completed by the Region III™ Environmental · The maximum concentrations of compounds found in the trip blank, equipment blanks, or method blanks are listed below. ... Cft c* 9

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

. . . . . . . .CENTRAL REGIONAL LABORATORY83a.BESTGATE ROAD

ANNAPOLIS, MARYLAND 21401(301) 266-9180 [

I ; '

! j ' ! , - . . ,

DATE : December 8, :19S9 '} - '-". "7: '-"~-X_: •*_*" ; ".".:"L

SUBJECT: 9- Del JJuarries-. Site

FROM : Theresa A.Region III ESAT;DPQ (3ES23)

!

• Donna McCartneyRegional Project MaHager ( 3HW21 )

THRU : Patricia J. KrantzQuality Assurance Branch (

* Quarriescompleted by the Region III Environmental™

have any : questions: please

Attachment

cc: Andy Hop ton,, COM

TID File: 03890 15 !" Task 1126

flR3029!6

2S68A RIVA ROADSUITE 300ANNAPOUS, MD 21401

.M PHONE; 301-266-9887aesBBc&'CoriSLCJWTs

DATE: 7 DECEMBER 1989

SUBJECTS QmMI VALIDATION FOCASE 32544.,.. -fite: DELTA QUARRIES

EROM: DOUO HcXN gS v~" .. .. DON Q'BRI|lf.*-yORGANIC DATA REVIEWER ; *'_ 'ORGANIC £)AfA REVIEWER

IS AT DEPUTY PROJECT OFFICER;

THRU: DAN DRESSfiTEftMT tfSNApSR (acting)

Case 12544 consisted 9f ten'Vio °w evel water samples,submitted to IEAr Inc. / for volatile, semi-volatile^ andpesticide/PCB ahalyses. One (1) field duplicate _palr,_ one (1)trip blank/ and two (2) equipment blanks were included in thesesamples. The "trip blank wasT analyzed for volatiles only. Thesamples weife anaiyzed as a Contract Laboratory Program (CLP)Routine Analytical Service (RAS).

All samples were successfully analyzed for all target compounds,with the exception of 2-butanone. All instrumentând methodsensitivities were according to the Contract^Laboratory Program(CLP) Routine""Analytical Service (RAS) protocol.

MAJOR .jgQBLBM

o The response factor (RF) for 2-butanone was less than 0.05 inthe initial and/or continuing calibrations* The guantitationlimits for these compounds were qualified "R", and thepositive results were qualified "L". (See Table I in AppendixF for the affected samples).

HINDI :HBBl!BHffJ~ _ "". "• - - ".--" " . ' - . - . - . - .:,-;, ' '. -. _..._ TjS; :-~' --~-

O The^volatiies analyses of samples "CCHOO, 'CCH05_/ and CCH06 wereperformed eight (8) days from the date of sample collection.The technical holding time for volatile aromatics in watersamples of seven (7) days has been exceeded by~~one (1) day.The guantitation limits for aromatic volatiles were qualified

"the"affected samples.

302917

Page 2 of 3

o Several compounds failed precision criteria for initial and/orcontinuing calibrations. Quantitation limits for thesecompounds were qualified "UJ", and positive results warequalified "J" for the affected samples. (See Table I inAppendix F) . .........

BOTBS

o The MS/MSD analyses had compounds other than the spikingcompounds present. Following is a table of results andprecision estimates for these non-spiked ccsmpounds:

MS/MSD Non-Spiked Compounds

___Concentration fucr/L)___Compound . ,: CCH03 CCH03MS CCH03MSD %RSD

2-butanone 170 L 180 L 180 L 3.3%

phenol 72 NE NE IN

RSD - Relative Standard DeviationIN - IndeterminateNE - Mot Evaluated, a spiking compound found

during original sample analysis

o One (1) field duplicate pair was analyzed. Following is atable of results and precision estimates for these analyses:

Field Duplicate

: Concentration fgg/L)_____Compound . CCH05 _ CCH06 %RPD

1,1-dichloroethane 34 36 5.71,1,1-trichloroethane 29 31 6.7trichloroethene 3 J 3 J 0

o The reported Tentatively Identified Compounds (TIC's) inAppendix D have been reviewed and corrected during datavalidation. The semivolatile blanks contained several TIC's.These semivolatile TIC's were crossed out on the Form I's, andwere noted as blank contaminants.

fiR3Q2918

Page 3 of 3

The maximum concentrations of compounds found in the tripblank, equipment blanks, or method blanks are listed below.All samples with concentrations of common laboratorycontaminants less than ten times (<10X) the blankconcentration, and .uncommon laboratory contaminants less thanfive times (<5X) the blank concentration have been qualified"B11 in the data summary. (See Appendix F).

Compound Concentration

acetone * 12

* - Common Laboratory Contaminant

All data for Case 12544 were reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModifications for use within Region III. The text of this reportaddresses only those problems affecting usability.

ATTACHMENTS

1) Appendix A - Glossary of Data Qualifiers2) Appendix B - Data Summary. These include:

(a) All positive results for target compounds withqualifier codes where applicable.(b) All unusable detection limits (qualified "R").

3) Appendix C - Results as Reported by the Laboratory for AllTarget Compounds

4) Appendix D - Reviewed and Corrected Tentatively IdentifiedCompounds

5) Appendix E - DPO Report for Contractual Compliance6) Appendix F - Support Documentation

DCN - DM911A10

Appendix A

Glossary of Data Qualifiers

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES RELATING TO(confidence concerning presence or absence of compounds):

U s Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected*

(NO CODE) « Confirmed identification.

B - Not detected substantially above the level reportedin laboratory or field blanks.

R * Unreliable result. Analyte may or may not bepresent in the sample. Supporting data necessary toconfirm result.

N » Tentative identification. Consider present.Special methods may be needed to confirm itspresence or absence in future sampling efforts.

CODES RELATED IQ OUMTIT&TION(can'be used for both positive results and sample quantitatijlimits):

J « Analyte present. Reported value may not be accurateor precise.

K - Analyte present. Reported value may be biased high.Actual value is expected to be lower.

I, « Analyte present. Reported value may be biased low.Actual value is expected to be higher.

UJ « Not detected, quantitation limit may be inaccurateor imprecise.

TIL - Not detected, quantitation limit is probably higher.

CODES

Q - No analytical result.

HR30292I':

Appendix B

Data Summary Forms

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Appendix C

Results as Reported by the Laboratoryfor all Target Compounds

30293

1 '1AVOLATILE ORGANICS ANALYSIS DATA SHEET

CCHOOLab Name: ISA ; ' Contract: 6S-W8-Q045 j

Lab Code: IEA Case po.: 12544 SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER Lab Sample ID:

Sample wt/vol: 5. (g/mL) ML Lab File ID: 0822306

Level: (low/med) LOW ; :: : Date Received: 8/16/89

% Moisture: not dec.100. , - .-: . ; ,. ^ ^Date Analyzed: 8/22/89

Column: (pack/cap) CAP . . \ Dilution Factor: 1.00

i • * • ' • ' -CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Qi r f. ..'..* -

i i——————j——f| 74-87-3—————Chlorornethane __________ I 10. U

74-83-9—————Brqmomethane_____.______75-01-4—————Vinyl Chloride_________75-00-3—————Chloroe thane___________75-09-2—————Methylene Chloride :.67-64-1—————Acetone ,________75-15-0—————Carbon Disulfide________75-35-4—————1,1-Dichloroethene_______75-34-3—————lrlrDichloroethane_______540-59-0—————1,2-Dichloroethene (total),67-66-3—————Chloroform_________\____"107-06-2 ————— 1,2-Dichloroethane „ ... .__78-93-3—————2-Butanone_________71-55-6—————1,1 > 1-Trichloroethane ___56-23-5—————Carbon Tetrachloride_____108-05-4—————Vinyl Acetate _________75-27-4—————Bromodichloromethane1-87-5—————1,2-Dichloropropane

10061-01-5——.-—-cis-1, 3-Dichloropropene79-01-6—————Trichloroethene124-48-1—————Dibromochloromethane_79-00-5—————1,1,2-Trichloroethane71-43-2—————Benzene

10061-02-6—————trans-1,3-Dichloropropene75-25-2—————Bromofonn108-10-1—————4-Methyl-2-Pentanone____591-78-6—————2-He?canone____________127-18-4—————Tetrachloroethene ..79-34-5—————1,1,5,2-Tetrachloroethane108-88-3—————Toluene ___________'108-90-7—————Chlorobenzene _________100-41-4—————Sthylbenzene__________100-42-5———— _____1330-20-7—————Xylene (total).

10. |U10. IU10. |U5. |U

13. IB.5. !U5. |U5. |U5. 1U5. IU5. IU10. |U5. |U5. IU10. |U5. |U5. [U5. |U5. IU5. IU5. IU5. [U5. [U5. |U10. |U10. ]U5. [U5. IU5. |U5. IU5. IU5. |U5. |U

IB EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ___

| CCHOOLab Name: IEA . Contract: 68-W8-0045

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO



Level: (low/med) LOW Date Received: 8/16/89

% Moisture: not dec.100. dec. 0. Date Extracted: 8/21/89

Extraction: (SepF/Cont/Sonc) CONT Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol______________111-44-4—————bis (2-Chloroethyl) ether95-57-8—————2-Chlorophenol_______541-73-1—————1,3-Dichlorobenzene __106-46-7—————1,4-Dichlorobensene __100-51-6—————Benzyl alcohol_______95-50-1—————1,2-Dichlorobenzene __95-48-7—————2-Methylphenol108-60-1—————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane_________98-95-3—————Nitrobenzene_____________78-59-1—————Isophorone______________88-75-5———--2-Nitrophenol ___________105-67-9—————2 , 4-Dimethylphenol________65-85-0—————Benzoic acid111-91-1—————bis(2-Chloroethoxy)methane_120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene_____91-20-3—————Naphthalene _____________106-47-8—————4-Chloroaniline _________87-68-3—————Hexachlorobutadiene ______59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4,6-Trichlorophenol _____95-95-4—————2,4,5-Trichlorophenol _____91-58-7—————2-Chloronaphthalene ______88-74-4—————2-Nitroaniline___________131-11-3—————Dimethylphthalate ________208-96-8—————Acenap_hthylene___________606-20-2—————2,6-Dinitrotoluene________

10. |U10. |U10. |U10. |U10. IU10. (U10. JU10. [U10. (U10. |U10. |U10. IU10. |U10. |U10. JU10. IU50. |U10. |U10. |U10. |U10. |U10. |U10. |U10, IU10. IU10. IU10. |U50. |U10. |U50. IU10. IU10. "IU10. ]U

FORM I SV-1 o « 1/87 Re^

i 1C EPA SAMPLE NOSEMIVQLATILE ORGANICS ANALYSIS DATA SHEET - ______

; I CCHOOLab Name: IEA . i. Contract: 6S-W8-0045 I

Lab Code: IEA Case No.: 12544 "SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER| , „ : .„.,.„, j , Lab Sample ID:

Sample wt/vol: 1000. (g/mL) ML ^ Lab,File ID: 0901403

Q Level: (low/med) LOW ; -: Date Received: 8/16/89

% Moisture: not dec.100. dec. 0. , ,. Date Extracted: 8/21/89


GPC Cleanup: (Y/N) N pH: 6.0 " Dilution Factor: 1.00

1 ' '""" CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

99-09-2—————3-Nitroaniline__83-32-9 ——— — -Aceiiaphthene____51-28-5 ————— 2,4-Dinitrophenol100-02-7 ————— 4-Nitrophenol __132-64-9—————Dibenzofuran121-14-2—————2,4-Dinitrotoluene______84-66-2—————Diet'hylPhthalate

7005-72-3—————4-Chlorophenyl-phenylether.86-73-7—————Fluorene______________"100-01-6—————4-Nitroaniline______534-52-1—————4,6-pinitro-2-methylphenol_86-30-6—————N-Nitrosodiphenylamine (1)~101-55-3 ————— 4-Bromophenyl-phenylether ~118-74-1—————Hexachlorobenzene ____"87-86-5—————Pentachlorophenol ______85-01-8—————Phenanthrene___________120-12-7—————Anthracene_____' ". ; . -84-74-2—————Di-n-butylphthalate _____206-44-0—————Fluoranthene_______-129-00-0—————Pyrene____s______i_______85-68-7—————Butylbenzylphthalate^^___91-94-1—————3,3 r-Dichlorgbenzidine___56-55-3—————Benzo(a) anthracene______218-01-9—————Chrysene ——117-81-7—————bis(2-Ethylhexyl)phthalate_117-84-0—————Di-n-octylphthalate ____"205-99-2—————Benzo(b)fluoranthene_____207-08-9—————3en2o(k)fluoranthene_____50-32-8—————Benzo(a)pyrene_________193-39-5—————Indeno( 1,2,3-cd)pyrene___53-70-3—————Dibenz(a,h)anthracene ___191-24-2—————3enzo(g,h,i)perylene_____

50. IU10. IU50. IU50. |U10. (U10. |U10. |U10. |U10. IU50. IU50. (U10. IU10. IU10. |U50. ]U10. |U10. IU10. JU10. IU10. |U10. |U20. |U10. IU10. 1U10. IU10. IU10. IU10. IU10. |U10. |U10. |U10. (U

(1) - Cannot be separated from diphenylaminei '•' •FORM I SV-2 1/87 Re

ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET _____

| " CCHOOLab Name: IEA Contract: 68-WS-0045 |______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No,: CCHOO


Sample wt/vol: 1000. (g/mL)ML * Lab File ID: DB5A4557


% Moisture: not dec. 100. dec. 0. Date Extracted: 8/21/89

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 9/ 1/89



O

319-84-6 ———— alpha-BHC319-85-7 ———— beta-BHC"51 Q_fi£*_3... _-.^c»T 4* =1 — Qtir*

58-89-9 ———— gamma-BHC76-44-8 ——— Heptachlor309-00-2 ———— Aldrin1024-57-3 ——— Heptachlor epoxide959-98-8 ———— Endosulfan I60-57-1 ——— Dieldrin72-55-9 ———— 4 4 ' -DDEf £• W ^ -3, f .U'J.U

72-20-8 ———— Endrin33213-65-9 ———— Endosulfan II

72-54-8 ———— 4 4 ' -DDDf & w / ~ Z W ~l f ±*U U

1031-07-8 ——— Endosulfan sulfate

72-43-5 ——— Methoxychlor53494-70-5 ——— Endrin ketone5103-71-9 ——— alpha-Chlordane5103-74-2 ——— gamma-Chlordane8001-35-2 ———— Toxaphene12674-11-2 ——— Aroclor-101611104-28-2 ——— Aroclor-122111141-16-5 ——— Aroclor-123253469-21-9 ——— -Aroclor-124212672-29-6 ——— Aroclor-124811097-69-1 ——— Aroclor-125411096-82-5 ———— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050.10.10.10.10.10.10.10.50.10.50.501.0.50.50.50.50.501.01.0

1IUiuIUiu|U iiu 1iu 1iuIUiuIUiuIUiuIUiuIUiuIUiuiuIUiuiuiuiuiuI

FORM I PEST ftR3Q2935 1/87 Rev

: 1A - ^ EPA SAMPLE NO,VOLATILE ORGANICS ANALYSIS DATA SHEET . .. . .

I CCH01Lab Name: IEA _ .Contract: 68-W8-0045 |______

Lab Code: IEA Case No.: 12544. SAS No,, t. SDG No.: CCHOO

Matrix: (soil/water) WATER ; Lab Sample ID:

Sample wt/vol: 5. (g/mL) ML Lab rFile ID: 0822307


% Moisture: not dec.100. \ .. :. Date Analyzed: 8/22/89

Column: (pack/cap) CAP ! ! Dilution Factor: 1.00

'-.- CONCENTRATION UNITS;CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

1| 74-87-3-i *?.£ — a ** — Q_j / 4 — 00 — ;? —| 75-01-4-| 75-00-3-| 75-09-2-

67-64-1-75-15-0-

; 75-35-4-ITT e ""i jf *s75-34-3-I 540-59-0-

67-66-3-107-06-2-7Q_QT_'l_/ O J J — J —

71-55-6-56-23-5-108-05-4-75-27-4-"7Q_Q*T_C_./o— o /— D—

10061-01-5-"7Q m _£C_/ y-Ul — O —124-48-1-J» £• T U ^

79-00-5-71-43-2-

10061-02-6-75-25-2-108-10-1-COT —"70— £ .

127-18-4-79-34-5-.i -• j

i na-sa— "3-.1 flQ — QH— 7— -

100-41-4-100-42-5-1330-20-7-

———— Chlpromethane ; - .———— Bromomethane———— vinyl Chloride———— Chloroe thane———— Methylene Chloride———— Acetone———— Carbon Disulf ide

^ f ±, ^ . S A U ^ " *—— '••*i4—— *A"»—

———— 1 , 1-Dichloroethane———— 1,2-Dichloroethene (total) _———— Chloroform———— 1 f 2-Dichloroethane———— 2-Butanone———— 1,1,1-Trichloroethane———— Carbon Tetrachloride

vinyi Aceuaue———— Brombdichloromethane———— 1,2-Dichloropropane———— cis-1 , 3 -Dichloroprqpene _^ _ (

^ •>* S«*A-i* V * "*«• '•**!«•**'••

———— Dibromochloromethane———— 1,1,2-Trichloroethane— — — — — uenzeiie———— trans-1 , 3 -Dichloropropene _———— Bromoform———— 4-Methyl-2-Pentanone

———— Toluene———— Chlofobenzene

———— Styrene- ——— Xvlene (total)

' !

10.10.10.10.5.10.5.5.5.5.5.5.10.5.5.10.5.5.5.5.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUiuIUIUIUIUIUIUIU1

FORM I VGA fl R 3 0 2 9 3 6

IB EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ' ______

II CCH01

Lab Name: IEA Contract: 68-W8-0045 1






Extraction: (SepF/Cont/Sonc) CCNT Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/NJ N pH: 6.0 Dilution Factor: : 1.00


J

108-95-2—————Phenol_______________111-44-4—————bis (2-Chloroethyl) ether95-57-8—————2-Chlorophenol_______541-73-1—————1,3-Dichlorobenzene __

46-7—————1,4-Dichlorobenzene ______100-51-6 ——— —Benzyl alcohol___________95-50-1—————1,2-Dichlorobenzene ______95-48-7—————2-Methylphenol___________108-60-1—————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine67-72-1————QQ — Q ?_•)_ __ -.__yo—yO JS-59-1—————Isophorone

•2-Nitrophenol-67-9—————2,4-Dimethylphenol_

65-85-0—————Benzoic acid111-91-1—————bis (2-Chloroethoxy) methane_120-83-2—————2,4-Dichlorophenol_______120-82-1—————1,2,4-Trichlorobenzene_____91-20-3—————Naphthalene '___________106-47-8—————4-Chloroaniline

•Hexachlorobutadiene59-50-7—————4-Chloro-3-methylphenol

•2-Methylnaphthalene77-47-4—————Hexachlorocyclopentadiene88-06-2—————2,4,6-Trichlorophenol __95-95-4—————2,4,5-Trichlorophenol __

•2-Chloronaphthalene88-74-4—————2-Nitroaniline____131-11-3—————Dimethylphthalate _208-96-8—————Acenaphthylene____606-20-2—————2,6-Dinitrotoluene

10. |U10. |U10. |U10. |U10. IU10. IU10. IU10. |U10. |U10. IU10. IU10. |U10. |U10. |U10. |U10. (U50. |U10. IU10. IU10. |U10. |U10. |U10. |U10. |U10. (U10. IU10. IU50. |U10. IU50. |U10. |U10. 'IU10. IU

FORM I SV-1 ^ rt ™ ~ -T i/87 R£SR302937

"" " "1C " " . . . -^_ ....... • EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET . ___________ -_

' -^ • | CCH01

Lab Name: IEA ,' t Contract: 68-W8-0045 |


Matrix: (soil/water) WATER _ , Lab Sample ID:


Level: (low/med) LOW * Date Received: 8/16/89


Extraction: (SepF/Cont/Sonc) CCNT ___ Date Analyzed: 9/ 1/89[ '• , -- - " .t: -:._?T" pi ~~ ." -

GPC Cleanup: (Y/N) N pH: 6.0 " Dilution Factor: 1.00

:C"6NCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

99-09-2 ——8*5 — T3 -Q__-c 1 i Q cDl-2o-3 —— -•100-02-7 ——132 64-9- — -.!» J A* W i-"

121 14-2- — •^ Af - j» *•84-66-2 —— •W W v A*

7005-72-3 —— -O d "7T "7oo— / J — / — — — •100-01-6 —— -534-52-1 —— •86-30-6 —— •101-55-3 —— •118-74-1 —— -D*7 QC_C_ _.__.o / — ob— O— — — •85-01-8 —— -

1 A 1 1 "7120-12-7----84-74 2 — --U X 1 ^>

206-44-0 —— -129-00-0 —— •O C CO "7O3-OO-7-- —QI -QA-1 ....

56-55-3 —— •*5i fl-.ni — Q— — --1 1 "7 O1 "T11 /-81-7 — —

on^— QQ O-__.207-08-9 —— -^n-77-fl __ -

1 Q7_'IQ_ «;_ — — .C *5 "7 f\ OD 3" /0-3----

TOT ^ Jl ^191-24-2 —— -

—— 3-Nitroaniline—— Acenaphthene—— 2 , 4-Dinitrophenol—— 4-Nitrophenol—— Dibenzofuran—— 2 , 4-Dinitrotoluene—— Diethylphthalate—— 4-Chlorophenyl-phenylether _—— Fluorene :—— 4-Nitroaniline—— 4 , 6-Dinitro-2-methylphenol _—— N-Nitrosodiphenylamine ( 1 )"__—— 4-Bromophenyl-phenylether ~_ _

—— Pentachlorophenol

—— Anthracene ...—— Di-n-butylphthalate—— Fluoranthene—— Pyrene- —— Butylbenzylphthalate—— 3 , 3 r:-Dichlorobenzidine—— Benzo ( a ) anthracene

Vr** * J »JWiA*—

. —— bis(2-Ethylhexyl)phthalate _- —— Di-n-octylphthalate ~- —— Benzo ( b ) f luoranthene. —— Benzo ( k) f luoranthene

. —— Indeno (1,2 , 3-cd)pyrene

• —— Benzo ( a , h , i ) perylene

50.10.50.50.10.10.10.10.10.50.50.10.10.10.50.10.10.10.10.10.10.20.10.10.10.10.10.10.10.10.10.10.

1IUiuIUIUIUIUIUIUIUIU!UIUIUIUIUIUIUIUIUIUiuIUIUIUIUIU .IUIUIUIUIUIUI

(1) - Cannot be separated from diphenylamine

' : FORM I SV-2 " 1/87 Re

I " ^ 1M302938

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

I CCH01Lab Name: IEA . Contract: 63-W3-Q045 j______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO '


Sample wt/vol: 1000, (g/mL)ML * Lab File ID: DB5A4555

Level: (low/med) LOW . Date Received: 8/16/89





319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9———gamma-BHC76-44-8————Heptachlor309-00-2————Aldrin1024-57-3———Heptachlor epoxide959-98-8————Endosulfan I60-57-1———Dieldrin72-55-9————4,4! -DDE72-20-8———Endrin

33213-65-9———Endosulfan II72-54-8————4 ,4 ' -DDD

1031-07-8———Sndosulfan sulfate50-29-3————4, 4 ' -DDT72-43-5———Methoxychlor

53494-70-5————Endrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2———Aroclor-122111141-16-5———Aroclor-123253469-21-9———Aroclor-124212672-29-6————Aroclor-124811097-69-1———Aroclor-125411096-82-5————Aroclor-1260

I.050 |U.050 |U.050 |U.050 IU.050 IU.050 IU.050 [U.050 (U.10 IU.10 IU,10 |U.10 IU.10 |U.10 IU.10 IU,50 IU.10 |U.50 |U.50 |U1.0 |U.50 |U.50 [U,50 [U,50 [U,50 [U1.0 [U1.0 IU

FORM I PEST 1/87 RevAR302939

r1A EPA SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEET ____________; I

I CCH02Lab Name: IEA m Contract: 68-W8-0045 (___________



O Sample wt/vol: 5. (g/rnL) ML Lab File ID: 0822308

Level": (low/med) LOW Date Received: 8/18/89

% Moisture: not dec.100. -: ;. Date Analyzed: 8/22/89

O Column: (pack/cap) CAP '. . . r . Dilution Factor: 1.00

' ' :: '••-- CONCENTRATION UNITS:CAS NO. COMPOUND , (ug/L or ug/Kg) UG/L Q

C|

3

74-87-3—————Chloromethane _____._____| 10. |U74-83-9—————Bromomethane :______| 10. JU75-01-4—————Vinyl Chloride,75-00-3—————Chloroethanei-09-2—————Methylene Chloride_

67-64-1- , ________75-15-0—————Carbon Disulfide_75-35-4—————1,1-Dichloroethene75-34-3—————1,1-Dichloroethane^_______540-59-0—————1,2-Dichloroethene (total)_67-66-3—————Chloroform_________107-06-2—————1,2-Dichloroe thane__78-93-3—————2-Butanone. .___. ...,,..„ .71-55-6—————1,1,1-Trichloroethane56-23-5—————Carbon Tetrachloride__108-05-4—————Vinyl Acetate _____75-27-4—————Bromodichlorqrnethane

•1,2-Dichloropropane10061-01-5—————cis-1,3-Dichloropropene

79-01-6—————Trichloroethene124-48-1—————Dibromochlorome thane_79-00-5—————l,lf 2-Trichloroethane71-43-2————

10061-02-6—————trans-1,3-Dichloropropene __75-25-2—————Bromoform108-10-1—————4-Methyl-2-Pentanone_591-78-6—————2-Hexanone________"127-18-4—————Tetrachloroethene .....79-34-5—————1,1,2,2-Tetrachloroethane _

88-3—————Toluene __-• :108-90-7—————Chlorobensene100-41-4——:——Ethylbenzene_\100-42-5—————Styrene _____1330-20-7—————Xylene (total)

10. IU10. |U5. [U10. |U5. |U5. IU5. |U5. IU5. [U5. |U10. |U5. |U5. |U

10. IU5. |U5. [U5. [U5. IU5. IU5. [U5. |U5. |U5. |U10. |U10. [U5. [U5. [U5. IU5. IU5. |U5. [U5. |U

FORM I VOA flR3029^0 ' 1/87 Rev

rIB EPA SAMPLE NO

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET '________

1 CCH02Lab Name: IEA Contract: 68-W8-0045 |_______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No,: CCHOO


Sample wt/vol: 1000. (g/mL) ML Lab File ID: 0828409O Level: (low/med) LOW Date Received: 8/18/89

% Moisture: not dec.100. dec. 0. . Date Extracted: 8/18/89

Extraction: (SepF/Cont/Sonc) CONT Date Analyzed: 8/28/89O



108-95-2—————Phenol______________111-44-4—————bis (2-Chloroethyl) ether95-57-8—————2-Chlorophenol_______541-73-1—————1,3-106-46-7—————1,4-100-51-6—————Benzyl alcohol

i-50-1—————1,2-Dichlorobenzene ______95-48-7—————2-Methylphenol____________108-60-1—————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane

•Nitrobenzene73-59-1—————Isophorone______________88-75-5—————2-Nitrophenol ___________105-67-9—————2,4-Dimethylphenol________65-85-0———-——Bensoic acid_____________111-91-1—————bis (2-Chloroethoxy)me thane_120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-91-20-3—————Naphthalene __106-47-8 ————— 4-Chloroaniline

•Hexachlorobutadiene59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _

•2,4,6-Trichlorophenol ____•2,4,5-Trichlorophenol ____

91-58-7—————2-Chloronaphthalene88-74-4 ————— 2-Nitroaniline____131-11-3————Dimethylphthalate _208-96-8—————Acenaphthylene____606-20-2—————2,6-Dinitrotoluene_

10. |U10. IU10. [U10. [U10. IU10. IU10. IU10. |U10. |U10. |U10. |U10. |U10. |U10. IU10. IU10. IU50. |U10. IU10. |U10. |U10. |U10. |U10. |U10. |U10. IU10. IU10. IU50. IU10. |U50. ]U10. |U10. '|U10. IU

FORM I SV-1 a n o r» rt f , 1/87 -Ri

: 1C . . . . . _ ' EPA SAMPLE NCSEMIVOIATILS ORGANXCS ANALYSIS DATA SHEET

.... I CCH02

Lab Name: IEA Contract: 68-WS-Q045 |

Lab Code: IEA Case No.: 12544 SAS No.: . - SDG No.: CCHOO

Matrix: (soil/water) WATER " Lab iSample ID:

Sample wt/vol: 1000. - (g/mL) ML - Lab File ID: 0828409

Level: (low/med) LOW "ii' Date Received: 8/18/89


Extraction: (SepF/Cont/Sonc) CONT • '...Date Analyzed: 8/28/89

GPC Cleanup: (Y/N) N pH: 6.0 ^Dilution Factor: 1.00


99-09-2—————3-Nitroaniline_____[_____83-32-9—————Acenaphthene____ :_____51-28-5 ————— 2,4-Dini'trophenol _______100-02-7 ————— 4-Nitrophenol ___________132-64-9—————Dibenzofuran_____ . ____121-14-2—————2,4-Dinitrotoluene________84-66-2—————Diethylphthalate_________

7005-72-3 ————— 4-Chlorqphenyl-phenylether _86-73-7—————Fluorene_______... ____"__100-01-6—————4-Nitroaniline___________534-52-1—————4,6-Dinitro-2-methylphenol_86-30-6—————N-Nitrosodiphenylamine (1)I_101-55-3 ————— 4-Bromophenyl-phenylether ~__118-74-1—————Hexachlorobenzene :____~__87-86-5—————Pentachlorophenol ..______85-01-8—————Phenanthrene - -----____120-12-7—————Anthracene_______________84-74-2—————Di-n-butylphthalate ______206-44-0—————Fluoranthene_____________129-00-0—————Pyrehe______ .. . . .______85-68-7—————Butylbenzylphthalate______91-94-1—————3 ,3 T -Dichlorobenzidine_____56-55-3—————Benzo (a) anthracene________218-01-9—————Chrysene_________._______117-81-7—————bis(2-Ethylhexyl)phthalate_117-84-0—————Di-n-octylphthalate ______205-99-2—————Benzo (b)f luoranthene______207-08-9—————Benzo (kjf luoranthene______50-32-8—————Benzo(a)pyrene___________193-39-5—————Indeno(l,2,3-cd)pyrene_____53-70-3—————Dibenz( a, h) anthracene191-24-2—————Benzo (g,h,i)perylene

50. IU I10. IU I50. [U I50, |U |10. IU I10. |U 110. |U |10. IU |10. |U I50. |U I50. |U I10. |U I10. |U |10. |U I50. ]U T10. IU I10. IU I10. IU I10. IU I10. |U I10. |U I20. IU I10. IU I10. IU I10. |U I10. |U 110. |U 110. [U I10. IU I10. IU I10. |U I10. .|U I

(1) - Cannot be seoarated from diphenylamine* i - , j - - - - -i FORM I SV-2 1/87 Re

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

| CCH02Lab Name: IEA Contract: 68-W8-0045 I



O Sample wt/vol: 1000. (g/mL)ML Lab File ID: DB5A4558



O Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 9/ 1/89



O

O

319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-76-44-8———Heptachlor309-00-2————Aldrin1024-57-3————Heptachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4'-DDE72-20-8———Endrin

33213-65-9————Endosulfan II72-54-8————4,4'-DDD

1031-07-8———Endosulfan sulfate:,4f-DDT

72-43-5———Methoxychlor53494-70-5—-—Endrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2———Aroclor-122111141-16-5———Aroclor-123253469-21-9————Aroclor-124212672-29-6———Aroclor-124811097-69-1———Aroclor-125411096-82-5———Aroclor-1260

.050 |U

.050 |U

.050 |U

.050 |U

.050 |U

.050 ]U

.050 IU

.050 |U.10 ]U.10 IU.10 IU.10 IU.10 |U.10 IU.10 |U.50 |U.10 |U.50 |U.50 |U1.0 |U.50 |U.50 |U.50 |U.50 |U.50 IU1.0 IU1.0 IU

FOKM I PEST 1/87flR3029U3

1A EPA SAMPLE NO.VOLATILE ORSANICS ANALYSIS DATA SHEET m___________

; |

I CCH03Lab Name: IEA . . .. Contract: 68-W8-OQ45 j___________

Lab Code: IEA Case No.: 12544 SAS Np.: SDG No.: CCHOO


Sample wt/vol: 5.' (g/mL) ML_ Lab File ID: 0822309


% Moisture: not dec.100. ', "'„ .', . , :,i .Date Analyzed: 8/22/89

Column: (pack/cap) CAP __ j : DilutionTFactor: 1.00

..-CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

74-87-3 ————— Chlorornethane74-83-9 ————— Bromomethane . _75-01-4 ————— Vinyl Chloride - - - -75-00-3 ————— Chloroethane75_Q9_2- — ------Methylene Chloride67-64-1 ————— Acetone :. -75-15-0 ————— Carbon Disulfide.75-35-4 ————— 1,1-Dichloroethene75-34-3 ————— 1,1-Dichloroethane540-59-0 ————— 1,2-Dichloroethene (total)67-66-3 ————— Chloroform107-06-2 ————— 1 , 2-Dichloroethane

71-55-6 ————— 1,1,1-Trichloroethane56-23-5 ————— Carbon Tetrachloride108-05-4 ————— Vinyl Acetate75-27-4 ————— Bromodichloromethane78-87-5 ————— 1,2-Dichloropropane

10061-01-5 ————— cis-1, 3-Dichloropropene ___

124-48-1 ————— Dibromqqhlqrome thane79-00-5 ————— 1,1,2-Trichloroe thane71-43-2 ————— Benzene

10061-02-6 ————— trans-1, 3-Dichloropropene _T t "1C *1 ~» - - - — _g — - - —75-25-2 — • ——— Bromororm108-10-1 ————— 4-Methyl-2-Pentanone591-78-6 ————— 2-Hexanone

108-90-7 ————— Chlorcbenzene100-41-4 ————— Ethylbenzene,4. W W 1 4_ _^ _^W.T-«B S_>AA^^

1330-20-7 ————— Xylene (total)

10.10.10.10.5.19.5.5.5.5.5.5.

170.5.5.10.5.5.5.5.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

1IUIUIUIUinIBiuiu

. iuiuiu[U1iuiuITTITJiuiuiu!U|U|UiuiuiuiuiuIUiuIUIUiuIU1

VOA

IB EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET •_________

I CCH03Lab Name: IEA • Contract: 68-W8-0045 ______






Extraction: (SepF/Cont/Sonc) CONT Date Analyzed: 8/28/89



-Phenol111-44-4—————bis (2-Chloroethyl) ether95-57-8—————2-Chlorophenol_______541-73-1—————1,3-Dichlorobenzene __106-46-7—————1,4-100-51-6—————Benzyl alcohol____95-50-1—————1,2-Dichlorobenzenej-48-7—————2-Methylphenol

108-60-1————bis (2"Chloroisopropyl) ether106-44-5 ————— 4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane

-Nitrobenzenet-59-1—————Isophorone

88-75-5—————2-Nitrophenol ___105-67-9—————2,4-Dimethylphenol_65-85-0—————Benzoic acid111-91-1—————bis (2-Chloroethoxy) methane_120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene____91-20-3—————Naphthalene

•4-Chloroaniline87-68-3—————Hexachlorobutadiene59-50-7—————4-Chloro-3-methylphenol91-57-6—————2-Methylnaphthalene __77.47-4—————Hexachlorocyclopentadiei88-06-2—————2,4,6-Trichlorophenol __95-95-4—————2,4,5-Trichlorophenol __91-58-7—————2-Chloronaphthalene __88-74-4—————2-Nitroaniline_______131-11-3—————Dimethylphthalate ____

606-20-2—————2,6-Dinitrotoluene

72. |10. |U10. IU10. IU10. IU10. |U10. |U10. |U10. ]U10. |U10. |U10. IU10. |U10. IU10. IU10. |U50. IU10. IU10. |U10. IU10. |U10. |U10. |U10. IU10. IU10. IU10. IU50. |U10. IU50. |U10. |U10. IU10. |U •

SR30291t5 l'j

.: 1C ... ' EPA SAMPLE NCSEMIVOLATILE ORGANICS ANALYSIS DATA.SHEET ____________

.- , - ., - • . - " : • | CCH03Lab Name: IEA Contract: 68-W8-0045 |

Lab Code: IEA . Case No.: 12544 SAS No.: SDG No.: CCHOO


Sample wt/vol: 1000. (g/mL) ML '.__ Lab File ID: 0828410

Level: (low/med) LOW - "Date Received: 8/18/89



GPC Cleanup: (Y/N) N , pH: 6.0 Dilution Factor: 1.00

' " - - CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or -ug/Kg) UG/L Q

i : : i——————i——i1 99-09-2 ————— 3-Nitroaniline .:. . ... I 50. |U I

S3-3 2-9—————Acenaohthene __________| 10. JU I51-28-5—————2,4-Dinitrophenol ___,____| 50. |U I100-02-7 ————— 4-Nitrophenol ___________I 50. |U |132-64-9—————Dibenzofuran_______;______\ 10. |U I

_ 121-14-2—————2,4-DinitrQto_luene____ .__.. I 10. 1U |" "84-66-2—————Diethylphthalate_________I 10. |U I7005-72-3 ————— 4-Chlorophenyl-phenylether_| 10. JU |86-73-7—————Flubrene . ... ' I 10. IU I100-01-6—————4-Nitroaniline___________| 50. [U 1534-52-1 ————— 4,6-Dinitro-2-methylphenol_| 50. IU I86-30-6—————N-Nitrosodiphenylamine (1)"_| 10. IU I101-55-3—————4-Bromophenyl-phenylether "_1 10. |U j118-74-1—————Hexachlorobenzene I 10. |U |87-86-5—————Pentachlorophenol .____| 50. |U I85-01-8—————Phenanthrene_______ I 10. | U |120-12-7—————Anthracene______________| 10. |U |84-74-2—————Di-n-butylphthalate ______| 10. IU j206-44-0—————Fluoranthene]_____________| 10. JU |129-00-0—————Pyrene_________________| 10. JU I85-68-7—————Butylbenzylphthalate______| 10. |U I91-94-1—————3 ,3 ' -Dichlorobenzidine____| 20. |U I56-55-3—————Benzo (a) anthracene________j 10. |U j218-01-9—————Chrysene__________:_____| 10. [U I117-81-7—————bis(2-Ethylhexyl)phthalate _J 10. |U I117-84-0—————Di-n-octylphthalate | 10. |U |205-99-2—————Benzo (b)f luoranthene______I 10. |U 1207-08-9—————Benzo(k)f luoranthene______| 10. |U |50-32-8—————Benzo (a)pyrene___________j 10. JU [193-39-5—————Indeno(l,2,3-cd)pyrene____| 10. |U |53-70-3—————Dibenz(a,h)anthracene _____j 10. |U j191-24-2—————Benzo (g,h,i)perylene_____ | 10. JU j


FORM I SV-2 1/87 Re

: ^ ^ "^ flR3029U6 '

rID EPA SAMPLE NO.

PESTICIDE ORGANICS ANALYSIS DATA SHEET ____

| - CCH03Lab Name: IEA Contract: 68-W3-0045 |______


Matrix: (sail/water) WATER Lab Sample ID:

Sample wt/vol: 1000. (g/mL)ML • Lab File ID: DB5A4560






O

O

319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC76-44-8———Heptachlor309-00-2————Aldrin1024-57-3———Heptachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4'-DDE72-20-8———Endrin

33213-65-9————Endosulfan II72-54-8————4,41-DDD

1031-07-8———Endosulfan sulfate50-29-3————4,4f -DDT72-43-5———Methoxychlor

53494-70-5———Endrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2————Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5———Aroclor-123253469-21-9———Aroclor-124212672-29-6———Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

.050 |U

.050 |U

.050 |U

.050 )U

.050 IU

.050 ]U

.050 IU

.050 IU.10 |U.10 IU.10 IU.10 |U.10 |U.10 |U.10 |U.50 IU.10 |U.50 |U.50 )U1.0 |U.50 IU.50 IU.50 |U.50 |U.50 |U1.0 |U1.0 |U

FORM i PEST flR3029U7 1>f87 Rev

r. .:... • . - - i - - •. -1A EPA SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEET ______________I

• - - — - - - - * • ' | CCH04Lab Name: IEA Contract: 6S-W8-OQ45 I



Sample wt/vol: 5. (g/mL) ML \ Lab File ID: 0822313


% Moisture: not dec.100. ; _^Date Analyzed: 8/22/89

Column: (pack/cap) CAP \ . Dilution Factor: 1.00

! ~ ", ' ... CONCENTRATION UNITS:CAS NO. COMPOUND , (ug/L or ug/Kg) UG/L Q

74-87-3 ——74-83-9 ——75-01-4 ——75-00-3 ——75-09-2 ——67-64-1 ——75-15-0 ——75-35-4- —1 W —4 _/ j»

~7 e "5 A n75-34-3 ——540-59-0 ——£ 7 — A £ _ "5 _ — _

107-06-2 ——78-93-3 —— -71-55-6 ——C f ™l "5 !?56-23-5 —— •108-05-4 —— •"T C ^ A75-27-4- — •7fl — Q7 — R — — _.

10061-01-5 —— -79-01-6 —— -124-48-1 —— -79-00-5 —— -71-43-2 ———

10061-02-6 —— -7K_^ C — T —/ 3™ -i3*"Z— — — -108-10-1 —— -5Q1 — 7fl — £-.— . -1 ?7 — 1 Q — A — — — .79-34-5 ———1 — ' V * "• «J

1 OS-Sfl — "5— — — -1 053 — 00 — 7 — — — -100-41-4 —— r100-42-5 ———1330-20-7 ———

—— Chloromethane—— Bromomethane—— Vinyl Chloride—— Chloroethane

fc*W 1— >i*_J __%__'! A S_ «a* t A. V_V<V ____ . _ .. __

——— Acetone—— Carbon Disulfide—— 1 , 1-Dichloroethene—— 1 , 1-Dichloroethane—— 1,2-pichloraethene . (total) _—— Chloroform—— 1 , 2-Dichloroethane—— 2-Butanone—— 1,1,1-Trichloroethane—— Carbon Tetrachloride

r 11 J. JAW— > W*i WC

—— Bromodichlororne thane—— 1 , 2-Dichloropropane—— cis-1, 3 -Dichloropropeiie ___—— Trichloroethene—— Dibromochloromethane—— 1 , 1 , 2-Trichloroethane

—— trans-l/3-Dichloropropene _. —— Bromofonn

*_w «>*A_2 _• _• *—*— -i-k***rf**1—>

- —— 2-Hexanone_> <u • «— . i— fc«irf»_rf. ^ A. *rf ••_ <B*_<H>4<A^v

• —— 1,1,2,2-Tetrachloroethahe _

s*iiJ,W_. WA-"i.ll<.*CiliV—

•— — — Ft~Hvl fo 'n 7*e*ne*ij*— iijr ^ w«x*4 iAw.-. — -. c v VT n Afcj> W^ — • WllW

—— Xylene (total)i

10.10.10.10.5.10.5.5.5.5.5.5.10.5.5.10.5.5.5.5.5.5.5.5.S.10.10.5.5.5.5.5.5.5.

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU -IUIUIUIUiuIU

• iuIUiuIUIU .IU1

flfi30291(8 i/87 K«M31

r

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

I CCH05Lab Name: IEA Contract: 68-W8-0045





%.Moisture: not dec.100. Date Analyzed: 8/31/89

Column: (pack/cap) CAP Dilution Factor: 1.00


C

O

iI 74-87-3 ——

1 75-01-4 ——| 1 — * v> _> X

1 75-00-3 ——

| 75-15-0 —— •1~r i™ « i r* * 475-35-4 —— •1*7 C — 1 jl • 175-34-3 —— •I 540-59-0 —— •| 67-66-3 —— -| 107-06-2 —— •

I 71-55-6 —— -I 56-23-5 —— -I 108-05-4 —— •IT C. *• t *T A75-27-4 —— •1 7Q..Q7 — c: _ .,.

[10061*01-5 —— •

I 124-48-1 —— -

I 71-43-2 —— •i * _• A •—« _•110061-02-6 —— -i 7 c; _•?=;.. •?— — *..| 108-10-1 —— -

1 127-18-4 —— -| UV — • V «W W "X

| 79-34-5 —— -

i 108-90-7 —— •

i 1QQ-42-5 ———| U* U U "1 _» ~JIt — t *^ rt O rt ~T1330-20-7 ———

—— Chloromethane—— Bromomethane—— Vinvl Chloride——— Chloroethane—— Methvlene Chloride

—— Carbon Disulfide—— 1 , 1-Dichloroethene—— 1 f 1-Dichloroethane—— 1 f 2-Dichloroethene ( total ) _—— Chloroform—— 1,2-Dichloroethane—— 2-Butanone

—— Carbon TetrachlorideV J«t_j[ Jv «-% rt v *•<•_. '—.'w.

—— Bromodichloromethane—— 1 , 2-Dichloropropane—— cis-1, 3-Dichloropropene ___- —— Trichloroethene—— Dibromochloromethane—— 1 , 1 f 2-Trichloroethane

—— trans-1, 3-Dichloropropene _——— Bromof orm—— 4-Methyl-2-Pentanone——— 2 -Hexano ne

—— 1,1,2,2-Tetrachloroethane _

- —— Chlorobenzene

b> v*^ — > <- ** -*• —— Xvlene "(total)

10.10.10.10.5.10.5.5.34.5.5.5.10.29.5.10.5.5.5.3.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

1

IUiuIUIU[Uiu|U1IUiuIUiuIiuiuiuIUIU1 JIUIU -iuIUiuiuiuiuiu!Uiuiuiu |IU |1

FORM i VOA AR3G29^9 -/"

rIB EPA SAMPLE NO

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET '________m

I ' - - - - | CCH05Lab Name: IEA ' t ~ . Contract: 63-W8-0045 I____________





% Moisture: not dec.100. dec. 0. : Date. Extracted: 8/25/89

Extraction: (SepF/Cont/Sonc) CONT . . Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N | pH: 6.0 _ ' ; Dilution Factor: 1.00

i . : • CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol ____________111-44-4—————bis(2-Chloroethyl)ether95-57-8 ————— 2-Chlorophenol_____.541-73-1—————1,3-Dichlorobenzene106-46-7—————1,4-Dichlorobenzene

Cjfc 1 100-51-6—————Benzyl alcohol95-50-1—————1,2-Dichlorobenzene _____95-48-7—————2-Methylphenol_____108-60-1—————bis (2-Chloroisopropyl) ether"106-44-5—————4-Methylphenol_________621-64-7—————N-Nitroso-di-n-propylamine^"67-72-1—————Hexachloroethane _____"_98-95-3—————Nitrobenzene _ ________"78-59-1—————Isophorone_______________88-75-5—————2-Nxtrophenol ___________105-67-9—————2,4-Dimethylphenol______"65-85-0—————Benzoic acid _____111-91-1—————bis (2-Chloroethoxy)methane120-83-2—————2,4-Dichlorophenol______"120-82-1—————I,2r4-Trichlorobenzene____"91-20-3—————Naphthalene '_______ "106-47-8 ————— 4-Chloroaniline - -87-68-3—————Hexachlorobutadiene . .59-50-7—————4-Chloro-3-methylphenol __"91-57-6—————2-Methylnaphthalene _____"77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4,6-Trichlorophenol ____~95-95-4—————2t 4,5-Trichlorophenol _____91-58-7—————2-Chloronaphthalene ______88-74-4 ————— 2-Nitroaniline______;____"131-11-3—————Dimethylphthalate _______)208-96-8—————Acenaphthylene______;_____606-20-2 ————— 2,6-Dinitrotoluene_______[

10. |U10. |U10. |U10. |U10. [U10. |U10. |U10. |U10. |U10. |U10. IU10. |U10. IU10. (U10. |U10. |U50. IU10. IU10. [U10. ]U10. IU10. |U10. |U10. |U10. |U10. |U10. [U50. (U10. |U50. |U10. |U10. |U10. |U

EPA SAMPLE NO

| CCH05Lab Name: IEA Contract: 68-W8-0045 I______




Level: (low/med) LOW ' Date Received: 8/25/89





99-09-2—————3-Nitroaniline___83-32-9—————Acenaphthene______51-28-5—————2,4-Dinitrophenol100-02-7—————4-Nitrophenol "132-64-9—————Dibenzofuran_____121-14-2—————2,4-Dinitrotoluene84-66-2—————Diethylphthalate-72-3—————4-Chlorophenyl-phenylether_

86-73-7—————Fluorene_______________100-01-6—————4-Nitroaniline__________534-52-1—————4,6-Dinitro-2-methylphenol_86-30-6—————N-Nitrosodiphenylamine (1)~101-55-3 ————— 4-Bromophenyl-phenylether _118-74-1—————Hexachlorobenzene

•Pentachlorophenol85-01-8——— ___________120-12-7—————Anthracene_____________84-74-2—————Di-n-butylphthalate _____206-44-0—————Fluoranthene____________129-00-0—————Pyrene________________85-68-7—————Butylbenzylphthalate_____91-94-1—————3,3' -Dichlorobenzidine56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene_______________117-81-7—————bis(2-Ethylhexyl)phthalate_117-84-0—————Di-n-octylphthalate

-Benzo (b) f luoranthene^207-08-9—————Benzo (k)f luoranthene"

32-s—————Benzo (a) pyrene______39-5—————Indeno (1,2,3-cd)pyrene_

53-70-3—————Dibenz(a,h)anthracene191-24-2—————Benzo (g ,h, i) perylene

50. [U10. |U50. IU50. |U10. |U10. IU10. |U10. |U10. IU50. [U50. |U10. IU10. |U10. [U50. IU10. IU10. |U10. |U10. |U10. IU10. IU20. ]U10. IU10. |U10. |U10. |U10. |U10. IU10. IU10. IU10. IU10. IU


FORM I SV-2 1/87 ReSR30295I

r

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________

- - •- - - 1 I| CCH05 I

Lab Name: IEA Contract: 68-W8-0045 I____________1

Lab Code: IEA Case No.: 12544 SAS No.: ' SDG No.: CCHOO

Matrix: (soil/water) WATER , Lab Sample ID:

> Sample wt/yol: 1000. (g/mL)ML • Lab File ID: DB5A4564

Level: (low/med) LCW . -T Date Received: 8/25/89

% Moisture: not dec.100. '., dec. 0. ^ Date Extracted: 8/29/89

r> Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N pH: 6.0 ..._._. Dilution Factor: 1.00


319-84-6 ——— alpha-BHC319-85-7 ——— beta-BHC31 Q — Q £_Q____..,-3i-» 1 +-a— tatir1

58-89-9 ——— gamma-BHC76-44-8 ———— Heptachlor

I 309-00-2 ———— AldrinI 1024-57-3 ——— Heptachlor epoxide

959-98-8 ——— Endosulfan I60-57-1 ——— Dieldrin

72-20-8 ——— Endrin33213-65-9 ———— Endosulfan II

72-54-8 ———— 4 4 ' -DDD1 — • «J * w f , "4 _^ l. ._

1031-07-8 ——— Endosulfan sulfate50-29-3- — — -4 4 ' -T)DT•— ' W *• — / — ' 1,1 i»/XS_.

72-43-5 ——— Methoxychlor53494-70-5 ——— Endrin ketone5103-71-9 ——— alpha-Chlordane5103-74-2 ——— gamma-Chlordane8001-35-2 ——— Toxaphene12674-11-2 ——— Aroclor-101611104-28-2 ——— r-Aroclor-122111141-16-5 ———— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ———— Aroclor-124811097-69-1 ——— Aroclor-125411096-82-5 ——— Aroclor-1260

.050

.050

.050

.050

.050

.050

.050

.050.10.10.10.10.10,10.10.50.10.50.501.0.50.50.50.50.501.01.0

iiuiuiuiuiuiuiuIUiuIUIUIUIUIUIUIUIUiuIUiuiuiuIUiuiuiuiu1

FORM I PEST ^R302952 . 1/87

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

i .I CCH06

Lab Name: IEA Contract: 63-W8-0045 j________





% Moisture: not dec.100. Date Analyzed: 8/31/89



74-87-3 ————— Chloromethane/ ** — o j **;? —— ———— n-7OuiOiiieuiia.iis75-01-4 ————— Vinyl Chloride75-00-3 ————— Chloroethane75-09-2 ————— Methylene Chloride

75-15-0 ————— Carbon Disulfide

75-34-3 ————— 1,1-Dichloroethane540-59-0 ————— 1,2-Dichloroethene (total) _67-66-3 ————— Chloroform107-06-2 ————— 1 , 2-Dichloroethane78-93-3 ————— 2-Butanone

108-05-4 ————— Vinyl Acetate75-27-4 ————— Bromodichlorome thane78-87-5 ————— 1 , 2-Dichloropropane

10061-01-5 ————— cis-1, 3-Dichloropropene79-01-6 ————— Trichloroethene124-48-1 ————— Dibromochloromethane79-00-5 ————— 1 , 1 , 2-Trichloroethane

10061-02-6 ————— trans-1, 3-Dichloropropene _75-25-2 ————— Bromoform .108-10-1 ————— 4-Methyl-2-Pentanone591-78-6 ————— 2-Hexanone127-18-4 ————— Tetrachloroethene79-34-5 ————— 1 ,1,2, 2-Tetrachloroethane _

108-90-7 ————— Chlorobenzene100-41-4 ————— Ethylbenzene

1330-20-7 ———— Xylene (total)

10.10.10.10.5.10.5.5.36.5.5.5.10.31.5.10.5.5.5.3.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

tIU!UIUIUIU IIU|U 1iu 11IUIUIUIU1IUIUIUIUIU1 Jiu|UiuIUIUIUIUiuiuIUiuIUiuIU.1

3R3G2953FORM I VOA 1/87 Rev

/ — • ' ' ' --.- _ . _ _ — — - " - : . - - - - . - - — - - - - -

IB : SPASEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

.

^ * • .:: _,*•''* r • . - | CCH06Lab Name: IEA -' ' Contract: 68-W8-0045 |

Lab Code: IEA Case No.: 12544 SAS No,: SDG No.: CCHOO



Level: (low/med) LOW ; Date Received: 8/25/89

% Moisture: not dec.100. dec. 0. T Date Extracted: 8/25/89

Extraction: (SepF/Cont/Sonc) CONT, ._ ... _.Date. Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N pH: 6.0 .,. 1 Dilution Factor: 1.00

; ^ -XON-ENTRATION UNITS:CAS.NO. COMPOUND (ug/L or ug/Kg) UG/L Q

111-44-4—————bis;(2-Chloroethyl) ether95-57-8 ————— 2-Chlorophenol_______541-73-1—————l,3|-Dichlorobenzene __106-46-7—————1,4-Dichlorobenzene __100-51-6—————Benzyl alcohol_______95-50-1—————1,2-Dichlorobenzene __

•2-Methylphenol108-60-1—————bis (2-Chloroisopropyl) ether106-44-5 ————— 4-Methyiphenol_________621-64-7—————N-Nitroso-di-n-propylaminea_67-72-1—————Hexachloroethane

108-95-2—————Phenol _" _ _ - _ - - - - \ 10, |U10. |U10. |U10. |U10. |U10. [U10. |U10. |U10. |U10. |U10. |U10. |U10. JU10. [U10. |U10. |U50. |U10. |U10. |U10. IU10. [U10. IU10. IU10. |U

78-59-1—————Isophorone______________88-75-5 ————— 2-Nitrophenol _________105-67-9—————2,4-Dimethylphenol________65—85—0———•"———Benzoic acid_____________111-91-1—————bis (2 -Chloroe thoxy) methane^

"-83-2 ————— 2,4-Dichlorophenol120-82-1—————1,2,4-Trichlorobenzene____91-20-3—————Naphthalene ____ . .106-47-8—————4-Chloroaniline ________"87-68-3—————Hexachlorqbutadiene _____59-50-7—————4-Chloro-3-methylphenol __"91-57-6—————2-Methylnaphthalene _____"77-47-4—————Hexachlorocyclopentadiene J88-06-2—————2,4,6-T.richlorophenol ___™95-95-4—————2,4,5-Trichlorophenol ___"91-58-7—————2-Chloronaphthalene .______"88-74-4—————2-Nitroaniline_____ -131-11-3—————Dimethylphthalate ______"

-96-8—————Acenaphthylene606-20-2—————2,6-Dinitrotoluene

10. |U10. |U10. |U50. |U10. |U50. IU-10. |U10. '|U10. IU

FORM I SV-1

1C EPA SAMPLE NOr SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ___

I CCH06Lab Name: IEA Contract: 68-W8-0045 j______

Lab Code: IEA Case No-: 12544 SAS No.: SDG No.: CCHOO



Level: (low/med) LOW 4 Date Received: 8/25/89





99-09-2 ————— 3-Nitroaniline __________83-32-9 ————— Acenaphthene ___________51-28-5 ————— 2, 4-Dinitrophenol ______100-02-7 ————— 4-Nitrophenol- __________132-64-9 ————— Dibenzofuran ____121-14-2 ————— 2 , 4-Dinitrotoluene ______84-66-2 ————— Diethylphthalate ________

7005-72-3 ————— 4-Chlorophenyl-phenylether_86-73-7 ————— Fluorene ______________ "100-01-6 ————— 4-Nitroaniline __________534-52-1 ————— 4,6-Dinitro-2-methylphenol_86-30-6 ————— N-Nitrosodiphenylamine (1)~101-55-3 ————— 4-Bromophenyl-phenylether ~118-74-1 ————— Hexachlorobenzene ______ "87-86-5 ————— Pentachlorophenol ______85-01-8 ————— Phenanthrene ___________120-12-7 ————— Anthracene _____________84-74-2 ————— Di-n-butylphthalate _____206-44-0 ————— Fluoranthene ____129-00-0^- ———— Pyrene ________________85-68-7 ————— Butylbenzylphthalate _____91-94-1 ————— 3 , 3 ! -Dichlorobenzidine ___56-55-3 ————— Benzo (a) anthracene ______218-01-9 ————— Chrysene117-81-7 ————— bis(2-Ethylhexyl)phthalate.117-84-0 ————— Di-n-octylphthalate ____ ]205-99-2 ————— Benzo (b)f luoranthene _____207-08-9 ————— Benzo (k)f luoranthene _____50-32-8 ————— Benzo(a)pyrene _________193-39-5 ————— Indeno(l,2,3-cd)pyrene ___53-70-3 ————— Dibenz ( a ,h) anthracene ___191-24-2 ————— Benzo (g,h,i)perylene _____

(1) - Carihot'be separated from diphenylamine

50. |U10. |U50. |U50. IU10. |U10. |U10. |U10. |U10. |U50. |U50. |U10. |U10. IU10. IU50. |U10. |U10. |U10. |U10. |U10. IU10. |U20. IU10. IU10. IU10. IU10. |U10. |U10. IU10. |U10. |U10. |U10. |U

FORM I SV-2 1/87 ReflR302955

ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET

I CCH06Lab Name: IEA Contract: 68-W8-0045


Matrix: (soil/water) WATER ; Lab Sample ID:



% Moisture: not dec.100, dec. 0. Date Extracted: 8/29/89



; CONCENTRATION UNITS:CAS NO. COMPOUND _ (ug/L or ug/Kg) UG/L Q

319-84-6————alpha-BHC319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————ganuna-BHC76-44-8————Heptachlor309-00-2————Aldrin1024-57-3———Heptachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4'-DDE72-20-8———Endrin

33213-65-9———Endosulfan II72-54-8————4,4'-DDD

1031-07-8———Endosulfan sulfate50-29-3 ———— 4,4!-DDT72-43-5———Methoxychlor

53494-70-5———Endrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlqrdane8001-35-2———Toxaphene12674-11-2————Aroclor-101611104-28-2———Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6———Aroclor-124811097-69-1———Aroclor-125411096-82-5———Aroclor-1260

I.050 |U.050 |U.050 IU.050 (U.050 IU.050 |U.050 |U.050 IU.10 |U.10 ]U.10 IU.10 IU.10 IU.10 |U.10 IU• 50 IU.10 IU.50 |U.50 [U1.0 |U.50 |U.50 |U.50 |U.50 |U.50 |U1.0 |U1.0 |U

FORM I PEST ' 1/87 Rev

1A EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET

I CCH07Lab Name: IEA Contract: 63-W8-0045 I





% Moisture: not dec.100* Date Analyzed: 8/31/89



o

o

74-87-3—————Chloromethane74-83-9 —— —— -Bromome thane__75-01-4—————Vinyl Chloride75-00-3—————Chloroethane

•Methylene Chloride67-64-1—————Acetonei-15-0—————Carbon Disulfide

-1,1-Dichloroethene______•1,1-Dichloroethane______-1,2-Dichloroethene (total)

r-66-3—————Chloroform107-06-2—————1,2-Dichloroethane__78-93-3—————2-Butanone_________71-55-6—————1,1,1-Trichloroethane56-23-5—————Carbon Tetrachloride_108-05-4—————Vinyl Acetate _____75-27-4—————Bromodichloromethane_78-87-5—————1,2-Dichloropropane

10061-01-5—————cis-1,3-Dichloropropene79-01-6—————Trichloroethene ____124-48-1—————Dibromochloromethane_79-00-5—————1,1,2-Trichloroethane71-43-2————

10061-02-6—————trans-1,3-Dichloropropene75-25-2—————Bromoform108-10-1—————4-Methyl-2-Pentanone,

78-6—————2-Hexanone-18-4—————Tetrachloroethene

79-34-5—————1 f 1,2,2-Tetrachloroethane•Toluene

108-90-7—————Chlorobenzene100-41-4——-——Ethylbenzene100-42-5—————Styrene _____1330-20-7—————Xylene (total).

10. IU10. |U10. |U10. IU5. IU

170. IB5. |U5. [U5. |U48. |5. |U12. |10. |U12. |5. |U10. |U5. |U5. |U5. |U53. |5. |U5. |U5. |U5. |U5. IU

11. I10. |U4. | J5. [U5. |U5. |U5. |U5. |U5. IU

an o n o Q c "7_™. _ ._. HO Uel 3 3 / 1/87 Rev

r

IB , EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____ ___

1 * = - • - " * • : ' • • • . I CCH07Lab Name: IEA Contract: 68-W8-0045 |______

Lab Code: IEA Case No.: 12544 SAS No.: . SDG No.: CCHOO

Matrix: (soil/water) WATER __ . Lab Sample ID:

Sample wt/vol: 1000. ' (g/mL) ML Lab File ID: 0911407



Extraction: (SepF/Cont/Sonc) SEPF ^ Date Analyzed: 9/11/89



108-95-2—————Phenol______111-44-4————-bis(2-Chloroethyl)ether __95-57-8 ————— 2-Chlorophenol__________541-73-1—————1,3 -Dichlorobenzene .106-46-7—————1,4-Dichlorobenzene _____"100-51-6—————Benzyl alcohol__________95-50-1—————1,2-Dichlorobenzene _____"95-48-7—————2-Methylphenol .. .____"108-60-1—————bis (2-Chloroisopropyl) ether"106-44-5 ————— 4-Methylphenol .. /' "621-64-7—————N-Nitroso-di-n-propylamine_"67-72-1—————Hexachloroethane ___~98-95-3—————Nitrobenzene____.._._. ._____78-59-1—————Isophorone_____________"88-75-5—————2-Nitrophenol ____________105-67-9—————2,4-Dimethylphenol _____65-85-0—————Benzoic acid ____"111-91-1—————bis(2-Chloroethoxy)methane_"120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene____91-20-3—————Naphthalene _____________"106-47-8—————4-Chloroaniline _________"87-68-3—————Hexaqhlorobutadiene __,____59-50-7—————4-Chioro-3-methylphenol __"91-57-6—————2-Methylnaphthalene _______"77-47-4—————Hexachlorocyclopentadiene_88-06-2—————2,4,6-Trichlorophenol ___"95-95-4—————2,4,5-Trichlorophenol [____~m91-58-7—————2-Chloranaphthalene ______88-74-4—————2-Nitroaniline__________]131-11-3—————Dimethylphthalate _______]208-96-8—————Acenaphthylene___________606-20-2—————2,6-Dinitrotoluene________

10. IU10. (U10. |U10. IU10. |U10. |U10. |U10. [U10. |U10. |U10. IU10. (U10. |U10. |U10. |U10. IU50. |U10. |U10. IU10. |U10. IU10. ]U10. IU10. |U10. |U10. |U10. |U50. |U10. IU50. (U10. .|U10. IU10. |U

FORM i sv-i4R302958 1/87

1C EPA SAMPLE NCSEMI VOLATILE ORGANICS ANALYSIS DATA SHEET ____________

| CCH07Lab Name: IEA Contract: 68-W8-0045 [_____

Lab Code: IEA Case No,: 12544 SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER . _. Lab 'Sample ID:


Level: (low/med) LOW • Date Received: 8/26/89


Extraction: (SepF/Cont/Sonc) *SEPF Date Analyzed: 9/11/89



J

ft? ?7 QSI 9ft S

inn n7 7132-64-9 ———•if -J *• W X ->

1 71 —1 A-.7 — — —Q A _£ C n _.O4— too— Z— — — —

7005-72-3 ———O tf ~T "5 ~T

100-01-6 ———E? ™t >* C •"* •*534-52-1 ——— •

101-55-3 ——— -1 1 fl-7-l-1 —— — -.Q7 — QK t£ — _.

1 7H-1 '7—7 — - -,8 A — 7 A — 7— — — — .

206-44-0 ——— -129-00-0 ——— -85-68-7 ——— -

Sfi cc t01 a_ni -Q— — -.1 1 7— QI — 7 — __-..1 17 — QA — 0 — - — --205-99-2 ————****** _f _< _*C A 0*5 Q50-j.i-S — - —

1 QT — Q_c;— ___-

191-24-2 ————_W — ' U. _• '4 _r

—— 3-Nitroaniline^ ^ _/\csno.pri wiiGns—— 2 , 4-Dinitrophenol—— 4-Nitrophenol—— Dibenzofuran- — 2 , 4-Dinitrotoluene—— Diethylphthalate—— 4-Chlorophenyl-phenylether _—— Fluorene— 4-Nitroaniline—— 4 1 6-Dinitro-2-methylphenol _—— N-Nitrosodiphenylamine (1) _—— 4-Bromophenyl-phenylether _

nts -ddiiui tjiJGii-* ciit-—— Pentachlorophenol—— Phenanthrene

Ar^+*Viv-a r*^n&jHwlltil— T^lCGnC

—— Di-n-butylphthalate- — Fluoranthene- — Pyrene• — Butylbenzylphthalate- — 3,3 ' -Dichlorobenzidine- — Benzo ( a ) anthracene

.-tt. — .- f c-c^r^dt—iiir _r *— <cnc—bis ( 2-Ethylhexyl)phthalate _- — Di-n-octylphthalate• — Benzo ( b ) f luoranthene- — Benzo ( k ) f luoranthene• — Benzo ( a ) pyrene• — Indeno (1,2, 3-cd ) pyrene. — Dibenz ( a ,h) anthracene

T 2 _ _ / y« £ \ — .rt >— *»1 Ar\^Ds.iiio , ti , j- j yttijf icnc

50.10.50.50.10.10.10.10.10.50.50.10.10.10.50.10.10.10.10.10.10.20.10.10.10.10.10.10.10.10.10.10.

iiuIUiutuiuIU Iiu !IUIUiuIUiuIUiuiutuiuiuiuiuiuiuiuIUiuiuiuIUiuiu

•!° ((1) - Cannot be separated from diphenylamine

FORM I SV-2 1/87 ReSR302959 •

PESTICIDE ORGANICS ANALYSIS DATA SHEET _______ LE

~_ == ~? ^ ! CCH07Lab Name: IEA ,. _"" ' Contract": 68-W8-0045 1______

Lab Code: IEA Case No.: 12544 SAS No.: ' SDG No.: CCHQQ

Matrix: (soil/water) WATER . I ab Sample ID:

> Sample wt/vol: 1000. (g/mL)ML * Lab File ID: DB5A4568


% Moisture: not dec.100. dec. 0. Pate Extracted: 8/28/89

r> Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 9/ 1/89


1 - CONCENTRATION UNITS: "CAS NO. COMPOUND . (ug/L or ug/Kg) UG/L Q

j 319-84-6————alpha-BHC| 319-85-7————beta-BHC| 319-86-8————delta-BHC1 58-89-9———gamma-BHC| 76-44-8———Heptachlor[ 309-00-2———AldrinI 1024-57-3———Heptachlor epoxide| 959-98-8———Endpsulfan II 60-57-1———DieldrinI 72-55-9————4,4'-DDE1 72-20-8———Endrin| 33213-65-9————Endpsulfan III 72-54-8————4,4!-DDDj 1031-07-8———Endpsulfan sulfate[ 50-29-3————4, 4' -DOT| 72-43-5———Methoxychlor| 53494-70-5———Endrin ketpne| 5103-71-9———alpha-Chlordanej 5103-74-2———gamma-Chlordanej 8001-35-2———Toxaphenet 12674-11-2————Aroclor-1016| 11104-28-2————Aroclor-1221| 11141-16-5———Aroclor-1232| 53469-21-9————Aroclor-1242| 12672-29-6———Aroclor-1248I 11097-69-1———Aroclor-1254

.050 IU

.050 |U

.050 |U

.050 |U

.050 IU

.050 |U

.050 |U

.050 [U.10 IU.10 [U.10 |U.10 IU.10 |U.10 [U.10 |U.50 |U.10 IU.50 |U.50 |U1-0 |U.50 |U.50 |U.50 [U,50 |U.50 |U1.0 |U

11096-82-5————Aroclor-1260 | 1.0 [U

FORM I PEST 1/87 Re\

, : i:; SR302960

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

I ccHoaLab Name: IEA Contract: 63-W8-OQ45 ____

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCEOO







74-87-3 ————— Chlorome thane7 4 - 8 3 - 9 ————— Bromome thane75-01-4 ————— Vinyl Chloride75-00-3 ————— Chloroethane

O / 0*41, — — — — — rtCSuOllS75-15-0 ————— Carbon Disulfide75-35-4 ————— 1,1-Dichloroethene75-34-3 ————— 1,1-Dichloroe thane540-59-0 ————— 1,2-Dichloroethene (total) _67-66-3 ————— Chloroform107-06-2 ————— 1,2-Dichloroethane

/ o — jj — j— — — — £.~~ ouucmoiis71-55-6 ————— 1 „ 1 . 1-Trichloroethane

108-05-4 ————— Vinyl Acetate75-27-4 ————— Bromodichlorome thane78-87-5 ————— 1,2-Dichloropropane

10061-01-5 ————— cis-1, 3-Dichloropropene ___79-01-6 ————— Trichloroethene124-48-1 ————— Dibromochloromethane79-00-5 ————— 1,1,2-Trichloroethane

10061-02-6 ————— trans-1, 3-Dichloropropene _75-25-2 ————— Bromoform108-10-1 ————— 4-Methyl-2-Pentanone591-78-6 ————— 2-Hexanone127-18-4 ————— Tetrachloroethene

/ - 7 J r t 3 _-,,_. f £, f £• J.S Ui cLWii-Lwiwe; UIIcLilc108-88-3 ————— Toluene108-90-7 ————— Chlorobenzene100-41-4 ————— Ethylbenzene

10.10.10.10.5.10.5.5.5.5.5.5.10.5.5.10.5.5.5.5.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

1|UIU|U!UIUIUiu iIU 'IUIUIUiuiuIUIUIUIUIUIUIUiuIUIUIUIUiuIUIUIUIUIUIUIU jIU1

FORM I VOA fl R 3 0 2 9 6 1 1/87 Rev

rI B , „ ; . , . - E P A SAMPLE N O .

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

"••""' : I CCH08Lab Name: IEA ^ .& Contract: 63-W8-0045 |______

Lab Code: IEA Case No.:.12544 SAS No.: . SDG No.: CCHOO

Matrix: (soil/water) WATER, . i., ..Lab Sample ID:


Level: (low/med) LOW " :. Date Received: 8/26/89

% Moisture: not dec.lQQ, dec. 0. Date Extracted: 8/28/89



: ' CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol_________________111-44-4—————bis (2-Chloroethyl)ether __"m95-57-8 ————— 2-Chlorophenol___________541-73-1—————1,3-Dichlorobenzene _____]106-46-7—————1,4-Dichlorobenzene _____]100-51-6—————Benzyl alcohol___________95-50-1—————1,2-Dichlorobenzene _____"95-48-7—————2-Methylphenol__________"108-60-1—————bis (2-Chloroisopropyl) ether"106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane________"98-95-3—————Nitrobenzene_______ "78-59-1—————Isophorone_____________88-75-5—————2-Nitrophenol __________105-67-9—————2,4-Dimethylphenol_______65-85-0—————Benzoic acid111-91-1—————bis (2-Chloroethoxy)me thane_120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene____91-20-3—————Naphthalene ____________"106-47-8—————4-Chloroaniline _________~87-68-3—————Hexachlorobutadiene : -59-50-7—————4-Chioro-3-methylphenol __91-57-6—————2-Methylnaphthalene ______"77-47-4—————Hexachlorocyclopentadiene _"88-06-2—————2,4,6-Trichlorophenol ____"95-95-4—————2,4,5-Trichlorophenol ____"91-58-7 ————— 2-Chloronaphthalene -____"88-74-4 ————— 2-Nitroa.niline___________*131-11-3—————Dime thy Iphthalate _______"208-96-8—————Acenaphthylene___________"606-20-2 ————— 2,6-Dinitrotoluene________

10. [U10. |U10. |U10. |U10. |U10. |U10. |U10. IU10. [U10. |U10. ]U10. IU10. [U10. |U10. |U10. |U50. IU10. |U10. IU10. |U10. |U10. |U10. |U10. IU10. IU10. IU10. |U50. |U10. |U50. JU10. .|U10. |U10. |U

FORM I SV-1 fiDOfionro ' 1/87 Re

1C " EPA SAMPLE NCSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ________ _____

I CCH08Lab Name: IEA Contract: 68-W8-0045 1______




Level: (low/med) LOW ' Date Received: 8/26/89% Moisture: not dec.100. dec. 0. Date Extracted: 8/28/89




.? i? — U j ** £. — — — 3 fi -L V.J. UculX.L J.ilt;83-32-9 ————— Acenaphthene51-28-5 ————— 2,4-Dinitrophenol100-02-7 ————— 4-Nitrophenol132-64-9 ————— Dibenzofuran121-14-2 ————— 2 , 4-Dinitrotoluene84-66-2 ————— Diethylphthalate

7005-72-3 ————— 4-Chlorophenyl-phenylether86-73-7 ————— Fluorene100-01-6 ————— 4-Nitroaniline534-52-1 ——— - — 4,6-Dinitro-2-methylphenol _86-30-6 ————— N-Nitrosodiphenylamine (1) _101-55-3 ————— 4-Bromophenyl-phenylether _118-74-1 ————— Hexachlorobenzene87-86-5 ————— Pentachlorophenol85-01-8 ————— Phenanthrene

84-74-2 ————— Di-n-butylphthalate206-44-0 ————— Fluoranthene129-00-0 ————— Pyrene85-68-7 ————— Butylbenzylphthalate91-94-1 ————— 3 , 3 ' "Dichlorobenzidine

117-81-7 ————— bis(2-Ethylhexyl)phthalate _117-84-0 ————— Di-n-octylphthalate205-99-2- ————— Benzo (b)f luoranthene207-08-9 ————— Benzo (k)f luoranthene

193-39-5 ————— Indeno(l,2,3-cd)pYrene53-70-3 ————— DibenzC a, h) anthracene191-24-2 ————— Benzo (g,h,i)perylene

-

50.10.50.50.10.10.10.10.10.50.50.10.10.10.50.10.10.10.10.10.10.20.10.10.10.10.10.10.10.10.10.10.

1IUIUIUIUIUIUIU .iu 1iuIUIUIUiuIUIUIUIUIUiuIUtuiuIUIU|UiuIUIUIUiuiu•1" (

•

ft(1) - Cannot be separated from diphenylamine

FORM I SV-2 1/87 Re

&R3Q2963

r . - . .

EPA SAMPLE NO,

| CCH08Lab Name: IEA i; Contract: 68-W8-0045 |_ _


Matrix: (soil/water) WATER _, . . , Lab Sample ID:

Sample wt/vol: 1000. (g/mL)ML - Lab File ID: DB5A4569

Level: (low/med) LOW \ ... Date Received: 8/26/89



GPC Cleanup: (Y/N) N pH: 6.0 T :__. Dilution Factor: 1.00

UNITS :CAS NO. COMPOUND _ (ug/L or ug/Kg) UG/L

1 : . • , •I 319-84-6 ———— alpha-BHC

"71 Q — sm — "7 — — — — _T-t«+-3 —rsErr*JJ.-7 03 / — — se&a, ariw

58-89-9 ———— gamma-BHC76-44-8 ———— Heptachlor309-00-2 ——— Aldrin1024-57-3 ——— Heptachlor epoxide959-98-8 ——— Endosulfan I60-57-1 ——— Dieldrin77 — =;=;-Q— -_-.- A _it -.nnp72-20-8 ——— Endrin

33213-65-9 ——— Endosulfan II72-54-8- —— --4 4 ' DDDI f* -J ~* <ij ~X f ±J±S±J

1031-07-8 ——— Endosulfan sulfate

72-43-5 ——— Methoxychlor53494-70-5 ——— Endrin ketone5103-71-9 — — — alpha-Chlordane _ . . . . . .5103-74-2 ——— gamma-Chlordane8001-35-2 ——— Toxaphene12674-11-2 ———— Aroclor-101611104-28-2 ——— Aroclor-122111141-16-5 ——— Aroclor-123253469-21-9 ———— Aroclor-124212672-29-6 ——— Aroclor-124811097-69-1 ——— Aroclor-125411096-82-5 ——— Aroclor-1260

,050.050.050.050.050.050.050.050.10.10.10.10.10.10.10.50.10.50.501.0.50.50.50.50.501.01.0

1IUIUIUIUIUIUIUIUiuiuiuIUIUIUIUiuIUIUIUIUiuiuIUIU[UIUIU1

FORM I PEST . 1/87

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

1 CCH09Lab Name: IEA Contract: 68-W3-0045 j______








74-87-3 ————— Chloromethane74-83-9 ————— Bromome thane75-01-4 ————— Vinyl Chloride75-00-3 ————— Chloroethane75-09-2 ————— Methylene Chloride\J * W X _» C >h*iM *•*•****-»

75-15-0 ————— Carbon Disulfide75-35-4 ————— 1,1-Dichloroethene75-34-3 ————— 1,1-Dichloroe thane540-59-0 ————— 1,2-Dichloroethene (total)67-66-3 ————— Chloroform107-06-2 ————— 1,2-Dichloroethane78-93-3 ————— 2-Butanone71-55-6 ————— 1,1, 1-Trichloroe thane

108-05-4 ————— Vinyl Acetate75-27-4 ————— Bromodichloromethane78-87-5 ————— 1 , 2-Dichloropropane

10061-01-5 ————— cis-1, 3-Dichloropropene ___i J \JJrn W ^L_> U.'wll.L WX. Ww U. i'— 11<_>

124-48-1 ————— Dibromochlorome thane79-00-5 ————— 1,1,2-Trichloroethane

10061-02-6 ————— trans-lf 3-Dichloropropene _»t •• ^ ™* ~» »* _ - _ — _ _ff _ _ ___75-25-2 —— —--Bromoform108-10-1 ————— 4-Methyl-2-Pentanone591-78-6 ————— 2-Hexanone

108-88-3 ————— Toluene108-90-7 ————— Chlorobenzene100-41-4 ————— Ethvlbenzene100-42-5 ————— Stvrene1330-20-7 ————— Xvlene (total)

10.10.10.10.5.8.5.5.5.5.5.5.10.5.5.10.5.5.5.5.5.5.5.5.5.10.10.5.5.5.5.5.5.5.

1IUIU

iuIUIBJiuiuiu[UiuIUIUiuIUIUiuiuiuiuiuiuiuIU

IU

iuIUiuIUiuiu ;|U II I

FORM I VOA " 1/87 RevflR302965

; IB EPA SAMPLE NO.SEMIVOLATILE CRGANICS ANALYSIS DATA SHEET

. . : - , . -- _ I CCH09Lab Name: IEA r Contract: 68-W8-0045 |______

Lab Code: IEA Case No.: 12544 _ SAS No.: SDG No.: CCHOO


Sample wt/vol: 1000. , (g/mL) ML Lab File ID: 0911410

Level: (low/med) LOW ; Date Received: 8/26/89


Extraction: (SepF/Cont/Scnc) CONT Date Analyzed: 9/11/89


: CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol______________111-44-4—————bis (2-Chloroethyl)ether ___95-57-8 ————— 2-Chlorophenol___________541-73-1—————1,3-Dichlorobenzene ^______106-46-7—————1,4-Dichlorobenzene . ____100-51-6—————Benzyl alcohol___________95-50-1—————1,2-Dichlorobensene ______95-48-7 ————— 2-Methylphenol___________108-60-1—————bis (,2-Chloroisopropyl) ether106-44-5 ————— 4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane____98-95-3—————Nitrobenzene______i_______78-59-1—————Isophorone ____\_____88-75-5 ————— 2-Nitrophenol ___________105-67-9 ————— 2,4-Dimethylphenol________65-85-0—————Benzoic acid111-91-1—————bis (2-Chloroethoxy)me thane_120-83-2 ————— 2,4-Dichlorophenol______120-82-1—————1,2,4-Trichlorobenzene____91-20-3—————Naphthalene ... _____106-47-8—————4-Chloroaniline ________~87-68-3—————Hexachlorobutadiene _^____~59-50-7—————4-Chloro-3-methylphenol _._91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4,6-Trichlorophenol ____~95-95-4—————2,4,5-Trichlorophenol____"91 58-7 ————— 2-Chloronaphthalene _____388-74-4—————2-Nitroaniline.____~131-11-3—————Dimethylphthalate ________208-96-8—————Acenaphthylene___________606-20-2—————2,6-Dinitrotoluene_______~

10. |U10. |U10. |U10. |U10. IU10. IU10. IU10. |U10. |U10. |U10. |U10. |U10. |U10. |U10. |U10. |U50. |U10. |U10. [U10. |U10. |U10. |U10. |U10. |U10. |U10. IU10. |U50. |U10. |U50. |U10. |U10. '|U10. |U__I

Fc^Misv-1- UR3Q2966

r- EPA SAMPLE NC

I CCH09Lab Name: IEA Contract: 68-W8-0045 I______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHQO








C 99-09-2 ————— 3-Nitroaniline ___________83-32-9 ————— Acenaphthene _____________51-28-5 ————— 2 , 4-Dinitrophenol ________100-02-7 ————— 4-Nitrophenol ___________132-64-9 ————— Dibenzofuran _____________121-14-2 ————— 2 , 4-Dinitrotoluene _______84-66-2 ————— Diethylphthalate _________

7005-72-3 ————— 4-Chlorophenyl-phenylether _86-73-7 ————— Fluorene ________________100-01-6 ————— 4-Nitroaniline ___________534-52-1 ————— 4f 6-Dinitro-2-methylphenol _86-30-6 ————— N-Nitrosodiphenylamine (1) _101-55-3 ——— — 4-Bromophenyl-phenylether _118-74-1 ————— Hexachlorobenzene ________87-86-5 ————— Pentachlorophenol ________85-01-8 ————— Phenanthrene _____________120-12-7 ————— Anthracene ______________84-74-2 ————— Di-n-butylphthalate ______206-44-0 ————— Fluoranthene _____________129-00-0 ————— Pyrene _________ - _______85-68-7 ————— Butylbenzylphthalate ______91-94-1 ————— 3 , 3 f -Dichlorobenzidine _____56-55-3 ————— Benzo (a) anthracene ________218-01-9 ————— Chrysene

O I 117-81-7—————bis (2-Ethylhexyl) phthalate_117-84-0—————Di-n-octylphthalate205-99-2 ————— Benzo (b)f luoranthene207-08-9 ————— Benzo (k)f luoranthene50-32-8 ————— Benzo(a)pyrene193-39-5 ————— Indeno( 1,2, 3 -cd) pyrene53-70-3 ————— Dibenz( a ,h) anthracene191-24-2 ————— Benzo (g,h,i)perylene

50. )U10. IU50. IU50. |U10. |U10. |U10. [U10. IU10. |U50. IU50. IU10. |U10. |U10. |U50. |U10. |U10. |U10. IU10. |U10. IU10. |U20. IU10. IU10. |U10. |U10. |U10. |U10. |U10. |U10. IU10. |U10. .IU


FORM I SV-2 1/87 Re88302967

ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET

<. - " . " - • • ? - . - | CCH09Lab Name: IEA Contract: 68-W8-0045 |

Lab Code: ISA Case No.: 12544 SAS No.: SDG No.: CCHOO


Sample wt/vol: 1000. (g/raL)ML ^ Lab File ID: DB5A4570

Level: (low/med) LOW _ Date Received: 8/26/89

% Moisture: not dec. 100. dec. 0. _ Da?e Extracted: 8/28/89


GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1,00

"CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-84-6————alpha-BHC 1 .050 |U319-85-7————beta-BHC319-86-8————delta-BHC58-89-9————gamma-BHC76-44-8———Heptachlor309-00-2———Aldrin1024-57-3———Heptachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4'-DDE72-20-8———Endrin

33213-65-9———Endosulfan II72-54-8————4,4 '-DDD

1031-07-8———Endosulfan sulfate50-29-3————4,4'-DOT72-43-5———Methoxychlor

53494-70-5———Endrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2———Toxaphene12674-11-2————Aroclor-101611104-28-2———Aroc-lor-122111141-16-5———Aroclor-123253469-21-9————Aroclor-124212672-29-6———Aroclor-124811097-69-1———Aroclor-125411096-82-5———Aroclor-1260

.050 IU

.050 |U

.050 [U

.050 IU

.050 |U

.050 |U

.050 |U.10 |U.10 |U.10 IU.10 ]U.10 IU.10 |U.10 IU.50 |U.10 |U.50 [U.50 |U1.0 IU.50 IU.50 [U.50 IU.50 |U.50 |U1.0 |U1.0 |U

FORM I PEST • 1/87 Re\

flR302968

Appendix D

Reviewed and CorrectedTentatively Identified Compounds

flR302969

IS EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDENTIFIED COMPOUNDS I ————————————

: I CCHOOLab Name: IEA . Contract: 63-W8-0045

Lab Code: ISA Case No-: 12544 SAS No.: • SDG No.: CCHOO


Sample wt/vol: 5. (g/mL) ML , Lab File ID: 0822306



Column: (pack/cap) CAP - - -- ; Dilution Factor: ... 1..00

- CONCENTRATION UNITS:Number TICs found: 0 .-,:.. (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25,26.27.28.29.30.

.

; COMPOUND NAME

r . i

,

I

I

t

RT | EST. CONC.r . . . . . . , | — . -, . i . ._

111111111111111I1111111I1!11111

Q

FORM I VOA-TJCT 1/87 Re

- - f IF . -- ... -. . -- - EPA SAMPLE NCSEMIVOLATILE ORGANICS ANALYSIS DATA S2EET ____________

TENTATIVELY IDENTIFIED COMPOUNDS II CCHOO

Lab Name: IEA Contract: 68-W8-0045 I

Lab Code: IEA Case No.: 12544 .SAS No.: SDG No..: CCHOO





Extraction: (SepF/Cont/Sohc) CONT . . . . Date Analyzed: 9/ 1/89


CONCENTRATION UNITS:Number TICs found: 12 (ug/L or ug/Kg) UG/L

CAS NUMBER COMPOUND NAME

_. . . 3. 4 _____ ---• — --— I TJN^MCWNT _ „ i TrvrryvTOT,rvr

—— 3-, ——————— - —— —4. - -5. - -6. - -7. - -8. - -9. - -10. - -11. - -12. - -13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

-WKNGWN ——————————————UNKNOWN

I UNKNOWNUNKNOWN AROMATIC[UNKNOWN — - 'UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN

i 1| RT

—— i —— i ——— 8.62—— i ——— 3—43 —

1 10 081 10.671 14.721 18.70

- : - i 18.971 19.051 20.73I 22.101 22.631 23.031111

: 111111111

- 1111

: I1

EST. CONC. Q!_...___ —— .. ..-_Q — f-3-T— -————— «-= — S-BT? —

20 I"077>vi 20./// /jrf 10.

&*<"£ ?2*s • .20.to~Tfi'~>.-*7i+r-

10!50.10.40.

JJJJJJJJJ

FORM I SV-TIC 1/87 R

: " I" flR30297l '

r

C

O

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ___________TENTATIVELY IDENTIFIED COMPOUNDS |

I CCH01Lab Name: IEA Contract: 68-W8-0045 I



Sample wt/vol: 5. (g/mL) ML . Lab File ID: 0822307





CAS NUMBER | COMPOUND NAME^ __ -__« ——————— s ——— -:.,,...,.. J ---< —————— -i—— - —————————————————————————————————————— : ——————— * ————

1. 1' 2. !

3. 14. 15. 16. 17. I8. 19. !

10. 111. 112. 113. 114. 115. I16. I17. I18. I19. I20. !21. |'22. |~ 23. I24. I2 5 . |26. 127. I28. |29. I30. 1

1

RT EST. CONC. Q

A-W^

-_h —

FORM I VOA-TIC 1/87 Re

flR302372

-" IF EPA SAMPLE NCSSM1VOLATILE ORGANICS ANALYSIS DATA SHSST .____________

TENTATIVELY IDENTIFIED COMPOUNDS I-LT-.K.*- . i . • I CCH01Lab Name: I2A ... _ .Contract: 68-W8-0045 I




Level: (low/med) LOW -; Date Received: 8/16/89




CONCENTRATION UNITS:Number TICs found: 4 Jug/L or ug/Kg) UG/L

CAS NUTXSER 1 COMPOUND NAME

— In ————————T _

3. - -—— 4-, ——————— - —— ___

5.6.7.8.9.10.11.12.13.14.15.16. !17. 118. I19. I20, 121. I22. i

1 23. I24. I25. I26. I27. I28. I29. 130. 1

i

t TTKlT'xTrrWltT ', lJ*<*>-»i w VV.t - -

-UN-KNCWN ————UNKNOWNU N WN

i - ! '

i * !

_ ;

,

O £f\w • U UQ yJT

9.6710 08

!_.._ . - - 10.*» w •

10• "" 10i;/z*v *X'&/*+•*£< «7*wf"X *» .?•— ' ""Jo -*

— — •_J|J

hB —J

•

RT | EST. CONC,

FORM I SV-TIC " 1/87 R

:; " . : - ' ",::Mft"R'302973 '

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDENTIFIED COMPOUNDS [

I CCH02Lab Name: IEA Contract: 63-W8-0045 |


Matrix: (soil/water) WATER. Lab Sample ID:

Sample wt/vol: 5.' (g/mL) ML . Lab File ID: 0822303


% Moisture: not dec.100. Date Analysed: 8/22/39iColumn: (pack/cap) CAP Dilution Factor: 1.00


1CAS NUMBER | COMPOUND NAME

1. 1-2. i3. !4. i5. i6. i7. 18. i9. 1

10. 111. 112. i13. 114. i15. i16. I17. 118. !19. i20. I'21. - IJ22. i23. I24. 125. 126. 127. 128. 129. 130. [

1

RT EST. CONC.

-

Q...

^_^——

••w


v«A/

r . : IF EPA SAMPLE NCSSMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

TENTATIVELY IDENTIFIED COMPOUNDS |~~——————————I CCH02

Lab Name: IEA Contract: 63-W8-0045 j




Level: (low/med) LOW - Date Received: 8/18/89


Extraction: (SepF/Cont/Sonc) CONT Date Analysed: 8/28/89

GPC Cleanup: (Y/N) N ' pH: 6.0 Dilution Factor: 1.00

.CONCENTRATION UNITS:Number TICs found: 4 (ug/L or ug/Kg) UG/L

CAS NUMBER i COMPOUND NAME1 — -J J.i — t, ——————1 -»1 —— a-* ——————— " —— "" —13. - -1 —— 4, ——————— - —— —1 5.1 6.! 7.! 8.1 9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

f^JNKNGWN —————— : ————————— : — « ——[-UNKM WNUNKNOWN , — - .. , ;- -UNKNOWN ——————— - ————— -- - • : ——

,

,

- •i - !

ii

863Q 439.43

I —— 10,13-

~ ~ 10 ~! 30

L>f> 3}i/±&j*4 */ ' ' •*- af J^ « —,

•"•"• " ' ""'_.•>>> ' '"

&/#**:(os r* »jr >r » *s

! "D TpoU — -1-BJJ

hB^ —

RT I EST. CONC.


• flR302975

IE EPA SAMPLE NO-VOLATILE ORGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDEOTIFIED COMPOUNDS I

1. CCH03Lab Name: ISA. Contract: 68-W8-0045 I__



Sample wt/vol: 5. (g/mL) ML . Lab File ID: 0822309

Level: (low/med) LCW Date Received: 8/18/89

%_ Moisture: not dec.100. • Date Analyzed: 8/22/89


CONCENTRATION UNITS:Number TICs found: 1 • (ug/L or ug/Kg) UG/L

i i i i———————j| CAS NUMBER 1 COMPOUND NAME | RT 1 EST. CONC. 1 Q

1. 109-99-92.3.4.5.6.7.a.9.10.11.12.13.14.15.16.17.18.19.20.21.'22.23.24.25.26.27.28.29.30.

Furan, tetrahydro- 11.63 100. J

A*r

— * —


flR30Z976

IF : EPA SAMPLESSMIVOLATILS CRGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS. . I- - - - - | CCH03

Lab Name: IEA : , . Contract: 68-W8-0045 I


Matrix: (soil/water) WATER _ Lab Sample ID:


Level: (low/med) LOW . _: :: Date Received: 8/18/89

% Moisture: not dec. 100. dec. 0* . . Date Extracted: 8/22/89

Extraction: (SepF/Cont/Sonc) CONT ^ ..„_,« Date Analyzed: 8/28/89

-GPC Cleanup: (Y/N) N pH: 6.0 _ Dilution Factor: 1.00

• ""' CONCENTRATION UNITS:Number TICs found: 6 ; , (ug/L or ug/Kg) UG/L

CAS NUMBER

1. - --j _3. - -4. 104-76-75. 872-50-46. 149-57-57.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30. 1

1

,: 1.COMPOUND NAME | RT

UNKNOWN I 8.62•UNKNOWN- ———————— - ————————— 1 ——— 9.43UNKNOWN ' I 9.671-Hexanol, 2-ethyl- I 11.682-Pyrrolidinone, 1 -methyl- _ j 11.88Hexanoic acid, 2-ethyl- I 13.33

i1iiI11i1111Iii1!111111

^ 11

EST. CONC.

20.— ^0D3>~1 q"""" 40?}"~* 1000.r*"' 100.

QJ

T2 T-o& ——J

J

J

J

FORM I SV-TIC 1/87 EifiR302977 '

IE EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET _____________TENTATIVELY IDENTIFIED COMPOUNDS [

[ CCHQ4Lab Name: IEA Contract: 63-WS-QQ45 |_______



Sample wt/vol: 5. (g/mL) ML ' Lab File ID: 0822313





1GAS NUMBER | COMPOUND NAME

1. I2. 13. 14. 15. 16. 17. 18. 19. 1

10. I11. !12. 113. i14. 115. 116. 117. 118. 119. 120. i21. 122. I23. 124. 125. 126. 127. 128. 129. I30. I

1

RT EST. CONC.— ———— . ———— Q

_^_" B~BF

-A.


fiR3Q?378

IS EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________TENTATIVELY IDENTIFIED COMPOUNDS [

| CCH05Lab Name: IEA -..- - Contract: 63-W8-0045 I______

Lab Code: IEA Case No.: 12544 SAS No.: • SDG No.: CCHOO

Matrix: (soil/watsr) WATER Lab Sample ID:


Level: (low/med) LOW Dates Received: 8/25/89

% Moisture: not dec. 100. : Date Analyzed: 8/31/89

Column: (pack/cap) CAP : Dilution Factor: 1.00


1 ' 1CAS NUMBER | COMPOUND NAME ( RT

i. i • • i2. 1 . ' |3. I '- : 1 '4. 1 15. 1 16. 1 17. 1 ^-18. 1 19. 1 1

10. 1 I11. 1 '112. 1 I13. 1 114. 1 I15. I 116. I I1 7 . I ' 118. I I19. 1 I20. 1 I21. 1 I22. I I23. 1 I24. I I25. I I26. I I27. | I28. 1 I29. 1 130. 1 1

1 1

EST. CONC.=====

Q

FORM I VOA-TIC 1/87 Rev

- 1 flR30297"9

IF EPA SAMPLESEMIVOLATILE ORGANICS ANALYSIS DATA SHEET __

TENTATIVELY IDENTIFIED COMPOUNDS II CCH05

Lab Name: IEA Contract: 68-W8-0045 I______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: .CCHOQ








iCAS NUMBER \ COMPOUND NAME

» 1 w.t. .l'w ti *,i

2. - - I UNKNOWN3. 14. I5. 16. 17. 18. 19. I

10. I11. 112. 113. 114. 115. !16. I17. 118. 119. I20. I21. 122. I23. ]24. I25. I26. 127. I28. I29. I30. 1

1

1RT 1 EST. CONC.B A -i j r> 3 f*i -i -.10 7 j'""/" lo!

i Zf& k.\ f o-r- 7 ** s»~~-<+'7~dst'

111I1111111!111111111111111

Q.L"JJ

Aw

ftFORM I SV-TIC , 1/87 R

rIE EPA SAMPLE NO.

VOLATILE CRGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDENTIFIED COMPOUNDS 1———————————

| CCH06Lab Name: IEA - Contract: 68-W8-0045 |______



Sample wt/vol: 5. (g/mL) ML > Lab File ID: 0831304

Level: (low/med) LOW : Date Received: 8/25/89

% Moisture: not dec.100. , .. . >- Date Analyzed: 8/31/89

Column: (pack/cap) CAP . : Dilution Factoi::. . 1.00

; CONCENTRATION UNITS:Number TICs found: 1 - (ug/L or ug/Kg) UG/L

1 1I CAS NUMBER [ COMPOUND NAME

|1. - - [UNKNOWN1 2 . 11 3. 1! 4. II 5. 1! 6. |17. I1 8. !1 9 . 11 10. 11 11. 11 12. 11 13. I1 14. I! 15. 11 16. 11 17. !1 18. 11 19. 11 20. 1I 21. II 22. 11 23. 11 24. 11 25. 1I 25. I1 27. 11 28. 11 29. II 30. i1 I

RT

5.20

EST. CONC.

5.

Q

J

FORM:I VOA-TIC .. 1/87 Re

"-AR302981 ' -""'

-____ IF EPA SAMPLE N<.SEMIVOLATILE ORGANICS" ANALYSIS DATA SHEET ___________

TENTATIVELY IDENTIFIED COMPOUNDS I "I CCH06

Lab Name: IEA Contract: 68-W8-0045 j

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.:

Matrix: (soil/water) WATER Lab 'Sample ID:


Level: (low/med) LOW * Date Received: 8/25/89


Extraction: (SepF/Cont/Sonc) COOT " Date Analyzed: 9/ 1/89



iCAS NUMBER i COMPOUND NAME

————— ————— | .HTT ,_ .^___^. ^ ^____. ————— .Tr

i — ± ——— . , -4.tT>nc rcwN — ~- • • -2. - - [UNKNOWN

__ 3...J ——————— . —— - — (-UNXNCWN"- •-•••' • — '•»- "--— i- ...«4. - - [UNKNOWN5. I6. 17. Ia. .]9. I10. i

11. i12. 113. !14, 115. I16. I17. i18. I19. I20. [21. 122. 123. 124. 125. 126. !27. I28. I29. 130. 1

I

RT

9 42>^ • £ J~

9.67....... 10-tlO •J. U • .*. w

10.68„

EST. CONC.

...-) Q •Sk --•-.. -j y *£>„/•» 10lt/2J?/&4 "it/ t~3 fa** - f\

J. U I

20.£/ /4r{ot iTrf j*£*s*& T &AS

•

Q_<w

J

Mf W

J4fc-•-

4_v—*_FORM I SV-TIC 1/87 E^

: • IE EPA SAMPLEVOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED. COMPOUNDS I

| CCH07Lab Name: IEA . ;s .Contract: 63-WS-Q045 j

Lab Code: IEA Case No".: 12544 SAS No.: • SDG No.: CCHOO




% Moisture: not dec.100. . ' "" ., ; Date Analysed: 8/31/89

Column: (pack/cap) CAP Dilution Factor: 1-00

; CONCENTRATION UNITS:Number TICs found: 1 (ug/L or ug/Kg) UG/L

1| CAS NUMBER— ™— ~"~" ~* ~"11. - -

1 2.\ 3.1 4.I 5.1 6.1 7.i a.I 9.! 10.1 11.1 12.1 13.1 14.1 15.1 16.1 17.1 18.! 19.1 20.1 21.I 22.i 23.I 24.1 25.1 26.i 27.! 23.1 29.i 30.I

ICOMPOUND NAME | RT

UNKNOWN "-" | 7.65|111

' 1' 1

11111111111.-.. ,1

- - 111

- 11111111

EST. CONC.

20.

QJ

FORM I VOA-TIC 1/87 Re-

_ ,-Vr-fiR3Q2983

IF . EPA SAMPLE NSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

TENTATIVELY IDENTIFIED COMPOUNDS II CCE07

Lab Name: IEA Contract: 63-WS-Q045 I

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO*

Matrix: (soil/water) WATER Lab'Sample ID:




Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 9/11/89



iCAS NUMBER I COMPOUND NAME

_,,,.,!-, _,..„, — , ___ — j.UNKNSW T— •• - — • ————————————————2 . 128-37-0 [ Phenol, 2 , 6-bis 1 1 , 1 -dimethyl3. i4. . i5. 16. 17. i8. !9. 1

10. I11. 112. I13. i14. I15. I16. I17. i18. i19. 120. !21. I22. 123. 124. 125. I26. 127. 128. 129. i30. I

1

RT

!„ , _£._£5_19.18

EST. CONC.£>3>-7 D

'"*"*> 20'.

Q

?—J

*FORM I SV-TIC _ 1/87

"

IS EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ____________TENTATIVELY IDENTIFIED COMPOUNDS [ —————————————

I CCH08Lab Name: IEA - Contract: 6S-W8-OG45 I

Lab Code: IEA Case No.: 12544 SAS No.: - SDG No.: CCHOO

Matrix: (soil/water) WATER - Lab Sample ID:



% Moisture: not dec.100. ; . Date Analyzed: 8/31/89

Column: (pack/cap) CAP ]- Dilution Factor: 1.00

~- CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.15.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME | RT

1111111

- 111111111111111111111I11

EST. CONC. Q

FORM I VOA-TIC ' 1/87 Re

- . - - ' ftR3Q2935.

IF EPA SAMPLE N(SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

TENTATIVELY IDENTIFIED COMPOUNDS . II CCH08

Lab Name: IEA Contract: 63-W8-OQ45 _______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHQl



Q Level: (low/med) LOW • Date Received: 8/26/89



'• GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1.00


i : i i————\——————jI CAS NUMBER I COMPOUND NAME I RT I EST. CONC. I <

. 1.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

- - [UNKNOWN———— - —— - — f UNKNOWN —————————————————————

- - [UNKNOWN CYCLOHEXANE1tIf1Ii11!I1IIAIIff!!11II1I[

8.45[,. .._9_2.5_

9.92

7-, 9-.JZttL, ,40, ..UtWtf 10.

t*l/*M>t

fo~ rt Z** *~Zo*s

—————— 1

J•a?—J

ft=

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FORM I SV-TIC 1/87 RflR302986

i - IE " E£»A SAMPLE NO-VOLATILE ORGANICS ANALYSIS DATA SHEET _____________TENTATIVELY IDENTIFIED COMPOUNDS _ I

| CCH09Lab Name: IEA : Contract: 68-W3-0045 I_____

Lab Code: IEA Case No.: 12544 SAS No.: . . SDG No.: CCHOO




% Moisture: not dec.100. Date Analysed: 8/31/89


-CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

| COMPOUND NAME

---

;'.

iiiiiii

RT

1

EST. CONC. Q

FORM I VOA-TIC 1/87 Re<

IF EPA SAMPLE NSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ___________

TENTATIVELY IDENTIFIED COMPOUNDS I1 CCH09

Lab Name: IEA Contract: 68-W8-0045 |______

Lab Code: IEA Case No.: 12544 SAS No.: SDG'NO.: CCHOcJB)


Sample wt/vol: 1000, (g/mL) ML Lab File ID: 0911410



Extraction: (SepF/Cont/Sonc) CONT ' Date Analyzed: 9/11/89



1CAS NUMBER i COMPOUND NAME

1. - - [UNKNOWN"1 ! TrkTT \T("*r "ITi- • I U-4*^—JUW.i

3. - - [UNKNOWN CYCLOHEXANE4. 128-37-0 [Phenol, 2,6-bis(l,l-dimethyl5. I6. I7. I8. 19. 1

10. 111. !12. !13. I14. 115. I16. I17. I18. 119. 120. !21. 122. I23. I24. I25. - 126. I27. 128. I29. I30. I

1

RT

8.4591 *™• -* 39.92

19.17

EST. CONC.

8.P— ' *** -» n—— K. —— . ——— ,HTT — " —///*-a/^»T <t n10 .

20.

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k-_LFORM I SV-TIC 1/87 I

flR3Q2988

Appendix E

DPO Report for Contractual Compliance

/TR3Q2989

page x of 2ORGANIC DATA VALIDATION SUMMARY

Date Review Completed: 29 November 1989 Contract Lab.: IEACase No.: 12544 Contract No.: 68-W8-0045Site Name: DELTA QUARRIES Lab DPO: Tom Bennett, Jr.Sample Nos. : CCHOO through CCH09 Reviewer: Doug Mclnnes

From: Region III/ESATPhone: (301) 266-9887

CONCENTRATIONMATRIX ! low jmed Jhiahj MATRIX RELATED COMMENTSsoil/solid ! ! ! ]aaueous j 10 j j j| other ! ! ! !

7OLATILESGC/MS TUNING — BFBInitial CalibrationContinuina CalibrationSurroaate RecovervMatrix SpikesReaaent BlanksHoldina times

OK | FYI 'ActionY * I———— £ —— i ——————— i ———————i x !

» Y 1———————— i ———— £ —— j ———————Y i i——— £ —— I —————— I ——————1 y 1

1 x i—————— I ——— £ —— j ——————Y 1 11 ———— £• ——— 1 ——— .__„.. i.,,. „ ,

COMMENT

See notes 1 and 2See notes 1 and 2

See note 3See note 4

SEMI-VOLATILES.

Initial Calibrationjcontinuina Calibration j jj Surroaate Recoverv } !Matrix Soikes _

XXXX

{Reaaent Blanks { x {i Holdina Times { X }

SeeSee

j SeeSee

notenotenotenote

2256

—————— 1 ————————————————————— t

PESTICIDESj Instrument Performance iInitial Calibration jjcontinuina Calibration jSurrocrate Recovery jMatrix SpikesJReaaent Blanks jJHoldina Times j

OVERALL CASE f! Compound Identification!Data Completeness }

v

XXXXXX t

! 1

———— 1 ————————————————— 1———— 1 ————————————————— 1———— , ______________ |———— 1 ———————————— 1———— 1 ————————————————— |

i

OK PYI Action!XX

1—————————— , ———————————————————————————————————— |.,, „ 1 ———— „.,..„.„.,.,„..„ ,,.,..„. ,.,— ————————— 1

REVIEWERrS COMMENTS:

DOCUMENTATION ATTACHED (see following pages)

SR302990

Case 12544 - . . . . : . Page 2 of 2

ORGANIC DATA VALIDATION SUMMARY

Note 1 - The response factor (RF) for 2-butanone was less than0.05 in the initial and/or continuing calibrations. (SeeTable 1 in Appendix F).

Note 2 - The %RSD and %D values for several compounds exceededprecision criteria in the initial and/or continuingcalibrations. (See Table 1 in Appendix F) .

Note 3 - The volatile MS/MSD analyses of sample CCH03 had a totalof four (4) out of ten (10) spike recoveries outside theQC limits. (See Appendix F),

Note 4 - The maximum concentration of the common laboratorycontaminant acetone found in the method blanks is 12j-g/L. (See Appendix F) .

Note.5 - Two samples, CCHOO and CCH01, had surrogate recoveriesfor 2-fluorophenol outside the QC limits. (See AppendixF).

Note 6 - The semivolatile MS/MSD analyses of sample CCH03 had atotal of one (1) out of eleven (11) RPD values outsidethe QC limits. (See Appendix F).

DCN - DM911A05

AR3Q2991

- " DPO:" I ] ACTION K( FYI

CJRGA&TC fSCpOtfAL BATA ASSESSMENT SVMMAX?

CASE NO. )7-$LiH __________ LABORATORY ______2

SDG NO. ££ gQ___________ DATA USER Tom g gU gr-r, JV.

SOW >/^-^______-________ " REVIEW COMPLETION DATE _££

NO. OF SAMPLES / Q MATRIX

REVIEWER [ ] ESD M H3AT [ ] OTHER,

VOA SNA PEST OTHER

1. HOLDING TIMES O O & ____

2. GC-MS TUNS/ GC PERFORMANCE O O ® ____

3. INITIAL CALIBRATIONS X X ^ ————

4. CONTINUING CALIBRATIONS * X p ____

5. FIELD BLANKS 0?* - not applicable) X O & ————

6. LABORATORY BLANKS X 0 ^ ————

7. SURROGATES O O ® ____

S, MATRIX SPKE/-DUPLICATES O Q ^ ___

9. REGIONAL QC C?* « sot applicable) _____ _____ _____ ___

10. INTERNAL STANDARDS O & ———

11. COMPOUND IDENTIFICATION O. ® & ———

1Z COMPOUND QUANTITATSON / T O... . ^ ——,

is. SYSTEM PERFORMANCE" P Q ^ ——14. OVERALL ASSESSMENT X X O ———

O * No problems or minor problems that do not affect data usability.X « No more than about 5% of the data points are qualified as either estimated or unusable.M ** More than about 5% of the data points are qualified as (estimated.Z « More than about 5% of the data points are qualified as unusable.A «• D?0 action requested; use in conjunction with one of the above codes.

DPO ACTION ITEMS;

AREAS OF CONCERN:

TTT Rev,8/8

Appendix F

Support Documentation

AR302993

TASLS I P«g«_l of bPftOTECriOM ASSHCY REStOH III

CALI33ATIOX QUTLIEXS_ VOLATILE HSL COHPQUMOS

CASI/SAS Mo. / -t-a. 7_______C3MT3ACTQR _____________J~ & f t _ _ _ _ _ _ _ _ _ _ _ _ _*—•-'

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t \CCilGO 1 t-C]-h}f.

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s r_o a c e of t J i f s t a b l e for DEE I M f T t O M OF COOES:

S I

E3VISCSMEHWL PROTECTION AG2HCT HEGIQHCALIBRATION OUTLISSS

S2*I7QLATH,2 HSL COMPOUNDS (Part 1 of 2)^ m-/ ________ CONTRACTOR

i Inscrênt* fr^t.I DATI/TrXE;: !

IKF !*3oâ^/o ' i. . .~..u _ > tb is ( -Chloroethvl) ether f !2-ChIoroohenol ! !t . —Dichlorobenzene ! !1 , -Diohlorobensene { • !Hensvl alcohol ! !1 ,2-Qichlorobensene ! !2-Methvlohenol ! !bis (2-Chloroisooroovl) ether! !H-Methvlohenol ! !tf— Mitroso— di— i— oroovlamiê ! !Ksxaohloroe thane : ! !Nitrobenzene • ! !Isoohorone ! !2-ttitroohenol ! !2 . --Dinethvlohenol ! !Benzole acid ! !bis(2-Chloroethoxv)methane { !2 . --Dichloroohenol ! !1.2, -Trichlorobenzene ! !Naohthalene ! !U-Chloroaniline f !Hexachlorobutadiene \ !4-Chloro-^-Methylohenol ! !2-MethvlnaDhthalene ! !Kexachlorocyctooentadiene [ !2.^.6-Triohloroohenol ! !2.4. 5-Trichioroohenol ! !2-Chloronaohthalene ! !2-?Titroarrline ! !Diaethvlohthalate ! . !Aeenachthvlsne • ! !2.6-Dinitrotoluene ! !^-tt-'troaniline ! !Acenaohthene • I !2,fc-Dinitroohenol ? fU-Mitroohenol f !

iAFFECTED !SAMPLES: !,.„,

[Reviewer J,Cnitials/Date: J>s" liters* \

iii_'-...._

•j ____

Ca^. fCont. Cal. ICont. Cal.fft! WM/** o $/-3 ! 1M& & ii*

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TABL3 I page_

ENVIRONMENTAL PROTECTION AGSNCT REGION inCALIBRATION OUTLIERS

SZJCTCLATILH ESL COMPOUNDS (Part 2 of 2)CASE/SAS No._L£vS_î________CONTRACTOR_____________*£&#

! "-scr-js €"^--i JTa-ft Cal! DATE/TIME: !; , « RF t *rtSD i *! Diber.sofuras l> ! !! 2,^-Dinitrotoluene ! ! !! DietsvloctSialate ! ! !! --Chloroonesvl-chenYlether ! f !! Fluor*n« ! I I! a-Mitroaniline i 1 !! tt,6-Diaitro-2-aethrlBhenol I ! !1 tf-tfitrQsodlohesvlamine ! ! ff .fc-Brooooherrvl-ohenvlether 1 f f! Hexachlorobenzene ! \ \! Pentachloroohenol ! f fi . Phenanthrene ! ! f! Anthracene ! 1 !! .Di-n-butvi_hthaiata ! ! I1 ..Fluoranthene I ! f1 Pvrtr.e | I I! ButvlbenzTlonthaiate I ! !! 3.^-Dichiorobenzidine f ! fI B@nzo(a)anthrmcene f ! f| r*Vtw*r«a>*t A I I f

! bis(2-EthvlheTVl)Dhthalata ! ! f1 Di-n-octvlohthalate. ! ! If Benzo(o) fluoranthene f ! ff Benzo(lc) f luormnthene ! ! !! Benzofalovrene ! ! !! IndenoC 1.2. ^— cd) Dvrene ! f !f Dibeiz a h^sîtGrscsns ! ! !! Benzo (ff.h.i)oervlene ! I f

iAFFECTED !SAMPLES: !

4, Jl _____ m

Revitwer . iInitials/Date: &>* "A*/f} \

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• " " K : î-TA3L2 I1.. . oage 7 of

ENVIRONMENTAL PROTECTION AGENCT REGION IIICALIBRATION OOTLI22S

SH-OTCLATILZ HSL COMPOUNDS (Part 1 of 2)*^ _____ CONTRACTOR

• Cal.fCont. eal.JCont-. Cal. f Coot. Cal.!Zz/*±

!» I3F f,P f* fgp ftp Ift fHF !JP f* ISF I

bisi^-ChloroethvDether2-Chlorochenol7 .^-Dichlorobenzane______f { If | f | | j j j f ! j f. -Oichlorobensene

Ser.zvl alcohol1 . 2-Dichlorobensene2-Methvlshesolb is (2-Chloroi3ooroDvl) ether! f^-Methvlohenol

Hexachloro ethaneMi t rob enzereIso.ohorone2-Mitroohenol2 . fc-.Benzole acid____ _L L5"* 3 EP L _!_ J_~ L L £ I I __I f 1 !bisC2-Chloroet&oy70agthane If f I ! I ! ! ! ! I f ! t I t.g.tt-OiQhloroohenol L ! ! _L _L L L L !_ ! L i ! t i !1.2. -TrichlorobenzeneNaohthaleneii-ChloroanilineKexachlorobutadieneft-Chloro-1-Methylohenol ! f ! f ! ! I ! f ! f ! L I I2-Methvlnaohthalene ! ! ? ! ! ! ! ! ! ! ! ! ! I !Rexachlorocvclooentadiene !2^^6-trichloroohenol If f [ I I ! ! I ! ! ! L I fS.aj-TrichloroDhenol ?! ! \ I L L f ! I ! ? f i f2-Chloronaphthalene______I ! f i t ! I ! f f ! I !2-Nitro aniline___________! ! _ I !Diaethylohtaalate_______! * ! ! 'j———J——L———L.Acenaohthvlene2. 6-Dinitrotoluene_______f f

Ac snaoh there2.U-Dinitropheaol_______! ! ! ! ! I ? !

I a-Mitrooheaol___________I f f I ! I ? I ! I ! ! I

AFFECTEDSAMPLES:

^ReviewerInitials/Date;

70e,fe page of f.h^c, feahia for PP?T^TTTOM OF CQnffS.firto'uzygy

TABLE I page.

ENVIRONMENTAL PROTECTION AGENCT REGION IIICALIBRATION OUTLIERS

SHMI7CLATIL3 HSL COMPOUNDS (Part 2 of 2) „CONTRACTOR _________________.

T^gc-^m^t^ £ X"T# Y

! DATE/TIMS:ii!. Dibensofuran! 2 . &-Dlnitro£oluen@I DieshylsbthaiateU-Chiorooherivl-ohenTletherFluorine-?Titro anilineH . S-înitro-2-methylDhenoTN-Nitro30di3henvlamine^-Broooohenvl-ohenvletherHexachlorobenzenePentachioroohenolPher.anthrana

_ Anthracene_ Di-r.-butvlohthalateFluoranthenePvrsneButvlbenzvlohthalate^ . -DichlorobenzidineBanzo(m) anthraceneChrvsenebisC2-EthvliiexTl)ohthalateDI-n-octTlohthalateBenzo(b) fluorantheneBenzo Iclf luorantheneB @nzo f & / ovr @rsIndenoC 1.2. ~cd ) oyrensDxbenzC a. n / *yi "racene

' Benzo f s.h. i)o@rylene

AFFECTEDSAMPLES:

ReviewerCnltiala/Date: ^ ''/

f"nit. Cal. ICont L\tf//f/33 /o' ^ f ////P*f* T?tT I^TSCm'-* * TJTT '<Tt rcr i *rtû f t rtr t sii i l i tt t i i fi t i i ii i i t ii t t i iI ! . ! I1 I I f !i t t i ii t t i ii t t t i

i t i i ii i t i ti t t i ii t i i ii i i i i1 1 t f !

1 1 I I I

I I I I I

1 1 ( I t

I I I I I

f f ! I !! f I f fi i i i \2_f-! f ! f !f ! ! I ff ! 1 ! !f 1 I ! fi i i i i! 1 ! ! !! !3o,zL£-I_ !! <: 3.) tr a-y. \ $E.il<] CCô* \\ rc.ôT !| r <• •->*& \i : -.- , ,• /,, fi i! I! f! If f

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Cal . ! Cost. Cal . ! Coat. Cal . 1! ! f

) !* fHF I ID !* !RF !*D !« f1 I ! ! I 1 I !! ! ! ! ! I ! f1 f ! f I ! f! ! ! ! ! ! ! ?i i i i i ii i i i i i i! ! ! ! ! ! !! ! ! ! ! ! !t t i i t ii t i i i i ii t t i i i ii t t i t f ii ; i t t ii t t t t it 1 t i f i *

! ! ! ! ! ! !! ! ! ! ! I f -! ! ! f f ! !•! ! ! ! ! ! ^! 1 ! ! 1 1! I f ! 1 1i i i i i t! ! ! ! ! !f * t f t ii t t t i i! ! ! ! ! 1! ! ! ! ! !i i i i t (t i r » i •

1 tt iI t

; ;i ii l1 !j i! Ii ii tt i

* See last page of this table for DEFINITION OF COPES.

flR3Q2998

OEfXXlT.QJI OF COOES USED XN TABLE I

I - Saso exceeded 30S in tht initial calibration, "positiveresult* are qualified -a", and qu«ntf tatf on Uaits «r«qu«l f f f *d »UJ".

C » XO •xe«*d*d 25 X In tht contfnufng calibration, Po*f tfv*results art qualified »J- and quant (tat ion " U«f ts are qualfffed

f » «F less than 0.05 in all ca I f brat f ons. 'AU quantisation limitsare qualified "R«. ; ..-..*.——

* * The "S- qualifier denoting blank eontaninat I on supersedes thequalifier issued in this table.

AR302999

6AVOLATILE CRGANICS INITIAL CALIBRATION DATA

Lab Name: IEA . Contract: 63-W8-0045

Lab Coda: IEA Case No.: 12544 SAS No.: SDG No.: CCHQQ

Instr-oment ID: EXTR3 Calibration Date(s): 8/10/89 8/10/89

Matrix: (soil/water) WATER Level: (low/med): LOW Column: (pack/cap) CAP

Min RR5 for SPCC(t) = .300 (0.250 for Bromoform) Max %RSD for CCCC*) = 30.

LAB FILE ID: RRF20 = 0810G04 RRF50 = 081QC02s 081QG01 ... - RRF150= 0810G02 RRF20Q= 0810GQ5

COMPOUND

Chloromethane|Bromomethane_iVinyl Chloride1ChloroethaneIMethylene ChlorideAcetone

,BromodichloromethaneJ1,2-Dichloropropane __|cis-1f3-DichloropropeneTrichloroethene|Dibramochloromethane_j1,1,2-Trichloroethane!Benzeneitrans-1,3-Dichloropropene _\Bromoform ________4-Methyl-2-?entanone2-HexanoneITetrachloroethene _____[1,1/2,2-Tetrachloroethanej Toluene

|RRI?20 IRRFSO IRHF100 1RRF150 1RRF20Q i

[Carbon Disulfide_11/1-Dichloroethene11,1-Dichloroethane^________11,2-Dichloroethene (total)_| Chloroform_____________* 3j 1,2-Dichloroethane_______ 1I2-Butanone_________11,1,1-Trichloroethane|Carbon TetrachlorideIVinyl Acetate

1Chlorobenzene__________S .953[ 1.0191 1.0151 1.0021 1.010| 1.0001 2.'[Ethylbenzene____________* .5051 .5471 .531| .567| .528| .5361 4.IStyrene ________________| 1.0031 1.1191 1.1771 1.211| 1.248| 1.1521 8.:IXylene (total)__________| .6371 .7311 -7531 .770| .764| .7311 7.!

IToluene-dS_______________| 1.222| 1.400] 1.376| 1.396| 1.351| 1.349| _IBromofluorobenzene_______1 .561] .617| .619| .587| .6271 .6021 4.'|l,2-Dichloroethane-d4 ____| 1.887| 1.924| 1.920| 1.834] 1.7951 1.8721 3.'

FORM VI VOA flR303000

7AVOLATILE CONTINUING CALIBRATION CEECX

Lab Name: IEA _* | Contract: 68-W8-0045


Instrument ID: EXTR3 ; Calibration Date: 8/22/89 Time: 7:52

Lab File ID: 0822301 Init. Calib. Date(s): 8/10/89 8/10/89


Min RRF50 for SPCC(t) = .300 (0.250 for Bromoform) Max %D for CCC(*} is 2.

COMPOUND

t Chloramethanej Bromcme thane_I Vinyl Chloride1Chloroethane____[Methylene ChlorideAcetone[Carbon Disulfide_11,1-Dichioroethenei lf 1-Dichloroethane__ ___!1,2-Dichloroethene (total)_. Chlorof orm_____"_" _____*1 f 2-Dichloroethane2-Butanone11,1,1-Trichloroethane[Carbon Tetrachloridej Vinyl Acetate| Bromodichlorome thane11,2-Dichloropropane __j cis-1 f 3-DichloropropeneTrichloroethene[ Dibromochloromethane_[1,1,2-TrichlorqethaneBenzene

! trans-1,3-Dichloropropene _;Bromoform ________4-Methyl-2-Pentanone2-Hexanone

I Tetrachloroethene11,1,2,2-Tetrachloroethane _I Toluene ________ * 1[Chlorobenzene __________#IEthylbenzene___________StyreneXylene (total)

Toluene-d3Bromofluorobenzene1 , 2-Dichloroethane-d4

1.1521.7311

1.3491.602]

1.8721i

1.0841.720]

1.4451.6121

1.963|!

5.91.5

7.11.64.9

flR30300

r7A

VOLATILE CONTINUING CALIBRATION CHECK

Lab Name: IEA Contract: 63-W8-0045

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOQ

Instrument: ID: EXTR3 Calibration Date: 8/31/89 Time: 9:22



Min RRF50 for SPCC(i) = .300 (0.250 for Bromoform) Max %D for CCC(*J is 2

COMPOUND [ RRF IRRF50 | %D1 ——— ——— —— —————————( Chloromethane J! Bromome thane[Vinyl Chloride1 ChloroethaneIMethylene ChlorideI Acetone[Carbon Disulfide1 1 , 1-Dichloroethene :1 1 , 1-Dichloroethane \1 1 , 2-Dichloroethene ( total ) _1 Chloroform 31 1 , 2-Dichloroethane1 2-Butanone11,1, 1-Trichloroethane[ Carbon Tetrachloride[Vinyl AcetateI Bromodichlorome thanej 1 f 2-Dichloropropane *jcis-l,3-Dichloropropene __I Trichloroethenej Dibromochlorome thane11,1, 2-Trichloroethane1 BenzeneI trans-1 e 3 -Dichloropropene _JBromofara :I 4-Methyl-2-Pentanone1 2-Kexanone1 Tetrachloroethene11,1,2,2-Tetrachloroethane _J[Toluene '1 Chlorobenzene i1 Ethylbenzene *IStyrene[Xylene (total)1 - - - - - "— - ————————————[Toluene-dS1 Bromof luorobenzenei 1 , 2-Dichloroethane-d4I

t 11 1* 11 11 1

6* 21 34

* 31(

t1

1

'

t* 1t I*

111

—— t'.4301.8961.867].433|.864|.564!.918|.099|.660].043!-230|.988|<L" ,>J. 0451Tisfl.438).800|.5421.4331.124|.374].545|.499].440].4921.372|.334|.2011.319|.540|.035|.000|.5361.1521.731|

.3491

.602|

.872]I

1.1.1.1.1..

6.1.3.3.3.1.(\.»...•

.

.1.•

.

.

.•

•.

1.•

1..

1.

—— I-2631994)681|5091772|469!565|995|474|780|178|3Z8|Q3$\T87|444|599|515|419|987|360|504|459(3571429!322]357]171 1321!4631981|9741436)04716751

389!577[904]

I

115105516555618152._!(25T312378512136

15

1452997

241

.6

.2

.0

.3

.0

.7

.1

.0

.1

.5

.6

.0

.8

.3-frT.1.1.8.5.0.3.8.5.3.3.5.4.3.6-2.0.6

,9.2.7

*1*ii*i1*

)*

FORM VII VGA . 1/87 ReflR303002 " *m<

r63

SEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: IEA - •*- ' 'Contract: 68-W8-0045

Lab Code: IEA Case No.s 12544 SAS~No.: ' SDG No.: CCHOO

Instrument ID: EXTR4 Calibration Date(s): 8/25/89 8/25/89

Mia RRF for SPCC(f) = .050 \ Max %RSD for CCC(*J = 30

LAS FILE ID: RRF20 = 0825402 RRF50 = 0825403 [RRF80 = 0825404 RRF120= 0825405 ._ „. _RRF16Q= 0825401 1

COMPOUND

' Phenol______________bis(2-Chloroethyl)ether2-Chlorophenoli1,3-Dichlorobenzene1,4-DichlorobenseneBenzyl alcohol1,2-Dichlorobenzene2-Methylphenol_bis (2-Chloroisopropyl) ether4-Methylphenol| N-Nitroso-di-n-propylamine_I Hexachloroethane_; Nitrobenzene___~ilsophorone2-Nitrophenol ___

! 2,4-Dimethylphenol_Benzoic acid| bis (2-Chloroethoxy) methane_j 2,4-Dichlorophenol____[1,2,4-Trichlorobenzene(Naphthalene

i I 1 I I __ I %RRF20 IRRF50 |RRF80 |RJRF120 [RRF1601 RRF [ RS

_4-Chloroaniline __[Hexachlorobutadiene __|4-Chloro-3-methylphenolj 2-Methylnaphthalene _ _1 Hexachlorocyclopentadiene __12,4,6-Trichlorophenol - *[2,4,5-Trichlorophenolj2-Chloronaphthalenej 2-Nitroaniline__1 Dime thy Iphthalate| Acenaphthylene2,6-Dinitrotoluene13-Nitroaniline1Acenaphthene2,4-Dinitrophenol4-Nitrophenol ___

1.4921 12.3231 2.352

&R303003FORM VI SV-1 M 1/87 K

6CSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: IEA . Contract: 6S-W8-0045

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHO<

Instrument ID: EXTR4 Calibration Date(s): 8/25/89 8/25/39

Min RRF for SPCC(S) = .050 Max %RSD for CCC(*) = 3C

;LAB FILE ID: RRF20 = 0325402 RRTSQ - 0325403i'RRFSO = 0825404 RRF120= 0825405 RRF160= 0825401

COMPOUND 1RRF20 (RRF50 (RRF80 [RRF1201RRF160

; DibenzofuranI 214-Dinitrotoluene_j Diethylphthalate4-Chlorophenyl-phenylether_IFluorene______________| 4-Nitroaniline__________j 4/6-Dinitro-2-methylphenol_j N-Nitrosodiphenylamine (1) _j 4-Bromophenyl-phenylether _j Hexachlorobenzene _______I Pentachlorophenol _______;j Phenanthrene____________j Anthracene______________JDi-n-butylphthalate _____j Fluoranthene____________•j Pyrene_________________I Butylbenzylphthalate_____j 3 f 3 ' -Dichlorobenzidine____j Benzo(a)anthracene_______j Chrysene_______________j bis (2-Ethylhexyl) phthalate_JDi-n-octylphthalate _____:j Benzo (b) f luoranthene_____Benzo(k)fluoranthene_____| Benzo (a) pyrene__________* 1.713 1Indeno (1,2,3 -[Dibenz(a,h)anthracene[ Benzo(g,h,i)perylene

JNitrobenzene-d5 ___j 2-Fluorobiphenyl___JTerphenyl-dl4 _____IPhenol-dS ________I 2-Fluorophenol_____[2,4,6^-Tribromophenol

1.9731 1.740.460[

1.3111.8831

1.7031

.705)

.3321

.3321

1,572]1.464]1.441]1.628]1.570].5501.4601

1.50611.4071 1.334).721] .865]

1.37511.86911.902)

834]268]

1.7251.763

1.8291.473)1.564) 1.7631 1.5661 1.3481 1.3691 1.522] 11

.491] .4661 -369| .3751 .3851 .4171 131.6191 1.4011 1.2971 1.1781 1.087] 1.3161 15.988] 1.0251 .9171 .8711 -873) .9351 7

2.504] 2.5681 1.9841 2.099) 2.014) 2.2341 121.955) 1.904] 1.5471 1.6421 1.560| 1.722] 11.335] .2791 -266) .223) .2221 .265) 17

(1) Cannot be separated from_Diphenylamine

FORM VI SV-2 1/87 F

AR3Q3QQU

735EHIVOIATJLE CONTINUING CALIBRATION CHECK


Lab Code: IEA Case No:: J.2544 iSAS No.: SDG No.: CCHOO

Instrument ID: EXTR4 • Calibration Date: 8/28/89 Time: 8:27

Lab File ID: 0823401 ; Init. Calib. Date(s): 8/25/89 8/25/89

Min RRF50 for SPCC(i) = .050 ^ Max %D for CCC(*J is 2

I .. . I1 COMPOUND __ ..._J_

I Phenol *i bis (2-Chloroethyl) ether __ 11 2-Chlorophenol 111,3 -Dichlorobensene [1 1 , 4-Dichlorobensene *I Benzyl alcohol ._._[i 1 , 2 -Dichlorobenzene „ 11 2-Methylphenol 1I bis ( 2-Chloroisopropyl ) ether |1 4-Methylphenol . 1I N-Nitroso-dirn-propylamine^fI Hexachloroethane . 11 Nitrobenzene 1llsophorone |I 2-Nitrophenol *[ 2 , 4-Dimethylphenol 1IBenzoic acid ' 11 bis ( 2-Chloroethoxy } methane_ |j 2 , 4-Dichlorophenol *1 1 , 2 , 4-Trichldrobenzene I1 Naphthalene - - 11 4-Chloroaniline 1j Hexachlorobutadiene *I 4-Chloro-3-methylphenol __ *1 2-Methylnaphthalene 1IHexachlorocyclopentadiene _#12,4, 6-Trichlorophenol - *12,4, 5-Trichlorophenol 11 2-Chloronaphthalene 1I 2-Nitroaniline I1 Dimethylphthalate 11 Acenaohthvlene 11 2 , 6-Dinitrotoluene 11 3 -Nitroaniline 1I Acenaphthene *1 2 , 4-Dinitroohenol #1 4-Nitrophenol #1 I

.RRF ...

2.4881.8551.7751.7141.7361.1671.6441.7551.9881.8531.201.689.367.731.270.355.230.554.375.364

1.157.534..188.336.773.309.437.465

1.114.3351.2781.854.319.417

1.020.198.126

1 1IRRF50 I

I 2.9481| 2.440]| 2.317]I 2.032]I 1.984!1 1.392]| 2.04811 2.1611I 2.1311I 2.2361[ 1.501[! -897!1 -42911 -851!1 -271]i -363]1 .219]1 -622]1 -4101I .3921| 1.26911 -53111 -19211 -413]I .854]I -309|1 .467[1 -5401| 1.22511 -3961| 1.4061[ 1.97911 -34311 - 477 1I 1.1961| ,20211 .13911 1

%D

18.5 *

§S518.514.3 *19.324.623.17.2

20.62^0 :

16.89.0.3 *2.14.7

12.49.2 *7.89.8S.82.3 *

22.7 *10.4 I

.2 %6.8 *

15.99.9

18.210.06.77.614.417.3 *1.9 *

10.4 J

CC14

FORM VII SV-1 1/87

- : SR303005 ''•

7C- SSMIVOLATILE CONTINUING CALIBRATION CHECK


Lab Code: IEA Case No.: 12544 SAS No.: SDG'No.: CCHOO fc

Instrument ID: EXTR4 Calibration Date: 8/23/89 Time: 8:27


Min RRF50 for SPCC(t) = .050 , Max %D for CCC(*) is

COMPOUND

[Dibenzofuran____________I 2,4-Dinitrotoluene_______i Diethylphthalate________, 4-Chlorophenyl-phenylether_,Fluorene[4-Nitroaniline__________I 4,6-Dinitro-2-methylphenol_I N-Nitroscdiphenylamine (1) _I4-Bromophenyl-phenylather _Hexachlorobenzene

RRF IRRF50 | %D

1.612] 1.753] 9.1.403) .489) 21.3

1.163) 1.389) 19.4.6721 .7411 10.1

1.3371 1.4361 7.4.400) .418) 4.5.1821 .1791 1.9.594! .6401 7.8.270] .2821 4.7.280! .290! 3.4

|Pentachlorophenol _______* .1851 .1791 3.4IPhenanthrene ________1 1.1921 1.261] 5.8[Anthracene______________1 1.1701 1.3141 12.3IDi-n-butvlphthalate _____1 1.250) 1.433] 14.71 Fluoranthene____________* 1.316) 1.495] 13.6 *| Pyrene_________________] 1.410] 1.433] 5.2Butylbenzylphthalate3,3' -DichlorobenzidineBenzo ( a) anthraceneChrysenebis ( 2-Ethylhexyl ) phthalate_Di-n-octylphthalateBenzo (b) fluorantheneBenzo ( k} fluorantheneBenzo ( a 5 pyrene *Indeno (1,2,3 -cd ) pyreneDibenz ( a , h ) anthraceneBenzo ( g,h, i ) perylene

Nitrobenzene-d52 -F luorobipheny 1Terphenyl-dl4I?henol-d52-Fluoroohenol2,4, 6-Tribromophenol

11

* 111

k 1111

1

21

.578)

.456]

.339)

.229]

.761)

.465]

.693)

.581]

.580)

.604]

.462)

.522]

.417)

.316]

.935)

.2341

.7221

.26511

.

.1.1.1.1.1.1.1.1.1.1.

*1.1.2.1.•

678498535384045790849914711941600|499

480)4091043|822]998!270|

1

17.49.314.712.6

<J7-A>22718.921.18.321.09.41.5

15.17.111.6(2T6 . 3)rSTD1.9

(1) Cannot be separated from Diphenylamine

S&IK

C C i-fo-i f"-

FORM VII SV-2 ' 1/87 I

AR3Q30Q6 '

r . i:. 7B . _i:.v:: ../"SEHIVOIAXILS CONTINUING CALIBRATION. CHECK


Lab Code: IEA Case No.::,12544. *.SAS No.: SDG'No.: CCHOO

Instrument ID: EXTR4 Calibration Date: 9/ 1/89 Time: 9:48

Lab File ID: 0901401 - Init. Calib. Date(s): 8/25/39 8/25/89

Min RRF50 for SPCCU) = .050 .. Max %D for CCC(*) is 2

$ 5//CCcc

1 . . . . . . . 11 COMPOUND . |

- , — lI Phenol *I bis (2-Chloroethyl) ether __ )I 2-Chlorophenol I1 1 , 3-Dichlorobenzene . . . . 11 1 , 4 -Dichlorobenzene *[Benzyl alcohol 11 1,2-Dichlorobenzene _.._.__. __i1 2-Methylphenol .\\ bis ( 2-Chloroisopropyl ) ether )1 4-Methylphenol 1( N-Nitroso-di-n-propylamine_j1 Hexachloroethane 1[Nitrobenzene —— |1 Isophorone 11 2-Nitrophenol *[2,4 -Dimethylpheriol 1[Berizoic acid jj bis ( 2 -Chloroethoxy ) methane_ j1 2 , 4-Dichlorophenol - *11,2, 4-Trichlorobenzene 11 Naphthalene 11 4-Chloroaniline 11 Hexachlorobutadiene *[4-Chloro-3-methylphenol __ *I 2-Methylnaphthalene 1(Hexachlorocyclopentadiene __#12,4, 6-Trichlorophenol *I 2,4,5-Trichlorophenol 1I 2-Chloronaphthalene [I 2-Nitroaniline 1I Dimethylphthalate _. 11 Acenaphthylene 11 2 , 6-Dinitrotoluene 1I 3-Nitroaniline _ 1I Acenaphthene - •• *\ 2 , 4-Dinitrophenol %1 4-Nitrophenol iI 1

RRF

2.4881.8551.7751.7141.7361.1671.6441.7551.9881.8531.201.639.367.781.270.355.230.554.375.364

1.157.534.188.336.773.309.437.465

1.114.335

1.2781.854.319.417

1.020.198.126

i 1[RRF50 1

I 2.537|i 1.86011 1,750)1 1.621]I 1.557|| 1.134!| 1.462]I 1.672]i 2.364)i 1.664!] 1.2361| .660(| .38S|1 -764]1 -2391i -35111 .243]1 .523]1 -31311 -31511 1.045]I .44511 -16911 .33211 .6701I -257|1 -4351

.46011.0981.453] <

| 1.334]1.854|.2931.3211.9971.122] <•161|<

1

%D

2.0.31.45.410.32.811.04.718.910.22.94.25.62.211.51.25.95.616.513.49.616.69.91.213.416.6.4

1.11.455JP4.4.0

8.323.12.3sm2¥.rj•" — —

1

A

•

*

3

**

1*

**i

FORM VII SV-1 1/87

flRSQSOQ? "•

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK.


Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO I

Instrument ID: EXTR4 Calibration Date: 9/ 1/89 Time: 9:48


Min RRF50 for SPCC(S) = .050 • Max %D for CCC(*) is 2

11 COMPOUND

IDibenzofuran1 2,4-Dinitrotoluene1 Diethylphthalate| 4-Chlorophenyl-phenylether_I FluoreneI 4-Nitroaniline| 4 r 6-Dinitro-2-methylphenol_j N-Nitrosodipheny lamine ( 1 ) _j 4 -Bromophenyl-pheny lather _I HexachlorobenzeneI Pentachlorophenol1 Phenanthrene1 Anthracene1 Di-n-butylphthalatej Fluoranthene "I PyreneI Butylbenzylphthalate13,3' -DichlorobenzidineI Benzo ( a ) anthracene1 Chrysene[ bis ( 2-Ethylhexyl ) phthalate_I Di-n-octylphthalate "*I Benzo (b) fluorantheneI Benzo ( k ) fluoranthene1 Benzo ( a) pyrene *1 Indeno (1,2,3 -cd ) pyr ene1 Dibenz ( a , h ) anthracene1 Benzo ( g , h , i ) pery lene

1 Nitrobenzene-d51 2-Fluorobiphenyl1 Terphenyl-dl41 Phenol-d51 2-Fluorophenol12,4, 6-Tribromophenol1

1 __RRF

; 1.612.403

1.163.672

1.337.400.182

* .594.270.230

* .1351.1921.1701.250

* 1.3161.410.578.456

1.3391.229.761

' 1.4651.6981.581

* 1.5801-6041.4621.522

.4171.316.9352.2341.722.265

1 t1RRF50 1t - — .— —— i -I- f1 1.55111 .42611 1.235]I -622)| 1.34011 .3641I .14111 .55311 .24311 -263!| .164]) 1.158]I 1.042]1 1.132]) 1.317)I 1.25311 .55411 .27911 1.23411 1.1251] .801|| 1.610]| 1.646)1 1.6851I 1.43211 1.57411 1.3111| 1.2851

1 .431]| 1.28611 .8551I 2.2351[ 1.564J1 .24211 1

%D

3.85.36.27.5.39.2

22.56.9 *3.06.211.5 *2.810.99.4.1 *

11.14J.

Cp78>/ . o8.45.49.9 *3.06.69.4 *1.910.315.6

3.42.38.6.0

9.28.9


cccc

FORM VII SV-2 1/87 E

flR303008 - "

63SEMIVOLATILE CRGAN1CS INITIAL , CALIBRATION DATA

Lab Name: IEA ... -= - --'Cohtr ct: 63-W8-0045

Lab Code: IEA l Case No.: 12544 SAS No.: , SDG No.: CCHOO

Instrument ID: EXTR4 Calibration Date(s) : 9/11/89 9/11/89

Min RRF for SPCC(S) = .050 Max %RSD for CCC(*) = 30

| LAS FILE ID: RRF20 = 0911402 RRF50 = 0911403 IIRRF30 = 0911404 RRF120= 0911405 RRF160= 0911401 1I _______________________________________________________________ I __1 I I I 1 1 I __ I %| COMPOUND . , |RRF20 |RRF50 [RRF30 [RRF120 |RRF160 | RRF | RS

IPhenol _________________ * 3.443) 2.7731 2.3811 2.447] 2.324] 2.6731 17|bis(2-Chloroethyl)ether _, _ 1 2.314] 2.169) 1.635) 1.6731 1.5991 1.8731 171 2-Chlorophenol __________ | 2.160) 1.8441 1.567] 1.559! 1.519) 1.7301 1511,3-Dichlorobenzene _____ | 1.984[ 1-720) 1.4001 1.468) 1.311] 1.5771 17|l,4-Dichlorobenzene _____ * 2.149] 1.828] 1.425] 1.467) 1.273) 1.630) 21[Benzyl alcohol _____ I 1.340| 1.155| .969| 1.009] .969| 1.089] 141 1,2-Dichlorobenzene _____ [ 1.9081 1.683J 1.3241 1.232] 1.2121 1.432] 2012-Methylphenol ________ | 2.135| 1.9911 1-5651 1.7051 1.597] 1.799] 14Ibis(2-Chloroisaprapyl)etheri 1.9111 2.438J 1.5271 1.4391 1.220] 1.707] 28|4-Methylphenol ___________ J 2.371] 1.854! 1,4561 1.645J 1.638] 1.7931 19|N-Nitroso-di-n-propylamine_# 1.497] 1.302] .9551 -9641 1.023] 1.1481 21[Hexachloroethane ____ I .769] .652) .571| .554) .558) .621) 14[Nitrobenzene ____________ 1 .426] .364] .343] .322] .3061 .3521 13[Isophorone ____________ _] .5151 .747] .724) ,649) .636[ .6541 13|2-Nitraphenol __________ * .2691 -2101 -226] .2201 .2031 .226] 1112,4-Dimethylphenol _____ __I .428) .337) .323] .2951 .3061 .3331 JJIBenzoic acid ________ _| _____ | .0611 -0861 .119] .2221 .122 1 (£8]bis(2-Chloroethoxy)methane_r .597] .499] .5091 .466] .4611 .5061 lU1 2,4-Dichlorophenol _______ * .354| .2941 -3031 .281| .2601 .2981 1111,2,4-Trichlorobenzene ____ | .386] .292) .287] .251] .246] .2921 IS[Naphthalene ____________ | 1.371] 1.057] 1.031] .8991 .935[ 1.0591 171 4-Chloroaniline _______ ___[ .6321 .505] .475) .4281 .429] .5041 201 Hexachlorobutadiene _____ * .185] .135] .137| ,126) .129) .143) 1714-Chloro-3-methylphenol __ * .3761 .2941 -274| .272] .275] .2931 14[2-Methylnaphthalene ____ _| .8401 -631| .533] .555) .552] .622] 20[Hexachlorocyclopentadiene _# .2561 .221] .219] .242) .238] .235] 6[2,4,6-Trichlorophenol ____ * .446] .388] .362J .3301 .3491 .3851 S12,4,5-Trichlorophenol ____ | ____ I .429[ .3831 .417) .375) .4011 6|2-Chloronaphthalene _____ |~1.272| 1-064) .957) .920] .891) 1.021) 15|2-Nitroaniline __________ | ____ I .3561 -3231 .328] .3131 .3301 5(Dimethylphthalate _______ f 1.265] 1.159| 1.033] .997| .950| 1.0811 11iAcenaphthylene __________ 1 1.972] 1.790] 1.545] 1.4531 1.4541 1.6431 14I 2 , 6-Dinitrotoluene _______ I . 313 1 . 285 | . 245 ] . 237 1 . 247 ] . 265 | 12|3-Nitroaniline __________ I ____ I .397] .3631 -342] .3531 .364] 6(Acenaphthene _____________ *~1.154[ ,980( .893] .798] .8041 -9261 15[2,4-Dinitrophenol _______ # _____ 1 .0871 .120] .1491 .168] .1311 27[4-Nitrophenol __________ $ _____ | .071! -1031 .108] .133| .1041 24

QRR3030099'n

6CSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: IEA Contract: 63-W8-Q045

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOi

Instrument: ID: EXTR4 Calibration Date(s): 9/11/89 9/11/89

Min HRF for SPCC(i) = .050 Max %RSD for CCC(*) = 30

O | LAB FILE ID: RRF2Q = 0911402 : RRF50 = 0911403 I1RRF80 « 0911404 RRF120= 0911405 RRF160= 0911401 ]

O

11 COMPOUND

I Dibenzofuran1 2 , 4-Dinitrotoluene! Diethylphthalatej 4-Chlorophenyl-phenylether_IFluorene1 4-NitroanilineI 4 , 6-Dinitro-2-methylphenol1 N-Nitrosodiphenylamine ( 1 ) _j 4-Brcmophenyl-phenylether _1 Hexachlorobenzene| PentachloroohenolI PhenanthreneI Anthracene1 Di-n-butylphtihalateI Fluoranthene1 Pyrene1 Butylbenzylphthalate1 3 , 3 ' -Dichlorobenzidine1 Benzo ( a ) anthracene1 Chrysene| bis ( 2-Ethylhexyl ) phthalate_I Di-n-octylphthalate "1 Benzo ( b ) fluoranthene1 Benzo ( k) fluoranthene1 Benzo ( a ) pyr ene *1 Indeno (1,2,3 -cd) pyrene1 Dibenz ( a , h ) anthracenej Benzo ( g , h , i ) peryleneI . . - -- — . ,.-. ..... _.__.. .._1 Nitrobenzene-d51 2-FluorobiphenylJTerphenyl-dl4IPhenol-d5[ 2-Fluorophenol[2,4, 6-Tribroraophenol1

RRf

1..

1.

i!IT

lr

1.1.1.

* 1.1...

1.1.

i!i.i.i.i.i.i.9

i..3.2..

'20

744403080769426

693297301

340375208407331500419389236678420306985603592256319

037623870111304227

1IRR! ——il illll illlilli il il il il iill il ill il il il il il il ill il1 2i 2| •1

FSO

.528

.377

.992

.646

.265

.374

.124

.625

.274

.271

.105

.147

.225

.120

.215

.169

.454

.354]

.058)

.121]

.615)

.325

.6511

.6701

.449

.321]

.196]

.123]

.409]

.264]

.8071,475|.1911.2221

I

RRF80

1.197.357.963.615

1.122.365.152.561.249.253.116

1.0271.0701.0411.0691.097.470.3471.1001.083.678

1.4331.5091.7621.5101.4461.2371.238

.3891.100.783

2.0911.564.201

1IRRjss-1 l11111I11111 i1 i1 l1 i1 iiI1 i1 iI1 l1 i1 i1 i1 i1 i1 i11 iII 2i 111

F

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.

.••

.

.•*..

120

193293837536955320167642264231166124125124163170474370130012624537533584487383305054

381149855063594199

11RRF160

| 1.2871 .3261 .8891 .5451 1.0561 .353I .167I .5421 .235I .2471 .1861 .983| 1.001I 1.046| 1.008| 1.092) .486| .389| 1.109I 1.0281 .6201 1.4581 1.329) 1.5391 1.4181 .8361 .9401 .512

1 .369| 1.052I .756| 2.010| 1.481| .2011

_.5

1....

1..•«-..

1.1.1.1.1.

«

•

I-

1

•

1

1-

1

I-

1

1

1

1

21 11

ISF I RS

3901 173511 129531 96221 151651 153531 €152] 13613) 102641 82711 S.1431 27,1241 12,153 12.ioM e.17ZT13,1721 8477] 3376) 7157] 11,096[ 8,643| 5,4451 6.5761 11,708| 10.494] 4.326] 20.1871 12.049] (30

.317[ 49

.2391 18

.8141 5

.351! 19

.8271 21

.2101 61

(1) Cannot be separated from Diphenylaraine

FORM VI SV-2 .1/87 B

flR3030IO

i 7BSEMXVCLATILE CONTINUING CALIBRATION CHECK

Lab Name: IEA . __ ( .' ^pntract: 63-W8-0045

Lab Code: IEA Case No.: 12544 SAS No. : SDG No.: CCHOO

Instrument ID: EXTR4 - Calibration Date: 9/11/89 Time: 23:37

Lab File ID: 0911D01 Init. Calib. Date(s)? 9/11/89 9/11/89

Min RRF50 for SPCC(i) = .050 ' Max %D for CCC(*J is 2

iCOMPOUND

;Phenol______________: bis (2-Chioroethyl) ether2-Chloropheno1i1,3-Dichlorobenzene,1,4-DichlorobenzeneBenzyl alcohol1,2-Dichlorobenzene2-Methylphenol

I bis ( 2-Chloroisopropyl ) etherI 4-Methylghenbl_ ____I N-Nitroso-di-n-propylamine__i 1I Hexachloroe thane(NitrobenzeneI Isophorone ________I 2 -Nitr opheno 1; 2 , 4-DimethylpheriolBenzoic acid[ bis (2 -Chloroethoxy} methane_I 2,4-Dichlorophenol_______*11,2,4-Trichlorobenzene[Naphthalene|4-Chloroaniline.Hexachlorobutadiene; 4-Chloro-3-methylphenol2 -MethylnaphthaleneIHexachlorocyclopentadiene _jI 2,4,6-Trichlorophenol ____*I 2p4,5-Trichl6rophenolI 2-ChloronaphthaleneI 2-NitroanilineJDimethylphthalateI Acenaphthylene_I 2,6-Dinitrotoluene^13-Nitroaniline1Acenaphthene^2,4-Dinitrophenol4-Nitrophenol .

-274|.375

1.009].104.125

FORM VII SV-1 n n, n n o o I I i/87-; - i -:- flRSOoU I l

7CSEMIVCLATILE CONTINUING CALIBRATION CHECK

Lab Name: IEA Contract: 68-WS-0045


Instrument ID: EXTR4 Calibration Date: 9/11/39 Time: 23:37

Lab File ID: 0911D01 Init. Calib. Date(s): 9/11/89 9/11/89

Min RRF50 for S2CC(S) = .050 - Max %D for CCC(*) is 2

11 COMPOUND

1 DibenzofuranI 2 , 4-Dinitrotoluene1 Diethylphthalate1 4-Chlorophenyl-phenylether_1 FluoreneI 4-NitroanilineI 4,6-Dinitro-2-methylphenol_j N-Ni troscdiphenylamine ( 1 ) _>! 4-3rcmophenyl-phenylether _I Hexachlorobenzene1 Pentachlcrophenol 5! Phenanthrenei Anthracene1 Di-n-butylphthalate1 Fluoranthene '1 Pyrene1 Butylbenzylphthalate13,3' -Dichlorobenzidine1 Benzo ( a } anthracene1 Chrysene1 bis ( 2-Ethylhexyl ) phthalate_1 Di-n-octylphthalate *1 Benzo ( b } fluoranthene1 Benzo ( k) fluoranthene1 Benzo ( a ) pyrene *1 Indeno {1,2,3 -cd } pyr eneI Dibenz ( a ,h) anthracene1 Benzo ( g , h , i ) perylene1 ^ '—— — — — -1 Nitrobenzene-d51 2-FluorobiphenylI Terphenvl-dl4IPhenol-d51 2-Fluorophenol12,4, 6-Tribromophenol1

RRF

1.390.351.953.622

1.165.353.152

* .613.264.271

* .1431.1241.1591.108

* 1.1721.172.477.376

1.1571.096.643

* 1.4451.5761.708

" 1.4941,3261.1871.049

.3171.239.814

2.3511.827.210

1IRRF50

| 1.492[ .3841 1.1531 .6041 1.2951 .4251 .140I .619I .2401 .239I .112I 1.153I 1.2221 1.230I 1.2391 1.279| .594I .4321 1.2461 1.2221 .836I 1.663I 1.602I 1.869I 1.4731 1.373I 1.1341 1.198

1 .4291 1.1721 .8441 2.343I 2.1891 .188I

11 %D

1 7.4I 9.31 20.91 2.91 11.11 20.21 8.01 1.0 *1 9-1I 11.7| 21.9 *1 2.6I 5.4I 11.11 5.7 *1 9.2] 24.5] 15.11 7.71 i-L_JI (29.J>1 1571 *| 1.61 9.41 1.1 *1 3.61 4.5) 14.2

1 <5C£>1 5.41 3.61 -31 19.8I 10.31


FORM VII SV-2 . 1/87 !

flR3030i2

3AWATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: IEA - .._ , £aixtract: 6E-W8-0045


Matrix Spike - EPA Sample No.: CCH03

COMPOUND

1 , 1-DichloroetheneTrichloroetheneBenzeneTolueneChlorobenzene

| SPIKE1 ADDEDI (UG/L )

= 1 ———————J 250.| 250.I 250.I 250.I 250.j

1 SAMPLEI CONCENTRATION1 (UG/L )

•1 —— • —————————1 o.i o.1 o.1 o.I o.

MS | MSCONCENTRATION 1 %- (UG/L ) ] REC

194.337.299.236.343.

— i ———U7-3—ft351120.

i<uzL-

1 QCILIMI#1 ESC

.161-1£[71-1|76-1176-1

*>[75-lI

COMPOUND

1 , 1-Dichloroethene ___TrichloroetheneBenzeneTolueneChlorobenzene

| SPIKE| ADDED1 (UG/L )

= | ————————I 250.

"l 250.1 250.| 250.| 250.i

I MSDI CONCENTRATION[ (UG/L )

1 203.I 342.I 315.| 299.1 350. |1

MSD |% j %

REC #| RPD_ ——— _ — i ————————— i ————81 1 4.<U?T3>| 2.126. [ 5.

<HH1 1*\i*« V . Jf £• .

1

11 QC

II RPD= 1 =

I 141 141 111 131 131

LIMITS| REC

|61-1|71-1176-1176-1175-11

$ Column to be used to flag recovery ,and RPD values with an asterisk

* Values outside of QC limits

RPD: 0 out of 5 outside limitsSpike Recovery: 4 out of 10 outside limits,

COMMENTS: , . . .... -

FORM III VOA-1 1/87 Re

BR3030I3

2CWATER SEMIVOLATILE SURROGATE RECOVERY


Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOQl

| EPA1 SAMPLE NO.

11SBLK7921S3LK8331S3LK8941CCH0251CCH036ICCH03MS71CCH03MSD81 CCHOO9|CCH0110IS3LK93111CCK05121CCH0613114115116117118]19120121122123]24125126]27)28]29130]

SI t S2(NB2)*l(FBP)|

63 1 6574 1 7770 1 7050 1 5559 1 6761 I 64

. 66 I 6889 | 8578 1 8062 1 6163 1 6683 1 77

ii1111111IIii11i !i11

S3(TPH)S

637367624342438991367970

,

S4(PHL)S

575159505341402316753926

l S5(2FP)#

5949605148233*-(13 *)Ctr 5763322

| S6;(Tsp)#61585554

[ 6451532414633728

.OTHER

Mii

TOou000c0001100c

*

QC LIMITSSI (NB2) = Nitrobensene-d5 (35-114)S2 (FBP) = 2-Fluorobiphenyl (43-116)S3 (TPK) = Terphenyl-dl4 (33-141)S4 (PHL) = Phenol-d5 (10- 94)S5 (2FP) = 2-Fluorophenol (21-100)S6 (TBP) = 2r4,6-Tribromophenol (10-123)

S Column to be used to flag recovery values

* Values outside of contract required QC limits

D Surrogates diluted out •

page 1 of 1FORM II SV-1 1/87

D P* o o o n r iARJ030 1 k

• " 3C - ' • : - - -

WATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: IEA - -^Contract: 68-W8-0045

Lab Code: IEA Case No.: 12544 SAS No.: . SDG No.: CCHOO

Matrix Spike - EPA Sample No.: CCH03

i:l

COMPOUND [

Phenol : 12-Chlorophenol [1,4-Dichlorobenzene , IN-Nitroso-di-n-prop.'d) |1,2, 4-Trichlorobenzene |4-Chloro-3-methylphenollAcenaphthene I4-Nitrophenol j2 , 4-Dinitrotaluene |Pentachlorophenol |Pyrene . . I

1

SPIKEADDED(UG/L )

200.200.100.100.100.200.100.200.'100.200.100.

SAMPLECONCENTRATION

(UG/L )

72.0.0.0.0.0.0.0.0.0.0.

MS |CONCENTRATION]

(UG/L ) i_ — —— _ — — ——— . j161. I78. [47. 162. 155. 1

107. |64. |74. |67, 184. 168. |

1

MS%

REC

45.39.47.62.55.53.64.37.67.42.68.

1 CILKII R-T112-127-(36-141-139-123-|46-1 10-124-1 9-126-1

i ii - i| COMPOUND |

_-. ——— „ ^ K_, ._ _^ |

I Phenol II 2-Chlorophenol 1j 1,4-Dichlorobensene __ 1j N-Nitroso-di-n-prop. (1) |I 1,2, 4-Trichlorobenzene_ j1 4-Chloro-3-methylphenol |j Acenaphthene II 4-Nitrophenol 1[ 2 , 4-Dinitrotoluene 1j Pentachlorophenol I1 Pyrene 11 1

SPIKEADDED(UG/L )

200.200.100.100.100.200.100.200.100.200.100.

MSDCONCENTRATION

(UG/L )

196.91.55.59.58.113.66.124.70.114.66.

MSD%REC *

62.46.55. .59.58.56.66 .62.70.57.66.

%RPD i

33.15.15.5.5.5.2.

C50. i5.30.3.

QCRPD

42402838234231

F 5 0385031

LIMI:1 w112-|27-|36-|41-139-123-146-110-124-1 9-126-1

(1) N-Nitroso-di-n-propylamine

i Column to be used to flag recovery and RPD values with an asterisk

* Values outside of QC limits

RPD: 1 out of 11 outside limitsSpike Recovery: 0 out of 22 outside limits

•COMMENTS: , ... , - :

FORM III SV-1

ftR3030S5

1A EPA SAMPLE. NOVOLATILE CRGANICS ANALYSIS DATA SHEET

I| VBLK01

Lab Name: IEA . Contract: 63-W8-OQ45 j_______




Level: (low/med) LOW Date Received: O/ O/ 0

% Moisture: not dec,100. Date Analyzed: 8/22/89

Column: (pack/cap) CAP Dilution Factor: 1-00


74-87-3—————Chlorcmethane _________74-83-9—————Bromcmethane____________75-01-4—————Vinyl Chloride_________75-00-3—————Chloroethane____________75-09-2—————Hethylene Chloride______67-64-1—————Acetone ______________75-15-0—————Carbon Disulfide________75-35-4—————1,1-Dichloroethene______75-34-3—————1,1-Dichloroethane______540-59-0—————1,2-Dichloroethene (total).67-66-3—————Chloroform_____________'107-06-2—————l,2-Dichloroethane___78-93-3—————2-3utanone_________71-55-6—————1,1,1-Trichloroethane56-23-5—————Carbon Tetrachloride_108-05-4—————Vinyl Acetate ______75-27-4—————3romodichloromethane_78-37-5—————1,2-Dichloropropane

10061-01-5—————cis-1,3-Dichloropropene79-01-6—————Trichloroethene ___..___124-48-1—————Dibromochloromethane__79-00-5—————3. f 112-Trichloroethane71-43-2—————Benzene .__________

10061-02-6—————trans-l,3-Dichloropropene75-25-2—————Bromoform ____________108-10-1—————4-Methyl-2-Pencanone____591-78-6—————2-Hexanone____________127-18-4—————Tetrachloroethene ______79-34-5—————1,1,2,2-Tetrachloroethane108-88-3—————Toluene _______________108-90-7—————Chlorobenzene _________100-41-4—————Ethylbenzene__________100-42-5—————Styrene ______________1330-20-7—————Xylene (total)_________

10. [U10. |U10. [U10. IU5. IU12. |5. IU5. )U5. IU5. IU5. [U5. |U10. (U5. [U5. IU10. IU5. IU5. IU5. ]U5. |U5. IU5. )U5. [U5. [U5. |U10. |U10. IU5. IU5. IU5. IU5. IU5. IU5. |U5. IU

FORM I VOAfi R 3 0 3 0 1 6 ' 1/87 R

V/3-

IE i E5A SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SEEST ____________TENTATIVELY IDENTIFIED COMPOUNDS I

I VBLK01Lab Name: IEA Contract: 68-W8-0045 [

Lab Code: IEA Case No".: 12544 . VSAS No.: SDG No.: CCHQO

Matrix: (soil/water) WATER : Lab Sample ID:

Sample wt/vol: 5. (g/inL) ML . Lab File ID: 0822302

Level: (low/med) LOW - Date Received: O/ O/ 0

% Moisture: not dec.100. - Date Analyzed: 8/22/89

Column: (pack/cap) CAP _ __ Dilution Factor:. . 1.00

CONCENTRATION UNITS:Number TICs found: Q (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.D.6.7.3.9.10.11.12.13.14.15.16.17.18,19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

,

.

1RT | EST. CONC.

, ,!111

11111111111111111111I1111I

Q

FORM I ypA-TIC. 1/87 Re

' fl"R3Q3QI7

1A EEA SAMPLE NOVOLATILE CRGANICS ANALYSIS DATA SHEET ________

II' VBLK02

Lab Name: IEA . Contract: 63-W8-0045 j_______

Lab Code: IEA Case No.: 12544 SAS No.: " SDG No.: CCHQO


Sample wt/vol: 5. (g/mL) ML ' Lab File ID: 0831302

Level: (low/med) LCW Date Received: 0/0/0.

% Moisture: not dec. 100. Date Analyzed: 8/31/89


CONCENTRATION UNITS:CAS NO, COMPOUND (ug/L or ug/Kg) UG/L Q

C

74-37-3—————Chlorcmethane __________74-83-9—————Bromome thane___________75-01-4—————Vinyl Chloride_________75-00-3—————Chloroerhane____________75-09-2—————Methylene Chloride______67-64-1—————Acetone ______________75-15-0—————Carbon Disulfide________75-35-4—————1,1-Dichlorcethene______75-34-3—————1,1-Dichloroethane______540-59-0—————1,2-Dichloroethene (total).67-66-3—————Chloroform____________'107-06-2——>———1,2-Dichloroethane______78-93-3—————2-Butanone. _....._.. ______71-55-6—-*~—>~1,1,1-Trichloroethane ___56-23-5—————Carbon Tetrachlaride____108-05-4—————Vinyl Acetate _________75-27-4—————Bromcdichlorome thane____78-87-5—————1,2-Dichloropropane

10061-01-5—————cis-1,3-Dichloropropene79-01-6—————Trichloroethene124-48-1—————Dibromochloromethane_79-00-5—————1,1,2-Trichloroethane71-43-2—————Benzene

[10061-02-6—————trans-1,3-Dichloropropene _75-25-2—————Bromoform

O | 108-10-1—--——4-Methyl-2-Pentanone591-78-6—————2-Hexanone______________127-18-4—————Tetrachloroethene ________79-34-5—————1,1,2,2-Tetrachloroethane _108-88-3—————Toluene _________________108-90-7—————Chlorofaenzene ___________100-41-4—————Ethylbenzene______________100-42-5—————Styrene _________________1330-20-7————Xylene (total)__________

10. IU10. |U10. |U10. |U5. |U

11* 15. IU5. )U5. | XT5. |U5. IU5. | XT10. )U5. |U5. |U10. | XT5. IU5. IU5. IU5, IU5. IU5. IU5. [U5. |U5. IU10. IU10. IU5. IU5. IU5, IU5. IU5. IU5. IU5- |U

BR30^FORM I VOA R SI O U o w i w 1/87

IE EPA SAMPLE NO.VOLATILE CRGANICS ANALYSIS DATA SHEET m____________TENTATIVELY IDENTIFIED COMPOUNDS [-

. - , . I VBLK02Lab Name: IEA Contract: 68-W8-0045 |



Sample wt/vol: 5. (g/znL) ML 4 Lab File ID: 0831302

Level: (low/med) LOW . T "" Date Received: O/ O/ 0

% Moisture: not dec.100. ;_ Date Analysed: 8/31/89

Column: (pack/cap) CAP . . . . ;_ Dilution Factor: 1.00


CAS NUMBER

1.2.3.4.5.6.7.3.9.10.11.12.13.14.15.16.17.18.19.20.21.22.

[ 23.; 24.25.26.27.28.29.30.

.COMPOUND NAME

— • -- - ' -

•

,

RT EST. CONC.

i

i

Q

-

FORM I VOA-TIC 1/87

AR3030l<?

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ____________

j CCHQ3MSLab Name: IEA . Contract: 63-W8-QQ45 I_______

i Lab Code: IEA Case No.: 12544 SAS No.: SDG No-: CCHOO3


O Sample wt/vol: 5. (g/mL) ML • Lab File ID: 0822310



^ Column: (pack/cap) CAP Dilution Factor: 1.00

CONCENTRATION XJNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

O

ij 74-87-3 ————— Chloromethane1 74-83-9 ————— Bromomethane1 75-01-4 ————— Vinyl Chloride| 75-00-3 ————— Chloroethane| 1 «4 W — ' «• •-'•—I >_*i.J . >»«_.*•• 1_>**._.1_'_» f\ I|> il

W » W T ^ k *W *— «— JiJ,l—

75-15-0 ————— Carbon Disulfide75-35-4 ————— 1, 1-Dichloroethene75-34-3 ————— 1,1-Dichloroethane540-59-0 ————— 1,2-Dichloroethene (total) _67-66-3 ————— Chloroform107-06-2 ————— 1,2-Dichloroethane78-93-3 ————— 2-3utanone71-55-6 ————— 1 , 1 , 1-Trichloroethane56-23-5 ————— Carbon Tetrachloride

_W W W W _J i T B**_2 J« * * *— *— 1«* hat_>

75-27-4 ————— Bromodichloromethane78-87-5 ————— 1,2-Dichloropropane

10061-01-5 ————— cis-1, 3-Dichloropropene ___79-01-6 ————— Trichloroethene124-48-1 ————— Dibromochloromethane

10061-02-6 ————— trans-1, 3-Dichloropropene _75-25-2 ————— Bromoform

591-78-6 ————— 2-Hexanone127-18-4 ————— Tetrachloroethene79-34-5 ————— 1 ,1,2, 2-Tetrachlorbethane _

100-41-4 ————— Ethylbenzene100-42-5 ————— Styrene1330-20-7 ————— Xylene (total)

10.10.10.10.5.19.5.39.5.5.5.5.

180.5.5.10.5.5.5.67.5.5.

60-5.5.10.10.5.5.57.69.5.5.5.

1 \HI IIU Iiu 1iu liu lIB |IU J

Iu \\vIUiu1|UItriuiuiuiu1iu[U\iuiuiuiuiu|U1 ^1 1.IU 1iu 4iu 11 1

FOEHI VOA (\R303G20 ' 1/87

1A EPA SAMPLE NOVOLATILE ORGANICS ANALYSIS DATA SHEET _______._____: ; .- i——————'

I CCH03MSDLab Name: IEA m. * Contract: 63-W8-0045 |



Sample wt/vol: 5., (g/mL) ML , Lab File ID: 0822311


% Moisture: not dec.100. i - - ""Date Analyzed: 8/22/89

Column: (pack/cap) CAP , : ,. , Dilution Factor: 1.00


74-87-3—————Chloromethane ___74-83-9—————Sromome thane_____75-01-4—————Vinyl Chloride___75-00-3—————Chloroe-chane_____75-09-2—————Methylene Chloride^67-54-1—————Acetone ________*75-15-0—————Carbon Disulfide_75-35-4—————1,1-Dichloroethene75-34-3—————l,l-Dichloroethane-______540-59-0—————1,2-Dichloroethene {total)J67-66-3—————Chloroform107-06-2—————1,2-Dichloroethane__78-93-3—————2-Butanone_______.71-55-6—————1 f 1 f 1-Trichloroethane56-23-5—————Carbon Tetrachloride_108-05-4—————Vinyl Acetate .- - - -75-27-4—————3romodichloromethane_78-87-5—————1 r 2-Dichloropropane

10061-01-5—————cis-1,3-Dichloropropene ___79-01-6—————Trichloroethene124-48-1—————Dibromochloromethane^79-00-5—————1,1,2-Trichloroethane71-43-2—————Benzene

10061-02-6—————trans-1,3-Dichloropropene75-25-2—————Bromoform108-10-1—————4-Methyl-2-Pentanone_591-78-6—————2-Hexanone127-18-4—————Tetrachloroethene _____79-34-5—————1,1,2,2-Tetrachloroethane108-88-3—————Toluene __________'_'108-90-7—————Chlorobenzene _________100-41-4—————Ethylbenzene_________100-42-5—————Styrene ______________1330-20-7—————Xylene (total)_________

FORM I VOAflR30302

10. [U10. IU10. I XT10. | XT5. | XT

29. IB5. [U

41- I5. [U5. |U5. IU5. 1U

ISO. I5. IU5- |U10. |u5. IXT5- IXT5. |U

68. I5. [U5. |U

63. I5. |XT5. | XI

10. IXT10. IU5. |U5. IU

60. I70. I5. IXT5. .fU5. IUI

IB EPA SAMPLE NCSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I| SBLK79

Lab Name: IEA • Contract: 63-W8-0045 I_____







GPC Cleanup: (Y/N) N pK: 6.0 Dilution Factor: 1.00

CONCENTRATION XJNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol__________________111-44-4—————bis (2-Chloroethyl) ether ___95-57-8 ————— 2-Chlorophenol___________541-73-1————1,3-Dichlorobenzene ______106-46-7—————1, 4-Dichlorobenzene ______100-51-6—————Benzyl alcohol____________95-50-1—————1,2-Dichlorobenzene ______95-48-7 ————— 2-Methylphenol___________108-60-1—————bis (2-Chloroisopropyl) ether106-44-5 ————— 4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane_________98-95-3—————Nitrobenzene_____________78-59-1—————Isor>horone______________88-75-5—————2-Nitrophenol ___________105-67-9—————2,4-Dimethylphenol________65-85-0—————Benzoic acid____________111-91-1—————bis (2-Chloroethoxy) me thane_120-83-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene_____91-20-3—————Naphthalene ____________106-47-8 ————— 4-Chloroaniline _________87-68-3—————Hexachlorobutadiene ______59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4,6-Trichlorophenol ____95-95-4—————2,4,5-Trichlorophenol _____91-58-7—————2-Chloronaphthalene ______88-74-4—————2-Nitroaniline___________131-11-3—————Dime thy Iphthalate ________208-96-8—————Acenaphthylene^

1 606-20-2—————2,-6-Dinitrotoluene^

10. IU10. IU10. IU10. IU10. )U10. IU10. |U10. IU10. IU10. IU10. IU10. IU10. IU10. IU10. |U10. |U50. IU10. IU10, IU10, |U10. |U10. |U10. IU10. IU10. IU10. IU10. IU50. IU10. IU50. |U10. IU10. [U10. IU

FORM I SV-1 a p O ft 1 i}9 9 ' ' 1/87flnuuoucd. ^,.

r 1C " EPA SAMPLESSMIVOLATILI. ORGAN!CS ANALYSIS DATA SHEET

j S3LK79Lab Name: IEA Contract: 68-W8-0045

Lab Code: IEA Case No". :• 12544 ^. SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER Lab "Sample ID:



% Moisture: not dec.100. dec. 0. Eate Extracted: 8/18/89

Extraction: (SepF/Cont/Sonc) CONT \ _:__Date Analyzed: 8/28/89



99-09-2 ————— 3-Nitroaniline _____83-32-9—————Acenaphthene _____.51-28-5 ————— 2 r 4-Dinitrophenol ______100-02-7—————4-Nitrophenol _________132-54-9—————Dibenzofuran___________121-14-2 ————— 2,4-Dinitrotoluene - :___84-66-2————-Diethylphthalate________

7005-72-3 ————— 4-Chlorophenyl-phenylether86-73-7————-Fluorene_________;____[100-01-6—————4-Nitroaniline_________534-52-1—————4/6-Dinitro-2-methylphenol_8"6-30-6—————N-Nitrosodiphenylamine (1)~101-55-3 ————— 4-Bromophenyl-phenylether ~118-74-1—————Hexachlorobenzene ______"87-86-5—————Pentachlorophenol ... . . .85-01-8—————Shenanthrene___________120-12-7—————Anthracene_____________84-74-2—————Di-n-butylphthalate ____206-44-0—————Fluoranthene___________"129-00-0—————Pyrene____i___^_^______85-68-7—————Butylbenzylphthalate_____91-94-1—————3,3 '-Dichlorobenzidine___56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene______117-81-7—————bis(2-Ethylhexyl)phthalate117-84-0—————Di-n-octylphthalate ____"205-99-2—————Benzo (b) fluoranthene____~207-08-9—————Benzo (k) fluoranthene_____50-32-8—————Benzo (a)pyrene_____;_____~193-39-5—————Indeno (1,2,3-cd) pyrene___53-70-3—————Dibenzta,h)anthracene ___191-24-2—————Benzo (g,h,i)perylene_____

50. |U I10. |U I50. )U 150. IU 110. |U 110. |U 110. |U I10. |U 110. |U I50. IU I50. IU I10. |U 110. IU |10. |U I50. |U |10. IU 110. |U I10. IU 110. [U 110. (U I10. IU I20. IU 110. IU 110. [U 110. IU 110. IU I10. |U 110. |U 110. IU I10. IU 110. JU I10. IU I


FORM I SV-2 1/87 Ij : flR303023

O

IF EPA SAMPLESEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _________

TENTATIVELY IDENTIFIED COMPOUNDS 1I SBLK79


Lab Cade: IEA Case No,: 12544 SAS No.: SDG No.:

Matrix: (soil/water) WATER Lab'Sample ID:


Level: (low/rued) LOW • Date Received: 0/0/0



GPC Cleanup: (Y/NJ N pH: 6.0 Dilution Factor: 1.00

CONCENTRATION XJNITS:Number TICs found: 4 (ug/L or ug/Kg) UG/L

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

tI COMPOUND NAME

- ÛNKNOWN- [UNKNOWN- iUNKNOWN- {UNKNOWN CYCLOHEXANE

FtI\1Ii?1t\\I:11Ir\\ \t if it ii ii ii ii iS I

RT

8.639.439.6710.10

EST. CONC.

10.40.20.20.

————— <

—— i

QJJJJ^•L

_tFORM I SV-TIC 1/87

.._-.. flR303.02U '

IB - EPA SAMPISEMIVOLATILE ORGANICS ANALYSIS DATA SHEET '

] SBLK83Lab Name: IEA ^ -* Contract: 63-W8-0045 1

Lab Code: IEA Case No.: 12544 SAS No.: _ SDG No.: CCHOO



Level: (low/med) LOW : Date Received: O/ O/ 0

% Moisture: not dec. 100. dec. 0. . Date Extracted: 8/21/89


GPC Cleanup: (Y/N) N pH: 6.0 : .Dilution Factor: 1.00

""- CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

1I1 1-44-4 — — — -j« _» ^ M ^Q~—^7-Q-------

541-73-1 ———— -106-46-7 ———— -100-51-6 ———— -Q ^ H — 1-O — OU-J.- — -----Q q. /i Q— 7-- —— - —108-60-1 —————106-44-5 —————621 -64-7 —————** *• -*> ™* /67-72-1 —————

7S — Q — 1 —— — — .. — _Q Q "7 C C88- / J-O- ——— ——105-67-9 —————65-85-0 —————

1 1 1 — QI -1 -------120-83-2 —————

106-47-8 —————Q7 £3— •? _ — _— _

QI — 7— £— -.—— — — _77-47-4 ——————/ * "» / Tt

Q s;-aq_ A _._----

88-74-4 —————131-11-3 —————OnQ— QC — Q— — — — — — —£ A C. "~J rt *1606 20-2 ——————

•Phenol•bis (2-Chloroethyl) ether ___•2-Chlorophenol•1 r 3 -Dichlorobenzene•1 , 4-DichlorobenzeneBenzyl alcohol•1 , 2-Dichlorobenzene•2-Methylphenolbis ( 2-Chloroisopropyl ) ether4-MethylphenolN-Nitroso-di-n-propylamine _HexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4 -DimethylphenolBenzoic acidbis (2-Chloroethoxy)me thane _2 , 4-Dichlorophenol1,2,4 -Tr ichlorobenzerieNaphthalene4-ChloroanilineKexachlorobutadiene4-Chloro-3-methylphenol ___2-MethylnaphthaleneHexachlorocyclopentadiene _2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Chloronaphthalene2-NitroanilineDimethvlphthalateAcenaphthylene2 , 6-Dinitrotoluene

10.10.10.10.10.10.10.10.10.10.10.10.10.10.10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.50.10.10.10.

IIU

IUIUiuIUIUIUIUiuIUIUIUIUIUIUIUIUIUIUiuIU[UIUIUIUIUIUIUJu|U1

sv-i ' „ n 'n n Q n 9 q • 1/87 ifiR303025

1C "" ESA SAMPLESEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

| SBLK33Lab Name: IEA Contract: 63-W8-0045 |______




Level: (low/med) LOW . Date Received: O/ O/ 0


Extraction: (SepF/Cont/Sonc) CQNT Date Analyzed: 8/28/89



99-09-2—————3-Nitroaniline_________83-32-9—————Acenaphthene___________51-28-5—————2,4-Dinitrophenol ______100-02-7—————4-Nitrophenol __________132-64-9—————Dibenzofuran___________121-14-2 ————— 2,4-Dinitrotoluene______84-66-2—————Diethylphthalate________

7005-72-3—————4-Chlorophenyl-phenyletherw86-73-7—————Fluorene_______________]100-01-6—————4-Nitroaniline_________534-52-1—————4,6-Dinitro-2-methylphenol^86-30-6—————N-Nitrosodiphenylamine (1)]101-55-3 ————— 4-Bromophenyl-phenylether ]118-74-1—————Hexachlorobenzene ______^87-86-5—————Pentachlorophenol ______85-01-8—————Phenanthrene___________120-12-7—————Anthracene_____________84-74-2—————Di-n-butylphthalate _____206-44-0—————Fluoranthene___________129-00-0—————Pyrene________________85-68-7—————Butylbenzylphthalate_____91-94-1—————3,3' -Dichlorobenzidine___56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene______________117-81-7—————bis (2-Ethylhexyl )phthalate_117-84-0—————Di-n-octylphthalate ____j205-99-2—————Benzo (b) fluoranthene_____207-08-9—————Benzo(k) fluoranthene____50-32-8—————Benzo (a) pyrene193-39-5—————Indenod, 2,3-cd) pyrene.53-70-3—————Dibenz(a,h)anthracene [191-24-2—————Benzo(g,h,i)perylene "

50. |U10. IU50. |U50. ]U10. IU10. IU10. |U10. ]U10. |U50. IU50, |U10. IU10. IU10. IU50. [U10. IU10. IU10. IU10. IU10. ]U10. IU20. 1U10. ]U10. (U10. IU10. IU10. IU10. IU10. ]U10. [U10. [U10. - IU


FORM I SV-2 1/37 R

flR3G3026 "

, „ IF .. . . . . . . . . . . .. . EPA SAMPLESEMIVOLATXLE ORGAN! CS ANALYSIS DATA SHS2T _

TENTATIVELY IDENTIFIED COMPOUNDS l" "- . - . - I S3LK33

Lab Name: IEA t -;? - f Contract: 63-W8-Q045 I

Lab Code: IEA Case No.s 12544 SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER Lab "sample ID:


Level: (low/med) LOW ' Date Received: O/ O/ 0


Extraction: (SepF/Cont/Sonc) CONT _ .___ _ Date Analyzed: 8/23/89

GPC Cleanup: (Y/N) N pH: 6.0 _ .Dilution Factor: 1.00

..: CONCENTRATION UNITS:Number TICs found: 3 (ug/L or ug/Kg) UG/L

1 _ . . . . . - : -CAS NUMBER | COMPOUND NAME

1. - - I UNKNOWN2. - - | UNKNOWN3 . - - 1 UNKNOWN4. 15. 16. 17. |8. 19. 110. |11. 112. I13. 114. I15. I16. |17. I18. |19. 1 . .20. I21. 1 • i I22. | |23. | -- |

I 24. I I1 25. | I[26. 1 - - • |

27. I I28. I I29. 1 • - |30. |

1 * ; 1

RT

8.629.43

10.10

EST. CONC.

3.30.10,

Q

JJJ

FORM I SV-TIC 1/87 I;;: .-91303027 , •

IB EPA SAMPLESEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

I SBLK39Lab Name: IEA Contract: 68-W8-0045 I______

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO^


Sample wt/vol: 1000. (g/mL) ML Lab File ID: 0828405& Level: (low/med) LOW ' Date Received: O/ O/ 0


Extraction: (SepF/Con-/Sonc) CONT Date Analyzed: 8/23/89



O

108-95-2 ————— Phenol111-44-4 ————— bis(2-Chloroenhyl)et:her ___95-57-8 ————— 2-Chlorophenol

541 —73-1- ——— --T 3-DichlQrohenz'an.e*ml T. — . * —* ^> ^ f -mJ *•/ •••*** ti_»*-* _• W_rf S»».fcA t* (_>**<*«•

106-46-7 ————— 1,4-Dichlorobenzene100-51-6 ————— Benzyl alcohol95-50-1 ————— 1,2-Dichlorobenzene95-43-7 ————— 2-Methylphenol108-60-1 ————— bis (2-Chloroisopropyl) ether10 6 — 44-5— — — — ---4— MethvlnhenolU_ W sj 1 — ' ^ fa *>_• <_>** T >J. t ** "*- '

621-64-7 ————— N-Nitroso-di-n-propylamine _67-72-1 ————— Hexachlo roe thane98-95-3 ————— Nitrobenzene78-59-1 ————— Isophorone88-75-5 ————— 2-Nitrophenol105-67-9 ————— 2,4-Dimethylphenol65-85-0 ————— Benzoic acid111-91-1 ————— bis (2-Chloroethoxy) methane _120-83-2 ————— 2,4-Dichlorophenol120-82-1 ————— 1,2,4-Trichlorobenzene91-20-3 ————— Naphthalene106-47-8 ————— 4-Chloroaniline87-68-3 ————— Kexachlorobutadiene59-50-7 ————— 4-Chloro-3-methylphenol91-57-6 ————— 2-Methylnaphthalene77-47-4 ————— Kexachlorocyclopentadiene _88-06-2 ————— 2.4,6-Trichlorophenol95-95-4 ————— 2 . 4 , 5-Trichlorophenol91-58-7 ————— 2-Chloronaphthalene88-74-4 ————— 2-Nitroaniline131-11-3 ————— Dimethylphthalate208-96-8 ————— Acenaphthylene606-20-2 ————— 2,6-Dinitrotolue'ne

10.10.10,10.10.10.10.10.10,10.10.10.10.10.10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.50.10.10.10.

1

IUIUiuiu^ 1iuiuIUiuiuIU[UIUiuiuIUIUIUIUiuIUIUiuiu|UIUiuIS 11

FORM I SV-1 1/87 R

r 1C - EPA SAMPLE NSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET. ..:•-• - •• ---• .r ' . - i :————

- I SBLK89Lab Name: IEA Contract: 63-W8-0045 |

Lab Code: IEA Case No.: 12544 , SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER .v , _ Lab .Sample ID:





GPC Cleanup: (Y/N) N . pH: 6.0 „ . Dilution Factor: 1.00

-- - "CONCENTRATION UNITS:CAS NO. COMPOUND . (ug/L or ug/Kg) UG/L Q

99-09-2—————3-Nitroaniline _ . ..... .. .83-32-9—————Acenaphthene___________51-28-5——'—"—2"f4-Dinitrqphenol ______100-02-7—————4-Nitrophenol __________132-64-9—————Dibenzofuran___________"121-14-2 ————— 2,4-Dinitrotoluene-_____84-66-2—————Diethylphthalate _____]

7005-72-3—————4-Chlorophenyl-phenylether_86-73-7—————Fluorene__________]____"100-01-6 ————— 4-Nitroaniline_____534-52-1—————4,6-Dinitro-2-methylphenolM86-30-6—————N-Nitrosodiphenylamine (1)~101-55-3—————4-3romophenyl-phenylether ^118-74-1—————Hexachlorobenzene ______"87-86-5—————Pentachlorophenol ______85-01-8—————Phenanthrene__________120-12-7—————Anthracene_____________84-74-2—————Di-n-butylphthalate _____206-44-0—————Fluoranthene____________129-00-0—————Pyrene ... _ _ _ _ , . '85-68-7—————Butylbenzylphthalate_____91-94-1—————3,3 ' -Dichlorobenzidine___|56-55-3—————Benzo (a) anthracene_______218-01-9—————Chrysene_____ " -- :117-81-7—————bis(2-Ethylhexyl)phthalate117-84-0—————Di-n-octylphthalate ____"205-99-2—————3enso(b) fluoranthene_____207-08-9—————Benzo (k) fluoranthene_____50-32-8—————Benzo(a)pyrene__________193-39-5—————Indeno (1,2,3-cd)pyrene___53-70-3—————Dibenz(a,h)anthracene ___191-24-2————Benzo (g,h,i) perylene_____

50. |U10. |U50. [U50. |U10. |U10. |U10. ]U10. IU10. IU50. |U50. IU10. |U10. IU10. IU50. |U10, |U10. |U10. IU10. |U10. |U10. IU20. |U10. IU10. [U10. (U10. |U10. [U10. )U10. |U10. |U10. IU10. IU


FORM I SV-2 1/87 F

3Q3029 '*

IF EPA SAMPLESEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _

TENTATIVELY IDENTIFIED COMPOUNDS - II S3LK89


Lab Cede: IEA Case No.: 12544 SAS No.: SDG-No.:



O Level: (low/med) LOW Date Received: O/ Q/ 0


Extraction: (SepF/Cont/Sonc) CONT . Date Analyzed: 8/28/89

^ GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: " 1.00


CAS NUMBER

1. - -2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

UNKNOWN

'

RT

9.43

EST. CONC.

20.

QJ

*FORM I SV-TIC 1/87 I

AR303030 •"

rIB EPA SAMPLE NC

SEMIVOLAXILE ORGAJTICS ANALYSIS DATA SHEET _______________II SBLK93

Lab Name: IEA Contract: 63-W8-0045 |___________

Lab Code: IEA Case No.: 12544 SAS No.: , SDG No.: CCHOO



Level: (low/med) LOW ,/ ; _ Date Received: O/ O/ 0

% Moisture: not dec.100. dec. 0. _ P§te Extracted: 8/25/39


GPC Cleanup: (Y/N) N pH: .6.0 ,__ ..Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L Or ug/Kg) UG/L Q

s

111-44-4—————bis (2-Chloroethyl)ether ___95-57-8 ————— 2-Chlorophenol________541-73-1—————1,3-Dichlorobenzene ______106-46-7—————1,4-Dichlorobenzene ______100-51-6—————Benzyl alcohol___________95-50-1—————1,2-Dichlorobenzene ______95-48-7—————2-Methylphenol___________108-60-1—————his (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7————-N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane________'98-95-3—————Nitrobenzene_____________78-59-1—————Isophorone______________88-75-5 ————— 2-Nitrophenol ___________105-67-9 ————— 2,4-Dimethylphenol_________65-85-0—————Benzoic acid____________111-91-1—————bis (2-Chloroethoxy)me thane_120-83-2 ————— 2,4-Dichlorophenol______'_120-82-1—————1,2,4-Trichlorobenzene_____91-20-3—————Naphthalene _______;______106-47-8 ————— 4-Chloroaniline __________87-68-3—————Kexachlorobutadiene ______59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2 ————— 2,4,6-Trichlorophenol _____95-95-4—————2,4,5-Trichlorophenol ____91-58-7—————2-Chloronaphthalene ______88-74-4—————2-Nitroaniline___________131-11-3—————Dime thy Iphthalate ________208-96-8—————Acsnaphthylene___________606-20-2—————2,6-Dinitrotoluene________

FORM I SV-1 ~ - 1/87 R

1C " EPA SAMPLE NSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____

| SBLK93Lab Name: IEA Contract: 68-WS-0045 |______

Lab Code: IEA Case No.: 12544 SAS No.: " SDG No.:





Extraction: (SepF/Cont/Sonc) CCNT Date Analyzed: 9/ 1/89



1 \————————————j ,| 99-09-2—————3-Nitroaniline___________i 50. IU 1| 83-32-9—————Acenaphthene_____________| 10. [U 1| 51-28-5—————2,4-Dinitrophenol ________1 50. |U 11 100-02-7—————4-Nitrophenol ____________1 50. ]U |i 132-64-9—————Dibenzofuran 1 10. IU 1

121-14-2—————2,4-Dinitrotoluene______84-66-2—————Diethylphthalate________

7005-72-3 ————— 4-Chlorophenyl-phenylether^86-73-7—————Fluorene______________'_100-01-6—————4-Nitroaniline_________534-52-1—————4,6-Dinitro-2-methylphenol_86-30-6—————N-Nitrosodiphenylamine (1)]101-55-3—————4-Bromophenyl-phenylether ~118-74-1—————Hexachlorobenzene ______87-86-5—————Pentachlorophenol ______85-01-8—————Phenanthrene___________120-12-7—————Anthracene_____________84-74-2—————Di-n-butylphthalate _____206-44-0—————Fluoranthene___________129-00-0—————Pyrene________________85-68-7—————Butylbenzylphthalate_____91-94-1—————3,3 f -Dichlorobenzidine___56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene______________117-81-7—————bis(2-Ethylhexyl)phthalate117-84-0—————Di-n-octylphthalate ____"m205-99-2—————Benzo (b) fluoranthene_____207-08-9—————Benzo(k)fluoranthene_____50-32-8—————Benzo (a)pyrene__________193-39-5—————Indeno (1,2,3-cd) pyrene___53-70-3—————Dibenz(a,h)anthracene ___191-24-2—————Benzo (g ,h, i) perylene_____

10. |U10. IU10. |U10. |U50. IU50. IU10. [U10. |U10. IU50. IU10. IU10. IU10. IU10. IU10. |U10. |U20. |U10. IU10. JU10. IU10. IU10. IU10. IU10. [U10. IU10. |U10. .IU

(1) - Cannot be separated from diphenylamineFORM I SV-2 . 1/87

AR3Q3Q32 " "

IF EPA SAMPLE KSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _ _________

TENTATIVELY IDENTIFIED COMPOUNDS |"I SBLK9 3

Lab Name: IEA t Contract: 63-W8-0045 I__________

Lab Code: IEA Case No.: 12544" SAS Wo.: - SDG No.: CCHOO

Matrix: (soil/water) WATER . ... _^v. Lab_ Sample ID:



% Moisture: not dec.100. dec. 0, „ Date Extracted: 8/25/S9

Extraction: (SepF/Cont/Sonc) CONT Data Analyzed: 9/ 1/89GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: • 1.00

; - - .-CONCENTRATION UNITS:Number TICs found: 2 . . (ug/L or ug/Kg) UG/L

1I CAS NUMBERI11. - -12. - -I 3.1 4.1 5.1 6.! 7.1 8.1 9.1 10.1 11.1 12.1 13.I 14.! 15.1 16.1 17.I 18.I 19.1 20.1 21. 11 22. 11 23. 11 24. 11 25. 11 26. 1i 27. Ii 28. I1 29. 11 30. 11 1

COMPOUND NAME

UNKNOWNUNKNOWN

.

;

1

„-. , _

|RT [ EST. CONC.

9.42 i 10.10.10 | 10.

11111111111111111111111I11111

QJJ

FORM I JV-TIC _ _ l/_87•—•'---- flR303033 ''

r13 EPA SAMPLE

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET '•

I SBLK97Lab Name: IEA • Contract: 68-W8-0045 |

Lab Code: IEA Case No.: 12544 SAS No.: SDG No.: CCHQO'








I I I II 108-95-2—————Phenol . 1 10. ]U 1

111-44-4—————bis (2-Chloroethyl)ether ___95-57-8 ————— 2-Chlorophenol___________541-73-1————-1,3-Dichlorobenzene ______106-46-7 ————— 1,4-Dichlorobenzene ______100-51-6—————Benzyl alcohol___________95-50-1—————1,2-Dichlorobenzene ______95-48-7—————2-Methylphenol___________108-60-1—————bis (2-Chloroisopropyl) ether106-44-5 ————— 4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1————Hexachlor oethane_________98-95-3—————Nitrobenzene____________78-59-1—————Isophorone______________88-75-5—————2-Nitrophenol ___________105-67-9—————2,4-Dimethylphenol________65-35-0—————Benzoic acid_____________111-91-1—————bis (2-Chloroethoxy) me thane_120-33-2—————2,4-Dichlorophenol________120-82-1—————1,2,4-Trichlorobenzene_____91-20-3—————Naphthalene ____________106-47-8—————4-Chloroaniline _________87-63-3—————Hexachlorobutadiene

O 1 59-50-7—————4-Chloro-3-methylphenolj 91-57-6—————2-Methylnaphthalene __

77-47-4—————Hexachlor ocyclopentadiene88-06-2—————2,4,6-Trichlorophenol __95-95-4—————2,4,5-Trichlorophenol __91-58-7—————2-Chloronaphthalene ____88-74-4—————2-Nitroaniline_________131-11-3—————Dimethylphthalate ______208-96-8—————Acenaphthylene_________606-20-2—————2,6-Dinitrotoluene_____

10. IU10. |U10. IU10. [U10. IU10. |U10. IU10. IU10. IU10. IU10. [U10. )U10. |U10. IU10. IU50. IU10. IU10. IU10. |U10. IU10. IU10. IU10. IU10. |U10. |U10. IU50. IU10. IU50. |U10. |U10. ' *IU10. IU

FORM I SV-

1C • EPA SAMPLESEMIVOLATILZ ORGANICS ANALYSIS. DATA SHEET , „

I S3LK97Lab Name: IEA Contract: 63-WS-Q045 |_______

Lab Cede: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO

Matrix: (soil/water) WATER Lab "Sample ID:


Level: (low/med) LOW !1 "" /'"""Gate Received: O/ O/ 0



GPC Cleanup: (Y/N) N pH: 6.0 , Dilution Factor: 1.00

"CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or Ug/Kg) UG/L Q

99-09-2—————3-Nitroanilii83-32-9—————Acenaphthene

| 51-28-5 ————— 2,4-DinitrophenolI 100-02-7 ————— 4-Nitrophenol __

132-64-9—————Dibenzofuran121-14-2————-2,4-Dinitrotoluene

•Diethylphthalate________•4-Chlorophenyl-phenylether

86-73-7—————Fluorene______________100-01-6—————4-Nitroaniline________]534-52-1—————4,6-Dinitro-2-methylphenol_86-30-6—————N-Nitrosodiphenylamine (1)~101-55-3—————4-3romophenyl-phenylether118-74-1—————Hexachlorobenzene ______87-36-5—————Pentachlorophenol _______

-Phenanthrene________120-12-7—————Anthracene__________84-74-2—————Di-n-butylphthalate _206-44-0—————Fluoranthene . ....._.. :129-00-0—————Pyrene_____________85-68-7—————Butylbensylphthalate__91-94-1—————3 , 3 ' -Dichlorobenzidine

-Benzo(a)anthracene218-01-9—————Chrysene_______________117-81-7—————bis(2-Ethylhexyl)phthalate117-84-0—————Di-n-octylphthalate ____~205-99-2—————Benzo (b) fluoranthene_____

-Benzo (k) f luoranthene_•Benzo(a)pyrene

193-39-5—————Indeno (1,2,3-cd)pyrene_

191-24-2————Benzo(g,h,i)perylene

50. |U10. |U50. 1U50. IU10. (U10. |U10. |U10. |U10. (U50. |U50. |U10. IU10. |U10. )U50. |U.10. |U10. |U10. IU10. [U10. |U10. ]U20. IU10. (U10. IU10. IU10. [U10. [U10. IU10. |U10. IU10. IU10. . IU'I


FORM I SV-2 1/87 J=

~ ftR303035

IF EPA SAMPLE NSEMIVOLATILE ORGA.NICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS1 S3LK97

Lab Name: IEA : Contract: 63-W8-OQ45 1




Level: (low/med) LOW . Date Received: 0/0/0



GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1*00

CONCENTRATION UNITS:Number Ties found: 1 (ug/L or ug/Kg) UG/L

CAS NUMBER

1. - -2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.

1 25.I 26.27.28.29.30.

ICOMPOUND NAME

UNKNOWN

RT

9.25

1

EST. CONC.

20.

i

QJ

*

—-fe_


flR303036"

r-IB " EPA SAMPLE K-

SEMXVOLATILE ORGANICS ANALYSIS DATA SHEET ' " -

• "- -— I SBLK10Lab Name: IEA Contract: 63-W8-0045 I



Sample wt/vol: 1000. (g/mL) ML Lab File ID: 0911D10

Level: (low/med) LOW _ ...;. Date Received: 0/0/0

% Moisture: not dec.lOQ. dec. 0. Date Extracted: 8/30/89

„ Extraction: (SepF/Cont/Sonc) SEPF . Date Analyzed: 9/12/89

GPC Cleanup: (Y/N) N : pH: 6.0 Dilution Factor: 1.00

""'CONCENTRATION UNITS:CAS NO. COMPOUND . (ug/L or ug/Kg) UG/L Q

108-95-2—————Phenol^__________________________111-44-4 ———— -bis.( 2-Chloroethyl)ether ___95-57-8 ————— 2-Chlorophenol____541-73-1 ————— 1,3-Dichlorobenzene106-46-7—————1,4- _____100-51-6—————Benzyl alcohol _____95-50-1—————1,2-Dichlorobenzene ______95-48-7—————2-Methylphenol___________108-60-1—————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Hexachloroethane

•Nitrobenzene78-59-1—————Isonhorone____________88-75-5 ————— 2-Nitrophenol _________]105-67-9—————2,4-Dimethylphenol____'65-85-0—————Bensoic acid . . . . . _ . . . .111-91-1—————bis (2-ChloroethoxyJmethaneJ120-83-2—————2,4-Dichlorophenol______"120-82-1—————If 2, 4-Trichlorobenzene___"91-20-3—————Naphthalene ___________106-47-8 ————— 4-Chloroaniline ________.87-68-3—————Hexachlorobutadiene _____'59-50-7—————4-Chloro-3-methylphenol __91-57-6—————2-Methylnaphthalene _____77-47-4—————Hexachlorocyclopentadiene88-06-2—————2,4,6-Trichlorophenol _^__"

•2,4,5-Trichlorophenol ___'91-58-7—————2-Chloronaphthalene88-74-4—————2-Nitroaniline__131-11-3—————Dimethylphthalate208-96-8———•

•2,6-Dinitrotoluene

10. IU10. |U10. |U10. IU10. IU10. |U10. IU10. [U10. |U10. IU10. |U10. ]U10. |U10. |U10. [U10. [U50. IU10, |U10. IU10. IU10. |U10. [U10. IU10. |U10. |U10. 1U10. |U50. |U10. |U50. |U10. . |U10. '|U10. |U

FORM I SV-1 ' . 1/87 I_fiR3G3Q37

1C • EPA SAMPLESEMIVOLATILE CRGANICS ANALYSIS DATA SHEET _____

1 " S3LK10Lab Name: IEA Contract: 63-W8-0045 I_______



Sample wt/vol: 1000. (g/mL) ML Lab File ID: 0911D10




'3 GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1.00


o

O

99-09-2—————3-Nitroaniline ! 50. IU83-32-9—————Acenashthene I 10. IU51-28-5 ————— 2,4-Dinitrophenol ________I 50. jU100-02-7————-4-Nitrophenol 50. U132-64-9—————Dibenzofuran I 10. |U

7005-72-3—————4-Chlorophenyl-phenylether_86-73-7—————Fluorene________________100-01-6-.————— 4-Nitroaniline_________.534-52-1—————4,6-Dinitro-2-methylphenol_86-30-6————N-Nitrosodiphenylamine (1)_101-55-3 ————— 4-3romoDhenyl-phenylether118-74-1—————87-86-5—————

•Phenanthrene120-12-7——————Anthracene________84-74-2—————Di-n-butylphthalate206-44-0—————Fluoranthene______129-00-0—————

121-14-2—————2,4-Dinitrotoluene________| 10. | U84-66-2————Diethylphthalate_________| 10. IU

10. IU10. IU50. |U50. [U10. |U10. IU10. |U50. IU10. IU10. (U10. IU10. IU10. IU10. IU20. |U10. |U10. IU10. IU10. ]U10. (U10. [U10. (U10. IU10. IU10. IU

91-94-1——————3.3 '-Dichlorobenzidine___56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene_______________117-81-7—————bis (2-Ethylhexyl )phthalate_117-84-0—————Di-n-octylphthalate

-99-2—————Benzo (b) fluoranthene,207-08-9—————Benzo(k) fluoranthene"

-Benzo(a)pyrene______•Indeno (1,2,3 -cd) pyrene_•Dibenz(a,h)anthracene

191-24-2—————Benzo (g,h,i)peryl


FORM I SV-2 1/87 E

IF . . • EPA SAMPLESZMIVCLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS [I S3LK10

Lab Name: IEA •--: ---- ' Contract: 68-W8-0045

Lab Code: IEA Case No.: 12544 SAS No..: SDG No.: CCHOO


Sample wt/vol: 1000. (g/mL) ML ' Lab File ID: 0911D10

Level: (low/med) LOW • Date Received: O/ O/ 0

% Moisture: not dec.100. dec. 0.. , :. Date Extracted: 8/30/89



- CONCENTRATION UNITS:Number TICs found: 1 (ug/L or ug/Kg) UG/L

1 1 . ...._".......I CAS NUMBER | COMPOUND NAME

|1. - - I UNKNOWN1 2 . |1 3. I1 4. I1 5 . |1 6. I1 7. |1 8. |1 9- 11 10. |1 11. 11 12. |1 13. I1 14. Ii 15. !1 16. I1 17. |1 18. [i 19. 11 20. I1 21. I1 22. |1 23. I1 24. I1 25. I1 25. I1 27. |1 28. I1 29. |

30. I1

RT

9.23

EST. CONC.

8.

QJ

FORM I SV-TIC ' " 1/87flR303039 '

IB EPA SAMPLE fifeSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET "________

II CCH03MS

Lab Name: IEA . Contract: 63-W8-0045 I



Sample wt/vol: 10QQ. (g/mL) ML Lab File ID: 0828411



Extraction: (SepF/Cont/Scnc) CCNT Date Analyzed: 8/23/89


CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L 'Q

! I I i[ 108-95-2—————Phenol__________________I 160. 1 i| 111-44-4—————bis(2-Chloroethyl)ether ___1 10. IU |

95-57-8 ————— 2-Chlorophenol____ _______541-73-1—————1,3-Dichlorobenzene ______106-46-7—————1,4-Dichlorobenzene ______100-51-6—————Benzyl alcohol___________95-50-1—————Ir2-Dichlorobenzene ______95-4S-7—————2-Methylphenol___________108-60-1————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol___________621-64-7—————N-Nitroso-di-n-propylamine_67-72-1—————Kexachloroethane_________98-95-3—————Nitrobenzene_____________78-59-1—————Isophorone______________88-75-5——————2-Nitrophenol ____________105-67-9—————2,4-Dimethylphenol________65-85-0—————Benzoic acid111-91-1—————bis (2-Chloroethoxy) methane_120-83-2—————2, 4-Dichlorophenol________120-82-1—————1.2. 4-Trichlorobenzene_____91-20-3—————Naphthalene ____________106-47-8—————4-Chloroaniline _________87-68-3—————Hexachlorobutadiene ______59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4.6-Trichlorophenol ____95-95-4—————2,4,5-Trichlorophenol _____91-58-7—————2-Chloronaphthalene ______88-74-4——-^~-2-NitroaniIine___________131-11-3—-———Dimethylphthalate ________208-96-8—————Acenaphthylene___________606-20-2—————2f 6-Dinitrotoluene________

78. |10. |U47. |10. |U10. [U10. IU10. IU10. IU62. I10. IU10. |U10. IU10. |U10. IU50. IU10. |U10. IU55. |10. |U10. |U10. [U110. |10. IU10. IU10. IU50. ]U10. IU50. |U10. IU10. -IU10. IU 4

FORM I SV-1 _. . n . 1/87 F

1C . . -. EPA SAMPLE ISSEMIVOLATILE CRGANICS ANALYSIS DATA SHEET ___________

• ' ' ' . . :".. " " ' _ ———————I CCH03MS

Lab Name: IEA ^ _^ ... Contract: 63-W8-0045 I_______






Extraction: (SepF/Ccnt/Sonc) CONT Date Analyzed: 3/28/89

GPC Cleanup: (Y/N) N pK: 6.0 " Dilution Factor: 1.00


99-09-2 ————— 3-Nitroaniline _____S3 -3 2-9-- ——— • Acenaphthene...51-28-5 ————— 2,4-Dinitrophenol ; _____100-02-7 ————— 4-Nitrophenol __________132-64-9 ————— Dibenzofuran _____121-14-2 ————— 2 , 4-Dinitrotoluene_ _____84-66-2 ————— Diethylphthalate

7005-72-3 —— ----4-Chlorophenyl-phenylether _*86-73-7—————Fluorene______________

100-01-6—————4-Nitroaniline__________534-52-1—————;4/6-Dinitro-2-methylphenol-

. 86-30-6—————N-Nitrosodiphenylamine (1)]3 , I 101-55-3 ————— 4-Bromophenyl-phenylether ~_

118-74-1—————Hexachlorobenzene . ..87-86-5 ————— Pentachlorophenol85-01-8 ————— Phenanthrene ______120-12-7 ————— Anthracene84-74-2 ————— Di-n-butylphthalate206-44-0 ————— Fluoranthene129-00-0 ————— Pyrene85-68-7 ————— Butylbenzylphthalate91-94-1 ————— 3 . 3 ' -Dichlorobenzidine __ _56-55-3 ————— Senzo ( a ) anthracene218-01-9 ————— Chrysene ______________117-31-7 ————— bis(2-Ethylhexyl)phthalate117-84-0 ————— Di-n-octylphthalate205-99-2 ————— Benzo (b) fluoranthene207-08-9 ————— Benzo(k) f luoranthene_50-32-8 ————— Benzo(a)pyrene193-39-5 ————— Indeno (1,2, 3 -cd) pyrene53-70-3 ————— Dibenz( a, h) anthracene ___191-24-2 ————— Senzo (g.h/i)perylene

50. IU64. I50. IU74. I10. |U67. |10. |U10. IU10. IU50. [U50. IU10. |U10. [U10. |U84. |10. (U10. IU10. |U10. |U63. |10. |U20. |U10. |U10. IU10. IU10. |U10. IU10. |U10. |U10. IU10. IU10. IU


FORM I SV-2 1/87 3

IB EPA SAMPLE NCSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________,

I CCH03MSDLab Name: IEA Contract: 68-W8-0045 j.____

Lab Cede: IEA Case No.: 12544 SAS No.: SDG No.: CCHOO





Extraction: (SepF/Cont/Sonc) CCNT Date Analyzed: 8/28/89



I 1 I II 108-95-2—————Phenol___________________I 2 0 0 - 1 || 111-44-4—————bis(2-Chloroethyl)ether ___i 10. IU 1

95-57-8 ————— 2-Chloroohenol 91.541-73-1—————1,3-Dichlorobenzene ______| 10106-46-7 ————— 1,4-Dichlorobenzene 55100-51-5—————Benzyl alcohol__________95-50-1—————lf2-Dichlorobenzene ______95-48-7—————2-Methylphenol _____108-60-1—————bis (2-Chloroisopropyl) ether106-44-5—————4-Methylphenol__________621-64-7—————N-Nitroso-di-n-propylamine__67-72-1—————Hexachloroethane_________98-95-3—————Nitrobenzene __1-59-1—————Isophorone

83-75-5 ————— 2-Nitrophenol-67-9 ————— 2,4-Dimethylphenol

•Benzoic acid-91-1—————bis (2-Chloroethoxy) me thane_

120-83-2—————2,4-Dichlorophenol________120-82-1—————112 ,4-Trichlorobenzene_____91-20-3—————Naphthalene

•4-Chloroaniline'-68-3—————Hexachlorobutadiene

59-50-7—————4-Chloro-3-methylphenol ___91-57-6—————2-Methylnaphthalene ______77-47-4—————Hexachlorocyclopentadiene _88-06-2—————2,4,6-Trichlorophenol ____

-2.4,5-Trichlorophenol91-58-7—————2-Chloronaphthalene88-74-4—————2-Nitroaniline____131-11-3—————Dimethylphthalate __

-96-8—————Acenaphthylene_606-20-2—————2,6-Dinitrotoluene

10. ]U10. 1U10. IU10. |U10. |U59. 110. IU10. IU10. IU10. IU10. IU50. IU10. |U10. |U58. |10. [U10. IU10. IU

110. I10. |U10. IU10. IU50. IU10. IU50. IU10. • IU10. "IU10. IU

*

*FORM I SV-1 • 1/87 F

flB3030i42

: 1C EPA SAMPLESEMIVOLATILE ORGAN!CS ANALYSIS DATA SHEET ______^'

I ~~—————I CCH03MSD

Lab Name: IEA v'\r :--- -Contract: 63-W8-0045 |_________





% Moisture: not dec. 100. ; dec. 0. Date Extracted: 8/22/89

Extraction: {SepF/Cont/Sonc) CCNT Date Analyzed: 8/28/89

GPC Cleanup: (Y/N) 'N pH: 6.0 Dilution Factor: 1.00


O—' -" W —' 4* —I fcl^WÛU.Â.J. . **>•— ____________________^_^____________ I

66

O

99-09-2————-3-Nitroaniline___________1 50. |U83-32-9—————Acsnaphthene51-28-5 ————— 2,4-Dinitrophenol ______100-02-7 ————— 4-Nitrophenpl13 2-64-9--———Dibenzofuran______121-14-2 ————— 2,4-Dinitrotoluene_______84-66-2—————Diethylphthalate________

7005-72-3 ————— 4-Chlorcphenyl-phenylether_86-73-J—————:Fluorene_________]____"100-01-6 ————— 4-Nitroaniline_________"534-52-1—————.4,6-Dinitro-2-methylphenol_i86-30-6—————N-Nitrosodiphenylamine (1)]101-55-3———:——4-3romophenyl-phenylether [118-74-1—————Hexachlorobenzene ______87-86-5—————Pentachlorophenol ______35-01-8—————Phenanthrene - . „„_120-12-7—————Anthracene______- . .____84-74-2—————Di-n-butylphthalat_e .._ .__ .206-44-0—————Fluoranthene____________129-00-0—————Pyrene____________85-58-7—————Butylbenzylphthalate____"91-94-1—————3 , 3' -Dichlorobenzidine___56-55-3—————Benzo (a) anthracene______218-01-9—————Chrysene______________~117-81-7—————bis (2-Ethylhexyl )phthalate_117-84-0—————Di-n-octylphthalate ____"205-99-2—————Benso(b) fluoranthene____~207-08-9—————Benzo(k)fluoranthene_____50-32-8—————Benzo (a) pyrene_________"193-39-5—————Indenod, 2,3-cd)pyrene___53-70-3—————Dibenz(a,h)anthracene ___191-24-2—————Benzo (g,hf i)perylene_____

50. |U120. |10. |U70. |10. ]U10. IU10. |U50. IU50. (U10. IU10. IU10. |U110. 110. [U10. IU10. IU10. IU66. |10. [U20. |U10. |U10, |U10. |U10. IU10. IU10. IU10. IU10. IU10. IU10. IU


FORM I SV-2 1/87 I

ID EPA SAMPLE NOPESTICIDE CRGANICS ANALYSIS DATA SHEET

1 PBLK73Lab Name: IEA Contract: 63-W8-0045



Sample wt/vol: 1000. (g/mL)ML ' Lab File ID: DB5A4554


% Moisture: not dec,100. dec. 0. Date Extracted: 8/17/39




O

319-34-5————aloha-BHC | .050 [U319-85-7————beca-BHC I .050 IU319-86-3————delta-BEC I .050 [U58-89-9———gamma-BHC [ .050 (U76-44-3————Heptachlor | .050 IU309-00-2————Aldrin I .050 IU1024-57-3———Heptachlor epoxide j .050 JU959-98-8————Endosulfan I I .050 )U60-57-1————Dieldrin I .10 IU72-55-9————4,4r -DDE I . 10 IU72-20-8———Endrin I .10 IU

33213-65-9———Endosulfan II I .10 |U72-54-8————4.4'-DDD | .10 IU

1031-07-8———Endosulfan sulfate [ .10 IU50-29-3————4,4' -DDT I . 10 IU72-43-5———Methoxychlor I .50 JU

53494-70-5————Endrin ketone 1 .10 IU5103-71-9———alpha-Chlordane | .50 |U5103-74-2———gamraa-Chlordane j .50 JU8001-35-2————Toxaphene | 1.0 IU12674-11-2———Aroclor-1016 | . 50 | U11104-23-2————Aroclor-1221 I .50 [U11141-16-5———Aroclor-1232 | .50 IU53469-21-9————Aroclor-1242 [ .50 IU12672-29-6———Aroclor-1248 1 .50 |U11097-69-1———Aroclor-1254 I 1.0 IU11096-82-5————Aroclor-1260 I 1.0 IU

FORM I PEST 1/87 Re'

ID EPA SAMPLE NO-PESTICIDE ORGANICS ANALYSIS DATA SHEET

I PBLK79Lab Name: IEA r - Contract: 6S-W8-0045 I______


Matrix: (soil/water) WATER . ... r"~_. Lab Sample ID:

Sample wt/vol: 1000. (g/mL)ML ' Lab File ID: DB5A4556

Level: (low/med) LOW '. Date Received: 0/0/0


Extraction: (SepF/Conr/Sonc) SEPF _ ... : Date Analyzed: 9/ 1/89


- , • - - ,. CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-84-6———alpha-3HC I .050 |U319-35-7———ceta-3EC I .050 [U319-86-3———delta-BHC . [ .050 [U53-39-9———gamma-3HC I .050 IU76-44-3———Heptachlor I .050 |U309-00-2———Aldrin 1 .050 |U1024-57-3———Heatachlor eraoxide I .050 |U959-98-8———Sndosulfan I I .050 (U60-57-1———Dieidrin I .10 IU72-55-9————4f4r-DDE I .10 |U72-20-8———Endrin I . 10 | U

33213-65-9———Sndosulfan II [ .10 |U72-54-8————4,4f-DDD | .10 JU

1031-07-3———Endosulfan sulfate I .10 ]U50-29-3 ———— 4,4f-DDT I .10 IU72-43-5———Methoxychlor I • .50 [U

53494-70-5———Endrin ketone | .10 |U5103-71-9———alpha-Chlordane | .50 |U5103-74-2———gamma-Chlordane j .50 |U8001-35-2———Toxaphene I 1.0 (U12674-11-2————Aroclor-1016 I .50 [U11104-28-2———Aroclor-1221 | .50 JU11141-16-5———Aroclor-1232 I .50 IU53469-21-9———Aroclor-1242 1 .50 |U12672-29-6———Aroclor-1248 | .50 IU11097-69-1———Aroclor-1254 I 1.0 |U11096-82-5————Aroclor-1260 | 1.0 |U

FORM I PEST . 1/87 Re

r

ID ' EPA SAMPLE NO.PESTICIDE CRGANICS ANALYSIS DATA SHEET

~| "PBLK35Lab Name: IEA Contract: 63-WS-Q045 I



Sample wt/vol: 1000. (g/mLJML ' Lab File ID: DB5A4563

Level: (Icw/med) LOW Date Received: O/ O/ 0


Extraction: (SepF/Conc/Sonc) SEP? Date Analyzed: 9/ 1/89



O

319-34-6————alpha-3HC319-85-7————beta-3HC319-86-8————delta-BHC53-89-9-———gamma-3HC76-44-8————Hentachlor309-00-2————Aldrin1024-57-3———Keotachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4' -DDE72-20-3————Sndrin

33213-65-9———Sndosulfan II72-54-8 ———— 4,4'-DDD

1031-07-8———Sndosulfan sulfate50-29-3———4.4' -DDT72-43-5———Methoxychlor

53494-70-5———Sndrin ketone5103-71-9————alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2————Toxaphene12674-11-2———Aroclor-101611104-28-2———Aroclor-122111141-16-5———Aroclor-123253469-21-9———Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5————Aroclor-1260

.050 IU

.050 [U

.050 (U

.050 |U

.050 |U

.050 |U

.050 |U

.050 |U.10 |U.10 |U.10 |U.10 IU.10 IU.10 |U.10 iy.50 IU.10 ju.50 IU.50 ]U1,0 |U.50 IU.50 ]U.50 |U.50 [U.50 |U1.0 [U1.0 IU

FORM I PEST 1/87 Re"

ID EPA SAMPLE NO,PESTICIDE ORGANICS ANALYSIS DATA SHEET _______

I PBLKS 3Lab Name: ISA Contract: 63-W3-0045 [______



Sample wt/vol: 1QOO. (g/mL)ML - Lab File ID: DB5A4567


% Moisture: not dec.100, dec. 0. __ Date Extracted: 8/28/89

Extraction: (SepF/Conc/Sonc) SEPF Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N pH: 6.0 Dilution Factor: 1,00


i i i i| 319-84-5————alpha-BHC I .050 |U || 319-35-7————beta-BEC I .050 |U! 319-36-8————delta-3EC I .050 |U

53-89-9———gamma-BHC| 76-44-8———Heotachlor| 309-00-2———Aldrin1 1024-57-3———He-ntachlor epoxide! 959-98-3———Sndosulfan II 60-57-1———Dieldrin| 72-55-9————4,4'-DDEI 72-20-8———EndrinI 33213-65-9———Sndosulfan III 72-54-8————4,4 ' -DDDI 1031-07-8———Sndosulfan sulfate| 50-29-3 ———— 4,4'-DDTI 72-43-5———Methoxychlor[ 53494-70-5———Sndrin ketone| 5103-71-9———alpha-ChlordaneI 5103-74-2———gamma-Chlordanej 8001-35-2———ToxapheneI 12674-11-2———Aroclor-1016| 11104-23-2————Aroclor-1221| 11141-16-5———Aroclor-1232| 53469-21-9———Aroclor-1242| 12672-29-6————Aroclor-1248I 11097-69-1———Aroclor-1254| 11096-82-5———Aroclor-1260

.050 |U

.050 IU

.050 [U

.050 IU

.050 IU.10 IU.10 [U.10 |U.10 [U.10 IU.10 |U.10 IU.50 |U.10 ]U.50 IU.50 [U1.0 [U.50 |U.50 IU.50 [U.50 IU.50 [U1.0 |U1.0 |U

FORM I PEST ' 1/87 Re

' - : ; SR303QU '

ID EPA SAMPLE NO,PESTICIDE CRGANICS ANALYSIS DATA SHEET _____________

|• CCH03MSLab Name: IEA . Contract: 63-W3-0045 1______





% Moisture: not dec.lQQ. dec. 0. Date Extracted: 8/21/39




O

319-84-6————alpha-BBC319-85-7————beta-3HC319-86-3————delta-3EC58-89-9————gamma-BBC76-44-8———Heptachlor309-00-2————Aldrin1024-57-3———Heptachlor epoxide959-98-8———Endosulfan I60-57-1———Dieldrin72-55-9————4,4' -DDE72-20-3———Sndrin


1031-07-8———Endosulfan sulfatef _

72-43-5———Methoxychlor53494-70-5———Sndrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2————Toxachene12674-11-2————Aroclor-101611104-28-2———Aroclor-122111141-16-5————Aroclor-123253469-21-9————Aroclor-124212672-29-6————Aroclor-124811097-69-1————Aroclor-125411096-82-5———Aroclor-1260

,050 |U,050 |U,050 IU.16 I• 14 |.14 [,050 [U,050 )U.33 1.10 IU.40 |.10 |U.10 ITT,10 [U.33 I.50 IU.10 ITT.50 IU.50 IU1.0 IU.50 IU.50 IU.50 IU.50 IU.50 |U1.0 IU1.0 IU

•

FORM I PEST . 1/87 Re-

BR3030U8

ID EPA SAMPLE NOPESTICIDE CRGANICS ANALYSIS DATA SHEET

: I CCH03MSDLab Name: IEA Contract: 68-W8-G045 I



Sample wt/vol: 1000. (g/mL)ML Lab File ID: DB5A4562



Extraction: (SepF/Conz/Sonc) SEPF . Date Analyzed: 9/ 1/89

GPC Cleanup: (Y/N) N pH: "6.6"" " Dilution Factor: 1.00

' CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

319-34-6————alpha-BBC319-85-7————bera-3HC319-36-8————delta-3HC58-89-9————gamma-3KC76-44-3———Heptachlor309-00-2r——Aldrin1024-57-37-——Heptachlor epoxide959-93-8———Sndosulfan I60-57-1———Dieldrin72-55-9————4, 4' -DDE72-20-8———Sndrin


1031-07-8———Sndosulfan sulfate50-29-3————4,4'-DDT72-43-5———Methoxychlor

53494-70-5———Sndrin ketone5103-71-9———alpha-Chlordane5103-74-2———gamma-Chlordane8001-35-2———Toxaphene12674-11-2————Aroclor-101611104-28-2————Aroclor-122111141-16-5———Aroclor-123253469-21-9———Aroclor-124212672-29-6———Aroclor-124811097-69-1———Aroclor-125411096-82-5———Aroclor-1260

.050 IU

.050 IU

.050 [U.18 I.13 1.13 I

.050 |U

.050 )U.33 |.10 IU.41 |.10 JU.10 IU.10 |U.32 [.50 IU.10 |U.50 |U.50 [U1.0 IU.50 |U.50 IU.50 IU.50 [U.50 IU1.0 IU1.0 |U

FORM I PEST 1/87 Re

flR3Q30*t9

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completed by the Region III™ Environmental · The maximum concentrations of compounds found in the trip blank, equipment blanks, or method blanks are listed below. ... Cft c* 9