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Negative impacts of heavy oil fired fly ash Prof. Dr. Mamdouh F. Abdel-Sabour International Innovative Environmental Solution Center (IIESC) Prof. Emeritus of soil science, Department of Soil and Water Research, Nuclear Research Center, Atomic Energy Authority. / 444 / 999 a/ 2 sabour/ - http://sa.linkedin.com/pub/mamdouh Sabour - https://www.researchgate.net/profile/Mamdouh_Abdel [email protected] 2007 wise

fly ash landfill

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Table (1). Heavy metals in oil and ash samples (ug/g). Pb Sb Cd Se As Zn Cu Ni Co Mn Cr V Ti

0.16

4

0.028

12

LLD LLD LLD 0.69

8

0.60

5

12.5

4

0.58

23

0.04

12

0.46

6

113

8

0.11

73

Fuel oil

%RSD

9.2

7

0.032

10

0.073

11

0.46

17

0.39

7

56

8

46

7

20

8

4.5

6

15

7

13

8

15

12

11

8

Crude

%RSD

0.18

5

0.024

6

0.005

24

LLD 0.07

29

1.76

5

0.47

4

16

2

6.3

7

0.18

7

0.62

0

225

11

0.12

70

Medium

%RSD

0.28

6

LLD 0.01

32

0.06

68

LLD 0.27

50

0.50

10

39

8

3.3

16

0.15

12

0.72

11

250

7

1.9

12

H. oil

%RSD

87

4

0.97

2

1.99

1

1.90

10

2.6

2

634

3

180

4

4824

5

156

6

258

4

107

2

27 k

9

47

1

Ash

%RSD

556 34 200 475 86 915 302 385 271 6059 235 240 412 factor

%RSD uncertainties of three replicates., LLD (As)=0.03, LLD(Se)=0.004; LLD(Sr)=0.004; Cd=0.01;

LLD(Sb)=0.02.

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Table (2). Radioactivity concentration (Bq/kg) in ashes of burned fuel oil No6.

40

K 238U 235

U 232Th

* 232Th

+ 212Bi 214

Bi 208Ti 214

Pb 212Pb 226

Ra 223Th

20

5 0.65

3.6 4*10

4

6 38

10 0.48

3 70

10 16.7

6 27

35 17

5 63

10 16

14 112

14 X

% + Th and U were directly measured by ICP_MS and then the activities were calculate

This 232

Th value was obtained assuming secular equilibrium along the series and it is clearly

estimated.

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Fly ash land fill impact on the surrounding environment

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Fly ash land fill impact on the surrounding environment

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علي البيئة المحيطة للمردمأثار سالبة واضحة

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علي البيئة المحيطة للمردمأثار سالبة واضحة

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الممارسات الخاطئة في إدارة المردم

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الممارسات الخاطئة في إدارة المردم

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Traps for coming generations

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Fly ash despersion