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R. G
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TT1-Chap6 - 1
Chapter 6
6 Flux Pinning and Critical Currents
6.1 Power Applications of Superconductivity
6.1.1 Examples
6.1.2 Materials Requirements
6.1.3 Superconducting Wires and Tapes
6.2 Critical Current of Superconductors
6.2.1 Depairing Critical Current Density
6.2.2 Depinning Critical Current Density
6.3 Flux Line Pinning
6.4 Magnetization of Hard Superconductors
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TT1-Chap6 - 2
Jc
B T
Jc (T)Jc (B)
Bc2 (T)
Bc2 (0)
Jc (0)
Tc (0)
6.1 Power Applications of Superconductivity
• power applications require high Tc, Bc2, and Jc
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TT1-Chap6 - 3
6.1 Power Applications of Superconductivity
• energy transport and storage
SMES (2 MJ)superconducting magnetic energy storage
fault current limiter
6.1.1 Examples
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TT1-Chap6 - 4
6.1 Power Applications of Superconductivity
Comparison of the amount of space consumed by a superconducting cable (blue) with copper wires carrying the same amount of current
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TT1-Chap6 - 5
• superconducting magnets
magnetic resonance imaging
high energy physics
fusion
6.1 Power Applications of Superconductivity
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TT1-Chap6 - 6
1m
6.1 Power Applications of Superconductivity
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TT1-Chap6 - 7
AMS-02 is the Alpha Magnetic Spectrometer, a superconducting particle physics experiment which will be launched on the Space Shuttle and installed on the International Space Station. The project is an international collaboration of 56 research institutes from 16 countries.
6.1 Power Applications of Superconductivity
http://www.scientificmagnetics.co.uk/special-superconducting-magnets.htm
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TT1-Chap6 - 8
6.1.2 Materials Requirements
• manufacturability• low cost• availability (sustainability)
• high Tc, Bc2, Jc
6.1 Power Applications of Superconductivity
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TT1-Chap6 - 9
• important low Tc superconductors
NbTi Nb3Sn
material:
Tc
1:1 alloy
9.6 K
Bc2(T=0) 10.5 - 15 T
intermetallic compound
18 K
23 - 29 T
(application in commercial magnets)
• high Tc superconductors
BSCCO YBCO
material:
Tc
powder in Ag-tube
110 K
Bc2(T=0) 1000 T
thin film on metal tape
91 K
800 T
still under development
6.1.2 Materials Requirements
material parameters:
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TT1-Chap6 - 10
6.1.2 Materials Requirements
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TT1-Chap6 - 11
6.1.2 Materials Requirements
material parameters:
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TT1-Chap6 - 12
6.1.2 Materials Requirements
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TT1-Chap6 - 15
crit
ical
curr
en
td
en
sity
(n
on
-Cu
) (
A/m
m²)
10
100
1,000
10,000
100,000
1,000,000
0 5 10 15 20 25 30 35
applied field (T)
YBCO: Tape, || Tape-plane, SuperPower
(Used in NHMFL tested Insert Coil 2007)
YBCO: Tape, |_ Tape Plane, SuperPower
(Used in NHMFL tested Insert Coil 2007)
Bi-2212: non-Ag Jc, 427 fil. round wire,
Ag/SC=3 (Hasegawa ASC-2000/MT17-2001)
Nb-Ti: Max @1.9 K for whole LHC NbTi
strand production (CERN, Boutboul '07)
Nb-Ti: Nb-47wt%Ti, 1.8 K, Lee, Naus and
Larbalestier UW-ASC'96
Nb3Sn: Non-Cu Jc Internal Sn OI-ST RRP
1.3 mm, ASC'02/ICMC'03
Nb3Sn: Bronze route int. stab. -VAC-HP,
non-(Cu+Ta) Jc, Thoener et al., Erice '96.
Nb3Sn: 1.8 K Non-Cu Jc Internal Sn OI-ST
RRP 1.3 mm, ASC'02/ICMC'03
Nb3Al: RQHT+2 At.% Cu, 0.4m/s (Iijima et al
2002)
Bi 2223: Rolled 85 Fil. Tape (AmSC) B||,
UW'6/96
Bi 2223: Rolled 85 Fil. Tape (AmSC) B|_,
UW'6/96
MgB2: 4.2 K "high oxygen" film 2, Eom et
al. (UW) Nature 31 May '02
MgB2: Tape - Columbus (Grasso) MEM'06
2212round wire
2223tape B|_
@ 4.2 K unless
otherwise stated
Nb3SnInternal Sn
Nb3Sn1.8 K
2223tape B||
Nb3SnITER
MgB2
film MgB2
tape
Nb3Al
RQHT
1.9 K LHC
Nb-Ti
YBCO B||c
YBCO B||ab
6.1.2 Materials Requirements
critical current density of superconductors:
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TT1-Chap6 - 17
10
100
1000
10000
0 5 10 15 20 25 30 35 40 45
applied field (T)
J E(A
/mm
²)
YBCO Insert Tape (B|| Tape Plane)
YBCO Insert Tape (B Tape Plane)
MgB2 19Fil 24% Fill (HyperTech)
2212 OI-ST 28% Ceramic Filaments
NbTi LHC Production 38%SC (4.2 K)
Nb3Sn RRP Internal Sn (OI-ST)
Nb3Sn High Sn Bronze Cu:Non-Cu 0.3
YBCO B|| Tape Plane
YBCO B Tape Plane
2212
RRP Nb3Sn
Bronze
Nb3SnMgB2
Nb-Ti
SuperPower
tape used in
record breaking
NHMFL insert
coil 2007
18+1 MgB2/Nb/Cu/Monel
Courtesy M. Tomsic,
2007
427 filament strand
with Ag alloy outer
sheath tested at
NHMFL
Maximal JE for
entire LHC NbTi
strand production
(–) CERN-
T. Boutboul '07,
and (- -) <5 T data
from Boutboul et
al. MT-19, IEEE-
TASC’06)
Complied from
ASC'02 and
ICMC'03 papers
(J. Parrell OI-
ST)
4543 filament High Sn
Bronze-16wt.%Sn-
0.3wt%Ti (Miyazaki-
MT18-IEEE’04)
6.1.2 Materials Requirements
“engineering” critical current density of superconductors:
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TT1-Chap6 - 19
December 2002 - Compiled by Peter J. Lee
University of Wisconsin-Madison
Applied Superconductivity
Center
crit
ical
cu
rre
nt
de
nsi
ty (
A/m
m²)
10
100
1 000
10 000
0 5 10 15 20 25 30applied field (T)
Nb3Al
Nb-Ti
2212 Round Wire
2223
At 4.2 K Unless
Otherwise Stated
1.8 K
Nb-Ti-Ta
Nb3Sn Internal Sn
1.8 K
Nb3SnBronze Process
Nb3AlITER
2 K
Nb-Ti-Ta
Nb-Ti: Example of Best Industrial Scale Heat Treated
Composites ~1990 (compilation)
Nb-Ti(Fe): 1.9 K, Full-scale multifilamentary billet for
FNAL/LHC (OS-STG) ASC'98
Nb-44wt.%Ti-15wt.%Ta: at 1.8 K, monofil. high field
optimized, unpubl. Lee et al. (UW-ASC) ‘96
Nb-37Ti-22Ta: at 2.05 K, 210 fil. strand, 400 h total HT,
Chernyi et al. (Kharkov), ASC2000
Nb3Sn: Bronze route VAC 62000 filament, non-Cu
0.1µW·m 1.8 K Jc, VAC/NHMFL data courtesy M. Thoener.
Nb3Sn: Non-Cu Jc Internal Sn OI-ST RRP #6555-A, 0.8mm,
LTSW 2002
Nb3Al: Nb stabilized 2-stage JR process (Hitachi,TML-
NRIM,IMR-TU), Fukuda et al. ICMC/ICEC '96
Nb3Al: JAERI strand for ITER TF coil
Bi-2212: non-Ag Jc, 427 fil. round wire, Ag/SC=3
(Hasegawa ASC2000+MT17-2001)
Bi 2223: Rolled 85 Fil. Tape (AmSC) B||, UW'6/96
Bi 2223: Rolled 85 Fil. Tape (AmSC) B|_, UW'6/96
6.1.2 Materials Requirements
“engineering” critical current density of 100 m cable
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TT1-Chap6 - 20
6.1.3 Superconducting Wires and Tapes
fabrication of superconducting wires:
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TT1-Chap6 - 21
superconducting wires:NbTi, Nb3Sn in Cu-matrix
cable from high-Tc
superconductor
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 22
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 23
pipe coating
stainless pipe
electrical insulation
high temperaturesuperconductor
LN2
LN2
Sumitomo
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 24
6.1.3 Superconducting Wires and Tapes
high-Tc wires:
can be made
• Ag is too expensive and too soft• HTS have higher critical fields
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TT1-Chap6 - 25
Preparation of multi-filamentary BiSrCaCu-oxid (2223) tapes in Ag/AgMg-sheath by the powder in tube method Investigation of the structural and superconducting properties
cross-section of 61 filamentary tape
600m tape on a coil for Jc-measurement
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 26
6.1.3 Superconducting Wires and Tapes
HTS cable
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TT1-Chap6 - 27
6.1.3 Superconducting Wires and Tapes
The "AmpaCity" project has been kicked off: The RWE Group and its partners are just about to replace a 1-kilometre-long high-voltage cable connecting two transformer stations in the Ruhr city of Essen with a state-of-the-art superconductor solution. This will mark the longest superconductor cable installation in the world. As part of this project, the Karlsruhe Institute of Technology will analyse suitable superconducting and insulating materials.
The three-phase, concentric 10 kV cable will be produced by Nexans and is designed for a transmission capacity of 40 megawatts.
19. January 2012
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TT1-Chap6 - 28
evaporator230 mm
• low cost process for large area deposition of HTS films
• high quality and reproducibility
heater700°C
O2 oxygen
Y
rotating
vacuum pumpto
vacuum
substrate
Ba
Cu
"Garching-technology": http://www.theva.com/
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 29
6.1.3 Superconducting Wires and Tapes
coated conductor:
superconducting film onflexible steel tape
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TT1-Chap6 - 30
6.1.3 Superconducting Wires and Tapes
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TT1-Chap6 - 31
6.1.3 Superconducting Wires and Tapes
pulsed laser
deposition
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TT1-Chap6 - 32
fiber for IR laser heating
substrate manipulators
excimer laser optics
target manipulators
pyrometer
casing of RHEED screen and camera
operator tool
AFM/STM system
atomic oxygen source
Laser Molecular Beam Epitaxy, Garching 2006
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TT1-Chap6 - 33
L-MBE: Fully automated target holder
K.-W. Nielsen,S. Geprägs,Th. Brenninger
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TT1-Chap6 - 34
Fully automated control of beam profile
S. Geprägs,M. Opel,Th. Brenninger
computer controlled variation of beam profile and power density
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TT1-Chap6 - 36
6.1.4 Superconducting Bulk Material
bulk superconductors as “permanent magnets”
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TT1-Chap6 - 37
6.1.4 Superconducting Bulk Material
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TT1-Chap6 - 38
6.1.4 Superconducting Bulk Material
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TT1-Chap6 - 39
maximum velocity:
581 km/h (02. 12. 2003)
Jap. Yamanashi MAGLEV-System
MLX01
(42.8 km long test track between Sakaigawaand Akiyama)
6.1.4 Superconducting Bulk Material
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TT1-Chap6 - 41
6.2 Critical Current of Superconductors
• increase of supercurrent density results in increase of velocity of superconducting electron
critical current density: kinetic energy = binding energy of Cooper pairs
• increase of supercurrent results in Lorentz force on flux lines in mixed stateof type-II superconductors
critical current density: Lorentz force = pinning force
depairing critical current density
depinning critical current density
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TT1-Chap6 - 42
6.2.1 Depairing Critical Current Density
• minimization of free enthalpy of superconductor: integration of enthalpy density over whole volume of superconductorminimization by variation of Y and A
revision: Ginzburg-Landau theory:
1. GL-equation
2. GL-equation
2nd characteristic length scale
GL coherence length
Ginzburg-Landau equations:
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TT1-Chap6 - 43
6.2.1 Depairing Critical Current Density
• consider a thin wire with diameter d << xGL
no amplitude variation of order parameter Y across wire
• superconducting material is assumed homogeneous• same current density along the wire
no amplitude variation of order parameter Y along the wire
• we use 1. and 2. GL equation:
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TT1-Chap6 - 44
6.2.1 Depairing Critical Current Density
• we obtain:
condensation energy per Cooper pair
reduction of is just proportional to ratio of kinetic and condensation energy
order parameter decreases due to additional kinetic energy of pairs
• expression for current density:
• determine maximum of Js by setting :
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TT1-Chap6 - 45
6.2.1 Depairing Critical Current Density
• T-dependence of Jc determined by T-dependence of lL and xGL:
close to Tc:
• we can use
• note: according London theory we would expect Jc = Hcth/lL
(London theory does not take into account reduction of OP with increasing Js)
Pb:Bcth ≈ 80 mT, lL ≈ 40 nm Jc ≈ 8 x 1011 A/m²
Nb:Bcth ≈ 200 mT, lL ≈ 40 nm Jc ≈ 2 x 1012 A/m²
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TT1-Chap6 - 46
6.2.1 Depairing Critical Current Density
• Gedanken experiment: what is the critical current of a Pb rod with large diameter d ?
d = 1cm
critical current Ic = Jc ∙ A = Jc ∙ p (d/2)² ≈ 6 x 107 A ????
London theory:
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TT1-Chap6 - 47
d = 1cm
lL ≈ 40 nm
critical current:
Ic = Jc ∙ A = Jc ∙ p d lL ≈ 1 x 103 A
• supercurrent flow only within surface layer of thickness lL
6.2.1 Depairing Critical Current Density
technical critical current density:
Jc = Ic / ∙ p (d/2)² ≈ 10 A/mm²
comparable to Cu-wire
• solution: - use multifilament wire with d < lL
difficult to fabricate
- use type-II superconductor
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TT1-Chap6 - 48
6.2.2 Depinning Critical Current Density
• type-II superconductors:partial field penetration above Bc1
Bi > 0 for Bext > Bc1
Shubnikov phase between Bc1 ≤ Bext ≤ Bc2
upper and lower critical fields Bc1 and Bc2
200 nm
• in mixed state field penetratesthe superconductor
current flow is not restrictedto thin surface layer
high values of Bc2
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TT1-Chap6 - 49
6.2.2 Depinning Critical Current Density
• extreme type-II superconductors (k >> 1) have very high Bc2 high field operation
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TT1-Chap6 - 50
6.2.2 Depinning Critical Current Density
• how does the transport current interact with the vortex lattice ??
µ0Hext
H(r)y0
y(r)
0 x l r
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TT1-Chap6 - 51
- force on single pair:
fL results in force on charge carriers, which cannot leave conductor
flux motion perpendicular to applied transport current
6.2.2 Depinning Critical Current Density
• interaction of a transport current with the vortex lattice:
Fnetto
total current density
for charge density r:
force density charge density
Jtr
Jcirc
Bx
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TT1-Chap6 - 52
6.2.2 Depinning Critical Current Density
Jtr
Jcirc
B small total superfluid velocity small total FL
large total superfluid velocity large total FL
net force
core offlux line
• analogy to Magnus force
• origin of force acting on a flux line (plausibility check)
• Benoulli‘s principle:an increase in the speed of the fluid occurs simultaneously with a decrease in pressure or a decrease in the fluid's potential energy
• without transport current: zero net force• contributions of circulating current cancel
+ =
+ =
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TT1-Chap6 - 53
0
• FL causes motion of the flux line- what is the velocity vL of the flux line (depends on damping)- what is the work done by the Lorentz force
homogeneous
6.2.2 Depinning Critical Current Density
• calculation of the total Lorentz force on single flux line:
• force per unit length of flux line:
Jtr
FL
B
L
B(r)y0
y(r)
0r
x l
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TT1-Chap6 - 54
6.2.2 Depinning Critical Current Density
• dissipation by moving flux line:- motion with velocity vL induces electric field:- E is parallel to Jtr acts like resistive voltage
• Faraday's law of induction:The induced electromotive force (EMF) in any closed circuit is equal to the time rate of change of the magnetic flux through the circuit.
• electromotive force (EMF):
flux density inside loop doesnot change
(no flux change)
vL
A
B
JtrE
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TT1-Chap6 - 55
sample widthsample length cross-sectional area
superconductor shows resistance: flux-flow resistance
6.2.2 Depinning Critical Current Density
• generated power for - single flux line:- N flux lines:
voltage drop along sample
• power balance:
L
bB
other point of view: power balance
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TT1-Chap6 - 56
• assumption: single flux line in sample
• phase difference between sample ends:
• integration path 2:
• note: only the phase factor eiq must be unambiguous
6.2.2 Depinning Critical Current Density
• phase change due to flux motion:
2p
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TT1-Chap6 - 57
• crossing of single flux line changes phase differenceby 𝜑 = 𝜃2 − 𝜃1 = 2𝜋
• required time for crossing: 𝛿𝑡 = 𝑏/𝑣𝐿
q1
q2
temporal change of phase difference
6.2.2 Depinning Critical Current Density
• moving flux line:
vL
N
b
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TT1-Chap6 - 58
- we make use of
"2. Josephson Equation“
6.2.2 Depinning Critical Current Density
• relation between change of phase difference and electric field:
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TT1-Chap6 - 59
- behind the flux-line: |Ψ| increases
recombination of pairs by phonon emission:
(a) pair breaking and recombination:
Ψ 𝑥, 𝑡
x
pair breakingrecombination
vL
- in front of flux-line: |Ψ| decreases
pairs have to break up
- pair breaking due to absorption of phonons:
- finite phonon lifetime delays thermal equilibrium:
irreversible process friction, viscous flow
- electric energy is transferred to heat
6.2.2 Depinning Critical Current Density
• power dissipation during vortex motion:
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TT1-Chap6 - 60
(b) eddy current losses:
eddy current with ohmic losses
core of the flux line is considered as normal conductor
• both mechanisms: E vL friction force
• balance between Lorentz and friction force: vL becomes stationary
vL Jtr vL E
• we expect: Jtr E Ohm‘s law zero critical current density
B(x,t)
x
dB/dt
vF
6.2.2 Depinning Critical Current Density
• power dissipation during vortex motion:
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TT1-Chap6 - 61
• Ic depends on defect density
• inhomogeneities pin flux-lines: flux pinning
• vL = 0 is caused by flux pinning no work, no dissipation
no voltage drop
• experimental result:
„technically usable“ critical current
ideal superconductor
superconductor with low defect density
superconductor with high defect density
V
IIc
6.3 Flux Line Pinning
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TT1-Chap6 - 62
precipitatewith small
or normalconducting
• at precipitate: vortex core causes no additional loss in condensation energy
x
condensation energyis lost
„pinning force"
• most effective, if defect size x
• motion of vortex core costs energy (condensation energy)
• effective binding forced at precipitate
6.3 Flux Line Pinning
• pinning mechanism:
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TT1-Chap6 - 63
6.3 Flux Line Pinning
r
Vpin
• pinning force: reduce rp to increase Fp
optimum: rp ≈ x (vortex size ≈ pin size)
reduced condensation energy at defect
rpcondensation energy:
homgeneous for ideal superconductor
• for high-temperature superconductors: x ≈ 1 nm, Econ large
very small pinning sites required large pinning force
• problem for HTS: thermally activated escape of flux line (thermally activated flux flow: TAFF)
(x small and T large)
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TT1-Chap6 - 64
6.3 Flux Line Pinning
• so far: pinning of a single flux line
• now: pinning of a flux line lattice
complicated problem:- flux line lattice is elastic object
(stiffness of the lattice, flux lines can bend)- pinning potential is disordered
• example: net pinning force of completely stiff flux line lattice by statistical pinningpotential vanishes flux line lattice has to deform to adopt to pinning potential even if a single flux line does not sit in a potential well, it is pinned by
the interaction with the other flux lines (rigidity of the lattice) collective pinning theory
see e.g.Vortices in high-temperature superconductorsG. Blatter, M. V. Feigel'man, V. B. Geshkenbein, A. I. Larkin, and V. M. VinokurRev. Mod. Phys. 66, 1125 (1994)
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TT1-Chap6 - 65
important for superconducting thin films
relative length difference of flux line at different positions may be large
x
surface
surface roughness
6.3 Flux Line Pinning
• surface pinning:
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TT1-Chap6 - 66
• decrease of Jc with increasing B: - several flux lines per pinning site
• decrease of Jc with increasing T: - thermally activated flux motion- reduced condensation energy
E
JJc
6.3 Flux Line Pinning
• Jc as a function of temperature and applied magnetic field:
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TT1-Chap6 - 67
• pinning prevents flux motion, i.e. penetration and exit of flux lines
• Bi is inhomogeneous within the sample
hysteresis loop !
• Bc1 and Bc2 stay the same
remanentflux
Bi
BaBc1 Bc2-Bc1-Bc2
virgin curve
ideal SC
6.4 Magnetization of Hard Superconductors
• flux line pinning in an external field:
magnetization curve
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TT1-Chap6 - 68
• sample surface: jump ideal magnetization curve
B
SLx
Ba < Bc1 (Meißner)
Ba Bc2
Ba increases
Bi
BaBc1 Bc2
• within superconductor: field gradient gradient of flux density
• gradient decreases with increasing magnetic field
• flux lines repel each other: motion if repulsion > pinning force
6.4 Magnetization of Hard Superconductors
• field distribution in sample:
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TT1-Chap6 - 69
Bi
Bc1 Bc2-Bc1
Ba
B
x0
• gradient changes sign
• Ba < - Bc1: flux lines with opposite direction penetrate
recombination with frozen-in flux lines inside the superconductor
6.4 Magnetization of Hard Superconductors
• field distribution in sample (demagnetization):
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TT1-Chap6 - 70
• flux gradient shielding current
Ampère‘s law
• macroscopic average:
• here:
• for small Bi,z/x: J < Jc flux lines are pinned x
y
• for large Bi,z/x: J > Jc flux lines move
"critical state"
• note:
x
B
• motion until J = Jc
measurement of Bi,z(x)/x: Jc
Jc decreases with increasing Bi smaller slope
6.4 Magnetization of Hard Superconductors
• Bean model:
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TT1-Chap6 - 71
6.4 Magnetization of Hard Superconductors
• magneto-optical imaging of flux distribution
Meißner state
critical state
remanent state
B
SL x
B
x0
SL