DATA VALIDATION REVIEW REPORT EPA …newtowncreek.info/docs2/2 Remedial Investigation/Phase 1... · 2015. 10. 21. · Project: Newtown Creek Project Number: 130782-01.01 Date: April

305 West Grand Avenue, Suite 300 Montvale, New Jersey 07645

Phone 201.930.9890 Fax 201.930.9805

www.anchorqea.com

DATA VA L I DAT I O N RE V I E W R E P O R T – EPA STA G E2B Project: Newtown Creek

Project Number: 130782-01.01

Date: April 1, 2013

This validation report summarizes the review of analytical results for 27 water samples, one

field duplicate, one rinse blank, and 6 trip blanks collected September 9-14, 2012. The

samples were collected by Anchor QEA, LLC, and submitted to Alpha Analytical (Alpha) in

Mansfield, Massachusetts. Alpha sample delivery group (SDG) numbers L1216052 and

L1216289 were reviewed in this report. Verification was performed electronically using

Automated Data Review (ADR) software followed by manual validation of the automated

qualifiers. Specific criteria that could not be automatically verified (i.e. tune criteria, select

calibration criteria, etc.) were also manually validated. Electronic and manual qualifications

made during the data validation process can be found in the attached reports referenced

throughout this document. Sample ids of the results reviewed in this report are listed in the

attached EDD Summary Report. The samples were analyzed for the following parameters:

Arsenic by U.S. Environmental Protection Agency (USEPA) method 1632

Chloride, sulfate and bromide (Cl, SO4, and Br-) by USEPA method 300.0

Ammonia (NH3) by USEPA method 350.1

Alkalinity by SM 2320B

Total dissolved solids (TDS) by SM 2540C

Total suspended solids (TSS) by SM 2540D

Kjeldahl nitrogen (KN), nitrate/nitrite, total and dissolved phosphorus by SM 4500

Total and dissolved organic carbon (TOC/DOC) by SM 5310C

Total and dissolved metals by USEPA method 6020

Petroleum hydrocarbons by USEPA method 8015 modified

Volatile organic compounds (VOCs) by USEPA method 8260B

Semivolatile organic compounds (SVOCs) by USEPA method 8270C SIM modified

Total cyanide (CN) by USEPA method 9012A

Particulate organic carbon (POC) by USEPA method 9060 modified

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DATA VALIDATION AND QUALIFICATIONS

The following comments refer to the laboratory’s performance in meeting the quality

assurance/quality control (QA/QC) criteria outlined in Worksheet #36 (Validation Summary

Table) of the Quality Assurance Project Plan (QAPP, Anchor QEA, 2011). Laboratory results

were reviewed using the following:

USEPA Contract Laboratory Program National Functional Guidelines for Organic

Data Review (USEPA 1999).

USEPA Contract Laboratory Program National Functional Guidelines for Inorganic

Data Review (USEPA 2004).

USEPA Contract Laboratory Program National Functional Guidelines for Organic

Data Review (USEPA 2008)

FIELD DOCUMENTATION

Field documentation was checked for completeness and accuracy. The chain-of-custody

forms were signed by Alpha at the time of sample receipt; the samples were received and in

good condition. Two sample containers associated with SDG L1216052 were broken upon

receipt. Sufficient volume remained in additional containers for all requested analyses to be

performed.

HOLDING TIMES AND SAMPLE PRESERVATION

Samples were appropriately preserved and analyzed within holding times.

LABORATORY METHOD BLANKS AND CALIBRATION BLANKS

Laboratory method and calibration blanks were analyzed at the required frequencies. Several

compounds were detected in method blanks at levels between the method detection limit

(MDL) and the project-required quantitation limit (QL). These detections occurred in the

petroleum hydrocarbon, total and dissolved metals, and conventional analyses.

Phenanthrene was detected at a level above the QL in one method blank in SDG L1216052.

Some metals were also detected in initial calibration blanks (ICB) and continuing calibration

blanks (CCB) at levels between the MDL and QL. Associated detected sample results that

were not significantly greater than (>5x) the levels detected in these blanks were qualified

“U” as non-detects. Detected method blank results, associated samples, and qualified sample

results can be found in the attached Method Blank Outlier Report. Qualified sample results

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April 1, 2013

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due to concentrations found in the ICB/CCBs can be found in the attached Manual Changes

History Report.

FIELD QUALITY CONTROL

Rinse Blanks

One rinse blank was collected and analyzed in association with these sample sets. Detected

results are summarized in the attached Rinse Blank Summary Table. No data were qualified

based on rinse blank results.

Trip Blanks

Six trip blanks were analyzed in association with the VOC samples in these SDGs and were

free of target analytes with the exception of acetone which was detected at a level between

the MDL and QL in one trip blank. No data were qualified based on trip blank results.

Field Duplicates

One field duplicate collected in association with these sample sets. Results at or near the QL

(≤5x) may have exaggerated relative percent difference (RPD) values. Non-detected values

were treated as zero for the purposes of calculating RPD values. Detected results are

summarized in the attached Field Duplicate RPD Report. No data were qualified based on

field duplicate results.

INSTRUMENT PERFORMANCE CHECKS

Instrument performance checks were performed at required frequencies. Ion abundance

requirements were met for the VOC method.

INITIAL CALIBRATIONS AND CALIBRATION VERIFICATIONS

All initial calibrations (ICAL), initial calibration verifications (ICV), and continuing

calibration verifications (CCV) associated with reported results met method and validation

criteria with the exceptions of some VOCs. In instances where the percent difference (%D)

value or recovery between the initial calibration and the continuing calibration is above the

control limit, associated detected results have been qualified “J” to indicate a potentially high

bias. Associated non-detect results were not qualified. In instances of a %D value or

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April 1, 2013

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recovery below the control limit, associated sample results have been qualified “J” or “UJ” to

indicate a potentially low bias. Calibration values outside of control limits and associated

sample ids and results are summarized in the attached Calibration Verification Outliers,

Manual Changes History, and Qualification Summary Reports.

INTERNAL STANDARD/SURROGATE RECOVERIES

All internal standard and surrogate recoveries were within method or laboratory control

limits with a few exceptions. Benzo(a)pyrene-d12 and naphthalene-d8 did not recover, or

recovered below control limits, in several samples in SDG L1216052. In all instances where

one of these surrogate recoveries were outside of control limits, the recoveries of the other

two associated surrogate recoveries were within control limits and no qualification was

necessary.

SERIAL DILUTION

Serial dilution analyses were performed and met method criteria with some exceptions. The

serial dilution performed on sample WC001SW-C-20120911 resulted in a %D value above

the control limit for total and dissolved calcium, and for dissolved potassium. The serial

dilution analyses performed on sample DK001SW-A-20120912 resulted in a %D value above

the control limit for total calcium, magnesium, potassium and hardness. Associated sample

results have been qualified “J” or “UJ” to indicate they are estimated.

INTERFERENCE CHECK

Interference check samples (ICS) were analyzed at the required frequency and met method

criteria with the exception of one of the sodium recoveries associated with both SDGs.

Sodium was not reported from the analyses associated with this ICS recovery, and no

qualification was necessary.

LABORATORY CONTROL SAMPLES AND LABORATORY CONTROL SAMPLE DUPLICATES

Laboratory control samples (LCS) and laboratory control sample duplicates (LCSD) were

analyzed at required frequencies and yielded recoveries and/or RPD values within project-

required control limits with the following exceptions:

SDG L1216052:

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April 1, 2013

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o Petroleum hydrocarbons – The LCS and/or LCSD recoveries were below

control limits for dodecane, n-decane and n-nonane. The LCS/LCSD RPD

values for n-decane and n-nonane were also above the control limit.

Associated sample results have been qualified “J” or “UJ” to indicate a

potentially low bias.

o VOCs – Bromomethane recovered below the control limit in both sets of LCS

and LCSDs. Associated sample results have been qualified “UJ” to indicate a

potentially low bias.

o Metals – The LCS recovery for total tin was above control limits. Associated

detected sample results have been qualified “J” to indicate a potentially high

bias.

SDG L1216289:

o VOCs – One of the LCS/LCSD sets recovered below the control limit for

chloromethane and/or bromomethane. Associated sample results have been

qualified “UJ” to indicate a potentially low bias.

o Metals – The LCS recovery for dissolved tin was above control limits.

Associated detected sample results have been qualified “J” to indicate a

potentially high bias.

o Conventionals – The LCS recoveries for bromide, chloride and sulfate

recovered above the control limit in the original analyses of the samples in

this SDG. Samples were reanalyzed and LCS recoveries for these compounds

were within control limits; however the re-analyses occurred outside of

holding time. The original analyses have been reported, and associated

detected sample results have been qualified “J” to indicate a potentially high

bias.

These compounds, the percent recovery values, and associated sample ids are summarized in

the attached Laboratory Control Sample/Laboratory Control Sample Duplicate Outlier

Reports. Edits to electronically applied qualifiers can be found in the attached Manual

Changes History Report.

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April 1, 2013

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STANDARD REFERENCE MATERIAL

Standard reference materials (SRM) were analyzed in lieu of LCSs for some analyses and

recovered within specified limits.

MATRIX SPIKE AND MATRIX SPIKE DUPLICATE

Matrix spike (MS) and matrix spike duplicate (MSD) samples were analyzed at the required

frequencies with the exception of the petroleum hydrocarbon and SVOC analyses in

association with SDG L1216289. If the parent sample concentration is significantly greater

than (>4x) the spike concentration, the MS/MSD recovery and/or RPD limits do not apply.

All MS/MSD results were within these criteria or within project-required control limits with

the following exceptions:

SDG L1216052:

o VOCs – The MS and/or MSD analyzed on samples NC007SW-A-20120909 and

WC001SW-C-20120911 recovered below the control limit for bromomethane and

chloromethane. The associated parent sample results have been qualified “UJ” to

indicate a potentially low bias. Six analytes recovered above the control limits in

the MS and/or MSD analyzed on these samples. These analytes were not detected

in the parent samples so no data were qualified. Methyl acetate did not recover in

the MS analyzed on sample NC007SW-A-20120909; however, the spike level was

at the MDL and could not be accurately quantified so the result was not qualified.

o Petroleum hydrocarbons – The MS analysis performed on sample WC001SW-C-

20120911 recovered below the control limit for n-nonane. The associated sample

result has been qualified “UJ” to indicate a potentially low bias.

o SVOCs – The MS analysis performed on sample WC001SW-C-20120911

recovered below control limits for anthracene and benzo(a)pyrene. The

associated sample results have been qualified “J” to indicate a potentially low bias.

o Metals – The MS analyzed on sample WC001SW-C-20120911 recovered below

the control limit for dissolved antimony. Associated sample results have been

qualified “J” or “UJ” to indicate a potentially low bias.

SDG L1216289:

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April 1, 2013

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o VOCs – The MS and/or MSD analyzed in association with this SDG recovered

outside of control limits for six analytes; however, the MS/MSD were analyzed on

a sample which was not included in this SDG, and no results have been qualified.

These compounds, the percent recovery values, and associated samples can be found in the

attached Matrix Spike/Matrix Spike Duplicate Outlier Reports. Edits to electronically

applied qualifiers can be found in the attached Manual Changes History Report.

LABORATORY DUPLICATES

Laboratory duplicates were analyzed at the required frequencies. If a sample or duplicate

result is less than 5x the QL, the RPD control limit does not apply and the sample and

duplicate result must be within ± QL of each other. All duplicate results were within these

criteria or within project-required control limits with the exceptions of some total Kjeldahl

nitrogen, cyanide, and total suspended solids analyses in association with SDG L1216052.

Associated sample results have been qualified “J” to indicate that they are estimated.

SAMPLE ANALYSES

The laboratory flagged several sample results in both SDGs due to a potentially high bias due

to matrix interference or co-elution with laboratory standards or non-target analytes.

Results that were qualified as non-detects due to method blank contamination or previously

qualified as estimated were not qualified any further. The remaining results will be qualified

“J” to denote the potential high bias upon data processing for upload to the database.

PROJECT REQUIRED QUANTIATION LIMITS

Quantitation limits were acceptable as reported. All values were reported using the

laboratory reporting limits. Values were reported as undiluted, or when reported as diluted,

the QL accurately reflects the dilution factor.

OVERALL ASSESSMENT

As was determined by this evaluation, the laboratory followed the specified analytical

methods and all requested sample analyses were completed. Accuracy was acceptable as

demonstrated by the LCS/LCSD, MS/MSD, SRM, internal standard, surrogate, and/or

interference check recoveries with the exceptions noted above and in the validation reports.

Precision was also acceptable as demonstrated by the laboratory duplicates, LCS/LCSD and

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April 1, 2013

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MS/MSD results with the exceptions noted above and in the validation reports. Most data

were acceptable as reported; other data are acceptable as qualified. Completeness goals were

met. The qualifiers applied to sample results reviewed in this validation report are

summarized in the attached Qualifier Summary Report.

DATA QUALIFIER DEFINITIONS

U Indicates the compound or analyte was analyzed for but not detected at or above the

specified limit.

J Indicates an estimated value.

UJ Indicates the compound or analyte was analyzed for but not detected and the

specified limit reported is estimated

R Indicates data is rejected and unusable

ATTACHED VALIDATION REPORTS

EDD Summary Report by Analysis Method

Outlier Reports

Rinse Blank Summary Table

Field Duplicate RPD Report

History of Manual Changes to Automated Data Review Qualifiers

Data Qualifier Summary

Reason Code Legend (last page of summary)

REFERENCES

Anchor QEA, 2011. Quality Assurance Project Plan, Remedial Investigation/Feasibility

Study, Newton Creek. October.

USEPA, 1999. USEPA Contract Laboratory Program National Functional Guidelines for

Organic Data Review. U.S. Environmental Protection Agency, Office of Emergency

and Remedial Response (OERR). EPA 540-R-99-008. October 1999.

USEPA, 2004. USEPA Contract Laboratory Program National Functional Guidelines for

Inorganic Data Review. U.S. Environmental Protection Agency, Office of Superfund

Newtown Creek

April 1, 2013

Page 9

Remediation and Technology Innovation (OSRTI). EPA 540-R-04-004. October

2004.

USEPA. 2008. USEPA Contract Laboratory Program National Functional Guidelines for

Superfund Organic Methods Data Review. U.S. Environmental Protection Agency,

Office of Superfund Remediation and Technology Innovation. USEPA 540-R-08-01.

June.

Data Review Sample Summary Report by Analysis MethodReviewed By: Approved By: Laboratory: AAL

PreparationMethod Validation CodeClient Sample ID Lab Sample ID Matrix Sample Type Collection Date

Lab Reporting Batch: L1216052

Method: E1632EK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-A-20120911 L1216052-46 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N METHOD 9/11/2012 12:23:00 PM S2BVEMWS


MC008SW-A-20120910 L1216052-33 N METHOD 9/10/2012 2:32:00 PM S2BVEMWS


MC1008SW-A-20120910 L1216052-36 FD METHOD 9/10/2012 2:32:00 PM S2BVEMWS


NC007SW-A-20120909 L1216052-01 N METHOD 9/9/2012 9:19:00 AM S2BVEMWS


NC007SW-C-20120909 L1216052-04 N METHOD 9/9/2012 10:22:00 AM S2BVEMWS


NC034SW-A-20120909 L1216052-14 N METHOD 9/9/2012 1:47:00 PM S2BVEMWS


NC034SW-C-20120909 L1216052-17 N METHOD 9/9/2012 2:45:00 PM S2BVEMWS








4/1/2013 12:27:54 PM ADR version 1.7.0.207 Page 1 of 21



Method: E1632NC068SW-C-20120910 L1216052-23 N METHOD 9/10/2012 10:14:00 AM S2BVEMWS










WC001SW-A-20120911 L1216052-52 N METHOD 9/11/2012 2:32:00 PM S2BVEMWS


WC001SW-C-20120911 L1216052-55 N METHOD 9/11/2012 3:07:00 PM S2BVEMWS


WC001SW-C-20120911DUP WG560485-3 DUP METHOD 9/11/2012 3:07:00 PM S2BVEMWS


WC001SW-C-20120911MS WG560485-4 MS METHOD 9/11/2012 3:07:00 PM S2BVEMWS


Method: E300.0EK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS








Method: E300.0NC007SW-C-20120909 L1216052-04 N METHOD 9/9/2012 10:22:00 AM S2BVEMWS















Method: E350.1EK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS











Method: E350.1NC046SW-A-20120909 L1216052-07 N METHOD 9/9/2012 10:58:00 AM S2BVEMWS





NC070SW-A-20120911DUP WG561383-3 DUP METHOD 9/11/2012 9:27:00 AM S2BVEMWS


NC070SW-C-20120911MS WG561383-4 MS METHOD 9/11/2012 10:36:00 AM S2BVEMWS







Method: SM2320BEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS












Method: SM2320BNC046SW-C-20120909 L1216052-10 N METHOD 9/9/2012 11:48:00 AM S2BVEMWS











Method: SM2540CEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS















Method: SM2540CNC070SW-A-20120911 L1216052-39 N METHOD 9/11/2012 9:27:00 AM S2BVEMWS







Method: SM2540DEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS



















Method: SM2540DWC001SW-A-20120911 L1216052-52 N METHOD 9/11/2012 2:32:00 PM S2BVEMWS



Method: SM4500NO3FEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS























Method: SM4500NO3FNC068SW-A-20120910 L1216052-20 N METHOD 9/10/2012 9:23:00 AM S2BVEMWS




















Method: SM4500NorgCEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS






Method: SM4500NorgCEK014SW-C-20120911 L1216052-49 N METHOD 9/11/2012 12:23:00 PM S2BVEMWS









NC007SW-A-20120909MS WG561447-4 MS METHOD 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-A-20120909MS WG561995-4 MS METHOD 9/9/2012 9:19:00 AM S2BVEMWS

















Method: SM4500NorgCNC068SW-C-20120910 L1216052-24 N METHOD 9/10/2012 10:14:00 AM S2BVEMWS

















Method: SM4500PEEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS









Method: SM4500PEMC1008SW-A-20120910 L1216052-36 FD METHOD 9/10/2012 2:32:00 PM S2BVEMWS



























Method: SM4500PENC079SW-C-20120910 L1216052-29 N METHOD 9/10/2012 11:46:00 AM S2BVEMWS










Method: SM5310CEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS
















Method: SM5310CNC034SW-A-20120909 L1216052-15 N METHOD 9/9/2012 1:47:00 PM S2BVEMWS



























Method: SM5310CWC001SW-C-20120911DUP WG561972-3 DUP METHOD 9/11/2012 3:07:00 PM S2BVEMWS



Method: SW6020AEK014SW-A-20120911 L1216052-45 N SW3005A 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-A-20120911 L1216052-46 N FLDFLT 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N SW3005A 9/11/2012 12:23:00 PM S2BVEMWS

EK014SW-C-20120911 L1216052-49 N FLDFLT 9/11/2012 12:23:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-33 N SW3005A 9/10/2012 2:32:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-34 N FLDFLT 9/10/2012 2:32:00 PM S2BVEMWS

MC1008SW-A-20120910 L1216052-36 FD SW3005A 9/10/2012 2:32:00 PM S2BVEMWS

MC1008SW-A-20120910 L1216052-37 FD FLDFLT 9/10/2012 2:32:00 PM S2BVEMWS

NC007SW-A-20120909 L1216052-01 N SW3005A 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-A-20120909 L1216052-02 N FLDFLT 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-C-20120909 L1216052-04 N SW3005A 9/9/2012 10:22:00 AM S2BVEMWS

NC007SW-C-20120909 L1216052-05 N FLDFLT 9/9/2012 10:22:00 AM S2BVEMWS

NC034SW-A-20120909 L1216052-14 N SW3005A 9/9/2012 1:47:00 PM S2BVEMWS

NC034SW-A-20120909 L1216052-15 N FLDFLT 9/9/2012 1:47:00 PM S2BVEMWS

NC034SW-C-20120909 L1216052-17 N SW3005A 9/9/2012 2:45:00 PM S2BVEMWS

NC034SW-C-20120909 L1216052-18 N FLDFLT 9/9/2012 2:45:00 PM S2BVEMWS








Method: SW6020ANC068SW-A-20120910 L1216052-20 N SW3005A 9/10/2012 9:23:00 AM S2BVEMWS












WC001SW-A-20120911 L1216052-52 N SW3005A 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-A-20120911 L1216052-53 N FLDFLT 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-55 N SW3005A 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-56 N FLDFLT 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911DUP WG563344-3 DUP SW3005A 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911DUP WG563489-3 DUP FLDFLT 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG563344-4 MS SW3005A 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG563489-4 MS FLDFLT 9/11/2012 3:07:00 PM S2BVEMWS

Method: SW8015MEK014SW-A-20120911 L1216052-45 N SW3510C 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N SW3510C 9/11/2012 12:23:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-33 N SW3510C 9/10/2012 2:32:00 PM S2BVEMWS




Method: SW8015MMC1008SW-A-20120910 L1216052-36 FD SW3510C 9/10/2012 2:32:00 PM S2BVEMWS

NC007SW-A-20120909 L1216052-01 N SW3510C 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-C-20120909 L1216052-04 N SW3510C 9/9/2012 10:22:00 AM S2BVEMWS

NC034SW-A-20120909 L1216052-14 N SW3510C 9/9/2012 1:47:00 PM S2BVEMWS

NC034SW-C-20120909 L1216052-17 N SW3510C 9/9/2012 2:45:00 PM S2BVEMWS









WC001SW-A-20120911 L1216052-52 N SW3510C 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-55 N SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG560729-4 MS SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MSD WG560729-5 MSD SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

Method: SW8260CEK014SW-A-20120911 L1216052-45 N SW5030 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N SW5030 9/11/2012 12:23:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-33 N SW5030 9/10/2012 2:32:00 PM S2BVEMWS

MC1008SW-A-20120910 L1216052-36 FD SW5030 9/10/2012 2:32:00 PM S2BVEMWS

NC007SW-A-20120909 L1216052-01 N SW5030 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-A-20120909MS WG562624-6 MS SW5030 9/9/2012 9:19:00 AM S2BVEMWS




Method: SW8260CNC007SW-A-20120909MSD WG562624-7 MSD SW5030 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-C-20120909 L1216052-04 N SW5030 9/9/2012 10:22:00 AM S2BVEMWS

NC034SW-A-20120909 L1216052-14 N SW5030 9/9/2012 1:47:00 PM S2BVEMWS

NC034SW-C-20120909 L1216052-17 N SW5030 9/9/2012 2:45:00 PM S2BVEMWS









SW-TB-20120909 L1216052-13 TB SW5030 9/9/2012 12:55:00 PM S2BVEMWS



WC001SW-A-20120911 L1216052-52 N SW5030 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-55 N SW5030 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG562638-6 MS SW5030 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MSD WG562638-7 MSD SW5030 9/11/2012 3:07:00 PM S2BVEMWS

Method: SW8270DSIMEK014SW-A-20120911 L1216052-45 N SW3510C 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N SW3510C 9/11/2012 12:23:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-33 N SW3510C 9/10/2012 2:32:00 PM S2BVEMWS

MC1008SW-A-20120910 L1216052-36 FD SW3510C 9/10/2012 2:32:00 PM S2BVEMWS




Method: SW8270DSIMNC007SW-A-20120909 L1216052-01 N SW3510C 9/9/2012 9:19:00 AM S2BVEMWS












WC001SW-A-20120911 L1216052-52 N SW3510C 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-55 N SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG560729-4 MS SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MSD WG560729-5 MSD SW3510C 9/11/2012 3:07:00 PM S2BVEMWS

Method: SW9012AEK014SW-A-20120911 L1216052-45 N SW9010B 9/11/2012 11:33:00 AM S2BVEMWS

EK014SW-C-20120911 L1216052-48 N SW9010B 9/11/2012 12:23:00 PM S2BVEMWS

MC008SW-A-20120910 L1216052-33 N SW9010B 9/10/2012 2:32:00 PM S2BVEMWS

MC1008SW-A-20120910 L1216052-36 FD SW9010B 9/10/2012 2:32:00 PM S2BVEMWS

NC007SW-A-20120909 L1216052-01 N SW9010B 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-A-20120909MS WG560671-4 MS SW9010B 9/9/2012 9:19:00 AM S2BVEMWS

NC007SW-A-20120909MSD WG560671-5 MSD SW9010B 9/9/2012 9:19:00 AM S2BVEMWS




Method: SW9012ANC007SW-C-20120909 L1216052-04 N SW9010B 9/9/2012 10:22:00 AM S2BVEMWS

NC034SW-A-20120909 L1216052-14 N SW9010B 9/9/2012 1:47:00 PM S2BVEMWS

NC034SW-C-20120909 L1216052-17 N SW9010B 9/9/2012 2:45:00 PM S2BVEMWS


NC046SW-C-20120909 L1216052-10 N SW9010B 9/9/2012 11:48:00 AM S2BVEMWS







WC001SW-A-20120911 L1216052-52 N SW9010B 9/11/2012 2:32:00 PM S2BVEMWS

WC001SW-C-20120911 L1216052-55 N SW9010B 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911DUP WG560672-6 DUP SW9010B 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MS WG560672-4 MS SW9010B 9/11/2012 3:07:00 PM S2BVEMWS

WC001SW-C-20120911MSD WG560672-5 MSD SW9010B 9/11/2012 3:07:00 PM S2BVEMWS

Method: SW9060MEK014SW-A-20120911 L1216052-45 N METHOD 9/11/2012 11:33:00 AM S2BVEMWS










Method: SW9060MNC034SW-A-20120909 L1216052-14 N METHOD 9/9/2012 1:47:00 PM S2BVEMWS













Validation Label Legend

Label Code Label Decription EPA Level

N/ANV Not_Validated

N/AS1VE Stage_1_Validation_Electronic

N/AS1VEM Stage_1_Validation_Electronic_and_Manual

N/AS1VM Stage_1_Validation_Manual

Level 3 w/o calibrationS2AVE Stage_2A_Validation_Electronic

Level 3 w/o calibrationS2AVEM Stage_2A_Validation_Electronic_and_Manual

Level 3 w/o calibrationS2AVM Stage_2A_Validation_Manual

Level 3 with S2BVE Stage_2B_Validation_Electronic




Level 3 with S2BVEM Stage_2B_Validation_Electronic_and_Manual

Level 3 with S2BVM Stage_2B_Validation_Manual

Level 4S3VE Stage_3_Validation_Electronic

Level 4S3VEM Stage_3_Validation_Electronic_and_Manual

Level 4S3VM Stage_3_Validation_Manual







Lab Reporting Batch: L1216289

Method: E1632DK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912 L1216289-02 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-04 N METHOD 9/12/2012 9:56:00 AM S2BVEMWS






EB010SW-A-20120913 L1216289-23 N METHOD 9/13/2012 10:56:00 AM S2BVEMWS




EK006SW-C-20120914 L1216289-30 N METHOD 9/14/2012 9:31:00 AM S2BVEMWS








NC020SW-C-20120912DUP WG561146-3 DUP METHOD 9/12/2012 3:49:00 PM S2BVEMWS

NC020SW-C-20120912DUP WG561147-3 DUP METHOD 9/12/2012 3:49:00 PM S2BVEMWS




Method: E1632NC020SW-C-20120912MS WG561146-4 MS METHOD 9/12/2012 3:49:00 PM S2BVEMWS

NC020SW-C-20120912MS WG561147-4 MS METHOD 9/12/2012 3:49:00 PM S2BVEMWS

SW-RB-20120914 L1216289-33 EB METHOD 9/14/2012 10:47:00 AM S2BVEMWS

SW-RB-20120914 L1216289-34 EB METHOD 9/14/2012 10:47:00 AM S2BVEMWS

Method: E300.0DK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912DUP WG566277-4 DUP METHOD 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912MS WG566277-3 MS METHOD 9/12/2012 9:17:00 AM S2BVEMWS










Method: E350.1DK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS









Method: E350.1EB010SW-A-20120913 L1216289-23 N METHOD 9/13/2012 10:56:00 AM S2BVEMWS






Method: SM2320BDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS







EK006SW-C-20120914DUP WG561835-4 DUP METHOD 9/14/2012 9:31:00 AM S2BVEMWS

EK006SW-C-20120914MS WG561835-3 MS METHOD 9/14/2012 9:31:00 AM S2BVEMWS




Method: SM2540CDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS







Method: SM2540CDK011SW-C-20120912 L1216289-10 N METHOD 9/12/2012 11:14:00 AM S2BVEMWS







Method: SM2540DDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS










Method: SM4500NO3FDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS








Method: SM4500NO3FDK011SW-A-20120912 L1216289-08 N METHOD 9/12/2012 10:40:00 AM S2BVEMWS



















Method: SM4500NorgCDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS







Method: SM4500NorgCDK001SW-C-20120912 L1216289-04 N METHOD 9/12/2012 9:56:00 AM S2BVEMWS




















Method: SM4500PEDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS






Method: SM4500PEDK001SW-C-20120912 L1216289-05 N METHOD 9/12/2012 9:56:00 AM S2BVEMWS





















Method: SM5310CDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS





Method: SM5310CDK001SW-A-20120912DUP WG563631-3 DUP METHOD 9/12/2012 9:17:00 AM S2BVEMWS






















Method: SW6020ADK001SW-A-20120912 L1216289-01 N SW3005A 9/12/2012 9:17:00 AM S2BVEMWS




Method: SW6020ADK001SW-A-20120912 L1216289-02 N FLDFLT 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912DUP WG563469-3 DUP SW3005A 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912DUP WG563476-3 DUP FLDFLT 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912MS WG563469-4 MS SW3005A 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912MS WG563476-4 MS FLDFLT 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-04 N SW3005A 9/12/2012 9:56:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-05 N FLDFLT 9/12/2012 9:56:00 AM S2BVEMWS

DK011SW-A-20120912 L1216289-07 N SW3005A 9/12/2012 10:40:00 AM S2BVEMWS

DK011SW-A-20120912 L1216289-08 N FLDFLT 9/12/2012 10:40:00 AM S2BVEMWS

DK011SW-C-20120912 L1216289-10 N SW3005A 9/12/2012 11:14:00 AM S2BVEMWS

DK011SW-C-20120912 L1216289-11 N FLDFLT 9/12/2012 11:14:00 AM S2BVEMWS

EB010SW-A-20120913 L1216289-23 N SW3005A 9/13/2012 10:56:00 AM S2BVEMWS

EB010SW-A-20120913 L1216289-24 N FLDFLT 9/13/2012 10:56:00 AM S2BVEMWS

EK006SW-A-20120914 L1216289-27 N SW3005A 9/14/2012 8:39:00 AM S2BVEMWS


EK006SW-C-20120914 L1216289-30 N SW3005A 9/14/2012 9:31:00 AM S2BVEMWS

EK006SW-C-20120914 L1216289-31 N FLDFLT 9/14/2012 9:31:00 AM S2BVEMWS

EK022SW-A-20120913 L1216289-20 N SW3005A 9/13/2012 9:31:00 AM S2BVEMWS


NC020SW-A-20120912 L1216289-14 N SW3005A 9/12/2012 2:58:00 PM S2BVEMWS

NC020SW-A-20120912 L1216289-15 N FLDFLT 9/12/2012 2:58:00 PM S2BVEMWS

NC020SW-C-20120912 L1216289-17 N SW3005A 9/12/2012 3:49:00 PM S2BVEMWS

NC020SW-C-20120912 L1216289-18 N FLDFLT 9/12/2012 3:49:00 PM S2BVEMWS

SW-RB-20120914 L1216289-33 EB SW3005A 9/14/2012 10:47:00 AM S2BVEMWS




Method: SW6020ASW-RB-20120914 L1216289-34 EB FLDFLT 9/14/2012 10:47:00 AM S2BVEMWS

Method: SW8015MDK001SW-A-20120912 L1216289-01 N SW3510C 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-04 N SW3510C 9/12/2012 9:56:00 AM S2BVEMWS

DK011SW-A-20120912 L1216289-07 N SW3510C 9/12/2012 10:40:00 AM S2BVEMWS


EB010SW-A-20120913 L1216289-23 N SW3510C 9/13/2012 10:56:00 AM S2BVEMWS

EK006SW-A-20120914 L1216289-27 N SW3510C 9/14/2012 8:39:00 AM S2BVEMWS

EK006SW-C-20120914 L1216289-30 N SW3510C 9/14/2012 9:31:00 AM S2BVEMWS




SW-RB-20120914 L1216289-33 EB SW3510C 9/14/2012 10:47:00 AM S2BVEMWS

Method: SW8260CDK001SW-A-20120912 L1216289-01 N SW5030 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-04 N SW5030 9/12/2012 9:56:00 AM S2BVEMWS

DK011SW-A-20120912 L1216289-07 N SW5030 9/12/2012 10:40:00 AM S2BVEMWS

DK011SW-C-20120912 L1216289-10 N SW5030 9/12/2012 11:14:00 AM S2BVEMWS

EB010SW-A-20120913 L1216289-23 N SW5030 9/13/2012 10:56:00 AM S2BVEMWS

EK006SW-A-20120914 L1216289-27 N SW5030 9/14/2012 8:39:00 AM S2BVEMWS

EK006SW-C-20120914 L1216289-30 N SW5030 9/14/2012 9:31:00 AM S2BVEMWS

EK022SW-A-20120913 L1216289-20 N SW5030 9/13/2012 9:31:00 AM S2BVEMWS

NC020SW-A-20120912 L1216289-14 N SW5030 9/12/2012 2:58:00 PM S2BVEMWS

NC020SW-C-20120912 L1216289-17 N SW5030 9/12/2012 3:49:00 PM S2BVEMWS




Method: SW8260CSW-RB-20120914 L1216289-33 EB SW5030 9/14/2012 10:47:00 AM S2BVEMWS


SW-TB-20120913 L1216289-26 TB SW5030 9/13/2012 11:42:00 AM S2BVEMWS

SW-TB-20120914 L1216289-36 TB SW5030 9/14/2012 11:08:00 AM S2BVEMWS

Method: SW8270DSIMDK001SW-A-20120912 L1216289-01 N SW3510C 9/12/2012 9:17:00 AM S2BVEMWS


DK011SW-A-20120912 L1216289-07 N SW3510C 9/12/2012 10:40:00 AM S2BVEMWS


EB010SW-A-20120913 L1216289-23 N SW3510C 9/13/2012 10:56:00 AM S2BVEMWS


EK006SW-C-20120914 L1216289-30 N SW3510C 9/14/2012 9:31:00 AM S2BVEMWS




SW-RB-20120914 L1216289-33 EB SW3510C 9/14/2012 10:47:00 AM S2BVEMWS

Method: SW9012ADK001SW-A-20120912 L1216289-01 N SW9010B 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912MS WG561587-4 MS SW9010B 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-A-20120912MSD WG561587-5 MSD SW9010B 9/12/2012 9:17:00 AM S2BVEMWS

DK001SW-C-20120912 L1216289-04 N SW9010B 9/12/2012 9:56:00 AM S2BVEMWS

DK001SW-C-20120912MS WG561633-4 MS SW9010B 9/12/2012 9:56:00 AM S2BVEMWS

DK001SW-C-20120912MSD WG561633-5 MSD SW9010B 9/12/2012 9:56:00 AM S2BVEMWS

DK011SW-A-20120912 L1216289-07 N SW9010B 9/12/2012 10:40:00 AM S2BVEMWS




Method: SW9012ADK011SW-C-20120912 L1216289-10 N SW9010B 9/12/2012 11:14:00 AM S2BVEMWS

EB010SW-A-20120913 L1216289-23 N SW9010B 9/13/2012 10:56:00 AM S2BVEMWS

EK006SW-A-20120914 L1216289-27 N SW9010B 9/14/2012 8:39:00 AM S2BVEMWS

EK006SW-C-20120914 L1216289-30 N SW9010B 9/14/2012 9:31:00 AM S2BVEMWS

EK022SW-A-20120913 L1216289-20 N SW9010B 9/13/2012 9:31:00 AM S2BVEMWS

NC020SW-A-20120912 L1216289-14 N SW9010B 9/12/2012 2:58:00 PM S2BVEMWS

NC020SW-C-20120912 L1216289-17 N SW9010B 9/12/2012 3:49:00 PM S2BVEMWS

Method: SW9060MDK001SW-A-20120912 L1216289-01 N METHOD 9/12/2012 9:17:00 AM S2BVEMWS











Validation Label Legend

Label Code Label Decription EPA Level

N/ANV Not_Validated

N/AS1VE Stage_1_Validation_Electronic




N/AS1VEM Stage_1_Validation_Electronic_and_Manual

N/AS1VM Stage_1_Validation_Manual

Level 3 w/o calibrationS2AVE Stage_2A_Validation_Electronic

Level 3 w/o calibrationS2AVEM Stage_2A_Validation_Electronic_and_Manual

Level 3 w/o calibrationS2AVM Stage_2A_Validation_Manual

Level 3 with S2BVE Stage_2B_Validation_Electronic

Level 3 with S2BVEM Stage_2B_Validation_Electronic_and_Manual

Level 3 with S2BVM Stage_2B_Validation_Manual








Method Blank Outlier ReportLab Reporting Batch ID: L1216052 Laboratory: AALEDD Filename: L1216052 eQAPP Name: Newtown Creek - Alpha

Method: E1632Matrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG560490-1 9/17/2012 1:27:00 PM ARSENIC 0.00016 mg/l EK014SW-A-20120911EK014SW-C-20120911MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910WC001SW-A-20120911WC001SW-C-20120911

Method: E300.0Matrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG562539-1 9/21/2012 9:49:00 PM SULFATE AS SO4 0.17 mg/l EK014SW-A-20120911EK014SW-C-20120911MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910WC001SW-A-20120911WC001SW-C-20120911

Project Name and Number: 120782-01.01 - NEWTOWN CREEK RI2/22/2013 10:05:56 AM ADR version 1.7.0.207 Page 1 of 10


Method: E350.1Matrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG561383-1 9/20/2012 9:46:00 PM Ammonia as nitrogen 0.021 mg/l MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910

Method: SM2540CMatrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG560750-1 9/14/2012 12:55:00 PM TOTAL DISSOLVED SOLIDS 5.0 mg/l EK014SW-A-20120911EK014SW-C-20120911MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910WC001SW-A-20120911WC001SW-C-20120911

Project Name and Number: 120782-01.01 - NEWTOWN CREEK RI2/22/2013 10:05:56 AM ADR version 1.7.0.207 Page 2 of 10


Method: SM4500NO3FMatrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG561255-1 9/17/2012 9:21:00 PM Nitrate + nitrite as nitrogen 0.03 mg/l EK014SW-A-20120911EK014SW-C-20120911MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910WC001SW-A-20120911WC001SW-C-20120911

The following samples and their listed target analytes were qualified due to contamination reported in this blank

Sample ID AnalyteReported

ResultModified

Final ResultEK014SW-A-20120911(RES/DIS) Nitrate + nitrite as nitrogen 0.07 mg/l 0.10U mg/l

EK014SW-C-20120911(RES/DIS) Nitrate + nitrite as nitrogen 0.02 mg/l 0.10U mg/l

NC068SW-C-20120910(RES/DIS) Nitrate + nitrite as nitrogen 0.02 mg/l 0.10U mg/l



Method: SM4500NorgCMatrix: WSMethod Blank Sample ID Analysis Date Analyte Result

AssociatedSamples

WG561447-1 9/20/2012 9:21:00 PM Nitrogen (Kjeldahl) 0.24 mg/l EK014SW-A-20120911MC008SW-A-20120910MC1008SW-A-20120910NC007SW-A-20120909NC007SW-C-20120909NC034SW-A-20120909NC034SW-C-20120909NC046SW-A-20120909NC046SW-C-20120909NC068SW-A-20120910NC068SW-C-20120910NC070SW-A-20120911NC070SW-C-20120911NC079SW-A-20120910NC079SW-C-20120910

The following samples and their listed target analytes were qualified due to contamination reported in this blank

Sample ID AnalyteReported

Documents

DATA VALIDATION REVIEW REPORT EPA …newtowncreek.info/docs2/2 Remedial Investigation/Phase 1... · 2015. 10. 21. · Project: Newtown Creek Project Number: 130782-01.01 Date: April