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Research Trends Array MEAs for high-throughput screening of DMFC anode catalysts A high-throughput screening device for fuel cell electrocatalysts was developed incorporating fuel cell design features. State-of-the-art MEA fabri- cation methods permitted catalyst testing with realistic reactant exposure histories and steady- state reaction conditions. Results are reported for testing of several DMFC anode catalysts. R. Liu and E.S. Smotkin: J. of Electroanalytical Chemistry 535(1/2) 49–55 (1 November 2002). Link between power and energy density in DMFCs DMFC performance data were used to model a continuous loop mode, clarifying the impact of parameter variations on energy and power density. Compromises are required for reasonable energy and power densities to be simultaneously maintained in DMFCs using Nafion™ 117. B. Gurau and E.S. Smotkin: J. of Power Sources 112(2) 339–352 (14 November 2002). Hybrid compressive mica SOFC seals Thermal cycling was conducted on compressive mica SOFC seals at 800°C in air for plain and hybrid designs. The hybrid adds two glass interlayers, for greatly reduced leakage. The muscovite mica in the hybrid could yield a fuel leak of ~0.9% of the total for a 60-cell stack. Y.-S. Chou and J.W. Stevenson: J. of Power Sources 112(2) 376–383 (14 November 2002). Micro fuel cell array with ‘flip-flop’ interconnection This design for integrated series connection of PEMFCs in a planar array is particularly favorable for miniature fuel cells, and has been prototyped using etch and deposition techniques. The ‘flip- flop’ configuration gives the advantage of a continuous electrolyte with no interconnecting bridges across or around the membrane. S.J. Lee, A. Chang-Chien, S.W. Cha, R. O’Hayre, Y.I. Park, Y. Saito and F.B. Prinz: J. of Power Sources 112(2) 410–418 (14 November 2002). DMFC with small back-up battery This hybrid cellphone power supply comprises a DMFC and parallel backup Li-ion battery. In talk mode, 10–50% of the full current (100 mA) is provided by the DMFC and the remainder by the battery. In standby, the DMFC module supplies 10 mA, with the excess recharging the battery. J. Han and E.-S. Park: J. of Power Sources 112(2) 477–483 (14 November 2002). Metal-membrane 25 kW methanol fuel processor for FCV A 25 kW on-board methanol fuel processor has been developed, comprising a steam reformer and two metal-membrane modules to clean the gas mixture to high-purity hydrogen. The operating condition of the reformer and metal membrane modules is nearly identical, for simple operation and a compact system by eliminating extensive temperature control of intermediate gas streams. J. Han, S.-M. Lee and H. Chang: J. of Power Sources 112(2) 484–490 (14 November 2002). Membrane-electrode-gasket assembly (MEGA) technology for PEMFCs This novel PEMFC membrane-electrode-gasket assembly (MEGA) was prepared by sealing an MEA in a molded gasket, with a silicone-based liquid mix injected into the MEA borders. The technology offers reduced fabrication time, quality control and substitution of failed elements. A. Pozio, L. Giorgi, M. De Francesco, R.F. Silva, R. Lo Presti and A. Danzi: J. of Power Sources 112(2) 491–496 (14 November 2002). Water balance in a PEMFC system The amount of water lost from a system as exhaust water vapor is be very sensitive to system pressure and ambient temperature, while the amount of water produced in the system depends on fuel composition. Fuels with a high hydrogen/carbon ratio allow operation with net water production under a range of operating conditions. S. Ahmed, J. Kopasz, R. Kumar and M. Krumpelt: J. of Power Sources 112(2) 519–530 (14 November 2002). Combined water vapor exchanger/ exhaust gas diffusion barrier Fuel cells operating on hydrocarbon fuels require water vapor injection into the fuel stream. This passive approach eliminates the need for a separate water source, pumps and actuators, reducing parasitic thermal losses. A capillary pump recovers exhaust water vapor, and provides a diffusion barrier that prevents exhaust gases from entering the fuel stream. R.E. Williford, B.K. Hatchell and P. Singh: J. of Power Sources 112(2) 570–576 (14 Nov. 2002). RESEARCH TRENDS 12 Fuel Cells Bulletin May 2003 fuel cells with integrated hydrogen storage; and development of components for direct methanol fuel cells. Zentrum für BrennstoffzellenTechnik (ZBT) The ZBT in Duisburg was established in 2001 for development, system integration and coordination across stationary, automotive and portable fuel cell systems. Its R&D portfolio ranges from prototype assembly to small series production. The institute links basic research at universities and its industrial application. Its activities are focused in four divisions: Gas process and hydrogen technology; Materials and components for fuel cell stacks; Systems and Applications; and Simulation and integration. In particular its researchers are working on compact PEM hydrogen generators, stack characterization for various manufacturers, development of its own stacks, and integrating hydrogen technology and fuel cells into power supply systems. New members welcome Even with more than 230 members already, the Fuel Cell Network is keen to recruit new members with expertise that is needed for the development of fuel cell systems. In particular, it would welcome approaches from companies from industrial branches of chemistry, materials, mechanical, chemical or electrical engineering that could play an important role as system integrators or suppliers. Membership – and inclusion in the ‘Industries Atlas’ – is free, and is necessary for participation in the working groups. Application forms can be found on the website. The Network offers various services: Information and communication (e.g. conferences, a newsletter, working groups). Cooperative and individual projects. Qualification (e.g. workshops, round-tables, company visits). Internationalization (e.g. participation in delegations and trade fairs, contacts with international fuel cell initiatives). Settlement (e.g. consultancy in cooperation with regional industrial assistance, and acquisition of companies willing to relocate to NRW). Public relations (e.g. a website including a members-only area, an online ‘industries atlas’, technical publications). For more information on the Fuel Cell Network NRW, contact: Dr-Ing Frank Koch or Dr-Ing Ernst Kugeler, Fuel Cell Network NRW [Kompetenz-Netzwerk Brennstoffzelle NRW], c/o NRW State Initiative on Future Energies [Landesinitiative Zukunftsenergien NRW], Haroldstrasse 4, D-40213 Düsseldorf, Germany.Tel: +49 211 86642-16 (Dr-Ing Koch) or -15 (Dr-Ing Kugeler),Fax: +49 211 86642-22, Email: brennstoffzelle@energieland. nrw.de (or [email protected] or kugeler@ energieland.nrw.de),Web: www.fuelcell-nrw.de or www.brennstoffzelle-nrw.de For more information on the projects or project funding, contact the executive body of the ‘REN Programme’: Forschungszentrum Jülich GmbH, Projektträger ETN, D-52425 Jülich, Germany. Tel: +49 2461 690601, Fax: +49 2461 690610, Email: [email protected],Web: www.kfa-juelich.de/etn

Combined water vapor exchanger/ exhaust gas diffusion barrier

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Research TrendsArray MEAs for high-throughputscreening of DMFC anode catalystsA high-throughput screening device for fuel cellelectrocatalysts was developed incorporating fuelcell design features. State-of-the-art MEA fabri-cation methods permitted catalyst testing withrealistic reactant exposure histories and steady-state reaction conditions. Results are reported fortesting of several DMFC anode catalysts.R. Liu and E.S. Smotkin: J. of ElectroanalyticalChemistry 535(1/2) 49–55 (1 November 2002).

Link between power and energydensity in DMFCsDMFC performance data were used to model acontinuous loop mode, clarifying the impact ofparameter variations on energy and powerdensity. Compromises are required for reasonableenergy and power densities to be simultaneouslymaintained in DMFCs using Nafion™ 117.B. Gurau and E.S. Smotkin: J. of Power Sources112(2) 339–352 (14 November 2002).

Hybrid compressive mica SOFC sealsThermal cycling was conducted on compressivemica SOFC seals at 800°C in air for plain andhybrid designs. The hybrid adds two glassinterlayers, for greatly reduced leakage. Themuscovite mica in the hybrid could yield a fuelleak of ~0.9% of the total for a 60-cell stack.Y.-S. Chou and J.W. Stevenson: J. of PowerSources 112(2) 376–383 (14 November 2002).

Micro fuel cell array with ‘flip-flop’interconnectionThis design for integrated series connection ofPEMFCs in a planar array is particularly favorablefor miniature fuel cells, and has been prototypedusing etch and deposition techniques. The ‘flip-flop’ configuration gives the advantage of acontinuous electrolyte with no interconnectingbridges across or around the membrane.S.J. Lee, A. Chang-Chien, S.W. Cha, R. O’Hayre,Y.I. Park, Y. Saito and F.B. Prinz: J. of PowerSources 112(2) 410–418 (14 November 2002).

DMFC with small back-up batteryThis hybrid cellphone power supply comprises aDMFC and parallel backup Li-ion battery. In talkmode, 10–50% of the full current (100 mA) isprovided by the DMFC and the remainder by thebattery. In standby, the DMFC module supplies10 mA, with the excess recharging the battery.J. Han and E.-S. Park: J. of Power Sources 112(2)477–483 (14 November 2002).

Metal-membrane 25 kW methanolfuel processor for FCVA 25 kW on-board methanol fuel processor hasbeen developed, comprising a steam reformer andtwo metal-membrane modules to clean the gasmixture to high-purity hydrogen. The operatingcondition of the reformer and metal membranemodules is nearly identical, for simple operationand a compact system by eliminating extensivetemperature control of intermediate gas streams.J. Han, S.-M. Lee and H. Chang: J. of PowerSources 112(2) 484–490 (14 November 2002).

Membrane-electrode-gasket assembly(MEGA) technology for PEMFCsThis novel PEMFC membrane-electrode-gasketassembly (MEGA) was prepared by sealing anMEA in a molded gasket, with a silicone-basedliquid mix injected into the MEA borders. Thetechnology offers reduced fabrication time, qualitycontrol and substitution of failed elements.A. Pozio, L. Giorgi, M. De Francesco, R.F. Silva,R. Lo Presti and A. Danzi: J. of Power Sources112(2) 491–496 (14 November 2002).

Water balance in a PEMFC systemThe amount of water lost from a system as exhaustwater vapor is be very sensitive to system pressureand ambient temperature, while the amount ofwater produced in the system depends on fuelcomposition. Fuels with a high hydrogen/carbonratio allow operation with net water productionunder a range of operating conditions.S. Ahmed, J. Kopasz, R. Kumar and M.Krumpelt: J. of Power Sources 112(2) 519–530(14 November 2002).

Combined water vapor exchanger/exhaust gas diffusion barrierFuel cells operating on hydrocarbon fuels requirewater vapor injection into the fuel stream. Thispassive approach eliminates the need for aseparate water source, pumps and actuators,reducing parasitic thermal losses. A capillarypump recovers exhaust water vapor, and providesa diffusion barrier that prevents exhaust gasesfrom entering the fuel stream.R.E. Williford, B.K. Hatchell and P. Singh: J. ofPower Sources 112(2) 570–576 (14 Nov. 2002).

RESEARCH TRENDS

12Fuel Cells Bulletin May 2003

fuel cells with integrated hydrogen storage; anddevelopment of components for direct methanolfuel cells.

Zentrum fürBrennstoffzellenTechnik (ZBT)The ZBT in Duisburg was established in 2001 for development, system integration andcoordination across stationary, automotive andportable fuel cell systems. Its R&D portfolioranges from prototype assembly to small seriesproduction.

The institute links basic research atuniversities and its industrial application. Itsactivities are focused in four divisions: Gasprocess and hydrogen technology; Materials andcomponents for fuel cell stacks; Systems andApplications; and Simulation and integration.

In particular its researchers are working oncompact PEM hydrogen generators, stackcharacterization for various manufacturers,development of its own stacks, and integratinghydrogen technology and fuel cells into powersupply systems.

New members welcomeEven with more than 230 members already, theFuel Cell Network is keen to recruit newmembers with expertise that is needed for thedevelopment of fuel cell systems. In particular, itwould welcome approaches from companiesfrom industrial branches of chemistry, materials,mechanical, chemical or electrical engineeringthat could play an important role as systemintegrators or suppliers.

Membership – and inclusion in the ‘IndustriesAtlas’ – is free, and is necessary for participationin the working groups. Application forms can befound on the website.

The Network offers various services:

• Information and communication (e.g.conferences, a newsletter, working groups).

• Cooperative and individual projects.• Qualification (e.g. workshops, round-tables,

company visits).• Internationalization (e.g. participation in

delegations and trade fairs, contacts withinternational fuel cell initiatives).

• Settlement (e.g. consultancy in cooperationwith regional industrial assistance, andacquisition of companies willing to relocateto NRW).

• Public relations (e.g. a website including amembers-only area, an online ‘industriesatlas’, technical publications).

For more information on the Fuel Cell NetworkNRW, contact: Dr-Ing Frank Koch or Dr-Ing ErnstKugeler, Fuel Cell Network NRW [Kompetenz-NetzwerkBrennstoffzelle NRW], c/o NRW State Initiative onFuture Energies [Landesinitiative Zukunftsenergien NRW],Haroldstrasse 4, D-40213 Düsseldorf, Germany. Tel: +49211 86642-16 (Dr-Ing Koch) or -15 (Dr-Ing Kugeler), Fax:+49 211 86642-22, Email: [email protected] (or [email protected] or [email protected]), Web: www.fuelcell-nrw.de orwww.brennstoffzelle-nrw.de

For more information on the projects orproject funding, contact the executive body ofthe ‘REN Programme’: Forschungszentrum JülichGmbH, Projektträger ETN, D-52425 Jülich, Germany.Tel: +49 2461 690601, Fax: +49 2461 690610, Email:[email protected], Web: www.kfa-juelich.de/etn