Client : Daeeun Global - crystalwash.com · Client : Daeeun Global Date : March 12, ... NMR Solvent Data Sheet Soluvets ... 1,1,2,2-Tetrachloroethane-d2 6.0 73.78 (3)

Analysis Report

Cluster Analysis of Water

Client : Daeeun Global

Date : March 12, 2014

tested by

Korea Polymer Testing & Research Institute (KOPTRI), Ltd. (ISO 17025 Certified Laboratory)

CRYSTAL WASH

Korea Polymer Testing & Research institute www.polymer.co.kr

Koptri_1420236 Daeeun Global Cluster Analysis of Water-1

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2. Testing Institute, Analyzer, and Author

Address: Korea Polymer Testing & Research Institute (KOPTRI) 24-194 Sangwolgok-dong, Sungbook-ku, Seoul 136-120, Korea

Analyzer: Jinhwa.Kim Signature :

Tel: +82-2-963-2586, Fax: +82-2-963-2587, e-mail: [email protected]

Technical director : Jiyoung.Park Signature :

Tel: +82-2-963-2566, Fax: +82-2-963-2587, e-mail: [email protected]

Quality director: cheonki.kim Signature :

Tel: +82-2-963-2566, Fax: +82-2-963-2587 e-mail: [email protected]

Chief executive: Kihong Park, Ph.D. Signature : Tel: +82-2-969-5291, Fax: +82-2-963-2587 e-mail: [email protected]



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3. Analysis Conditions

3-1. 1H-NMR ( Nuclear Magnet Resonance spectrometer)

(1) Equipment : JeolJNM-LA400 with LFG, JEOL (Japan)

(2) Solvent : Deuterium Oxide (system peak : 2.50 (5))

(3) TMS Reference : None



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Normative Reference

NMR Solvent Data Sheet

Soluvets 1H Chemical Shift (ppm from TMS)

(multiplicity)

13C Chemical Shift (ppm from TMS)

(multiplicity)

1H Chemical Shift of HOD

(ppm from TMS)

Acetic Acid-d4 11.65 (1) 178.99 (1) 11.5

2.04 (5) 20.0 (7) 11.5

Acetone-d6 206.68 (1) 2.8

2.05 (5) 29.92 (7) 2.8

Acetonitrile-d3 118.69 (1) 2.1 1.94 (5) 1.39 (7) 2.1

Benzene-d6 7.16 (1) 128.39 (3) 0.4

Chloroform-d 7.24 (1) 77.23 (3) 1.5

Cyclohexane-d12 1.38 (1) 26.43 (5) 0.8

Deuterium Oxide 4.80 (DSS) NA 4.8

4.81 (TSP)

N, N-Dimethyl-formamide-d7 8.03 (1) 163.15 (3) 3.5 2.92 (5) 34.89 (7) 2.75 (5) 29.76 (7)

Dimethyl Sulfoxide-d6 2.50 (5) 39.51 (7) 3.3

1,4-Dioxane-d8 3.53 (m) 66.66 (5) 2.4

Ethanol-d6 5.19 (1) 5.3 3.56 (1) 56.96 (5) 1.11 (m) 17.31 (7)

Methanol-d4 4.78 (1) 4.9 3.31 (5) 49.15 (7)

Methylene Chloride-d2 5.32 (3) 54.00 (5) 1.5

Pyridine-d5

8.74 (1) 150.35 (3) 5

7.58 (1) 135.91 (3)

7.22 (1) 123.87 (3)

1,1,2,2-Tetrachloroethane-d2 6.0 73.78 (3)

Tetrahydrofuran-d8 3.58 (1) 67.57 (5) 2.4-2.5

1.73 (1) 25.37 (5)

Toluene-d8

137.86 (1) 0.4

7.09 (m) 129.24 (3)

7.00 (1) 128.33 (3)

6.98 (5) 125.49 (3)

2.09 (5) 20.4 (7)

Trifluoroacetic Acid-d 11.50 (1) 164.2 (4) 11.5

116.6 (4)

Trifluoroethanol-d3 5.02 (1) 126.3 (4) 5

3.88 (4x3) 61.5 (4x5)



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4. Analysis Results

4-1. 17O-NMR

Table 3.Result of 17O-NMR

Sample name Unit Result

Koptri-1420236-1 17O-NMR See ficture 1



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5. Raw data

17O-NMR data

Ficture1. Koptri-1420236-1

( Koptri-1420236-1-1)



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( Koptri-1420236-1-2)

The End.

Documents

Client : Daeeun Global - crystalwash.com · Client : Daeeun Global Date : March 12, ... NMR Solvent Data Sheet Soluvets ... 1,1,2,2-Tetrachloroethane-d2 6.0 73.78 (3)