Effect of Radiative Heat Transfer on Thermal Ignition

Embed Size (px)

Citation preview

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    1/6

    260

    J.THERMOPHYSICS

    VOL.3, NO. 3

    Effect

    of

    Radiative Heat Transfer

    on

    Thermal Ignition

    W .W.Yuen*and S. H.Zhu|

    University of

    California,

    Santa Barbara, Santa Barbara,

    California

    The

    effect

    of

    radiative heat transfer

    on

    thermal ignition

    is

    analyzed numerically.

    Tw o

    specific problems

    are

    considered. They are 1) the semi-in finite problem in which a large mass of hot burnt gas is suddenly brou ght

    into contact with

    a

    large mass

    of

    cold unburnt air/fuel mixture,

    and 2) the finite-hot-slab

    problem

    in

    which

    a finite slab of hot burnt gas is suddenly immersed in a sea of cold unburnt air/fuel mixture. Numerical results

    show that

    in

    both problems

    theradiative

    emission

    and

    absorption

    by

    physical boundaries play essential roles

    in

    determining the effect of radiation on thermal ignition. In general, radiation is shown to have important effects

    on the

    ignition delay.

    For the finite-hot-slab

    problem,

    the

    minimum slab thickness required

    for

    ignition

    is

    also

    shown to depend strongly on the radiation effect. Both the optical thickness of the burnt mixture and the

    unburnt

    mixture

    are

    important

    in

    determining

    the

    actual effect

    of

    radiation.

    Nomenclature

    x

    b

    (t )

    a = absorption coefficient,1/m *s(0

    B

    =

    dimensionless parameter,

    Eq .

    (11

    a) #

    C

    = dimensionless parameter, Eq.(lib)

    c

    =

    specific heat

    of

    gas, KJ/(Kg-K) *

    E

    a

    =

    activation energy,K J / K m o l

    E

    n

    (x) = exponential integral function ^ o

    f ( r f ) =

    dimensionless temperatureprofile, Eq. ^

    (2 1 ) 6/,m

    F n,\

    c

    )

    =

    function utilizedin Eq. (12)

    e

    G/(i

    =

    1,2,3,4,5)

    =

    parameters defined

    by

    Eqs. (A3-A7) f

    / / ( /=1,2,3,4)

    =

    param eters utilized

    in

    Eqs. (22)

    an d

    (23)

    ft

    k - thermal conductivityofgas, W/(m -K)

    K

    u

    = initial optical thick ness of the unbur n t

    f t ,

    mixture

    K

    b

    = initial

    optical

    thickness of the burnt

    ft>(

    r

    )

    mixture

    l

    c

    =characteristic length defined

    by Eq.

    &

    (3b), m

    L =total length of the one-dimensional

    * ?

    system defined

    in

    Fig.

    1, m

    m

    =

    mass loading

    of the

    mixture, Kg/m

    3

    0

    M = dimensionless mass loading definedby c

    Eq. (10)

    M

    bu

    = mass loading ratio,m

    b

    /m

    u

    K

    n

    = complex index of refractionof particles

    K

    b - i

    N(n)

    =function defined

    by Eq.

    (A10)

    *o

    q

    r

    =radiative heat flux, W /m

    2

    * 2 5

    q

    r

    =

    dimensionless rad iative heat

    flux

    K

    L

    Q

    =

    volumetric heat generation rate,

    W/m

    3

    V

    Go

    = characteristic heat of reaction,

    W/m

    3

    P

    R =dimensionless heat generation rate

    defined

    by Eq. (4) r

    R =total dimensionless heat generation

    defined by Eq. (5)

    T

    R

    c

    =universal gas constant, K J/(Kmo l-K)

    T

    m,o

    S = dimensionless temperature gradient, 0(

    T

    )

    /'(O)

    t =t ime,

    s

    t

    c

    =characteristic time d efined by Eq. (3a), s Subscripts

    T = temperature,

    K

    u

    x =space co ordinate, m b

    coordinate

    of the

    foot

    of the

    f lame,

    m

    half-thickness of the f lame, m

    dimensionless temperature ratio defined

    by

    Eq. (9)

    dimensionless half-thickness

    of

    f lame,

    =

    value

    of 6 at

    which

    dr

    m

    /d0

    = 0

    = minimum value of 6 ,-

    = activation number,E

    a

    /R

    c

    T

    b

    = dimensionless length defined by Eq. (2)

    = dimensionless initial position of the foot

    of the

    f lame

    =

    minimum initial slab thickness

    fo r

    ignition

    = d imensionless position of the foot of the

    flame

    = dimensionless length of the one-dimen-

    sional system

    = dimensionless variable defined by

    Eq. (20)

    =

    dimensionless time defined

    by Eq. (2)

    = dimensionless time at which the two

    combustion zones are in contact

    = optical thickness defined by Eq. (9)

    =

    optical thickness defined

    by Eq.

    (A8a)

    = optical thickness defined by Eq. (A8b)

    = optical thickness defined by Eq. (A8c)

    =

    optical thickn ess defined by Eq.

    (A8d)

    = characteristic wavelength, m

    = gas

    density,

    Kg/m

    3

    = Stefan-Boltzmann constant, W/(m

    2

    -K

    4

    )

    =

    dimensionless temperature defined

    by

    Eq. (2)

    =r(0)

    = value of

    T

    m

    at whichdr

    m

    /d0= 0

    =

    dimensionless heat generation rate used

    in

    Eq. (1)

    :

    properties of theun burnt mixture

    properties

    of the

    burnt mixture

    Received

    Feb.

    9,

    1988;

    revision received Ju ne

    23,

    1988.

    C opyright

    American

    Institute of

    Aeronautics

    and

    Astronautics, In c., 1988.

    All

    rights reserved.

    *Professor,

    Department

    of M echanical and Environmental Engi-

    neering. M ember AIAA.

    fGraduate Student,

    D epartment

    of

    M echanical

    and

    Environmental

    Engineering.

    I.

    Introduction

    T

    HE present work is the second in a series of two papers

    that deals with

    th e

    general

    effect of

    radiation

    on

    f lame

    propagation and ignition. In the first paper

    1

    the effect of radi-

    ation

    on

    f lame speed, f lame thickness,

    a nd fuel

    consumption

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    2/6

    JULY

    1989

    RADIATIVE

    THERMAL IGNITION

    261

    rate

    (flame

    propagation parameters that are important after

    ignition has

    occurred)

    w as

    demonstrated.

    The radiative prop-

    erties

    of the combustion products and the reacting mixture,

    together with

    the

    radiation

    from th e

    physical boundaries,

    were

    demon strated to have

    significant

    effectson theflamepropaga-

    tion behavior. The present

    work

    considers the

    effect

    of radi-

    ative heat transfer on thermal ignition. Tw o specific

    one-di-

    mensional problems

    will

    be

    analyzed. First,

    a large mass of

    hot burnt gas is

    suddenly

    brought into

    contact

    with

    a

    large

    mass of

    coldunbu rnt ai r / fuel mixture.

    The

    conditions

    under

    which

    ignition occurs

    and the

    m agnitude

    of the

    ignitiondelay

    will

    be determined.Second,aslabof hot bu rnt gas is

    suddenly

    immersed in a sea of cold unburnt air/fuel

    mixture.

    Thecrit-

    icalconditionsrequired

    fo r

    ignition will

    be

    developed. Based

    on numerical results

    generated

    for the two

    cases,

    th e fund-

    amental

    effect ofradiation (both fromthe medium and

    physi-

    ca l

    boundaries)

    on general

    ignition

    phenomena

    will

    be estab-

    lished.

    In recent years, a number ofworks

    2

    '

    6

    have been

    reported

    dealing

    with

    the general effect of radiation on thermal igni-

    tion. For aone-dimensionalplanar absorbing-emittinghomo-

    geneous medium with volumetric Arrhenius

    heat

    generation,

    the critical ignition parameters

    (similar

    to that derived by

    Frank-Kamenetskii

    7

    in the

    no-radiation

    case)

    f or

    thermal

    igni-

    tiona re

    calculated

    b y

    various

    nume rical techniques or approx-

    imation procedures. In these analyses, the radiative heating

    (or cooling) of the medium b y a hot (cold)wallwas considered

    as the major

    physical

    mechanism leading to

    ignition

    (extinc-

    tion). In manypractical situations,

    however,

    the combustion

    in a

    premixed

    air/fuel

    mixture

    is promoted by the use of

    sparks or pilot flames.

    Ignition

    also can be induced by the

    simultaneous conductive and radiative heating of the pre-

    mixed air/fuel mixture with

    a hot

    wall

    and hot

    combustion

    products .

    Even in an initially

    hom ogeneous air/fuel

    mixture,

    th e heat generation is a function of the

    concentration

    of the

    reacting mixture and temperature. Results from the existing

    works

    2

    '

    6

    are clearly not

    applicable

    fo r

    such

    situations. The

    objective

    to thepresent

    work

    is to illustrate the

    effect

    ofradia-

    tion on theseimportant practicalignition problem s.

    II . Semi-Infinite

    Problem

    The

    physical

    modelisillustratedby Fig. la. A large slab

    of

    hot combustion products at temperature T

    b

    is brought into

    contact

    with a

    large slab

    of

    cold

    unburn t

    air/fuel mixture

    at

    temperature

    T

    u

    .

    T heobjectiveof the analysis is to determine

    conditions under which

    the energy

    generated

    by chemical

    reactioni s

    sufficient

    toovercome thermaldiffusion and ignite

    the unburnt

    m ixture.

    As

    discussed

    in the previous

    work,

    1

    th e

    assumption

    of a

    semi-infinite

    absorbing medium is

    accurate

    only in the optically thick limit. In order to illustrate the

    general

    effect of

    radiation

    for systems

    with arbitrary optical

    thickness, theanalysismu st include the existence of two black

    walls

    of temperature

    T

    u

    an d

    T

    b

    in the considered

    one-dimen-

    sional system as

    shown

    inFig.

    la.

    As in the previous

    wor k ,

    1

    the energy an d

    species

    conserva-

    tion

    equationcan besimplified

    based

    on the

    Shvab-Zeldovich

    transformation and a procedure developed originally by

    Spalding

    8

    to become

    2

    r

    dq

    r

    (1)

    where r, 0, and

    f

    are dimensionless temperature, time, an d

    distance defined

    by

    T T

    (2a)

    T

    b

    -T

    u

    P ( x ) d x

    Pule

    (2b)

    (2c)

    The subscripts

    u

    an d b stand for propertiesevaluated for the

    upstream

    unburned

    reacting mixtures (T=0) and the down-

    stream

    burned products ( j =

    1), respectively. Note that the

    region

    0

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    3/6

    262 W.

    W. Y U E NAND S. H. ZHU

    J. THERMOPHYSICS

    particles

    9

    ),q

    r

    can be generatedreadily fromthe solution to the

    radiative transfer equation as

    u

    = C f

    L

    - fc )

    B

    r(=2-

    K

    +

    0]

    4

    E

    2

    (K - K' ) d K

    f

    - [T(K') +(3 ]

    4

    E

    2

    (

    K

    f

    - K)

    d*'

    (8)

    with

    T

    b

    -T

    u

    9

    d / c

    =CM(f) df

    an d5, Caredimensionless parameters

    given

    by

    C =a

    u

    l

    c

    a

    u

    =

    F n,\

    c

    )p

    u

    m

    u

    (9)

    (10)

    (lla)

    (lib)

    (12)

    Physically,

    small particles in the

    reacting

    mixture and prod-

    ucts are

    assumed

    to be the prim ary species responsible for the

    radiativeabsorption and emission in thedevelopmentofEqs.

    (10-12);

    m( ) represents the mass loading of the small par-

    ticles. The dimensionless parameter

    B

    represents th eratio of

    radiative

    flux

    to reactive

    heat

    generation,

    while

    C stands for

    the optical thickness of the system based on the unburned

    absorption

    coefficient a

    u

    .

    The two

    ends

    of the

    one-dimen-

    sional systemare assumed to be bounded byblack boundary

    at

    temperature

    T

    u

    an d

    T

    b

    ,

    respectively. The

    parameter

    F n,

    A

    c

    )

    is a function of theoptical constant of the

    solid

    particles

    evaluated at a

    characteristic

    wavelength X

    c

    . Th e definition of

    various dimensional

    parametersa re

    given

    in the

    Nom enclature

    section. A more detailed

    discussion

    of the physical assump-

    tions and the

    mathematical

    development of the

    preceding

    equationswerepresented in the earlier work.

    1

    The initialcon-

    dition, as represented byFig. la, can bewritten as

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    4/6

    JULY 1989

    R A D I A T I V E

    THERMAL

    IGNITION

    263

    III. Finite-Hot-Slab Problem

    The physical model is illustrated by Fig. 3. A slab of hot

    combustion products at temperature T

    b

    and thickness 2x/ is

    initially

    surrounded by a cold

    unburn t

    air/fuel mixture at

    temperature T

    u

    o n

    both

    sides.Becauseof thesymmetryof the

    problem,x =0 ischosento be thecenterof theinitialhot slab,

    and the

    totalthickness

    of the medium is taken to be2 L.

    Using

    the same physical assumptions and definition of

    dimensionless

    variables as the

    semi-infinite

    problem,

    the dimensionless

    ener-

    gy

    equation isagaingivenbyEq.(1).Because of the change in

    coordinate

    system

    (f is measured

    from

    the midpoint

    between

    the two

    walls,

    an d K

    L

    no w represents the optical

    thickness

    from theoriginf= 0 to thewallat

    f

    =

    f

    L

    ) ,

    thedimensionless

    radiative

    heat flux

    becomes

    K

    L

    )- E

    3

    (K

    L

    - i c ) ]+

    [T(K')

    +

    0]*E

    2

    (

    K

    - K ' ) d/c '- [r(/O+

    /3]

    4

    2

    (

    K

    '

    - K )

    The initial

    condition,

    as represented by

    Fig.

    3,

    is

    0

    (17)

    (18)

    Forcasesinwhichignitionoccurs,the expected temperature

    profile

    after ignitioni sillustrated

    qua litatively

    b yFig.4a. The

    transient

    flame

    propagating behavior

    is similar to that of the

    semi-infinite

    problem

    as

    presented

    in the previous

    work.

    1

    For

    the extinction

    and almost-ignition

    case,

    the expected

    tempera-

    ture

    profile

    is shown

    qualitatively

    byFig. 4b. The two com-

    bustion zones are in contact, and the temperature at

    f

    = 0 ,

    T

    m

    is

    lessthan 1.0.

    In the

    extinctioncase,r

    m

    decreases mono-

    tonically

    toward

    zero

    after th e

    initial

    contact. If ignition

    occurs, on the other hand, r

    m

    will

    decrease to a minimum

    valuegreater

    than zero

    and,

    subsequently,

    increase. The

    med-

    iu m

    will eventually

    achieve a temperature

    profile similar

    to

    that inFig. 4a, and the flame willpropagate. Sincet he

    objec-

    tive of thepresent analysis is to determine the minimum slab

    thickness required for ignition, the present work willconsider

    only th e

    flame behavior after

    the initial

    contact

    of the two

    combustion

    zones.

    The integral

    method

    will

    be

    used

    to

    deter-

    mine the behavior of r

    m

    an d

    d.

    Specifically, assuming

    that

    the temperature

    profile

    has the

    following

    generalized form,

    0 < f < 2 6

    where

    r j

    is

    given

    by

    r - s

    (19)

    (20)

    As

    demonstrated in Spalding

    8

    and solutions to the semi-in-

    finite

    problem,

    numerical

    predictions

    for the

    ignition

    an d

    flame propagat ion

    behavior are

    insensitive

    to the

    assumed

    dimensionless temperature profile

    /(r/).

    The same expression

    used

    in the

    previous work

    1

    is ,

    thus, assumed

    to be

    applicable

    in the present

    case.

    It is

    1

    (21)

    M athematically, Eq.

    (21)

    is

    generated

    by the

    combination

    of

    tw o

    pieces

    of error functions.

    Numerical

    experiments

    show

    that

    it is an

    dequ te

    approximation of the temperature pro-

    file within

    the

    combustion zone. Notethat

    6, in

    addition

    to

    being the dimensionless thickness of the

    combustion

    zone, can

    also be interpreted as the dimensionless

    flame

    center for the

    present problem. Substituting

    Eq.

    (21)into

    Eq.

    (1),

    and

    inte-

    grating

    from

    0 to

    L

    an d

    from

    6 to

    & ,

    ,

    a set of two

    nonlinear

    ordinary

    differential

    equations can begenerated fo r

    6(0)

    an d

    T

    m

    (0).

    They

    are

    y

    +

    7- *IA

    -

    /

    2

    (/3

    d(r

    m

    5)

    d9

    (22)

    (23)

    with

    S

    =/'(0) being thedimensionless temperature gradient

    atf = 0. Theparameters

    / ,

    7

    2

    ,

    /

    3

    ,

    and7

    4

    ,whichare

    related

    to

    the integral of the dimensionless temperature

    profile

    and heat

    generation

    across

    the combustion zone, have

    been

    evaluated in

    the previous

    wor k .

    1

    Expressionsforq

    r

    (d) and

    q

    r

    ( L)

    are

    given

    indetailin Appen dix A. TheinitialconditionforEqs.(22)and

    (23)

    are

    r

    m

    (0

    c

    )=1.0, 6(0

    C

    )

    =

    S

    7

    (24)

    where

    0

    C

    stands fo r the dimensionless time required by the

    initial

    step-function temperature

    profile (a s

    shown

    in

    Fig.

    3) to

    develop into a

    profile

    in

    which

    the two combustion

    zones

    ar e

    in

    contact

    (as

    shown inFig.4b); B

    c

    an d

    < 5 /(notethat

    in

    general,

    6

    f

    . ft) can be determined from an early time

    solution

    to

    Eq. (1), which is equivalent to the

    semi-infinite

    case.

    As in the semi-infinite

    problem,

    the important dimension-

    less

    parameters for thepresent problem ar e B,

    C ,

    e,

    f t ,

    f

    L

    , |8,

    and themass loadingratioM

    bu

    . Physically,theparameter

    B

    illustrates the

    importance

    of the radiativeeffect relative to the

    chemical

    heat

    generation

    effect. The parameter C is a char-

    acteristic

    optical thicknessthatalso

    represents

    the importance

    of

    th e radiative

    effect

    compared to the conduction effect.

    Again, in

    contrast

    to

    previous

    ignition analyses

    that

    do not

    include

    th e effect ofradiation, th e size and theoptical

    thick-

    ness

    of the

    system(and

    the

    radiative

    emission and

    absorption

    by

    the two cold walls at ft, an d f t , ) play important roles in

    determining

    th e

    effect

    of radiation on ignition.

    To illustrate the

    mathematical

    behaviorof T

    m

    ,it isuseful to

    expand Eq. (23) and combine with Eq . (22) to yield

    (25)

    I-28

    Fig .

    4a Exp ected temperature profile for the finite-slab problem in

    which ignition

    occurs.

    Fig.

    4 b

    Expected

    temperature

    profile

    for the

    finite-slab

    problem in

    which

    possible extinction occurs.

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    5/6

    264

    1.0

    0.8

    0.6

    0 4

    0 2

    W. W. YUEN AN D S . H . ZHU J . THERMOPHYSICS

    100 r

    1rnr

    n

    r

    ~

    r

    n

    r

    ~

    r

    ~ n

    r

    ~

    r r

    i

    r

    8

    F ig. 5 Schematic representation of the numerical

    procedure

    used to

    determine the minimu m ignition thick ness. (Curve A represents the set

    of

    points at

    which

    dr

    m

    /d 5

    =

    0.

    Curves

    i 2 and 3

    represent

    the

    variation

    of

    r

    m

    with

    6 for

    various starting values

    of 5. The starting

    value

    of 5 for curve 1 corresponds approximately to the minimum

    ignition thickness.)

    Since dd/dd

    is

    always

    positive [as it can be

    observed readily

    from

    Eq. (22), and is also consistent

    with

    physical expecta-

    tion]

    , a nd

    dT

    m

    /dO

    always

    starts

    out to be negative at

    0

    =

    d

    c

    [a s

    it

    can be

    observed

    readily from Eq.

    (23)],

    dr

    m

    /d6 is

    also

    negative at 0 =

    6

    C

    .

    If ignition

    occurs,

    T

    m

    must eventually in-

    crease

    back

    to

    1.0.

    This

    requires

    a positive

    dr

    m

    /dd.

    A

    neces-

    sary condition

    fo r

    ignition

    is ,

    thus, dr

    m

    /d d

    = 0 .

    M athemati-

    cally,

    the

    smallest f /

    for which

    such condition

    can be satisfied

    will

    have the physical interpretation of a minimum ignition

    thickness.

    Specifically,

    the

    following

    mathematical

    procedure

    is used

    to determine the minimum thickness

    r

    quired for

    ignition.

    For

    a

    given

    set of specified dimensionless

    parameters,

    a set of

    points T

    W > O

    ^o)atwhich

    dr

    m

    /dS

    = 0 are

    first

    determined from

    Eq .

    (25).

    A

    typical

    set of solutions for

    (r

    w> 0

    ,

    S o )

    are

    illustrated

    inFig.

    5. For

    each

    set of

    r

    m

    6

    0

    ),Eqs. (22)

    a nd

    (23)

    a re

    then

    solved

    ( in

    backward

    time

    step)

    to determine the initial value of

    6 / [which is identical to 5(0

    C

    )]at whichr

    m

    = 1.0.Some typical

    solutions

    for the (j

    mt

    d)

    history generated

    from

    Eqs.

    (22) and

    (23)arealsoshown inFig.5 asillustrations.It can be observed

    readily [andalso

    can be shown rigorously

    from Eqs. (22)

    an d

    (23)] that as 6

    0

    increases, the corresponding 6 / approaches

    asymptotically to a

    constant

    6

    /> m

    .

    M athematically,

    no

    solu-

    tions with

    6 / m

    isdetermined, th e early-time solution can beused

    to relate 6 /

    > /n

    to theminimum

    initial

    slabthickness f /

    > / w

    . Numer-

    ical results,

    however,

    showthat in all cases considered in the

    present work ,

    6 /

    > w

    isessentiallyidentical to

    f/,

    m

    (i.e., the flame

    does

    not move very much during the initial diffusion

    stage);

    6 /

    > m

    thus can be interpreted as the

    minimumhot-slabthickness

    required for ignition.

    As in the previous work,

    1

    a

    survey

    of the physicochemical

    dataand typicalflame

    temperatures

    f or

    common hydrocarbon

    fuels

    10

    suggests values of 5.0 and

    10.72

    foreandB/C,respec-

    tively.Num ericaldatafo r

    other

    values of e (which are of

    some

    practical

    interest in terms of analyzing

    different

    fuels an d

    air/fuel ratios) ar e

    presented

    elsewhere.

    11

    Assuming that f

    L

    =

    1500,

    th e

    minimum ignition

    thicknesses for

    different

    ab -

    sorption

    coefficients

    for the burnt mixture are calculated and

    presented in

    Fig.

    6.The

    no-radiation result,

    which is

    identical

    to that generated bySpalding,

    8

    is presented in the same

    figure

    for

    comparison. The absorption

    coefficient

    of the

    unburnt

    mixture

    does not appear as a parameter in the

    figure

    because

    it

    has

    practically

    n o

    effect

    on the minimum

    ignition

    thickness.

    1.0

    1.0

    0 1

    1 0

    10

    10

    I0

    3

    K

    K

    Fig .6 Effect of the absorp tion coefficient of the burnt

    mixture

    on

    the minimum

    ignition thickness.

    The broken line represents the no-

    radiation

    result.

    1 0

    0 5

    K

    U

    =O.OI

    0 01

    0 1

    1 0

    Fig.

    7 Effects of

    optical

    thicknesses of the

    burnt

    and unburnt

    mixtures on the

    ignition

    delay for the

    finite-slab

    problem (the broken

    line represents the

    no-radiation

    results).

    Physically,

    th e

    major

    effect of

    radiation

    on the

    minimum

    ignition

    thickness is to

    increase

    th e

    heat

    loss from the initial

    burnt mixture to the unburnt mixture an d

    cold

    wall. As the

    optical

    thickness of the

    burn t

    m ixture increases, the radiative

    heat loss increases,

    and a

    larger slab

    of

    burnt mixture

    is re-

    quired fo r ignition. The lack of dependence on the optical

    property of the unburnt mixture

    suggests

    that th e

    radiative

    heattransfer from the hotburn tmixture to thecoldwallis the

    dominating cooling

    effect controlling ignition.

    Another important physical resultassociated wtih th e igni-

    tion

    process is the

    ignition

    delay.

    Assuming f /

    = 50 (which is

    greater than the minimum ignition thickness calculated an d

    presented in

    Fig.

    6

    and, therefore,

    th e

    two-combustion zone

    does no t meet , an d ignition always occurs), results for the

    ignition delay

    ar e

    plotted

    fo r different initial optical

    thick-

    nesses

    K

    b

    an d

    K

    u

    inFig.7 .Notethat

    K

    b

    an dK

    u

    ar e

    still defined

    byEqs. (15)

    and (16). Although the

    optical

    properties of the

    unburn t

    mixture have

    only a small effect on the mini-

    mum

    ignition thickness,

    results in

    Fig.

    7

    show

    that

    i ts

    effect

    on

    the

    ignition

    delay is

    quite significant. Because

    of the increased

    preheating

    of the

    unburn t

    mixture by

    radiative

    absorption,the

    ignition delay decreases with

    increasing

    optical thickness

    of

    th eunburnt mixtureK

    u

    .Increasingthe opticalthicknessof the

    burn t

    mixture,

    on the

    other

    hand,

    first increases

    an d

    then

  • 7/24/2019 Effect of Radiative Heat Transfer on Thermal Ignition

    6/6

    JULY

    1989

    RADIATIVE

    THERMAL IGNITION

    265

    decreases th e

    ignition

    delay. Physically, the increase in the

    optical thickness of theburntmixtureleads to two

    com peting

    effects

    on ignition delay.First, it increases the radiative heat

    lossfrom the burnt mixtureand,second, it leads to additional

    preheatingof the unburnt mixture. For a burnt

    mixture

    with

    small optical

    thickness, the

    first effect

    dominates, and the

    ignition

    delay thus increases with increasing

    optical

    thickness

    of th e

    burnt mixture.

    In the limit of an

    optically

    thick burnt

    mixture, the

    increase

    in

    heat

    loss caused

    by an

    increase

    in

    opti-

    cal thickness

    is

    small compared

    to the

    total energy radiated

    into the unburnt mixture by the burnt

    mixture.

    The second

    effect dominates and leads, therefore, to a reduction in

    ignition delay.

    IV . Conclusions

    An

    approximate

    analysis is

    performed

    to

    determine

    th e

    igni-

    t ion behavior

    of two simple problems: 1) a semi-infinite

    one-

    dimensional problem in which a slab of hot

    burnt

    mixture is

    brought

    into contact with a slab of cold

    unburn t

    air/fuel

    mixture, and 2) a finite-hot-slab problemin which afinite slab

    of

    hot burntmixtureis surrounded by a cold unburntair /fuel

    mixture. Inboth cases, the present work can be considered as

    an

    extension

    of a

    previous

    work by

    Spalding

    8

    with the inclu-

    sion

    of the

    radiative

    heat transfer effect. Th e following

    con-

    clusions

    ar e

    generated:

    1) In general, the radiation

    effect

    increases

    ignition delay

    fo r both

    problems,

    and for the finite-hot-slab problem it in-

    creases

    the minimum

    thickness required

    fo r

    ignition. Physi-

    cally, this is because of the heat-loss

    enhancement

    effect of

    radiation.

    2)

    Radiative emission and absorption by physical bound-

    ariesplayessential roles indetermining the

    effect

    ofradiation

    on

    ignition. Analysesthat assume

    semi-infinite medium

    with-

    out boundary correspond only to cases with

    infinite optical

    thickness.

    Such

    analyses

    ar e

    thus

    not useful in illustrating the

    general effect ofradiation.

    3) For the semi-infinite problem, the ignition delay in-

    creases

    with

    th einitial

    optical

    thickness of the

    burnt

    mixture.

    The

    optical thickness

    of the

    unburn t

    mixture has

    only

    minor

    effect

    on ignition delay, except in the limit of an

    optically

    thick burnt mixture. In the limit of an

    optical

    thick burnt

    mixture

    and an optically

    thin

    unburn t

    mixture,

    ignition

    fails.

    4) For the finite-hot-slab problem, the minimum thickness

    required for ignition increases with

    increasing

    absorption

    coefficient for the hotburn tgas.T heabsorptioncoefficient of

    the unburnt m ixture has

    practically

    no effect on the

    minimum

    ignition thickness.

    5)

    When ignition

    occurs in the finite-hot-slab

    problem,

    th e

    ignition delay

    depends on

    both

    the

    opticalthickness

    of the hot

    burnt

    gas and of the cold unburnt

    mixture.

    The ignition delay

    decreases withincreasingoptical

    thickness

    of the unb urnt mix-

    ture. For a

    fixed

    opticalthicknessof the cold

    unbu rnt mixture,

    increasing the optical thickness of the hot burnt ga s first in -

    creases, and then decreases the

    ignition

    delay.

    Appendix

    Substituting

    Eq.

    (19)

    intoEq.

    (17)

    andevaluatingat f

    L

    and

    < ,

    one

    obtains

    K2 8

    )- E

    3

    (

    KL

    -

    K 2 d

    ) ]

    2Bd(G

    l

    + G

    2

    )

    =2

    (Al)

    2Bd(G

    3

    +G

    4

    -

    G

    5

    ) (A2)

    =

    \i[l-fW]T

    m

    +0}

    4

    E

    2

    [K

    L

    +K

    b

    -

    r

    , -ri)]N ri)dr

    )

    (A3)

    -i

    i

    dr ,

    -/di)]T

    m

    1

    0

    i = \[ T

    m

    f(ri)

    J

    0

    with

    =

    C6[l+(M

    bu

    -

    X L

    =C[ f

    L

    + (M

    bu

    -

    (A4)

    (A5)

    (A6)

    (A7)

    (A8a)

    (A8b)

    (A8c)

    (A8d)

    where

    Physically, K

    O

    is the optical

    thickness

    form f= 0 to the

    flame

    center

    f

    = 6; K

    L

    is the optical

    thickness

    of the half-domain

    ranging

    from f

    = 0 to

    f

    =

    f

    L

    ; K

    2d

    is the

    opticalthickness

    of the

    flame,

    an d

    / ^ - ^ ( r? )stands

    for the

    opticalthickness from f

    = 0

    to an

    arbitrary

    f.

    Th e

    functions A/0?)

    an d

    7 V r ? )

    ar e

    given

    by

    (A9)

    (A10)

    References

    Yuen,

    W. W. and Zhu , S .

    H.,

    TheEffect of

    Thermal R adiation

    on the Propagation of Laminar Flames,

    Proceedings

    of the 8th

    International

    Heat Transfer Conference,

    Vol.

    2, 1986, pp.

    835-842.

    2

    Khalil,H., Shultis,J. K .,and Lester,T. W., StationaryThermal

    Ignitiono f ParticleSuspensions, ASME Transactions of

    th e

    Journal

    of

    Heat Transfer, Vol. 105, M ay 1983, pp.

    288-294.

    3

    Arpaci, V.S., RadiationAffected ThermalIgnition, American

    Society of M echanical Engineers Paper 83-WA/HT-61,

    1983.

    4

    Arpaci,

    V. S. and

    Tabaczynski,

    R . J.,

    "Radiat ion-Affected

    Laminar FlameQuenching, Combustionand Flames,

    Vol.

    57 , 1984,

    pp.

    169-178.

    5

    Arici, O .,

    Radiation

    Affect

    Thermal Ignition Near th e

    Wall,

    Fundamental an d

    Applications

    of

    Radiation Heat Transfer, H TD-

    Vol.

    72 ,

    edited

    b y A . M .

    Smith

    and T. F.

    Smith, American Society

    of

    M echanicalEngineers, New York, 1987, pp.53-57.

    6

    Crosbie, A. L. and Pattabongse, M .,

    Radiative Ignition

    in a

    Planar

    Medium,

    Journal

    of Quantitative Spectroscopy and Radia-

    tive

    Transfer, Vol.

    37, No. 2, 1987, pp . 192-203.

    7

    Frank-Kamenetski i , D. A., Diffusion

    and

    Heat Transfer

    in

    Chemical

    Kinetics,

    Plenum

    Press ,

    1969.

    8

    Spalding, D. B ., Approximate

    Solutions

    of Transient and

    Two-Dimensional

    F lame Phenomena:

    Constant-Enthalpy Flames,

    Philosophical Transactions of the Royal Society of London, Vol.

    245A,

    1957,

    pp. 352-372.

    9

    Yuen,

    W. W . and

    Tien,

    C .L., "A SimpleCalculation Scheme fo r

    Luminous-Flame Emissivity," T he

    Sixteenth

    International

    Sympo-

    sium

    on

    Combustion, The Combustion Inst . ,

    Pit tsburgh,

    P A ,

    1976,

    pp. 1481-1487.

    10

    Kanury, A .

    M ., Introduction

    to

    Combust ion Phenomena, Gor-

    don and Breach Sciences Publisher, 1977.

    H

    Zhu, S . H., "A Study of the Effect of Thermal Radiation on

    Laminar

    Flame Propagation and Ignition,

    Ph.D. Thesis,

    Dept. of

    M echanical and Environm ental Engineering,

    Univ.

    of Cal ifornia,

    Santa Barbara,

    CA,

    1986.