6
FD&C Red 3 2',4',5',7'-Tetraiodoflu orescein disodium salt 2',4',5',7'-Tetraiodoflu oroescein disodium salt 2,4,5,7-Tetraiod ofluorescein disodium salt 9-(o-Carboxy phenyl)-6-hydrox y-2,4,5,7-tetraiod o-3H-xanthen e-3-on disodium salt monohydrate Acid Red 51 Aizen Food Red 3 Aizen erythrosine C.I. 45430 C.I. 773 C.I. Food Red 14 Erythrosin Erythrosin B Erythrosin B sodium salt Erythrosin BS Erythrosine Erythrosine 3B Erythrosine B Erythrosine BS Erythrosine I Erythrosine TB Erythrosine sodium FD and C Red 3 FD and C Red No. 3 Food Color Red 3 Food Dye Red 3 Food Red 14 Food Red 3 Food Red No. 3 Tetraiodofluoresce in sodium salt Fluorescein, 2',4',5',7'-tetraiodo-, disodium salt C20H6I4Na2O5 Not available. LM5950000 16423-68-0 FD135 45430 SPECTRUM LABORATORY PRODUCTS INC. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 CALL (310) 516-8000 SPECTRUM LABORATORY PRODUCTS INC. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 1 1 0 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment Section 1. Chemical Product and Company Identification Common Name/ Trade Name Catalog Number(s). CAS# RTECS CI# Manufacturer Synonym Chemical Name Chemical Family IN CASE OF EMERGENCY CHEMT REC (24hr) 800-424-9300 Chemical Formula Supplier See Section 15. Commercial Name(s) Not available. TSCA TSCA 8(b) inventory: FD&C Red 3 1 1 0 Health Hazard Fire Hazard Reactivity Page Number: 1 Continued on Next Page 

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FD&C Red 3

2',4',5',7'-Tetraiodofluorescein disodium salt2',4',5',7'-Tetraiodofluoroescein disodium salt2,4,5,7-Tetraiodofluorescein disodium salt9-(o-Carboxyphenyl)-6-hydroxy-2,4,5,7-tetraiodo-3H-xanthene-3-ondisodium salt monohydrateAcid Red 51Aizen Food Red 3Aizen erythrosineC.I. 45430C.I. 773C.I. Food Red 14

ErythrosinErythrosin BErythrosin B sodium saltErythrosin BSErythrosineErythrosine 3BErythrosine BErythrosine BSErythrosine IErythrosine TBErythrosine sodiumFD and C Red 3FD and C Red No. 3Food Color Red 3Food Dye Red 3Food Red 14Food Red 3Food Red No. 3Tetraiodofluorescein sodium salt

Fluorescein, 2',4',5',7'-tetraiodo-, disodium salt

C20H6I4Na2O5

Not available.

LM5950000

16423-68-0

FD135

45430

SPECTRUM LABORATORY PRODUCTS INC.

14422 S. SAN PEDRO STREETGARDENA, CA 90248

CALL (310) 516-8000

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

11 0

Material Safety Data SheetNFPA HMIS Personal Protective Equipment

Section 1. Chemical Product and Company Identification 

Common Name/ 

Trade Name

Catalog

Number(s).

CAS#

RTECS

CI#

Manufacturer

Synonym

Chemical Name

Chemical Family

IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300

Chemical Formula

Supplier

See Section 15.

Commercial Name(s) Not available.

TSCA TSCA 8(b) inventory: FD&CRed 3

1

1

0

Health Hazard

Fire Hazard

Reactivity

Page Number: 1

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FD&C Red 3  Page Number: 2 

FD&C Red 3:

  ORAL (LD50): Acute: 1840 mg/kg [Rat]. 1264 mg/kg [Mouse].

1) FD&C Red 3 16423-68-0 100

Toxicological Data

on Ingredients

Name

Section 2.Composition and Information on Ingredients 

 Exposure Limits

TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #

Slightly hazardous in case of skin contact (sensitizer), of eye contact (irritant), of ingestion, of inhalation.

CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.The substance may be toxic to thyroid.Repeated or prolonged exposure to the substance can produce target organs damage.

Section 3. Hazards Identification 

Potential Acute Health Effects

Potential Chronic HealthEffects

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosentight clothing such as a collar, tie, belt or waistband.

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water forat least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.

In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

Not available.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.

Not available.

Not available.

Section 4. First Aid Measures 

Eye Contact

Skin Contact

Serious Skin Contact

Inhalation

Serious Inhalation

Ingestion

Serious Ingestion

Not available.

May be combustible at high temperature.

These products are carbon oxides (CO, CO2), halogenated compounds. Some metallic oxides.

Not available.

Not available.

SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Slightly flammable to flammable in presence of open flames and sparks.

When heated to decomposition it emits very toxic fumes of sodium oxide, and hydrogen iodide. Material inpowder form, capable of creating a dust explosion.

Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.

Section 5. Fire and Explosion Data 

Flammability of the Product

Auto-Ignition Temperature

Flash Points

Flammable Limits

Products of Combustion

Fire Hazards in Presence of Various Substances

Explosion Hazards in Presence

of Various Substances

Fire Fighting Media

and Instructions

Special Remarks on

Fire Hazards

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FD&C Red 3  Page Number: 3 

Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potentialdust explosion hazard.

Special Remarks on ExplosionHazards

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning byspreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading

water on the contaminated surface and allow to evacuate through the sanitary system.

Section 6. Accidental Release Measures 

Small Spill

Large Spill

Keep container tightly closed. Keep container in a cool, well-ventilated area.

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do notingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediatelyand show the container or the label. Keep away from incompatibles such as oxidizing agents.

Section 7. Handling and Storage 

Precautions

Storage

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels belowrecommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keepexposure to airborne contaminants below the exposure limit.

Safety glasses. Lab coat.

Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult aspecialist BEFORE handling this product.

Not available.

Section 8. Exposure Controls/Personal Protection 

Engineering Controls

Personal Protection

Personal Protection in Case of a Large Spill

Exposure Limits

Not available.

Solid. (Powdered solid.)

Not available.

Not available.

Decomposes.

Not available.

Not available.

Not applicable.

The product is equally soluble in oil and water; log(oil/water) = -0.05

Not available.

See solubility in water.

Soluble in cold water.Soluble in alcohol.Solubility in glycerol: 20 g/100 ml @ 25 deg. CSolubility in propylene glycol: 20 g/100 ml @25 deg. CSolubility in Water: 9 g/100 ml @ 25 deg. C

Not available.

Not available.

879.92 g/mole

Not available.

Not available.

Brown. Red.

Section 9. Physical and Chemical Properties 

Physical state and appearance Odor

Taste

Color

Molecular Weight

pH (1% soln/water)

Boiling Point

Melting Point

Critical Temperature

Specific Gravity

Vapor Pressure

Vapor Density

Volatility

Odor Threshold

Water/Oil Dist. Coeff.

Ionicity (in Water)

Dispersion Properties

Solubility

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FD&C Red 3  Page Number: 4 

The product is stable.

Non-corrosive in presence of glass.

Reactive with oxidizing agents.

Not available.

Not available.

Not available.

Excess heat, incompatible materials, dust generation

Section 10. Stability and Reactivity Data 

Stability

Instability Temperature

Conditions of Instability

Incompatibility with various

substances

Corrosivity

Special Remarks on

Reactivity

Special Remarks onCorrosivity

Polymerization Will not occur.

Inhalation. Ingestion.

Acute oral toxicity (LD50): 1264 mg/kg [Mouse].

Slightly hazardous in case of skin contact (sensitizer), of ingestion, of inhalation.

MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.May cause damage to the following organs: thyroid.

Not available.

Acute Potential Health Effects:

Skin: May cause skin irritationEyes: May cause eye irritation.Inhalation: May cause respiratory tract irritation.Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting,diarrhea. May affect behavior/central nervous system (convulsions).Chronic Potential Health Effects:Ingestion: Prolonged or repeated ingestion may affect the thyroid (thyroid hyperfunction)

May affect genetic material (mutagenic)

Section 11. Toxicological Information 

Routes of Entry

Toxicity to Animals

Chronic Effects on Humans

Other Toxic Effects onHumans

Special Remarks onToxicity to Animals

Special Remarks on

Chronic Effects on Humans

Special Remarks on other

Toxic Effects on Humans

Ecotoxicity in water (LC50): 340-900 mg/l 48 hours [Fish (Oryzias latipes)]. 710-1100 mg/l 24 hours [Fish(Oryzias latipes)].

Not available.

Possibly hazardous short term degradation products are not likely. However, long term degradation productsmay arise.

The products of degradation are as toxic as the product itself.

Not available.

Section 12. Ecological Information 

Ecotoxicity

BOD5 and COD

Products of Biodegradation

Toxicity of the Products

of Biodegradation

Special Remarks on the

Products of Biodegradation

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FD&C Red 3  Page Number: 5 

Section 13. Disposal Considerations 

Waste Disposal Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.

DOT Classification Not a DOT controlled material (United States).

Not an IATA controlled material

Not applicable.

Not applicable.

Section 14. Transport Information 

Identification

DOT (Pictograms)

Special Provisions for

Transport

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECSNo. 240-474-8).Canada: Listed on Canadian Domestic Substance List (DSL).China: Listed on National Inventory.Japan: Listed on National Inventory (ENCS).Korea: Listed on National Inventory (KECI).Philippines: Listed on National Inventory (PICCS).

Australia: Listed on AICS.

01

1

1

1

0

a

Not controlled under WHMIS (Canada).

R22- Harmful if swallowed.

Section 15. Other Regulatory Information and Pictograms 

Other Regulations

Other Classifications WHMIS (Canada)

DSCL (EEC)

HMIS (U.S.A.) Health Hazard

Fire Hazard

Reactivity

National Fire Protection

Association (U.S.A.)

Personal Protection

Health

Flammability

Reactivity

Specific hazard

WHMIS (Canada)

(Pictograms)

DSCL (Europe)

(Pictograms)

Federal and StateRegulations

TSCA 8(b) inventory: FD&C Red 3

CaliforniaProposition 65Warnings

California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause cancer which would require a warning under the statute: No products were found.

California prop. 65: This product contains the following ingredients for which the State of California hasfound to cause birth defects which would require a warning under the statute: No products were found.

S46- If swallowed, seek medical adviceimmediately and show this container or label.

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FD&C Red 3  Page Number: 6 

TDG (Canada)

(Pictograms)

ADR (Europe)

(Pictograms)

Protective Equipment

Not applicable.

Lab coat.

Safety glasses.

Not applicable.

Major Uses: colorant; color additive; biological stain

Not available.

CALL (310) 516-8000

 All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.

Notice to Reader

Verified by Sonia Owen.

Printed 8/15/2012.

Validated by Sonia Owen on 8/15/2012.

Other SpecialConsiderations

References

Section 16. Other Information 

MSDS Code F3065