit: Not applicable
Vapor pressure No data availableVapor density No data availableRelative density 1.00-1.10Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosityDynamic viscosity
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_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
Incompatible materials Strong oxidizing agents. Aldehydes. Halogens. Acids. Ketone. Nitrates. Halogenatedcompounds. Phenols. Isocyanates.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 768.00 mg/kgATEmix (dermal) 2,985.00 mg/kgATEmix (inhalation-gas) 2,859.84 ppmATEmix (inhalation-dust/mist) 2.54 mg/l
Unknown acute toxicity 47 % of the mixture consists of ingredient(s) of unknown toxicity0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity0 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity34 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)47 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)34 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Hexanedinitrile, hydrogenated,
high-boiling fraction= 1500 mg/kg ( Rat ) > 200 mg/kg ( Rabbit ) -
Hydrochloric acid 238 - 277 mg/kg ( Rat ) > 5010 mg/kg ( Rabbit ) = 1.68 mg/L ( Rat ) 1 hSee section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Irritating to skin.
Serious eye damage/eye irritation Risk of serious damage to eyes.
Respiratory or skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity None known.
Carcinogenicity None known.
Reproductive toxicity None known._____________________________________________________________________________________________
UGHS Page 6 / 9
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
STOT - single exposure Target Organs. Respiratory system.
STOT - repeated exposure None known.
Aspiration hazard None known.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 34 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Chemical Name Algae/aquatic plants Fish Toxicity tomicroorganisms
Crustacea
Hydrochloric acid - 282: 96 h Gambusiaaffinis mg/L LC50 static
- -
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
_____________________________________________________________________________________________
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Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
No information available
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS Does not complyIECSC CompliesKECL Does not complyPICCS Does not complyAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 29-Jul-2016
Revision Date 08-Feb-2018
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
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Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
_____________________________________________________________________________________________NDF00185 AVAPERM NF Revision Date 08-Feb-2018
DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
_____________________________________________________________________________________________
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AVAPOLYMER 5050
EN
SAFETY DATA SHEET
Issue Date 12-Apr-2017 Revision Date 02-Aug-2017 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name AVAPOLYMER 5050
Product Code NDF00252
Other means of identification
Pure substance/mixture Mixture
Recommended use of the chemical and restrictions on use
Recommended Use shale stabilizer
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Other hazards
_____________________________________________________________________________________________
UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
May be harmful in contact with skinGeneral HazardsNo information available
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Not applicable
Mixture
Additional informationThe product contains no substances which at their given concentration, are considered to be hazardous to health
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing mediaWater spray (fog). Carbon dioxide (CO2).
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
_____________________________________________________________________________________________
UGHS Page 2 / 8
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials None known
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
_____________________________________________________________________________________________
UGHS Page 3 / 8
Individual protection measures, such as personal protective equipment
_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Solid
Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableDensity No information availableBulk density No information availableParticle Size No information availableParticle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity Stable.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Appearance powder Odor Slight.Color No information available Odor threshold No information available
Property Values Remarks • Method pH 8.0 - 11.0 20 g/L solutionMelting point / freezing point No data availableBoiling point / boiling range No data availableFlash point Not applicableEvaporation rate No data availableFlammability (solid, gas) No data availableFlammability Limit in Air No data available
Upper flammability limit: No data availableLower flammability limit: No data available
Vapor pressure No data availableVapor density No data availableRelative density No data availableWater solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No data availableDecomposition temperature No data availableKinematic viscosity Not applicableDynamic viscosity Not applicable
_____________________________________________________________________________________________
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_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials None known.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 27,000.00 mg/kgATEmix (dermal) 2,002.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity40 % of the mixture consists of ingredient(s) of unknown acute oral toxicity40 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not regulated
IATA Not regulated
IMDG Not regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________NDF00252 AVAPOLYMER 5050 Revision Date 02-Aug-2017
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
Ozone-depleting substances (ODS) Not applicable
Persistent Organic Pollutants Not applicable
Export Notification requirements Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 12-Apr-2017
Revision Date 02-Aug-2017
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONTWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
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DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
_____________________________________________________________________________________________
UGHS Page 8 / 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
BARITE (API 13A SECTION 7) ● NEWBAR ● RHEOBARSynonyms
DRILLING FLUID ADDITIVE ● WEIGHTING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
BARITE POWDERProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol. 68,1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite from occupationalsources causes cancer in humans. IARC Classification Group I.
2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>89%7727-43-7 231-784-4BARIUM SULPHATE
<3%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities should be available.First aid facilities
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Revision No: 3.3ofPage 1 6
BARITE POWDERPRODUCT NAME
Repeated exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
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BARITE POWDERPRODUCT NAME
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Barium sulphate SWA [AUS] -- 10 -- --
Barium sulphate (inhalable) SWA [Proposed] -- 4 -- --
Barium sulphate (respirable) SWA [Proposed] -- 1.35 -- --
Quartz (respirable dust) SWA [AUS] -- 0.1 -- --Quartz (respirable dust) SWA [Proposed] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesOFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling point> 1300°CMelting pointNOT RELEVANTEvaporation rate8.2 (20% Slurry)pHNOT RELEVANTVapour density4.20Specific gravityINSOLUBLESolubility (water)NOT RELEVANTVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT RELEVANTPartition coefficientNOT RELEVANTAutoignition temperatureNOT RELEVANTDecomposition temperatureNOT RELEVANTViscosityNOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT RELEVANTOdour threshold
9.2 Other information~1.5 kg/LBulk density
10. STABILITY AND REACTIVITY
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BARITE POWDERPRODUCT NAME
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), alkalis (e.g. sodium hydroxide), heat and ignitionsources.
May evolve toxic gases (sulphur oxides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Based on available data, the classification criteria are not met.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rat) --BARIUM SULPHATE
Contact may result in irritation, redness, pain and rash.Skin
Contact may result in irritation, lacrimation, pain, redness and blurring or dimness of vision.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Over exposure may result in irritation of the nose and throat, coughing, dizziness, drowsiness and headache.STOT - singleexposure
Not classified as causing aspiration.Aspiration
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused by deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is a body ofevidence supporting the fact that increased cancer risk would be limited to people already suffering fromsilicosis.
Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Fish Toxicity: LC50 (Rainbow trout) > 7500 ppm/96hrs; LC50 (Fresh Water Trout) > 21,000 ppm/96hrs; LC50 (Salt Water StickelBack) > 56,000 ppm/96hrs.
12.2 Persistence and degradabilityBarium sulphate (major ingredient of barite (60-100%)) is insoluble in water and not biodegradable.
12.4 Mobility in soil
No information provided.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
SDS Date: 06 Feb 2020
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BARITE POWDERPRODUCT NAME
13. DISPOSAL CONSIDERATIONS
Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 06 Feb 2020
Revision No: 3.3ofPage 5 6
BARITE POWDERPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 06 Feb 2020
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1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
AVAGEL ● BENTONIL HR ● HISWELL ● MAXIGEL ● NATURALGEL ● NEWGEL ● RHEOBEN ● RHEOBENNT ● SODIUM BENTONITE ● SODIUM MONTMORILLONITE
Synonyms
DRILLING FLUIDUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
BENTONITE POWDERProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Storage statementsNone allocated.
Get medical advice/attention if you feel unwell.P314Response statements
Do not breathe dust/fume/gas/mist/vapours/spray.P260Prevention statements
May cause damage to organs through prolonged or repeated exposure.H373Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Specific Target Organ Toxicity (Repeated Exposure): Category 2
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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BENTONITE POWDERPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
90 to 98%1302-78-9 215-108-5BENTONITE
2 to 10%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
2 to 4%- -SODA ASH
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Repeated exposure to crystalline silica may result in lung fibrosis (silicosis). Principal symptoms of silicosis are coughing andbreathlessness. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up
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BENTONITE POWDERPRODUCT NAME
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packaging are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Quartz (respirable dust) SWA [AUS] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesBROWN POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point1100°C to 1200°C (Fusion Point)Melting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limit
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BENTONITE POWDERPRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT EXPLOSIVEExplosive propertiesNON OXIDISINGOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information~ 0.9 kg/LBulk density
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Toxicity Data available for the ingredients:QUARTZ (SILICA CRYSTALLINE) (14808-60-7):LCLo (inhalation) = 300 ug/m³/10 years (human)TCLo (inhalation) = 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)BENTONITE (1302-78-9):LD50 (intravenous) = 35 mg/kg (rat)LD50 (oral): > 2000mg/kg (rat)LDLo (intravenous) = 10 mg/kg (dog)Inhalation LC 50: > 5.27 mg/L, 4hr (rat)
Acute toxicity
Not classified as a skin irritant. Contact may result in mild irritation and dermatitis.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not expected to present an aspiration hazard.Aspiration
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused by deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
This product contains crystalline silica which is classified as carcinogenic to humans (IARC Group 1).However, there is sufficient information to conclude that the relative risk of lung cancer is increased inpersons with silicosis. Therefore, preventing the onset of silicosis will also reduce the cancer risk.
Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity values:
BENTONITE (1302-78-9)LD50 (intravenous) 35 mg/kg (rat)LDLo (intravenous) 10 mg/kg (dog)
11.1 Information on toxicological effects
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BENTONITE POWDERPRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Bentonite (1302-78-9):EC50 Daphnia > 100 mg/l, 48 hoursEC50 Freshwater algae > 100 mg/l, 72 hoursLC50 Freshwater fish = 16000 mg/l, 96 hoursLC50 Marine water fish = 2800 - 3200 mg/l, 24 hoursEC50 Coon stripe shrimp (Pandalus danae) = 24.8 mg/l, 96 hoursEC50 Dungeness or edible crab (Cancer magister) = 81.6 mg/l, 96 hoursLC50 Rainbow trout, donaldson trout (Oncorhynchus mykiss) = 19000 mg/l, 96 hours
12.2 Persistence and degradabilityNot relevant for inorganic substances.
12.4 Mobility in soil
Low water solubility, expected to sink and migrate into the sediment. Expected to partition to sediment and wastewater solids.
The main component/s of this product are not anticipated to cause any adverse effects to plants or animals.
12.5 Other adverse effects
12.3 Bioaccumulative potentialWill not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Reuse where possible. No special precautions are normally required when handling this product.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)All components are listed on AIIC, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
SDS Date: 20 Oct 2020
Revision No: 3.3ofPage 5 6
BENTONITE POWDERPRODUCT NAME
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
[ End of SDS ]
SDS Date: 20 Oct 2020
Revision No: 3.3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
ABGRIT ● CIRCAL ● LIMESTONE ● MARBLE ● NEWCARB, AG LIMESTONE, UNICAL 20 ● OMYACARB ●STONEDUST ● TRUECARB
Synonyms
DRILLING FLUID ADDITIVE ● WEIGHTING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
CALCIUM CARBONATEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>96%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)
<1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 1 6
CALCIUM CARBONATEPRODUCT NAME
May cause irritation to the eyes, skin and respiratory system.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
No fire or explosion hazard exists.5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
If spilt, collect and reuse where possible. If reuse is not possible, contain spillage, then collect and place in suitable containers fordisposal. Avoid generating dust.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium carbonate (Limestone, Marble, Whiting) SWA [AUS] -- 10 -- --
Quartz (respirable dust) SWA [AUS] -- 0.05 -- --
Quartz (respirable dust) (Precautionary advice) WorkSafe VIC -- 0.02 -- --
No Biological Limit Value allocated.Biological limits
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 2 6
CALCIUM CARBONATEPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesOFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point840°C (Decomposes)Boiling point825°CMelting pointNOT AVAILABLEEvaporation rate9pHNOT AVAILABLEVapour density2.7Relative densityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts. Incompatible with oxidising agents (e.g.hypochlorites).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization will not occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCalcium carbonate reacts with acids and acidic salts to generate gaseous carbon dioxide with effervescence (bubbling). The reactionwith concentrated solutions of acids is rapid and exothermic. The effervesence can create extensive foaming. Ignites on contact withfluorine.
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 3 6
CALCIUM CARBONATEPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.LD50 (Ingestion) = 6450 mg/kg (rat).
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) -- --LIMESTONE (CALCIUM CARBONATE)
Not classified as a skin irritant. Contact may result in mild irritation, redness and rash.Skin
Contact may result in irritation, lacrimation, pain and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure. Chronic exposure to respirable silica mayresult in pulmonary fibrosis (silicosis). However, given the low levels present, over exposure is notanticipated.
STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Insufficient data available to classify as a carcinogen.Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated tocause adverse environmental effects.
12.2 Persistence and degradabilityDissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in thewater and the carbonate will become part of the carbon cycle.
12.4 Mobility in soil
Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.
Avoid contamination of drains and waterways.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 4 6
CALCIUM CARBONATEPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)All components are listed on AIIC, or are exempt.
Inventory listings
Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals (GHS Revision 7).
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 5 6
CALCIUM CARBONATEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 02 Jun 2021
Revision No: 2.4ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
CALCIUM CHLORIDE ANHYDRATESynonyms
CONCRETE CONDITIONER ● DESICCANT ● DUST CONTROL AGENT ● FOOD ADDITIVE ● INDUSTRIALAPPLICATIONS
Uses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
CALCIUM CHLORIDE POWDER 94-97%Product name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
If eye irritation persists: Get medical advice/attention.P337 + P313
Response statements
Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
Causes serious eye irritation.H319Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Serious Eye Damage / Eye Irritation: Category 2A
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 1 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
No information provided.2.3 Other hazards
Disposal statementsNone allocated.
Storage statementsNone allocated.
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
94 to 97%10043-52-4 233-140-8CALCIUM CHLORIDE ANHYDROUS
1 to 5%7647-14-5 231-598-3SODIUM CHLORIDE
1%7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 2 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 1600°CBoiling point772°CMelting pointNOT RELEVANTEvaporation rate7.0 to 9.0pHNOT AVAILABLEVapour density2.15Specific gravity590 kg/m³ (Approximately)Solubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limit
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 3 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid contact with incompatible substances.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calciumoxide. May react exothermically with water (i.e. releasing heat).
May evolve toxic gases (chlorides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients:CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman)SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
2301 mg/kg (rat) > 5000 mg/kg (rabbit) --CALCIUM CHLORIDE ANHYDROUS
3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hour(rat)
SODIUM CHLORIDE
11.1 Information on toxicological effects
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 4 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.Skin
Causes serious eye irritation. Contact may result in irritation, lacrimation, pain and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Insufficient data available to classify as a carcinogen.Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity values:
SODIUM CHLORIDE (7647-14-5)LD50 (intraperitoneal) 2602 mg/kg (mouse)LD50 (intravenous) 645 mg/kg (mouse)LD50 (subcutaneous) 3000 mg/kg (mouse)LDLo (intravenous) 300 mg/kg (guinea pig)LDLo (oral) 8000 mg/kg (rabbit)LDLo (subcutaneous) 2160 mg/kg (guinea pig)TDLo (oral) 12357 mg/kg (human)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 5 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 6 7
CALCIUM CHLORIDE POWDER 94-97%PRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
SODIUM HYDROXIDE SOLIDSynonyms
MANUFACTURE OF CHEMICALS ● REAGENT ● SCRUBBING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
CAUSTIC SODAProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word DANGER
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
Causes severe skin burns and eye damage.H314Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Skin Corrosion/Irritation: Category 1A
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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CAUSTIC SODAPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store locked up.P405Storage statements
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.P301 + P330 + P331IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin withwater/shower.
P303 + P361 + P353
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310Specific treatment is advised - see first aid instructions.P321Wash contaminated clothing before reuse.P363
Response statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>99%1310-73-2 215-185-5SODIUM HYDROXIDE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. To protect rescuer, use an Air-line respirator where an inhalationrisk exists. Apply artificial respiration if not breathing.
Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Causes severe skin burns and eye damage.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededCORROSIVE POISONING TREATMENT: Immediate treatment preferably in a hospital is mandatory. In treating corrosive poisoning,DO NOT INDUCE VOMITING; DO NOT ATTEMPT GASTRIC LAVAGE; and DO NOT ATTEMPT TO NEUTRALISE THE CORROSIVESUBSTANCE. Vomiting will increase the severity of damage to the oesophagus as the corrosive substance will again come incontact with it. Attempting gastric lavage may result in perforating either the oesophagus or stomach. Immediately dilute the corrosivesubstance by having the patient drink milk or water. If the trachea has been damaged tracheostamy may be required. Foroesophageal burns begin broad-spectrum antibiotics and corticosteroid therapy. Intravenous fluids will be required if oesophageal orgastric damage prevents ingestion of liquids. Long-range therapy will be directed toward preventing or treating oesophageal scarsand strictures.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve flammable hydrogen gas in contact with some metals. Direct contact with water can produce a violentexothermic reaction.
5.2 Special hazards arising from the substance or mixture
Use an extinguishing agent suitable for the surrounding fire. Use carbon dioxide or suitable dry chemical extinguisher. Do NOT usewater.
5.1 Extinguishing media
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Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
2X2 Fine Water Spray.X Wear liquid-tight chemical protective clothing and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Allow only trained personnel wearing appropriateprotective equipment to be involved in spill response. Avoid accidents, clean up immediately. Increase ventilation. Avoid walkingthrough spilled product as it is slippery when spilt. Isolate the danger area. Use clean, non-sparking tools and equipment. Shut off allpossible sources of ignition.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Mechanically collect as much of the spill as possible. Absorb with sand, earth or clay. Transfer to suitable, labelled,corrosion-resistant containers and dispose of promptly as hazardous waste. Spill on areas other than pavement, dirt or sand may behandled by removing the affected soils and placing into approved containers.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such asdamage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Store away fromaluminium, tin, zinc and alloys (bronzes), chrome and lead. Protect from damp and kept apart from acids, halogenated hydrocarbons,nitroparaffins, etc. The floor must be waterproof and anti-slip. A water supply or source must be provided in the place of storage.Emergency showers and eye-washes must be available. Special conditions: Prevent the product from becoming damp or erated.Hygroscopic product. Becomes carbonated in contact with the air or moisture.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommendedprocedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and groundingequipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid prolonged or repeated exposure. Do notsmoke, eat or drink when handling product. Product can react violently with water and acids. Caustic solution generates heat whenfurther diluted with water. Concentrations greater than 40%, the heat generated can raise temperatures above the boiling pointresulting in sporadic, violent eruptions or spattering. Emergency showers and eye-washes must be available. When used in itsvarious applications, the product must be prevented from coming into uncontrolled direct contact with other products such as acidsand metals. Never neutralise the solid product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium hydroxide (peak limitation) SWA [AUS] -- 2 (Peak) -- --
Biological limits
No biological limit values have been entered for this product.
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CAUSTIC SODAPRODUCT NAME
PPE
Eye / Face Wear a faceshield and dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Wear coveralls and rubber boots and a PVC apron.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear anAir-line respirator or a Full-face Class P3 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE DELIQUESCENT PEARLSAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1390°CBoiling point318°CMelting pointNOT AVAILABLEEvaporation rate13.5 (1 % solution)pHNOT AVAILABLEVapour density2.12Specific gravity1110 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityHighly exothermal reaction with strong acids. Reacts dangerously with acetic acid, allyl chloride, chlorine trifluoride, chloroform,methylic alcohol, chloronitrotoluene, chlorosulphonic acid, glyoxal, cyanohydrin, hydrochloric acid, hydrofluoric acid, hydroquinone,nitric acid, sulphuric acid and oleum, nitropropane, phosphorous, propiolactone, phosphorous pentoxide, tetrachlorobenzene,tetrahydrofuran, etc. Caustic soda forms salts with nitromethane and nitroparaffins that explode on impact. Heat is generated whenmixed with water. Spattering and boiling can occur. Caustic soda solution reacts readily with various reducing sugars (ie: fructose,glactose, maltose, dry whey solids) to produce carbon monoxide. Caustic soda forms salts with nitromethane and nitroparaffins thatexplode on impact. Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen.
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CAUSTIC SODAPRODUCT NAME
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.
Reacts with aluminium, tin, zinc and their alloys, copper, lead, etc. giving off hydrogen. When the product decomposes, toxic sodiumoxide gases are evolved.
10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Highly corrosive. This product has the potential to cause serious adverse health effects. Use safe workpractices to avoid eye or skin contact and inhalation. Over exposure may result in severe burns withcorrosive tissue damage. Upon dilution, the potential for corrosive effects may be reduced.
SODIUM HYDROXIDE (1310-73-2):LD50 (Intraperitoneal): 40 mg/kg (mouse)LDLo (Ingestion): 1.57 mg/kg (human)
Acute toxicity
Causes severe burns. Contact may result in irritation, redness, pain, rash, dermatitis and skin burns.Skin
Causes severe burns. Contact may result in irritation, lacrimation, pain, redness and corneal burns withpossible permanent eye damage.
Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may resultin breathing difficulties.
STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin. Insufficient data available to classify as a reproductive toxin. Thesubstance is not expected to be systemically available in the body under normal handling and use conditionsand for this reason it can be stated that the substance will not reach the foetus nor reach male and femalereproductive organs. The substance is not expected to be systemically available in the body under normalhandling and use conditions and for this reason additional testing is considered unnecessary.
Reproductive
Not classified as a carcinogen. Insufficient data available to classify as a carcinogen. Systemiccarcinogenicity is not expected to occur because the substance is not expected to be systemically availablein the body under normal handling and use conditions.
Carcinogenicity
Insufficient data available to classify as a mutagen. Both the in vitro and the in vivo genetic toxicity testsindicated no evidence of mutagenic activity. Furthermore the substance is not expected to be systemicallyavailable in the body under normal handling and use conditions and for this reason additional testing isconsidered unnecessary (EU RAR, 2007).
Mutagenicity
Additional ingredient toxicity values:
SODIUM HYDROXIDE (1310-73-2)LD50 (intraperitoneal) 40 mg/kg (mouse)LDLo (oral) 500 mg/kg (rabbit)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
EC50 Ceriodaphnia: 40 mg/L.
No other valid studies available. The hazard of NaOH for the environment is caused by the hydroxyl ion (pH effect). For this reason theeffect of NaOH on the organisms depends on the buffer capacity of the aquatic or terrestrial ecosystem (see also 3.1.2). Also thevariation in acute toxicity for aquatic organisms can be explained for a significant extent by the variation in buffer capacity of the testmedium. LC50 values ranged between 33 and 189 mg/L.
12.2 Persistence and degradabilityReadily biodegradable. NaOH is a strong alkaline substance that dissociates completely in water to Na+ and OH-. High watersolubility and low vapour pressure indicate that NaOH will be found predominantly in aquatic environment. This implies that it will notadsorb on particulate matter or surfaces. Atmospheric emissions as aerosols are rapidly neutralized by carbon dioxide and the saltswill be washed out by rain.
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CAUSTIC SODAPRODUCT NAME
12.4 Mobility in soil
High water solubility and mobility
WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11(goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Notexpected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
12.5 Other adverse effects
12.3 Bioaccumulative potentialDoes not bioaccumulate. Considering its high water solubility, NaOH is not expected to bioconcentrate in organisms. In addition,sodium is a naturally-occurring element that is prevalent in the environment and to which organisms are exposed regularly, for whichthey have some capacity to regulate the concentration in the organism.
13. DISPOSAL CONSIDERATIONS
Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required). The product can be neutralisedusing highly diluted hydrochloric acid, which should be added very slowly by specialised personnel wearingproper protection. Never neutralise the solid product.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
II
8 8
II II
814.3 Transporthazard class
14.4 Packing Group
SODIUM HYDROXIDE, SOLID
1823
SODIUM HYDROXIDE, SOLID
1823 1823
SODIUM HYDROXIDE, SOLID
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
2XHazchem code
F-A, S-BEmS
8A1GTEPG
14.6 Special precautions for user
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
15. REGULATORY INFORMATION
Classified as a Schedule 6 (S6) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
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CAUSTIC SODAPRODUCT NAME
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
[ End of SDS ]
SDS Date: 05 Feb 2020
Revision No: 2.5ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
2-HYDROXY-1,2,3-PROPANETRICARBOXYLIC ACID ● CITRIC ACID ANHYDROUS ● CITRIC ACIDMONOHYDRATE
Synonyms
INDUSTRIAL APPLICATIONSUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
CITRIC ACIDProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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CITRIC ACIDPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statements
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321Take off contaminated clothing and wash before re-use.P362
Response statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>99%77-92-9 201-069-1CITRIC ACID
<1%7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Irritating to the eyes, skin and respiratory system.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
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CITRIC ACIDPRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure containers areadequately labelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
No Biological Limit Value allocated.Biological limits
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE CRYSTALLINE POWDERAppearanceODOURLESSOdourCOMBUSTIBLEFlammability174°CFlash point175°C (Decomposes)Boiling point153°CMelting point
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CITRIC ACIDPRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT AVAILABLEEvaporation rate2.2 (0.1M Solution)pHNOT AVAILABLEVapour density1.665Specific gravity1330 kg/m³ @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient345°CAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and alkalis (e.g. sodium hydroxide).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Based on available data, the classification criteria are not met. LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Intraperitoneal): 290 mg/kg (rat)LD50 (Intravenous): 42 mg/kg (mouse)LDLo (Ingestion): 7000 mg/kg (rabbit)
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
3000 mg/kg (rat) > 2000 mg/kg (rat) --CITRIC ACID
Irritating to the skin. Contact may result in irritation, redness, rash and dermatitis.Skin
Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness. May result in burns withprolonged contact.
Eye
Not classified as causing skin or respiratory sensitisation. However, citric acid has the potential to causeallergic effects.
Sensitisation
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity values:
CITRIC ACID (77-92-9)LD50 (intraperitoneal) 290 mg/kg (rat)LD50 (intravenous) 42 mg/kg (mouse)LDLo (oral) 7000 mg/kg (rabbit)
11.1 Information on toxicological effects
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CITRIC ACIDPRODUCT NAME
Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing.
STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Insufficient data available to classify as a carcinogen.Carcinogenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
LC50 (Leuciscus idus melanotus): 440 mg/L/48hrs.LC50 (Daphnia magna (Water flea)): 1.535 mg/L/24hrs.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
Citric acid is expected to have very high mobility in soil (HSDB).
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Neutralise with lime, anion exchanger or similar. For small amounts, absorb with sand or similar anddispose of to an approved landfill site. Contact the manufacturer/supplier for additional information (ifrequired).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 5 7
CITRIC ACIDPRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 6 7
CITRIC ACIDPRODUCT NAME
[ End of SDS ]
SDS Date: 05 Feb 2020
Revision No: 2.2ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
DEFOAMERSynonyms
TREATMENT OF FOAMING IN DRILLING FLUIDSUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
DEFOAM AP 400Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
45 to 60%25322-68-3 500-038-2POLYETHYLENE GLYCOL
40 to 55%123-96-6 204-667-0OCTAN-2-OL
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
None allocated.First aid facilities
SDS Date: 03 Feb 2020
Revision No: 2ofPage 1 6
DEFOAM AP 400PRODUCT NAME
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal. Eliminate all sources of ignition.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
SDS Date: 03 Feb 2020
Revision No: 2ofPage 2 6
DEFOAM AP 400PRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCLEAR COLOURLESS LIQUIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point100°C to 102°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density1.00 to 1.17Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information-7°C to 0°CFreezing point
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
SDS Date: 03 Feb 2020
Revision No: 2ofPage 3 6
DEFOAM AP 400PRODUCT NAME
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 15,000 mg/kg (rat) > 20,000 mg/kg (rabbit) --POLYETHYLENE GLYCOL
-- 2000 mg/kg (rat) --OCTAN-2-OL
Not classified as a skin irritant. Contact may cause temporary mild skin irritation.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 2ofPage 4 6
DEFOAM AP 400PRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 2ofPage 5 6
DEFOAM AP 400PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 2ofPage 6 6
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 1/9
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information
Product Name : Driscal® D Polymer Material : 1112534, 1016818
Company : Chevron Phillips Chemical Company LP
Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380
Local : Chevron Phillips Chemicals Australia Pte Ltd
Suite 409 685 Burke Road Camberwell, Victoria Australia 3124 Hours of Operation: 9:00 a.m. - 5:00 p.m. SDS Requests: 61 3 8080 5700 Technical Information: 61 3 8080 5700 Responsible Party: Product Safety Group Email:[email protected]
Emergency telephone:
Health: 866.442.9628 (North America) 1.832.813.4984 (International) 61 3 8080 5700 (Australia) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Mexico CHEMTREC 01-800-681-9531 (24 hours) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Argentina: +(54)-1159839431
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 2/9
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
Classification of the substance or mixture Model Work Health and Safety Regulations 2011, Model Code of Practice for the Labelling of Workplace Hazardous Chemicals (2011), Guidance on the Classification of Hazardous Chemicals under the WHS Regulations (2012) (GHS 2009)
Classification
Not a hazardous substance or mixture.
Labeling
Not a hazardous substance or mixture.
SECTION 3: Composition/information on ingredients
Synonyms : High Temperature Polymer
Contains no hazardous ingredients according to GHS. SECTION 4: First aid measures
General advice : No hazards which require special first aid measures. If inhaled : If unconscious, place in recovery position and seek medical
advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye
irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Never give anything by mouth to
an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : Not applicable Autoignition temperature : No data available
Specific hazards during fire fighting
: Risks of ignition followed by flame propagation or secondary explosions can be caused by the accumulation of dust, e.g. on floors and ledges.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if necessary.
Further information : Standard procedure for chemical fires. Use extinguishing
measures that are appropriate to local circumstances and the surrounding environment.
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 3/9
Fire and explosion protection
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Hazardous decomposition products
: No data available.
SECTION 6: Accidental release measures
Personal precautions : Avoid dust formation. Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities. Methods for cleaning up : Pick up and arrange disposal without creating dust. Clean up
promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.
Additional advice : Contaminated surfaces will be extremely slippery. Avoid
spillage on floor as the product can become very slippery when wet. Sweep up to prevent slipping hazard. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
SECTION 7: Handling and storage
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and
drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.
Advice on protection against fire and explosion
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Storage
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
SECTION 8: Exposure controls/personal protection
Engineering measures
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 4/9
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a supplied-air NIOSH approved respirator unless
ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.
Hand protection : The suitability for a specific workplace should be discussed
with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : General industrial hygiene practice.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance
Form : Powder Physical state : Solid Color : White Odor : No odor Odor Threshold : No data available
Safety data
Flash point : Not applicable
Lower explosion limit : No data available
Upper explosion limit : No data available
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 5/9
Oxidizing properties : No
Autoignition temperature : No data available
Thermal decomposition : No data available
Molecular weight : Not applicable
pH : Not applicable
Pour point : No data available
Boiling point/boiling range : No data available
Vapor pressure : No data available
Relative density : 1.44
Density : No data available
Water solubility : Soluble
Partition coefficient: n-octanol/water
: Pow: < 3
Viscosity, kinematic : No data available
Relative vapor density : No data available
Evaporation rate : No data available
SECTION 10: Stability and reactivity
Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions
Hazardous reactions : Hazardous reactions: Hazardous polymerization does not
occur.
Further information: Stable under recommended storage conditions., No hazards to be specially mentioned.
Conditions to avoid : Generation of Dusts. Thermal decomposition : No data available
Hazardous decomposition products
: No data available
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 6/9
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Driscal® D Polymer Further information : The product contains no substances classified as hazardous
to health in concentrations which should be taken into account.
SECTION 12: Ecological information
Biodegradability : Taking into consideration the properties of several ingredients,
the product is estimated not to be readily biodegradable according to OECD classification.
Elimination information (persistence and degradability) Bioaccumulation : Accumulation in aquatic organisms is unlikely.
Additional ecological information
: This material is not expected to be harmful to aquatic organisms.
Ecotoxicology Assessment
SECTION 13: Disposal considerations
The information in this SDS pertains only to the product as shipped.
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
SECTION 14: Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 7/9
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
Standard for the Uniform Scheduling of Medicines and Poisons
: No poison schedule number allocated
Notification status Europe REACH : On the inventory, or in compliance with the inventory Switzerland CH INV : On the inventory, or in compliance with the inventory United States of America (USA) TSCA
: On TSCA Inventory
Canada DSL : All components of this product are on the Canadian DSL
Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : This product contains one or more substances that
have been notified under New Substances Notification
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 8/9
laws. However, only CPChem and other independent notifiers are approved to be the importers of record.
SECTION 16: Other information
Further information
Legacy SDS Number : 244990
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportat ion, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of
Government Industrial Hygienists LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical Substances
LOAEL Lowest Observed Adverse Effect Level
DSL Canada, Domestic Substances List
NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substances List
NIOSH National Institute for Occupational Safety & Health
CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of
Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure
Scenario Tool OSHA Occupational Safety & Health
Administration EOSCA European Oilfield Specialty
Chemicals Association PEL Permissible Exposure Limit
EINECS European Inventory of Existing Chemical Substances
PICCS Philippines Inventory of Commercial Chemical Substances
MAK Germany Maximum Concentration Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery Act
>= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act. IARC International Agency for Research
on Cancer TLV Threshold Limit Value
IECSC Inventory of Existing Chemical Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory
UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System
LC50 Lethal Concentration 50%
SAFETY DATA SHEET
Driscal® D Polymer Version 1.10 Revision Date 2018-09-20
SDS Number:100000066569 9/9
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 1/11
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information
Product Name : Drispac® (Regular and Superlo®) Polymer Material : 1016806, 1016803, 1116045
Use : Drilling Mud Additive Company : Chevron Phillips Chemical Company LP
Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380
Emergency telephone:
Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) Mexico CHEMTREC 01-800-681-9531 (24 hours) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600 Argentina: +(54)-1159839431
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
SECTION 2: Hazards identification
Classification of the substance or mixture This product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labels contain all the information as required by the standard.
Classification : Combustible dust
Labeling
Signal Word : Warning
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 2/11
Hazard Statements : May form combustible dust concentrations in air.
Carcinogenicity:
IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
SECTION 3: Composition/information on ingredients
Synonyms : Viscosifier, Water loss control agent
Component CAS-No. Weight % Sodium Carboxymethylcellulose 9004-32-4 98 - 100
SECTION 4: First aid measures
General advice : No hazards which require special first aid measures. If inhaled : If unconscious, place in recovery position and seek medical
advice. If symptoms persist, call a physician. In case of eye contact : Remove contact lenses. Protect unharmed eye. If eye
irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic
beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
SECTION 5: Firefighting measures
Flash point : Not applicable Autoignition temperature : Not applicable
Unsuitable extinguishing media
: High volume water jet.
Specific hazards during fire fighting
: Risks of ignition followed by flame propagation or secondary explosions shall be prevented by avoiding accumulation of dust, e.g. on floors and ledges.
Special protective equipment for fire-fighters
: Wear self-contained breathing apparatus for firefighting if necessary.
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 3/11
Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Fire and explosion protection
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
SECTION 6: Accidental release measures
Personal precautions : Avoid dust formation. Environmental precautions : Prevent further leakage or spillage if safe to do so. If the
product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Pick up and arrange disposal without creating dust. Sweep up
and shovel. Keep in suitable, closed containers for disposal. Additional advice : Contaminated surfaces will be extremely slippery. Avoid
spillage on floor as the product can become very slippery when wet. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
SECTION 7: Handling and storage
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and
drinking should be prohibited in the application area. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.
Advice on protection against fire and explosion
: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.
Storage
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned. Use : Drilling Mud Additive
SECTION 8: Exposure controls/personal protection
Engineering measures
Adequate ventilation to control airborned concentrations below the exposure guidelines/limits.
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 4/11
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection : Wear a supplied-air NIOSH approved respirator unless
ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.
Hand protection : The suitability for a specific workplace should be discussed
with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.
Hygiene measures : General industrial hygiene practice.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance
Form : Powder Physical state : Solid Color : White to off-white Odor : Slight Odor Threshold : No data available
Safety data
Flash point : Not applicable
Lower explosion limit : Not applicable
Upper explosion limit : Not applicable
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 5/11
Flammability (solid, gas) : May form combustible dust concentrations in air.
Oxidizing properties : no
Autoignition temperature : Not applicable
Thermal decomposition : No data available
Molecular weight : No data available
pH : Not applicable
Pour point : No data available
Melting point/range No data available
Boiling point/boiling range : No data available
Vapor pressure : Not applicable
Relative density : Not applicable
Density : 1.5 g/cm3
Water solubility : Completely Soluble
Partition coefficient: n-octanol/water
: No data available
Solubility in other solvents : No data available
Viscosity, kinematic : No data available
Relative vapor density : Not applicable
Evaporation rate : No data available
SECTION 10: Stability and reactivity
Reactivity : Stable at normal ambient temperature and pressure.
Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
Possibility of hazardous reactions
Hazardous reactions : Further information: Stable under recommended storage
conditions., No hazards to be specially mentioned.
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 6/11
Conditions to avoid : Generation of Dusts. Materials to avoid : No data available. Thermal decomposition : No data available
Other data : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Acute oral toxicity
Sodium Carboxymethylcellulose
: LD50: 27,000 mg/kg Species: Rat
Acute inhalation toxicity
Sodium Carboxymethylcellulose
: LC50: > 5800 mg/m3Exposure time: 4 h Species: Rat Test atmosphere: dust/mist
Drispac® (Regular and Superlo®) Polymer Further information : No data available.
SECTION 12: Ecological information
Ecotoxicity effects Toxicity to fish : This material is not expected to be harmful to aquatic
organisms.
Toxicity to daphnia and other aquatic invertebrates
: This material is not expected to be harmful to aquatic organisms.
Toxicity to algae : This material is not expected to be harmful to aquatic
organisms.
Biodegradability Sodium Carboxymethylcellulose
: This material is expected to be readily biodegradable.
Bioaccumulation Sodium Carboxymethylcellulose
: This material is not expected to bioaccumulate.
Mobility
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 7/11
Sodium Carboxymethylcellulose
: No data available
Additional ecological information
: No data available
Ecotoxicology Assessment
Short-term (acute) aquatic hazard Sodium Carboxymethylcellulose
: This material is not expected to be harmful to aquatic organisms.
Long-term (chronic) aquatic hazard Sodium Carboxymethylcellulose
: This material is not expected to be harmful to aquatic organisms.
SECTION 13: Disposal considerations
The information in this SDS pertains only to the product as shipped.
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.
Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
SECTION 14: Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 8/11
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)
NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
SARA 311/312 Hazards : Combustible dust
CERCLA Reportable Quantity
: This material does not contain any components with a CERCLA RQ.
SARA 302 Reportable Quantity
: This material does not contain any components with a SARA 302 RQ.
SARA 302 Threshold Planning Quantity
: This material does not contain any components with a section 302 EHS TPQ.
SARA 304 Reportable Quantity
: This material does not contain any components with a section 304 EHS RQ.
SARA 313 Components : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 9/11
Ozone-Depletion Potential
: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): : Sodium Carboxymethylcellulose - 9004-32-4
US State Regulations
Pennsylvania Right To Know : Sodium Carboxymethylcellulose - 9004-32-4 California Prop. 65 Components
: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
Notification status Europe REACH : This product is in full compliance according to REACH
regulation 1907/2006/EC. Switzerland CH INV : Not in compliance with the inventory United States of America (USA) TSCA
: On or in compliance with the active portion of the TSCA inventory
Canada DSL : All components of this product are on the Canadian DSL
Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : On the inventory, or in compliance with the inventory Korea KECI : A substance(s) in this product was not registered,
notified to be registered, or exempted from registration by CPChem according to K-REACH regulations. Importation or manufacture of this product is still permitted provided the Korean Importer of Record has themselves notified the substance.
Philippines PICCS : On the inventory, or in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory Taiwan TCSI : On the inventory, or in compliance with the inventory
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 10/11
SECTION 16: Other information
NFPA Classification : Health Hazard: 0 Fire Hazard: 2 Reactivity Hazard: 0
Further information
Legacy SDS Number : 25950
Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of
Government Industrial Hygienists LD50 Lethal Dose 50%
AICS Australia, Inventory of Chemical Substances
LOAEL Lowest Observed Adverse Effect Level
DSL Canada, Domestic Substances List
NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substances List
NIOSH National Institute for Occupational Safety & Health
CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of
Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure
Scenario Tool OSHA Occupational Safety & Health
Administration EOSCA European Oilfield Specialty
Chemicals Association PEL Permissible Exposure Limit
EINECS European Inventory of Existing Chemical Substances
PICCS Philippines Inventory of Commercial Chemical Substances
MAK Germany Maximum Concentration Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery Act
>= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act. IARC International Agency for Research
on Cancer TLV Threshold Limit Value
IECSC Inventory of Existing Chemical Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act
0
2
0
SAFETY DATA SHEET
Drispac® (Regular and Superlo®) Polymer Version 2.2 Revision Date 2020-07-30
SDS Number:100000014007 11/11
New Chemical Substances KECI Korea, Existing Chemical
Inventory UVCB Unknown or Variable Composition,
Complex Reaction Products, and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System
LC50 Lethal Concentration 50%
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
1093242, 1016819 - MATERIAL NUMBERSynonyms
DEFOAMER ● DEFOAMING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
DSCO DEFOAMProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>60%25322-69-4 500-039-8POLYPROPYLENE GLYCOL
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 08 Jun 2018
Version No: 2ofPage 1 6
DSCO DEFOAMPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems. Store as a Class C2 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
SDS Date: 08 Jun 2018
Version No: 2ofPage 2 6
DSCO DEFOAMPRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls. In a laboratory situation,wear a laboratory coat.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCLEAR TO LIGHT AMBER LIQUIDAppearanceSLIGHT ODOUROdourCLASS C2 COMBUSTIBLEFlammability185°CFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.00Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising properties
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsAcute toxicity
11.1 Information on toxicological effects
SDS Date: 08 Jun 2018
Version No: 2ofPage 3 6
DSCO DEFOAMPRODUCT NAME
are not anticipated.
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
300 - 57000 mg/kg(range)
-- --POLYPROPYLENE GLYCOL
Not classified as a skin irritant. Contact may cause temporary mild skin irritation.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 08 Jun 2018
Version No: 2ofPage 4 6
DSCO DEFOAMPRODUCT NAME
None allocated.Hazchem code
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.NEW ZEALAND: NZIoC (New Zealand Inventory of Chemicals)All components are listed on the NZIoC inventory, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 08 Jun 2018
Version No: 2ofPage 5 6
DSCO DEFOAMPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 08 Jun 2018
Version No: 2ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
POTASSIUM SILICATE POWDERSynonyms
DRILLING AIDUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
FLEXFIRM KAProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Harmful if swallowed.H302Causes skin irritation.H315Causes serious eye irritation.H319May cause respiratory irritation.H335May cause damage to organs through prolonged or repeated exposure.H373
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Acute Toxicity: Oral: Category 4Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)Specific Target Organ Toxicity (Repeated Exposure): Category 2
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
SDS Date: 06 Feb 2020
Revision No: 2.4ofPage 1 7
FLEXFIRM KAPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statements
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Get medical advice/attention if you feel unwell.P314Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin or eye irritation occurs: Get medical advice/ attention.P332 + P337 + P313Take off contaminated clothing and wash before re-use.P362
Response statements
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
99%1312-76-1 215-199-1POTASSIUM SILICATE
0.1 to 1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
None allocated.First aid facilities
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
SDS Date: 06 Feb 2020
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FLEXFIRM KAPRODUCT NAME
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Quartz (respirable dust) SWA [AUS] -- 0.1 -- --Quartz (respirable dust) SWA [Proposed] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
SDS Date: 06 Feb 2020
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FLEXFIRM KAPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate11.3 (50 % solution) (Approximately)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Harmful if swallowed.Acute toxicity
11.1 Information on toxicological effects
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FLEXFIRM KAPRODUCT NAME
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
1600 mg/kg (rat) -- --POTASSIUM SILICATE
Contact may result in irritation, redness, rash and dermatitis.Skin
Contact may result in irritation, lacrimation, pain and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.
STOT - singleexposure
Not classified as causing aspiration.Aspiration
Repeated exposure to respirable silica may result in pulmonary fibrosis (silicosis). Silicosis is a fibronodularlung disease caused by deposition in the lungs of fine respirable particles of crystalline silica. Principalsymptoms of silicosis are coughing and breathlessness.
STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is a body ofevidence supporting the fact that increased cancer risk would be limited to people already suffering fromsilicosis.
Carcinogenicity
Not classified as a mutagen.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
The high pH when undiluted or unneutralized is acutely harmful to aquatic life. The following data is reported for chemically similarSodium Silicates on a 100% solids basis: A 96 hour median tolerance for fish (Gambusia affnis) of 2320 ppm; a 96 hour mediantolerance for water fleas (Daphnia magna) of 247 ppm; a 96 hour median tolerance for snail eggs (Lymnea) of 632 ppm; and a 96 hourmedian tolerance for Amphipoda of 160 ppm.
12.2 Persistence and degradabilityThis material is not persistent in aquatic systems.
12.4 Mobility in soil
Expected to be mobile in soil. Diluted material rapidly depolymerizes to yield dissolved silica in a form that is indistinguishable fromnatural dissolved silica.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNeither silica nor potassium will appreciably bio-concentrate up the food chain.
13. DISPOSAL CONSIDERATIONS
Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
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FLEXFIRM KAPRODUCT NAME
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 06 Feb 2020
Revision No: 2.4ofPage 6 7
FLEXFIRM KAPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 06 Feb 2020
Revision No: 2.4ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
FRAC-ATTACKSynonyms
LOST CIRCULATION MATERIALUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
FRAC ATTACKProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word DANGER
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
Causes skin irritation.H315Causes serious eye damage.H318May cause respiratory irritation.H335
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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FRAC ATTACKPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statements
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310Specific treatment is advised - see first aid instructions.P321If skin irritation occurs: Get medical advice/ attention.P332 + P313Take off contaminated clothing and wash before re-use.P362
Response statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
<30%9004-34-6 232-674-9CELLULOSE
<15%61790-53-2 612-383-7DIATOMACEOUS EARTH
<12%8031-18-3 617-052-0FULLERS EARTH
<10%1305-78-8 215-138-9CALCIUM OXIDE
<5%1305-62-0 215-137-3CALCIUM HYDROXIDE
<5%14464-46-1 238-455-4CRISTOBALITE
<3%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
<2%1309-48-4 215-171-9MAGNESIUM OXIDE
<50%9003-55-8 618-370-21,3 BUTADIENE/STYRENE COPOLYMERS
<50%9003-18-3 618-357-12-PROPENENITRILE-1,3-BUTADIENE RUBBER
<50%9006-04-6 232-689-0NATURAL RUBBER
<50%9003-31-0 618-362-9POLYISOPRENE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities should be available.First aid facilities
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
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FRAC ATTACKPRODUCT NAME
Non flammable.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium hydroxide SWA [AUS] -- 5 -- --Calcium hydroxide SWA [Proposed] -- 1 -- --
Calcium oxide SWA [AUS] -- 2 -- --Calcium oxide SWA [Proposed] -- 1 -- --
Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --
Cristobalite SWA [AUS] -- 0.1 -- --
Diatomaceous earth (uncalcined) (a) SWA [AUS] -- 10 -- --
Magnesium oxide (fume) SWA [AUS] -- 10 -- --
Quartz (respirable dust) SWA [AUS] -- 0.1 -- --Quartz (respirable dust) SWA [Proposed] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --
SDS Date: 05 Feb 2020
Revision No: 2.3ofPage 3 7
FRAC ATTACKPRODUCT NAME
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesBROWN/GREY POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNON VOLATILEEvaporation rateALKALINEpHNOT AVAILABLEVapour density2.10Specific gravityNEGLIGIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other informationNOT RELEVANT% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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FRAC ATTACKPRODUCT NAME
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve Fluorine, Oxygen Difluoride, Chlorine, Trifluoride and Hydrofluoric Acid when heated to decomposition.10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Toxicity Data available for the ingredients:CALCIUM HYDROXIDE (1305-62-0): LD50 (ingestion): 7300 mg/kg (mouse)CRISTOBALITE (14464-46-1): TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)QUARTZ (SILICA CRYSTALLINE) (14808-60-7): LCLo (inhalation): 300 ug/m³/10 years (human) TCLo (inhalation): 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)CELLULOSE (9004-34-6): LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit)MAGNESIUM OXIDE (1309-48-4): TCLo (inhalation): 400 mg/kg (human)
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)
CELLULOSE
> 5000 mg/kg (rat) > 5000 mg/kg (rabbit) --DIATOMACEOUS EARTH
7300 mg/kg (mouse) -- --CALCIUM HYDROXIDE
Irritating to the skin. Contact may result in irritation, redness, pain, rash, dermatitis and possible skin burns.Skin
Irritating to the eyes. Contact may result in irritation, lacrimation, pain, redness, conjunctivitis and possibleburns.
Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Irritating to the respiratory system. Over exposure may result in irritation of the nose and throat, withcoughing.
STOT - singleexposure
Not classified as causing aspiration. Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure. Repeated exposure to crystalline silicamay cause lung fibrosis (silicosis), however due to the low levels of respirable crystalline silica in thisproduct, adverse health effects are not anticipated with normal use.
STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Crystalline silica is classified as carcinogenic to humans (IARC Group 1). However, there is a body ofevidence supporting the fact that increased cancer risk would be limited to people already suffering fromsilicosis.
Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity values:
CELLULOSE (9004-34-6)LD50 (intraperitoneal) > 31600 mg/kg (rat)
CRISTOBALITE (14464-46-1)TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
The manufacturer reports that this product is harmful to aquatic life.
12.2 Persistence and degradabilityNo information provided.
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FRAC ATTACKPRODUCT NAME
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
Additional information
SDS Date: 05 Feb 2020
Revision No: 2.3ofPage 6 7
FRAC ATTACKPRODUCT NAME
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 05 Feb 2020
Revision No: 2.3ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
FRACSEAL F ● FRACSEAL FINE ● FRACSEAL M ● FRACSEAL MEDIUMSynonyms
DRILLING FLUID ADDITIVEUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
FRACSEAL FINE/MEDIUMProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%9004-34-6 232-674-9CELLULOSE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
Exposure is considered unlikely. Skin irritation is not anticipated.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
Ingestion
None allocated.First aid facilities
This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.4.2 Most important symptoms and effects, both acute and delayed
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FRACSEAL FINE/MEDIUMPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for damage tocontainers.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --
Biological limitsNo biological limit values have been entered for this product.
SDS Date: 29 Oct 2019
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FRACSEAL FINE/MEDIUMPRODUCT NAME
PPE
Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceODOURLESSOdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling point500°C to 518°CMelting pointNOT AVAILABLEEvaporation rate6.5 to 7.5pHNOT AVAILABLEVapour density0.9Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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FRACSEAL FINE/MEDIUMPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Oral LD50 (rat) is > 5000 mg/kg.Dermal LD50 (rabbit) is > 2000 mg/kg.LC50 (rat) is 510 mg/m³/2 hours.
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)
CELLULOSE
Not classified as a skin irritant.Skin
Not classified as an eye irritant. Contact may cause mild discomfort.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
Additional ingredient toxicity values:
CELLULOSE (9004-34-6)LD50 (intraperitoneal) > 31600 mg/kg (rat)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Reuse where possible. No special precautions are normally required when handling this product.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
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FRACSEAL FINE/MEDIUMPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 29 Oct 2019
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FRACSEAL FINE/MEDIUMPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 29 Oct 2019
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GageTrolÔ
EN
SAFETY DATA SHEET
Issue Date 15-Mar-2017 Revision Date 15-Mar-2017 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name GageTrolÔ
Product Code NDF00018
Other means of identification
Pure substance/mixture Substance
Recommended use of the chemical and restrictions on use
Recommended Use filtration control agent
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number +(61)-290372994 (Australia); +(64)-98010034 (New Zealand)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Other hazards
_____________________________________________________________________________________________
UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
General HazardsThis substance does not meet the PBT/vPvB criteria of REACH, annex XIII
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing media Dry chemical, CO2, water spray or regular foam.
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Non-hazardous ingredients Proprietary
_____________________________________________________________________________________________
UGHS Page 2 / 8
>99
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Strong oxidizing agents Strong acids
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
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UGHS Page 3 / 8
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Solid
Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density No information availableBulk density 30-45 lb/ft3 (480-720 kg/m3)Particle Size No information availableParticle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity No information available.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Appearance Powder Odor Slight.Color Off-white Odor threshold No information available
Property Values Remarks • Method pH 9.0-10.5 4% solutionMelting point / freezing point Not applicableBoiling point / boiling range Not applicableFlash point Not applicableEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air No information available
Upper flammability limit: No data availableLower flammability limit: No data available
Vapor pressure No data availableVapor density No data availableRelative density 1.5Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity Not applicableDynamic viscosity Not applicable
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UGHS Page 4 / 8
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
Conditions to avoid None known based on information supplied.
Incompatible materials
Incompatible materials Strong oxidizing agents. Strong acids.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity100 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation None known.
Serious eye damage/eye irritation None known.
Respiratory or skin sensitization None known.
Germ cell mutagenicity None known.
Carcinogenicity None known.
Reproductive toxicity None known.
STOT - single exposure None known.
STOT - repeated exposure None known.
Aspiration hazard Not applicable.
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UGHS Page 5 / 8
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not Regulated
IATA Not Regulated
IMDG Not Regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
Section 15: REGULATORY INFORMATION
Regulatory information
National regulations
_____________________________________________________________________________________________
UGHS Page 6 / 8
Australia
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable
The Stockholm Convention on Persistent Organic Pollutants Not applicable
The Rotterdam Convention Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 15-Mar-2017
Revision Date 15-Mar-2017
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individuals
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
_____________________________________________________________________________________________
UGHS Page 7 / 8
_____________________________________________________________________________________________NDF00018 GageTrolÔ Revision Date 15-Mar-2017
or situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
_____________________________________________________________________________________________
UGHS Page 8 / 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
IDCIDE 20Synonyms
BIOCIDE ● DRILLING FLUID ADDITIVE ● WATER TREATMENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
IDCIDE-20Product name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Harmful if swallowed.H302Causes skin irritation.H315May cause an allergic skin reaction.H317Causes serious eye irritation.H319
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Acute Toxicity: Oral: Category 4Skin Corrosion/Irritation: Category 2Skin Sensitisation: Category 1Serious Eye Damage / Eye Irritation: Category 2A
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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IDCIDE-20PRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Storage statementsNone allocated.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.P301 + P312IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Specific treatment is advised - see first aid instructions.P321Rinse mouth.P330If skin irritation or rash occurs: Get medical advice/attention.P333 + P313Take off contaminated clothing and wash before re-use.P362
Response statements
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
18 to 25%55566-30-8 259-709-0TETRAKIS(HYDROXYMETHYL)PHOSPHONIUMSULPHATE(2:1)
Remainder7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.
Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities should be available.First aid facilities
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. May evolve carbon oxides, sulphuroxides and phosphates when heated to decomposition.
5.2 Special hazards arising from the substance or mixture
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
SDS Date: 16 Aug 2019
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IDCIDE-20PRODUCT NAME
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should haveappropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body Wear coveralls. In a laboratory situation, wear a laboratory coat.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
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IDCIDE-20PRODUCT NAME
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCOLOURLESS TO PALE YELLOW LIQUIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 100°CBoiling point< 0°CMelting pointAS FOR WATEREvaporation rate3.0 to 3.5pHNOT AVAILABLEVapour density1.08Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information> 60 % (Water)% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Harmful if swallowed.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
248 mg/kg (rat) > 2000 mg/kg (rat) 5.5 mg/L/4hrs (rat)TETRAKIS(HYDROXYMETHYL)PHOSPHONIUMSULPHATE(2:1)
Contact may result in irritation, redness, pain and rash.Skin
Additional ingredient toxicity values:
TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE(2:1) (55566-30-8)TDLo (oral) 650 mg/kg/13 weeks - intermittent (rat)
11.1 Information on toxicological effects
SDS Date: 16 Aug 2019
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IDCIDE-20PRODUCT NAME
Contact may result in irritation, lacrimation, pain and redness.Eye
May cause an allergic skin reaction. This product is not classified as a respiratory sensitiser.Sensitisation
Over exposure may result in respiratory irritation, nausea, dizziness, drowsiness and headache.STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
SDS Date: 16 Aug 2019
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IDCIDE-20PRODUCT NAME
12. ECOLOGICAL INFORMATION
12.1 Toxicity
75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):LC50 (Rainbow Trout) = 119 mg/L/96 hrLC50(Bluegill Sunfish) = 93 mg/L/ 96 hrEC50 (Daphnia Magna) = 19 mg/L/48 hrLC50 (Brown Shrimp) = 340 mg/L/96 hrLC50 (Mysid Shrimp ) = 9.5 mg/L/96 hrLC50 (Sheepshead Minnow) = 94 mg/L/96 hrLC50 (Jevenile Plaice) = 86 mg/L/96 hr
Waste Water managementEC50 (Activated Sludge) = 24 mg/L/3 hr
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarge quantities, contact the manufacturer/supplier for additional information. Prevent contamination of drainsand waterways as aquatic life may be threatened and environmental damage may result.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
SDS Date: 16 Aug 2019
Version No: 2.1ofPage 6 8
IDCIDE-20PRODUCT NAME
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Additional information
SDS Date: 16 Aug 2019
Version No: 2.1ofPage 7 8
IDCIDE-20PRODUCT NAME
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 16 Aug 2019
Version No: 2.1ofPage 8 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
JK - 161 LV ● LOW MOLECULAR WEIGHT PHPA ● PARTIALLY HYDROLYZED POLYACRYLAMIDE ●PHPA
Synonyms
ENCAPSULATING AGENT ● HIGH PERFORMANCE WBMUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
JK-161 LVProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>90%25085-02-3 607-529-1ACRYLAMIDE, SODIUM ACRYLATE COPOLYMER
Remainder7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
SDS Date: 03 Feb 2020
Revision No: 2ofPage 1 6
JK-161 LVPRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Acrylamide SWA [AUS] -- 0.03 -- --
No Biological Limit Value allocated.Biological limits
SDS Date: 03 Feb 2020
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JK-161 LVPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE GRANULAR SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.8Specific gravity10 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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JK-161 LVPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401).
Acute toxicity
Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.Skin
Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation. However, allergic reactions are possible.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
This product may contain trace amounts of residual acrylamide, which is classified as a probable humancarcinogen (IARC Group 2A). However, due to the very low levels present, adverse health effects are notanticipated with normal use.
Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
(10000 ppm test concentration) (EPA-821-R-02-012) Mysidopsis bahia = 48hr LC50 = 16.2 mg/L. Menidia beryllina = 48hr LC50 = 34.2 mg/L. Scophthalmus Maximus = 96hr LC50 > 1000 mg/L. Skeletonemia costatum = 72hr EC50 = 393 mg/L [NOEC = 118 mg/L] Acartia tonsa = 48 hr EC50 = 393 mg/L [NOEC = 112 mg/L] Corophium Volutator = 10 Day LC50 = 9338 mg/Kg [NOEC = 1000 mg/Kg
12.2 Persistence and degradabilityNot readily biodegradable (by OECD criteria).
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialBased on its structural properties, the polymer is not biologically available. Accumulation in organisms is not to be expected.
13. DISPOSAL CONSIDERATIONS
Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
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JK-161 LVPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
ACRYLIC - ACRYLAMIDE RESINS: These resins are generally of low toxicity. Toxicity increases withpresence of significant concentrations of acrylic - acrylamide monomers. These monomers havebeen linked with the development of skin sensitisation.
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 2ofPage 5 6
JK-161 LVPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 2ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
CALCINED MAGNESIA ● MAGNESIA ● MAGOXI16 / 27 - PRODUCT CODESynonyms
DRILLING FLUID ADDITIVE ● PH INDICATORUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
MAGNESIUM OXIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>94%1309-48-4 215-171-9MAGNESIUM OXIDE
<3.5%1305-78-8 215-138-9CALCIUM OXIDE
<2.5%7631-86-9 231-545-4SILICON DIOXIDE (SILICA, AMORPHOUS)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
SDS Date: 03 Feb 2020
Revision No: 3ofPage 1 6
MAGNESIUM OXIDEPRODUCT NAME
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve magnesium oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure product is adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium oxide SWA [AUS] -- 2 -- --Calcium oxide SWA [Proposed] -- 1 -- --
Fumed silica (respirable dust) SWA [AUS] -- 2 -- --
Magnesium oxide (fume) SWA [AUS] -- 10 -- --
SDS Date: 03 Feb 2020
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MAGNESIUM OXIDEPRODUCT NAME
Biological limitsNo biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE GRANULESAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point3600°CBoiling point2800°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density3.6 - 3.7Specific gravitySLIGHTLY SOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information0 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
SDS Date: 03 Feb 2020
Revision No: 3ofPage 3 6
MAGNESIUM OXIDEPRODUCT NAME
10.5 Incompatible materials
Incompatible (violently) with interhalogens (e.g. bromine pentafluoride, chlorine trifluoride) and phosphorus pentachloride. May igniteor explode when heated with aluminium powder. Also incompatible with acids (e.g. nitric acid) and dampness as material hydrates.
May evolve magnesium oxides when heated to decomposition.10.6 Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Based on available data, the classification criteria are not met.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
3160 mg/kg (rat) -- --SILICON DIOXIDE (SILICA, AMORPHOUS)
Contact may result in irritation, redness, rash and dermatitis.Skin
Contact may result in irritation, lacrimation, pain and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure. However, over exposure may result inirritation of the nose and throat, with coughing.
STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityThe methods for determining the biological degradability are not applicable to inorganic substances.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
For small amounts, cover with moist sand, vermiculite or similar to avoid dust hazard and dispose of to anapproved landfill site. Contact the manufacturer/supplier for additional information if disposing of largequantities (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 3ofPage 4 6
MAGNESIUM OXIDEPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 3ofPage 5 6
MAGNESIUM OXIDEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
Monoethylene Glycol (MEG)
SAFETY DATA SHEET
NDF00270 Revision Date 01-Mar-2019 Version 1.1
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING
1.1. Product identifier
Product Code NDF00270Product Name Monoethylene Glycol (MEG)
Contains Ethylene glycol
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use hydrate-control additive
Uses advised against No information available
1.3. Details of the supplier of the safety data sheet
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
1.4. Emergency telephone number
Emergency telephone number 1800 127 406 (Australia); +64 4 917 9888 (International)
Section 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008Acute toxicity - Oral Category 4 - (H302)Specific target organ toxicity (repeated exposure) Category 2 - (H373)
Classification according to Directive 67/548/EEC or 1999/45/ECFull text of R-phrases: see section 16
Hazard symbolsXn - Harmful
R-code(s)Xn;R22
2.2. Label elements Product identifier203-473-3Contains Ethylene glycol
Supplier Newpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
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_____________________________________________________________________________________________NDF00270 Monoethylene Glycol (MEG) Revision Date 01-Mar-2019
Signal wordWarning
Hazard statementsH302 - Harmful if swallowedH373 - May cause damage to organs through prolonged or repeated exposure
Precautionary Statements - EU (§28, 1272/2008)P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP314 - Get medical advice/attention if you feel unwellP501 - Dispose of contents/container to industrial incineration plant
2.3. Other hazards Harmful to aquatic life
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Chemical Name CAS No Weight-% Classification according toDirective 67/548/EEC or
1999/45/EC
Classificationaccording to
Regulation (EC) No.1272/2008 [CLP]
Ethylene glycol 107-21-1 100 Xn; R22 Acute Tox. 4 (H302)STOT RE 2 (H373)
Full text of R-phrases: see section 16
Full text of H- and EUH-phrases: see section 16
Section 4: FIRST AID MEASURES
4.1. Description of first aid measures
General advice If symptoms persist, call a physician. Do not breathe dust/fume/gas/mist/vapors/spray. Donot get in eyes, on skin, or on clothing.
Inhalation Remove to fresh air. Call a physician. If breathing is irregular or stopped, administerartificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouthresuscitation.
Skin contact Wash skin with soap and water. Remove contaminated clothing and shoes. Washcontaminated clothing before reuse. Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses andcontinue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptomspersist, call a physician.
Ingestion Rinse mouth. Drink plenty of water. If symptoms persist, call a physician. Do NOT inducevomiting.
Self-protection of the first aider Use personal protective equipment as required.
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4.2. Most important symptoms and effects, both acute and delayed
Symptoms No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES5.1. Extinguishing media
Suitable extinguishing mediaDry chemical, CO2, alcohol-resistant foam or water spray.
Unsuitable extinguishing mediaNo information available
5.2. Special hazards arising from the substance or mixture
Thermal decomposition can lead to release of irritating and toxic gases and vapors
Hazardous combustion productsCarbon oxides.
5.3. Advice for firefighters
Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautionsEnsure adequate ventilation, especially in confined areas. Keep people away from and upwind of spill/leak.
For emergency respondersIn the case of vapor formation use a respirator with an approved filter.
6.2. Environmental precautions
Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. SeeSection 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills.
Methods for cleaning up Use personal protective equipment as required. Use a non-combustible material likevermiculite or sand to soak up the product and place into a container for later disposal. Useclean non-sparking tools to collect absorbed material.
6.4. Reference to other sections
See section 13 for more information.
Section 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
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Advice on safe handlingWash contaminated clothing before reuse. Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly
_____________________________________________________________________________________________NDF00270 Monoethylene Glycol (MEG) Revision Date 01-Mar-2019
after handling.
General Hygiene ConsiderationsHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children.
7.3. Specific end use(s)
Risk Management Methods (RMM)The information required is contained in this Material Safety Data Sheet.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Chemical Name Australia EuropeanUnion
UnitedKingdom
France Spain Germany
Ethylene glycol 107-21-1
10 mg/m3
20 ppm52 mg/m3
40 ppm STEL104 mg/m3
STEL
TWA 20 ppmTWA 52 mg/m3
STEL 40 ppmSTEL 104
mg/m3
*
TWA: 10 mg/m3
TWA: 20 ppmTWA: 52 mg/m3
STEL: 40 ppmSTEL: 104
mg/m3
STEL: 30 mg/m3
Sk*
TWA: 20 ppmTWA: 52 mg/m3
STEL: 40 ppmSTEL: 104
mg/m3
*
TWA: 20 ppmTWA: 52 mg/m3
STEL: 40 ppmSTEL: 104
mg/m3
vía dérmica*
TWA: 10 ppmTWA: 26 mg/m3
Ceiling / Peak:20 ppm
Ceiling / Peak:52 mg/m3
Skin
Chemical Name Italy Portugal Netherlands Finland DenmarkEthylene glycol
107-21-1TWA: 20 ppm
TWA: 52 mg/m3
STEL: 40 ppmSTEL: 104 mg/m3
pelle*
TWA: 20 ppmTWA: 52 mg/m3
STEL: 40 ppmSTEL: 104 mg/m3
Ceiling: 100 mg/m3
P*
TWA: 52 mg/m3
TWA: 10 mg/m3
STEL: 104 mg/m3
H*
TWA: 20 ppmTWA: 50 mg/m3
STEL: 40 ppmSTEL: 100 mg/m3
iho*
TWA: 10 ppmTWA: 26 mg/m3
TWA: 10 mg/m3
H*
Chemical Name Austria Switzerland Poland Norway IrelandEthylene glycol
107-21-1TWA: 10 ppm
TWA: 26 mg/m3
STEL 20 ppmSTEL 52 mg/m3
H*
TWA: 10 ppmTWA: 26 mg/m3
STEL: 20 ppmSTEL: 52 mg/m3
H*
STEL: 50 mg/m3
TWA: 15 mg/m3TWA: 20 ppm
TWA: 52 mg/m3
STEL: 104 mg/m3
STEL: 40 ppmH*
TWA: 10 mg/m3
TWA: 20 ppmTWA: 52 mg/m3
STEL: 40 ppmSTEL: 30 mg/m3
STEL: 104 mg/m3
Sk*
Derived No Effect Level (DNEL) No information available
Predicted No Effect Concentration(PNEC)
No information available.
8.2. Exposure controls
Engineering Controls Ensure adequate ventilation, especially in confined areas.
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_____________________________________________________________________________________________NDF00270 Monoethylene Glycol (MEG) Revision Date 01-Mar-2019
Personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Suitable protective clothing.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties Physical state Liquid
Explosive properties Not an explosiveOxidizing properties Not applicable
9.2. Other information Softening point Not applicableMolecular weight No data availableVOC Content (%) Not applicableDensity No data availableBulk density Not applicable
Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal conditions.
Explosion data Sensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Appearance liquid Odor No information availableColor colorless Odor threshold No data available
Property Values Remarks • Method pH No data availableMelting point / freezing point -13 °C / 9 °FBoiling point / boiling range 196 °C / 385 °FFlash point 111 °C / 232 °FEvaporation rate 1Flammability (solid, gas) No data availableFlammability Limit in Air
Upper flammability limit: No data availableLower flammability limit: No data available
Vapor pressure No data availableVapor density No data availableSpecific Gravity 1.11Water solubility Miscible in waterSolubility(ies) No information availablePartition coefficient No data availableAutoignition temperature 400 °C / 752 °FDecomposition temperature No data availableKinematic viscosity No data availableDynamic viscosity No data available
No data available.
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10.3. Possibility of hazardous reactions
Possibility of Hazardous ReactionsNone under normal processing.
10.4. Conditions to avoid
Extremes of temperature and direct sunlight. Incompatible materials.
10.5. Incompatible materials
Strong oxidizing agents. Strong acids. Strong bases. Aldehydes. Aluminum.
10.6. Hazardous decomposition products
None under normal use conditions.
Section 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity
Product InformationProduct does not present an acute toxicity hazard based on known or supplied information.
National Regulations No data available.Eye contact No data available.Skin contact No data available.Ingestion No data available.
Unknown acute toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity.
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 500.00 mg/kg
Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50Ethylene glycol = 4700 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) = 9530 µL/kg
( Rabbit )
Skin corrosion/irritation None known.
Serious eye damage/eye irritation None known.
Sensitization None known.
Germ cell mutagenicity None known.
Carcinogenicity None known.
Reproductive toxicity None known.
STOT - single exposure None known.
STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure if swallowed.
Target Organ Effects kidney.
Aspiration hazard No information available.
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Section 12: ECOLOGICAL INFORMATION
12.1. Toxicity
0 % of the mixture consists of component(s) of unknown hazards to the aquatic environmentChemical Name Algae/aquatic plants Fish CrustaceaEthylene glycol 6500 - 13000: 96 h
Pseudokirchneriella subcapitatamg/L EC50
14 - 18: 96 h Oncorhynchus mykissmL/L LC50 static 40000 - 60000: 96h Pimephales promelas mg/L LC50static 16000: 96 h Poecilia reticulata
mg/L LC50 static 27540: 96 hLepomis macrochirus mg/L LC50static 40761: 96 h Oncorhynchus
mykiss mg/L LC50 static 41000: 96h Oncorhynchus mykiss mg/L LC50
46300: 48 h Daphnia magna mg/LEC50
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
.
Chemical Name Partition coefficientEthylene glycol -1.93
12.4. Mobility in soil
Mobility in soilNo information available.
12.5. Results of PBT and vPvB assessment
No information available.
12.6. Other adverse effects
No information available
Section 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from residues/unusedproducts
Disposal should be in accordance with applicable regional, national and local laws andregulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.
Other Information Waste codes should be assigned by the user based on the application for which the productwas used.
Section 14: TRANSPORT INFORMATION
IMDG 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated_____________________________________________________________________________________________
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14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Marine pollutant Not applicable14.6 Special Provisions None14.7 Transport in bulk according toAnnex II of MARPOL 73/78 and theIBC Code
No information available
RID 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None
ADR 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None
ICAO (air) 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None
IATA 14.1 UN/ID no Not regulated14.2 Proper shipping name Not regulated14.3 Hazard Class Not regulated14.4 Packing Group Not regulated14.5 Environmental hazard Not applicable14.6 Special Provisions None
HAZCHEM Emergency Action CodeNo information available
Section 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
AustraliaSee section 8 for national exposure control parameters
Carcinogenicity
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS Complies
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ENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
15.2. Chemical safety assessment
No information available
Section 16: OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3R22 - Harmful if swallowed
Full text of H-Statements referred to under section 3H302 - Harmful if swallowedH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Issue Date 18-May-2017
Revision Date 01-Mar-2019
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerAccording to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 onclassification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and1999/45/EC, and amending Regulation (EC) No 1907/2006, as amended by Regulation (EU) No. 2015/830.This document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources includingmanufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
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1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
MICRO FLOWSynonyms
DRILLING FLUID ADDITIVEUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
MICROFLOWProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Flammable liquid and vapour.H226May cause an allergic skin reaction.H317Causes serious eye irritation.H319May cause drowsiness or dizziness.H336
Hazard statements
Pictograms
Physical Hazards
Flammable Liquids: Category 3
Health Hazards
Skin Sensitisation: Category 1BSerious Eye Damage / Eye Irritation: Category 2ASpecific Target Organ Toxicity (Single Exposure): Category 3 (Narcotic Effects)
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
SDS Date: 29 Jan 2020
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MICROFLOWPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store in a well-ventilated place. Keep cool. Keep container tightly closed.P403 + P233 + P235Store locked up.P405
Storage statements
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.P303 + P361 + P353IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Call a POISON CENTER or doctor/physician if you feel unwell.P312Specific treatment is advised - see first aid instructions.P321If skin irritation or rash occurs: Get medical advice/attention.P333 + P313If eye irritation persists: Get medical advice/attention.P337 + P313Wash contaminated clothing before reuse.P363In case of fire: Use appropriate media for extinction.P370 + P378
Response statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.P210Keep container tightly closed.P233Ground/bond container and receiving equipment.P240Use explosion-proof electrical/ventilating/lighting equipment.P241Take precautionary measures against static discharge.P243Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
20 to 60%68647-72-3 614-678-6SWEET ORANGE OIL
15 to 50%67-63-0 200-661-7ISOPROPYL ALCOHOL
Terpenes (Sweet Orange Oil) may appear as CAS# 94266-47-4.Ingredient Notes
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities should be available.First aid facilities
Irritating to the eyes. Vapours may cause drowsiness and dizziness.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
SDS Date: 29 Jan 2020
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MICROFLOWPRODUCT NAME
Flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. Eliminate all ignition sources includingcigarettes, open flames, spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones, etc when handling. Earthcontainers when dispensing fluids.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
●3Y●3 Alcohol Resistant Foam is the preferred firefighting medium but, if it is not available, normal foam can be used.Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Large storage areas should bebunded and have appropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Isopropyl alcohol SWA [AUS] 400 983 500 1230
Biological limits
Ingredient Determinant BEISampling Time
40 mg/LEnd of shift atend of workweek
Acetone in urineISOPROPYL ALCOHOL
Reference: ACGIH Biological Exposure Indices
SDS Date: 29 Jan 2020
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MICROFLOWPRODUCT NAME
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear nitrile or neoprene gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilatedareas. Vapours are heavier than air and may travel some distance to an ignition source and flash back.Maintain vapour levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCLEAR TO OPAQUE MILKY WHITE LIQUIDAppearanceCITRUS ODOUROdourFLAMMABLEFlammability25°CFlash point154.4°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.917 - 0.977Specific gravitySOLUBLESolubility (water)18 mm Hg @ 20°CVapour pressure6.1 %Upper explosion limit0.7 %Lower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information55 - 75 %% Volatiles
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), metals, heat and ignition sources.
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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MICROFLOWPRODUCT NAME
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
SDS Date: 29 Jan 2020
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MICROFLOWPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
May be harmful if swallowed. Oral Toxicity: An oral LD50 in mice of 3600 mg/kg has been reported forisopropanol.
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 2000 mg/kg (rat)(NICNAS)
> 2000 mg/kg (rat)(NICNAS)
> 20 mg/L (rat)(NICNAS)
ISOPROPYL ALCOHOL
Not classified as a skin irritant. Prolonged or repeated contact may result in irritation, rash and dermatitis.Skin
Causes serious eye irritation. Contact may result in irritation, lacrimation, pain and redness.Eye
May cause an allergic skin reaction. This product is not classified as a respiratory sensitiser.Sensitisation
Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposuremay result in nausea, dizziness and drowsiness.
STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure. However, repeated exposure to somesolvents have been reported to cause adverse effects to the central nervous system (CNS), liver and kidney.
STOT - repeatedexposure
Not classified as a reproductive toxin. Insufficient data available to classify as a reproductive toxin.Reproductive
Isopropyl alcohol is not classifiable as to its carcinogenicity to humans (IARC Group 3).Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Not expected to be dangerous to the aquatic environment.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
Relatively volatile and would therefore readily evaporate from dry soil and surfaces.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information if disposing of large quantities (if required).Prevent contamination of drains and waterways as aquatic life may be threatened and environmentaldamage may result.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
SDS Date: 29 Jan 2020
Revision No: 3ofPage 6 8
MICROFLOWPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
III
3 3
III III
314.3 Transporthazard class
14.4 Packing Group
FLAMMABLE LIQUID, N.O.S.(Contains isopropyl alcohol)
1993
FLAMMABLE LIQUID, N.O.S.(Contains isopropyl alcohol)
1993 1993
FLAMMABLE LIQUID, N.O.S.(Contains isopropyl alcohol)
14.1 UN Number
14.2 ProperShipping Name
Not a Marine Pollutant
14.5 Environmental hazards
●3YHazchem code
F-E, S̲-̲E̲EmS
3A1GTEPG
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 29 Jan 2020
Revision No: 3ofPage 7 8
MICROFLOWPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 29 Jan 2020
Revision No: 3ofPage 8 8
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
NDFT 376 ● NDFT 377Synonyms
LOST CIRCULATION MATERIALUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
DYNAFIBER (TM) AP (F, M, C)Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%9004-34-6 232-674-9ORGANIC FIBRE(S)
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.
Ingestion
None allocated.First aid facilities
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 1 6
DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate ventilation systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --
Biological limitsNo biological limit values have been entered for this product.
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 2 6
DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 to 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), heat and ignition sources.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 3 6
DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)
ORGANIC FIBRE(S)
Not classified as a skin irritant. Skin irritation is not anticipated under normal conditions of use.Skin
Not classified as an eye irritant. Eye irritation is not anticipated under normal conditions of use.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Reuse or recycle where possible. Alternatively, ensure product is covered with moist soil to prevent dustgeneration and dispose of to an approved landfill site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 4 6
DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).
COMBUSTIBLE - EXPLOSIVE CARBONACEOUS DUST: Carbonaceous/organic dusts have thepotential, with dispersion, to present an explosion hazard if an ignition source exists. All equipmentused to handle, transfer or store this product MUST BE cleaned thoroughly prior to cutting, welding,drilling or exposure to any other form of heat or ignition sources. If bulk stored, containers should beventilated on a routine basis to avoid vapour accumulation (where applicable, eg for flocculants).
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 5 6
DYNAFIBER (TM) AP (F, M, C)PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 26 Aug 2019
Version No: 2.1ofPage 6 6
NewPacÔÔÔÔÔ LV
SAFETY DATA SHEET
Issue Date 02-Aug-2017 Revision Date 25-Nov-2020 Version 1.1
1. Identification 1
1.1. Product identifier
Product Code NDF00012
Product Name NewPacÔ LV
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use filtration control agent
Uses advised against No information available
1.3. Details of the supplier of the safety data sheet
For further information, please contact Contact Point Telephone: + 39 06 8856111
Fax: +39 06 8889363 Website: www.newpark.com
E-mail address [email protected] 1.4. Emergency telephone number
Emergency Telephone - §45 - (EC)1272/2008 Europe 112 Austria +(43)-13649237 France +(33)-975181407 Germany 0800-181-7059; +(49)- 69643508409 Hungary +(36)-18088425 Italy 800-789-767; +(39)-0245557031
Milano 24/24 Ospedale Niguarda Ca'grande Piazza ospedale maggiore 3 +39 0266101029
Roma 24/24 Policlinico Gemelli Largo Agostino Gemelli 8 +39 063054343
Netherlands +(31)-858880596 Romania (+40)-37-6300026 Spain 900-868538; +(34)-931768545 Switzerland 145; (+41) 435082011 United Kingdom +(44)-870-8200418
SupplierNewpark Drilling Fluids Via Salaria 1313/C 00138 ROMA (Italy)
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
2. Hazard(s) identification
2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]
2.2. Label elements This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP] Hazard statements This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]
2.3. Other hazards This substance does not meet the PBT/vPvB criteria of REACH, annex XIIIMay form combustible dust concentrations in air
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
The product contains no substances which at their given concentration, are considered to be hazardous to health
Full text of H- and EUH-phrases: see section 16
4. First-aid measures
4.1. Description of first aid measures
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin contact Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician.
Ingestion Clean mouth with water and drink afterwards plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
5. Fire-fighting measures 5.1. Extinguishing media
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
Avoid generation of dust. Fine dust dispersed in air may ignite.
Hazardous combustion products Carbon oxides. Sodium oxides.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
7. Handling and storage
7.1. Precautions for safe handling
Advice on safe handling Ensure adequate ventilation. Avoid generation of dust. Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed in a dry and well-ventilated place.
7.3. Specific end use(s)
_____________________________________________________________________________________________
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Identified Uses
_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
8. Exposure controls/personal protection
8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Derived No Effect Level (DNEL) No information available.
Predicted No Effect Concentration (PNEC)
No information available.
8.2. Exposure controls
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Use eye protection according to EN 166, designed to protect against spray mists.
Skin and body protection Wear suitable protective clothing. (EN 340).
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. (EN 136, EN 140, EN 141, EN 143, EN 149, EN 405).
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls No information available.
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state Solid Appearance Powder Color White to Pale yellow Odor Odorless. Odor threshold No information available
Property Values Remarks • Method pH 6.0 - 8.5 0.5% solution Melting point / freezing point No data available Boiling point / boiling range No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limit in Air No data available
Upper flammability limit: Lower flammability limit:
Vapor pressure No data available Vapor density No data available Relative density 1.6 _____________________________________________________________________________________________
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_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Explosive properties Fine dust dispersed in air, in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard
Oxidizing properties Not applicable
9.2. Other information Softening point No information available Molecular weight No information available VOC Content (%) No information available Liquid Density No information available Bulk density No information available
10. Stability and reactivity
10.1. Reactivity
Reactivity Not reactive under normal conditions.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid dust formation.
10.5. Incompatible materials
Incompatible materials Strong oxidizing agents.
10.6. Hazardous decomposition products
Hazardous Decomposition Products None known based on information supplied.
11. Toxicological information
11.1. Information on toxicological effects
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Water solubility Soluble in water Solubility(ies) No data available Partition coefficient No data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity Not applicable Dynamic viscosity
_____________________________________________________________________________________________
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Not applicable
_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available.
Information on toxicological effects
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 13,636.40 mg/kg
Unknown acute toxicity 90.6 % of the mixture consists of ingredient(s) of unknown toxicity. 0.6 % of the mixture consists of ingredient(s) of unknown acute oral toxicity. 90.6 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity. 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas). 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor). 90.6 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist).
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitization No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard Not applicable.
12. Ecological information
12.1. Toxicity
Ecotoxicity
Unknown Aquatic Toxicity Contains 0.6 % of components with unknown hazards to the aquatic environment.
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
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_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Bioaccumulation No information available.
12.4. Mobility in soil
Mobility in soil No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects No information available.
13. Disposal considerations
13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
Waste codes / waste designations according to EWC / AVV
Waste codes should be assigned by the user based on the application for which the product was used.
14. Transport information
IMDG 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Marine pollutant Not applicable 14.6 Special Provisions None 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
No information available
RID 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None
ADR 14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None
IATA Not Regulated
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14.1 UN/ID no Not Regulated 14.2 Proper shipping name Not Regulated 14.3 Hazard Class Not Regulated 14.4 Packing Group Not Regulated 14.5 Environmental hazard Not applicable 14.6 Special Provisions None
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
Germany Water hazard class (WGK) slightly hazardous to water (WGK 1)
Italy -D. LGs. 81/2008 (single text on the protection of health and safety in the workplace) and subsequent amendments and Directive 2009/161/EU-assessment of chemical risk under title IX-Legislative Decree 3 April 2006, no 152 (environmental standards)-"Seveso III Directive" – Legislative Decree of 26 June 2015, n° 105 (Implementation of the Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
Authorizations and/or restrictions on use:This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
Persistent Organic PollutantsNot applicable
Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable
International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies NZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances
_____________________________________________________________________________________________
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_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
15.2. Chemical safety assessment
Chemical Safety Report None
16. Other information
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend SVHC: Substances of Very High Concern for Authorization:
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Classification procedure Classification according to Regulation (EC) No. 1272/2008 [CLP] Method Used Acute oral toxicity Calculation method Acute dermal toxicity Calculation method Acute inhalation toxicity - gas Calculation method Acute inhalation toxicity - vapor Calculation method Acute inhalation toxicity - dust/mist Calculation method Skin corrosion/irritation Calculation method Serious eye damage/eye irritation Calculation method Respiratory sensitization Calculation method Skin sensitization Calculation method Mutagenicity Calculation method Carcinogenicity Calculation method Reproductive toxicity Calculation method STOT - single exposure Calculation method STOT - repeated exposure Calculation method Acute aquatic toxicity Calculation method Chronic aquatic toxicity Calculation method Aspiration hazard Calculation method Health hazards not otherwise classified (HHNOC) Calculation method
Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine's PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID)
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *
_____________________________________________________________________________________________
Page 9 / 10
Skin designation
_____________________________________________________________________________________________ NDF00012 - NewPacÔÔÔÔÔ LV Revision Date 25-Nov-2020
Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set RTECS (Registry of Toxic Effects of Chemical Substances) World Health Organization
Issue Date 02-Aug-2017
Revision Date 25-Nov-2020
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
DisclaimerAccording to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006, as amended by Regulation (EU) No. 2015/830.This document is provided as an information resource relating exclusively to the product or material described herein. The information contained herein may not be applicable to other products/ materials or processes and may not be valid when this product/material is used in combination with any other product/material or process. The information provided in this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources including manufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated date of preparation. As the conditions under which this product could be used will vary and may not be within the control of Newpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individuals or situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state, provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 10 / 10
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
NEWZAN D ● XANTHAN GUM (BIOPOLYMER) ● XANTHAN GUM (P)Synonyms
DRILLING FLUID ADDITIVE ● VISCOSITY MODIFIERUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (NEW ZEALAND) LTDSupplier name
PO BOX 6092, Moturoa, New Plymouth, TARANAKI, 4310, NEW ZEALANDAddress
0204 0234 734Telephone
+61 8941 08299Fax
0800 243 622 (New Zealand); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
NEWZAN DProduct name
2. HAZARDS IDENTIFICATION
NON HAZARDOUS ACCORDING TO NZ ENVIRONMENTAL PROTECTION AUTHORITY CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>90%11138-66-2 234-394-2XANTHAN GUM
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact the National Poisons Centre on 0800 764 766 (0800 POISON) or +643 479 7248 or adoctor (at once). If swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 11 Feb 2020
Revision No: 2ofPage 1 6
NEWZAN DPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.
5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
SDS Date: 11 Feb 2020
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NEWZAN DPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate)respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesLIGHT BEIGE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.5Specific gravityMISCIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
SDS Date: 11 Feb 2020
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NEWZAN DPRODUCT NAME
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.
Acute toxicity
Not classified as a skin irritant. Contact may result in mild irritation.Skin
Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
12.5 Other adverse effects
No information provided.
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (NZS 5433) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD ACCORDING TO LAND TRANSPORT RULE: DANGEROUS GOODS 2005; NZS5433:2012, UN, IMDG OR IATA
15. REGULATORY INFORMATION
SDS Date: 11 Feb 2020
Revision No: 2ofPage 4 6
NEWZAN DPRODUCT NAME
NEW ZEALAND: NZIoC (New Zealand Inventory of Chemicals)All components are listed on the NZIoC inventory, or are exempt.
Inventory listings
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Approval code NON HAZARDOUS
NON HAZARDOUSGroup standard
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCCID Chemical Classification and Information Database (HSNO)CNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)EPA Environmental Protection Authority [New Zealand]GHS Globally Harmonized SystemHSNO Hazardous Substances and New OrganismsIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)TLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 11 Feb 2020
Revision No: 2ofPage 5 6
NEWZAN DPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 11 Feb 2020
Revision No: 2ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
KCL ● MURIATE OF POTASH ● POTASH ● SYLVITESynonyms
DRILLING FLUID ADDITIVE ● FERTILISER ● INHIBITORUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
POTASSIUM CHLORIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>97%7447-40-7 231-211-8POTASSIUM CHLORIDE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 03 Feb 2020
Revision No: 3ofPage 1 6
POTASSIUM CHLORIDEPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
SDS Date: 03 Feb 2020
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POTASSIUM CHLORIDEPRODUCT NAME
PPE
Eye / Face At high dust levels, wear dust-proof goggles.
Hands With prolonged use, wear PVC or rubber or cotton gloves.
Body With prolonged use, wear coveralls.
Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point773°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.0Specific gravity340 g/L @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Potassium chloride is not in general strongly reactive. Violent reaction with BrF3 and with a mixture of sulfuric acid potassiumpermanganate mixture (NTP, 1992). Reacts with concentrated sulfuric acid to generate fumes of hydrogen chloride. Incompatible withoxidising agents.
May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization will not occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
May be harmful if swallowed in large quantities. Additional toxicity data for potassium chloride:LD50 (Intraperitoneal): 620 mg/kg (mouse)LD50 (Intravenous): 117 mg/kg (mouse)LDLo (Ingestion): 20 mg/kg (man)LDLo (Intraperitoneal): 900 mg/kg (guinea pig)LDLo (Intravenous): 77 mg/kg (guinea pig)
Acute toxicity
11.1 Information on toxicological effects
SDS Date: 03 Feb 2020
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POTASSIUM CHLORIDEPRODUCT NAME
LDLo (Subcutaneous): 2120 mg/kg (frog)TDLo (Ingestion): 60 mg/kg/days (woman)
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
2600 mg/kg (rat) -- --POTASSIUM CHLORIDE
Not classified as a skin irritant. Contact may result in mild irritation and rash.Skin
Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, andpotassium is rapidly excreted by the body, however this product does have the potential to causecardiovascular disorders.
STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictaluruspunctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronicreproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronicaquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerationsthe background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for furtherinvestigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulationpotential for the substance.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No impact if small amount is released to the soil.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialDoes not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 3ofPage 4 6
POTASSIUM CHLORIDEPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 3ofPage 5 6
POTASSIUM CHLORIDEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
QUICKSEALSynonyms
DRILLING FLUID ADDITIVEUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
QUICKSEAL (F,M,C)Product name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%9004-34-6 232-674-9CELLULOSE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
None allocated.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 03 Feb 2020
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QUICKSEAL (F,M,C)PRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.Difficult to extinguish once burning.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach ofchildren.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --
No Biological Limit Value allocated.Biological limits
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
SDS Date: 03 Feb 2020
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QUICKSEAL (F,M,C)PRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesYELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 - 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrateand sodium nitrite.
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
SDS Date: 03 Feb 2020
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QUICKSEAL (F,M,C)PRODUCT NAME
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats).Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats).Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat).
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)
CELLULOSE
Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.Skin
Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness andlacrimation.
Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
Additional ingredient toxicity values:
CELLULOSE (9004-34-6)LD50 (intraperitoneal) > 31600 mg/kg (rat)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Low toxicity to aquatic organisms.
12.2 Persistence and degradabilityThis product is readily biodegradable.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Reuse where possible. No special precautions are normally required when handling this product.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 3ofPage 4 6
QUICKSEAL (F,M,C)PRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 3ofPage 5 6
QUICKSEAL (F,M,C)PRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
BUTCHERS SALT ● FLOSSY SALT ● HALITE ● NACL ● SODIUM CHLORIDESynonym(s)
CHLORIDE SOURCE ● DRILLING FLUID ADDITIVEUse(s)1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
SALTProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>98%7647-14-5 231-598-3SODIUM CHLORIDE
<0.8%- -INORGANIC SALT(S)
<0.8%7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
None allocated.First aid facilities
SDS Date: 10 Mar 2017
Version No: 2.2ofPage 1 6
SALTPRODUCT NAME
Under normal conditions of use, adverse health effects are not anticipated. This product is generally considered to be of low toxicity.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate fire protection systems.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
No exposure standards have been entered for this product.
Biological limits
No biological limit values have been entered for this product.
SDS Date: 10 Mar 2017
Version No: 2.2ofPage 2 6
SALTPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesTRANSLUCENT TO WHITE GRANULES OR POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point801°CMelting pointNOT AVAILABLEEvaporation rate7 (1 % Solution)pHNOT AVAILABLEVapour density2.163Specific gravity357 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid) and alkalis (e.g. sodium hydroxide).
May evolve toxic gases when strongly heated.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
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SALTPRODUCT NAME
11. TOXICOLOGICAL INFORMATION
May be harmful if swallowed in large quantities. Repeated ingestion of excessive amounts of sodiumchloride may cause disturbance of body electrolyte and fluid balance. LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Skin): > 10000 mg/kg (rabbit)
Acute toxicity
Information available for the ingredient(s):
IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity
(LC50)
3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hourSODIUM CHLORIDE
Contact may result in mild irritation and rash.Skin
Contact may cause discomfort, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
No relevant or reliable studies were identified.Reproductive
No evidence of carcinogenic effects.Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
Additional ingredient toxicity value(s):
SODIUM CHLORIDE (7647-14-5)LD50 (intraperitoneal) 2602 mg/kg (mouse)LD50 (intravenous) 645 mg/kg (mouse)LD50 (subcutaneous) 3000 mg/kg (mouse)LDLo (intravenous) 300 mg/kg (guinea pig)LDLo (oral) 8000 mg/kg (rabbit)LDLo (subcutaneous) 2160 mg/kg (guinea pig)TDLo (oral) 12357 mg/kg (human)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic Toxicity: LC50 (water flea) is 2122 mg/L/48 hours; LC50 (fathead minnow) is 6.57 g/L/96 hours.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
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SALTPRODUCT NAME
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
None allocated.Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
None allocated.Safety phrases
None allocated.Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 10 Mar 2017
Version No: 2.2ofPage 5 6
SALTPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Prepared by
[ End of SDS ]
SDS Date: 10 Mar 2017
Version No: 2.2ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
DISODIUM DIHYDROGEN PYROPHOSPHATE ● DISODIUM PYROPHOSPHATESynonyms
ACIDIFIER ● BUFFERING AGENTUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
SAPPProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
100%7758-16-9 231-835-0DISODIUM PYROPHOSPHATE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 03 Feb 2020
Revision No: 3ofPage 1 6
SAPPPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases (phosphorus oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Nuisance dust SWA [AUS] -- 10 -- --
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
SDS Date: 03 Feb 2020
Revision No: 3ofPage 2 6
SAPPPRODUCT NAME
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point> 600°CMelting pointNOT AVAILABLEEvaporation rate4 - 5 (10% Solution)pHNOT AVAILABLEVapour density1.35 - 1.41Specific gravity119 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases (phosphorus oxides) when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.Acute toxicity
11.1 Information on toxicological effects
SDS Date: 03 Feb 2020
Revision No: 3ofPage 3 6
SAPPPRODUCT NAME
Ingestion of large quantities may also result in serious disturbances in calcium metabolism.
LD50 (Ingestion): 2650 mg/kg (mouse)LD50 (Intraperitoneal): 1 g/kg (mouse)LD50 (Intravenous): 59 mg/kg (mouse)LD50 (Subcutaneous): 480 mg/kg (mouse)
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
2650 mg/kg (mouse) > 2000 mg/kg (rat) > 0.58 mg/L/4hrs (rat)DISODIUM PYROPHOSPHATE
Low to moderate irritant. Prolonged or repeated contact may result in irritation and rash.Skin
Low to moderate irritant. Contact may result in mild irritation, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.STOT - singleexposure
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
Additional ingredient toxicity values:
DISODIUM PYROPHOSPHATE (7758-16-9)LD50 (intraperitoneal) 1 g/kg (mouse)LD50 (intravenous) 59 mg/kg (mouse)LD50 (subcutaneous) 480 mg/kg (mouse)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialDoes not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 3ofPage 4 6
SAPPPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 03 Feb 2020
Revision No: 3ofPage 5 6
SAPPPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
SODA ASH DENSE ● SODIUM CARBONATESynonyms
DRILLING AIDUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
SODA ASHProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word DANGER
Avoid breathing dust/fume/gas/mist/vapours/spray.P261Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statements
Causes serious eye damage.H318May cause respiratory irritation.H335
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Toxicity (Single Exposure): Category 3 (Respiratory Irritation)
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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SODA ASHPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statements
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310
Response statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>97%497-19-8 207-838-8SODIUM CARBONATE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities should be available.First aid facilities
Irritating to the eyes and skin.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
SDS Date: 05 Feb 2020
Revision No: 2.5ofPage 2 6
SODA ASHPRODUCT NAME
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Carbonate (total dust) SWA [AUS] -- 10 -- --
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpH
SDS Date: 05 Feb 2020
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SODA ASHPRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT AVAILABLEVapour density2.533Specific gravity170 g/LSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
May be harmful if swallowed.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 2000 mg/kg (rat)(NICNAS)
> 2000 mg/kg (rat)(NICNAS)
> 2000 mg/m³ (rat)(NICNAS)
SODIUM CARBONATE
Contact may result in irritation, redness, rash and dermatitis.Skin
Contact may result in irritation, lacrimation, pain, redness and possible permanent damage.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may resultin breathing difficulties.
STOT - singleexposure
Not classified as causing organ damage from repeated exposure. Carbonate ions are neutralised underphysiological conditions to form bicarbonate ions and/or carbon dioxide, which are major products of allhuman metabolic activities; therefore, systemic toxicity is not expected.
STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
Additional ingredient toxicity values:
SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)
11.1 Information on toxicological effects
SDS Date: 05 Feb 2020
Revision No: 2.5ofPage 4 6
SODA ASHPRODUCT NAME
Not classified as causing aspiration.Aspiration
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Fishes, Lepomis macrochirus, LC50, 96 h, 300 mg/l. Crustaceans, Ceriodaphnia dubia, EC50, 48 h, 200 - 227 mg/l.
12.2 Persistence and degradabilityNot applicable for inorganic substances. The methods for determining the biological degradability are not applicable to inorganicsubstances.
12.4 Mobility in soil
If sodium carbonate is emitted to soil it can escape to atmosphere as carbon dioxide, precipitate as a metal carbonate, formcomplexes or stay in solution.
WATER: If released to waterways, alkaline products may change the pH of the waterway. Fish will die if the pH reaches 10-11(goldfish 10.9, bluegill 10.5). SOIL: May leach to groundwater with toxic effects on aquatic life as above. ATMOSPHERE: Notexpected to reside in the atmosphere. Drops or particles released to atmosphere should be removed by gravity and/or be rained out.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNot expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Collect without generating dust. Place in clean, sealed containers and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
SDS Date: 05 Feb 2020
Revision No: 2.5ofPage 5 6
SODA ASHPRODUCT NAME
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
[ End of SDS ]
SDS Date: 05 Feb 2020
Revision No: 2.5ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
BAKING SODA ● BICARBONATE OF SODA ● CARBONIC ACID, MONOSODIUM SALT ● MONOSODIUMCARBONATE ● SODIUM ACID CARBONATE ● SODIUM HYDROGEN CARBONATE
Synonyms
PH CONTROLUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
SODIUM BICARBONATEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>99%144-55-8 205-633-8SODIUM BICARBONATE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).Ingestion
Eye wash facilities should be available.First aid facilities
No adverse health effects expected if the product is handled in accordance with the SDS and the product label.4.2 Most important symptoms and effects, both acute and delayed
SDS Date: 03 Feb 2020
Revision No: 3ofPage 1 6
SODIUM BICARBONATEPRODUCT NAME
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure packages are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Bicarbonate (total dust) SWA [AUS] -- 10 -- --
Biological limitsNo biological limit values have been entered for this product.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
SDS Date: 03 Feb 2020
Revision No: 3ofPage 2 6
SODIUM BICARBONATEPRODUCT NAME
PPE
Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.
Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.
Body Not required under normal conditions of use.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point854°CMelting pointNOT AVAILABLEEvaporation rate8 (1% Solution)pHNOT AVAILABLEVapour density2.533Specific gravity170 g/L @ 25°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid).
May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. Sodium bicarbonate can neutralise the gastric juices in the stomach. Duringneutralisation, carbon dioxide gas is evolved and may cause stretching of the stomach, and with very largedoses possible damage or rupture.
LD50 (Ingestion): 3360 mg/kg (mouse)LC50 (inhalation): 4.74 mg/L (rat)
Acute toxicity
11.1 Information on toxicological effects
SDS Date: 03 Feb 2020
Revision No: 3ofPage 3 6
SODIUM BICARBONATEPRODUCT NAME
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 4000 mg/kg (rat) -- > 4.74 mg/L/4.5hrs (rat)SODIUM BICARBONATE
Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.Skin
Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure.STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
12. ECOLOGICAL INFORMATION
12.1 Toxicity
LC50 (Oncorhynchus mykiss) = 7.700 mg/l/96hrs.LC50 (Lepomis macrochirus) = 7.100 mg/l/96hrs.EC50 (Crustaceans, Daphnia magna) = 4.100 mg/l/48hrsLOEC (Crustaceans, Daphnia magna) = 3.100 mg/l/48hrs.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
High mobility in water and soil/sediments.
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.5 Other adverse effects
12.3 Bioaccumulative potentialDoes not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Dispose of to an approved landfill or waste processing site. Contact the manufacturer/supplier for additionalinformation (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
SDS Date: 03 Feb 2020
Revision No: 3ofPage 4 6
SODIUM BICARBONATEPRODUCT NAME
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
Additional information
SDS Date: 03 Feb 2020
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SODIUM BICARBONATEPRODUCT NAME
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
SODIUM SULFITESynonyms
ANTIOXIDANT ● FOOD PRESERVATIVE ● LABORATORY REAGENT ● PAPER INDUSTRY ●PHOTOGRAPHIC DEVELOPER ● REDUCING AGENT ● WATER TREATMENT
Uses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
SODIUM SULPHITEProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word DANGER
Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Wear protective gloves/protective clothing/eye protection/face protection/hearing protection.P280
Prevention statements
Contact with acids liberates toxic gas.AUH031Harmful if swallowed.H302Causes serious eye damage.H318
Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Acute Toxicity: Oral: Category 4Serious Eye Damage / Eye Irritation: Category 1Contact with acids liberates toxic gas.
Environmental Hazards
Not classified as an Environmental Hazard
2.1 Classification of the substance or mixture
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SODIUM SULPHITEPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
Storage statementsNone allocated.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTRE or doctor/physician.P310Rinse mouth.P330
Response statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>97%7757-83-7 231-821-4SODIUM SULPHITE
<2.5%7757-82-6 231-820-9SODIUM SULPHATE
<0.1%497-19-8 207-838-8SODIUM CARBONATE
<0.1%7732-18-5 231-791-2WATER
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgenthospital treatment is likely to be needed. If swallowed, do not induce vomiting.
Ingestion
Eye wash facilities and safety shower are recommended.First aid facilities
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve sulphur oxides and sodium oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
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SODIUM SULPHITEPRODUCT NAME
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Sodium Carbonate (total dust) SWA [AUS] -- 10 -- --
Biological limits
No biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aFull-face Class P3 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE CRYSTALLINE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammability
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SODIUM SULPHITEPRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5pHNOT AVAILABLEVapour density2.6Relative densitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources. Avoid exposure to air and moisture. Sensitive to air and moisture.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid). Strong reducing agent.
May evolve sulphur oxides and sodium oxides when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityContact with acids liberates toxic gas.
11. TOXICOLOGICAL INFORMATION
Harmful if swallowed.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
820 mg/kg (mouse);3560 mg/kg (rat)
> 2000 mg/kg (rat) > 5500 mg/m3/4hrs (rat)SODIUM SULPHITE
5989 mg/kg (mouse) -- --SODIUM SULPHATE
> 2000 mg/kg (rat)(AICIS)
> 2000 mg/kg (rat)(AICIS)
> 2000 mg/m³ (rat)(AICIS)
SODIUM CARBONATE
11.1 Information on toxicological effects
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SODIUM SULPHITEPRODUCT NAME
Contact may result in irritation, redness, rash and dermatitis.Skin
Contact may result in irritation, lacrimation, pain, redness and possible serious eye damage.Eye
Some individuals are hypersensitive to sulphites and may experience adverse reactions following exposure.Individuals known to be hypersensitive or with existing respiratory problems (eg asthma) are advised to avoidexposure.
Sensitisation
Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing.STOT - singleexposure
Not classified as causing aspiration.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Not classified as a reproductive toxin.Reproductive
Not classified as a carcinogen.Carcinogenicity
Not classified as a mutagen.Mutagenicity
Additional ingredient toxicity values:
SODIUM SULPHITE (7757-83-7)LD50 (intraperitoneal) 950 mg/kg (mouse)LD50 (intravenous) 175 mg/kg (mouse)LDLo (intravenous) 400 mg/kg (cat)LDLo (oral) 2825 mg/kg (rabbit)LDLo (subcutaneous) 600 mg/kg (rabbit)
SODIUM SULPHATE (7757-82-6)LD50 (intravenous) 1220 mg/kg (rabbit)LDLo (intravenous) 1220 mg/kg (mouse)TDLo (oral) 14 g/kg (mouse - 8-12 days pregnant)TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)
SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.
12.4 Mobility in soil
No information provided.
Avoid contamination of drains and waterways.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait untilreaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite(reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorbwith sand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewerwith large excess of water.
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
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SODIUM SULPHITEPRODUCT NAME
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)All components are listed on AIIC, or are exempt.
Inventory listings
Safe Work Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals (GHS Revision 7).
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for ahazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure.The best protection is to enclose operations and/or provide local exhaust ventilation at the site ofchemical release. Isolating operations can also reduce exposure. Using respirators or protectiveequipment is less effective than the controls mentioned above, but is sometimes necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
Additional information
SDS Date: 28 Apr 2021
Revision No: 3ofPage 6 7
SODIUM SULPHITEPRODUCT NAME
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
[ End of SDS ]
SDS Date: 28 Apr 2021
Revision No: 3ofPage 7 7
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
STRATA VANGUARDSynonyms
DRILLING FLUID ADDITIVEUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
STRATA-VANGUARDProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.
No information provided.2.3 Other hazards
2.1 Classification of the substance or mixture
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
<30%9004-34-6 232-674-9CELLULOSE
<15%68855-54-9 272-489-0DIATOMACEOUS EARTH, FLUX CALCINED
<10%8031-18-3 617-052-0FULLERS EARTH
<10%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)
<5%14464-46-1 238-455-4CRISTOBALITE
<2%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)
<1%1309-48-4 215-171-9MAGNESIUM OXIDE
<50%9003-55-8 618-370-21,3 BUTADIENE/STYRENE COPOLYMERS
<50%9003-18-3 618-357-12-PROPENENITRILE-1,3-BUTADIENE RUBBER
<50%9006-04-6 232-689-0NATURAL RUBBER
<50%9003-31-0 618-362-9POLYISOPRENE
<3%9002-88-4 618-339-3POLYETHYLENE
3.1 Substances / Mixtures
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STRATA-VANGUARDPRODUCT NAME
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
None allocated.First aid facilities
See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture
No fire or explosion hazard exists.5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
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STRATA-VANGUARDPRODUCT NAME
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Calcium carbonate (Limestone, Marble, Whiting) SWA [AUS] -- 10 -- --
Cellulose (paper fibre) (a) SWA [AUS] -- 10 -- --
Cristobalite SWA [AUS] -- 0.1 -- --
Magnesium oxide (fume) SWA [AUS] -- 10 -- --
Quartz (respirable dust) SWA [AUS] -- 0.1 -- --Quartz (respirable dust) SWA [Proposed] -- 0.05 -- --Quartz (respirable dust) WorkSafe VIC -- 0.05 -- --
Biological limitsNo biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aPowered Air Purifying Respirator (PAPR) with Class P3 (Particulate) filter or a Full-face Class P3(Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesTAN COLOURED POWDERAppearanceMILD ODOUROdourNON FLAMMABLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate6.3 (5% Suspension)pHNOT AVAILABLEVapour density2.1Specific gravityINSOLUBLESolubility (water)1 mm Hg @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
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STRATA-VANGUARDPRODUCT NAME
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid contact with incompatible substances.
10.5 Incompatible materials
Incompatible with acids (e.g. nitric acid). Also incompatible with oxygen difluoride, chlorine and trifluoride.
May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
Toxicity Data available for the ingredients:CRISTOBALITE (14464-46-1): TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)QUARTZ (SILICA CRYSTALLINE) (14808-60-7): LCLo (inhalation) 300 ug/m³/10 years (human) TCLo (inhalation) 16 000 000 particles/ft3/8 hours/17.9 years (human-fibrosis)CELLULOSE (9004-34-6): LC50 (inhalation) > 5800 mg/m³/4 hours (rat) LD50 (ingestion) > 5000 mg/kg (rat) LD50 (intraperitoneal) > 31600 mg/kg (rat) LD50 (skin) > 2000 mg/kg (rabbit)POLYETHYLENE (9002-88-4): LDLo (ingestion) 3000 mg/kg (rat)MAGNESIUM OXIDE (1309-48-4): TCLo (inhalation) 400 mg/kg (human)
Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
> 5000 mg/kg (rat) > 2000 mg/kg (rabbit) > 5800 mg/m³/4 hours(rat)
CELLULOSE
> 5000 mg/kg (rat) -- --LIMESTONE (CALCIUM CARBONATE)
Not classified as a skin irritant. Contact may result in mechanical irritation.Skin
Not classified as an eye irritant. Contact may result in mechanical irritation.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
No known effects from this product.STOT - singleexposure
No relevant or reliable studies were identified.Reproductive
Not classified as a carcinogen. Crystalline silica is classified as carcinogenic to humans (IARC Group 1).However, there is a body of evidence supporting the fact that increased cancer risk would be limited topeople already suffering from silicosis.
Carcinogenicity
No evidence of mutagenic effects.Mutagenicity
Additional ingredient toxicity values:
CELLULOSE (9004-34-6)LD50 (intraperitoneal) > 31600 mg/kg (rat)
CRISTOBALITE (14464-46-1)TCLo (inhalation) 16 mppcf/8hours/17.9 years (human-fibrosis)
POLYETHYLENE (9002-88-4)LDLo (oral) 3000 mg/kg (rat)
11.1 Information on toxicological effects
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STRATA-VANGUARDPRODUCT NAME
This product does not present an aspiration hazard.Aspiration
Not classified as causing organ damage from repeated exposure. Adverse health effects associated withsilica, such as the development of silicosis (lung fibrosis), is not anticipated unless prolonged and repeatedexposure to respirable silica quartz dust occurs.
STOT - repeatedexposure
12. ECOLOGICAL INFORMATION
12.1 Toxicity
This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.
12.2 Persistence and degradabilityNot applicable.
12.4 Mobility in soil
This product has low mobility in soil.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
16. OTHER INFORMATION
SDS Date: 03 Feb 2020
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STRATA-VANGUARDPRODUCT NAME
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
[ End of SDS ]
SDS Date: 03 Feb 2020
Revision No: 3ofPage 6 6
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
TEASynonym(s)
CHEMICAL INTERMEDIATE ● LABORATORY REAGENT ● SOLVENTUse(s)1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone number(s)
www.newpark.comWebsite
1.1 Product identifier
TRIETHANOLAMINEProduct name
2. HAZARDS IDENTIFICATION
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 Label elements
DANGERSignal word
Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Use only outdoors or in a well-ventilated area.P271Wear protective gloves/protective clothing/eye protection/face protection.P280
Prevention statement(s)
Causes skin irritation.H315Causes serious eye damage.H318May cause respiratory irritation.H335May cause damage to organs through prolonged or repeated exposure.H373
Hazard statement(s)
Pictogram(s)
Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Systemic Toxicity (Single Exposure): Category 3Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2
GHS classification(s)
2.1 Classification of the substance or mixture
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TRIETHANOLAMINEPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)
Store in a well-ventilated place. Keep container tightly closed.P403 + P233Store locked up.P405
Storage statement(s)
IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.P304 + P340IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.
P305 + P351 + P338
Immediately call a POISON CENTER or doctor/physician.P310Get medical advice/attention if you feel unwell.P314Specific treatment is advised - see first aid instructions.P321If skin irritation occurs: Get medical advice/ attention.P332 + P313Take off contaminated clothing and wash before re-use.P362
Response statement(s)
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>60%102-71-6 203-049-8TRIETHANOLAMINE
>=10 to <=30%111-42-2 203-868-0DIETHANOLAMINE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.
Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink.
Ingestion
Eye wash facilities and safety shower should be available.First aid facilities
Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.
5.3 Advice for firefighters
None allocated.
5.4 Hazchem code
Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media
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TRIETHANOLAMINEPRODUCT NAME
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.
6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.
6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Store as a Class C2 Combustible Liquid (AS1940).
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end use(s)
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Diethanolamine (h) SWA (AUS) 3 13 -- --
Triethanolamine SWA (AUS) -- 5 -- --
Biological limitsNo biological limit values have been entered for this product.
PPE
Eye / Face Wear splash-proof goggles.
Hands Wear PVC or rubber gloves.
Body Wear coveralls.
Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
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TRIETHANOLAMINEPRODUCT NAME
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesCLEAR LIQUIDAppearanceMILD AMMONIACAL ODOUROdourCLASS C2 COMBUSTIBLEFlammability190°C (cc)Flash point335°CBoiling point12°CMelting point< 0.01 (n-Butyl acetate = 1)Evaporation rate10.5 (1 % Solution)pH4.80 (Air = 1)Vapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)< 1 kPa @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperature450 mPa·s @ 25°CViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
9.2 Other information1.123Relative density
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), nitrites, heat and ignition sources. Also incompatiblewith organic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper,brass and aluminium.
May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products
Hazardous polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
May be harmful if swallowed, in contact with skin, and/or if inhaled.Acute toxicity
Information available for the ingredient(s):
IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity
(LC50)
2200 mg/kg (rabbit) > 20 mL/kg (rabbit) --TRIETHANOLAMINE
620 uL/kg (rat) 7640 uL/kg (rabbit) --DIETHANOLAMINE
11.1 Information on toxicological effects
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TRIETHANOLAMINEPRODUCT NAME
Contact may result in irritation, redness and rash.Skin
Contact may result in irritation, lacrimation, pain and redness.Eye
Triethanolamine has been reported to cause allergic contact dermatitis. It is not known to cause respiratorysensitisation.
Sensitisation
Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.
STOT - singleexposure
Not expected to present an aspiration hazard.Aspiration
Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure.STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3).Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity value(s):
TRIETHANOLAMINE (102-71-6)LD50 (intraperitoneal) 1450 mg/kg (mouse)TDLo (oral) 16 g/kg/64 weeks (mouse - cancer)
DIETHANOLAMINE (111-42-2)LD50 (intramuscular) 1500 mg/kg (rat)LD50 (intraperitoneal) 120 mg/kg (rat)LD50 (intravenous) 778 mg/kg (rat)LD50 (subcutaneous) 2200 mg/kg (rat)LDLo (oral) 3 g/kg (rat)
12. ECOLOGICAL INFORMATION
12.1 Toxicity
No information provided.
12.2 Persistence and degradabilityNo information provided.
12.4 Mobility in soil
No information provided.
In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil,residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.
12.5 Other adverse effects
12.3 Bioaccumulative potentialNo information provided.
13. DISPOSAL CONSIDERATIONS
Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid.Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of toan approved landfill site. Contact the manufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
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TRIETHANOLAMINEPRODUCT NAME
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
None allocated.
None allocated. None allocated.
None allocated. None allocated.
None allocated.14.3 Transporthazard class
14.4 Packing Group
None allocated.
None allocated.
None allocated.
None allocated. None allocated.
None allocated.
14.1 UN Number
14.2 ProperShipping Name
No information provided.
14.5 Environmental hazards
None allocated.Hazchem code
14.6 Special precautions for user
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA
15. REGULATORY INFORMATION
Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
R37/38 Irritating to respiratory system and skin.R41 Risk of serious damage to eyes.R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Risk phrases
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listing(s)
S25 Avoid contact with eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS39 Wear eye/face protection.
Safety phrases
Xi IrritantXn Harmful
Hazard codes
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].
Classifications
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
Additional information
SDS Date: 09 Jun 2017
Version No: 2.2ofPage 6 7
TRIETHANOLAMINEPRODUCT NAME
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au
Prepared by
[ End of SDS ]
SDS Date: 09 Jun 2017
Version No: 2.2ofPage 7 7
TrueScavÔ HD
EN
SAFETY DATA SHEET
Issue Date 29-Aug-2018 Revision Date 29-Aug-2018 Version 1
Section 1: IDENTIFICATION: PRODUCT INDENTIFIER AND CHEMICAL IDENTITY
Product identifier
Product Name TrueScavÔ HD
Product Code NDF00394
Other means of identification
Recommended use of the chemical and restrictions on use
Recommended Use oxygen scavenger
Uses advised against No information available
Details of manufacturer or importer
For further information, please contact
Contact Point Telephone: +61 8 9410 8200Fax: +61 8 9410 8299Website: www.newpark.com
Emergency telephone number
Emergency telephone number +(61)-290372994 (Australia); +(64)-98010034 (New Zealand)
Section 2: HAZARD(S) IDENTIFICATION
GHS - Classification
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Label elements
Hazard statementsNot a dangerous substance or mixture according to the Globally Harmonized System (GHS)
Other hazards General HazardsNo information available
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UGHS Page 1 / 8
SupplierNewpark Drilling Fluids (Australia) LTD11 Alacrity PlaceHenderson, WA, 6166Australia
_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Section 3: COMPOSITION AND INFORMATION ON INGREDIENTS, IN ACCORDANCE WITHSCHEDULE 8
Substance
Section 4: FIRST AID MEASURES
Description of first aid measures
Emergency telephone number Poisons Information Center, Australia: 13 11 26Poisons Information Center, New Zealand: 0800 764 766
Inhalation Remove to fresh air.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.
Skin contact Wash skin with soap and water.
Ingestion Clean mouth with water and drink afterwards plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
Note to physicians Treat symptomatically.
Section 5: FIREFIGHTING MEASURESSuitable Extinguishing Media
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment.
Unsuitable extinguishing media No information available.
Specific hazards arising from the chemical
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Do not allow run-off from fire-fighting to enterdrains or water courses.
Hazardous combustion products Carbon oxides.
Special protective actions for fire-fighters
Special protective equipment forfire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnoutgear. Use personal protection equipment.
Hazchem code Not Listed.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Non-hazardous ingredients Proprietary
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UGHS Page 2 / 8
>99
_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Personal precautions Ensure adequate ventilation.
For emergency responders Use personal protection recommended in Section 8.
Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information. Do not flush into surface water orsanitary sewer system. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Pick up and transfer to properly labeled containers.
Precautions to prevent secondary hazards
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Section 7: HANDLING AND STORAGE, INCLUDING HOW THE CHEMICAL MAY BE SAFELYUSED
Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid generation ofdust. Wash thoroughly after handling. Wash contaminated clothing before reuse.
General hygiene considerations Do not eat, drink or smoke when using this product. Wash hands before breaks and afterwork.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Strong oxidizing agents
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupationalexposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits Not applicable
Appropriate engineering controls
Engineering controls ShowersEyewash stationsVentilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Tight sealing safety goggles.
Skin and body protection Wear suitable protective clothing.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
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_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state Solid
Other Information Softening point No information availableMolecular weight No information availableVOC Content (%) No information availableLiquid Density No information availableBulk density No information availableParticle Size No information availableParticle Size Distribution No information available
Section 10: STABILITY AND REACTIVITY
Reactivity
Reactivity Stable under normal conditions.
Chemical stability
Stability Stable under normal conditions.
Explosion dataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.
Possibility of Hazardous Reactions
Possibility of hazardous reactions None under normal processing.
Conditions to avoid
Conditions to avoid None known based on information supplied.
Appearance Powder Odor No information available.Color White Odor threshold No information available
Property Values Remarks • Method pH 5 - 8Melting point / freezing point 160 °CBoiling point / boiling range No information availableFlash point No information availableEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limit in Air No information available
Upper flammability limit: No data availableLower flammability limit: No data available
Vapor pressure No data availableVapor density No data availableRelative density 1.2-1.7Water solubility Soluble in waterSolubility(ies) No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity Not applicableDynamic viscosity
_____________________________________________________________________________________________
UGHS Page 4 / 8
Not applicable
_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Incompatible materials
Incompatible materials Strong oxidizing agents.
Hazardous Decomposition Products
Hazardous Decomposition Products None known based on information supplied.
Section 11: TOXICOLOGICAL INFORMATION
Acute toxicity
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available
Symptoms No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS documentATEmix (oral) 5,005.00 mg/kg
Unknown acute toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity100 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor)100 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist)
Component Information
See section 16 for terms and abbreviations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation None known.
Serious eye damage/eye irritation None known.
Respiratory or skin sensitization None known.
Germ cell mutagenicity None known.
Carcinogenicity None known.
Reproductive toxicity None known.
STOT - single exposure None known.
STOT - repeated exposure None known.
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_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
Aspiration hazard Not applicable.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity The environmental impact of this product has not been fully investigated.
Unknown aquatic toxicity 100 % of the mixture consists of component(s) of unknown hazards to the aquaticenvironment.
Persistence and degradability
Persistence and degradability No information available.
Bioaccumulative potential
Bioaccumulation No information available.
Mobility
Mobility in soil No information available.
Mobility No information available.
Other adverse effects
Other adverse effects No information available.
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations. Dispose of waste in accordance withenvironmental legislation.
Contaminated packaging Do not reuse empty containers.
Section 14: TRANSPORT INFORMATION
ADG Not Regulated
IATA Not Regulated
IMDG Not Regulated
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNo information available
Section 15: REGULATORY INFORMATION
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Regulatory information
_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
National regulations
Australia See section 8 for national exposure control parameters
Standard for Uniform Scheduling of Medicines and Poisons (SUSMP)No poisons schedule number allocated
International Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals
International Regulations
The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable
The Stockholm Convention on Persistent Organic Pollutants Not applicable
The Rotterdam Convention Not applicable
Section 16: ANY OTHER RELEVANT INFORMATION
Issue Date 29-Aug-2018
Revision Date 29-Aug-2018
Revision NoteNo information available.
Key or legend to abbreviations and acronyms used in the safety data sheet
Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
DisclaimerThis document is provided as an information resource relating exclusively to the product or material described herein.The information contained herein may not be applicable to other products/ materials or processes and may not be validwhen this product/material is used in combination with any other product/material or process. The information providedin this document is compiled by Newpark Drilling Fluids LLC or its representatives from various sources including
TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)Ceiling Maximum limit value * Skin designationC Carcinogen
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UGHS Page 7 / 8
_____________________________________________________________________________________________NDF00394 TrueScavÔ HD Revision Date 29-Aug-2018
manufacturers, suppliers and other third-party sources, and is based on the information available as of the indicated dateof preparation. As the conditions under which this product could be used will vary and may not be within the control ofNewpark Drilling Fluids LLC there is no guarantee that the precautions outlined above will be sufficient for all individualsor situations. The buyer assumes all responsibility for using and handling the product in accordance with federal, state,provincial, or local regulations. For the product/ material described in this document, NO WARRANTY IS MADE,EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE.
End of Safety Data Sheet
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1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
ZINC WHITESynonyms
SCAVENGERUses1.2 Uses and uses advised against
1.3 Details of the supplier of the product
NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name
11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress
+61 8 9410 8200Telephone
+61 8 9410 8299Fax
1800 127 406 (Australia); +64 4 917 9888 (International)Emergency
1.4 Emergency telephone numbers
www.newpark.comWebsite
1.1 Product identifier
ZINC OXIDEProduct name
2. HAZARDS IDENTIFICATION
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
2.2 GHS Label elements
Signal word WARNING
Storage statementsNone allocated.
Collect spillage.P391Response statements
Avoid release to the environment.P273Prevention statements
Very toxic to aquatic life with long lasting effects.H410Hazard statements
Pictograms
Physical Hazards
Not classified as a Physical Hazard
Health Hazards
Not classified as a Health Hazard
Environmental Hazards
Aquatic Toxicity (Chronic): Category 1
2.1 Classification of the substance or mixture
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ZINC OXIDEPRODUCT NAME
No information provided.2.3 Other hazards
Dispose of contents/container in accordance with relevant regulations.P501Disposal statements
3. COMPOSITION/ INFORMATION ON INGREDIENTS
Ingredient CAS Number EC Number Content
>99%1314-13-2 215-222-5ZINC OXIDE
3.1 Substances / Mixtures
4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
4.1 Description of first aid measures
Eye
If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Skin
For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.
Ingestion
Eye wash facilities should be available.First aid facilities
Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed
4.3 Immediate medical attention and special treatment neededTreat symptomatically.
5. FIRE FIGHTING MEASURES
Non flammable. May evolve zinc oxides when heated to decomposition.5.2 Special hazards arising from the substance or mixture
Evacuate area and contact emergency services. Remain upwind and notify those downwind of hazard. Wear full protective equipmentincluding Self Contained Breathing Apparatus (SCBA) when combating fire.
5.3 Advice for firefighters
2Z2 Fine Water Spray.Z Wear full fire kit and breathing apparatus. Contain spill and run-off.
5.4 Hazchem code
Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media
6. ACCIDENTAL RELEASE MEASURES
Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Ventilate area where possible.6.1 Personal precautions, protective equipment and emergency procedures
Prevent product from entering drains and waterways.6.2 Environmental precautions
Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up
See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections
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ZINC OXIDEPRODUCT NAME
7. HANDLING AND STORAGE
Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.
7.2 Conditions for safe storage, including any incompatibilities
No information provided.7.3 Specific end uses
7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Exposure standards
Ingredient ReferenceTWA STEL
ppm mg/m³ ppm mg/m³
Zinc oxide (dust) SWA [AUS] -- 10 -- --
Zinc oxide (fume) SWA [AUS] -- 5 -- 10
Biological limitsNo biological limit values have been entered for this product.
PPE
Eye / Face Wear dust-proof goggles.
Hands Wear PVC or rubber gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.
Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proofextraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
8.2 Exposure controlsEngineering controls
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical propertiesWHITE TO YELLOW-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling point1975°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperature
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ZINC OXIDEPRODUCT NAME
9.1 Information on basic physical and chemical propertiesNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
10. STABILITY AND REACTIVITY
10.2 Chemical stability
Stable under recommended conditions of storage.
10.4 Conditions to avoid
Avoid heat, sparks, open flames and other ignition sources.
10.5 Incompatible materials
Incompatible with metals if heated and with acids (e.g. nitric acid).
May evolve zinc oxides when heated to decomposition.10.6 Hazardous decomposition products
Polymerization is not expected to occur.
10.3 Possibility of hazardous reactions
10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.
11. TOXICOLOGICAL INFORMATION
This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.Acute toxicity
Information available for the ingredients:
IngredientOral LD50 Dermal LD50 Inhalation LC50
7950 mg/kg (mouse) -- 2500 mg/m³ (mouse)ZINC OXIDE
Not classified as a skin irritant. Prolonged or repeated contact may result in mild irritation.Skin
Not classified as an eye irritant. Contact may result in mild irritation, lacrimation and redness.Eye
Not classified as causing skin or respiratory sensitisation.Sensitisation
Not classified as causing organ damage from single exposure. Inhalation of freshly formed zinc oxide fumesmay result in the development of a flu-like illness termed metal fume fever.
STOT - singleexposure
Not relevant.Aspiration
Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure
Insufficient data available to classify as a reproductive toxin.Reproductive
Insufficient data available to classify as a carcinogen.Carcinogenicity
Insufficient data available to classify as a mutagen.Mutagenicity
Additional ingredient toxicity values:
ZINC OXIDE (1314-13-2)LD50 (intraperitoneal) 240 mg/kg (rat)LDLo (oral) 500 mg/kg (human)TCLo (inhalation) 600 mg/m³ (human)
11.1 Information on toxicological effects
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Very toxic to aquatic life with long lasting effects.
12.2 Persistence and degradabilityThis product is not readily biodegradable.
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ZINC OXIDEPRODUCT NAME
12.4 Mobility in soil
No information provided.
No information provided.
12.5 Other adverse effects
12.3 Bioaccumulative potentialAll living organisms have homeostasis mechanisms that actively regulate zinc uptake and absorption/excretion from the body; due tothis regulation, zinc and zinc compounds do not bioaccumulate or biomagnify.
13. DISPOSAL CONSIDERATIONS
Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).
13.1 Waste treatment methods
Waste disposal
Dispose of in accordance with relevant local legislation.Legislation
14. TRANSPORT INFORMATION
LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)
III
9 9
III III
914.3 Transporthazard class
14.4 Packing Group
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
3077
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
3077 3077
ENVIRONMENTALLYHAZARDOUS SUBSTANCE,
SOLID, N.O.S.
14.1 UN Number
14.2 ProperShipping Name
Marine Pollutant
14.5 Environmental hazards
2ZHazchem code
F-A, S-FEmS
The environmentally hazardous substance mark is not required when transported in packages of lessthan 5 kg/L (UN Model Regulations: Special Provision 375; IATA: Special Provision A197; IMDG:Special Provision 969) or less than 500 kg/L by Australian Road and Rail.
Other information
9C1GTEPG
14.6 Special precautions for user
CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
15. REGULATORY INFORMATION
A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule
AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.
Inventory listings
Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.
Classifications
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ZINC OXIDEPRODUCT NAME
16. OTHER INFORMATION
RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.
ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average
Abbreviations
This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.
Report status
Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com
Prepared by
Additional information
SDS Date: 03 Feb 2020
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ZINC OXIDEPRODUCT NAME
[ End of SDS ]
SDS Date: 03 Feb 2020
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SAFETY DATA SHEET
CEMENT - CLASS GRevision Date: 02-Aug-2018 Revision Number: 38
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name CEMENT - CLASS G
Other means of Identification Synonyms NoneHazardous Material Number: HM001839
Recommended use of the chemical and restrictions on use Recommended Use CementUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Skin Sensitization Category 1 - H317Carcinogenicity Category 1A - H350Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373
Label elements, including precautionary statements
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Hazard Pictograms
Signal Word DANGER
Hazard Statements: H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Precautionary Statements
Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required
Response P302 + P352 - IF ON SKIN: Wash with plenty of water.P333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER/doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations
ContainsSubstances CAS NumberPortland cement 65997-15-1Crystalline silica, quartz 14808-60-7
Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Portland cement 65997-15-1 60 - 100% Skin Irrit. 2 (H315)
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Eye Corr. 1 (H318)Skin Sens. 1 (H317)STOT SE 3 (H335)
Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 1A (H350)STOT RE 1 (H372)
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek
prompt medical attention.Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention.Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaNone - does not burn.Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireNot applicable
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Evacuate all persons from the area.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
7. Handling and storage
7.1. Precautions for safe handling
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Handling Precautions
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 02-Aug-2018
Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airbornewithout a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keepexposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator whenusing this product. Material is slippery when wet. Wash hands after use. Launder contaminated clothing before reuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf lifeof 24 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAPortland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3
Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.
Hand Protection Impervious rubber gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered
before reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 12.4Freezing Point / Range No data availableMelting Point / Range No data availablePour Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 3.14
Physical State: Solid Color GrayOdor: Odorless Odor Threshold:
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No information available
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 02-Aug-2018
Water Solubility No data availableSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from any contact with water.10.5. Incompatible materials Hydrofluoric acid.
10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation Causes moderate respiratory irritation. Inhaled crystalline silica in the form of quartz or
cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There issufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation. May cause alkali burns with confined contact. May cause an allergic
skin reaction. Can dry skin.Ingestion Causes burns of the mouth, throat and stomach.
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Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.
Exposure LevelsNo data available
Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationPortland cement 65997-15-1 Irritating to skin. (Rabbit)Crystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CAS Number Serious eye damage/irritationPortland cement 65997-15-1 Corrosive to eyesCrystalline silica, quartz 14808-60-7 Non-irritating to the eye No information available
Substances CAS Number Skin SensitizationPortland cement 65997-15-1 May cause sensitization by skin contactCrystalline silica, quartz 14808-60-7 No information available.
Substances CAS Number Respiratory SensitizationPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available
Substances CAS Number Mutagenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CAS Number Carcinogenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.
Substances CAS Number Reproductive toxicity
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Portland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 No information available
Substances CAS Number STOT - single exposurePortland cement 65997-15-1 May cause respiratory irritation.Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposurePortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CAS Number Aspiration hazardPortland cement 65997-15-1 Not applicableCrystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Portland cement 65997-15-1 No information available No information available No information available No information available
Crystalline silica,quartz
14808-60-7 EC50(72 h)=440 mg/L(Pseudokirchneriella
subcapitata)
LL0(96 h)=10000 mg/L(Danio rerio)
No information available LL50(24 h)>10000 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityPortland cement 65997-15-1 The methods for determining biodegradability are
not applicable to inorganic substances.Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are
not applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Bioaccumulation
Portland cement 65997-15-1 No information available
Crystalline silica, quartz 14808-60-7 No information available
12.4. Mobility in soil
Substances CAS Number MobilityPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.
Disposal of any contaminated packaging
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Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 02-Aug-2018
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.
16. Other information
Date of preparation or review
_____________________________________________________________________________________________Page 8 / 9
_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 02-Aug-2018
Revision Date: 02-Aug-2018
Revision NoteSDS sections updated:2
Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH350 - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 9 / 9
SAFETY DATA SHEET
SILICALITE LIQUID
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name SILICALITE LIQUID
Other means of Identification Synonyms: NoneProduct Code: HM001274
Recommended use of the chemical and restrictions on use Recommended Use Light Weight Cement AdditiveUses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
_____________________________________________________________________________________________Page 1 / 8
Revision Date: 22-Sep-2015 Revision Number: 20
_____________________________________________________________________________________________
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not ClassifiedRisk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Wash with soap and water.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasons
_____________________________________________________________________________________________Page 2 / 8
Revision Date: 22-Sep-2015SILICALITE LIQUID
_____________________________________________________________________________________________None known.
Specific hazards arising from the chemical Special Exposure HazardsNot applicable.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing.
6.2. Environmental precautions None known. Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothingbefore reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationKeep container closed when not in use. Product has a shelf life of 24 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Respiratory Protection Not normally necessary.
Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available
9. Physical and Chemical Properties
_____________________________________________________________________________________________Page 3 / 8
Revision Date: 22-Sep-2015SILICALITE LIQUID
_____________________________________________________________________________________________
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 6- 8Freezing Point/Range 0 °CMelting Point/Range No data availableBoiling Point/Range 100 °C / 212 °FFlash Point 100 °C / > 212 °FEvaporation rate No data availableVapor Pressure 22.9Vapor Density No data availableSpecific Gravity 1.37Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data availableLiquid Density 11.64 lbs/gal
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials None known.10.6. Hazardous Decomposition Products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye and skin contact.
Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values according
NA No data available No data available No data available
_____________________________________________________________________________________________Page 4 / 8
Odor Threshold: No information availablePhysical State: Liquid
SILICALITE LIQUID
Color: Dark gray
Revision Date: 22-Sep-2015
Odor: Odorless
_____________________________________________________________________________________________to the competentauthority
Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact Practically Non-toxic by Skin Contact.Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Reproductive toxicityContains no hazardous NA Not applicable
_____________________________________________________________________________________________Page 5 / 8
SILICALITE LIQUID Revision Date: 22-Sep-2015
_____________________________________________________________________________________________substances inconcentrations above cut-offvalues according to thecompetent authority
Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects Endocrine Disruptor Information
_____________________________________________________________________________________________Page 6 / 8
Revision Date: 22-Sep-2015SILICALITE LIQUID
_____________________________________________________________________________________________This product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 22-Sep-2015
Revision NoteSDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3None
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburton
_____________________________________________________________________________________________Page 7 / 8
SILICALITE LIQUID Revision Date: 22-Sep-2015
_____________________________________________________________________________________________representative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SILICALITE LIQUID Revision Date: 22-Sep-2015
SAFETY DATA SHEET
GASCON 469
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name GASCON 469
Other means of Identification Synonyms: NoneProduct Code: HM000753
Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
_____________________________________________________________________________________________Page 1 / 8
Revision Date: 22-Sep-2015 Revision Number: 25
_____________________________________________________________________________________________
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not ClassifiedRisk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasons
_____________________________________________________________________________________________Page 2 / 8
Revision Date: 22-Sep-2015GASCON 469
_____________________________________________________________________________________________None known.
Specific hazards arising from the chemical Special Exposure HazardsNot applicable.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep from excessive heat. Keep from freezing. Keep container closed when not in use. Store innon-rusting containers. Product has a shelf life of 12 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.
_____________________________________________________________________________________________Page 3 / 8
GASCON 469 Revision Date: 22-Sep-2015
_____________________________________________________________________________________________Dust/mist respirator. (N95, P2/P3)
Hand Protection None known.Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 10Freezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range 100 °C / 212 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.1Water Solubility Soluble in water (10g/100ml)Solubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) 80
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers. Strong acids.10.6. Hazardous Decomposition Products None known.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
Numerical measures of toxicity
_____________________________________________________________________________________________Page 4 / 8
Odor: Odorless
Revision Date: 22-Sep-2015
Odor Threshold: No information availablePhysical State: Liquid Color: Transparent
GASCON 469
_____________________________________________________________________________________________
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
_____________________________________________________________________________________________Page 5 / 8
GASCON 469 Revision Date: 22-Sep-2015
_____________________________________________________________________________________________Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
_____________________________________________________________________________________________Page 6 / 8
GASCON 469 Revision Date: 22-Sep-2015
_____________________________________________________________________________________________
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
_____________________________________________________________________________________________Page 7 / 8
GASCON 469 Revision Date: 22-Sep-2015
_____________________________________________________________________________________________Revision Date: 22-Sep-2015
Revision NoteSDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3None
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
GASCON 469 Revision Date: 22-Sep-2015
SAFETY DATA SHEET
HALAD® 413L CEMENT ADDITIVERevision Date: 07-May-2018 Revision Number: 26
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name HALAD® 413L CEMENT ADDITIVE
Other means of Identification Synonyms NoneHazardous Material Number: HM000824
Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss AdditiveUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
Hazard Statements: Not Classified
_____________________________________________________________________________________________Page 1 / 8
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
Precautionary Statements
Prevention NoneResponse NoneStorage NoneDisposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not classified
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
_____________________________________________________________________________________________Page 2 / 8
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Product has a shelf life of 24 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system
_____________________________________________________________________________________________Page 3 / 8
9. Physical and Chemical Properties
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 7.5Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.1Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Physical State: Liquid Color Brown-blackOdor: Sweet Odor Threshold: No information available
_____________________________________________________________________________________________Page 4 / 8
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact None known.Skin Contact None known.Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
_____________________________________________________________________________________________Page 5 / 8
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
Product contains one or more components not listed on the inventory.
_____________________________________________________________________________________________Page 6 / 8
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.
16. Other information
Date of preparation or review
Revision Date: 07-May-2018
Revision NoteSDS sections updated:2
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
_____________________________________________________________________________________________Page 7 / 8
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SAFETY DATA SHEET
SCR-100L
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name SCR-100L
Other means of Identification Synonyms: NoneProduct Code: HM001254
Recommended use of the chemical and restrictions on use Recommended Use RetarderUses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
_____________________________________________________________________________________________Page 1 / 8
Revision Date: 21-Sep-2015 Revision Number: 32
_____________________________________________________________________________________________
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not ClassifiedRisk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get
immediate medical attention.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasons
_____________________________________________________________________________________________Page 2 / 8
Revision Date: 21-Sep-2015SCR-100L
_____________________________________________________________________________________________None known.
Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Keep container closed when not in use.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator
is recommended:Dust/mist respirator. (N95, P2/P3)
Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system
_____________________________________________________________________________________________Page 3 / 8
SCR-100L Revision Date: 21-Sep-2015
_____________________________________________________________________________________________
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 3 - 4 (28%)Freezing Point/Range -4 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point > 93 °C / > 200 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.16Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 520 °CDecomposition Temperature No data availableViscosity 15-30 cP @ 25°CExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) ~60%Liquid Density 9.66
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances in
NA No data available No data available No data available
_____________________________________________________________________________________________Page 4 / 8
Odor Threshold: No information availablePhysical State: Liquid
Revision Date: 21-Sep-2015
Color: BlueOdor: Odorless
SCR-100L
_____________________________________________________________________________________________concentrations abovecut-off values accordingto the competentauthority
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects Skin disorders.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable.
Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
_____________________________________________________________________________________________Page 5 / 8
Revision Date: 21-Sep-2015SCR-100L
_____________________________________________________________________________________________Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority
NA Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
_____________________________________________________________________________________________Page 6 / 8
Revision Date: 21-Sep-2015SCR-100L
_____________________________________________________________________________________________12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance shouldNOT be deposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 21-Sep-2015
Revision NoteSDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3None
_____________________________________________________________________________________________Page 7 / 8
SCR-100L Revision Date: 21-Sep-2015
_____________________________________________________________________________________________
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SCR-100L Revision Date: 21-Sep-2015
SAFETY DATA SHEET
WellLife™ 734
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name WellLife™ 734
Other means of Identification Synonyms: NoneProduct Code: HM005965
Recommended use of the chemical and restrictions on use Recommended Use Cement EnhancerUses Advised Against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300
Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719
Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111
E-Mail address: [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
_____________________________________________________________________________________________Page 1 / 7
Revision Number: 18Revision Date: 30-Sep-2015
_____________________________________________________________________________________________Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
Hazard Statements Not Classified
Precautionary Statements
Prevention None
Response None
Storage None
Disposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).
Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16
Classification Not ClassifiedRisk Phrases None
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation Under normal conditions, first aid procedures are not required.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Under normal conditions, first aid procedures are not required.Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
_____________________________________________________________________________________________Page 2 / 7
WellLife™ 734 Revision Date: 30-Sep-2015
_____________________________________________________________________________________________
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special Exposure HazardsNot applicable.
Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Scoop up and remove.
7. Handling and storage
7.1. Precautions for Safe Handling Handling PrecautionsMaterial is slippery underfoot. Keep floors clean of spills. Avoid creating or inhaling dust. Avoid dust accumulations. Ensureadequate ventilation. Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a dry location. Product has a shelf life of 60 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls None known.
Personal protective equipment (PPE) Respiratory Protection Not normally necessary.
_____________________________________________________________________________________________Page 3 / 7
WellLife™ 734 Revision Date: 30-Sep-2015
_____________________________________________________________________________________________
Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: No data availableFreezing Point/Range 1200 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.6Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data availableBulk Density 44 lbs/ft3 @ 20 C
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials None known.10.6. Hazardous Decomposition Products None known.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
_____________________________________________________________________________________________Page 4 / 7
Odor: Odorless
Revision Date: 30-Sep-2015
Odor Threshold: No information availablePhysical State: Solid Color: White to Variable
WellLife™ 734
_____________________________________________________________________________________________Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according to
NA No information available
_____________________________________________________________________________________________Page 5 / 7
Revision Date: 30-Sep-2015WellLife™ 734
_____________________________________________________________________________________________the competent authority
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals
All components listed on inventory or are exempt.
EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.
_____________________________________________________________________________________________Page 6 / 7
WellLife™ 734 Revision Date: 30-Sep-2015
_____________________________________________________________________________________________Poisons Schedule number None Allocated
16. Other information
Date of preparation or review
Revision Date: 30-Sep-2015
Revision NoteSDS sections updated: 2
Full text of R-phrases referred to under Sections 2 and 3None
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 7 / 7
Revision Date: 30-Sep-2015WellLife™ 734
SAFETY DATA SHEET
CFR-3LRevision Date: 16-Sep-2016 Revision Number: 20
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name CFR-3L
Other means of Identification Synonyms NoneHazardous Material Number: HM000211
Recommended use of the chemical and restrictions on use Recommended Use Friction ReducerUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
_____________________________________________________________________________________________Page 1 / 7
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Hazard Statements: Not Classified
Precautionary Statements
Prevention NoneResponse NoneStorage NoneDisposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification None known
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters
_____________________________________________________________________________________________Page 2 / 7
Special protective equipment for firefighters
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values
Physical State: Liquid Color RedOdor: Musty Odor Threshold: No information available
_____________________________________________________________________________________________Page 3 / 7
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Remarks/ - Method pH: 7Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point > 98 °C / > 210 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.17Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data availableLiquid Density 9.75 lbs/gal
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact Non-irritating to rabbit's eye
_____________________________________________________________________________________________Page 4 / 7
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
Skin Contact Not irritating to skin in rabbits.Ingestion None known.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects
_____________________________________________________________________________________________Page 5 / 7
Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance shouldNOT be deposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number
_____________________________________________________________________________________________Page 6 / 7
None Allocated
_____________________________________________________________________________________________CFR-3L Revision Date: 16-Sep-2016
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 16-Sep-2016
Revision NoteSDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 7 / 7
SAFETY DATA SHEET
HR-25LRevision Date: 09-Mar-2016 Revision Number: 30
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name HR-25L
Other means of Identification Synonyms NoneProduct Code: HM000893
Recommended use of the chemical and restrictions on use Recommended Use Cement RetarderUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
Classification of the hazardous chemical Serious Eye Damage/Irritation Category 1 - H318Acute Aquatic Toxicity Category 3 - H402
Label elements, including precautionary statements
Hazard pictograms
_____________________________________________________________________________________________Page 1 / 8
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
Signal Word Danger
Hazard Statements H318 - Causes serious eye damageH402 - Harmful to aquatic life
Precautionary Statements
Prevention P273 - Avoid release to the environmentP280 - Wear eye protection/face protection
Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage NoneDisposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
ContainsSubstances CAS NumberTartaric acid 87-69-4
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Tartaric acid 87-69-4 30 - 60% Eye Corr. 1 (H318)Aquatic Acute 3 (H402)
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention. Remove contaminated clothing and launderbefore reuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.
Symptoms caused by exposure Causes severe eye irritation which may damage tissue.
_____________________________________________________________________________________________Page 2 / 8
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from alkalis. Store away from oxidizers. Store in a cool well ventilated area. Keep container closed when not in use.Product has a shelf life of 60 months.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWATartaric acid 87-69-4 Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area.
_____________________________________________________________________________________________Page 3 / 8
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Dust/mist respirator. (N95, P2/P3)Hand Protection Impervious rubber gloves.Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 1.7Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 103 °C / 219 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.2Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers. Strong alkalis.10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Physical State: Liquid Color Light yellow-greenOdor: Odorless Odor Threshold:
_____________________________________________________________________________________________Page 4 / 8
No information available
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Tartaric acid 87-69-4 2000 - 5000 mg/kg (Rat) > 2000 mg/kg (Rat) No data available
Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects Skin disorders.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationTartaric acid 87-69-4 Non-irritating to the skin (Rabbit) (in vitro)
Substances CAS Number Serious eye damage/irritationTartaric acid 87-69-4 Causes severe eye irritation (Rabbit)
Substances CAS Number Skin SensitizationTartaric acid 87-69-4 Did not cause sensitization on laboratory animals (mouse)
Substances CAS Number Respiratory SensitizationTartaric acid 87-69-4 No information available
Substances CAS Number Mutagenic EffectsTartaric acid 87-69-4 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Substances CAS Number Carcinogenic EffectsTartaric acid 87-69-4 Did not show carcinogenic effects in animal experiments (Rat) (similar substances)
Substances CAS Number Reproductive toxicityTartaric acid 87-69-4 Did not show teratogenic effects in animal experiments.
Substances CAS Number STOT - single exposureTartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposureTartaric acid 87-69-4 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number Aspiration hazardTartaric acid 87-69-4 Not applicable
_____________________________________________________________________________________________Page 5 / 8
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Tartaric acid 87-69-4 E(B)C50 2575.2 mg/L(Skeletonema costatum)
E(R)C50 1198 mg/L(Skeletonema costatum)
EC50 791.25 mg/L(Skeletonema costatum)
EC50 (72h) 51.4043 mg/L(Pseudokirchnerella
subcapitata)
LC50 250 mg/L(Scophthalmus maximus)LC50 (96h) > 100 mg/L
(Danio rerio)
EC50 (3h) > 1000 mg/L(Activated sludge)
TLM96 330-1000 ppm(Crangon crangon)
EC50 46.04 - 165.37mg/L (Ceriodaphnia
dubia)LC50 3753.85 (Acartia
tonsa)EC50 (48h) 93.313 mg/L
(Daphnia magna)
12.2. Persistence and degradability Readily biodegradableSubstances CAS Number Persistence and DegradabilityTartaric acid 87-69-4 Readily biodegradable (85% @ 28d)
12.3. Bioaccumulative potential Does not bioaccumulate.Substances CAS Number Log Pow
Tartaric acid 87-69-4 -1
12.4. Mobility in soil
Substances CAS Number MobilityTartaric acid 87-69-4 No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable
_____________________________________________________________________________________________Page 6 / 8
Special precautions during transport
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStolkhom Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 09-Mar-2016
Revision NoteSDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3H318 - Causes serious eye damage
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used
_____________________________________________________________________________________________Page 7 / 8
bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million
_____________________________________________________________________________________________HR-25L Revision Date: 09-Mar-2016
STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SAFETY DATA SHEET
ECONOLITE LIQUIDRevision Date: 14-Oct-2015 Revision Number: 34
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name ECONOLITE LIQUID
Other means of Identification Synonyms NoneProduct Code: HM000478
Recommended use of the chemical and restrictions on use Recommended Use Light Weight Cement AdditiveUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott RoadJandakotWA 6164Australia
ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318
Label elements, including precautionary statements
Hazard pictograms
_____________________________________________________________________________________________Page 1 / 8
_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
Signal Word Danger
Hazard Statements H315 - Causes skin irritationH318 - Causes serious eye damage
Precautionary Statements
Prevention P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/eye protection/face protection
Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Storage NoneDisposal None
ContainsSubstances CAS NumberSodium silicate 1344-09-8
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Sodium silicate 1344-09-8 30 - 60% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention. Remove contaminated clothing and launderbefore reuse.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.
Symptoms caused by exposure
_____________________________________________________________________________________________Page 2 / 8
_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
Causes severe eye irritation which may damage tissue. Causes skin irritation.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Neutralize to pH of 6-8. Scoop up andremove. Do NOT spread spilled product with water.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse. Avoid breathingvapors. Avoid breathing mist. Ensure adequate ventilation. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from acids. Store in a cool well ventilated area. Keep container closed when not in use.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWASodium silicate 1344-09-8 Not applicable Not applicable
Appropriate engineering controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
good cross ventilation.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorterthan the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.
Skin Protection Full protective chemical resistant clothing.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: 11.2Freezing Point / Range -1 °CMelting Point / Range No data availableBoiling Point / Range 101 °C / 214 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.4Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.
Physical State: Liquid Color Clear to hazyOdor: Slightly soapy Odor Threshold: No information available
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.10.6. Hazardous decomposition products Toxic fumes.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Sodium silicate 1344-09-8 3400 mg/kg (Rat) > 5000 mg/kg (Rat) (similarsubstance)
> 2.06 mg/L (Rat) 4h (similarsubstance – Potassium silicate)
Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation.Ingestion Irritation of the mouth, throat, and stomach.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects Skin disorders.
Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationSodium silicate 1344-09-8 Causes moderate skin irritation. (Rabbit)
Substances CAS Number Serious eye damage/irritationSodium silicate 1344-09-8 Causes severe eye irritation which may damage tissue. (Rabbit)
Substances CAS Number Skin SensitizationSodium silicate 1344-09-8 Did not cause sensitization on laboratory animals (mouse) (similar substances)
Substances CAS Number Respiratory SensitizationSodium silicate 1344-09-8 No information available
Substances CAS Number Mutagenic EffectsSodium silicate 1344-09-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Substances CAS Number Carcinogenic Effects
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
Sodium silicate 1344-09-8 No information available
Substances CAS Number Reproductive toxicitySodium silicate 1344-09-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
experiments. (similar substances)
Substances CAS Number STOT - single exposureSodium silicate 1344-09-8 No information available.
Substances CAS Number STOT - repeated exposureSodium silicate 1344-09-8 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number Aspiration hazardSodium silicate 1344-09-8 Not applicable
12. Ecological Information
Ecotoxicity Product Ecotoxicity DataNo data available
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Sodium silicate 1344-09-8 EC50 (72h) > 345 mg/L(growth rate)
(Scenedesmussubspicatus)
EC0 (72h) 35 mg/L(growth rate)
(Scenedesmussubspicatus)
LC50 (96h) 1108 mg/L(Danio rerio)
LC50 (96h) 260 – 310mg/L (Oncorhynchus
mykiss)
EC0 (0.5h) 3454 mg/L(Pseudomonas putida)
EC50 (48h) 1700 mg/L(Daphnia magna)
12.2. Persistence and degradability
Substances CAS Number Persistence and DegradabilitySodium silicate 1344-09-8 The methods for determining biodegradability are
not applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Sodium silicate 1344-09-8 No information available
12.4. Mobility in soil
Substances CAS Number MobilitySodium silicate 1344-09-8 No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
Environmental regulationsNot applicable
14. Transport Information
Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number S5
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStolkhom Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 14-Oct-2015
Revision NoteSDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH318 - Causes serious eye damage
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
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_____________________________________________________________________________________________ECONOLITE LIQUID Revision Date: 14-Oct-2015
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SAFETY DATA SHEET
NF-6Revision Date: 16-Aug-2016 Revision Number: 28
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
1.1. Product Identifier Product Name NF-6
Other means of Identification Synonyms NoneHazardous Material Number: HM001971
Recommended use of the chemical and restrictions on use Recommended Use DefoamerUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.
Classification of the hazardous chemical Not classified
Label elements, including precautionary statements
Hazard Pictograms
Signal Word Not Hazardous
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_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
Hazard Statements: Not Classified
Precautionary Statements
Prevention NoneResponse NoneStorage NoneDisposal None
ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority
NA
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA 60 - 100% Not Applicable
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.
Symptoms caused by exposure No significant hazards expected.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaCarbon dioxide, dry chemical, foam.Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Decomposition in fire may produce harmful gases.
_____________________________________________________________________________________________Page 2 / 8
Special protective equipment and precautions for fire fighters
_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.
6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.
6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA Not applicable Not applicable
Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in
areas without good cross ventilation.
Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator with a dust/mist filter. (A2P2/P3)
Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): Polyvinylchloride gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorter
_____________________________________________________________________________________________Page 3 / 8
_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
than the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.
Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 182 °C / 360 °FFlash Point > 170 °C / > 340 °FEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 0.93Water Solubility DispersibleSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 385 °C / 725 °FDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data availableLiquid Density 7.70 lbs/gal
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide and carbon dioxide.
11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/Effects
Physical State: Liquid Color YellowOdor: Mild Odor Threshold:
_____________________________________________________________________________________________Page 4 / 8
No information available
_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
No significant hazards expected.
Numerical measures of toxicity
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority
NA No data available No data available No data available
Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact None known.Skin Contact None known.Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.
Exposure LevelsNo data available
Interactive effects None known.
Data limitationsNo data available
12. Ecological Information
Ecotoxicity Product Ecotoxicity Data
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority
NA No information available No information available No information available No information available
12.2. Persistence and degradability
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_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.3. Bioaccumulative potential
Substances CAS Number Log Pow
Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority
NA No information available
12.4. Mobility in soil
Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority
NA No information available
12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT bedeposited into a sewage facility.
Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
_____________________________________________________________________________________________Page 6 / 8
Special precautions during transport
_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
EINECS (European Inventory ofExisting Chemical Substances)
This product, and all its components, complies with EINECS
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
Poisons Schedule number None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply
16. Other information
Date of preparation or review
Revision Date: 16-Aug-2016
Revision NoteSDS sections updated: 2
Full text of H-Statements referred to under sections 2 and 3None
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used
_____________________________________________________________________________________________Page 7 / 8
bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million
_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016
STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDCosmetic Ingredient Review
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
End of Safety Data Sheet
_____________________________________________________________________________________________Page 8 / 8
SAFETY DATA SHEET
TUNED SPACER E+Revision Date: 08-Jan-2019 Revision Number: 40
1. Product Identifier & Identity for the Chemical
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
1.1. Product Identifier Product Name TUNED SPACER E+
Other means of Identification Synonyms NoneHazardous Material Number: HM003335
Recommended use of the chemical and restrictions on use Recommended Use Cement SpacerUses advised against No information available
Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]
Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012
Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100
2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.
Classification of the hazardous chemical Carcinogenicity Category 1A - H350Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373
Label elements, including precautionary statements
Hazard Pictograms
_____________________________________________________________________________________________Page 1 / 9
_____________________________________________________________________________________________TUNED SPACER E+ Revision Date: 08-Jan-2019
Signal Word DANGER
Hazard Statements: H350 - May cause cancer by inhalationH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Precautionary Statements
Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required
Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell
Storage P405 - Store locked upDisposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations
ContainsSubstances CAS NumberCrystalline silica, quartz 14808-60-7
Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).
For the full text of the H-phrases mentioned in this Section, see Section 16
3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -Australia
Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 1A (H350)STOT RE 1 (H372)
4. First aid measures
Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.
Symptoms caused by exposure Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.
Medical Attention and Special Treatment Notes to Physician Treat symptomatically
_____________________________________________________________________________________________Page 2 / 9
_____________________________________________________________________________________________TUNED SPACER E+ Revision Date: 08-Jan-2019
5. Fire Fighting Measures
Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.
Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.
Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.
6.2. Environmental precautions None known.
6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.
7. Handling and storage
7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
7.2. Conditions for safe storage, including any incompatibilities Storage InformationUse good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.Other GuidelinesNo information available
8. Exposure Controls/Personal Protection
Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3
Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures
below applicable exposure limits.
_____________________________________________________________________________________________Page 3 / 9
Personal protective equipment (PPE)
_____________________________________________________________________________________________TUNED SPACER E+ Revision Date: 08-Jan-2019
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, theselection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.
Hand Protection Normal work gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered
before reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availablePour Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.88 - 2.05Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available
9.2. Other information VOC Content (%) No data available
10. Stability and Reactivity
10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated temperatures to tridymite (870C) or cristobalite (1470 C).
Physical State: Solid Color White to light strawOdor: Odorless Odor Threshold:
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No information available
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11. Toxicological Information
Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.
Symptoms related to exposure Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.
Toxicology data for the components
Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available
Immediate, delayed and chronic health effects from exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is
carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).
Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).
Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.
Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.
Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.
Exposure LevelsNo data available
Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.
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Data limitationsNo data available
Substances CAS Number Skin corrosion/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the skin
Substances CAS Number Serious eye damage/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the eye No information available
Substances CAS Number Skin SensitizationCrystalline silica, quartz 14808-60-7 No information available.
Substances CAS Number Respiratory SensitizationCrystalline silica, quartz 14808-60-7 No information available
Substances CAS Number Mutagenic EffectsCrystalline silica, quartz 14808-60-7 Not regarded as mutagenic.
Substances CAS Number Carcinogenic EffectsCrystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The
IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.
Substances CAS Number Reproductive toxicityCrystalline silica, quartz 14808-60-7 No information available
Substances CAS Number STOT - single exposureCrystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.
Substances CAS Number STOT - repeated exposureCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)
Substances CAS Number Aspiration hazardCrystalline silica, quartz 14808-60-7 Not applicable
12. Ecological Information
Ecotoxicity
Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to
MicroorganismsToxicity to Invertebrates
Crystalline silica,quartz
14808-60-7 EC50(72 h)=440 mg/L(Pseudokirchneriella
subcapitata)
LL0(96 h)=10000 mg/L(Danio rerio)
No information available LL50(24 h)>10000 mg/L(Daphnia magna)
12.2. Persistence and degradability Expected to be readily biodegradableSubstances CAS Number Persistence and DegradabilityCrystalline silica, quartz 14808-60-7 The methods for determining biodegradability are
not applicable to inorganic substances.
12.3. Bioaccumulative potential
Substances CAS Number Bioaccumulation
Crystalline silica, quartz 14808-60-7 No information available
12.4. Mobility in soil
Substances CAS Number MobilityCrystalline silica, quartz 14808-60-7 No information available
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12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors
13. Disposal Considerations
Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.
Disposal of any contaminated packaging Follow all applicable national or local regulations.
Environmental regulationsNot applicable
14. Transport Information
Transportation Information Australia ADG
UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable
Special precautions during transport None
HazChem Code None Allocated
15. Regulatory Information
Safety, health and environmental regulations specific for the product
International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.New Zealand Inventory ofChemicals
All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.
US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)
All components listed on inventory or are exempt.
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Poisons Schedule number
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None Allocated
International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.
16. Other information
Date of preparation or review
Revision Date: 08-Jan-2019
Revision NoteSDS sections updated:2
Full text of H-Statements referred to under sections 2 and 3H350 - May cause cancer by inhalationH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.
For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.
Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day
Key literature references and sources for datawww.ChemADVISOR.com/
Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.
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SDS no. D901 Version 6 Revision date 08-Jun-2021 Supersedes Date: 13-Apr-2016
Safety Data Sheet Cement Class A D901
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Class A D901 Product code D901
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1B Specific target organ toxicity - Single exposure Category 3
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 Level 5, 10 Telethon Avenue Perth WA 6000
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
Signal wordDANGER
Hazard StatementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation
Precautionary statements P271 - Use only outdoors or in a well-ventilated areaP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP310 - Immediately call a POISON CENTER or doctor/physician
Supplementary precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
Contains Portland cement
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Chemical Name EC No CAS No Weight-% Portland cement 266-043-4 65997-15-1 60-100
3.2 Mixtures
Not applicable
4. First Aid Measures
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors React with hydrofluoric acid (HF) forming toxic gas (SiF4).
5.3 Advice for firefighters
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Special protective equipment for fire-fighters
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
As in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with the skin and the eyes. Avoid dust formation. Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.
Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properly labeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Persons susceptible to allergic reactions should not handle this product. May produce an allergic reaction.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provide appropriate exhaust ventilation at places where dust is formed.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid heat, flames and other sources of ignition. Protect from moisture Avoid contact with: Oxidizing agents Strong acids Aluminum Hydrofluoric acid (HF)
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
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8. Exposure Controls/Personal Protection
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
Chemical Name Arabic Australia Egypt Portland cement 10 mg/m3 TWA 10mg/m3TWAinhalable dust Not determined Chemical Name India Indonesian Japan Portland cement 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL
1 mg/m3 OEL Chemical Name Kazakhstan Kuwait New Zealand Portland cement Not determined 10.0 mg/m3 TWA
5.0 mg/m3 TWA 10 mg/m3 TWA
Chemical Name Malaysia Philippines Russia Portland cement 10 mg/m3 TWA Not determined Not determined Chemical Name Thailand Vietnam Turkey Portland cement Not determined Not determined Not determined
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety goggles Hand protection Wear gloves according to EN 374 to protect against skin effects from powders
Impervious gloves made of: PVC disposable gloves Rubber gloves Frequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Powder Odor Odorless Color Gray or White
Density and/or Relative Density 2.75 - 3.20
Explosive properties Not applicable Oxidizing properties Not applicable
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
Physical state Solid
Property Values Remarks pH Not applicable pH @ dilution 11 - 13 @10% sol Melting / freezing point > 1250 °C / 2282 °F Boiling point/range No information available Flash point Does not flash Evaporation rate (BuAc =1) Not applicable Flammability Not applicable Explosion limits:
Upper explosion limit No information available Lower explosion limit No information available
Vapor pressure No information available Relative Vapor Density No information available Specific gravity No information available Bulk density 0.9 - 1.5 g/cm³ Water solubility Slightly soluble in water. Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)
No information available
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
10.4 Conditions to avoid
Protect from moisture. Avoid dust formation. Avoid heat, flames and other sources of ignition.
10.5 Incompatible materials
Oxidizing agents. Hydrofluoric acid (HF). Strong acids. Aluminium.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects Acute toxicity Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and
cough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contact with moist mucous membranes of the respiratory system can cause caustic condition resulting in burns.
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Ingestion Ingestion may cause irritation to mucous membranes.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Portland cement No data available No data available No data available
Sensitization May cause allergic skin reaction.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Inhalation. Eye contact.
Routes of entry Inhalation. Skin contact. Eye contact.
Specific target organ toxicity - Single exposure
Category 3
Specific target organ toxicity - Repeated exposure
Not classified.
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
11.2 Information on other hazards
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Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquatic organisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates Portland cement No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
12.4 Mobility
MobilitySlightly soluble in water.
Mobility in soilNo information available.
12.5 Other adverse effects
None known.
12.6 Other information.
Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
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Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Maritime transport in bulk according to IMO instruments Please contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons Portland cement Schedule 4 Schedule 6 Schedule 5
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
International inventories
USA (TSCA) Complies
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Cement Class A D901 SDS no. D901 Revision date 08-Jun-2021
Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory
Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam
Supersedes Date: 13-Apr-2016
Revision date 08-Jun-2021
Version 6
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 3* Flammability 1 Physical hazard 0 PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D907Version 5Revision date 01-Aug-2018Supersedes Date: 05-Mar-2014
Safety Data SheetCement Class G D907
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Class G D907Product code D907Country Limitations This SDS is not for use in the European Union (EU).
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Skin sensitization Sub-Category 1BSpecific target organ toxicity - Single exposure Category 3
Environmental hazards Not classified
Physical Hazards Not classified
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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2.2 Label elements
Signal wordDANGER
Hazard StatementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation
Precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP362 - Take off contaminated clothing and wash before reuseP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsPortland Cement Clinker
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%Portland Cement Clinker 266-043-4 65997-15-1 60-100
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CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors React with hydrofluoric acid (HF) forming toxic gas(SiF4).
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5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Avoid dust formation. Avoid breathing dust; if exposed to high dustconcentration, leave area immediately. Avoid contact with the skin and the eyes.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.
Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. Persons susceptible to allergic reactions should not handle this product.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Protect from moistureStore away from incompatibles, Powdered aluminum Acids Oxidizing agents Hydrofluoricacid (HF)
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Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptPortland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA Not determined
Chemical Name India Indonesian JapanPortland Cement Clinker 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL
1 mg/m3 OELChemical Name Kazakhstan Kuwait New Zealand
Portland Cement Clinker Not determined Not determined 10 mg/m3 TWAChemical Name Malaysia Philippines Russia
Portland Cement Clinker 10 mg/m3 TWA Not determined Not determinedChemical Name Thailand Vietnam Turkey
Portland Cement Clinker Not determined Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts
Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious
gloves made of: PVC disposable gloves Rubber gloves Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.
Type P2/P3 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
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Cement Class G D907 SDS no. D907Revision date 01-Aug-2018
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor OdorlessColor Gray or WhiteOdor threshold Not applicable
Explosive properties Not applicableOxidizing properties Not applicable
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) Not applicableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
Physical state Solid
Property Values Remarks pH Not applicablepH @ dilution 11 - 13 @10% solMelting / freezing point > 1250 °C / 2282 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity ~ 3Bulk density 0.9 - 1.5 g/cm³Relative density 2.75 - 3.20Water solubility 0.1-1.5 g/L @ 20 °CSolubility in other solvents No information availableAutoignition temperature Not applicableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from moisture. Avoid dust formation.
10.5 Incompatible materials
Acids. Powdered aluminum. Strong oxidizing agents. Hydrofluoric acid (HF).
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contactwith moist mucous membranes of the respiratory system can cause caustic conditionresulting in burns.
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Ingestion Ingestion may cause irritation to mucous membranes.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationPortland Cement Clinker No data available No data available No data available
Sensitization May cause allergic skin reaction.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Inhalation. Eye contact.
Routes of entry Inhalation. Skin contact. Eye contact.
Specific target organ toxicity -Single exposure
Category 3
Specific target organ toxicity - Not classified.
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Repeated exposure
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesPortland Cement Clinker No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradabilityPortland Cement Clinker Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationPortland Cement Clinker Product/Substance is inorganic
12.4 Mobility
MobilitySlightly soluble in water.
Mobility in soilNo information available.
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12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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Cement Class G D907 SDS no. D907Revision date 01-Aug-2018
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons
Portland Cement ClinkerSchedule 4Schedule 6Schedule 5New Zealand Hazard Classification Classified
HSNO approval no. 6.5B, 6.3A, 8.3A
Group number HSR002544
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 05-Mar-2014
Revision date 01-Aug-2018
Version 5
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
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Cement Class G D907 SDS no. D907Revision date 01-Aug-2018
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 3 *Flammability 1Physical hazard 0PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D066Version 3Revision date 02-Mar-2020Supersedes Date: 13-Jul-2017
Safety Data SheetSilica Flour D66
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Silica Flour D66Product code D066
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518Malaysian Local emergency number; +603 2161 7655
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazardsSpecific target organ toxicity - Repeated exposure Category 2
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
Signal wordWARNING
Hazard StatementsH373 - May cause damage to organs through prolonged or repeated exposure
Precautionary statements P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP314 - Get medical advice/attention if you feel unwellP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsQuartz, Crystalline silica
Respirable Crystalline Silica (Quartz)
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Chemical Name EC No CAS No Weight-%Quartz, Crystalline silica 238-878-4 14808-60-7 60-100
Respirable Crystalline Silica (Quartz) 238-878-4 14808-60-7 <10
3.2 Mixtures
Not applicable
CommentsThis product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol.68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite fromoccupational sources causes cancer in humans. IARC Classification Group I.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsReact with hydrofluoric acid (HF) forming toxic gas (SiF4).
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
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6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upAvoid dust formation. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Hydrofluoric acid (HF) Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptQuartz, Crystalline silica 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined
Respirable Crystalline Silica(Quartz)
0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined
Chemical Name India Indonesian JapanQuartz, Crystalline silica Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL
Respirable Crystalline Silica(Quartz)
Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL
Chemical Name Kazakhstan Kuwait New ZealandQuartz, Crystalline silica 1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWA
Confirmed carcinogen
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
Respirable Crystalline Silica(Quartz)
1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWAConfirmed carcinogen
Chemical Name Malaysia Philippines RussiaQuartz, Crystalline silica 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL
1 mg/m3 TWAFibrogenic substance 1177, 1178
Respirable Crystalline Silica(Quartz)
0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA
Fibrogenic substance 1177, 1178Chemical Name Thailand Vietnam Turkey
Quartz, Crystalline silica 0.025 mg/m3 TWA Not determined Not determinedRespirable Crystalline Silica
(Quartz)0.025 mg/m3 TWA Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Keep airborne concentrations below exposure limits
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders Repeated or
prolonged contact Use protective gloves made of: Nitrile Neoprene gloves Frequent changeis advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Suitable mask withparticle filter P3 (European Norm 143) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash andemergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor OdorlessColor Tan or White
Physical state
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Solid
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
Odor threshold Not applicable
Explosive properties Not applicableOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
Hazardous ReactionsNone known.
10.4 Conditions to avoid
Avoid dust formation.
Property Values Remarks pH Not applicablepH @ dilution No information availableMelting / freezing point > 1700 °C / 3092 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity 2.50 - 2.70 @20 °CBulk density 1100- 1600 kg/m3
Relative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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10.5 Incompatible materials
Hydrofluoric acid (HF). Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause respiratory irritation. Repeated or prolonged inhalation of crystallinesilica dust can cause delayed lung injury, and other diseases, including silicosis and lungcancer.
Eye contact Dust may cause mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationQuartz, Crystalline silica No data available No data available No data available
Respirable Crystalline Silica (Quartz) No data available No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC inGroup 1 as known to cause lung cancer in humans, if inhaled.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Category 2.
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
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12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesQuartz, Crystalline silica No information available No information available No information available
Respirable Crystalline Silica(Quartz)
No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradabilityQuartz, Crystalline silica Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationQuartz, Crystalline silica Product/Substance is inorganic
12.4 Mobility
MobilityThe product is insoluble and sinks in water.
Chemical Name MobilityQuartz, Crystalline silica Insoluble in water
Mobility in soilNo information available.
Chemical Name Mobility in soilQuartz, Crystalline silica Not expected to adsorb on soil
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12.5 Results of PBT and vPvB assessment
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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This safety data sheet complies with the requirements of:
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 13-Jul-2017
Revision date 02-Mar-2020
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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Silica Flour D66 SDS no. D066Revision date 02-Mar-2020
HMIS classification
Health 1*Flammability 1Physical hazard 0PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. B421Version 3Revision date 15-May-2020Supersedes Date: 12-Jan-2016
Safety Data SheetSlag Cement B421
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Slag Cement B421Product code B421Country Limitations This SDS is not for use in the European Union (EU).
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518Malaysian Local emergency number; +603 2161 7655
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Skin sensitization Category 1Specific target organ toxicity - Single exposure Category 3
Environmental hazards Not classified
Physical Hazards Not classified
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
2.2 Label elements
Signal wordDANGER
Hazard StatementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritation
Precautionary statements P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physician
Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP332 + P313 - If skin irritation occurs: Get medical advice/attentionP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash it before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsBlast furnace slag
Portland cement
Quartz, Crystalline silica
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Chemical Name EC No CAS No Weight-%Blast furnace slag 266-002-0 65996-69-2 60-100Portland cement 266-043-4 65997-15-1 30-60
Quartz, Crystalline silica 238-878-4 14808-60-7 <1
CommentsThis product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis.IARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz orcristobalite from occupational sources causes cancer in humans. IARC Classification Group I.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaThe product itself does not burn, Use extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
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5.2. Special hazards arising from the substance or mixture
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Unusual fire and explosion hazardsReact with hydrofluoric acid (HF) forming toxic gas (SiF4).
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Avoid breathing dust; if exposed to high dust concentration, leave areaimmediately. Avoid contact with the skin and the eyes.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil. Prevent entry into sewage.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.
Methods for cleaning upDo not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Pick up and transfer to properlylabeled containers. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. After cleaning, flushaway traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Do not breathe vapors/dust. Avoid contact with skin andeyes. Avoid handling causing generation of dust. Persons susceptible to allergic reactions should not handle this product.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Protect from moistureStore away from incompatibles, Acids Strong oxidizing agents Hydrofluoric acid (HF)
Storage class Chemical storage.
Packaging materials Use specially constructed containers only. Bag with moisture barrier
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA 10mg/m3TWAinhalable dust Not determined
Quartz, Crystalline silica 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determinedChemical Name India Indonesian JapanBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA 10 mg/m3 TWA 4 mg/m3 OEL
1 mg/m3 OELQuartz, Crystalline silica Not determined 0.1 mg/m3 TWA 0.03 mg/m3 OEL
Chemical Name Kazakhstan Kuwait New ZealandBlast furnace slag Not determined Not determined Not determinedPortland cement Not determined 10.0 mg/m3 TWA
5.0 mg/m3 TWA10 mg/m3 TWA
Quartz, Crystalline silica 1 mg/m3 MAC 0.1 mg/m3 TWA 0.1 mg/m3 TWAConfirmed carcinogen
Chemical Name Malaysia Philippines RussiaBlast furnace slag Not determined Not determined Not determinedPortland cement 10 mg/m3 TWA Not determined Not determined
Quartz, Crystalline silica 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA
Fibrogenic substance 1177, 1178Chemical Name Thailand Vietnam TurkeyBlast furnace slag Not determined Not determined Not determinedPortland cement Not determined Not determined Not determined
Quartz, Crystalline silica 0.025 mg/m3 TWA Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts
Tightly fitting safety goggles Safety glasses with side-shields
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Imperviousgloves made of: PVC disposable gloves Rubber gloves Frequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.Type P2/P3 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor NoneColor GrayOdor threshold Not applicable
Explosive properties No information availableOxidizing properties No information available
Physical state Solid
Property Values Remarks pH No information availablepH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 3.0 - 3.1Water solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
React with hydrofluoric acid (HF) forming toxic gas (SiF4).
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from moisture.
10.5 Incompatible materials
Acids. Strong oxidizing agents. Hydrofluoric acid (HF).
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Contactwith moist mucous membranes of the respiratory system can cause caustic conditionresulting in burns.
Eye contact Causes serious eye damage.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Ingestion Ingestion may cause irritation to mucous membranes.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Blast furnace slag No data available No data available No data availablePortland cement No data available No data available No data available
Quartz, Crystalline silica No data available No data available No data available
Sensitization May cause allergic skin reaction.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer inhumans, if inhaled.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Eye contact. Inhalation.
Routes of entry Inhalation. Eye contact. Skin contact.
Specific target organ toxicity -Single exposure
Category 3
Specific target organ toxicity -Repeated exposure
Not classified.
Target organ effects Respiratory system. Lungs.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesBlast furnace slag No information available No information available No information availablePortland cement No information available No information available No information available
Quartz, Crystalline silica No information available No information available No information available
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradability
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
Quartz, Crystalline silica Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationQuartz, Crystalline silica Product/Substance is inorganic
12.4 Mobility
MobilityThe product is miscible with water. May spread in water systems.
Chemical Name MobilityQuartz, Crystalline silica Insoluble in water
Mobility in soilNo information available.
Chemical Name Mobility in soilQuartz, Crystalline silica Not expected to adsorb on soil
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name
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The product is not covered by international regulation on the transport of dangerous goods
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons
Blast furnace slagSchedule 4Schedule 6Schedule 5Portland cementSchedule 4Schedule 6Schedule 5
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
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Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
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Slag Cement B421 SDS no. B421Revision date 15-May-2020
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies
This SDS is not for use in the European Union (EU).
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 12-Jan-2016
Revision date 15-May-2020
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D031Version 3Revision date 29-Aug-2018Supersedes Date: 29-Jul-2015
Safety Data SheetBARITE 4,1 D31
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name BARITE 4,1 D31Product code D031
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Weighting agent. Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
ContainsCrystalline silica (impurity)
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Chemical Name EC No CAS No Weight-%Crystalline silica (impurity) 238-878-4 14808-60-7 <5
3.2 Mixtures
Not applicable
CommentsThe product contains other ingredients which do not contribute to the overall classification.
This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis.
IARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz orcristobalite from occupational sources causes cancer in humans. IARC Classification Group I.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx).
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upAvoid generating or breathing dust. Take up mechanically and collect in suitable container for disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid dust formation. Do not breathe dust. Avoid contactwith skin and eyes.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Provideappropriate exhaust ventilation at places where dust is formed.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid extremetemperatures Store away from incompatibles, Hydrofluoric acid (HF) Strong oxidizingagents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptCrystalline silica (impurity) 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined
Chemical Name India Indonesian JapanCrystalline silica (impurity) Not determined 0.1 mg/m3 TWA Not determined
Chemical Name Kazakhstan Kuwait New ZealandCrystalline silica (impurity) 1 mg/m3 MAC Not determined 0.1 mg/m3 TWA
Confirmed carcinogenChemical Name Malaysia Philippines Russia
Crystalline silica (impurity) 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA
Fibrogenic substanceglass;regulated under Quartz 1123,
1124Chemical Name Thailand Vietnam Turkey
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Crystalline silica (impurity) 0.025 mg/m3 TWA Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Tightly fitting
safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious
gloves made of: Rubber Nitrile Neoprene gloves Frequent change is advisableRespiratory protection Use the indicated respiratory protection if the occupational exposure limit is exceeded
and/or in case of product release (dust) Half mask with a particle filter P2 (European NormEN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratoryprotection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor OdorlessColor Light tan - Light grayOdor threshold Not applicable
Physical state Solid
Property Values Remarks pH Not applicablepH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Explosive properties Not applicableOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid extreme temperatures. Avoid dust formation.
10.5 Incompatible materials
Hydrofluoric acid (HF). Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure Not applicableVapor density Not applicableSpecific gravity 4.1Bulk density No information availableRelative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Product information This product contains a small quantity of quartz, crystalline silica. Prolonged and repeatedexposure to concentrations of crystalline silica exceeding the workplace exposure limit(WEL) may lead to chronic lung disease such as silicosis.
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact Dust may cause mechanical irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCrystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Contains a known or suspected carcinogen. Crystalline silica dust is listed by IARC inGroup 1 as known to cause lung cancer in humans, if inhaled.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR
Toxicity to algaeThis product is not considered toxic to algae.
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Toxicity to fishThis product is not considered toxic to fish.
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesCrystalline silica (impurity) LC50 Danio rerio (zebra fish) : >
10000 mg/l 96hEC50: > 1000 mg/l 72h LC50 Daphnia manga (Water flea):
> 10000 mg/l 24h
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradabilityCrystalline silica (impurity) Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationCrystalline silica (impurity) Product/Substance is inorganic
12.4 Mobility
MobilityInsoluble in water.
Chemical Name MobilityCrystalline silica (impurity) Insoluble in water
Mobility in soilNo information available.
Chemical Name Mobility in soilCrystalline silica (impurity) Not expected to adsorb on soil
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 29-Jul-2015
Revision date 29-Aug-2018
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1*Flammability 0Physical hazard 0PPE E
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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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BARITE 4,1 D31 SDS no. D031Revision date 29-Aug-2018
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SDS no. D020Version 6Revision date 11-Oct-2018Supersedes Date: 19-Oct-2015
Safety Data SheetBentonite Extender D20
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Bentonite Extender D20Product code D020
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
ContainsCrystalline silica (impurity)
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteriaProduct dust may be irritating to eyes, skin and respiratory system
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
3.2 Mixtures
Not applicableChemical Name EC No CAS No Weight-%
Crystalline silica (impurity) 238-878-4 14808-60-7 1-5
CommentsNaturally occuring mineral.This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol.68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite fromoccupational sources causes cancer in humans. IARC Classification Group I.
The product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsDo not use water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors Nitrogen oxides (NOx).
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Material becomes slippery when wet. Use caution if wet.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upSweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Material becomes slippery when wet. Use caution if wet.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid wet and humidconditions.
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.No biological limit allocated
Component Information
Chemical Name Arabic Australia EgyptCrystalline silica (impurity) 0.1 mg/m3 TWA 0.1mg/m3TWArespirable dust Not determined
Chemical Name India Indonesian JapanCrystalline silica (impurity) Not determined 0.1 mg/m3 TWA Not determined
Chemical Name Kazakhstan Kuwait New ZealandCrystalline silica (impurity) 1 mg/m3 MAC Not determined 0.1 mg/m3 TWA
Confirmed carcinogenChemical Name Malaysia Philippines Russia
Crystalline silica (impurity) 0.1 mg/m3 TWA Not determined 3 mg/m3 STEL1 mg/m3 TWA
Fibrogenic substanceglass;regulated under Quartz 1123,
1124Chemical Name Thailand Vietnam Turkey
Crystalline silica (impurity) 0.025 mg/m3 TWA Not determined Not determined
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8.2 Exposure controls
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts
Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Wear gloves according to EN 374 to protect against skin effects from powders
Use protective gloves made of: Neoprene NitrileFrequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Suitable mask withparticle filter P3 (European Norm 143) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor OdorlessColor Cream - GrayOdor threshold Not applicable
Physical state Solid
Property Values Remarks pH 9-10pH @ dilution No information availableMelting / freezing point > 450 °C / 842 °FBoiling point/range No information availableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information available
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
Explosive properties Not applicableOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid wet and humid conditions. Avoid dust formation.
10.5 Incompatible materials
No materials to be especially mentioned.
10.6 Hazardous decomposition products
See Section 5.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Product information This product contains a small quantity of quartz, crystalline silica. Prolonged and repeatedexposure to concentrations of crystalline silica exceeding the workplace exposure limit(WEL) may lead to chronic lung disease such as silicosis.
Specific gravity 2.3 - 2.6 20 °CBulk density 750 – 950 kg/m³Relative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 500 °C / 932°FKinematic viscosity Not applicableDynamic viscosity . Not applicablelog Pow No information available
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact Dust may cause mechanical irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCrystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer inhumans, if inhaled.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.Listed on PLONOR list of OSPAR
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
aquatic invertebratesCrystalline silica (impurity) LC50 Danio rerio (zebra fish) : >
10000 mg/l 96hEC50: > 1000 mg/l 72h LC50 Daphnia manga (Water flea):
> 10000 mg/l 24h
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradabilityCrystalline silica (impurity) Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationCrystalline silica (impurity) Product/Substance is inorganic
12.4 Mobility
MobilityInsoluble in water.
Chemical Name MobilityCrystalline silica (impurity) Insoluble in water
Mobility in soilSee component information below.
Chemical Name Mobility in soilCrystalline silica (impurity) Not expected to adsorb on soil
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
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Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
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Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
_____________________________________________________________________________________________
Bentonite Extender D20 SDS no. D020Revision date 11-Oct-2018
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 19-Oct-2015
Revision date 11-Oct-2018
Version 6
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D600G Version 4 Revision date 26-Apr-2021 Supersedes Date: 15-Jul-2016
Safety Data Sheet D600G GASBLOK* Gas Migration Control Additive
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name D600G GASBLOK* Gas Migration Control Additive Product code D600G
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Gas control agent Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 Level 5, 10 Telethon Avenue Perth WA 6000
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains C12-15 alcohol ethyoxylated
Sodium dodecyl sulphate
1,4-Dioxane (Impurity)
5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-% C12-15 alcohol ethyoxylated 500-195-7 68131-39-5 1-<5
Sodium dodecyl sulphate 205-788-1 151-21-3 >= 0.1 - <0.3 1,4-Dioxane (Impurity) 204-661-8 123-91-1 <=0.1
5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
mixture 55965-84-9 < 0.0015
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
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4.2. Most important symptoms and effects, both acute and delayed
_____________________________________________________________________________________________
D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater spray, dry chemical, carbon dioxide (CO2), or foam.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsHeating of containers may cause pressure rise, with risk of bursting.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides, Sodium oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
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Environmental exposure controls
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Avoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use. Repeated or prolonged contact may cause allergic reactions in very susceptible persons. Persons susceptible to allergic reactions should not handle this product.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store away from heat and sources of ignition Avoid frost. Incompatible with materials which react with water. Avoid contact with: Strong acids Strong bases Strong oxidizing agents Strong reducing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits No biological limit allocated
Component Information
Chemical Name Arabic Australia Egypt C12-15 alcohol ethyoxylated Not determined Not determined Not determined
Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 90 ppm STEL
135 mg/m3 STEL 25 ppm TWA
90 mg/m3 TWA
10ppmTWA 36mg/m3TWA
Skin designation Suspected Human Carcinogen
20 ppm TWA 72 mg/m3 TWA
5-chloro-2-methyl-4-isothiazolin-3-one and
2-methyl-4-isothiazolin-3-one
Not determined Not determined Not determined
Chemical Name India Indonesian Japan
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D600G GASBLOK* Gas Migration Control Additive
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C12-15 alcohol ethyoxylated Not determined Not determined Not determined Sodium dodecyl sulphate Not determined Not determined Not determined
1,4-Dioxane (Impurity) Not determined 20 ppm TWA 90 mg/m3 TWA Skin notation
May cause substantial skin absorption
10 ppm ACL 1 ppm OEL
3.6 mg/m3 OEL 5-chloro-2-methyl-4-isothiazolin-3-o
ne and 2-methyl-4-isothiazolin-3-one
Not determined Not determined Not determined
Chemical Name Kazakhstan Kuwait New Zealand C12-15 alcohol ethyoxylated Not determined Not determined Not determined
Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 10 mg/m3 MAC 90.0 mg/m3 TWA
25.0 ppm TWA Skin notation
3.6 mg/m3 STEL
25 ppm TWA 90 mg/m3 TWA
Confirmed carcinogen Possibility of significant uptake
through the skin 5-chloro-2-methyl-4-isothiazolin-3-o
ne and 2-methyl-4-isothiazolin-3-one
Not determined Not determined Not determined
Chemical Name Malaysia Philippines Russia C12-15 alcohol ethyoxylated Not determined Not determined Not determined
Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 20 ppm TWA
72.1 mg/m3 TWA Skin notation
skin - potential for cutaneous absorption
100 ppm TWA 360 mg/m3 TWA
Skin notation 10 mg/m3 MAC
Skin
5-chloro-2-methyl-4-isothiazolin-3-one and
2-methyl-4-isothiazolin-3-one
Not determined Not determined Not determined
Chemical Name Thailand Vietnam Turkey C12-15 alcohol ethyoxylated Not determined Not determined Not determined
Sodium dodecyl sulphate Not determined Not determined Not determined 1,4-Dioxane (Impurity) 100 ppm TWA 10 mg/m3 TWA 20 ppm TWA
73 mg/m3 TWA 5-chloro-2-methyl-4-isothiazolin-3-o
ne and 2-methyl-4-isothiazolin-3-one
Not determined Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipment Eye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety
glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Use protective gloves made of: Neoprene Nitrile PVC Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Viscous Odor Slight Color Milky white
Density and/or Relative Density No information available
Explosive properties No information available Oxidizing properties No information available
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available
Physical state Liquid
Property Values Remarks pH 6 - 8 pH @ dilution No information available Melting / freezing point No information available Boiling point/range 100 °C / 212 °F Flash point > 100 °C / > 212 °F Closed cup Evaporation rate (BuAc =1) No information available Flammability Not applicable Explosion limits:
Upper explosion limit 12.60 %(V) Lower explosion limit 2.60 %(V)
Vapor pressure < 23.5 mmgHg (31.33 hPa) @ 25 °C Relative Vapor Density No information available Specific gravity 1.01 - 1.02 @ 20 °C Bulk density No information available Water solubility Dispersible Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)
No information available
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze. Store away from heat and sources of ignition.
10.5 Incompatible materials
Incompatible with materials which react with water. Strong acids. Strong bases. Strong oxidizing agents. Strong reducing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects Acute toxicity Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation C12-15 alcohol ethyoxylated 2.500- 5.000 mg/kg = 2500 mg/kg ( Rabbit ) No data available
Sodium dodecyl sulphate = 1288 mg/kg ( Rat ) = 200 mg/kg ( Rabbit ) > 3900 mg/m3 ( Rat ) 1 h 1,4-Dioxane (Impurity) = 4200 mg/kg ( Rat ) = 5170
mg/kg ( Rat ) = 7600 mg/kg ( Rabbit ) = 46 mg/L ( Rat ) 2 h
5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
= 53 mg/kg ( Rat ) No data available = 1.23 mg/L ( Rat ) 4 h = 0.11 mg/L ( Rat ) 4 h
Sensitization EUH208 - Contains ( 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one ). May produce an allergic reaction.
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Contains a known or suspected carcinogen.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Inhalation. Skin contact. Eye contact.
Routes of entry Skin contact.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not applicable.
11.2 Information on other hazards
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates C12-15 alcohol ethyoxylated 3.1 mg/L LC50 (Scophthalmus
maximus) = 96 h 1 - 3.2 mg/L EC50 (Skeletonema
costatum) = 72 h 0.88 mg/L LC50 (Acartia tonsa) = 48
h
Sodium dodecyl sulphate = 1.31 mg/L LC50 Cyprinus carpio 96 h 10.8 - 16.6 mg/L LC50 Poecilia
reticulata 96 h 13.5 - 18.3 mg/L LC50 Poecilia reticulata 96 h 6.2 -
9.6 mg/L LC50 Pimephales promelas 96 h 10.2 - 22.5 mg/L
LC50 Pimephales promelas 96 h 5.8 - 7.5 mg/L LC50 Pimephales promelas 96 h = 4.5 mg/L LC50
Lepomis macrochirus 96 h 4.2 - 4.8 mg/L LC50 Lepomis macrochirus 96
h 4.06 - 5.75 mg/L LC50 Lepomis macrochirus 96 h 9.9 - 20.1 mg/L
LC50 Brachydanio rerio 96 h = 7.97 mg/L LC50 Brachydanio rerio 96 h =
4.2 mg/L LC50 Oncorhynchus mykiss 96 h = 4.62 mg/L LC50
Oncorhynchus mykiss 96 h 4.3 - 8.5
= 42 mg/L EC50 Desmodesmus subspicatus 96 h = 117 mg/L EC50 Pseudokirchneriella subcapitata 96 h = 53 mg/L EC50 Desmodesmus subspicatus 72 h 30 - 100 mg/L
EC50 Desmodesmus subspicatus 96 h 3.59 - 15.6 mg/L EC50
Pseudokirchneriella subcapitata 96 h
= 1.8 mg/L EC50 Daphnia magna 48 h = 21.2 mg/L EC50 Daphnia
magna 24 h
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
mg/L LC50 Oncorhynchus mykiss 96 h 22.1 - 22.8 mg/L LC50
Pimephales promelas 96 h 15 - 18.9 mg/L LC50 Pimephales promelas
96 h 8 - 12.5 mg/L LC50 Pimephales promelas 96 h = 4.1 mg/L LC50 Leuciscus idus 48 h
1,4-Dioxane (Impurity) = 9850 mg/L LC50 Pimephales promelas 96 h 10306 - 14742 mg/L LC50 Pimephales promelas 96 h >
10000 mg/L LC50 Lepomis macrochirus 96 h
No information available = 163 mg/L EC50 water flea 48 h
5-chloro-2-methyl-4-isothiazolin-3-one and
2-methyl-4-isothiazolin-3-one
= 1.6 mg/L LC50 Oncorhynchus mykiss 96 h
0.11 - 0.16 mg/L EC50 Pseudokirchneriella subcapitata 72
h 0.03 - 0.13 mg/L EC50 Pseudokirchneriella subcapitata 96
h = 0.31 mg/L EC50 Anabaena flos-aquae 120 h
0.12 - 0.3 mg/L EC50 Daphnia magna 48 h 0.71 - 0.99 mg/L EC50 Daphnia magna 48 h = 4.71 mg/L
EC50 Daphnia magna 48 h
12.2 Persistence and degradability
See component information below.
Chemical Name Persistence and degradability C12-15 alcohol ethyoxylated Readily degradable in marine screening test
12.3 Bioaccumulative potential
See component information below.
Chemical Name Bioaccumulation C12-15 alcohol ethyoxylated Not likely to bioaccumulate
12.4 Mobility
MobilityDispersible in water. See component information below.
Chemical Name Mobility C12-15 alcohol ethyoxylated Soluble in water
Mobility in soilSee component information below.
Chemical Name Mobility in soil C12-15 alcohol ethyoxylated No information available
12.5 Other adverse effects
None known. Check for additional information in sect. 7.
12.6 Other information.
Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
Marine pollutantNo
14.6 Special precautions Not applicable
14.7 Maritime transport in bulk according to IMO instruments Please contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons 1,4-Dioxane (Impurity) Schedule 6 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one Schedule 6
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
Safe Work Australia.
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/2013] (CLASS Regulations) The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies Canada (DSL) Does not comply Philippines (PICCS) Does not comply Japan (ENCS) Does not comply China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory
Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam
Supersedes Date: 15-Jul-2016
Revision date 26-Apr-2021
Version 4
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1 Flammability 1 Physical hazard 0 PPE B
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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
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D600G GASBLOK* Gas Migration Control Additive
SDS no. D600G Revision date 26-Apr-2021
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D110Version 3Revision date 06-Jun-2018Supersedes Date: 20-Feb-2015
Safety Data SheetCement Retarder D110
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Retarder D110Product code D110
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Thermal decomposition can lead to release of irritating gases and vapors
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
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6.4 Reference to other sections
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Do not freeze Storeabove 0°C Store away from incompatibles, Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only. High density polyethylene (HDPE) drum
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical Use eye protection
according to EN 166, designed to protect against liquid splashes Tightly fitting safetygoggles
Hand protection Wear chemical resistant gloves such as nitrile or neoprene. Repeated or prolonged contactRubber gloves Neoprene NitrileBreak through time >480 minutesGlove thickness 0.5 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
ventilation wear suitable respiratory equipment Respirator with combination filter forvapour/particulate (EN 141) Type A/P2
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance OpaqueOdor SweetColor BrownOdor threshold Not applicable
Explosive properties None knownOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information available
Physical state Liquid
Property Values Remarks pH 6 - 9pH @ dilution No information availableMelting / freezing point -4 °C / 24.8 °FBoiling point/range 100 °C / 212 °FFlash point > 100 °C / > 212 °FEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity 1.14 20 °CBulk density No information availableRelative density No information availableWater solubility SolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature >242°C / >467.6 °FKinematic viscosity No information availableDynamic viscosity 1.5cst @ 40 °Clog Pow Does not bioaccumulate
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
VOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze. Store above 0°C.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact.
Routes of entry No route of entry noted.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishNot considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesNot considered toxic.
12.2 Persistence and degradability
Product is biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues / unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Does not comply
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 20-Feb-2015
Revision date 06-Jun-2018
Version 3
This SDS has been revised in thefollowing section(s)
1, 2, 7, 8, 9, 10, 11, 15, 16No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1Flammability 1Physical hazard 0PPE E
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Cement Retarder D110 SDS no. D110Revision date 06-Jun-2018
DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.
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SDS no. S001Version 3Revision date 09-Oct-2018Supersedes Date: 13-Mar-2015
Safety Data SheetCalcium Chloride S1
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Calcium Chloride S1Product code S001
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazardsSerious eye damage/eye irritation Category 2
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
Signal wordWARNING
Hazard StatementsH319 - Causes serious eye irritation
Precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves and eye/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP308 + P313 - IF exposed or concerned: Get medical advice/attentionP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
ContainsCalcium chloride
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%Calcium chloride 233-140-8 10043-52-4 60 - 100
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
clothes and shoes. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Continue to rinse for at least 15 minutes. Get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.
Methods for cleaning upAvoid generating or breathing dust. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traceswith water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid: Hightemperatures. Avoid contact with water and moist air - product is hygroscopic. SteelBromine trifluoride. Furan-2-peroxycarboxylic acid. Acids
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Component Information
Chemical Name Arabic Australia EgyptCalcium chloride Not determined Not determined Not determinedChemical Name India Indonesian JapanCalcium chloride Not determined Not determined Not determinedChemical Name Kazakhstan Kuwait New ZealandCalcium chloride Not determined Not determined Not determinedChemical Name Malaysia Philippines RussiaCalcium chloride Not determined Not determined 2 mg/m³ MAC (aerosol)Chemical Name Thailand Vietnam TurkeyCalcium chloride Not determined Not determined Not determined
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts It is good
practice to wear goggles when handling any chemical Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders Use
protective gloves made of: polyvinyl alcohol or nitrile-butyl rubber gloves Frequent changeis advisable
Respiratory protection No personal respiratory protective equipment normally required In case of insufficientventilation wear suitable respiratory equipment Effective dust mask. Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance GranulesOdor OdorlessColor WhiteOdor threshold Not applicable
Physical state Solid
Property Values Remarks pH No information availablepH @ dilution 9 - 10.5 (100 g/l soln @20°C)Melting / freezing point No information availableBoiling point/range > 1600 °CFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
Hygroscopic.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Avoid contact with water and moist air - product is hygroscopic. High temperatures.
10.5 Incompatible materials
Water. Bromine trifluoride. Furan-2-peroxycarboxylic acid. Acids. Steel.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density 800 mg/m3
Relative density 2.2 @ 20°C.Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature >772°CKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.
Eye contact Causes serious eye irritation.
Skin contact May cause skin irritation and/or dermatitis.
Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCalcium chloride = 1000 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Eye contact. Inhalation.
Routes of entry Eye contact. Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard No hazard from product as supplied.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesCalcium chloride = 10650 mg/L LC50 Lepomis
macrochirus 96 hNo information available 2,400 mg/L EC50 (Daphnia magna)
= 48 h
12.2 Persistence and degradability
Not Applicable - Inorganic chemical.
Chemical Name Persistence and degradabilityCalcium chloride Inorganic compound
12.3 Bioaccumulative potential
Not Applicable - Inorganic chemical.
Chemical Name BioaccumulationCalcium chloride Product/Substance is inorganic
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Chemical Name MobilityCalcium chloride Soluble in water
Mobility in soilSee component information below.
Chemical Name Mobility in soilCalcium chloride After release, disperses through ground water
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations.
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
products
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocatedNew Zealand Hazard Classification Classified
HSNO approval no. HSR003389
Group number 6.1D, 6.1E, 6.3A, 6.4A, 9.3C
Safe Work Australia.
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) Complies
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Calcium Chloride S1 SDS no. S001Revision date 09-Oct-2018
Canada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 13-Mar-2015
Revision date 09-Oct-2018
Version 3
This SDS has been revised in thefollowing section(s)
1, 7, 8, 12, 15, 16No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D161 Version 6 Revision date 15-Mar-2021 Supersedes Date: 11-Feb-2016
Safety Data Sheet Multi-Temperature Cement Retarder D161
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Multi-Temperature Cement Retarder D161 Product code D161
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Reproductive toxicity Category 2
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
Signal wordWARNING
Hazard StatementsH361 - Suspected of damaging fertility or the unborn child
Precautionary statements P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP280 - Wear protective gloves/protective clothing/eye protection/face protectionP308 + P313 - IF exposed or concerned: Get medical advice/attentionP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
Contains Sodium pentaborate
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-% Sodium pentaborate 234-522-7 12007-92-0 5-10
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek medical attention if irritation occurs.
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Oxides of phosphorus, Carbon oxides (COx), Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use. Not to be used by pregnant workers and workers who have recently given birth or who are breastfeeding.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store away from heat and sources of ignition Avoid extreme temperatures Store above 0°C Store away from incompatibles, Strong reducing agents Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits Contains no substances with occupational exposure limit values
Component Information
Chemical Name Arabic Australia Egypt Sodium pentaborate Not determined Not determined Not determined
Chemical Name India Indonesian Japan Sodium pentaborate Not determined Not determined Not determined
Chemical Name Kazakhstan Kuwait New Zealand Sodium pentaborate Not determined Not determined Not determined
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
Chemical Name Malaysia Philippines Russia Sodium pentaborate Not determined Not determined Not determined
Chemical Name Thailand Vietnam Turkey Sodium pentaborate Not determined Not determined Not determined
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.
Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety goggles Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Nitrile PVA PVC Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with a vapor filter (EN 141) Chemical respirator with inorganic vapour cartridge (Grey B). At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Clear Odor Slight Color Colorless Odor threshold Not applicable
Physical state
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Liquid
_____________________________________________________________________________________________
Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
Explosive properties Not applicable Oxidizing properties None known.
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) None Density 1.073 - 1.077 g/ml @ 20 °C
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid extreme temperatures. Do not freeze.
10.5 Incompatible materials
Strong oxidizing agents. Strong reducing agents.
10.6 Hazardous decomposition products
Property Values Remarks pH 6.9 pH @ dilution No information available Melting / freezing point ~0 °C / 32 °F Boiling point/range 100 °C / 212 °F Flash point Non-flammable Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air
Upper flammability limit Not applicable Lower flammability limit Not applicable
Vapor pressure No information available Vapor density No information available Specific gravity No information available Bulk density No information available Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available log Pow No information available
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort. May cause damage to organs through prolonged or repeated exposure.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium pentaborate No data available LD50 > 2000 mg/kg bw LC50 > 2.03 mg/l
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard.
Routes of Exposure Skin contact. Eye contact. Ingestion.
Routes of entry Ingestion.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates Sodium pentaborate LC50: 600 mg/l 96h No information available LC50: 86 mg/l 48h
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused Dispose of in accordance with local regulations.
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Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
products
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/2013] (CLASS Regulations) The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
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_____________________________________________________________________________________________
Multi-Temperature Cement Retarder D161
SDS no. D161 Revision date 15-Mar-2021
International inventories
USA (TSCA) Complies Canada (DSL) Complies Volume restriction. Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply Eurasian Economic Union: Russian Inventory
Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong
Supersedes Date: 11-Feb-2016
Revision date 15-Mar-2021
Version 6
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D080 Version 4 Revision date 10-Feb-2021 Supersedes Date: 22-Jan-2016
Safety Data Sheet Cement Liquid Dispersant D80
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Cement Liquid Dispersant D80 Product code D080
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Chronic aquatic toxicity Category 2
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
Signal wordNone
Hazard StatementsH411 - Toxic to aquatic life with long lasting effects
Precautionary statements P273 - Avoid release to the environmentP391 - Collect spillageP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
Contains Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureHAZARDOUS SUBSTANCE. DANGEROUS GOODS.Classified as Hazardous according to the criteria of NOHSC.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-% Naphthalenesulfonic acid, sodium salt, polymer with
formaldehyde Polymer 9008-63-3 30-60
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if symptoms occur.
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
Hazchem code ADG 3Z
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
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Use personal protective equipment. See also section 8.
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upContain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see Section 13). After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills and splashing during use. Do not breathe vapors or spray mist.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately after handling the product Do not eat, drink or smoke when using this product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Do not freeze Store above 0°C Avoid contact with: Oxidizing agents Acids
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limits established.
Component Information
Chemical Name Arabic Australia Egypt Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
Not determined Not determined Not determined
Chemical Name India Indonesian Japan Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
Not determined Not determined Not determined
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
Chemical Name Kazakhstan Kuwait New Zealand Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
Not determined Not determined Not determined
Chemical Name Malaysia Philippines Russia Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
Not determined Not determined Not determined
Chemical Name Thailand Vietnam Turkey Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
Not determined Not determined Not determined
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation, especially in confined areas
Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against liquid splashes Tightly
fitting safety goggles Safety glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Wear chemical resistant gloves such as nitrile or neoprene. Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Opaque Odor Pungent
Physical state
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Liquid
_____________________________________________________________________________________________
Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
Color Dark brown Odor threshold Not applicable
Explosive properties No information available Oxidizing properties No information available
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze. Store above 0°C.
Property Values Remarks pH 6 - 8 pH @ dilution No information available Melting / freezing point - 2 °C/ 28 °F
Boiling point/range 100 °C / 212 °F
Flash point Does not flash Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air
Upper flammability limit Not applicable Lower flammability limit Not applicable
Vapor pressure No information available Vapor density > 1 (air = 1) Specific gravity 1.2 g/cm3 20 °C Bulk density No information available Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity 60 mPa s log Pow No information available
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
10.5 Incompatible materials
Oxidizing agents. Acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Naphthalenesulfonic acid, sodium salt, polymer
with formaldehyde No data available No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure None known.
Routes of entry No route of entry noted.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
12.1 Toxicity
Toxic to aquatic life with long lasting effects
Toxicity to algaeEC50 1.46 mg/l Skeletonema Costatum 48 h.
Toxicity to fishNot considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesLC50 > 100 mg/l Acartia tonsa 48 h.
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates Naphthalenesulfonic acid, sodium salt, polymer with formaldehyde
No information available No information available No information available
12.2 Persistence and degradability
Product is not biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number UN/ID No. (ADR/RID/ADN/ADG) UN3082 UN No. (IMDG/ANTAQ) UN3082 UN No. (ICAO/ANAC) UN3082
14.2. UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Sodium polynaphthalene sulfonate)
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class 9 IMDG/ANTAQ Hazard class 9 ICAO/ANAC Hazard class/division 9
14.4 Packing group ADR/RID/ADN/ADG Packing group III IMDG/ANTAQ Packing group III ICAO/ANAC Packing group III
14.5 Environmental hazard Yes
14.6 Special precautions Hazard identification no (ADR) 90 EmS (IMDG) F-A, S-F Emergency Action Code (EAC) 3Z Tunnel restriction code (-) Hazchem code ADG 3Z
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Construction Products (Subsidiary Hazard) Group Standard 2020
HSNO approval no. HSR002544
Group number 9.1B
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
ADG Code – Australian Dangerous Goods Code
International inventories
USA (TSCA) Complies Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory
Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam
Supersedes Date: 22-Jan-2016
Revision date 10-Feb-2021
Version 4
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
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Cement Liquid Dispersant D80 SDS no. D080 Revision date 10-Feb-2021
Health 1 Flammability 1 Physical hazard 0 PPE B
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D186Version 8Revision date 23-Aug-2019Supersedes Date: 10-Feb-2016
Safety Data SheetLow Temperature Cement Set Enhancer D186
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Low Temperature Cement Set Enhancer D186Product code D186
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazardsAcute toxicity - Oral Category 4Serious eye damage/eye irritation Category 1
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Signal wordDANGER
Hazard StatementsH302 - Harmful if swallowedH318 - Causes serious eye damage
Precautionary statements P270 - Do not eat, drink or smoke when using this productP280 - Wear protective gloves/protective clothing/eye protection/face protectionP301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable
Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP330 - Rinse mouthP391 - Collect spillage
ContainsCalcium nitrate
2,2' -oxydiethanol
Calcium Bromide
2,2'-Methyliminodiethanol
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%Calcium nitrate 233-332-1 10124-37-5 10-30
2,2' -oxydiethanol 203-872-2 111-46-6 1-5Calcium Bromide 232-164-6 7789-41-5 1-5
2,2'-Methyliminodiethanol 203-312-7 105-59-9 1-5
CommentsThe product contains other ingredients which do not contribute to the overall classification.
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting. If conscious, give 2 glasses of water. Get immediatemedical attention. Never give anything by mouth to an unconscious person.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Seek medical attention if irritation occurs.
Eye Contact Remove contact lenses, if worn. Immediately flush eyes with water for 15 minutes whileholding eyelids open. Seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsThermal decomposition can lead to release of irritating gases and vapors.
Hazardous combustion productsFire or high temperatures create: Ammonia, Nitrogen oxides (NOx), Carbon oxides (COx).
5.3 Advice for firefighters
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective gloves/clothing and eye/face protection. Avoid contact with eyes. Do not get on skin or clothing. Wash thoroughlyafter handling. See also section 8.
6.2 Environmental precautions
Prevent further leakage or spillage. The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Washthoroughly with soap and water after handling and before eating, drinking, or using tobacco. Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Acids Bases Strong reducing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Component Information
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Chemical Name Arabic Australia EgyptCalcium nitrate Not determined Not determined Not determined
2,2' -oxydiethanol Not determined 23ppmTWA100mg/m3TWA
Not determined
Calcium Bromide Not determined Not determined Not determined2,2'-Methyliminodiethanol Not determined Not determined Not determined
Chemical Name India Indonesian JapanCalcium nitrate Not determined Not determined Not determined
2,2' -oxydiethanol Not determined Not determined Not determinedCalcium Bromide Not determined Not determined Not determined
2,2'-Methyliminodiethanol Not determined Not determined Not determinedChemical Name Kazakhstan Kuwait New ZealandCalcium nitrate Not determined Not determined Not determined
2,2' -oxydiethanol 10 mg/m3 MAC Not determined 23 ppm TWA101 mg/m3 TWA
Calcium Bromide Not determined Not determined Not determined2,2'-Methyliminodiethanol Not determined Not determined Not determined
Chemical Name Malaysia Philippines RussiaCalcium nitrate Not determined Not determined Not determined
2,2' -oxydiethanol Not determined Not determined 10 mg/m3 MACCalcium Bromide Not determined Not determined Not determined
2,2'-Methyliminodiethanol Not determined Not determined Not determinedChemical Name Thailand Vietnam TurkeyCalcium nitrate Not determined Not determined Not determined
2,2' -oxydiethanol Not determined Not determined Not determinedCalcium Bromide Not determined Not determined Not determined
2,2'-Methyliminodiethanol Not determined Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Local exhaust ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Tightly
fitting safety goggles Safety glasses with side-shieldsHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
trainingImpervious gloves made of: Nitrile PVCBreak through time >480 minutesGlove thickness 0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator with avapor filter (EN 141) Use respirator with organic vapor/acid gas protection (E, yellow) Atwork in confined or poorly ventilated spaces, respiratory protection with air supply must beused.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before breaks and immediately after handling the product
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance No information availableOdor NoneColor Light greenOdor threshold Not applicable
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
Physical state Liquid
Property Values Remarks pH 8 - 10pH @ dilution No information availableMelting / freezing point < -21 °C / -7 °FBoiling point/range ~ 108 °C / 226 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure ~2 kPa @ 25 °CVapor density 1 (air = 1)Specific gravity 1.4Bulk density No information availableRelative density 1.4Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature 538 °C / 1000 °F
Kinematic viscosity No information availableDynamic viscosity 2 mPa s @ 15.5 °Clog Pow No information available
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationNone under normal processing.
10.4 Conditions to avoid
Do not allow liquid to evaporate. Dry material is a strong oxidizer.
10.5 Incompatible materials
Acids. Bases. Strong reducing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Vapors may irritate throat and respiratory system.
Eye contact Causes serious eye damage.
Skin contact Irritating to skin. Substance may cause slight skin irritation.
Ingestion Harmful if swallowed.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationCalcium nitrate No data available No data available No data available
2,2' -oxydiethanol = 12565 mg/kg ( Rat ) = 11890 mg/kg ( Rabbit ) > 4600 mg/m3 ( Rat ) 4 hCalcium Bromide = 4100 mg/kg ( Rat ) No data available No data available
2,2'-Methyliminodiethanol No data available No data available No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Eye contact. Inhalation. Ingestion.
Routes of entry Skin contact. Eye contact. Inhalation. Ingestion.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic organisms.
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebratesCalcium nitrate No information available No information available No information available
2,2' -oxydiethanol = 75200 mg/L LC50 Pimephalespromelas 96 h
No information available = 84000 mg/L EC50 Daphniamagna 48 h
Calcium Bromide No information available No information available No information available2,2'-Methyliminodiethanol No information available No information available No information available
12.2 Persistence and degradability
Not readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility
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MobilityThe product is water soluble, and may spread in water systems.
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Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
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_____________________________________________________________________________________________
Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and Poisons
2,2' -oxydiethanolSchedule 6Schedule 5Calcium BromideSchedule 4
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong
Supersedes Date: 10-Feb-2016
Revision date 23-Aug-2019
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_____________________________________________________________________________________________
Low Temperature Cement SetEnhancer D186
SDS no. D186Revision date 23-Aug-2019
Version 8
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made. Updated accordingto GHS/CLP.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 3Flammability 1Physical hazard 0PPE X
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D182Version 3Revision date 06-Jul-2020Supersedes Date: 05-Apr-2017
Safety Data SheetMUDPUSH* II Spacer D182
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name MUDPUSH* II Spacer D182Product code D182
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
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MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsDust may form explosive mixture in air.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulphur oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upSweep up and shovel into suitable containers for disposal. Take precautionary measures against static discharges. After cleaning,flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and Storage
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MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Material becomes slippery when wet. Use caution if wet.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from openflames, hot surfaces and sources of ignition Keep away from direct sunlight. Incompatiblewith oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety gogglesHand protection Wear gloves according to EN 374 to protect against skin effects from powders
Use protective gloves made of: Rubber Neoprene NitrileFrequent change is advisable
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with aparticle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
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MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor Mild SweetColor Red brownOdor threshold Not applicable
Explosive properties Suspended dust may present a dust explosion hazardOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
Physical state Solid
Property Values Remarks pH No information availablepH @ dilution ~8 650g/l (Soln)Melting / freezing point No information availableBoiling point/range Not applicableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure Not applicableVapor density Not applicableSpecific gravity 1.3 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Partly soluble Gel in contact with
waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 242 °C / 468 °F
Kinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
10. Stability and Reactivity
10.1 Reactivity
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Keep away from open flames, hot surfaces and sources of ignition. Keep away from direct sunlight. Takeprecautionary measures against static charges.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.
Eye contact Dust contact with the eyes can lead to mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Inhalation. Skin contact. Eye contact.
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MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
Routes of entry No route of entry noted.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility
MobilityPartly soluble. Gel in contact with water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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_____________________________________________________________________________________________
MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
_____________________________________________________________________________________________
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Australian Standard for the Uniform Scheduling of Drugs and Poisons
_____________________________________________________________________________________________
MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
No poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong
Supersedes Date: 05-Apr-2017
Revision date 06-Jul-2020
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
_____________________________________________________________________________________________
Page 9 / 10
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on
_____________________________________________________________________________________________
MUDPUSH* II Spacer D182 SDS no. D182Revision date 06-Jul-2020
measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D256Version 2Revision date 11-Jul-2019Supersedes Date: 11-Apr-2016
Safety Data SheetMid-Range liquid FLAC D256
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Mid-Range liquid FLAC D256Product code D256
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia, Sulfur oxides, Hydrogen cyanide(hydrocyanic acid) may be produced in the event of combustion in an oxygen deficient atmosphere.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Contaminated surfaces will be extremely slippery.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
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_____________________________________________________________________________________________
Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.Repeated or prolonged contact may cause allergic reactions in very susceptible persons.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away fromdirect sunlight. Avoid excessive heat for prolonged periods of time. Protect from freezingAvoid contact with: Oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Butyl Neoprene Nitrile RubberBreak through time >480 minutesGlove thickness >=0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficientventilation wear suitable respiratory equipment Respirator with a vapor filter (EN 141) Userespirator with organic vapor protection (A, brown) At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance ClearOdor SlightColor Light yellowOdor threshold Not applicable
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
Physical state Liquid
Property Values Remarks pH 3 - 7pH @ dilution No information availableMelting / freezing point < 5 °C / 41 °FBoiling point/range > 100 °C / 212 °FFlash point Does not flashEvaporation rate (BuAc =1) Similar to water.Flammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure 2.3 kPa @ 20°CVapor density Similar to water.Specific gravity 1.0 - 1.3Bulk density No information availableRelative density 1.0-1.3Water solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 100°C / 212°F
Kinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Protect from freezing. Keep away from direct sunlight. Avoid excessive heat for prolonged periods of time.
10.5 Incompatible materials
Incompatible with oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing >0.1%.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity Contains a known or suspected carcinogen.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards atconcentrations >0.1%.
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
Routes of Exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation. Skin contact. Eye contact.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Not readily biodegradable.
12.3 Bioaccumulative potential
Product has a low potential to bioconcentrate.
12.4 Mobility
MobilityThe product is miscible with water. May spread in water systems.
Mobility in soilNo information available.
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12.5 Results of PBT and vPvB assessment
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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This safety data sheet complies with the requirements of:
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Not classified
HSNO approval no. not required
Group number Not required
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) Does not complyAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 11-Apr-2016
Revision date 11-Jul-2019
Version 2
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
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Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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Mid-Range liquid FLAC D256 SDS no. D256Revision date 11-Jul-2019
HMIS classification
Health 0Flammability 0Physical hazard 0PPE B
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D255 Version 3 Revision date 11-Jul-2019 Supersedes Date: 04-Jan-2018
Safety Data Sheet Mid-Range FLAC D255
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Mid-Range FLAC D255 Product code D255
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains 2-methylpropan-2-ol
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Suspended dust may present a dust explosion hazard
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-% 2-methylpropan-2-ol 200-889-7 75-65-0 <5
CommentsThe product contains other ingredients which do not contribute to the overall classification.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsDust may form explosive mixture in air.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Nitrogen oxides (NOx), Ammonia, Hydrogen cyanide (hydrocyanic acid).
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
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Methods for containment
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.
Methods for cleaning upAvoid generating or breathing dust. Take precautionary measures against static discharges. Take up mechanically and collect in suitable container for disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Do not breathe dust. Material becomes slippery when wet. Use caution if wet.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Take precautionary measures against static discharges.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from open flames, hot surfaces and sources of ignition Avoid excessive heat for prolonged periods of time. Keep away from direct sunlight. Incompatible with oxidizing agents Strong acids
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust. No biological limit allocated
Component Information
Chemical Name Arabic Australia Egypt 2-methylpropan-2-ol 100 ppm TWA
303 mg/m3 TWA 150ppmSTEL
455mg/m3STEL 100ppmTWA
303mg/m3TWA
100 ppm TWA 303 mg/m3 TWA
Chemical Name India Indonesian Japan 2-methylpropan-2-ol Not determined 100 ppm TWA
303 mg/m3 TWA 50 ppm OEL
150 mg/m3 OEL Chemical Name Kazakhstan Kuwait New Zealand
2-methylpropan-2-ol 10 mg/m3 MAC Not determined 150 ppm STEL 455 mg/m3 STEL
100 ppm TWA 303 mg/m3 TWA
Chemical Name Malaysia Philippines Russia 2-methylpropan-2-ol 100 ppm TWA
303 mg/m3 TWA 100 ppm TWA
300 mg/m3 TWA 10 mg/m3 MAC
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Chemical Name Thailand Vietnam Turkey 2-methylpropan-2-ol 100 ppm TWA Not determined Not determined
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipment Eye protection Use eye protection according to EN 166, designed to protect against dusts Safety glasses
with side-shields Tightly fitting safety goggles Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious
gloves made of: Rubber gloves Butyl Neoprene Nitrile Frequent change is advisable Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a
particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Granules Odor None Color White Odor threshold Not applicable
Physical state Solid
Property Values Remarks pH Not applicable pH @ dilution 4 - 9 @ 5 g/l Melting / freezing point > 250 °C / 482 °F Boiling point/range Not applicable Flash point Not applicable Evaporation rate (BuAc =1) Not applicable Flammability (solid, gas) Not applicable Flammability Limit in Air
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Explosive properties Suspended dust may present a dust explosion hazard Oxidizing properties None known.
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) No information available Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Keep away from direct sunlight. Avoid excessive heat for prolonged periods of time. Keep away from open flames, hot surfaces and sources of ignition.
10.5 Incompatible materials
Incompatible with oxidizing agents. Strong acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Upper flammability limit Not applicable Lower flammability limit Not applicable
Vapor pressure Not applicable Vapor density Not applicable Specific gravity 1.15 - 1.35 Bulk density ~ 0.20 - 0.40 Relative density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature >150°C / >302° F Kinematic viscosity No information available Dynamic viscosity No information available log Pow No information available
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Acute toxicity
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact Dust may cause mechanical irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation 2-methylpropan-2-ol = 2200 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) > 10000 ppm ( Rat ) 4 h
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Eye contact. Inhalation.
Routes of entry Inhalation.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates 2-methylpropan-2-ol 6130 - 6700 mg/L LC50 Pimephales
promelas 96 h > 1000 mg/L EC50 Desmodesmus
subspicatus 72 h 4607 - 6577 mg/L EC50 Daphnia
magna 48 h = 933 mg/L EC50 Daphnia magna 48 h
12.2 Persistence and degradability
Not readily biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
log Pow<0
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
International inventories
USA (TSCA) Does not comply
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Mid-Range FLAC D255 SDS no. D255 Revision date 11-Jul-2019
Canada (DSL) Complies Philippines (PICCS) Philippine PICCS - Components are listed or exempt from listing. Japan (ENCS) Does not comply China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Does not comply New Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam
Supersedes Date: 04-Jan-2018
Revision date 11-Jul-2019
Version 3
This SDS has been revised in the following section(s)
15. Regulatory Information No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1 Flammability 1 Physical hazard 0 PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D168Version 4Revision date 23-Mar-2018Supersedes Date: 19-Feb-2015
Safety Data SheetUNIFLAC* L D168
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name UNIFLAC* L D168Product code D168
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.
Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsHigh volume water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors Nitrogen oxides (NOx), Sulphur oxides.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Contaminated surfaces will be extremely slippery. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and Storage
_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. If spilled, take caution, as material can cause surfaces to become very slippery.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide sufficient air exchange and/or exhaust in work rooms.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Store above freezingtemperature Store away from incompatibles, Oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsProvide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Butyl Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact Eye wash andemergency shower must be available at the work place.
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solutionOdor OdorlessColor White - Light yellowOdor threshold Not applicable
Explosive properties No information availableOxidizing properties Not applicable
9.2 Other information Pour point -6°C / 21.2 °F
Molecular weight No information availableVOC content(%) NoneDensity 1.06 g/cm³ (20°C)
Comments
Physical state Liquid
Property Values Remarks pH 7 @ 20 °CpH @ dilution 10 g/lMelting / freezing point 0 °C / 32 °FBoiling point/range 100 °C / 212 °FFlash point Not applicableEvaporation rate (BuAc =1) Similar to water.Flammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure 2.34 kPa @ 20 °CVapor density No information availableSpecific gravity 1.06 g/cm3 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature 500 °C / 932 °FDecomposition temperature 260 °C / 500 °F
Kinematic viscosity No information availableDynamic viscosity 2000 - 4000 mPa slog Pow No information available
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
The data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Do not freeze.
10.5 Incompatible materials
Oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Skin contact. Eye contact. Inhalation.
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
Routes of entry No route of entry noted.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilityThe product is miscible with water. May spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
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Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
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UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
New Zealand Hazard Classification Not classified
HSNO approval no. Not applicable
Group number Not applicable
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not complyJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) Does not complyNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 19-Feb-2015
Revision date 23-Mar-2018
Version 4
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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_____________________________________________________________________________________________
UNIFLAC* L D168 SDS no. D168Revision date 23-Mar-2018
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D065 Version 6 Revision date 08-Jun-2021 Supersedes Date: 18-Jun-2014
Safety Data Sheet TIC* D65 Dispersant
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name TIC* D65 Dispersant Product code D065 Country Limitations This SDS is not for use in the European Union (EU).
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518, Canada 001 613 996 6666
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 Level 5, 10 Telethon Avenue Perth WA 6000
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains Sodium sulfate (Impurity)
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Combustible dust
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Chemical Name EC No CAS No Weight-% Sodium sulfate (Impurity) 231-820-9 7757-82-6 1-5
3.2 Mixtures
Not applicable
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek medical attention if irritation occurs.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsSuspended dust may present a dust explosion hazard.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Sulfur dioxide.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Keep away from combustible material. Avoid contact with heat, sparks, open flame, and static discharge. Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
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Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Methods for cleaning upAvoid dust formation. Do not dry sweep dust. Wet dust with water before sweeping or use a vacuum to collect dust. Take precautionary measures against static discharges. Use non-sparking tools and equipment. After cleaning, flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid handling causing generation of dust. All equipment used when handling the product must be grounded. Avoid breathing dust; if exposed to high dust concentration, leave area immediately. Fine dust dispersed in air may ignite. Take precautionary measures against static discharges.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed. Keep airborne concentrations below exposure limits. Take precautionary measures against static discharges. Ensure all equipment is electrically grounded before beginning transfer operations.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from direct sunlight. Protect from moisture
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust. Control as an ACGIH particulate not otherwise specified (PNOS): 10 mg/m3 (Inhalable); 3 mg/m3 (Respirable) and an OSHA particulate not otherwise regulated (PNOR): 15 mg/m3 (Total); 5 mg/m3 (Respirable).
Component Information
Chemical Name Arabic Australia Egypt Sodium sulfate (Impurity) Not determined Not determined Not determined
Chemical Name India Indonesian Japan Sodium sulfate (Impurity) Not determined Not determined Not determined
Chemical Name Kazakhstan Kuwait New Zealand Sodium sulfate (Impurity) 10 mg/m3 MAC Not determined Not determined
Chemical Name Malaysia Philippines Russia Sodium sulfate (Impurity) Not determined Not determined 10 mg/m3 MAC
Chemical Name Thailand Vietnam Turkey Sodium sulfate (Impurity) Not determined Not determined Not determined
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipment Eye protection Tightly fitting safety goggles Safety glasses with side-shields Hand protection Use protective gloves made of: Nitrile Neoprene
Frequent change is advisable Respiratory protection No personal respiratory protective equipment normally required In case of insufficient
ventilation wear suitable respiratory equipment Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust) Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the work place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Powder Odor Faint Color Tan
Physical state Solid
Property Values Remarks pH Approximately 10 pH @ dilution No information available Melting / freezing point No information available Boiling point/range Not applicable Flash point Does not flash Evaporation rate (BuAc =1) Not applicable Flammability Not applicable Explosion limits:
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Density and/or Relative Density No information available
Explosive properties Suspended dust may present a dust explosion hazard Oxidizing properties None known.
9.2 Other information Pour point No information available Molecular weight No information available VOC content(%) None
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Avoid contact with heat, sparks, open flame, and static discharge. Protect from moisture. Keep away from direct sunlight.
10.5 Incompatible materials
No materials to be especially mentioned.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological information
11.1 Information on toxicological effects Acute toxicity
Upper explosion limit No information available Lower explosion limit No information available
Vapor pressure Not applicable Relative Vapor Density Not applicable Specific gravity 0.8 20 °C Bulk density No information available Water solubility Soluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Partition Coefficient (n-octanol/water)
No information available
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.
Eye contact Dust may cause mechanical irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium sulfate (Impurity) > 10000 mg/kg ( Rat ) > 4 g/kg ( Rabbit ) No data available
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not classified.
11.2 Information on other hazards
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeSee component information below.
Toxicity to fishSee component information below.
Toxicity to daphnia and other aquatic invertebratesSee component information below.
Toxicology data for the components Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
aquatic invertebrates Sodium sulfate (Impurity) = 13500 mg/L LC50 Lepomis No information available = 630 mg/L EC50 Daphnia magna
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
macrochirus 96 h 3040 - 4380 mg/L LC50 Lepomis macrochirus 96 h >
6800 mg/L LC50 Pimephales promelas 96 h 13500 - 14500 mg/L LC50 Pimephales promelas 96 h
96 h = 2564 mg/L EC50 Daphnia magna 48 h
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Other adverse effects
None known.
12.6 Other information.
Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated
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TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Maritime transport in bulk according to IMO instruments Please contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
International inventories
USA (TSCA) Complies Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory
Complies
This SDS is not for use in the European Union (EU).
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam
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_____________________________________________________________________________________________
TIC* D65 Dispersant SDS no. D065 Revision date 08-Jun-2021
Supersedes Date: 18-Jun-2014
Revision date 08-Jun-2021
Version 6
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1 Flammability 1 Physical hazard 0 PPE E
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D075Version 4Revision date 19-Sep-2018Supersedes Date: 09-Apr-2014
Safety Data SheetSilicate Additive D75
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Silicate Additive D75Product code D075
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsContact with metals may evolve flammable hydrogen gas.
Hazardous combustion productsThermal decomposition can lead to release of toxic and corrosive gases/vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid spills andsplashing during use. Do not breathe vapors or spray mist.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep at temperaturesabove > 32F /0°C Avoid contact with: Strong acids Metals Aluminum Zinc Steel
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
Packaging materials to be avoided Metal Aluminium Zinc Steel
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: PVC Rubber Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Chemical respiratorwith inorganic vapour cartridge (Grey B). At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solutionOdor OdorlessColor ColorlessOdor threshold Not applicable
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
Physical state Liquid
Property Values Remarks pH 11pH @ dilution No information availableMelting / freezing point - 1 °C / 30 °F
Boiling point/range 101 °C / 214 °F
Flash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure <1 kPaVapor density No information availableSpecific gravity 1.3 - 1.6 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity 10-10000 mPa slog Pow No information available
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
10. Stability and Reactivity
10.1 Reactivity
Contact with metals may evolve flammable hydrogen gas.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep at temperatures above > 32°F / 0°C.
10.5 Incompatible materials
Aluminum. Zinc. Metals. Strong acids. Steel.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
Routes of entry None known.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
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Not classified as PBT/vPvB by current EU criteria.
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Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
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Australian Standard for the Uniform Scheduling of Drugs and Poisons
_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
No poisons schedule number allocated
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 09-Apr-2014
Revision date 19-Sep-2018
Version 4
This SDS has been revised in thefollowing section(s)
15, 16 There have been changes with regard to classification.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
HMIS classification
Health 1Flammability 1Physical hazard 0PPE B
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_____________________________________________________________________________________________
Silicate Additive D75 SDS no. D075Revision date 19-Sep-2018
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D194Version 3Revision date 12-Feb-2019Supersedes Date: 03-Jun-2015
Safety Data SheetLiquid Trifunctional Additive D194
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Liquid Trifunctional Additive D194Product code D194
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteriaThermal decomposition can lead to release of irritating gases and vapors
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid contact with:Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished. No biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance No information availableOdor MildColor BrownOdor threshold No information available
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
Physical state Liquid
Property Values Remarks pH 10pH @ dilution No information availableMelting / freezing point -2 °C / 28.4 °FBoiling point/range 104 °C / 219.2 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure 14.2 mmHg @ 20 °CVapor density No information availableSpecific gravity 1.30Bulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity <600 cstDynamic viscosity No information availablelog Pow No information available
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Inhalation. Ingestion. Eye contact.
Routes of entry Ingestion. Inhalation.
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
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_____________________________________________________________________________________________
Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 03-Jun-2015
Revision date 12-Feb-2019
Version 3
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no
_____________________________________________________________________________________________
Liquid Trifunctional Additive D194 SDS no. D194Revision date 12-Feb-2019
responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D047 Version 3 Revision date 03-Mar-2021 Supersedes Date: 21-Feb-2016
Safety Data Sheet Antifoam Agent D47
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Antifoam Agent D47 Product code D047
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Antifoam in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty Ltd ABN: 74 002 459 225 ACN: 002 459 225 256 St. Georges Terrace, Perth WA 6000 +47 5157 7424
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components 2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
3.2 Mixtures
Not applicable
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Seek medical attention if irritation occurs.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx), Harmful organic chemical fumes.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush away traces with water.
6.4 Reference to other sections
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See section 13 for more information.
_____________________________________________________________________________________________
Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and face before breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid excessive heat for prolonged periods of time. Avoid contact with: Strong acids Strong bases Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limits established.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation
Personal protective equipment Eye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety
glasses with side-shields Hand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Repeated or prolonged contact Use protective gloves made of: Butyl Gloves- Neoprene, Nitrile Unless Specified Be aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required In case of insufficient ventilation wear suitable respiratory equipment Respirator with combination filter for vapour/particulate (EN 141) Type A/P2 At work in confined or poorly ventilated spaces,
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
respiratory protection with air supply must be used. Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at the
work place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for more information
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Viscous Odor Odorless Color Colorless Odor threshold Not applicable
Explosive properties Not applicable Oxidizing properties None known.
9.2 Other information Pour point <0°C/32°F Molecular weight No information available
Physical state Liquid
Property Values Remarks pH No data available pH @ dilution No information available Melting / freezing point < -35 °C / -31 °F Boiling point/range No information available Flash point 229 °C / 444.2 °F ASTM D-93 Evaporation rate (BuAc =1) No information available Flammability (solid, gas) Not applicable Flammability Limit in Air
Upper flammability limit Not applicable Lower flammability limit Not applicable
Vapor pressure Not applicable Vapor density No information available Specific gravity 1 Bulk density No information available Relative density 1 @ 21.1°C. Water solubility Insoluble in water Solubility in other solvents No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity 414 - 496 cst Dynamic viscosity No information available log Pow Not determined
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
VOC content(%) None Density No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid excessive heat for prolonged periods of time.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure None known.
Routes of entry No route of entry noted.
Specific target organ toxicity - Single exposure
Not classified
Specific target organ toxicity - Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation is unlikely.
12.4 Mobility
MobilityThe product is insoluble and floats on water.
Mobility in soilNo information available.
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulated IMDG/ANTAQ Hazard class Not regulated ICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulated IMDG/ANTAQ Packing group Not regulated ICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
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15. Regulatory Information
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Not classified
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/2013] (CLASS Regulations) The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) Complies Canada (DSL) Complies Philippines (PICCS) Complies Japan (ENCS) Complies China (IECSC) Complies Australia (AICS) Complies Korean (KECL) Complies New Zealand (NZIoC) Complies Eurasian Economic Union: Russian Inventory
Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Poh Yue Cheong
Supersedes Date: 21-Feb-2016
Revision date 03-Mar-2021
Version 3
This SDS has been revised in the following section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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Antifoam Agent D47 SDS no. D047 Revision date 03-Mar-2021
HMIS classification
Health 1 Flammability 1 Physical hazard 0 PPE B
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon on measurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDS information, Supplier makes no express or implied warranties as to the information or product; merchantability or fitness of purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes no responsibility for any direct, special or consequential damages, results obtained, or the activities of others. To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separate agreement between the parties. This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D095Version 5Revision date 30-May-2018Supersedes Date: 09-May-2016
Safety Data SheetD095 Cement Additive
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name D095 Cement AdditiveProduct code D095
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Thermal decomposition can lead to release of irritating gases and vapors
3. Composition/information on ingredients
3.1 Substances
Not applicable
3.2 Mixtures Not applicable
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.
Extinguishing media which must not be used for safety reasonsNone known.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment identified in Section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.
Methods for cleaning upAvoid generating or breathing dust. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traceswith water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and Storage
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Avoid dust formation
Packaging materials Use specially constructed containers only.
8. Exposure controls/personal protection
8.1 Control parameters
Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Tightly fitting safety goggles Safety glasses with side-shieldsHand protection Use protective gloves made of: PVC Neoprene Nitrile Rubber Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Effective dust mask.
Type P1 At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before breaks and immediately after handling the product Remove and washcontaminated clothing before re-use
8.2.3 Environmental exposure controls
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance FibersOdor NoneColor WhiteOdor threshold Not applicable
Explosive properties None knownOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
Physical state Solid
Property Values Remarks pH No information availablepH @ dilution No information availableMelting / freezing point > 500 °C / 932 °FBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity 2.6 20 °CBulk density No information availableRelative density No information availableWater solubility InsolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation.
10.5 Incompatible materials
No materials to be especially mentioned.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.
Eye contact Dust may cause mechanical irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
Not applicable.
12.3 Bioaccumulative potential
Not applicable.
12.4 Mobility
MobilityThe product is insoluble and sinks in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions None
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
International inventories
USA (TSCA) Does not complyCanada (DSL) Does not complyPhilippines (PICCS) Does not complyJapan (ENCS) Does not complyChina (IECSC) CompliesAustralia (AICS) Does not complyKorean (KECL) Does not complyNew Zealand (NZIoC) Complies
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D095 Cement Additive SDS no. D095Revision date 30-May-2018
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Ingrid Helland
Supersedes Date: 09-May-2016
Revision date 30-May-2018
Version 5
This SDS has been revised in thefollowing section(s)
1, 7, 8, 15, 16 No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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SDS no. D081Version 4Revision date 12-May-2020Supersedes Date: 27-Mar-2018
Safety Data SheetLiquid Retarder D81
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Liquid Retarder D81Product code D081
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
This product does not contain any hazardous ingredients, or ingredients with national workplace exposure limits.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
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4.3 Indication of any immediate medical attention and special treatment needed
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Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
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Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid breathing vapors ormists. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing Do not eat, drink or smoke when using this product
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away fromdirect sunlight. Store away from incompatibles, Strong acids Strong oxidizing agents
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
NotesNo biological limit allocated
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Local exhaust ventilation
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Neoprene NitrileBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Use respirator withorganic vapor protection (A, brown) At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothing
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Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
before re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solutionOdor Of burnt sugar / SlightColor Dark brownOdor threshold Not applicable
Explosive properties Not applicableOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
Physical state Liquid
Property Values Remarks pH 3.5 - 5.1pH @ dilution No information availableMelting / freezing point No information availableBoiling point/range No information availableFlash point Does not flashEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure Not applicableVapor density No information availableSpecific gravity 1.24 - 1.26 @ 27 °CBulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature 400 °C / 752 °FDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity 350 mPa.s @ 20 °Clog Pow No information available
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Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Keep away from direct sunlight.
10.5 Incompatible materials
Strong oxidizing agents. Strong acids.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Eye contact. Inhalation.
Routes of entry No route of entry noted.
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_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganismsListed on PLONOR list of OSPAR
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility
MobilitySoluble in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
_____________________________________________________________________________________________
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Australian Standard for the Uniform Scheduling of Drugs and Poisons
_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
No poisons schedule number allocated
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 27-Mar-2018
Revision date 12-May-2020
Version 4
This SDS has been revised in thefollowing section(s)
9, 12, No changes with regard to classification have been made.
_____________________________________________________________________________________________
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Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory information
_____________________________________________________________________________________________
Liquid Retarder D81 SDS no. D081Revision date 12-May-2020
National occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
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SDS no. D175AVersion 4Revision date 29-Apr-2020Supersedes Date: 19-Jun-2015
Safety Data SheetAntifoam Agent D175A
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Antifoam Agent D175AProduct code D175A
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
ContainsNon-crystalline silica
2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
Chemical Name EC No CAS No Weight-%Non-crystalline silica Listed Proprietary 1 - 5
CommentsNo classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaExtinguish with carbon dioxide, dry chemical, foam or waterspray.
Extinguishing media which must not be used for safety reasonsDo not use water jet.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsNone known.
Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Solutions extremely slippery when spilled.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.
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6.4 Reference to other sections
_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid breathing vapors ormists. Avoid spills and splashing during use.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep at atemperature not exceeding 25 °C Store away from incompatibles, Strong oxidizing agentsUV or Ionising Radiation. Steel
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits Because this product is a liquid, the dust-related Workplace Exposure Limits for thecomponents do not apply.
Component Information
Chemical Name Arabic Australia EgyptNon-crystalline silica Not determined 2mg/m3TWArespirable dust Not determined
Chemical Name India Indonesian JapanNon-crystalline silica 10 mg/m3 TWA Not determined Not determined
Chemical Name Kazakhstan Kuwait New ZealandNon-crystalline silica 1 mg/m3 MAC
2 mg/m3 MAC6.0 mg/m3 TWA Not determined
Chemical Name Malaysia Philippines RussiaNon-crystalline silica Not determined Not determined 3 mg/m3 STEL
6 mg/m3 STEL1 mg/m3 TWA2 mg/m3 TWA
Fibrogenic substance also vitreous,in the form of disintegration aerosol
1177Fibrogenic substance in the form ofcondensation aerosol, containing>=10% Silicon dioxide 1175, 1176
Chemical Name Thailand Vietnam TurkeyNon-crystalline silica Not determined Not determined Not determined
NotesNo biological limit allocated
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8.2 Exposure controls
_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Mechanical ventilation or local exhaust ventilation is required.
Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against liquid splashes Safety
glasses with side-shields Tightly fitting safety gogglesHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
trainingImpervious gloves made of: Neoprene Nitrile Butyl RubberBreak through time >480 minutesGlove thickness >0.4 mmBe aware that liquid may penetrate the gloves. Frequent change is advisable.
Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment Respirator withcombination filter for vapor/particulate Type A/P2 At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance Aqueous solutionOdor SlightColor Milky whiteOdor threshold Not applicable
Physical state Liquid
Property Values Remarks pH ~ 5pH @ dilution No information availableMelting / freezing point ~ 0 °C / 32 °FBoiling point/range 100 °C / 212 °FFlash point Not applicableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicable
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
Explosive properties Not applicableOxidizing properties None known.
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid heat, flames and other sources of ignition.
10.5 Incompatible materials
Strong oxidizing agents. UV or Ionising Radiation. Steel.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Lower flammability limit Not applicableVapor pressure 2.3 kPa @ 20 °CVapor density No information availableSpecific gravity ~ 1 @ 25 °CBulk density No information availableRelative density No information availableWater solubility DispersibleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity ~ 100 mPa s @ 25 °Clog Pow No information available
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Toxicology data for the components
Chemical Name LD50 Oral LD50 Dermal LC50 InhalationNon-crystalline silica = 7900 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Skin contact. Inhalation. Ingestion. Eye contact.
Routes of entry Inhalation.
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae. See component information below.
Toxicity to fishThis product is not considered toxic to fish. See component information below.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates. See component information below.
Toxicology data for the componentsChemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and other
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
aquatic invertebratesNon-crystalline silica = 5000 mg/L LC50 Brachydanio
rerio 96 h= 440 mg/L EC50
Pseudokirchneriella subcapitata 72h
= 7600 mg/L EC50 Ceriodaphniadubia 48 h
12.2 Persistence and degradability
The product is not expected to be biodegradable. See component information below.
Chemical Name Persistence and degradabilityNon-crystalline silica No information available
12.3 Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating. See component information below.
Chemical Name BioaccumulationNon-crystalline silica Not likely to bioaccumulate
12.4 Mobility
MobilityDispersible in water.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
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14. Transport information
_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Antifoam Agent D175A SDS no. D175ARevision date 29-Apr-2020
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) Does not complyChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 19-Jun-2015
Revision date 29-Apr-2020
Version 4
This SDS has been revised in thefollowing section(s)
8, 11, 12, 15, 16 No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
_____________________________________________________________________________________________
Page 10 / 10
SDS no. D013Version 6Revision date 15-Jan-2020Supersedes Date: 17-Nov-2015
Safety Data SheetRetarder D013
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name Retarder D013Product code D013
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Used as a cementing additive in oilfield applications
Uses advised against Consumer use
1.3 Details of the supplier of the safety data sheet
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518
2. Hazards Identification
2.1 Classification of the substance or mixture
GHS Classification
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label elements
Signal wordNone
SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424
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_____________________________________________________________________________________________
Retarder D013 SDS no. D013Revision date 15-Jan-2020
Hazard StatementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.
Precautionary statements This product is not classified as hazardous therefore has no (P) precautionary statements assigned.
Contains No hazardous components2.3 Other hazards
Not classified as PBT/vPvB by current EU criteria
Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
3. Composition/information on Ingredients
3.1 Substances
Not applicable
3.2 Mixtures
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First Aid Measures
4.1 First aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.
Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses, if worn.Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.
Symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
_____________________________________________________________________________________________
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4.3 Indication of any immediate medical attention and special treatment needed
_____________________________________________________________________________________________
Retarder D013 SDS no. D013Revision date 15-Jan-2020
Notes to physician Treat symptomatically.
5. Fire-Fighting Measures
5.1 Extinguishing media
Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which must not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.
5.2. Special hazards arising from the substance or mixture
Unusual fire and explosion hazardsSuspended dust may present a dust explosion hazard.
Hazardous combustion productsFire or high temperatures create: Sulphur oxides, Carbon oxides (COx), Heating or fire can release toxic gas.
5.3 Advice for firefighters
Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.
6. Accidental Release Measures
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.
6.3 Methods and material for containment and cleaning up
Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.
Methods for cleaning upSweep up and shovel into suitable containers for disposal. Take precautionary measures against static discharges. After cleaning,flush away traces with water.
6.4 Reference to other sections
See section 13 for more information.
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7. Handling and Storage
_____________________________________________________________________________________________
Retarder D013 SDS no. D013Revision date 15-Jan-2020
7.1 Precautions for safe handling
HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.
Hygiene MeasuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.
Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place Keep away from openflames, hot surfaces and sources of ignition Avoid contact with: Strong oxidizing agentsStrong acids Strong alkalies.
Storage class Chemical storage.
Packaging materials Use specially constructed containers only.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limitsestablished.
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.
Engineering ControlsEnsure adequate ventilation Provide appropriate exhaust ventilation at places where dust is formed
Personal protective equipmentEye protection Eye protection must conform to standard EN 166 Tightly fitting safety goggles Safety
glasses with side-shieldsHand protection Wear chemically resistant gloves (tested to EN 374) in combination with 'basic' employee
training Impervious gloves made of: Neoprene Nitrile Rubber Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment Half mask with a
particle filter P2 (European Norm EN 143 = former DIN 3181) At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.
Skin and body protection Wear suitable protective clothing Eye wash and emergency shower must be available at thework place.
Hygiene Measures Wash hands before eating, drinking or smoking Remove and wash contaminated clothingbefore re-use
_____________________________________________________________________________________________
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_____________________________________________________________________________________________
Retarder D013 SDS no. D013Revision date 15-Jan-2020
8.2.3 Environmental exposure controls
Environmental exposure Use appropriate containment to avoid environmental contamination See section 6 for moreinformation
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Appearance PowderOdor FaintColor BrownOdor threshold Not applicable
Explosive properties No information availableOxidizing properties No information available
9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available
CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.
10. Stability and Reactivity
Physical state Solid
Property Values Remarks pH No information availablepH @ dilution 4 - 5Melting / freezing point No information availableBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air
Upper flammability limit Not applicableLower flammability limit Not applicable
Vapor pressure No information availableVapor density No information availableSpecific gravity 1.2 20 °CBulk density 480 kg/m3
Relative density No information availableWater solubility SolubleSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available
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Retarder D013 SDS no. D013Revision date 15-Jan-2020
10.1 Reactivity
Dust may form explosive mixture in air.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerizationHazardous polymerization does not occur.
10.4 Conditions to avoid
Avoid dust formation. Take precautionary measures against static charges. Avoid heat, flames and other sources of ignition.
10.5 Incompatible materials
Strong oxidizing agents. Strong acids. Strong alkalies.
10.6 Hazardous decomposition products
See Section 5.2.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough. May cause irritation of respiratory tract.
Eye contact Dust may cause mechanical irritation.
Skin contact Repeated exposure may cause skin dryness or cracking.
Ingestion Ingestion may cause stomach discomfort.
Unknown acute toxicity Not applicable.
Sensitization This product does not contain any components suspected to be sensitizing.
Mutagenic effects This product does not contain any known or suspected mutagens.
Carcinogenicity This product does not contain any known or suspected carcinogens.
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Routes of Exposure Inhalation. Skin contact. Eye contact.
Routes of entry Inhalation.
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Retarder D013 SDS no. D013Revision date 15-Jan-2020
Specific target organ toxicity -Single exposure
Not classified
Specific target organ toxicity -Repeated exposure
Not classified.
Aspiration hazard Not applicable.
Other information Key literature references and sources for data. See Section 16 for more information.
12. Ecological Information
12.1 Toxicity
The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.
Toxicity to algaeThis product is not considered toxic to algae.
Toxicity to fishThis product is not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.
12.2 Persistence and degradability
No product level data available.
12.3 Bioaccumulative potential
No product level data available.
12.4 Mobility
MobilityThe product is water soluble, and may spread in water systems.
Mobility in soilNo information available.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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Retarder D013 SDS no. D013Revision date 15-Jan-2020
12.6 Other adverse effects.
None known.
12.7 Other information Key literature references and sources for data. See Section 16 for more information.
13. Disposal considerations
13.1 Waste treatment methods
Waste from residues/unusedproducts
Dispose of in accordance with local regulations.
Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.
14. Transport information
14.1. UN number Not regulated
14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods
14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG/ANTAQ Hazard class Not regulatedICAO/ANAC Hazard class/division Not regulated
14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG/ANTAQ Packing group Not regulatedICAO/ANAC Packing group Not regulated
14.5 Environmental hazard No
14.6 Special precautions Not applicable
14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety data sheet complies with the requirements of:The Globally Harmonized System of Classification and Labeling of Chemicals (GHS)
Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated
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Retarder D013 SDS no. D013Revision date 15-Jan-2020
New Zealand Hazard Classification Not classified
HSNO approval no. Not required
Group number Not required
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].
National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].
National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].
Safe Work Australia.
Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).
Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG)
International inventories
USA (TSCA) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies
16. Other Information
Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel
Supersedes Date: 17-Nov-2015
Revision date 15-Jan-2020
Version 6
This SDS has been revised in thefollowing section(s)
All sections No changes with regard to classification have been made.
Key literature references and sources for datawww.ChemADVISOR.comSupplierNational Chemical InventoriesNational regulatory informationNational occupational exposure limits
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Retarder D013 SDS no. D013Revision date 15-Jan-2020
DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.This Document is Confidential and Proprietary. Unless Otherwise Marked, It is an Uncontrolled Copy.
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RCMA-02-EM-PLN-001SUMv4 APPENDIX C
Risk Assessment Aspects ranked ‘MODERATE’ and above
Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)
Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking Site Preparation
1. Soil and Landform
Significant change in landform resulting in erosion/loss of topsoil
Increased risk of erosion due to change in drainage patterns
3 C C3 Medium
• Ongoing routine monitoring and maintenance throughout operations to address erosion or loss of landform
• Storage of topsoil lightly compacted to a height of no more than 2m and covered with brushto minimise erosion potential
• Drainage control implemented such as erosion berms
3 B B3 Medium
3. Vegetation
Clearing of access track and well pad impacts flora
Impacts to conservation significant flora and native vegetation, resulting in significant loss of species or community, significant fauna habitat
3 C C3 Medium
• Use of existing tracks to reduce areas of clearing • Desktop 1 Flora and Vegetation study undertaken with reconnaissance survey • Cleared vegetation to be stockpiled separately from topsoil (covered in brush)
and in windrows less than 2 m high • Areas to be cleared will be clearly demarcated • Induction of construction personnel on areas approved for clearing • Vehicles and equipment movement will be restricted to the designated tracks.
3 B B3 Medium
Clearing outside permitted footprint
3 C C3 Medium
• Site plan prepared in accordance with EP requirements • Areas to be cleared will be clearly demarcated • Induction of construction personnel on areas approved for clearing
3 A A3 Low
4. Weeds
Equipment presence on site results in spread of invasive species
Weed invasion or introduction of dieback
4 C C4 High
• Flora reconnaissance survey identifies general level of weed cover • Earthmoving equipment will be inspected and cleaned down prior to
mobilisation to site • Sheeting materials (marl to minimise dieback risk) brought to site are sourced
locally. The borrow pit is managed to minimise risk of weeds (topsoil exclusion) • Hygiene station is established during site preparation activities (including lined
pad with drainage sump, brushes/brooms and weatherproof container for inspection register)
• Vehicles and equipment are to arrive on site in a clean state and conduct inspection on site in accordance with the Hygiene Procedure including sign off on the hygiene inspection checklist
• Controlled access to site reduces the potential for weed invasion • Personnel are required to complete the induction which outlines weed and
dieback management
4 B B4 Medium
5. Dieback
6. Soil Contamination
Ruptured fuel / oil tank during clearing vegetation activities
Localise soil contamination 2 C C2
Medium
• Refuelling vehicle to have refuelling drip tray, spill kit and contaminated soil bunding tarp (for segregation of material if a spill occurs prior to disposal)
• Vehicles preferentially refuel offsite • OSCP in place and induction includes the requirements of personnel • Contaminated material is taken offsite for reuse or disposal • Refuelling vehicle is on site during daylight hours only • Construction vehicles are left locked when unattended
2 B B2 Low
Spill while refuelling construction vehicle Sabotage of equipment present on site during construction activities (overnight)
RCMA-02-EM-PLN-001SUMv4 APPENDIX C
Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)
Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking
7. Indigenous Heritage
Clearing of access track and initial earthworks for well pad construction and potential impacts to heritage values
Loss of heritage value due to disturbance of heritage site.
3 C C3 Medium
• Cervantes heritage and archaeological survey undertaken • Induction of site personnel to identify potential risk of encountering artefacts of
heritage value, and required actions and reporting if items identified 3 B B3
Medium
8. Emissions (Dust)
Localised generation of dust significantly impacting air quality (vegetation disturbance activities, vehicle movements)
Reduced air quality 1 E E1 Medium
• Speed limits for vehicle traffic imposed across Project area • Induction of site personnel on vehicle speed limits • The application of water (or appropriate suppressants) to access roads, working
surfaces and stockpiles (as required)
1 E E1 Medium
Mobilisation / Demobilisation
10. Emissions (Dust)
Localised generation of dust significantly impacting air quality
Reduced air quality 1 E E1 Medium
• Water spray on soil and /or access track as required • Speed limits adhered to in order to reduce dust emissions • Induction includes vehicle speed limits
1 D D1 Low
11. Emissions (Noise)
Noise from vehicles, equipment, and general setup activities
Noise impacts native fauna 2 D D2
Medium
• Maintenance of equipment and vehicles per manufacturer recommendations • Vehicles and equipment to be used only within the approved project footprint,
i.e. hygiene station, access tracks, campsites and well pad, to minimise disturbance of fauna.
• The activities are short term and not located within a noise sensitive locality
2 C C2 Medium
13.
Weeds Equipment and vehicle presence on site results in significant spread of weed species and soil pathogens
Weed invasion or introduction of dieback
4 C C4 High
• No dieback symptoms identified during field survey • Vehicles and equipment arrive to site in a clean state - hygiene inspection
checklist completed • Hygiene station in place and managed, as a minimum the hygiene station will
include a lined pad with drainage sump, brushes/brooms and weatherproof box for inspection register).
• Controlled access to site reduces potential for weed invasion • Induction process to educate personnel on weed and dieback
4 B B4 Medium Dieback
Drilling / Well Testing
15. Emissions (Dust)
Localised generation of dust significantly impacting air quality
Reduced air quality 1 E E1 Medium
• Water spray on well pad and /or access track as required • Speed limits in place for vehicle traffic • Induction includes vehicle speed limits
1 D D1 Low
16. Emissions (Noise)
Noise from vehicles and equipment being a nuisance, noise from drilling / well testing
Noise impacts native fauna 2 D D2
Medium
• Maintenance of equipment and vehicles per manufacturer recommendations • Vehicles and equipment to be used only within the approved project footprint,
i.e. hygiene station, access tracks, campsites and well pad, to minimise disturbance of fauna
• The drilling / well testing activities are short term and not located within a noise sensitive locality
• Consultation with near-by neighbours
2 C C2 Medium
RCMA-02-EM-PLN-001SUMv4 APPENDIX C
Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)
Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking
19. Weeds Presence of
infrastructure on site
Weed invasion or introduction of dieback
4 C C4 High
• Vehicles and equipment arrive to site in a clean state • Hygiene station in place and managed in accordance with Hygiene Procedure
[RCMA-02-EM-PRO-001] • Induction process to educate personnel on weed and dieback requirements
4 B B4 Medium
Dieback
20. Landowner / Socioeconomic
Operations disturb neighbouring landowner or nearby stakeholders
Noise, aesthetics, land use change, traffic
3 C C3 Medium
• Stakeholder engagement prior to commencement of activity • Noise and aesthetic impacts are anticipated to be negligible when considering
the remote location, duration of activity and distance to nearest sensitive receptors.
• The nearby stakeholders would be engaged on timing of the activity and key periods of traffic flow to minimise disruption.
• Consultation as part of self-referral to EPA
3 B B3 Medium
21. Ground water
Mud/cutting spills Mud/cuttings leaching from sump
Localised soil or groundwater impact 4 C C4
High
• Maintaining 0.5 m freeboard within the sump to minimise potential for overflow • The mud sump will be lined with Enviro Liner 6030HD liner (hereafter referred to
as ‘Enviro Liner’) (Thickness: 0.75 mm; Water Vapour Permeability 3 x 10-13 cm/sec)
• Benign water-based muds • Baseline monitoring to characterise groundwater prior to commencement of
activity
4 B B4 Medium
Groundwater extraction
Contribution to depletion of groundwater resources
0 E E0 Negligible
• Flow meter to monitor usage • Quantities of water required for drilling operations unlikely to drawdown aquifer • 26D licence to construct in place • 5C licence to take water in place
0 E E0 Negligible
22. Soil Contamination
Incorrect management of sewage treatment (on site)
Local soil contamination 2 C C2
Medium
• Septic holding tanks pumped out and taken offsite by Controlled Waste Carrier for disposal
• Level alarm on holding tank 2 B B2
Low
Care and Maintenance
27. Weeds Equipment presence on site results in spread of invasive species
Weed invasion or introduction of dieback
4 B B4 Medium
• Vehicles and equipment will be inspected and cleaned down prior to mobilisation to site in accordance with Hygiene Procedure including sign off on the hygiene inspection checklist
• Personnel are required to complete the induction which outlines weed and dieback management
• JPF personnel undertake inspections of well pad and access track during C&M (weekly) and rehabilitation (monthly) phases of project which include observations for weed infestations
• Bi-annual weed control program in place during C&M and Rehabilitation phases of project
4 A B4 Low
28. Dieback
26. Landowner / Socioeconomic
Security Issues associated with suspended wells and associated infrastructure remaining at site
Sabotage resulting in infrastructure damage and product or waste release to the environment
3 C C3 Medium
• Well cellar is fenced and locked with signage demarcating the name of the well, responsible entity, contact number and hazards associated with the well
• All non-fixed equipment is taken offsite at demobilisation unless brought onsite under supervision / securely locked
• Suspended wells are isolated via tubing plugs and/or well head back pressure valve
3 B B3 Medium
Decommissioning / Rehabilitation
23. Emissions (Dust)
Localised generation of dust significantly impacting air quality
Reduced air quality 2 D E1 Medium
• Water sprayed on soil and /or access track as required • Speed limits in place for vehicle traffic • Induction includes vehicle speed limits
2 D E1 Medium
RCMA-02-EM-PLN-001SUMv4 APPENDIX C
Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)
Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking
25.
Vegetation
Inadequate progression to rehabilitation Poor Rehabilitation Results Increased weed invasion, erosion, dust
Land degradation/decreased in biodiversity
4 C C4 High
• Validation sampling undertaken at key stages (i.e. removal of mud sump or flare pit)
• Waste material sampled and classified in accordance with the Landfill Waste Classification and Waste Definitions 1996 (as amended) (DEC 2009)
• Reputable earthworks contractor used to undertake works in accordance with defined scope
• Well site handover form completed for Care and Maintenance; routine workplace inspections undertaken thereafter
• Rehabilitation Plan with completion criteria implemented within 2 years of well decommissioning
• Completion criteria monitoring and remedial actions where rehabilitation unsuccessful
• Vehicles and equipment arrive to site in a clean state - hygiene inspection checklist completed in accordance with Hygiene Procedure [RCMA-02-EM-PRO-001].
• Controlled access to site reduces potential for weed invasion • Induction process to educate personnel on weed and dieback management
4 B B4 Medium
Soil and Landform
Weeds
Dieback
26. Landowner / Socioeconomic
Security Issues associated with suspended wells and associated infrastructure remaining at site
Sabotage resulting in infrastructure damage and product or waste release to the environment
3 C C3 Medium
• Well cellar is fenced and locked with signage demarcating the name of the well, responsible entity, contact number and hazards associated with the well
• All non-fixed equipment is taken offsite at demobilisation unless brought onsite under supervision / securely locked
• Suspended wells are isolated via tubing plugs and/or well head back pressure valve
3 B B3 Medium
27. Weeds Equipment presence on site results in spread of invasive species
Weed invasion or introduction of dieback
4 C C4 High
• Earthmoving equipment will be inspected and cleaned down prior to mobilisation to site
• Vehicles and equipment are to arrive on site in a clean state and conduct inspection on site in accordance with the Hygiene Procedure including sign off on the hygiene inspection checklist
• Personnel are required to complete the induction which outlines weed and dieback management
• Rehabilitation Plan to be submitted to DMIRS will outline measures during rehabilitation and over following periods to manage and control the spread of weed species and remediation actions to be implemented if required
4 B B4 Medium
28. Dieback
29. Soil Contamination
Localised contamination of soil
Reduced soil quality Potential for soil contamination
2 C C2 Medium
• Drilling sump materials will be taken offsite for disposal / reuse • Validation sampling on site will confirm no potential contamination has been left
2 B B2 Low
Unplanned Event
30. Fire Uncontrolled fire due to on-site activities
Potential habitat destruction 4 C C4
High
• All project site vehicles on site (at all stages of Project) have a serviceable fire extinguisher
• A mobile water cart is available on-site during construction, drilling and rehabilitation activities
• Smoking is permitted in designated areas only • Hot work is conducted under permit • Firebreaks surrounding drill site • Fire extinguishers located around the rig • General housekeeping • Rig identified electrical zoning areas and equipment suitably rated within areas
4 B B4 Medium
RCMA-02-EM-PLN-001SUMv4 APPENDIX C
Risk Identification Pre-treatment Risk Assessment Risk Treatment (Safeguards / Management Methods)
Post-treatment Risk Assessment # Aspect Source of Risk Potential Impact Consequence Likelihood Risk Ranking Consequence Likelihood Risk Ranking
32. Loss of Containment
Spill of diesel or hazardous liquid from delivery truck
Contamination of soil Contamination of Groundwater Degradation of Vegetation
4 B 4B Medium
• Standard operating procedures in place for handling and use of hazardous materials
• Spill kits are located as per OSCP • ERP and OSCP in place • Large diesel storage tank is self-bunded • Diesel transfer operations are manned • Spill trays are utilised for all diesel transfers • Drilling operations are conducted on 24-hour basis with light towers and
monitoring regime would result in prompt identification of a spill • Bunding of liquid chemicals in accordance with SDS requirements • Bunds are inspected during housekeeping inspections to determine integrity and
maintenance of capacity
4 A A4 Low
33. Well Control Situation
Worst case scenario well-blow out, fire, hydrocarbon contamination
Contamination of local environment – air, ground, noise Fire risk for Reserve
5 B B5 High
• Use Blow Out Preventor (BOP) that is operated and maintained as per OEM standard
• Double barrier philosophy • Standard well control practices implemented • Well control certificates for senior drilling personnel • Certified and tested equipment utilised • DMIRS approved drilling program • Competent and trained crew required to undertake periodic well control drills • Safe area on site to vent / flare in the case of an emergency • Pre-identified well control response contractor
5 A A5 Medium