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Chapter 3 Materials and Basic Processes. Picture of the chip set of SensoNor’s SP13 Tire Pressure Sensor. The course material was developed in INSIGTH II, a project sponsored by the Leonardo da Vinci program of the European Union. Materials: Metals. - PowerPoint PPT Presentation
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19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 1
Chapter 3Materials and Basic Processes
Picture of the chip set of SensoNor’s SP13 Tire Pressure Sensor
The course material was developed in INSIGTH II, a project sponsored by the Leonardo da Vinci program of the European Union
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 2
Materials: Metals
• Right choice, right use and compatibility of materials is the key to good packaging and optimal properties.
–Elemental metals:• High electrical conductivity• High thermal conductivity• Higher thermal coefficient of expansion (TCE) than
semiconductors and most ceramics
–Alloys: taylored to many uses:• Poorer electrical and thermal conductivity than elements• Taylored TCE• Lower melting point
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 3
Metals, continued
• (Table 3.1)Table 3.1 a): Properties of some important materials in electronics: Conductors[3.1].
Melting PointElectricalResistivity
ThermalExp. Coeff.
ThermalConductivity
Metal/Conductor [°C] [10-8Ohmm] [10-7/°C] [W/m.°K]Copper 1083 1.7 170 393Silver 960 1.6 197 418Gold 1063 2.2 142 297Tungsten 3415 5.5 45 200Molybdenum 2625 5.2 50 146Platinum 1774 10.6 90 71Palladium 1552 10.8 110 70Nickel 1455 6.8 133 92Chromium 1900 20 63 66Invar 1500 46 15 11Kovar 1450 50 53 17Silver-Palladium 1145 20 140 150Gold-Platinum 1350 30 100 130Aluminium 660 4.3 230 240Au-20%Sn 280 16 159 57Pb-5%Sn 310 19 290 63Cu-W(20%Cu) 1083 2.5 70 248Cu-Mo(20%Cu) 1083 2.4 72 197
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 4
Metal Alloys
• Alloys have poorer conductivity, both electrical and thermal.
• Fig. 3.1: Phase diagram for Sn/Pb. The eutectic mixture 63%/37% has a melting point of 183°C.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 5
Insulators
• (Fig 3.1b)Table 3.1 b): Properties of important materials in electronics: insulators [3.1].
Non Organics
RelativeDielectricConstant
Thermal Exp.Coefficient
[10-7/ oC]
ThermalConductivity
[W/ m.oK]
ApproximateProcessing
Temp.[oC]92% Alumina 9.2 60 18 150096% Alumina 9.4 66 20 1600Si3N4 7 23 30 1600SiC 42 37 270 2000AlN 8.8 33 230 1900BeO 6.8 68 240 2000BN 6.5 37 600 >2000Diamond - High Pressure 5.7 23 2000 >2000Diamond - Plasma CVD 3.5 23 400 1000Glass-Ceramics 4-8 30-50 5 1000Cu Clad Invar(10%Cu)/ (Glass Coated) - 30 100 800Glass coated Steel 6 100 50 1000OrganicsEpoxy-Kevlar(x-y) (60%) 3.6 60 0.2 200Polyimide-Quartz (x-axis) 4.0 118 0.35 200Fr-4(x-y plane) 4.7 158 0.2 175Polyimide 3.5 500 0.2 350Benzocyclobutene 2.6 350-600 0.2 240Teflon (™DuPont Co.) 2.2 200 0.1 400
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 6
Semiconductors, Si and GaAs
• High thermal conductivity
• Electrical conductivity spans many orders of magnitude, depending on doping
• Very low TCE
• "Machinable" by anisotropic etching (Si)
• Excellent protective oxide (Si)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 7
Ceramics
• Inorganic, non-metallic
• Made by powder, compressing or tape casting, and high temperature treatment (600-1800oC)
• Chemically and thermally very stable
• Electrical insulators
• Some ceramics are very good thermal conductors
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 8
Ceramics, continued
Table 3.1 c): Properties of ceramics, Si, Si3N4 and SiO2 and polyimide.[3.1]
Characteristic Al2O3 AlN SiC Si SiO2 Si3N4 PolyimideSpecific Resistance(Ohmcm) >1014 4x1011 1013
10-4 to
10+4 106 1012 1016
Relative Permittivity9.8 10
15 to45 11.9 3.9 7.5 3-4
ThermalConductivity (W/m °K)
10 to35
140 to170 270 150 1.5
10 to40 0.4
Thermal Expansion
Coefficient (10-6/°K) 5.5 2.65 3.7 2.60.3 to0.5
2.5 to3
20 to70
Breakdown FieldStrength (V/cm) 105 105 700 105
106 to
107106 to
107 106
Loss Factor (tan )
3x10-45x10-4
to 10-3 5x10-24x10-3
4x10-2 3x10-2_ _
Modulus of Elasticity
(kN/mm2)
300 to380 300 380 170
70 to72.5
280 to320 3
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 9
Ceramics, continued
• Dielectric loss:– tan = (1/R)/C = 1/Q
– = (k´ - jk")
– tan = k"/k´.
• Main uses:–Substrates for hybrid circuits, component packages, SMD resistors
–Multilayer capacitors–Future: Superconductors ?
Cp Rp
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 10
Materials
• Fig 3.1.d
Table 3.1 d): Elastic modules and thermal conductivity of some materials [3.1].
Material
Modulus ofElasticity E
[GPa]
ThermalConductivity k
[W/cm °C]
Application
90-99% Al2O3 262 0.17 SubstrateBeryllia (BeO) 345 2.18 SubstrateCommon Cu alloys 119 2.64 LeadframeNi-Fe Alloys(42 alloys) 147 0.15 LeadframeAu-20% Sn 59.2 0.57 Die bond attach and lid
sealantAu-3% Si 83 0.27 Die bond attachPb-5% Sn 7.4 0.63 Flip chip bondingSilicon 13.03 1.47 Electronic circuitAu 78 3.45 Wire metallurgyAg-loaded epoxy 3.5 0.008 Die bond adhesiveEpoxy (Fused silica filler) 13.8 0.007 Moulding Compound
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 11
Ceramics, continuedTable 3.1 e): Properties of low temperature ceramic. Burnout and firing conditions(a) Followed by a reduction step in N2/H2, 350C, 0.3h
System Matrix Filler Metallisation Burnout[oC/h]
Firing[oC/h]
Atmosphere Shrinkage[%]
High-temperature cofired ceramicIBM Alumina … Molybdenum … 1560/33 H2/N2 17
Low-temperature cofired ceramicAsahi glass Ba-Al2O3SiO2-
B2O3
Al2O3Forsterite
… …900/1 Air 12
DuPont Alumina silicate Al2O3 Silver, Gold 350/1 850/0.3 Air 12
Fujitsu Borate glassAl2O3 Copper
… 950 to1000/- Reducing
.....
Matsushita 0.35NaAlSi3O8-
0.65CaAl2Si2O8
… Copper 550/4(a)(in air) 900/0.3 Nitrogen
.....
Murata BaO-B2O3-
Al2O3-CaO-SiO2
.... Copper …950/- Reducing 13.5
Narumi CaO-Al2O3-
B2O3-SiO2
Al2O3 Silver,gold(top)
…880/0.3 Air 16
NEC Lead borosilicate Al2O3 Silver,palladium
…900/- Air
13
Shoei BaZr(BO3)2 SiO2 Copper 600/-(in air)
980/2.5 Nitrogen 12
Taiyo Yuden CaO-MgO-Al2O3-SiO2-
B2O3
…Copper
…950/- Reducing
.....
19.01.201107.10.99 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 12
Ceramics, continued
Fig 3.1 e.2 Physical propertiesSystem Dielectric
constantDissi-pationfactor
Insulationresistance,[Ohmcm]
Coefficientof thermalexpansion[10-6/°K]
ThermalConduc-
tivity[W/m°K]
Fracturetrength[MPa]
Breakdownvoltage
[kV/mm]
High-temperature cofired ceramicIBM 9.4 >1014 6.5 16.7 275
Low-temperature cofired ceramicAsahi glass 6.3 0,001 … 3,8-6,8 … 245 …DuPont 7.8 0,002 >1013 7,9 2,9 206 40Fujitsu 4.9 4,0 … … 50Matsushita 7.4 0,002 1014 6,1 2,9 245Murata 6.1 0,0007 >1014 8,0 4,2 196 20Narumi 7.7 0,0003 1014 5,5 2,5 196 88NEC 7.8
3.90,0030,003
>1014
>10137,91,9
……
343137
……
Shoei 7.0 0,001 >1014 7,7 3,3 196 …Taiyo Yuden 6.7 … … 5,8 6 245 …
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 13
Glasses:
• Glasses are amorphous, supercooled liquids–Uses:
• Matrix for thick film pastes
• Hermetic seals
• Substrates, together with ceramics
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 14
Plastics• Organic, synthetic polymer materials with numerous uses in
electronics
Table 3.3 a): Plastics in various types of electronics applications.Integrated circuits,transistors,diodes, and otherdiscrete devices
Transfer moulding compounds, injection mouldingcompounds, castings, potting, dip and powder coatingcompounds, and die attach adhesives. Photoresists. Junctioncoatings.
Wires and cables Sleevings, coatings, varnishes, intermetal dielectrics.Connectors Transfer moulding, injection moulding, compression
moulding compounds.Hybrids Conductive and non conductive adhesives, sealants,
conformal coatings.Transformers, coils,bushings
Transfer moulding compounds, coatings, potting compounds,coil impregnates, wire insulation.
Printed circuit boards Laminates, conformal coatings, solder masks, masking tapes,component attachment adhesives, and vibration dampers.Photoresists.
19.01.201107.10.99 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 15
Plastics, continued
• Composition, properties:–Monomers derived from benzene
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 16
Plastics, continued
Table 3.3 b):Types of plastics for various purposes.USE SUITABLE MATERIALSTransfer moulding Epoxides, silicones, phenolics, polyimides.Injection moulding Polyethylene, polypropylene, polyphenylene sulphide.Encapsulation/casting Epoxides, polyurethanes, silicones.Adhesives Epoxides, polyimides, cyanoacrylates, polyesters, polyurethanes.Coatings Silicones, fluorocarbons, epoxides, polyxylylenes, polyurethanes,
polyimides.Films Polyesters, polypropylene, polystyrene, polyimides.Sealants Silicones, polysulphides, polyurethanes, epoxide-polyamides, and fluoro-
silicones.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 17
Plastics, continued
• Requirements:–High electrical resistivity, high breakdown field,
low dielectric losses, low dielectric constant–Thermal and mechanical stability–Thermal expansion compatible with Si and metals–High mechanical strength/softness and flexibility–Chemical resistance–Good adhesion to other materials–Ease of processing–Low water absorption, small changes of the
properties during the effect of moisture.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 18
Plastics, continued
• Composition, properties:
–Linear, branched or crosslinked
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 19
Plastics, continued
• Thermoplastic or thermosetting
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 20
Plastics, continued• Polymerization: A-, B-, C-stages.
• High electrical resistivity , low dielectric constant r, low loss factor tan , high breakdown field Ecrit
• Poor thermal conductors
• Visco-elastic
• Fig 3.7: The structural unit of certain monomers/polymers.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 21
Plastics, continued
• "Glass transition": change from glass-like to rubber - like
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 22
Plastic Materials:
• Epoxy• Phenolic• Polyimide• Teflon• Polyester• Silicone• Polyurethane• Parylene• Acrylic• Polysulphone, polyethersulphone, polyetherimide
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 23
Plastics, continued• Fig. 3.9: a):The
epoxide group, which is the building block in epoxy, b) - e): Starting materials for epoxy:b): Bisphenol A, which constitutes most of the starting material. The H-atoms in the places X are often replaced with Br to reduce the flammability; c): Epoxy novolac; d): The hardener dicyandiamide; e): The catalyst.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 24
Plastics, continuedTable 3.5: Properties of high temperature moulding plastics [3.6, page 307]. Property Poly-
sulphone (Udel)
Polyether sulphone (Victrex)
Poly- -phenylene sulphide (Ryton)
Polyether- -imide (Ultem)
Ultem +20% glass reinforced
Flexural strength
[x10-3psi]
15.4
18.6
25
21
30
Flexural modulus
[x10-6psi]
0.39
0.37
1.7
0.48
0.9
Tensile strength
[x10-3psi]
10.2
12.2
16.2
15.2
20
Dielectric constant
[1 MHz, 25oC]
3.03
3.45
3.8
3.1
3.5
Dissipation factor
[1 MHz, 25oC]
0
0.008
0.0014
0.006
0.0015*
Volume resistivity
[x10-17 Ohmm]
50
100
45
6.7
0.7
Electrical strength [kV/mm]
17 16 17.7 28 26.5
Deflection temperature
[oC] at 264 psi
174
202
243
200
209
Thermal expansion
coefficient [ppm/oC]
56
55
40
56
25
Water absorption [%] (24h)
0.3 0.4 0.05 0.25 0.26
Maximum continuous
temperature [oC]
160
170-200
170
170
170
* 1kHz
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 25
Basic Processes
• Description of some of the basic processes used in microelectronics, microsystems and electronic packaging.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 26
Photolithography
• Fig. 3.10:The steps in photolithographic transfer of patterns and the subsequent etching of metal films with negative photoresist.
• If positive resist is used, it is the illuminated part of the photoresist, which is removed during the development.
• Positive resist most used today because of better accuracy
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 27
Photolithography, cont
• Also, please observe the concept of straight polarity masks and reverse polarity masks:
– Straight polarity:In layers with straight polarity, a positive image of the layout will be transferred onto the process layer. In other words, draw the objects that need to be covered with photo-resist after development.
• Openings: Mask pattern is repeated on the substrate for additive films etc., like metal patterns. (Assuming positive resist is used)
– Reverse polarity:In layers with reverse polarity, draw the areas where photo-resist should be removed. The actual mask will be the negative image of the layout.
• Mask pattern is oppositely repeated on the substrate for additive films etc., like openings in oxide for later difussion of dopants. (Assuming positive resist is used)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 28
Screen Printing and Stencil Printing
• Fig. 3.11: Screen printing: a) and b): Printing process, c) and d): Details of the
screen
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 29
Etching
• Wet, chemical etching
• "Dry" plasma- or reactive ion etching• Examples, wet etching:
Copper:FeCl3 + Cu -> FeCl2 + CuClIn addition:FeCl3 + CuCl -> FeCl2 + CuCl2
Need organic etch resist, not good with PbSn.
Gold:KI + I2 -> KI3 + KI (surplus)3 KI3 + 2 Au -> 2 KAuI4 + KI
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 30
Plating
• Electrolytic plating: –Electric current of ions in electrolyte. External circuit needed. All separate parts of area to be plated must be electrically contacted to external circuit.
Example: Cu in CuSO4 /H2SO4
Reaction at anode (Cu supply):Cu -> Cu2+ + 2e-
Reaction at catode (substrate):Cu2+ + 2e- -> Cu
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 31
Plating, continued
• Chemical plating:–Takes place without external current –Needed when insulating surfacec are to be plated –Often preceeds electrolytic plating, to make all
needed areas electrically conductive–Complex processes of "sensitizing", "activation"
and plating
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 32
Vacuum Deposition and Sputtering
• Vacuum evaporation:
–Chamber evacuated toless than 10-6 Torr
–Resistance heating
–Metal evaporation
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 33
Other Methods for Deposition of Conducting or Insulating Films
• DC Sputtering (Fig. 3.13.a)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 34
Deposition, continued• Radio Frequency AC Sputtering (Fig.3.13.b)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 35
Methods for Electrical and Mechanical Contact
• Soldering–Wetting: (Fig. 3.14)
Young´s eq.: lsl cos s
19.01.2011 Slide 36
Leadless soldering• Leadless soldering replacing lead-based solder due health hazards and
environmental issues
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 37
Soldering, continued
• Most common solder alloy: 63 % Sn / 37 % Pb (eutectic)Melting point 183 oC
Table 3.6: Properties of solder alloys 63 Sn:37 Pb or 60 Sn:40 Pb (weight %)
Temp. [oC] Value UnitElectrical resistivity, 25
1000.170.32
µOhmm"
Thermal conductivity, °K 25100
5149
W/m°K"
Thermal coeff. of expansion, 24.5 ppm/°CSpecific heat 46 000 J/kg°K
Modulus of elasticity, E 25 32 000 N/mm2
Density, 8.5 g/cm3
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 38
Soldering, continued• Fatigue: Coffin-Mansons formula:
N0.5 x p = constant
where N is number of stress cycles, and p is the relative deformation amplitude, meaning that both number of cycles and stress level determine lifetime
• Useful adition : 2 % Ag (Surface mount), to reduce leaching (dissolution of the termination metal that leads to deterioration of mechanical and electrical properties)
• Harmful contaminant: Au, will increase brittleness because of AuSn intermetallics
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 39
Soldering, continued
• Fig.3.15: Behaviour of solder metal at different temperatures, schematically. [W. Engelmaier].
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 40
Soldering, continued
• Fig. 3.16: Solder joint fatigue in surface mounted assemblies is often caused by power cycling.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 41
Soldering, continued
• Fig. 3.17: Experimental data for fatigue in Sn/Pb solder fillet by cyclical mechanical stress. High temperature and low cycling frequency gives the fastest failure, because the grain structure relaxes most and is damaged
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 42
Soldering, continued
• Fig. 3.18. a) Left: Dissolution rate of Ag in solder metal, and in solder metal with 2 % Ag, as function of temperatureb) Right: Dissolution rate of various metals in solder alloy
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 43
Soldering, continuedTable 3.7: Alloys for soft soldering [3.11]
Alloy System [mass%]
Code Melting Temperature [°C]
Shear Strength
at 1 mm min-1 [Nmm-2] Sn Pb Ag Sb In Bi Solid Liquid 20°C 100°C 100 Sn 232 22,1 19,0 63 37 Sn63 183 183 - - 60 40 Sn60 183 188 33,6 21,6 50 50 Sn50 183 216 30,0 24,0 40 60 Sn40 183 234 34,3 13,7 10 90 275 302 28,9 14,7 5 95 310 314 62 36 2 Sn62 179 179 43,0 18,6 10 88 2 268 299 - - 5 93,5 1,5 296 301 23,8 15,7 96,5 3,5 Ag3,5 221 221 37,7 22,5 95 5 Sb5 236 243 37,2 21,1 40 60 In60 174 185 - - 50 50 In50 180 209 - - 37 37 25 In25 138 138 - - 42 58 Bi58 139 139 50,0 19,5 15 33 52 Bi52 96 96 - - 34 42 24 Bi24 100 146 34,3 17,5 43 43 14 Bi14 143 163 - -
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 44
Soldering, continued
• Flux and cleaning–Purpose of flux:
• Dissolve and remove oxides etc.
• Protect surface
• Improve wetting
–Categories:• Soluble in organic liquids
• Water soluble
–Types:• Organic resin fluxes ("rosin")
• Organic non resin based fluxes
• Inorganic fluxes
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 45
Soldering: Flux and cleaning
• Fig. 3.19: Time for solder alloy to wet a pure Cu surface, depending on the activation of the solder flux. The degree of activation is given by the concentration of Cl- ions in the flux (temperature: 230 °C)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 46
Soldering: Flux and Cleaning
• Designations:– R (Rosin, non-activated): No clorine added.
– RMA (Rosin mildly activated): < 0.5 % Cl
– RA (Rosin, activated): > 0.5 % Cl
• Cleaning– Freon (TCTFE) now forbidden. Replaced by alcohol etc.
– Trend: No cleaning
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 47
Gluing• Purposes:
–Mechanical assembly–Electrical contact–Thermal contact
• Materials: polymers: –Epoxy, acrylic, phenolic, polyimide–Metal particles for electrical conductivity:
r = 1 - 10 x 10 -6 ohm m–Metal or ceramic particles for thermal
conductivity:K ≈ 1 - 3 W /m x oC
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 48
Gluing, continued
• Fig. 3.20: Thermal conductivity of epoxy adhesive with various amounts of Ag [3.16 a)]. The concentration is in volume % Ag. (23 vol. % corresponds to approximately 80 weight %).
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 49
Gluing, continued• Fig. 3.21: The thermal
resistance from the electronically active part, on top of the Si chip (¨junction¨) through a bonding layer of glue or soft solder and a thin alumina ceramic layer covered with Cu to heat sink. The samples with chips bonded by gluing, C and A, have approximately twice as high total thermal resistance as those which are soft soldered, D and B.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 50
Chip Mounting: Die Bonding
• Fig. 3.22: Thermal resistance from junction to heat sink through adhesive of various thicknesses. For thick layers the resistance approaches the value calculated, based on the bulk thermal conductivity of the adhesive. For thin layers the resistance is higher, approaching a constant value, which indicates an "interface thermal resistance" caused by defects in the adhesive layer
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 51
Chip Mounting: Die Bonding, continued
• Eutectic die bonding:
– Au/Si (363 oC), Au/Sn (280 oC)
• Soft soldering: Sn/Pb, Ag/Pb
• Glueing• Adhesive cracking, fig. 3.23: Thermal cycling
induces defects giving increased thermal resistance.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 52
Chip Mounting: Die Bonding, continued• Fig. 3.24: Use of adhesive for
contacting IC-chips with small pitch, schematically: a): Anisotropic conductive adhesive, the conduction is through the metal particles in the adhesive;
b): Electrically insulating adhesive, the conduction is through point contacts where the adhesive has been squeezed out.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 53
Si Chip Electrical Contact
• Wire bonding
• Tape Automated Bonding (TAB)
• Flip chip
• Planar bonding
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 54
Wire Bonding
• Ultrasonic
• Thermo-compression
• Thermosonic
• Geometry Types–Ball - wedge:
Shown in illustration
–Wedge - wedge
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 55
Wire Bonding
From Small Precision Tools
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 56
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 57
• Connection made in two steps:
– Inner Lead Bonding• Connecting tape to chip
– Outer Lead Bonding• Connecting tape to substrate
• Connection made by thermocompression
Tape Automated Bonding (TAB)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 58
Tape Automated Bonding (TAB)• Standard process:
– Fabrication of gold bumps (Fig. 3.28):
• Deposition of contact/barrier metals
• Photolithography
• Electroplating
• Strip and etch barrier metals
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 59
TAB, continued
• Fig. 3.26: A picture of a TAB film with the Cu pattern, as well as the holes in the film for excising the circuits, and the sprocket holes for moving the film during processing.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 60
TAB, continued
• Fig. 3.27: The main steps in TAB processing.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 61
Tape Automated Bonding (TAB)
• Wafer cutting
• Fabrication of TAB film–Hole punching–Cu foil lamination–Lithography + etch of Cu pattern–Tinning of Cu
• Inner lead bonding (ILB)
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 62
TAB, continued
• Protection (glob top)
• Testing
• Outer lead bonding:–Excising, lead
bending–Placement/thermode
soldering
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 63
Advantages of TAB:
• High packaging density
• Can contact chips with >1000 I/O
• Excellent electrical properties (high frequency)
• Robust mounting
• Pre-testable (contrary to COB)
• Gold bumps give hermetic seal to chip
• Gang bonding gives high yield, is less time consuming than wirebonding
• TAB film can be used as daughter board
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 64
Disadvantages of TAB:
• Non-standard wafer processes
• Special custom design film for chip
• Needs special machine/tool for OLB
• Demanding repair
• Low availability of std. chips and TAB service
• Little standardization
19.01.2011
• Active face of chip is flipped towards substrate– Substrate pads are identical to chip pads
• Area array connections possible• All connections done simultaneously• Smallest possible footprint (1:1)• Short interconnections
– Low inductance and resistance– Excellent electrical properties
• Little flexibility– Change of chip pad configuration implies redesign of
substrate
• Small, but increasing amount of interconnections are flip chip
• To be dealt with in much more detail…
Flip chip
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 66
Flip Chip
• Process:–Deposit barrier metals–Deposit solder bump metals (solder) by
photolithography/metal mask and sputter or plating
–Reflow–Cut wafer–Turn chip and mount on substrate–Heat substrate to reflow solder
19.01.2011
• Introduced by IBM 1962
• Flip chip has been used for decades, but with little impact
– Wire bonding is far more common
– Flip chip technology has not been considered mature
– The industrial infrastructure has been small
• The market share of flip chip connections is believed to increase significantly
– Wire bonding will remain dominating for many years
• Flip chip especially for ”advanced packaging”
Flip Chip, history
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 68
Flip Chip, continued
• Advantages:–Highest packing density–Excellent hi freq. properties–Up to 10 000 I/O
• Disadvantages:–Very difficult placement and reliable
solder/cleaning–Lack of thermal flexibility
19.01.2011
• Chip– Si, GaAs, etc.
• Substrate– Ceramic, organic,
dielectic-covered metal, silicon, etc.
• Interconnection system:– Metallization on chip and substrate pads
– Chip (or substrate) bumps
– Bonding material
– Underfill encapsulant
Flip Chip consists of:
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• Flip chip is not standardized!
Different Flip Chip technologies
From C. Lee, ESTC 2006, Dresden
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 71
Wire Bonding, TAB and Flip ChipTable 3.8: Comparison of wire bonding, TAB, and flip chip soldering [3.22]
Bonding technology Wire Bond TAB Flip-ChipMaterial(s) Al Au Cu Pb-SnMelting temperature [°C] 660 1064 1084 310Bonding geometry 25 µm diameter
x 2,5 mm length25x100 µm tapex 2,5 mm length
125 µm diameter100 µm height
Typical pitch [µm] 170 µm perimeter 200µm perimeter 250 µm areaMinimum Pitch [µm] 60 µm perimeter 70 µm perimeter 50 µm areaStrength per bond [gram] 6 10 50 30Lead resistance [mOhm] 142 122 17 1,2Interlead capacitance [pF] 0,025 0,025 0,006 <0,001Lead inductance [nH] 2,6 2,6 2,1 <0,2Thermal resistance[°C/mW] per bond 80 52 8 0,5No. of I/Os per chipTypical pitch8 mm chip size 184 160 1024Minimum pitch8 mm chip size 266 400 15150
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 72
Planar Bonding with Adaptive Routing
• Fig. 3.32: Planar bonding with laser-assisted adaptive conductor routing.
The top two figures a) and b) show a substrate cross section with details of the mounting of the chip in an etched through-hole.
Figure c) shows the conductor layers and polyimide insulation on top of the substrate. The bottom figures show an exploded view of all the layers.
19.01.2011 Electronic Pack….. Chapter 3 Materials and Basic Processes Slide 73
End of Chapter 3 Materials and Basic Processes
•Important issues:– Materials:
• Distinguish between metals, ceramics, glasses and plastics– Important mechanical and thermal parameters like modulus of eleasticity, thermal
expansion coefficient and thermal conductivity.– Important electrical parameters like dielectric constant and resistivity or
conductivity– Have a basic understand of the importance and value of the most important
materials parameter, and why they are important for the use of the specific material in specific applications.
– For instance knowing the electrical conductivity of copper or thermal conductivity of epoxy within an accuracy of 25%
– Basic processes• Lithographics, screen and stencil printing, etching, plating, vacuum
deposition, sputtering, soldering, gluing, wire bonding, TAB, and flip chip– Other basic processes described in other chapters, like surface mount technology
•Questions and discussions?