CLIENT NAME: CONOCOPHILLIPS CANADA RES. …registry.mvlwb.ca/Documents/S12A-005/S12A-005 - Lab Results - Tow... · Routine Chemistry Water Analysis 6310 ROPER ROAD EDMONTON, ... (BTEXS/F1-F4)

CLIENT NAME: CONOCOPHILLIPS CANADA RES. CORP.2100, 250 6 AVENUE SWCALGARY, AB T2P3H7 (403) 233-4000

6310 ROPER ROADEDMONTON, ALBERTA

CANADA T6B 3P9TEL (780)395-2525FAX (780)462-2490

http://www.agatlabs.com

Jennifer Jones, Trace Organics SupervisorTRACE ORGANICS REVIEWED BY:

Melinda Guay, Technical ReviewerWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 10

Jul 04, 2013

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (780) 395-2525

13E731516AGAT WORK ORDER:

ATTENTION TO: Cyril Jenkins

PROJECT NO: Chinook

Laboratories (V1) Page 1 of 10

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers, Geologists and Geophysicists of Alberta (APEGGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items tested

Tow Hill Water

#1SAMPLE DESCRIPTION:

WaterSAMPLE TYPE:

6/28/2013DATE SAMPLED:

4508539G / S RDLUnitParameter

<0.0005Benzene 0.0005mg/L

<0.0005Toluene 0.0005mg/L

<0.0005Ethylbenzene 0.0005mg/L

<0.0005Xylenes 0.0005mg/L

<0.0005Styrene 0.0005mg/L

<0.1C6 - C10 (F1) 0.1mg/L

<0.1C6 - C10 (F1 minus BTEX) 0.1mg/L

<0.1C>10 - C16 0.1mg/L

0.2C16 - C34 0.1mg/L

<0.1C>34 - C50 0.1mg/L

Acceptable LimitsUnitSurrogate

100Toluene-d8 (BTEX) % 50-150

95o-Terphenyl (F2-F4) % 50-150

RDL - Reported Detection Limit; G / S - Guideline / StandardComments:4508539 The C>6 - C10 fraction is calculated using the toluene response factor.

The C10 - C16 fraction is calculated using the average response factor for nC10, nC16 and nC34.BTEX has NOT been subtracted from Fraction 1.Sample is blank corrected.


DATE RECEIVED: 2013-06-29

Certificate of Analysis

ATTENTION TO: Cyril JenkinsCLIENT NAME: CONOCOPHILLIPS CANADA RES. CORP.

AGAT WORK ORDER: 13E731516

DATE REPORTED: 2013-07-04

PROJECT NO: Chinook

ConocoPhillips - Petroleum Hydrocarbons (BTEXS/F1-F4) in Water




CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 10

Tow Hill Water


WaterSAMPLE TYPE:



0.008Dissolved Aluminum 0.0020.005mg/L

<0.001Dissolved Antimony 0.0010.006mg/L

0.003Dissolved Arsenic 0.0010.005mg/L

0.16Dissolved Barium 0.051mg/L

<0.01Dissolved Boron 0.010.5mg/L

<0.000016Dissolved Cadmium 0.0000160.000017mg/L

<0.001Dissolved Chromium 0.001mg/L

0.003Dissolved Copper 0.0020.002mg/L

0.9Dissolved Iron 0.10.3mg/L

<0.001Dissolved Lead 0.0010.001mg/L

0.281Dissolved Manganese 0.0050.05mg/L

0.005Dissolved Molybdenum 0.003mg/L

<0.01Dissolved Nickel 0.010.025mg/L

0.001Dissolved Selenium 0.0010.001mg/L

<0.00005Dissolved Silver 0.000050.0001mg/L

13.7Dissolved Sodium 0.6200mg/L

<0.0005Dissolved Thallium 0.0005mg/L

<0.001Dissolved Uranium 0.0010.01mg/L

0.098Dissolved Zinc 0.0010.03mg/L

RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to ABTier1 GW (Ag, F)Comments:4508539 < - Values refer to Report Detection Limit.







PROJECT NO: Chinook

CCME / Alberta Tier 1 Metals (Dissolved)






Tow Hill Water


WaterSAMPLE TYPE:



8.02pH NA6.5-8.5pH Units

<5p - Alkalinity (as CaCO3) 5mg/L

171T - Alkalinity (as CaCO3) 5mg/L

209Bicarbonate 5mg/L

<5Carbonate 5mg/L

<5Hydroxide 5mg/L

451Electrical Conductivity 1uS/cm

<0.05Fluoride 0.051.5mg/L

17Chloride 1250mg/L

<0.05Nitrite 0.053.2mg/L

<0.5Nitrate 0.545mg/L

40Sulfate 1500mg/L

55.2Dissolved Calcium 0.3mg/L

15.7Dissolved Magnesium 0.2mg/L

13.7Dissolved Sodium 0.6200mg/L

3.9Dissolved Potassium 0.6mg/L

0.9Dissolved Iron 0.10.3mg/L

0.281Dissolved Manganese 0.0050.05mg/L

248Calculated TDS 1mg/L

202Hardness 1mg CaCO3/L

102Ion Balance 0.1%

<0.01Nitrate + Nitrite-N 0.01mg/L

<0.113Nitrate-N 0.113mg/L

<0.015Nitrite-N 0.015mg/L

RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to CCME (D Water)Comments:4508539 < - Values refer to Report Detection Limits.







PROJECT NO: Chinook

Routine Chemistry Water Analysis






ConocoPhillips - Petroleum Hydrocarbons (BTEXS/F1-F4) in Water

Benzene 416 < 0.0005 < 0.0005 0.0% < 0.0005 95% 80% 120% 96% 80% 120% 94% 70% 130%

Toluene 416 < 0.0005 < 0.0005 0.0% < 0.0005 97% 80% 120% 89% 80% 120% 92% 70% 130%

Ethylbenzene 416 < 0.0005 < 0.0005 0.0% < 0.0005 104% 80% 120% 93% 80% 120% 94% 70% 130%

Xylenes 416 < 0.0005 < 0.0005 0.0% < 0.0005 90% 80% 120% 103% 80% 120% 109% 70% 130%

Styrene

416 < 0.0005 < 0.0005 0.0% < 0.0005 91% 80% 120% 86% 80% 120% 93% 70% 130%

C6 - C10 (F1) 416 < 0.1 < 0.1 0.0% < 0.1 112% 80% 120% 83% 80% 120% 70% 70% 130%

C>10 - C16 423 4508455 <0.1 <0.1 0.0% < 0.1 106% 80% 120% 99% 80% 120% 108% 70% 130%

C16 - C34 423 4508455 <0.1 <0.1 0.0% < 0.1 109% 80% 120% 114% 80% 120% 121% 70% 130%

C>34 - C50 423 4508455 <0.1 <0.1 0.0% < 0.1 110% 80% 120%

Certified By:



Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance


CLIENT NAME: CONOCOPHILLIPS CANADA RES. CORP.

PROJECT NO: Chinook

Trace Organics Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Jul 04, 2013 REFERENCE MATERIAL

MethodBlank




QUALITY ASSURANCE REPORT (V1) Page 5 of 10


Routine Chemistry Water Analysis

pH 351 4508544 9.02 9.02 0.0% 100% 80% 120%

p - Alkalinity (as CaCO3) 351 4508544 147 147 0.0% < 5

T - Alkalinity (as CaCO3) 351 4508544 1550 1550 0.0% < 5 100% 80% 120%

Bicarbonate 351 4508544 1530 1530 0.0% < 5

Carbonate

351 4508544 176 176 0.0% < 5

Hydroxide 351 4508544 < 5 < 5 0.0% < 5

Electrical Conductivity 351 4508544 5770 5770 0.0% < 1 102% 80% 120%

Fluoride 496 4508522 < 0.05 < 0.05 0.0% < 0.05 97% 80% 120% 99% 80% 120% 107% 80% 120%

Chloride 496 4508522 30 30 0.0% < 1 99% 80% 120% 96% 80% 120% 100% 80% 120%

Nitrite

496 4508522 < 0.05 < 0.05 0.0% < 0.05 99% 80% 120% 99% 80% 120% 99% 80% 120%

Nitrate 496 4508522 < 0.5 < 0.5 0.0% < 0.5 95% 80% 120% 94% 80% 120% 97% 80% 120%

Sulfate 496 4508522 19 19 0.0% < 1 99% 80% 120% 100% 80% 120% 100% 80% 120%

Dissolved Calcium 625 4510158 322 323 0.2% < 0.3 104% 80% 120% 106% 80% 120%

Dissolved Magnesium 625 4510158 239 239 0.1% < 0.2 101% 80% 120% 99% 80% 120%

Dissolved Sodium

625 4510158 350 348 0.6% < 0.6 95% 80% 120% 99% 80% 120%

Dissolved Potassium 625 4510158 12.1 12.1 0.0% < 0.6 91% 80% 120% 95% 80% 120%

Dissolved Iron 625 4510158 1.7 1.6 6.1% < 0.1 97% 80% 120% 91% 80% 120%

Dissolved Manganese 625 4510158 0.026 0.023 12.2% < 0.005 94% 80% 120% 87% 80% 120%

Comments: N/A - Not Available.

CCME / Alberta Tier 1 Metals (Dissolved)

Dissolved Aluminum 591 4508544 0.005 0.005 0.0% < 0.002 94% 80% 120% 93% 80% 120%

Dissolved Antimony 591 4508544 0.003 0.002 NA < 0.001 109% 80% 120% 94% 80% 120%

Dissolved Arsenic 591 4508544 0.001 0.001 0.0% < 0.001 100% 80% 120% 103% 80% 120%

Dissolved Barium 591 4508544 3.00 3.03 1.0% < 0.05 117% 80% 120% 83% 80% 120%

Dissolved Boron

591 4508544 0.80 0.80 0.0% < 0.01 94% 80% 120% 94% 80% 120%

Dissolved Cadmium 591 4508544 0.000257 0.000200 24.9% < 0.000016 97% 80% 120% 94% 80% 120%

Dissolved Chromium 591 4508544 < 0.001 < 0.001 0.0% < 0.001 98% 80% 120% 99% 80% 120%

Dissolved Copper 591 4508544 0.001 0.001 0.0% < 0.002 93% 80% 120% 84% 80% 120%

Dissolved Iron 625 4510158 1.7 1.6 6.1% < 0.1 97% 80% 120% 91% 80% 120%

Dissolved Lead

591 4508544 0.002 0.002 0.0% < 0.001 99% 80% 120% 97% 80% 120%

Dissolved Manganese 625 4510158 0.026 0.023 12.2% < 0.005 94% 80% 120% 87% 80% 120%

Dissolved Molybdenum 591 4508544 0.148 0.151 2.0% < 0.003 99% 80% 120% 99% 80% 120%

Dissolved Nickel 591 4508544 < 0.01 < 0.01 0.0% < 0.01 91% 80% 120% 92% 80% 120%

Dissolved Selenium 591 4508544 0.0269 0.0262 2.6% < 0.001 99% 80% 120% 102% 80% 120%

Dissolved Silver

591 4508544 < 0.00005 < 0.00005 0.0% < 0.00005 102% 80% 120% 98% 80% 120%

Dissolved Sodium 625 4510158 350 348 0.6% < 0.6 95% 80% 120% 99% 80% 120%

Dissolved Thallium 591 4508544 < 0.0005 < 0.0005 0.0% < 0.0005 98% 80% 120% 95% 80% 120%

Dissolved Uranium 591 4508544 < 0.001 < 0.001 0.0% < 0.001 99% 80% 120% 103% 80% 120%



Dup #1 RPDMeasured


Quality Assurance



PROJECT NO: Chinook

Water Analysis

UpperLower

AcceptableLimits


IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits


MethodBlank






Dissolved Zinc 591 4508544 < 0.001 < 0.001 0.0% < 0.001 99% 80% 120% 92% 80% 120%

Certified By:



Dup #1 RPDMeasured


Quality Assurance



PROJECT NO: Chinook

Water Analysis (Continued)

UpperLower

AcceptableLimits


IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits


MethodBlank






Trace Organics Analysis

BenzeneORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

TolueneORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

EthylbenzeneORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

XylenesORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

StyreneORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

C6 - C10 (F1)ORG-170-5110/5140/5430/5440

CCME Tier 1 Method GC/FID

C6 - C10 (F1 minus BTEX)ORG-170-5110/5140/5430/5440

CCME Tier 1 Method GC/FID

C>10 - C16 ORG-170-5120/5300 CCME Tier 1 Method GC/FID

C16 - C34 ORG-170-5120/5300 CCME Tier 1 Method GC/FID

C>34 - C50 ORG-170-5120/5300 CCME Tier 1 Method GC/FID

Toluene-d8 (BTEX)ORG-170-5110/5140/5430/5440

EPA 8260 GC/MS

o-Terphenyl (F2-F4) ORG-170-5120/5300 CCME Tier 1 Method GC/FID



Method Summary



PROJECT NO: Chinook

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER




METHOD SUMMARY (V1) Page 8 of 10

Water Analysis

Dissolved AluminumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved AntimonyINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved ArsenicINOR-171-6202, INOR-171-6100

SM 3125 B ICP-MS

Dissolved BariumINOR-171-6202, INOR-171-6100

SM 3125 B ICP-MS

Dissolved BoronINOR-171-6202, INOR-171-6100

SM 3125 B ICP-MS

Dissolved CadmiumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved ChromiumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved CopperINOR-171-6202, INOR-171-6100

SM 3125 B ICP-MS

Dissolved IronINOR-171-6202, INOR-171-6100

SM 3120 B ICP/OES

Dissolved LeadINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved ManganeseINOR-171-6202, INOR-171-6100

SM 3120 B ICP/OES

Dissolved MolybdenumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved NickelINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved SeleniumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved SilverINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved SodiumINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES

Dissolved ThalliumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved UraniumINOR-171-6202, INOR-171-6100

SM 3125 B ICP/MS

Dissolved ZincINOR-171-6202, INOR-171-6100

SM 3125 B ICP-MS

pH INOR-171-6205 SM 4500 H+ PC Titrate

p - Alkalinity (as CaCO3) INOR-171-6205 SM 2320 B PC Titrate

T - Alkalinity (as CaCO3) INOR-171-6205 SM 2320 B PC Titrate

Bicarbonate INOR-171-6205 SM 2320 B PC Titrate

Carbonate INOR-171-6205 SM 2320 B PC Titrate

Hydroxide INOR-171-6205 SM 2320 B PC Titrate

Electrical Conductivity INOR-171-6205 SM 2510 B PC Titrate

Fluoride INOR-171-6200 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-171-6200 SM 4110 B ION CHROMATOGRAPH

Nitrite INOR-171-6200 SM 4110 B ION CHROMATOGRAPH

Nitrate INOR-171-6200 SM 4110 B ION CHROMATOGRAPH

Sulfate INOR-171-6200 SM 4110 B ION CHROMATOGRAPH

Dissolved CalciumINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES

Dissolved MagnesiumINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES



Method Summary



PROJECT NO: Chinook






Dissolved SodiumINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES

Dissolved PotassiumINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES

Dissolved IronINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES

Dissolved ManganeseINOR-171-6201, INOR-171-6100

SM 3120 B ICP/OES



Method Summary



PROJECT NO: Chinook




