Conforms to ANSI Z400.1-2004 Standard (United States, …shurhold.com/wp-content/uploads/2009/12/Click-here-for-MSDS-sheets… · ... Safety glasses, goggles or face shield. Impervious

Brite WashMaterial Safety Data Sheet

Product and company identification1 .Common name Brite Wash

Mild soap.SupplierMaterial uses

ManufacturerIn case of emergency :

:

::

:CHEMTREC, U.S. : (800) 424-9300International: (703) 527-3887

Shurhold Industries3119 SW 42nd AvenuePalm City, Florida 34990-5558Toll free : 800-962-6241Tel : (772) 287-1313Fax : (772) 286-9620Email : [email protected]

MSDS authored by: : Kemika XXI Inc. + 1-450-435-7475 10/30/2006

Conforms to ANSI Z400.1-2004 Standard (United States, Canada, Mexico).

Contact the supplier.

Dermal contact. Eye contact. Inhalation. Ingestion.

Hazards identification

Routes of entryPotential acute health effects

No known significant effects or critical hazards.

Irritating to eyes.

May be harmful if swallowed.

No known significant effects or critical hazards.EyesSkinInhalationIngestion

Physical state Liquid. (Clear.)

See toxicological information (section 11)

:

:

::::

Medical conditionsaggravated by over-exposure

Repeated or prolonged exposure is not known to aggravate any medical condition.:

Odor : Bouquet.

2 .

Emergency overview : WARNING !CAUSES EYE IRRITATION.MAY BE HARMFUL IF SWALLOWED.Do not ingest. Avoid contact with skin and clothing. Wash thoroughly after handling.

Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.

:Potential chronic healtheffects

Color : Gold.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the

WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.

Date of issue : 10/30/2006 Page: 1/6

Brite Wash

Composition/information on ingredients

Sodium Dodecylbenzene Sulfonate 25155-30-0 5 - 10

Name CAS number %Canada

Mexico

Name CAS number %Sodium DodecylbenzeneSulfonate

Notregulated.

- 1 0 0 25155-30-0 5 - 10

IDLH H F R SpecialClassification

UN number

3 .

%Name CAS numberUnited States

Sodium Dodecylbenzene Sulfonate 25155-30-0 5 - 10

First aid measures4 .Eye contact

Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention if symptoms appear.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medicalattention if symptoms appear.

Check for and remove any contact lenses. In case of contact with eyes, rinseimmediately with plenty of water. Get medical attention if symptoms occur.

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

: No specific antidote. Medical staff must contact Poison Control Center.

Wash with soap and water. Get medical attention if symptoms occur.

Non-flammable.

Use an extinguishing agent suitable for the surrounding fire.

Fire-fighting measuresFlammability of the productExtinguishing media

No specific hazard.Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

5 .

None known.Suitable :Not suitable :

Use suitable protective equipment.

For small spills, add absorbent (soil may be used in the absence of other suitablematerials), scoop up material and place in a sealable, liquid-proof container for disposal.For large spills, dike spilled material or otherwise contain material to ensure runoff doesnot reach a waterway. Place spilled material in an appropriate container for disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains andsewers.

Personal precautions :

Methods for cleaning up :

6 .


Brite Wash

Keep container tightly closed. Keep container in a cool, well-ventilated area.

Do not ingest. Avoid contact with eyes, skin and clothing. Wash thoroughly afterhandling.

Handling and storageHandling

Storage

:

:

7 .

Exposure controls/personal protection

Personal protection

Consult local authorities for acceptable exposure limits.

8 .

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol airborne levels.

Hygiene measures :

Personal protection in caseof a large spill

: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.

HMIS Code/Personalprotective equipment

: A

No special protective clothing is required.

Not required under normal conditions of uses.Not required under normal conditions of uses.

Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands

100°C (212°F)

Liquid. (Clear.)

12.8 [Basic.]

May start to solidify at 0°C (32°F) based on data for: Water.1.06 (Water = 1)

The highest known value is 0.62 (Air = 1) (Water).The highest known value is 2.3 kPa (17.5 mm Hg) (at 20°C) (Water).

Bouquet.Gold.

Boiling/condensation pointMelting/freezing point

0.36 (Water) compared with Butyl acetate.

Physical and chemical propertiesPhysical state

pH

Relative densityVapor pressureVapor densityEvaporation rate

OdorColor

::::::::::

9 .

Easily soluble in cold water, hot water, methanol, acetone.Solubility :

The product is stable.Reactive with oxidizing materials and acids.

Will not occur.

Stability and reactivityStability and reactivityIncompatibility with varioussubstancesHazardous polymerization

::

:

10 .

None known.Conditions of reactivity :


Brite Wash

Toxicological informationToxicity data

Product/ingredient name Test Result Route SpeciesSodium Dodecylbenzene Sulfonate LD50

LD50438 mg/kg1330 mg/kg

OralOral

RatMouse

11 .

Eyes : Irritating to eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : May be harmful if swallowed.

Acute Effects

Potential chronic healtheffects

: Carcinogenic effects: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.Mutagenic effects: Not available.Teratogenic effects: Not available.

These products are carbon oxides and water, sulfur oxides. Some metallic oxides.The products of degradation are less toxic than the product itself.

Ecological information

Toxicity of the products ofbiodegradation

Products of degradation

Ecotoxicity dataSpecies Period ResultProduct/ingredient name

Sodium Dodecylbenzene Sulfonate Daphnia magna (EC50)Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)

48 hour(s)96 hour(s)96 hour(s)96 hour(s)

5.88 mg/l1.18 mg/l1.68 mg/l6.5 mg/l

::

Environmental precautions : No known significant effects or critical hazards.

12 .

The generation of waste should be avoided or minimized wherever possible. Avoiddispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.Disposal of this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regionaland local authority requirements.

Waste disposal

Disposal considerations:

13 .

Transport information14 .

IATA :DOT/ TDGIMDG/ Not regulated.

NAERG : Not applicable.Regulatory information

UN/

Regulatory information

Clean Water Act (CWA) 307: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Sodium Dodecylbenzene SulfonateSARA 311/312 MSDS distribution - chemical inventory - hazard identification: SodiumDodecylbenzene Sulfonate: Immediate (acute) health hazard

United States

15 .

HCS ClassificationTSCA : All components listed.Irritating material

U.S. Federal regulations ::


Brite Wash

Clean Water Act (CWA) 311: Sodium Dodecylbenzene SulfonateClean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

International lists :

Canada

Mexico

01 0Health

FlammabilityReactivity

Special

Classification :

WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic).:

DSL : All components listed.

Pennsylvania RTK: Sodium Dodecylbenzene Sulfonate: (environmental hazard, genericenvironmental hazard); Diethanolamine: (environmental hazard, generic environmentalhazard)Massachusetts RTK: Sodium Dodecylbenzene Sulfonate; DiethanolamineNew Jersey: Sodium Dodecylbenzene Sulfonate; DiethanolamineCalifornia prop. 65: No products were found.

HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal

State regulations :

This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).

This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United StatesOSHA and the Mexican NOM -018-STPS-2000. This MSDS contains all the information required by the CPR, OSHA,the American National Standard Institute (ANSI) Z400.1 and NOM -018-STPS-2000.

Other information

Hazardous MaterialInformation System (U.S.A.)

National Fire ProtectionAssociation (U.S.A.)

HealthSpecial

ReactivityFlammability

CAUSES EYE IRRITATION.MAY BE HARMFUL IF SWALLOWED.

Label requirements (U.S.A.) :

:

:

16 .

00

1

HMIS RATING

Physical Hazard

Health 1

0Fire hazard

Personal protection A0

4- Extreme3- Serious

2- Moderate1- Slight

0- MinimalSee section 8 for more detailed

information on personal protection.

HAZARD RATINGS


Brite Wash

ReferencesReferences

Date of issueVersion :

:

:

10/30/20061

: ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.


Buff MagicMaterial Safety Data Sheet

Product and company identification1 .Common name

Rubbing compound for fiberglass and metal polish.SupplierMaterial uses


:

::






Buff Magic








Physical state Solid. (Paste.)


:

:

::::

Odor : Ammoniacal. (Slight.)

Hazard status :

2 .

Emergency overview : No specific hazard.USE WITH CARE.Follow good industrial hygiene practice.


Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light].Mutagenic effects: Not available.Teratogenic effects: Not available.

:

Color : White or a pale pink in color.This material is classified as not hazardous under OSHA regulations in the United States,the WHMIS in Canada and the NOM-018-STPS-2000 in Mexico.


Distillates (Petroleum), Hydrotreated Light 64742-47-8 10 - 30


3 .


Distillates (Petroleum), Hydrotreated Light 64742-47-8 10 - 30


Buff Magic

Mexico

Name CAS number %Distillates (Petroleum),Hydrotreated Light

Notregulated.

- 0 1 0 64742-47-8 10 - 30


UN number





Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:



May be combustible at high temperature.

Use dry chemical powder.


Special protectiveequipment for fire-fighters


:

:

5 .

Do not use water jet.Suitable :Not suitable :

Immediately contact emergency personnel. Eliminate all ignition sources. Keepunnecessary personnel away. Use suitable protective equipment. Do not touch or walkthrough spilled material.

If emergency personnel are unavailable, carefully scoop up spilled materials and use anon-sparking or explosion-proof means to transfer material to an appropriate container fordisposal by incineration. Avoid creating dusty conditions and prevent wind dispersal.






6 .

Keep container in a cool, well-ventilated area. Keep container tightly closed and sealeduntil ready for use. Avoid all possible sources of ignition (spark or flame).

Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources.

Handling and storageHandlingStorage

::

7 .

Distillates (Petroleum), Hydrotreated Light ACGIH TLV (United States, 1/2005). Skin TWA: 200 mg/m3 8 hour(s). Form: All forms.


Product name Exposure limitsUnited States

8 .


Buff Magic

Personal protection



Canada

Mexico

Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits. The engineering controls also need to keep gas, vapor or dust concentrationsbelow any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures :


: Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear.

Product name Exposure limits


Wash hands, forearms and face thoroughly after handling compounds and before eating,smoking and using the lavatory and at the end of the day. Follow good industrial hygienepractice.


: A

A respirator is not needed under normal and intended conditions of use.Lab coat.

Disposable vinyl gloves.

Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands

Solid. (Paste.)

8.5 (Conc. (% w/w): 1) [Basic.]1.09 (Water = 1)

Ammoniacal. (Slight.)White or a pale pink in color.

>1 compared with Butyl acetate.


pHRelative densityEvaporation rate

OdorColor

:

:::::

Flash point : Closed cup: 104.44°C (220°F). (Setaflash.)

9 .

Very slightly soluble in cold water, hot water.Solubility :


Buff Magic

The product is stable.Reactive with oxidizing materials.

Will not occur.


::

:

10 .

Flammable in the presence of the following materials or conditions: open flames, sparksand static discharge.Slightly flammable in the presence of the following materials or conditions: heat.

Conditions of reactivity :

Toxicological information11 .

Eyes : No known significant effects or critical hazards.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : No known significant effects or critical hazards.

Acute Effects


: Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light].Mutagenic effects: Not available.Teratogenic effects: Not available.

Not available.



Ecotoxicity data Species Period ResultProduct/ingredient name

Distillates (Petroleum), Hydrotreated Light Oncorhynchus mykiss (LC50 96 hour(s) 2.9 mg/l

:Environmental precautions : No known significant effects or critical hazards.

12 .


Waste disposal


13 .



Regulatory informationUN/


Buff Magic


Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: AmmoniaClean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

International lists

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Distillates (Petroleum), Hydrotreated LightSARA 311/312 MSDS distribution - chemical inventory - hazard identification: Distillates(Petroleum), Hydrotreated Light: Delayed (chronic) health hazard

:

Canada

United States

Mexico

15 .

10 0Health


Special

Classification :

HCS Classification Not regulated.TSCA : All components listed.U.S. Federal regulations :

:

WHMIS (Canada) Not regulated.:DSL : All components listed.

Not available.California prop. 65: No products were found.


State regulations :



Other information



HealthSpecial


USE WITH CARE.Label requirements (U.S.A.) :

:

:

16 .

01

0

HMIS RATING

Physical Hazard

Health 0

1Fire hazard






HAZARD RATINGS


Buff Magic



:

:

10/30/20061

: ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.



Pro PolishMaterial Safety Data Sheet

Product and company identification1 .Common name Pro Polish

Pro Polish is a fiberglass/gel coat cleaner, sealant/polish with UV inhibitors .SupplierMaterial uses


:

::









Irritating to respiratory system.

Severely irritating to eyes.


Irritating to skin.EyesSkinInhalationIngestion

Physical state Liquid.


:

:

::::


Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged contact with spray or mist may produce chronic eye irritation and severe skinirritation.

:

2 .

Emergency overview : WARNING !CAUSES SEVERE EYE IRRITATION.CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep containerclosed. Use only with adequate ventilation. Wash thoroughly after handling.


Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light]. Classified None. by NIOSH [Diethanolamine]. Classified3 (Not classifiable for humans.) by IARC [Diethanolamine]. Classified None. by OSHA[Isopropyl alcohol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3(Not classifiable for humans.) by IARC [Isopropyl alcohol]. Classified None. by OSHA,None. by NIOSH [Methanol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.

:

Hazard status : This material is classified hazardous under OSHA regulations in the United States, theWHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.


Pro Polish


Solvent naphtha (petroleum), heavy aliphatic 64742-96-7 5 - 10Solvent naphtha (petroleum), medium aliphatic 64742-88-7 5 - 10Distillates (Petroleum), Hydrotreated Light 64742-47-8 1 - 51-Tetradecene 1120-36-1 1 - 5Diethanolamine 111-42-2 1 - 5Methanol 67-56-1 0.1 - 0.5


Mexico

Name CAS number %Solvent naphtha (petroleum),heavy aliphatic

Notregulated.

- 1 2 0 64742-96-7 5 - 10

Solvent naphtha (petroleum),medium aliphatic

UN1223 - 1 1 0 64742-88-7 5 - 10

1-Tetradecene Notregulated.

- 2 1 0 1120-36-1 1 - 5

Diethanolamine Notregulated.

- 1 1 0 111-42-2 1 - 5

Distillates (Petroleum),Hydrotreated Light

Notregulated.

- 0 1 0 64742-47-8 1 - 5


UN number

3 .


Solvent naphtha (petroleum), heavy aliphatic 64742-96-7 5 - 10Solvent naphtha (petroleum), medium aliphatic 64742-88-7 5 - 10Distillates (Petroleum), Hydrotreated Light 64742-47-8 1 - 51-Tetradecene 1120-36-1 1 - 5Diethanolamine 111-42-2 1 - 5





Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:



CombustibleThese products are carbon oxides, nitrogen oxides. Some metallic oxides.


Fire-fighting measuresFlammability of the productProducts of combustionExtinguishing media

::

5 .



Pro Polish

Combustible liquid and vapor. Vapor may cause flash fire. Vapors may accumulate inlow or confined areas or travel a considerable distance to a source of ignition and flashback. Runoff to sewer may create fire or explosion hazard.



:

Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective equipment.

If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials), scoop upmaterial and place in a sealable, liquid-proof container for disposal. For large spills, dikespilled material or otherwise contain material to ensure runoff does not reach a waterway.Place spilled material in an appropriate container for disposal.






6 .


Avoid contact with eyes, skin and clothing. Keep container closed. Use only withadequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling.


Storage

:

:

7 .

Solvent naphtha (petroleum), heavy aliphatic ACGIH TLV (United States). TWA: 10 mg/m3 8 hour(s).

Solvent naphtha (petroleum), medium aliphatic Manufacturer (United States). TWA: 100 ppm 8 hour(s). Form: All forms.


Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). TWA: 15 mg/m3 10 hour(s). Form: All forms. TWA: 3 ppm 10 hour(s). Form: All forms.OSHA PEL 1989 (United States, 3/1989). TWA: 15 mg/m3 8 hour(s). Form: All forms. TWA: 3 ppm 8 hour(s). Form: All forms.





Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.

Methanol ACGIH TLV (United States, 1/2005). Skin STEL: 328 mg/m3 15 minute(s). Form: All forms. STEL: 250 ppm 15 minute(s). Form: All forms. TWA: 262 mg/m3 8 hour(s). Form: All forms.

United States

Canada

8 .



Pro Polish

Personal protection

TWA: 200 ppm 8 hour(s). Form: All forms.



Diethanolamine ACGIH TLV (United States, 1/2005). Skin TWA: 2 mg/m3 8 hour(s). Form: All forms. TWA: 0.46 ppm 8 hour(s). Form: All forms.

Mexico

Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits.

Hygiene measures :






: B

Natural rubber (latex).A respirator is not needed under normal and intended conditions of use.Lab coat.Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands

Weighted average: 129.57°C (265.2°F)

Liquid.

Basic.

Weighted average: -2.27°C (27.9°F)1.09 (Water = 1)

Weighted average: 1.54 (Air = 1)Weighted average: 1.96 kPa (14.7 mm Hg) (at 20°C)


>1 compared with Water = 1Kinematic (40C): The highest known value is 1 to 2 cSt (Solvent naphtha (petroleum),medium aliphatic)


pH

Relative densityVapor pressureVapor densityEvaporation rateViscosity

:

::::::::

Flash point : Closed cup: 104.44°C (220°F). (Setaflash.)The lowest known value is 229°C (444.2°F) (Solvent naphtha (petroleum), mediumaliphatic).

:Auto-ignition temperature

Flammable limits : The greatest known range is Lower: 1% Upper: 6% (Solvent naphtha (petroleum),medium aliphatic)

9 .

Easily soluble in methanol, acetone.Partially soluble in cold water, hot water.

Solubility :


Pro Polish


Will not occur.


::

:

10 .

Flammable in the presence of the following materials or conditions: open flames, sparksand static discharge.Slightly flammable in the presence of the following materials or conditions: heat.

Conditions of reactivity :


Product/ingredient name Test Result Route SpeciesSolvent naphtha (petroleum), mediumaliphatic

LD50LD50

>5000 mg/kg>2000 mg/kg

OralDermal

RatRabbit

Diethanolamine LD50LD50LD50

2200 mg/kg3300 mg/kg12200 mg/kg

OralOralDermal

RabbitMouseRabbit

11 .

Eyes : Severely irritating to eyes.Skin : Irritating to skin.Inhalation : Irritating to respiratory system.Ingestion : No known significant effects or critical hazards.

Acute Effects


: Carcinogenic effects: Classified A3 (Proven for animals.) by ACGIH [Distillates(Petroleum), Hydrotreated Light]. Classified None. by NIOSH [Diethanolamine]. Classified3 (Not classifiable for humans.) by IARC [Diethanolamine]. Classified None. by OSHA[Isopropyl alcohol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3(Not classifiable for humans.) by IARC [Isopropyl alcohol]. Classified None. by OSHA,None. by NIOSH [Methanol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.

These products are carbon oxides and waterThe product itself and its products of degradation are not toxic.





Distillates (Petroleum), Hydrotreated Light Oncorhynchus mykiss (LC50) 96 hour(s) 2.9 mg/lDiethanolamine Pimephales promelas (LC50)

Daphnia magna (LC50)Pimephales promelas (LC50)Daphnia magna (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)

96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)96 hour(s)

100 mg/l100 mg/l>100 mg/l>100 mg/l1370 mg/l1480 mg/l

::


12 .


Pro Polish


Waste disposal


13 .





Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: MethanolClean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Diethanolamine; Isopar MSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Diethanolamine: Immediate (acute) health hazard; Isopar M: Delayed (chronic) healthhazard

SARA 313

Canada

United States

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

Silica crystalline, quartz Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risklevel

Maximumacceptable dosagelevel

15 .

Diethanolamine 111-42-2 1 - 5

Diethanolamine 111-42-2 1 - 5

Form R - ReportingrequirementsSupplier notification

:

:

HCS Classification Irritating materialU.S. Federal regulations TSCA 8(a) PAIR: Decamethylcyclopentasiloxane; Trade secret

TSCA 8(b) inventory: All components listed.::

Rhode Island RTK hazardous substances: MethanolPennsylvania RTK: Diethanolamine: (environmental hazard, generic environmentalhazard); Methanol: (environmental hazard, generic environmental hazard); Silicacrystalline, quartz: (generic environmental hazard); Isopropyl alcohol: (environmentalhazard, generic environmental hazard)Florida: MethanolMinnesota: MethanolMassachusetts RTK: Diethanolamine; Methanol; Silica crystalline, quartz; IsopropylalcoholNew Jersey: Diethanolamine; Methanol; Silica crystalline, quartz; Isopropyl alcoholNew Jersey spill list: MethanolWARNING: This product contains a chemical known to the State of California to causecancer.

State regulations :


Pro Polish


Mexico

11 0Health


Special

Classification :

WHMIS (Canada)

CEPA DSL: All components listed.

CEPA NDSL: C10-16 Alkenes

Canadian NPRI: Methanol

Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

:




Other information



HealthSpecial


CAUSES SEVERE EYE IRRITATION.CAUSES RESPIRATORY TRACT AND SKIN IRRITATION.


:

:

16 .

01

1



:

:

10/30/20061

:

HMIS RATING

Physical Hazard

Health 1

1Fire hazard

Personal protection B0

ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of HazardousMaterials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2.Registration SOR/88-64, 31 December 1987. Hazardous Products Act "IngredientDisclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules,Clear Language version 2005. - Official Mexican Standards NOM-018-STPS-2000 andNOM-004-SCT2-1994.





HAZARD RATINGS


Pro Polish



Serious ShineMaterial Safety Data Sheet

Product and company identification1 .Common name Serious Shine

Cleaner and polish for fiberglass, glass, mirror, and most painted and solid surfaces.SupplierMaterial uses


:

::









Irritating to respiratory system.

Irritating to eyes.


Irritating to skin.EyesSkinInhalationIngestion

Physical state Liquid. (Aerosol.)


:

:

::::


Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged contact with spray or mist may produce chronic eye irritation and severe skinirritation. Repeated or prolonged exposure to the substance can produce target organdamage.

:

Odor : Petroleum. (Slight.)

2 .

Emergency overview : WARNING !CONTENTS UNDER PRESSURE.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.CONTAINS MATERIAL WHICH CAUSES DAMAGE TO TARGET ORGANS.Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep away fromheat, sparks and flame. Do not puncture or incinerate container. Keep container closed.Use only with adequate ventilation. Wash thoroughly after handling.


Carcinogenic effects: Classified None. by OSHA [Isopropyl alcohol]. Classified A4 (Notclassifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC[Isopropyl alcohol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.

:

Hazard status : This material is classified hazardous under OSHA regulations in the United States, theWHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.


Serious Shine


Stoddard Solvent 8052-41-3 5 - 10Propane 74-98-6 5 - 10Isopropyl alcohol 67-63-0 1 - 5n-Butane 106-97-8 1 - 5


Mexico

Name CAS number %Stoddard Solvent UN1268 20000 mg/m3 1 2 0 8052-41-3 5 - 10Propane UN1978 2100 ppm 1 4 0 74-98-6 5 - 10Isopropyl alcohol UN1219 2000 ppm 1 2 0 67-63-0 1 - 5n-Butane UN1011 - 0 4 0 106-97-8 1 - 5


UN number

3 .


Stoddard Solvent 8052-41-3 5 - 10Propane 74-98-6 5 - 10Isopropyl alcohol 67-63-0 1 - 5n-Butane 106-97-8 1 - 5





Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:



Non-flammable.These products are carbon oxides.

Use dry chemical, carbon dioxide, water spray (fog) or foam.

Fire-fighting measuresFlammability of the productProducts of combustionExtinguishing media



::

:

5 .

Do not use water jet.Suitable :Not suitable :


Serious Shine

Immediately contact emergency personnel. Eliminate all ignition sources. Keepunnecessary personnel away. Use suitable protective equipment. Do not touch or walkthrough spilled material.

If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion-proof means to transfer material to a sealable, appropriatecontainer for disposal. For large spills, dike spilled material or otherwise contain materialto ensure runoff does not reach a waterway. Place spilled material in an appropriatecontainer for disposal.






6 .

Store in a segregated and approved area. Keep container in a cool, well-ventilated area.Keep container tightly closed and sealed until ready for use. Avoid all possible sources ofignition (spark or flame).

Avoid contact with eyes, skin and clothing. Keep container closed. Use only withadequate ventilation. Avoid breathing vapor or mist. Keep away from heat, sparks andflame. To avoid fire or explosion, dissipate static electricity during transfer by groundingand bonding containers and equipment before transferring material. Do not puncture orincinerate container. Wash thoroughly after handling.


Storage

:

:

7 .

Stoddard Solvent ACGIH TLV (United States, 1/2005). TWA: 525 mg/m3 8 hour(s). Form: All forms. TWA: 100 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). CEIL: 1800 mg/m3 15 minute(s). Form: All forms. TWA: 350 mg/m3 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 2900 mg/m3 8 hour(s). Form: All forms. TWA: 500 ppm 8 hour(s). Form: All forms.

Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). TWA: 1800 mg/m3 10 hour(s). Form: All forms. TWA: 1000 ppm 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 1800 mg/m3 8 hour(s). Form: All forms. TWA: 1000 ppm 8 hour(s). Form: All forms.

Isopropyl alcohol ACGIH TLV (United States, 1/2005). STEL: 400 ppm 15 minute(s). Form: All forms. TWA: 200 ppm 8 hour(s). Form: All forms.NIOSH REL (United States, 12/2001). STEL: 1225 mg/m3 15 minute(s). Form: All forms. STEL: 500 ppm 15 minute(s). Form: All forms. TWA: 980 mg/m3 10 hour(s). Form: All forms. TWA: 400 ppm 10 hour(s). Form: All forms.OSHA PEL (United States, 8/1997). TWA: 980 mg/m3 8 hour(s). Form: All forms. TWA: 400 ppm 8 hour(s). Form: All forms.

n-Butane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.



8 .


Serious Shine

NIOSH REL (United States, 12/2001). TWA: 1900 mg/m3 10 hour(s). Form: All forms. TWA: 800 ppm 10 hour(s). Form: All forms.OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m3 8 hour(s). Form: All forms

Personal protection

Stoddard Solvent ACGIH TLV (United States, 1/2005). TWA: 525 mg/m3 8 hour(s). Form: All forms. TWA: 100 ppm 8 hour(s). Form: All forms.

Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.

Isopropyl alcohol ACGIH TLV (United States, 1/2005). STEL: 400 ppm 15 minute(s). Form: All forms. TWA: 200 ppm 8 hour(s). Form: All forms.

n-Butane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms

Stoddard Solvent NOM-010-STPS (Mexico, 9/2000). CCT: 1050 mg/m3 15 minute(s). Form: All forms. CCT: 200 ppm 15 minute(s). Form: All forms. CPT: 523 mg/m3 8 hour(s). Form: All forms. CPT: 100 ppm 8 hour(s). Form: All forms.

Propane ACGIH TLV (United States, 1/2005). TWA: 1000 ppm 8 hour(s). Form: All forms.Simple asphyxiant.

Isopropyl alcohol NOM-010-STPS (Mexico, 9/2000). Skin CCT: 1225 mg/m3 15 minute(s). Form: All forms. CCT: 500 ppm 15 minute(s). Form: All forms. CPT: 980 mg/m3 8 hour(s). Form: All forms. CPT: 400 ppm 8 hour(s). Form: All forms.

n-Butane NOM-010-STPS (Mexico, 9/2000). CPT: 1900 mg/m3 8 hour(s). Form: All forms CPT: 800 ppm 8 hour(s). Form: All forms

Canada

Mexico

Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor ormist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits. The engineering controls also need to keep gas, vapor or dust concentrationsbelow any lower explosive limits. Use explosion-proof ventilation equipment.




: B

Natural rubber (latex).

Lab coat.A respirator is not needed under normal and intended conditions of product use.

Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands


Serious Shine

Hygiene measures :



Weighted average: 105.03°C (221.1°F)

Liquid. (Aerosol.)

95.89% (w/w)

Neutral.



Petroleum. (Slight.)


Weighted average: 0.39 compared with Butyl acetate.


pH

Relative densityVapor pressureVapor densityVolatilityEvaporation rate

Odor

1795 (g/l).VOC

:

::::::::::

The lowest known value is 232.22°C (450°F) (Stoddard Solvent).:Auto-ignition temperature

9 .

Miscible in water.Solubility :


Will not occur.


::

:

10 .

May be combustible at high temperature.Conditions of reactivity :


Product/ingredient name Test Result Route SpeciesIsopropyl alcohol LD50

LD50LD50LD50LC50

5045 mg/kg6410 mg/kg3600 mg/kg12800 mg/kg16000 ppm (8 hour(s))

OralOralOralDermalInhalation

RatRabbitMouseRabbitRat

n-Butane LC50 658 mg/l (4 hour(s)) Inhalation Rat

11 .

Eyes : Irritating to eyes.Skin : Irritating to skin.Inhalation : Irritating to respiratory system.Ingestion : No known significant effects or critical hazards.

Acute Effects


: Carcinogenic effects: Classified None. by OSHA [Isopropyl alcohol]. Classified A4 (Notclassifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC[Isopropyl alcohol].Mutagenic effects: Classified None. for humans [Isopropyl alcohol].Teratogenic effects: Not available.

Target organs : Contains material which causes damage to the following organs: kidneys, the nervoussystem, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.


Serious Shine

These products are carbon oxides and water.The product itself and its products of degradation are not toxic.





Isopropyl alcohol Pimephales promelas (EC50)Lepomis macrochirus (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)Pimephales promelas (LC50)


10000 mg/l>1400 mg/l6550 mg/l9640 mg/l10400 mg/l11130 mg/l

::


12 .

Do not puncture or incinerate container. Disposal of this product, solutions and anyby-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional and local authority requirements.

Waste disposal


13 .

Transport information14 .NAERG : 126Regulatoryinformation

-

DOT Classification

TDG Classification 2.2

2

ORM-D -

UN1950AEROSOLS -

UN numberProper shipping name Class PG Label

-

UN / IMDG / IATAClassification

UN1950AEROSOLS 2.2 -

2

-

Additionalinformation

UN DOT TDGIMDGForbidden

IATA-


SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Stoddard Solvent; Propane; Isopropylalcohol; n-ButaneSARA 311/312 MSDS distribution - chemical inventory - hazard identification: StoddardSolvent: Fire hazard, Immediate (acute) health hazard; Propane: Fire hazard, Suddenrelease of pressure; Isopropyl alcohol: Fire hazard, Immediate (acute) health hazard,Delayed (chronic) health hazard; n-Butane: Fire hazard, Sudden release of pressure

United States

15 .

HCS Classification

TSCA : All components listed.

Compressed gasIrritating materialTarget organ effects

U.S. Federal regulations :

:


Serious Shine

Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: Propane; n-ButaneClean Air Act (CAA) 112 regulated flammable substances: Propane; n-ButaneClean Air Act (CAA) 112 regulated toxic substances: No products were found.


SARA 313

Canada

Mexico

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

11 0Health


Special

Classification :

Isopropyl alcohol 67-63-0 1 - 5

Isopropyl alcohol 67-63-0 1 - 5

Form R - ReportingrequirementsSupplier notification

:

:

WHMIS (Canada) Class A: Compressed gas.Class D-2B: Material causing other toxic effects (Toxic).

:

DSL : All components listed.

Pennsylvania RTK: Stoddard Solvent: (generic environmental hazard); Propane: (genericenvironmental hazard); Isopropyl alcohol: (environmental hazard, generic environmentalhazard); n-Butane: (generic environmental hazard)Massachusetts RTK: Stoddard Solvent; Propane; Isopropyl alcohol; n-ButaneNew Jersey: Stoddard Solvent; Propane; Isopropyl alcohol; n-ButaneCalifornia prop. 65: No products were found.


State regulations :



Other informationCONTENTS UNDER PRESSURE.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.CONTAINS MATERIAL WHICH CAUSES DAMAGE TO TARGET ORGANS.


16 .


Serious Shine



HealthSpecial


:

:

01

1



:

:

10/30/20061

:

HMIS RATING

Physical Hazard

Health * 1

1Fire hazard








HAZARD RATINGS


Serious Marine Cleaner (SMC) Concentrate

Directions for proper use: dilute 1 part of product in 4 parts of water.When used, in diluted water solution, this product is non-hazardous.

Material Safety Data Sheet


Serious Marine Cleaner is a concentrate that has been designed to clean a multitude ofsurfaces including fiberglass, vinyl, carpet, rubber, teak and acrylic canvas.

Supplier

Material uses


:

:

:










Corrosive to the respiratory system.

Corrosive to eyes.

May be harmful if swallowed. May cause burns to mouth, throat and stomach.

Corrosive to the skin. May cause sensitization by skin contact.EyesSkinInhalationIngestion



:

:

::::


Repeated skin exposure can produce local skin destruction or dermatitis. Repeated orprolonged exposure to the substance can produce lung damage. Repeated or prolongedcontact with spray or mist may produce chronic eye irritation and severe skin irritation.

:

Odor : Citrus.

2 .

Emergency overview : DANGER !CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED.

When used, in diluted water solution, this product is non-hazardous.Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Keepcontainer closed. Use only with adequate ventilation. Wash thoroughly after handling.



Color : Blue-Green.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the

WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 in Mexico.





Ethylene oxide-nonylphenol polymer 9016-45-9 1 - 53-Butoxypropan-2-ol 5131-66-8 1 - 5Tetrasodium EDTA 64-02-8 1 - 5Sodium hydroxide 1310-73-2 1 - 5Sodium Silicate 1344-09-8 1 - 5


Mexico

Name CAS number %3-Butoxypropan-2-ol Not

regulated.- 2 2 0 5131-66-8 1 - 5

Ethylene oxide-nonylphenolpolymer

Notregulated.

- 1 1 0 9016-45-9 1 - 5

Sodium Xylene Sulfonate Notregulated.

- 1 0 0 1330-72-7 1 - 5

Tetrasodium EDTA Notregulated.

- 1 0 0 64-02-8 1 - 5

Sodium Silicate Notregulated.

- 1 0 0 1344-09-8 1 - 5

Sodium hydroxide UN1823 10 mg/m3 3 0 0 1310-73-2 1 - 5


UN number

3 .


Sodium Xylene Sulfonate 1330-72-7 1 - 5Ethylene oxide-nonylphenol polymer 9016-45-9 1 - 53-Butoxypropan-2-ol 5131-66-8 1 - 5Tetrasodium EDTA 64-02-8 1 - 5Sodium hydroxide 1310-73-2 1 - 5Sodium Silicate 1344-09-8 1 - 5

First aid measures4 .Eye contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with

plenty of water for at least 20 minutes. Get medical attention immediately.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention immediately.Do not induce vomiting. Never give anything by mouth to an unconscious person. Getmedical attention immediately.

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:


In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Getmedical attention immediately.




Non-flammable.





:

:

5 .



If emergency personnel are unavailable, contain spilled material. For small spills, addabsorbent (soil may be used in the absence of other suitable materials), scoop upmaterial and place in a sealable, liquid-proof container for disposal. For large spills, dikespilled material or otherwise contain material to ensure runoff does not reach a waterway.Place spilled material in an appropriate container for disposal.






6 .


Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handlin


Storage

:

:

7 .

Sodium hydroxide ACGIH TLV (United States, 1/2005). CEIL: 2 mg/m3 Form: All forms.NIOSH REL (United States, 12/2001). CEIL: 2 mg/m3 Form: All forms.OSHA PEL (United States, 8/1997). TWA: 2 mg/m3 8 hour(s). Form: All forms.



Sodium hydroxide CSST (Canada, 2001). TWA: 2 mg/m3 8 hour(s).

Sodium hydroxide NOM-010-STPS (Mexico, 9/2000). LMPE-P: 2 mg/m3 Form: All forms

United States

Canada

Mexico

8 .







Personal protection

Hygiene measures :




: J

Synthetic apron.

Nitrile gloves.Vapor respirator.

Splash goggles.

Eyes

:

SkinRespiratory

:::

Hands

100°C (212°F)

Liquid.

12.8 [Basic.]



Citrus.Blue-Green.


<1 (Ethylene oxide-nonylphenol polymer) compared with Ether (anhydrous).


pH


OdorColor

::::::::::

9 .

Easily soluble in cold water, hot water, methanol, acetone.Solubility :

The product is stable.Highly reactive or incompatible with the following materials: acids and moisture.Reactive with oxidizing materials.Will not occur.


::

:

10 .



Product/ingredient name Test Result Route SpeciesEthylene oxide-nonylphenol polymer LD50 1310 mg/kg Oral Rat3-Butoxypropan-2-ol LD50


OralDermal

RatRabbit

Sodium Silicate LD50LD50

1960 mg/kg>4640 mg/kg

OralDermal

RatRabbit

11 .

Eyes : Corrosive to eyes.Acute Effects




Skin : Corrosive to the skin. May cause sensitization by skin contact.Inhalation : Corrosive to the respiratory system.Ingestion : May be harmful if swallowed. May cause burns to mouth, throat and stomach.



These products are carbon oxides and water, nitrogen oxides. Some metallic oxides.The products of degradation are less toxic than the product itself.





Ethylene oxide-nonylphenol polymer Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)


1.3 mg/l4.7 mg/l7.6 mg/l7.9 mg/l>10 mg/l>1000 mg/l

Tetrasodium EDTA Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)

96 hour(s)96 hour(s)96 hour(s)96 hour(s)

486 mg/l1030 mg/l2070 mg/l3092 mg/l

::


12 .


Waste disposal


13 .

Transport information14 .NAERG : 153Regulatoryinformation

8

8

CORROSIVE

DOT Classification

TDG Classification 8

8

CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)

III

UN3267CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)

III

UN numberProper shipping name Class PG Label

UN3267

UN / IMDG / IATAClassification

UN3267CORROSIVE LIQUID, BASIC, ORGANIC,N.O.S. (Sodium hydroxide)

8 III

8




EXEMPTED:For container of 1 gallon

or less.


or less.


or less.

Additionalinformation

UN DOT TDGIMDGEXEMPTED:

For container of 1 gallon or ess.

IATAEXEMPTED:

For container of 1 gallonor less.


Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: Sodium hydroxide; Sodium hydroxide; Formaldehyde;AcetaldehydeClean Air Act (CAA) 112 accidental release prevention: Formaldehyde; AcetaldehydeClean Air Act (CAA) 112 regulated flammable substances: AcetaldehydeClean Air Act (CAA) 112 regulated toxic substances: Formaldehyde

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Tetrasodium EDTA; Sodium hydroxideSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Tetrasodium EDTA: Immediate (acute) health hazard; Sodium hydroxide: Immediate(acute) health hazard

Canada

United States

1,4-Dioxane Yes. No. Yes. No.Acetaldehyde Yes. No. 90 µg/day (inhalation) No.Formaldehyde Yes. No. Yes. No.



15 .

HCS Classification Corrosive materialSensitizing materialTarget organ effects

U.S. Federal regulations TSCA 8(a) PAIR: Ethylene oxide-nonylphenol polymer; AcetaldehydeTSCA 8(b) inventory: All components listed.TSCA 8(d) H and S data reporting: 3-Butoxypropan-2-ol: 1994

:

:

WHMIS (Canada) Class D-2B: Material causing other toxic effects (Toxic).Class E: Corrosive material

:

Connecticut carcinogen reporting list.: FormaldehydeRhode Island RTK hazardous substances: FormaldehydePennsylvania RTK: Sodium hydroxide: (environmental hazard, generic environmentalhazard); Sodium hydroxide: (environmental hazard, generic environmental hazard); 1,4-Dioxane: (special hazard, environmental hazard, generic environmental hazard);Formaldehyde: (special hazard, environmental hazard, generic environmental hazard);Acetaldehyde: (environmental hazard, generic environmental hazard)Florida: FormaldehydeMinnesota: FormaldehydeMichigan critical material: FormaldehydeMassachusetts RTK: Sodium hydroxide; Glycine, n,n-bis(carboxymethyl)-, trisodium salt;Sodium hydroxide; 1,4-Dioxane; Formaldehyde; AcetaldehydeNew Jersey: Sodium hydroxide; Sodium hydroxide; 1,4-Dioxane; Formaldehyde;AcetaldehydeLouisiana RTK reporting list: FormaldehydeWARNING: This product contains a chemical known to the State of California to causecancer.

State regulations :





Mexico

03 0Health


Special

Classification :

CEPA DSL: All components listed.

CEPA NDSL: Glycine, n,n'-1,2-ethanediylbis-, disodium salt




Other information



HealthSpecial


CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.MAY CAUSE ALLERGIC SKIN REACTION.MAY BE HARMFUL IF SWALLOWED.

When used, in diluted water solution, this product is non-hazardous.


:

:

16 .

00

3



:

:

10/30/20061

:

HMIS RATING

Physical Hazard

Health 3

0Fire hazard

Personal protection J0







HAZARD RATINGS


Serious Marine Cleaner (SMC)Material Safety Data Sheet

Product and company identification1 .Common name Serious Marine Cleaner (SMC)

Serious Marine Cleaner is a concentrate that has been designed to clean a multitude ofsurfaces including fiberglass, vinyl, carpet, rubber, teak and acrylic canvas.

Supplier

Material uses


:

:

:










Moderately irritating to eyes.

May be harmful if swallowed.




:

:

::::


Repeated or prolonged exposure is not known to aggravate any medical condition.:

Odor : Citrus.

2 .

Emergency overview : WARNING!MAY BE HARMFUL IF SWALLOWED.Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Wash thoroughly after handling



Color : Blue-Green.Hazard status : This material is classified hazardous under OSHA regulations in the United States, the

WHMIS Controlled Product Regulation in Canada and the NOM-018-STPS-2000 inMexico.


Serious Marine Cleaner (SMC)


Ethylene oxide-nonylphenol polymer 9016-45-9 0.5 - 13-Butoxypropan-2-ol 5131-66-8 0.5 - 1


Mexico

Name CAS number %3-Butoxypropan-2-ol Not

regulated.- 2 2 0 5131-66-8 0.5 - 1

Ethylene oxide-nonylphenolpolymer

Notregulated.

- 1 1 0 9016-45-9 0.5 - 1

Sodium Xylene Sulfonate Notregulated.

- 1 0 0 1330-72-7 0.5 - 1


UN number

3 .


Sodium Xylene Sulfonate 1330-72-7 0.5 - 1Ethylene oxide-nonylphenol polymer 9016-45-9 0.5 - 13-Butoxypropan-2-ol 5131-66-8 0.5 - 1





Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:



Non-flammable.





:

:

5 .


Use suitable protective equipment.

For small spills, add absorbent (soil may be used in the absence of other suitablematerials), scoop up material and place in a sealable, liquid-proof container for disposal.For large spills, dike spilled material or otherwise contain material to ensure runoff doesnot reach a waterway. Place spilled material in an appropriate container for disposal.






6 .




Do not ingest. Do not get in eyes or on skin or clothing. Keep container closed. Use onlywith adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handlin


Storage

:

:

7 .


Personal protection

Consult local authorities for acceptable exposure limits.

8 .


Hygiene measures :




: B

Natural rubber (latex).A respirator is not needed under normal and intended conditions of use.Lab coat.Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands

100°C (212°F)

Liquid.

<11 [Basic.]



Citrus.Blue-Green.


<1 (Ethylene oxide-nonylphenol polymer) compared with Ether (anhydrous).


pH


OdorColor

::::::::::

9 .

Miscible in water.Solubility :


Will not occur.


::

:

10 .





Product/ingredient name Test Result Route SpeciesEthylene oxide-nonylphenol polymer LD50 1310 mg/kg Oral Rat3-Butoxypropan-2-ol LD50


OralDermal

RatRabbit

11 .

Eyes : Moderately irritating to eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : May be harmful if swallowed.

Acute Effects



These products are carbon oxides and water.The products of degradation are less toxic than the product itself.





Ethylene oxide-nonylphenol polymer Lepomis macrochirus (LC50)Oncorhynchus mykiss (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)Lepomis macrochirus (LC50)


1.3 mg/l4.7 mg/l7.6 mg/l7.9 mg/l>10 mg/l>1000 mg/l

::


12 .


Waste disposal


13 .



NAERG : Not applicable.Regulatory information

UN/




Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: Sodium hydroxide; Sodium hydroxide; Formaldehyde;AcetaldehydeClean Air Act (CAA) 112 accidental release prevention: Formaldehyde; AcetaldehydeClean Air Act (CAA) 112 regulated flammable substances: AcetaldehydeClean Air Act (CAA) 112 regulated toxic substances: Formaldehyde

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.

Canada

United States

1,4-Dioxane Yes. No. Yes. No.Acetaldehyde Yes. No. 90 µg/day (inhalation) No.Formaldehyde Yes. No. Yes. No.



15 .

HCS Classification Non hazardous.U.S. Federal regulations TSCA 8(a) PAIR: Ethylene oxide-nonylphenol polymer; Acetaldehyde

TSCA 8(b) inventory: All components listed.TSCA 8(d) H and S data reporting: 3-Butoxypropan-2-ol: 1994

::

WHMIS (Canada)CEPA DSL: All components listed.

CEPA NDSL: Glycine, n,n'-1,2-ethanediylbis-, disodium salt

Not controlled under WHMIS (Canada).:

Connecticut carcinogen reporting list.: FormaldehydeRhode Island RTK hazardous substances: FormaldehydePennsylvania RTK: Sodium hydroxide: (environmental hazard, generic environmentalhazard); Sodium hydroxide: (environmental hazard, generic environmental hazard); 1,4-Dioxane: (special hazard, environmental hazard, generic environmental hazard);Formaldehyde: (special hazard, environmental hazard, generic environmental hazard);Acetaldehyde: (environmental hazard, generic environmental hazard)Florida: FormaldehydeMinnesota: FormaldehydeMichigan critical material: FormaldehydeMassachusetts RTK: Sodium hydroxide; Glycine, n,n-bis(carboxymethyl)-, trisodium salt;Sodium hydroxide; 1,4-Dioxane; Formaldehyde; AcetaldehydeNew Jersey: Sodium hydroxide; Sodium hydroxide; 1,4-Dioxane; Formaldehyde;AcetaldehydeLouisiana RTK reporting list: FormaldehydeWARNING: This product contains a chemical known to the State of California to causecancer.

State regulations :





Mexico

01 0Health


Special

Classification : HAZARD RATINGS4- Extreme3- Serious2- Moderate1- Slight0- Minimal


Other information



HealthSpecial


MAY BE HARMFUL IF SWALLOWED.Label requirements (U.S.A.) :

:

:

16 .

00

1



:

:

10/30/20061

:

HMIS RATING

Physical Hazard

Health 1

0Fire hazard








HAZARD RATINGS


Snap-StickMaterial Safety Data Sheet


To lubricate and protect snaps and zippers.SupplierMaterial uses


:

::

:CHEMTREC, U.S. Domestic: (800) 424-9300CHEMTREC, International: (703) 527-3887





Snap-Stick





Slightly irritating to the eyes.



Physical state Solid.


:

:

::::


Repeated exposure of the eyes to a low level of dust can produce eye irritation.:

Odor : Odorless.

Hazard status :

2 .

Emergency overview : No specific hazard.USE WITH CARE.Follow good industrial hygiene practice.



Color : White.This material is classified as not hazardous under OSHA regulations in the United States,the WHMIS in Canada and the NOM-018-STPS-2000 in Mexico.


Mineral Oil 8042-47-5 5 - 10


3 .


Mineral Oil 8042-47-5 5 - 10


Snap-Stick

Mexico

Name CAS number %Mineral Oil Not

regulated.- 0 1 0 8042-47-5 5 - 10


UN number





Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:



May be combustible at high temperature.





:

:

5 .



If emergency personnel are unavailable, vacuum or carefully scoop up spilled materialand place in an appropriate container for disposal by incineration. Avoid creating dustyconditions and prevent wind dispersal.






6 .

Keep container tightly closed. Keep container in a cool, well-ventilated area.Wash thoroughly after handling.

Handling and storageHandlingStorage

::

7 .

Mineral Oil ACGIH TLV (United States). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist



8 .


Snap-Stick

Personal protection

Mineral Oil ACGIH TLV (Canada). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist

Mineral Oil ACGIH TLV (United States). STEL: 10 mg/m3 15 minute(s). Form: Mist TLV: 5 mg/m3 Form: Mist

Canada

Mexico

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol airborne levels. If this product contains ingredients with exposure limits, useprocess enclosures, local exhaust ventilation or other engineering controls to keep workerexposure below any recommended or statutory limits.

Hygiene measures :







: A

A respirator is not needed under normal and intended conditions of use.Lab coat.

Disposable vinyl gloves.

Safety glasses.

Eyes

:

SkinRespiratory

:::

Hands

Solid.

40 to 50°C (104 to 122°F)Weighted average: 0.83 (Water = 1)

The highest known value is >1 (Air = 1) (Paraffin wax).The highest known value is <1e-005 kPa (<0.0001 mm Hg) (at 20°C) (Paraffin wax).

Odorless.White.

Melting/freezing point

<1 (Paraffin wax) compared with Ether (anhydrous).


Relative densityVapor pressureVapor density

Evaporation rate

OdorColor

:

::::::

:

Flash point : The lowest known value is Closed cup: 232°C (449.6°F). (Paraffin wax)

9 .

Insoluble in cold water, hot water.Solubility :


Snap-Stick


Will not occur.


::

:

10 .

Not available.Conditions of reactivity :

Toxicological information11 .

Eyes : Slightly irritating to the eyes.Skin : No known significant effects or critical hazards.Inhalation : No known significant effects or critical hazards.Ingestion : No known significant effects or critical hazards.

Acute Effects



Not available.


Products of degradation :Environmental precautions : No known significant effects or critical hazards.

12 .


Waste disposal


13 .





Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean Air Act (CAA) 112 accidental release prevention: No products were found.Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.

United States

15 .

HCS Classification Not regulated.TSCA : All components listed.U.S. Federal regulations :

:

Not available.State regulations :


Snap-Stick


Canada

Mexico

00 0Health


Special

Classification :

WHMIS (Canada) Not regulated.:DSL : All components listed.

California prop. 65: No products were found.




Other information



HealthSpecial


USE WITH CARE.Label requirements (U.S.A.) :

:

:

16 .

00

0



:

:

11/30/20061

:

HMIS RATING

Physical Hazard

Health 0

0Fire hazard








HAZARD RATINGS


Serious Pad Cleaner

Not available.

Solid.

GHS product identifier

Other means of identification

Product type

Emergency telephone number (with hours of operation)

Section 1. Identification:

:

:

:

Supplier's details :

Identified uses

Serious Pad Cleaner

SAFETY DATA SHEETConforms to HazCom 2012/United States


CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887

Not available.

Section 2. Hazards identification

SKIN CORROSION/IRRITATION - Category 1BSERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Classification of the substance or mixture

:

Signal word : Danger

Hazard statements : Causes severe skin burns and eye damage.May cause respiratory irritation.

Hazard pictograms :

Precautionary statements

Prevention : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Use only outdoors or in a well-ventilated area. Avoid breathing dust. Wash hands thoroughly after handling.

GHS label elements

General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

1/11Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)www.kmkregservices.com www.askdrluc.com www.ghssmart.com

Serious Pad Cleaner

Section 2. Hazards identificationResponse : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED:Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or physician.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

Sodium carbonate 30 - 60 497-19-8Disodium metasilicate 10 - 30 6834-92-0Trisodium orthophosphate 10 - 30 7601-54-9Benzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts 1 - 5 68081-81-2Alcohols, C9-11, ethoxylated 1 - 5 68439-46-3Undecan-1-ol, ethoxylated 1 - 5 34398-01-1

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Other means of identification

: Not available.

CAS number : Not applicable.

Substance/mixture

Product code : Not available.

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician.

Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Inhalation :

:

Description of necessary first aid measures


Serious Pad Cleaner

Section 4. First aid measures

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.Loosen tight clothing such as a collar, tie, belt or waistband.

Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes.Chemical burns must be treated promptly by a physician. Wash clothing before reuse.Clean shoes thoroughly before reuse.

Skin contact

Ingestion :

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : May cause respiratory irritation.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Causes severe burns.

Causes serious eye damage.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing

Adverse symptoms may include the following:stomach pains

Adverse symptoms may include the following:pain or irritationrednessblistering may occur

:

:

:

Eye contact : Adverse symptoms may include the following:painwateringredness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary


Serious Pad Cleaner

Section 5. Fire-fighting measures

No special measures are required.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxidephosphorus oxidesmetal oxide/oxides

No specific fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters


Extinguishing media

:

:

:

None known.

Suitable extinguishing media

:

Unsuitable extinguishing media

:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures

:

: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Small spill

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed,labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

:


Serious Pad Cleaner

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

:

Precautions for safe handling

Sodium carbonate OSHA PEL (United States). TWA: 15 mg/m³ 8 hours.

Trisodium orthophosphate AIHA WEEL (United States, 10/2011). STEL: 5 mg/m³ 15 minutes.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

Skin protection


Serious Pad Cleaner

Section 8. Exposure controls/personal protectionHand protection

Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Respiratory protection :

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Solid.

Not available.

Not available.

Not available.

Not available.

Not available.

Citrus.Odor

pH

Orange.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: >93.333°C (>200°F)

Not available.

11.9 [Conc. (% w/w): 1%]

Viscosity Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.


Serious Pad Cleaner

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials: oxidizing materials and acids.

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Carcinogenicity

Specific target organ toxicity (single exposure)

Disodium metasilicate Category 3 Not applicable. Respiratory tract irritationTrisodium orthophosphate Category 3 Not applicable. Respiratory tract irritationBenzenesulfonic acid, mono-C10-16-alkyl derivs., sodium salts Category 3 Not applicable. Respiratory tract irritation

Name Category Route of exposure

Target organs

Information on toxicological effects

Acute toxicity

Sodium carbonate LD50 Oral Rat 4090 mg/kg -Disodium metasilicate LD50 Oral Rat 1153 mg/kg -Alcohols, C9-11, ethoxylated LD50 Dermal Rabbit >2 g/kg -

LD50 Oral Rat 1378 mg/kg -

Product/ingredient name Result Species Dose Exposure

Irritation/Corrosion

Sodium carbonate Eyes - Severe irritant Rabbit - 50 mg -Skin - Mild irritant Rabbit - 24 hours 500 mg -Eyes - Mild irritant Rabbit - 0.5 minutes 100

mg-

Eyes - Moderate irritant Rabbit - 24 hours 100 mg -Disodium metasilicate Skin - Moderate irritant Guinea pig - 24 hours 250 mg -

Skin - Severe irritant Human - 24 hours 250 mg -Skin - Severe irritant Rabbit - 24 hours 250 mg -

Product/ingredient name Result Score Exposure Observation

Sensitization

Species

There is no data available.

Information on the likely routes of exposure

Specific target organ toxicity (repeated exposure)

Aspiration hazard

: Not available.





Serious Pad Cleaner

Section 11. Toxicological information

Inhalation : May cause respiratory irritation.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Causes severe burns.

Causes serious eye damage.:Eye contact

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing

Adverse symptoms may include the following:stomach pains

Adverse symptoms may include the following:pain or irritationrednessblistering may occur

:

:

:

Eye contact : Adverse symptoms may include the following:painwateringredness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Oral 2884.3 mg/kg

Route ATE value

Acute toxicity estimates

Potential acute health effects

Potential immediate effects

: No known significant effects or critical hazards.

Short term exposure

Potential delayed effects : No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.


Serious Pad Cleaner

Section 12. Ecological information

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Toxicity

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Sodium carbonate Acute EC50 242000 µg/l Fresh water Algae - Navicula seminulum 96 hoursAcute LC50 176000 µg/l Fresh water Crustaceans - Amphipoda 48 hoursAcute LC50 265000 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours

Disodium metasilicate Acute EC50 33.53 mg/L Fresh water Crustaceans - Ceriodaphnia dubia -Neonate

48 hours

Acute LC50 2320 ppm Fresh water Fish - Gambusia affinis - Adult 96 hoursChronic NOEC 160 mg/L Fresh water Algae - Pseudokirchneriella subcapitata 72 hours

Trisodium orthophosphate Acute LC50 151 ppm Fresh water Fish - Gambusia affinis - Adult 96 hoursAlcohols, C9-11, ethoxylated Acute EC50 5.36 mg/L Fresh water Crustaceans - Ceriodaphnia dubia -

Neonate48 hours

Acute EC50 2686 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hoursAcute LC50 8500 µg/l Fresh water Fish - Pimephales promelas 96 hours

Undecan-1-ol, ethoxylated Acute EC50 6700 µg/l Fresh water Daphnia - Daphnia magna 48 hoursAcute LC50 7100 µg/l Fresh water Fish - Pimephales promelas 96 hours



Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

CORROSIVE SOLID, BASIC,INORGANIC N.O.S. (Disodium metasilicate)



UN3262UN3262 UN3262

DOT Classification IMDG IATA

UN number

UN proper shipping name


Serious Pad Cleaner

Section 14. Transport information8

III

8

III

8

III

Reportable quantity25000 lbs / 11350 kgPackage sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.

- -

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

:

AERG : 154

Section 15. Regulatory informationU.S. Federal regulations

Clean Water Act (CWA) 311: Trisodium orthophosphate

:

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

SARA 302/304

SARA 304 RQ : Not applicable.


SARA 311/312

Classification : Immediate (acute) health hazard


No products were found.


Serious Pad Cleaner

Section 15. Regulatory information

None of the components are listed.

No products were found.

Massachusetts :

California Prop. 65

New York : The following components are listed: Trisodium orthophosphate

New Jersey : The following components are listed: Trisodium orthophosphate

Pennsylvania : The following components are listed: Trisodium orthophosphate

State regulations

Sodium carbonate 30 - 60 No. No. No. Yes. No.Disodium metasilicate 10 - 30 No. No. No. Yes. No.Trisodium orthophosphate 10 - 30 No. No. No. Yes. No.Benzenesulfonic acid, mono-C10-16-alkyl derivs.,sodium salts

1 - 5 No. No. No. Yes. No.

Alcohols, C9-11, ethoxylated 1 - 5 No. No. No. Yes. No.Undecan-1-ol, ethoxylated 1 - 5 No. No. No. Yes. No.

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard

Section 16. Other informationHistory

Prepared by :

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

Date of issue mm/dd/yyyy

Version :

:

1

03/15/2014

KMK Regulatory Services Inc.

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Revised Section(s) : Not applicable.


Documents

Conforms to ANSI Z400.1-2004 Standard (United States, …shurhold.com/wp-content/uploads/2009/12/Click-here-for-MSDS-sheets… · ... Safety glasses, goggles or face shield. Impervious